diff --git a/CHANGELOG b/CHANGELOG
index 5f5552ac1ddd7028ae580e773ac56ef4177020d5..7992abc51d8a7cb2c1a97210ea765b30c1237bf7 100644
--- a/CHANGELOG
+++ b/CHANGELOG
@@ -2,6 +2,7 @@
## <small>0.0.18 (2018-04-23)</small>
* docs: Added bpt1 setup in examples ([a76abff](https://gitlab.pasteur.fr/bis-aria/Ariaec/commit/a76abff))
+* docs: updated changelog ([ceececc](https://gitlab.pasteur.fr/bis-aria/Ariaec/commit/ceececc))
* docs: updated changelog ([95d3f62](https://gitlab.pasteur.fr/bis-aria/Ariaec/commit/95d3f62))
* docs: Updated changelog (removed old tags) ([a59416d](https://gitlab.pasteur.fr/bis-aria/Ariaec/commit/a59416d))
* Added casp rr support when there is no header (pfrmatrr) ([d9d7349](https://gitlab.pasteur.fr/bis-aria/Ariaec/commit/d9d7349))
diff --git a/README.rst b/README.rst
index 293444deabcb16a531bf2f97f0d0fa0d5d1fd36b..e45160cc74ba474bd57ae2b3fe02f9d51587a643 100644
--- a/README.rst
+++ b/README.rst
@@ -41,10 +41,6 @@ Then the easiest solution is to call the **pip** command below :
``pip install git+https://gitlab.pasteur.fr/bis-aria/ariaec``
-Even though it is not recommanded, another possibility is to download the ZIP_
-or TAR_ version from Gitlab_, extract the files and run ``pip install .``
-inside the new directory.
-
For more information about installation and usage, please refer to the
`ARIAEC documentation <http://bis-aria.pages.pasteur.fr/ariaec>`_.
diff --git a/docs/examples/bpt1/bpt1.rst b/docs/examples/bpt1/bpt1.rst
index 3d10002a54e93ce2e7d9c864bd2d11990f8bf9d7..cef8bff8b42944e863a3c37b5509f832347cfed1 100644
--- a/docs/examples/bpt1/bpt1.rst
+++ b/docs/examples/bpt1/bpt1.rst
@@ -1,14 +1,9 @@
BPT1_BOVIN structure prediction with EC map
===========================================
-The files related to this example can be found in the ``docs`` folder or
-:download:`here <docs/examples.tar.gz>`
-
-Setup
------
-
-Here we show an example of setup with GREMLIN contacts with secondary structure
-prediction
+Here we show an example of *de novo* structure prediction from GREMLIN contacts
+combined with secondary structure prediction. The files related to this example
+can be found in the ``docs`` folder or :download:`here <docs/examples.tar.gz>`.
.. note::
@@ -17,9 +12,19 @@ prediction
path of your CNS_ executable (not supplied in this package). Otherwise,
you cannot run this example.
+Contact map analysis
+--------------------
+
.. code-block:: console
- ariaec -o examples/bpt1/out -c examples/bpt1/data/config.ini setup examples/bpt1/data/BPT1_BOVIN.fa examples/bpt1/data/BPT1_BOVIN_contacts.gremlin.out -t gremlin -s examples/bpt1/data/BPT1_BOVIN.indextableplus
+ > ariaec -o examples/bpt1/out maplot examples/bpt1/data/BPT1_BOVIN.fa examples/bpt1/data/BPT1_BOVIN.indextableplus examples/bpt1/.native.aligned.pdb $< -t pdb contactlist maplot --onlyreport $(DATADIR)/$${prot}/$${prot}.fa $${psipred_file} $(DATADIR)/$${prot}/$${prot}.native.aligned.pdb $< -t pdb contactlist
+
+Setup
+-----
+
+.. code-block:: console
+
+ > ariaec -o examples/bpt1/out -c examples/bpt1/data/config.ini setup examples/bpt1/data/BPT1_BOVIN.fa examples/bpt1/data/BPT1_BOVIN_contacts.gremlin.out -t gremlin -s examples/bpt1/data/BPT1_BOVIN.indextableplus
The output should look like this
@@ -77,39 +82,152 @@ The output should look like this
INFO Writing ARIA project file (examples/bpt1/out/ariaproject.xml)
INFO Generate contact file (examples/bpt1/out/etc/BPT1_BOVIN_gremlin_filtered.contact.txt)
-Run
----
+ARIA Setup
+----------
+
+.. code-block:: console
-Once the setup step is done. We can run the generated ARIA_ project using the
-command lines below
+ > aria2 -s examples/bpt1/out/ariaproject.xml
.. code-block:: console
- aria2 -s examples/bpt1/out/ariaproject.xml
- aria2 examples/bpt1/out/ariaproject.xml
+ ARIA Version 2.3.2. Authors: Benjamin Bardiaux, Michael Habeck, Jens Linge,
+ Therese Malliavin, Sean O'Donoghue, Wolfgang Rieping, and Michael Nilges.
-.. warning::
+ If you use this software, please quote the following reference(s):
- Depending on your environment, you probably have to give ``--no-test`` option
- for the second command in order to disable the dry run of the commands
- specified for the structure calculation.
+ Rieping W., Habeck M., Bardiaux B., Bernard A., Malliavin T.E.,
+ Nilges M.(2007) ARIA2: automated NOE assignment and data integration in NMR
+ structure calculation. Bioinformatics 23:381-382
- .. code-block:: console
- aria2 --no-test examples/bpt1/out/ariaproject.xml
+ Loading project "ariaproject.xml"...
+ Setting-up examples/bpt1/out/ariaproject.xml (run: 1)
+ MESSAGE [Project]: Protocols copied.
+ MESSAGE [Project]: Directory tree created.
+ MESSAGE [Project]: Copying data files into local data-directory...
-Analysis
+ Done.
+
+ For running ARIA: aria2 examples/bpt1/out/ariaproject.xml
+
+ARIA Run
--------
-Here is a brief list of files you should look at when all the iteration are finished:
+.. code-block:: console
+
+ > aria2 examples/bpt1/out/ariaproject.xml
-* ARIA ensemble for each iteration. Depending of the activation of the water refinment step, the last ensemble is located within ``runX/structures/itY`` or ``runX/structures/refine`` folder (X is the number related to the last iteration).
-* ``report`` (and ``report.clustering`` if clustering is activated) related to ensemble of generated structure
-* ``itY/analysis`` folder with all structure quality reports generated with Procheck, molprobity, whatif & prosa (iff the executable path are correct in the initial configuration file)
+.. code-block:: console
+
+ ARIA Version 2.3.2. Authors: Benjamin Bardiaux, Michael Habeck, Jens Linge,
+ Therese Malliavin, Sean O'Donoghue, Wolfgang Rieping, and Michael Nilges.
+
+ If you use this software, please quote the following reference(s):
+
+ Rieping W., Habeck M., Bardiaux B., Bernard A., Malliavin T.E.,
+ Nilges M.(2007) ARIA2: automated NOE assignment and data integration in NMR
+ structure calculation. Bioinformatics 23:381-382
+
+
+ Loading project "ariaproject.xml"...
+ MESSAGE [Project]: Temporary directory has been set to /tmp/BPT1_BOVIN/gremlin/
+ aria_temp.tmpw0BTnZ1524489605
+ MESSAGE [Project]: Host list check has been disabled.
+ MESSAGE [Project]: -------------------- Reading data --------------------
+ MESSAGE [Project]: Cache is enabled.
+ MESSAGE [Project]: Cache file does not exist. Creating new file.
+ MESSAGE [Project]: Reading molecule definition examples/bpt1/out/run1/data/
+ sequence/BPT1_BOVIN.xml.
+ MESSAGE [Project]: Data files read.
+ MESSAGE [Project]: Data files cached.
+ MESSAGE [Project]: ------------------- Filtering input data -------------------
+ MESSAGE [NOESYSpectrumFilter.TP]: Spectrum filter report written to file "
+ examples/bpt1/out/run1/data/spectra/
+ peak_list.filtered"
+ MESSAGE [Project]: ---------------- Preparing structure engine ----------------
+ MESSAGE [CNS]: Sequence PDB-file written.
+ MESSAGE [CNS]: PSF-file has been created.
+ MESSAGE [CNS]: Template PDB-file has been created.
+ MESSAGE [Project]: Starting ARIA main protocol on Mon Apr 23 15:20:31 2018
+ MESSAGE [Project]: -------------------- Assigning spectra --------------------
+ MESSAGE [Protocol]: ---------------------- Iteration 0 -----------------------
+
+ MESSAGE [Protocol]: Calibrating spectrum "gremlin"...
+ MESSAGE [Job]: Submitted batch job 18432586 (run_cns_99)
+ MESSAGE [Job]: Submitted batch job 18432587 (run_cns_96)
+ ...
+ MESSAGE [CNS]: Starting analyses...
+ MESSAGE [CNS]: Analyses done. Results are in examples/bpt1/out/run1/structures/
+ it8/analysis
+ MESSAGE [Project]: Temporary directory "/baycells/scratch/fallain/tmp/
+ BPT1_BOVIN/gremlin/aria_temp.tmpRNyO3Q1524493463" removed.
+ MESSAGE [Project]: ARIA run completed at Mon Apr 23 17:25:08 2018
+
+
+Violation analysis
+------------------
+
+Violation analysis for the last iteration
-A more detailed explanation of an ARIA output is on the main ARIA_ website.
+.. code-block:: console
+ > ariaec -c examples/bpt1/data/config.ini -o examples/bpt1/out/run1/structures/it8 analysis -r examples/bpt1/data/BPT1_BOVIN.native.aligned.pdb examples/bpt1/out/ariaproject.xml examples/bpt1/out/run1/structures/it8 gremlin
+
+
+**Output**
+
+.. code-block:: console
+
+ ================================================================================
+
+ ARIA Evolutive Contact toolbox
+
+ ================================================================================
+
+ INFO Initialize settings
+ INFO Updating settings according to config file
+ INFO Reading distance restraints file(s)
+ INFO Wrote 143 xml distance restraints in examples/bpt1/out/run1/structures/it0/unambig_restraints.xml
+ INFO Reading native structure
+ MESSAGE [StructureEnsemble]: Reading PDB files ...
+ MESSAGE [StructureEnsemble]: PDB files read.
+ INFO Reading structure ensemble(s)
+ INFO Clusters found in this iteration, compute analysis foreach generated cluster ensemble
+ INFO Violation analysis
+ INFO Writing violation analysis of clust 0 examples/bpt1/out/run1/structures/it0/violations.csv file
+ INFO Writing violation analysis of clust 1 examples/bpt1/out/run1/structures/it0/violations.csv file
+ MESSAGE [StructureEnsemble]: Reading PDB files ...
+ MESSAGE [StructureEnsemble]: PDB files read.
.. _CNS: http://cns-online.org/v1.3/
.. _ARIA: http://aria.pasteur.fr
+
+.. raw:: html
+ <style>
+ .panel {
+ padding: 0 18px;
+ background-color: white;
+ max-height: 0;
+ overflow: hidden;
+ transition: max-height 0.2s ease-out;
+ }
+ </style>
+
+ <script>
+ var acc = document.getElementsByClassName("accordion");
+ var i;
+
+ for (i = 0; i < acc.length; i++) {
+ acc[i].addEventListener("click", function() {
+ this.classList.toggle("active");
+ var panel = this.nextElementSibling;
+ if (panel.style.maxHeight){
+ panel.style.maxHeight = null;
+ } else {
+ panel.style.maxHeight = panel.scrollHeight + "px";
+ }
+ });
+ }
+ </script>
\ No newline at end of file
diff --git a/docs/examples/bpt1/data/BPT1_BOVIN.native.aligned.pdb b/docs/examples/bpt1/data/BPT1_BOVIN.native.aligned.pdb
new file mode 100644
index 0000000000000000000000000000000000000000..158de6761ead5548d67ce49fd6335e978428adeb
--- /dev/null
+++ b/docs/examples/bpt1/data/BPT1_BOVIN.native.aligned.pdb
@@ -0,0 +1,1048 @@
+ATOM 53 N PHE A 1 35.466 10.210 -7.174 1.00 12.38 N
+ATOM 54 CA PHE A 1 34.975 9.704 -5.855 1.00 13.61 C
+ATOM 55 C PHE A 1 33.438 9.514 -5.843 1.00 13.10 C
+ATOM 56 O PHE A 1 32.937 8.733 -5.020 1.00 13.82 O
+ATOM 57 CB PHE A 1 35.435 10.423 -4.613 1.00 12.65 C
+ATOM 58 CG PHE A 1 34.960 11.819 -4.512 1.00 12.81 C
+ATOM 59 CD1 PHE A 1 33.708 12.036 -3.946 1.00 12.38 C
+ATOM 60 CD2 PHE A 1 35.717 12.897 -4.923 1.00 13.29 C
+ATOM 61 CE1 PHE A 1 33.249 13.321 -3.826 1.00 14.62 C
+ATOM 62 CE2 PHE A 1 35.276 14.180 -4.764 1.00 14.01 C
+ATOM 63 CZ PHE A 1 33.998 14.423 -4.229 1.00 13.69 C
+ATOM 64 D PHE A 1 35.855 11.106 -7.148 1.00 12.61 D
+ATOM 65 HA PHE A 1 35.473 8.781 -5.789 1.00 13.11 H
+ATOM 66 HB2 PHE A 1 34.977 9.863 -3.723 1.00 13.10 H
+ATOM 67 HB3 PHE A 1 36.455 10.163 -4.400 1.00 13.31 H
+ATOM 68 HD1 PHE A 1 33.150 11.213 -3.635 1.00 13.03 H
+ATOM 69 HD2 PHE A 1 36.680 12.699 -5.370 1.00 12.63 H
+ATOM 70 HE1 PHE A 1 32.321 13.499 -3.366 1.00 13.29 H
+ATOM 71 HE2 PHE A 1 35.758 15.036 -5.065 1.00 13.88 H
+ATOM 72 HZ PHE A 1 33.588 15.411 -4.093 1.00 14.46 H
+ATOM 73 N CYS A 2 32.757 10.236 -6.732 1.00 12.49 N
+ATOM 74 CA CYS A 2 31.286 10.029 -6.794 1.00 10.18 C
+ATOM 75 C CYS A 2 30.864 8.652 -7.254 1.00 10.29 C
+ATOM 76 O CYS A 2 29.690 8.279 -7.116 1.00 10.73 O
+ATOM 77 CB CYS A 2 30.794 11.065 -7.789 1.00 10.74 C
+ATOM 78 SG CYS A 2 31.075 12.797 -7.325 1.00 12.66 S
+ATOM 79 D CYS A 2 33.206 10.888 -7.363 1.00 12.80 D
+ATOM 80 HA CYS A 2 30.964 10.266 -5.800 1.00 10.82 H
+ATOM 81 HB2 CYS A 2 31.501 10.869 -8.603 1.00 11.04 H
+ATOM 82 HB3 CYS A 2 29.793 10.892 -8.171 1.00 10.88 H
+ATOM 83 N LEU A 3 31.740 7.909 -7.843 1.00 10.75 N
+ATOM 84 CA LEU A 3 31.467 6.583 -8.351 1.00 12.75 C
+ATOM 85 C LEU A 3 31.799 5.589 -7.246 1.00 13.85 C
+ATOM 86 O LEU A 3 31.435 4.425 -7.543 1.00 15.33 O
+ATOM 87 CB LEU A 3 32.345 6.258 -9.563 1.00 14.73 C
+ATOM 88 CG LEU A 3 32.299 7.212 -10.787 1.00 16.78 C
+ATOM 89 CD1 LEU A 3 33.160 6.693 -11.917 1.00 17.42 C
+ATOM 90 CD2 LEU A 3 30.881 7.341 -11.280 1.00 16.88 C
+ATOM 91 D LEU A 3 32.679 8.218 -7.970 1.00 11.34 D
+ATOM 92 HA LEU A 3 30.422 6.406 -8.558 1.00 13.62 H
+ATOM 93 HB2 LEU A 3 33.392 6.256 -9.245 1.00 14.22 H
+ATOM 94 HB3 LEU A 3 32.141 5.230 -9.918 1.00 14.86 H
+ATOM 95 HG LEU A 3 32.550 8.192 -10.401 1.00 16.74 H
+ATOM 96 HD11 LEU A 3 34.189 6.620 -11.585 1.00 17.89 H
+ATOM 97 HD12 LEU A 3 32.719 5.718 -12.170 1.00 17.82 H
+ATOM 98 HD13 LEU A 3 33.064 7.391 -12.752 1.00 17.88 H
+ATOM 99 HD21 LEU A 3 30.328 6.553 -10.667 1.00 16.77 H
+ATOM 100 HD22 LEU A 3 30.078 8.051 -11.126 1.00 17.21 H
+ATOM 101 HD23 LEU A 3 30.861 7.064 -12.332 1.00 16.98 H
+ATOM 102 N GLU A 4 32.397 5.971 -6.128 1.00 12.79 N
+ATOM 103 CA GLU A 4 32.663 4.924 -5.112 1.00 15.64 C
+ATOM 104 C GLU A 4 31.435 4.576 -4.301 1.00 12.90 C
+ATOM 105 O GLU A 4 30.565 5.427 -4.120 1.00 12.97 O
+ATOM 106 CB AGLU A 4 33.865 5.265 -4.204 0.70 17.43 C
+ATOM 107 CB BGLU A 4 34.000 4.971 -4.371 0.30 15.43 C
+ATOM 108 CG AGLU A 4 34.117 6.694 -3.781 0.70 19.72 C
+ATOM 109 CG BGLU A 4 35.189 5.031 -5.331 0.30 15.96 C
+ATOM 110 CD AGLU A 4 34.935 7.120 -2.561 0.70 20.46 C
+ATOM 111 CD BGLU A 4 35.814 3.742 -5.819 0.30 16.40 C
+ATOM 112 OE1AGLU A 4 36.104 6.753 -2.502 0.70 22.37 O
+ATOM 113 OE1BGLU A 4 35.348 2.965 -6.631 0.30 16.49 O
+ATOM 114 OE2AGLU A 4 34.267 7.823 -1.815 0.70 18.99 O
+ATOM 115 OE2BGLU A 4 35.846 2.854 -4.979 0.30 16.88 O
+ATOM 116 D GLU A 4 32.631 6.879 -5.916 1.00 13.33 D
+ATOM 117 HA GLU A 4 32.837 4.055 -5.770 1.00 14.63 H
+ATOM 118 HB2AGLU A 4 33.913 4.637 -3.325 0.70 18.60 H
+ATOM 119 HB2BGLU A 4 34.007 5.833 -3.693 0.30 15.91 H
+ATOM 120 HB3AGLU A 4 34.757 4.929 -4.809 0.70 17.98 H
+ATOM 121 HB3BGLU A 4 34.147 4.095 -3.748 0.30 15.98 H
+ATOM 122 HG2AGLU A 4 34.689 7.248 -4.538 0.70 19.95 H
+ATOM 123 HG2BGLU A 4 34.911 5.551 -6.241 0.30 15.98 H
+ATOM 124 HG3AGLU A 4 33.221 7.296 -3.671 0.70 19.64 H
+ATOM 125 HG3BGLU A 4 35.976 5.605 -4.862 0.30 16.05 H
+ATOM 126 N PRO A 5 31.351 3.333 -3.911 1.00 13.23 N
+ATOM 127 CA PRO A 5 30.224 2.852 -3.086 1.00 13.50 C
+ATOM 128 C PRO A 5 30.334 3.516 -1.707 1.00 12.26 C
+ATOM 129 O PRO A 5 31.391 3.997 -1.293 1.00 11.77 O
+ATOM 130 CB PRO A 5 30.283 1.334 -2.995 1.00 15.10 C
+ATOM 131 CG PRO A 5 31.757 1.097 -3.199 1.00 16.05 C
+ATOM 132 CD PRO A 5 32.313 2.218 -4.085 1.00 15.37 C
+ATOM 133 HA PRO A 5 29.270 3.086 -3.515 1.00 13.91 H
+ATOM 134 HB2 PRO A 5 29.909 0.979 -2.059 1.00 15.27 H
+ATOM 135 HB3 PRO A 5 29.773 0.877 -3.721 1.00 15.88 H
+ATOM 136 HG2 PRO A 5 32.262 1.339 -2.263 1.00 15.42 H
+ATOM 137 HG3 PRO A 5 31.885 0.245 -3.473 1.00 15.73 H
+ATOM 138 HD2 PRO A 5 33.271 2.433 -3.655 1.00 14.70 H
+ATOM 139 HD3 PRO A 5 32.442 2.084 -5.129 1.00 13.81 H
+ATOM 140 N PRO A 6 29.200 3.631 -1.017 1.00 11.39 N
+ATOM 141 CA PRO A 6 29.160 4.238 0.321 1.00 11.12 C
+ATOM 142 C PRO A 6 29.993 3.377 1.274 1.00 10.17 C
+ATOM 143 O PRO A 6 30.074 2.152 1.156 1.00 12.88 O
+ATOM 144 CB PRO A 6 27.687 4.418 0.604 1.00 11.43 C
+ATOM 145 CG PRO A 6 27.075 3.186 -0.051 1.00 12.21 C
+ATOM 146 CD PRO A 6 27.842 3.087 -1.403 1.00 11.84 C
+ATOM 147 HA PRO A 6 29.948 4.895 0.524 1.00 11.67 H
+ATOM 148 HB2 PRO A 6 27.561 4.500 1.669 1.00 11.73 H
+ATOM 149 HB3 PRO A 6 27.101 5.216 0.385 1.00 11.99 H
+ATOM 150 HG2 PRO A 6 27.438 2.371 0.555 1.00 12.56 H
+ATOM 151 HG3 PRO A 6 26.185 3.227 -0.191 1.00 12.62 H
+ATOM 152 HD2 PRO A 6 28.020 2.060 -1.684 1.00 12.42 H
+ATOM 153 HD3 PRO A 6 27.381 3.649 -2.145 1.00 12.15 H
+ATOM 154 N TYR A 7 30.651 4.022 2.200 1.00 9.53 N
+ATOM 155 CA TYR A 7 31.512 3.320 3.156 1.00 10.73 C
+ATOM 156 C TYR A 7 31.044 3.577 4.617 1.00 9.35 C
+ATOM 157 O TYR A 7 31.146 4.687 5.117 1.00 9.61 O
+ATOM 158 CB TYR A 7 32.937 3.888 2.901 1.00 12.55 C
+ATOM 159 CG TYR A 7 33.970 3.270 3.808 1.00 14.36 C
+ATOM 160 CD1 TYR A 7 34.254 1.932 3.622 1.00 16.08 C
+ATOM 161 CD2 TYR A 7 34.619 4.002 4.797 1.00 14.93 C
+ATOM 162 CE1 TYR A 7 35.226 1.305 4.406 1.00 16.73 C
+ATOM 163 CE2 TYR A 7 35.621 3.422 5.573 1.00 15.90 C
+ATOM 164 CZ TYR A 7 35.896 2.071 5.383 1.00 17.33 C
+ATOM 165 OH TYR A 7 36.861 1.438 6.195 1.00 19.17 O
+ATOM 166 D TYR A 7 30.552 5.011 2.208 1.00 11.16 D
+ATOM 167 HA TYR A 7 31.496 2.274 3.038 1.00 9.89 H
+ATOM 168 HB2 TYR A 7 33.209 3.682 1.839 1.00 12.54 H
+ATOM 169 HB3 TYR A 7 32.886 4.980 2.956 1.00 13.38 H
+ATOM 170 HD1 TYR A 7 33.815 1.318 2.852 1.00 15.57 H
+ATOM 171 HD2 TYR A 7 34.400 5.053 4.955 1.00 15.82 H
+ATOM 172 HE1 TYR A 7 35.521 0.270 4.282 1.00 17.01 H
+ATOM 173 HE2 TYR A 7 36.108 3.926 6.391 1.00 16.44 H
+ATOM 174 DH TYR A 7 37.454 0.912 5.573 1.00 18.49 D
+ATOM 175 N THR A 8 30.520 2.576 5.235 1.00 10.38 N
+ATOM 176 CA THR A 8 30.045 2.720 6.641 1.00 12.46 C
+ATOM 177 C THR A 8 31.223 2.838 7.584 1.00 11.29 C
+ATOM 178 O THR A 8 31.192 3.641 8.497 1.00 11.82 O
+ATOM 179 CB THR A 8 29.228 1.496 7.037 1.00 13.67 C
+ATOM 180 OG1 THR A 8 28.069 1.656 6.232 1.00 15.23 O
+ATOM 181 CG2 THR A 8 28.852 1.446 8.517 1.00 14.27 C
+ATOM 182 D THR A 8 30.436 1.643 4.870 1.00 10.49 D
+ATOM 183 HA THR A 8 29.423 3.601 6.562 1.00 11.61 H
+ATOM 184 HB THR A 8 29.870 0.631 6.788 1.00 14.33 H
+ATOM 185 DG1 THR A 8 27.430 2.351 6.648 1.00 13.46 D
+ATOM 186 HG21 THR A 8 28.326 2.341 8.826 1.00 14.24 H
+ATOM 187 HG22 THR A 8 28.145 0.662 8.885 1.00 14.01 H
+ATOM 188 HG23 THR A 8 29.753 1.305 9.111 1.00 14.17 H
+ATOM 189 N GLY A 9 32.251 2.091 7.350 1.00 12.43 N
+ATOM 190 CA GLY A 9 33.523 2.128 8.130 1.00 13.15 C
+ATOM 191 C GLY A 9 33.399 1.159 9.309 1.00 12.80 C
+ATOM 192 O GLY A 9 32.437 0.461 9.511 1.00 12.30 O
+ATOM 193 D GLY A 9 32.396 1.396 6.648 1.00 13.32 D
+ATOM 194 HA2 GLY A 9 34.329 1.947 7.445 1.00 12.98 H
+ATOM 195 HA3 GLY A 9 33.702 3.161 8.474 1.00 12.73 H
+ATOM 196 N PRO A 10 34.502 1.082 10.072 1.00 14.49 N
+ATOM 197 CA PRO A 10 34.519 0.168 11.227 1.00 13.95 C
+ATOM 198 C PRO A 10 33.916 0.539 12.596 1.00 13.29 C
+ATOM 199 O PRO A 10 33.930 -0.237 13.544 1.00 14.10 O
+ATOM 200 CB PRO A 10 36.012 -0.082 11.370 1.00 13.23 C
+ATOM 201 CG PRO A 10 36.631 1.239 10.992 1.00 14.60 C
+ATOM 202 CD PRO A 10 35.765 1.879 9.928 1.00 13.98 C
+ATOM 203 HA PRO A 10 33.847 -0.643 11.074 1.00 14.35 H
+ATOM 204 HB2 PRO A 10 36.119 -0.140 12.472 1.00 14.34 H
+ATOM 205 HB3 PRO A 10 36.450 -0.937 11.151 1.00 15.01 H
+ATOM 206 HG2 PRO A 10 36.465 1.829 11.916 1.00 14.42 H
+ATOM 207 HG3 PRO A 10 37.553 1.200 10.948 1.00 14.14 H
+ATOM 208 HD2 PRO A 10 35.329 2.839 10.245 1.00 15.29 H
+ATOM 209 HD3 PRO A 10 36.248 1.923 9.001 1.00 14.83 H
+ATOM 210 N CYS A 11 33.434 1.727 12.750 1.00 12.13 N
+ATOM 211 CA CYS A 11 32.817 2.337 13.956 1.00 13.10 C
+ATOM 212 C CYS A 11 31.326 1.931 13.983 1.00 14.28 C
+ATOM 213 O CYS A 11 30.770 1.555 12.956 1.00 14.31 O
+ATOM 214 CB CYS A 11 33.176 3.792 14.087 1.00 11.97 C
+ATOM 215 SG CYS A 11 34.877 4.044 14.560 1.00 12.63 S
+ATOM 216 D CYS A 11 33.427 2.362 11.996 1.00 13.25 D
+ATOM 217 HA CYS A 11 33.224 1.848 14.827 1.00 13.16 H
+ATOM 218 HB2 CYS A 11 33.021 4.260 13.114 1.00 13.49 H
+ATOM 219 HB3 CYS A 11 32.555 4.350 14.792 1.00 13.18 H
+ATOM 220 N LYS A 12 30.797 1.938 15.212 1.00 15.59 N
+ATOM 221 CA LYS A 12 29.455 1.371 15.454 1.00 16.40 C
+ATOM 222 C LYS A 12 28.360 2.334 15.735 1.00 14.53 C
+ATOM 223 O LYS A 12 27.329 1.956 16.299 1.00 16.12 O
+ATOM 224 CB LYS A 12 29.669 0.354 16.551 1.00 20.41 C
+ATOM 225 CG LYS A 12 30.972 -0.476 16.541 1.00 23.07 C
+ATOM 226 CD LYS A 12 30.959 -1.503 15.478 1.00 26.62 C
+ATOM 227 CE LYS A 12 32.296 -2.170 15.136 1.00 30.12 C
+ATOM 228 NZ LYS A 12 31.836 -3.309 14.215 1.00 33.66 N
+ATOM 229 D LYS A 12 31.295 2.148 16.031 1.00 14.44 D
+ATOM 230 HA LYS A 12 29.255 0.802 14.539 1.00 16.86 H
+ATOM 231 HB2 LYS A 12 29.799 0.904 17.523 1.00 20.00 H
+ATOM 232 HB3 LYS A 12 28.831 -0.272 16.908 1.00 19.65 H
+ATOM 233 HG2 LYS A 12 31.824 0.190 16.751 1.00 23.69 H
+ATOM 234 HG3 LYS A 12 30.934 -0.947 17.555 1.00 23.35 H
+ATOM 235 HD2 LYS A 12 30.314 -2.379 15.590 1.00 26.65 H
+ATOM 236 HD3 LYS A 12 30.655 -1.058 14.485 1.00 26.43 H
+ATOM 237 HE2 LYS A 12 32.766 -1.611 14.351 1.00 30.52 H
+ATOM 238 HE3 LYS A 12 32.769 -2.717 15.928 1.00 30.42 H
+ATOM 239 DZ1 LYS A 12 31.352 -2.960 13.354 1.00 32.81 D
+ATOM 240 DZ2 LYS A 12 32.722 -3.881 14.018 1.00 33.31 D
+ATOM 241 DZ3 LYS A 12 31.212 -4.018 14.678 1.00 32.78 D
+ATOM 242 N ALA A 13 28.538 3.555 15.339 1.00 12.01 N
+ATOM 243 CA ALA A 13 27.519 4.598 15.454 1.00 12.90 C
+ATOM 244 C ALA A 13 26.498 4.287 14.310 1.00 12.51 C
+ATOM 245 O ALA A 13 26.836 3.476 13.402 1.00 13.19 O
+ATOM 246 CB ALA A 13 27.988 6.045 15.277 1.00 11.07 C
+ATOM 247 D ALA A 13 29.382 3.725 14.844 1.00 15.12 D
+ATOM 248 HA ALA A 13 27.005 4.610 16.375 1.00 11.30 H
+ATOM 249 HB1 ALA A 13 28.805 6.350 15.920 1.00 12.51 H
+ATOM 250 HB2 ALA A 13 28.517 6.226 14.332 1.00 12.25 H
+ATOM 251 HB3 ALA A 13 27.104 6.681 15.367 1.00 12.27 H
+ATOM 252 N ARG A 14 25.365 4.924 14.324 1.00 12.27 N
+ATOM 253 CA ARG A 14 24.373 4.865 13.248 1.00 13.57 C
+ATOM 254 C ARG A 14 24.031 6.307 12.896 1.00 11.67 C
+ATOM 255 O ARG A 14 23.100 6.914 13.431 1.00 13.64 O
+ATOM 256 CB ARG A 14 23.121 4.138 13.566 1.00 15.95 C
+ATOM 257 CG ARG A 14 23.529 2.682 13.790 1.00 21.32 C
+ATOM 258 CD ARG A 14 22.243 2.045 14.156 1.00 25.64 C
+ATOM 259 NE ARG A 14 21.702 1.586 12.894 1.00 32.90 N
+ATOM 260 CZ ARG A 14 20.864 1.665 11.854 1.00 35.77 C
+ATOM 261 NH1 ARG A 14 19.924 2.628 11.721 1.00 36.79 N
+ATOM 262 NH2 ARG A 14 20.970 0.717 10.868 1.00 36.81 N
+ATOM 263 D ARG A 14 25.215 5.619 15.055 1.00 13.85 D
+ATOM 264 HA ARG A 14 24.803 4.465 12.336 1.00 12.52 H
+ATOM 265 HB2 ARG A 14 22.566 4.456 14.456 1.00 17.10 H
+ATOM 266 HB3 ARG A 14 22.446 4.306 12.740 1.00 17.01 H
+ATOM 267 HG2 ARG A 14 24.096 2.201 13.028 1.00 20.76 H
+ATOM 268 HG3 ARG A 14 24.162 2.597 14.652 1.00 20.12 H
+ATOM 269 HD2 ARG A 14 22.509 1.196 14.762 1.00 27.02 H
+ATOM 270 HD3 ARG A 14 21.617 2.668 14.729 1.00 26.69 H
+ATOM 271 DE ARG A 14 22.338 0.732 12.765 1.00 34.58 D
+ATOM 272 DH11 ARG A 14 19.809 3.376 12.418 1.00 35.94 D
+ATOM 273 DH12 ARG A 14 19.300 2.647 10.901 1.00 35.75 D
+ATOM 274 DH21 ARG A 14 21.641 -0.055 10.942 1.00 35.56 D
+ATOM 275 DH22 ARG A 14 20.319 0.741 10.088 1.00 35.91 D
+ATOM 276 N ILE A 15 24.783 6.955 12.017 1.00 10.78 N
+ATOM 277 CA ILE A 15 24.709 8.341 11.537 1.00 10.61 C
+ATOM 278 C ILE A 15 24.204 8.278 10.079 1.00 10.94 C
+ATOM 279 O ILE A 15 24.876 7.679 9.249 1.00 10.62 O
+ATOM 280 CB ILE A 15 26.042 9.082 11.623 1.00 11.97 C
+ATOM 281 CG1 ILE A 15 26.652 9.020 13.051 1.00 13.12 C
+ATOM 282 CG2 ILE A 15 25.974 10.525 11.176 1.00 10.95 C
+ATOM 283 CD1 ILE A 15 28.148 9.276 13.084 1.00 13.42 C
+ATOM 284 H ILE A 15 25.549 6.401 11.624 1.00 11.76 H
+ATOM 285 HA ILE A 15 24.000 8.847 12.188 1.00 11.05 H
+ATOM 286 HB ILE A 15 26.865 8.594 11.118 1.00 11.50 H
+ATOM 287 HG12 ILE A 15 25.954 9.414 13.777 1.00 13.26 H
+ATOM 288 HG13 ILE A 15 26.548 7.951 13.380 1.00 13.89 H
+ATOM 289 HG21 ILE A 15 25.331 10.602 10.286 1.00 11.59 H
+ATOM 290 HG22 ILE A 15 25.493 11.179 11.921 1.00 12.37 H
+ATOM 291 HG23 ILE A 15 26.964 10.890 10.940 1.00 12.46 H
+ATOM 292 HD11 ILE A 15 28.535 10.191 12.656 1.00 14.38 H
+ATOM 293 HD12 ILE A 15 28.455 8.952 14.098 1.00 13.86 H
+ATOM 294 HD13 ILE A 15 28.699 8.514 12.441 1.00 13.73 H
+ATOM 295 N ILE A 16 23.050 8.866 9.854 1.00 10.63 N
+ATOM 296 CA ILE A 16 22.472 8.852 8.467 1.00 11.65 C
+ATOM 297 C ILE A 16 23.093 9.970 7.681 1.00 10.38 C
+ATOM 298 O ILE A 16 23.078 11.156 8.055 1.00 12.22 O
+ATOM 299 CB ILE A 16 20.954 9.049 8.496 1.00 13.30 C
+ATOM 300 CG1 ILE A 16 20.478 7.843 9.308 1.00 15.24 C
+ATOM 301 CG2 ILE A 16 20.383 9.074 7.118 1.00 13.64 C
+ATOM 302 CD1 ILE A 16 21.047 6.435 9.116 1.00 16.83 C
+ATOM 303 D ILE A 16 22.527 9.412 10.455 1.00 10.47 D
+ATOM 304 HA ILE A 16 22.918 7.937 8.132 1.00 10.97 H
+ATOM 305 HB ILE A 16 20.852 10.028 8.952 1.00 14.17 H
+ATOM 306 HG12 ILE A 16 20.631 8.038 10.370 1.00 15.45 H
+ATOM 307 HG13 ILE A 16 19.392 7.700 9.202 1.00 15.29 H
+ATOM 308 HG21 ILE A 16 20.776 8.130 6.682 1.00 13.57 H
+ATOM 309 HG22 ILE A 16 19.302 8.957 7.044 1.00 13.63 H
+ATOM 310 HG23 ILE A 16 20.641 9.847 6.406 1.00 14.10 H
+ATOM 311 HD11 ILE A 16 22.105 6.190 9.208 1.00 15.89 H
+ATOM 312 HD12 ILE A 16 20.411 5.657 9.580 1.00 16.70 H
+ATOM 313 HD13 ILE A 16 20.856 6.216 8.025 1.00 15.33 H
+ATOM 314 N ARG A 17 23.726 9.516 6.564 1.00 10.55 N
+ATOM 315 CA ARG A 17 24.442 10.455 5.670 1.00 10.78 C
+ATOM 316 C ARG A 17 23.927 10.184 4.206 1.00 9.27 C
+ATOM 317 O ARG A 17 23.300 9.191 3.965 1.00 10.69 O
+ATOM 318 CB ARG A 17 25.962 10.178 5.691 1.00 9.44 C
+ATOM 319 CG ARG A 17 26.624 10.625 7.025 1.00 10.78 C
+ATOM 320 CD ARG A 17 26.683 12.084 7.147 1.00 12.14 C
+ATOM 321 NE ARG A 17 27.301 12.496 8.436 1.00 13.47 N
+ATOM 322 CZ ARG A 17 28.569 12.515 8.793 1.00 14.63 C
+ATOM 323 NH1 ARG A 17 29.528 12.120 7.954 1.00 14.38 N
+ATOM 324 NH2 ARG A 17 28.880 12.930 10.036 1.00 15.39 N
+ATOM 325 H ARG A 17 23.787 8.592 6.237 1.00 11.60 H
+ATOM 326 HA ARG A 17 24.058 11.425 5.818 1.00 9.96 H
+ATOM 327 HB2 ARG A 17 25.997 9.096 5.514 1.00 11.42 H
+ATOM 328 HB3 ARG A 17 26.473 10.556 4.823 1.00 11.61 H
+ATOM 329 HG2 ARG A 17 26.061 10.144 7.831 1.00 10.85 H
+ATOM 330 HG3 ARG A 17 27.535 10.103 7.169 1.00 11.31 H
+ATOM 331 HD2 ARG A 17 27.287 12.570 6.390 1.00 12.19 H
+ATOM 332 HD3 ARG A 17 25.902 12.789 7.042 1.00 11.77 H
+ATOM 333 DE ARG A 17 26.641 12.861 9.099 1.00 15.00 D
+ATOM 334 DH11 ARG A 17 30.497 12.035 8.190 1.00 15.45 D
+ATOM 335 DH12 ARG A 17 29.294 11.758 7.027 1.00 15.68 D
+ATOM 336 DH21 ARG A 17 29.867 12.914 10.308 1.00 13.82 D
+ATOM 337 DH22 ARG A 17 28.137 13.263 10.632 1.00 14.55 D
+ATOM 338 N TYR A 18 24.290 11.111 3.341 1.00 9.20 N
+ATOM 339 CA TYR A 18 23.980 10.950 1.898 1.00 8.22 C
+ATOM 340 C TYR A 18 25.230 10.503 1.171 1.00 8.71 C
+ATOM 341 O TYR A 18 26.337 10.911 1.504 1.00 8.47 O
+ATOM 342 CB TYR A 18 23.571 12.308 1.316 1.00 9.14 C
+ATOM 343 CG TYR A 18 22.096 12.567 1.577 1.00 10.30 C
+ATOM 344 CD1 TYR A 18 21.657 13.359 2.656 1.00 10.02 C
+ATOM 345 CD2 TYR A 18 21.170 12.008 0.718 1.00 10.29 C
+ATOM 346 CE1 TYR A 18 20.312 13.586 2.819 1.00 11.24 C
+ATOM 347 CE2 TYR A 18 19.795 12.189 0.909 1.00 11.46 C
+ATOM 348 CZ TYR A 18 19.370 13.026 1.971 1.00 12.26 C
+ATOM 349 OH TYR A 18 17.995 13.168 2.092 1.00 13.81 O
+ATOM 350 H TYR A 18 24.869 11.855 3.627 1.00 9.54 H
+ATOM 351 HA TYR A 18 23.253 10.171 1.894 1.00 9.45 H
+ATOM 352 HB2 TYR A 18 24.218 13.154 1.485 1.00 10.74 H
+ATOM 353 HB3 TYR A 18 23.593 12.133 0.220 1.00 9.35 H
+ATOM 354 HD1 TYR A 18 22.396 13.821 3.302 1.00 11.00 H
+ATOM 355 HD2 TYR A 18 21.487 11.347 -0.072 1.00 10.53 H
+ATOM 356 HE1 TYR A 18 19.977 14.203 3.642 1.00 10.87 H
+ATOM 357 HE2 TYR A 18 19.073 11.749 0.247 1.00 11.44 H
+ATOM 358 DH TYR A 18 17.713 13.930 2.654 1.00 14.85 D
+ATOM 359 N PHE A 19 24.953 9.731 0.125 1.00 7.43 N
+ATOM 360 CA PHE A 19 25.997 9.344 -0.804 1.00 6.76 C
+ATOM 361 C PHE A 19 25.379 9.511 -2.224 1.00 7.20 C
+ATOM 362 O PHE A 19 24.147 9.372 -2.366 1.00 7.41 O
+ATOM 363 CB PHE A 19 26.543 7.944 -0.689 1.00 6.59 C
+ATOM 364 CG PHE A 19 25.670 6.853 -1.112 1.00 7.76 C
+ATOM 365 CD1 PHE A 19 25.945 6.167 -2.285 1.00 8.47 C
+ATOM 366 CD2 PHE A 19 24.511 6.513 -0.412 1.00 8.78 C
+ATOM 367 CE1 PHE A 19 25.147 5.127 -2.683 1.00 9.15 C
+ATOM 368 CE2 PHE A 19 23.691 5.457 -0.800 1.00 9.59 C
+ATOM 369 CZ PHE A 19 24.024 4.780 -1.963 1.00 9.79 C
+ATOM 370 H PHE A 19 24.062 9.484 -0.227 1.00 8.93 H
+ATOM 371 HA PHE A 19 26.914 9.910 -0.832 1.00 6.50 H
+ATOM 372 HB2 PHE A 19 27.448 8.048 -1.293 1.00 7.09 H
+ATOM 373 HB3 PHE A 19 26.675 7.814 0.433 1.00 5.77 H
+ATOM 374 HD1 PHE A 19 26.792 6.452 -2.819 1.00 8.71 H
+ATOM 375 HD2 PHE A 19 24.305 7.028 0.503 1.00 8.57 H
+ATOM 376 HE1 PHE A 19 25.378 4.634 -3.594 1.00 9.13 H
+ATOM 377 HE2 PHE A 19 22.866 5.192 -0.228 1.00 9.05 H
+ATOM 378 HZ PHE A 19 23.411 3.987 -2.299 1.00 9.64 H
+ATOM 379 N TYR A 20 26.248 9.721 -3.224 1.00 8.20 N
+ATOM 380 CA TYR A 20 25.779 9.725 -4.634 1.00 7.28 C
+ATOM 381 C TYR A 20 25.786 8.322 -5.124 1.00 7.57 C
+ATOM 382 O TYR A 20 26.818 7.621 -5.132 1.00 8.16 O
+ATOM 383 CB TYR A 20 26.759 10.511 -5.499 1.00 9.85 C
+ATOM 384 CG TYR A 20 26.248 10.666 -6.944 1.00 9.96 C
+ATOM 385 CD1 TYR A 20 26.914 10.044 -7.987 1.00 10.97 C
+ATOM 386 CD2 TYR A 20 25.125 11.475 -7.226 1.00 11.33 C
+ATOM 387 CE1 TYR A 20 26.451 10.178 -9.295 1.00 11.27 C
+ATOM 388 CE2 TYR A 20 24.587 11.603 -8.518 1.00 11.73 C
+ATOM 389 CZ TYR A 20 25.294 10.925 -9.501 1.00 11.91 C
+ATOM 390 OH TYR A 20 24.839 11.085 -10.793 1.00 14.10 O
+ATOM 391 H TYR A 20 27.210 9.753 -3.004 1.00 7.41 H
+ATOM 392 HA TYR A 20 24.818 10.226 -4.744 1.00 8.02 H
+ATOM 393 HB2 TYR A 20 26.593 11.519 -5.121 1.00 9.84 H
+ATOM 394 HB3 TYR A 20 27.819 10.292 -5.414 1.00 9.27 H
+ATOM 395 HD1 TYR A 20 27.785 9.438 -7.850 1.00 10.63 H
+ATOM 396 HD2 TYR A 20 24.614 11.894 -6.350 1.00 10.81 H
+ATOM 397 HE1 TYR A 20 26.909 9.696 -10.142 1.00 11.58 H
+ATOM 398 HE2 TYR A 20 23.716 12.164 -8.754 1.00 11.77 H
+ATOM 399 DH TYR A 20 24.638 12.063 -10.743 1.00 14.22 D
+ATOM 400 N ASN A 21 24.618 7.831 -5.550 1.00 7.53 N
+ATOM 401 CA ASN A 21 24.473 6.511 -6.126 1.00 8.25 C
+ATOM 402 C ASN A 21 24.533 6.730 -7.657 1.00 9.26 C
+ATOM 403 O ASN A 21 23.605 7.147 -8.338 1.00 9.06 O
+ATOM 404 CB ASN A 21 23.099 5.973 -5.764 1.00 9.60 C
+ATOM 405 CG ASN A 21 22.895 4.611 -6.330 1.00 10.11 C
+ATOM 406 OD1 ASN A 21 23.537 4.204 -7.313 1.00 13.10 O
+ATOM 407 ND2 ASN A 21 21.966 3.903 -5.800 1.00 12.51 N
+ATOM 408 H ASN A 21 23.768 8.406 -5.560 1.00 7.95 H
+ATOM 409 HA ASN A 21 25.252 5.817 -5.749 1.00 7.93 H
+ATOM 410 HB2 ASN A 21 23.193 5.827 -4.660 1.00 8.09 H
+ATOM 411 HB3 ASN A 21 22.291 6.679 -5.844 1.00 9.60 H
+ATOM 412 DD21 ASN A 21 21.767 2.914 -6.106 1.00 12.19 D
+ATOM 413 DD22 ASN A 21 21.419 4.231 -5.010 1.00 11.93 D
+ATOM 414 N ALA A 22 25.690 6.499 -8.244 1.00 10.90 N
+ATOM 415 CA ALA A 22 25.937 6.771 -9.710 1.00 12.18 C
+ATOM 416 C ALA A 22 25.108 5.883 -10.665 1.00 11.03 C
+ATOM 417 O ALA A 22 24.972 6.315 -11.816 1.00 12.22 O
+ATOM 418 CB ALA A 22 27.438 6.846 -9.903 1.00 11.38 C
+ATOM 419 D ALA A 22 26.523 6.274 -7.738 1.00 10.47 D
+ATOM 420 HA ALA A 22 25.558 7.786 -9.716 1.00 11.28 H
+ATOM 421 HB1 ALA A 22 28.036 7.257 -9.107 1.00 12.88 H
+ATOM 422 HB2 ALA A 22 27.681 5.764 -9.848 1.00 12.72 H
+ATOM 423 HB3 ALA A 22 27.740 7.086 -10.895 1.00 12.70 H
+ATOM 424 N LYS A 23 24.672 4.739 -10.226 1.00 10.74 N
+ATOM 425 CA LYS A 23 23.844 3.843 -10.944 1.00 13.89 C
+ATOM 426 C LYS A 23 22.458 4.414 -11.053 1.00 13.64 C
+ATOM 427 O LYS A 23 21.776 4.419 -12.113 1.00 15.07 O
+ATOM 428 CB LYS A 23 23.873 2.469 -10.338 1.00 18.92 C
+ATOM 429 CG LYS A 23 22.897 1.688 -11.164 1.00 23.44 C
+ATOM 430 CD LYS A 23 23.134 0.220 -10.987 1.00 28.41 C
+ATOM 431 CE LYS A 23 21.883 -0.282 -11.734 1.00 33.13 C
+ATOM 432 NZ LYS A 23 21.699 -1.653 -11.140 1.00 36.26 N
+ATOM 433 D LYS A 23 24.811 4.482 -9.301 1.00 12.45 D
+ATOM 434 HA LYS A 23 24.244 3.768 -11.951 1.00 13.36 H
+ATOM 435 HB2 LYS A 23 24.904 2.072 -10.313 1.00 18.73 H
+ATOM 436 HB3 LYS A 23 23.584 2.461 -9.286 1.00 18.71 H
+ATOM 437 HG2 LYS A 23 21.821 1.865 -11.054 1.00 23.71 H
+ATOM 438 HG3 LYS A 23 23.032 1.822 -12.264 1.00 23.90 H
+ATOM 439 HD2 LYS A 23 23.995 -0.194 -11.474 1.00 28.42 H
+ATOM 440 HD3 LYS A 23 23.120 -0.106 -9.964 1.00 28.28 H
+ATOM 441 HE2 LYS A 23 21.046 0.350 -11.524 1.00 32.48 H
+ATOM 442 HE3 LYS A 23 22.160 -0.402 -12.753 1.00 32.27 H
+ATOM 443 DZ1 LYS A 23 21.593 -1.586 -10.094 1.00 36.90 D
+ATOM 444 DZ2 LYS A 23 20.761 -1.979 -11.479 1.00 37.12 D
+ATOM 445 DZ3 LYS A 23 22.527 -2.262 -11.359 1.00 36.55 D
+ATOM 446 N ALA A 24 21.931 5.074 -10.038 1.00 13.18 N
+ATOM 447 CA ALA A 24 20.576 5.701 -10.043 1.00 11.76 C
+ATOM 448 C ALA A 24 20.606 7.178 -10.432 1.00 10.74 C
+ATOM 449 O ALA A 24 19.595 7.768 -10.820 1.00 11.30 O
+ATOM 450 CB ALA A 24 20.054 5.625 -8.612 1.00 12.78 C
+ATOM 451 D ALA A 24 22.488 5.076 -9.180 1.00 15.23 D
+ATOM 452 HA ALA A 24 20.090 5.015 -10.727 1.00 12.71 H
+ATOM 453 HB1 ALA A 24 20.772 6.088 -7.962 1.00 11.38 H
+ATOM 454 HB2 ALA A 24 19.100 6.124 -8.555 1.00 11.24 H
+ATOM 455 HB3 ALA A 24 20.011 4.596 -8.261 1.00 11.11 H
+ATOM 456 N GLY A 25 21.752 7.848 -10.373 1.00 9.60 N
+ATOM 457 CA GLY A 25 21.970 9.249 -10.618 1.00 10.58 C
+ATOM 458 C GLY A 25 21.292 10.175 -9.591 1.00 11.69 C
+ATOM 459 O GLY A 25 20.947 11.316 -9.904 1.00 12.66 O
+ATOM 460 D GLY A 25 22.531 7.298 -10.049 1.00 11.71 D
+ATOM 461 HA2 GLY A 25 22.992 9.579 -10.730 1.00 10.85 H
+ATOM 462 HA3 GLY A 25 21.483 9.541 -11.578 1.00 10.66 H
+ATOM 463 N LEU A 26 21.201 9.723 -8.370 1.00 11.42 N
+ATOM 464 CA LEU A 26 20.589 10.458 -7.271 1.00 13.44 C
+ATOM 465 C LEU A 26 21.437 10.194 -6.009 1.00 10.49 C
+ATOM 466 O LEU A 26 22.077 9.168 -5.914 1.00 11.18 O
+ATOM 467 CB LEU A 26 19.233 9.682 -6.932 1.00 15.84 C
+ATOM 468 CG LEU A 26 18.126 9.639 -7.924 1.00 17.24 C
+ATOM 469 CD1 LEU A 26 16.897 8.857 -7.584 1.00 18.29 C
+ATOM 470 CD2 LEU A 26 17.548 11.015 -8.232 1.00 18.39 C
+ATOM 471 D LEU A 26 21.510 8.788 -8.071 1.00 11.84 D
+ATOM 472 HA LEU A 26 20.311 11.468 -7.252 1.00 13.35 H
+ATOM 473 HB2 LEU A 26 19.436 8.685 -6.548 1.00 15.95 H
+ATOM 474 HB3 LEU A 26 18.858 10.134 -5.977 1.00 15.40 H
+ATOM 475 HG LEU A 26 18.531 9.305 -8.886 1.00 17.16 H
+ATOM 476 HD11 LEU A 26 16.985 7.826 -7.316 1.00 17.17 H
+ATOM 477 HD12 LEU A 26 16.567 9.316 -6.642 1.00 17.13 H
+ATOM 478 HD13 LEU A 26 16.204 9.016 -8.386 1.00 17.35 H
+ATOM 479 HD21 LEU A 26 18.381 11.675 -8.464 1.00 17.08 H
+ATOM 480 HD22 LEU A 26 16.837 10.957 -9.047 1.00 17.51 H
+ATOM 481 HD23 LEU A 26 17.112 11.417 -7.289 1.00 16.97 H
+ATOM 482 N CYS A 27 21.289 11.133 -5.121 1.00 10.45 N
+ATOM 483 CA CYS A 27 21.875 11.033 -3.734 1.00 10.30 C
+ATOM 484 C CYS A 27 20.869 10.289 -2.850 1.00 10.76 C
+ATOM 485 O CYS A 27 19.639 10.651 -2.961 1.00 12.39 O
+ATOM 486 CB CYS A 27 22.103 12.439 -3.217 1.00 10.60 C
+ATOM 487 SG CYS A 27 23.486 13.149 -4.087 1.00 11.79 S
+ATOM 488 D CYS A 27 20.752 11.960 -5.175 1.00 11.99 D
+ATOM 489 HA CYS A 27 22.835 10.632 -3.940 1.00 10.70 H
+ATOM 490 HB2 CYS A 27 21.141 12.922 -3.348 1.00 11.15 H
+ATOM 491 HB3 CYS A 27 22.434 12.440 -2.188 1.00 10.30 H
+ATOM 492 N GLN A 28 21.336 9.324 -2.086 1.00 8.79 N
+ATOM 493 CA GLN A 28 20.508 8.474 -1.259 1.00 10.62 C
+ATOM 494 C GLN A 28 21.184 8.402 0.118 1.00 10.68 C
+ATOM 495 O GLN A 28 22.328 8.784 0.291 1.00 10.44 O
+ATOM 496 CB GLN A 28 20.354 7.087 -1.858 1.00 11.67 C
+ATOM 497 CG GLN A 28 19.623 7.119 -3.183 1.00 13.65 C
+ATOM 498 CD GLN A 28 19.594 5.767 -3.853 1.00 14.34 C
+ATOM 499 OE1 GLN A 28 20.395 4.867 -3.653 1.00 15.59 O
+ATOM 500 NE2 GLN A 28 18.531 5.618 -4.678 1.00 18.68 N
+ATOM 501 H GLN A 28 22.343 9.128 -2.125 1.00 11.77 H
+ATOM 502 HA GLN A 28 19.517 8.874 -1.128 1.00 10.53 H
+ATOM 503 HB2 GLN A 28 21.356 6.648 -2.002 1.00 13.07 H
+ATOM 504 HB3 GLN A 28 19.931 6.372 -1.113 1.00 11.96 H
+ATOM 505 HG2 GLN A 28 18.690 7.661 -3.311 1.00 12.84 H
+ATOM 506 HG3 GLN A 28 20.219 7.714 -3.916 1.00 11.88 H
+ATOM 507 DE21 GLN A 28 18.411 4.689 -5.135 1.00 15.66 D
+ATOM 508 DE22 GLN A 28 17.891 6.434 -4.778 1.00 15.36 D
+ATOM 509 N THR A 29 20.404 7.934 1.103 1.00 11.66 N
+ATOM 510 CA THR A 29 20.941 7.836 2.490 1.00 11.14 C
+ATOM 511 C THR A 29 21.590 6.489 2.656 1.00 10.29 C
+ATOM 512 O THR A 29 21.401 5.428 2.076 1.00 11.74 O
+ATOM 513 CB THR A 29 19.849 8.116 3.568 1.00 11.90 C
+ATOM 514 OG1 THR A 29 18.807 7.216 3.348 1.00 14.39 O
+ATOM 515 CG2 THR A 29 19.240 9.473 3.369 1.00 13.60 C
+ATOM 516 D THR A 29 19.456 7.621 0.938 1.00 10.82 D
+ATOM 517 HA THR A 29 21.592 8.681 2.741 1.00 11.72 H
+ATOM 518 HB THR A 29 20.326 8.080 4.568 1.00 13.24 H
+ATOM 519 DG1 THR A 29 19.288 6.347 3.409 1.00 15.34 D
+ATOM 520 HG21 THR A 29 18.775 9.734 2.409 1.00 12.24 H
+ATOM 521 HG22 THR A 29 18.605 9.634 4.256 1.00 12.28 H
+ATOM 522 HG23 THR A 29 19.988 10.264 3.585 1.00 13.01 H
+ATOM 523 N PHE A 30 22.506 6.456 3.619 1.00 9.22 N
+ATOM 524 CA PHE A 30 23.207 5.275 4.060 1.00 9.74 C
+ATOM 525 C PHE A 30 23.550 5.541 5.559 1.00 9.40 C
+ATOM 526 O PHE A 30 23.556 6.640 6.034 1.00 10.22 O
+ATOM 527 CB PHE A 30 24.434 4.964 3.270 1.00 9.26 C
+ATOM 528 CG PHE A 30 25.710 5.682 3.555 1.00 9.20 C
+ATOM 529 CD1 PHE A 30 26.781 5.095 4.224 1.00 10.68 C
+ATOM 530 CD2 PHE A 30 25.843 6.975 3.069 1.00 10.04 C
+ATOM 531 CE1 PHE A 30 27.946 5.766 4.445 1.00 8.91 C
+ATOM 532 CE2 PHE A 30 27.014 7.710 3.271 1.00 10.37 C
+ATOM 533 CZ PHE A 30 28.008 7.053 3.984 1.00 9.71 C
+ATOM 534 H PHE A 30 22.695 7.266 4.199 1.00 11.07 H
+ATOM 535 HA PHE A 30 22.613 4.388 3.918 1.00 9.08 H
+ATOM 536 HB2 PHE A 30 24.660 3.891 3.281 1.00 8.91 H
+ATOM 537 HB3 PHE A 30 24.191 5.223 2.224 1.00 10.11 H
+ATOM 538 HD1 PHE A 30 26.642 4.136 4.599 1.00 10.02 H
+ATOM 539 HD2 PHE A 30 25.041 7.396 2.488 1.00 10.10 H
+ATOM 540 HE1 PHE A 30 28.767 5.394 5.011 1.00 10.09 H
+ATOM 541 HE2 PHE A 30 27.164 8.641 2.902 1.00 9.74 H
+ATOM 542 HZ PHE A 30 28.943 7.600 4.146 1.00 9.76 H
+ATOM 543 N VAL A 31 23.923 4.477 6.205 1.00 11.69 N
+ATOM 544 CA VAL A 31 24.349 4.496 7.646 1.00 11.33 C
+ATOM 545 C VAL A 31 25.894 4.524 7.711 1.00 10.54 C
+ATOM 546 O VAL A 31 26.638 3.625 7.263 1.00 11.75 O
+ATOM 547 CB VAL A 31 23.771 3.242 8.364 1.00 13.85 C
+ATOM 548 CG1 VAL A 31 24.190 3.382 9.822 1.00 15.43 C
+ATOM 549 CG2 VAL A 31 22.264 3.291 8.258 1.00 14.03 C
+ATOM 550 D VAL A 31 23.874 3.555 5.766 1.00 10.86 D
+ATOM 551 HA VAL A 31 23.896 5.373 8.063 1.00 13.01 H
+ATOM 552 HB VAL A 31 24.145 2.394 7.767 1.00 14.28 H
+ATOM 553 HG11 VAL A 31 25.215 3.495 10.080 1.00 14.34 H
+ATOM 554 HG12 VAL A 31 23.715 4.342 10.087 1.00 14.17 H
+ATOM 555 HG13 VAL A 31 23.671 2.771 10.508 1.00 14.55 H
+ATOM 556 HG21 VAL A 31 21.923 3.399 7.220 1.00 13.82 H
+ATOM 557 HG22 VAL A 31 21.859 2.299 8.478 1.00 13.92 H
+ATOM 558 HG23 VAL A 31 21.693 4.035 8.788 1.00 14.12 H
+ATOM 559 N TYR A 32 26.387 5.631 8.231 1.00 8.67 N
+ATOM 560 CA TYR A 32 27.814 5.860 8.458 1.00 8.52 C
+ATOM 561 C TYR A 32 28.085 5.455 9.938 1.00 9.39 C
+ATOM 562 O TYR A 32 27.356 5.880 10.841 1.00 10.05 O
+ATOM 563 CB TYR A 32 28.111 7.355 8.111 1.00 9.40 C
+ATOM 564 CG TYR A 32 29.487 7.835 8.503 1.00 9.39 C
+ATOM 565 CD1 TYR A 32 30.614 7.095 8.174 1.00 9.35 C
+ATOM 566 CD2 TYR A 32 29.613 8.943 9.313 1.00 9.32 C
+ATOM 567 CE1 TYR A 32 31.862 7.506 8.619 1.00 9.35 C
+ATOM 568 CE2 TYR A 32 30.895 9.387 9.715 1.00 9.94 C
+ATOM 569 CZ TYR A 32 31.977 8.641 9.373 1.00 10.13 C
+ATOM 570 OH TYR A 32 33.198 9.064 9.803 1.00 11.76 O
+ATOM 571 H TYR A 32 25.808 6.359 8.604 1.00 10.82 H
+ATOM 572 HA TYR A 32 28.395 5.346 7.704 1.00 8.94 H
+ATOM 573 HB2 TYR A 32 28.076 7.240 7.047 1.00 9.25 H
+ATOM 574 HB3 TYR A 32 27.271 7.909 8.560 1.00 9.74 H
+ATOM 575 HD1 TYR A 32 30.545 6.205 7.538 1.00 9.98 H
+ATOM 576 HD2 TYR A 32 28.750 9.553 9.589 1.00 10.16 H
+ATOM 577 HE1 TYR A 32 32.771 6.952 8.307 1.00 10.27 H
+ATOM 578 HE2 TYR A 32 30.943 10.289 10.353 1.00 9.68 H
+ATOM 579 DH TYR A 32 33.644 9.848 9.469 1.00 13.94 D
+ATOM 580 N GLY A 33 29.181 4.741 10.152 1.00 9.59 N
+ATOM 581 CA GLY A 33 29.544 4.252 11.487 1.00 9.91 C
+ATOM 582 C GLY A 33 30.219 5.242 12.389 1.00 9.25 C
+ATOM 583 O GLY A 33 30.414 4.897 13.554 1.00 9.95 O
+ATOM 584 D GLY A 33 29.796 4.369 9.440 1.00 10.72 D
+ATOM 585 HA2 GLY A 33 28.569 4.035 11.938 1.00 9.21 H
+ATOM 586 HA3 GLY A 33 29.951 3.244 11.467 1.00 9.63 H
+ATOM 587 N GLY A 34 30.587 6.373 11.911 1.00 8.45 N
+ATOM 588 CA GLY A 34 31.172 7.377 12.736 1.00 10.39 C
+ATOM 589 C GLY A 34 32.637 7.664 12.699 1.00 10.61 C
+ATOM 590 O GLY A 34 33.098 8.624 13.380 1.00 13.37 O
+ATOM 591 H GLY A 34 30.371 6.645 10.927 1.00 9.53 H
+ATOM 592 HA2 GLY A 34 30.644 8.301 12.496 1.00 10.62 H
+ATOM 593 HA3 GLY A 34 30.965 7.251 13.816 1.00 9.36 H
+ATOM 594 N CYS A 35 33.387 6.871 11.999 1.00 10.95 N
+ATOM 595 CA CYS A 35 34.813 7.212 11.868 1.00 11.65 C
+ATOM 596 C CYS A 35 35.267 6.763 10.481 1.00 12.05 C
+ATOM 597 O CYS A 35 34.729 5.808 9.860 1.00 11.60 O
+ATOM 598 CB CYS A 35 35.702 6.466 12.895 1.00 12.40 C
+ATOM 599 SG CYS A 35 35.719 4.684 12.827 1.00 12.21 S
+ATOM 600 D CYS A 35 33.052 6.073 11.478 1.00 11.38 D
+ATOM 601 HA CYS A 35 34.828 8.254 12.105 1.00 12.48 H
+ATOM 602 HB2 CYS A 35 36.717 6.782 12.719 1.00 11.84 H
+ATOM 603 HB3 CYS A 35 35.376 6.694 13.914 1.00 11.11 H
+ATOM 604 N ARG A 36 36.341 7.375 10.042 1.00 12.46 N
+ATOM 605 CA ARG A 36 37.025 7.056 8.805 1.00 14.63 C
+ATOM 606 C ARG A 36 36.187 7.227 7.520 1.00 12.13 C
+ATOM 607 O ARG A 36 36.332 6.391 6.640 1.00 13.93 O
+ATOM 608 CB ARG A 36 37.538 5.625 8.866 1.00 18.16 C
+ATOM 609 CG ARG A 36 38.516 5.562 10.066 1.00 22.63 C
+ATOM 610 CD ARG A 36 39.107 4.166 10.098 1.00 26.10 C
+ATOM 611 NE ARG A 36 39.805 4.035 11.371 1.00 30.83 N
+ATOM 612 CZ ARG A 36 40.590 3.032 11.775 1.00 32.34 C
+ATOM 613 NH1 ARG A 36 40.823 1.964 11.024 1.00 33.18 N
+ATOM 614 NH2 ARG A 36 41.144 3.105 12.987 1.00 33.57 N
+ATOM 615 D ARG A 36 36.670 8.142 10.540 1.00 12.82 D
+ATOM 616 HA ARG A 36 37.858 7.741 8.595 1.00 13.15 H
+ATOM 617 HB2 ARG A 36 36.821 4.846 9.058 1.00 18.94 H
+ATOM 618 HB3 ARG A 36 38.127 5.322 8.011 1.00 18.72 H
+ATOM 619 HG2 ARG A 36 39.277 6.303 10.090 1.00 22.77 H
+ATOM 620 HG3 ARG A 36 38.016 5.637 10.981 1.00 22.29 H
+ATOM 621 HD2 ARG A 36 38.282 3.473 10.078 1.00 26.48 H
+ATOM 622 HD3 ARG A 36 39.633 4.052 9.207 1.00 26.96 H
+ATOM 623 DE ARG A 36 39.685 4.801 12.039 1.00 31.59 D
+ATOM 624 DH11 ARG A 36 40.376 1.948 10.092 1.00 32.83 D
+ATOM 625 DH12 ARG A 36 41.429 1.235 11.413 1.00 32.46 D
+ATOM 626 DH21 ARG A 36 41.037 3.833 13.662 1.00 33.14 D
+ATOM 627 DH22 ARG A 36 41.738 2.325 13.284 1.00 33.33 D
+ATOM 628 N ALA A 37 35.456 8.280 7.530 1.00 11.13 N
+ATOM 629 CA ALA A 37 34.631 8.632 6.385 1.00 12.22 C
+ATOM 630 C ALA A 37 35.497 8.734 5.135 1.00 13.37 C
+ATOM 631 O ALA A 37 36.687 9.115 5.137 1.00 14.12 O
+ATOM 632 CB ALA A 37 33.941 9.981 6.542 1.00 11.96 C
+ATOM 633 D ALA A 37 35.340 8.972 8.208 1.00 12.73 D
+ATOM 634 HA ALA A 37 33.879 7.870 6.308 1.00 12.14 H
+ATOM 635 HB1 ALA A 37 34.528 10.829 6.846 1.00 12.60 H
+ATOM 636 HB2 ALA A 37 33.456 10.198 5.563 1.00 12.13 H
+ATOM 637 HB3 ALA A 37 33.155 9.774 7.271 1.00 11.94 H
+ATOM 638 N LYS A 38 34.889 8.428 4.019 1.00 12.73 N
+ATOM 639 CA LYS A 38 35.456 8.549 2.638 1.00 12.34 C
+ATOM 640 C LYS A 38 34.782 9.775 2.026 1.00 11.42 C
+ATOM 641 O LYS A 38 33.938 10.501 2.638 1.00 12.35 O
+ATOM 642 CB LYS A 38 35.426 7.283 1.843 1.00 15.66 C
+ATOM 643 CG LYS A 38 36.330 6.177 2.314 1.00 17.23 C
+ATOM 644 CD LYS A 38 36.220 4.925 1.492 1.00 21.83 C
+ATOM 645 CE LYS A 38 36.972 3.830 2.249 1.00 24.86 C
+ATOM 646 NZ LYS A 38 38.430 4.086 2.238 1.00 26.80 N
+ATOM 647 D LYS A 38 33.904 8.208 4.062 1.00 14.44 D
+ATOM 648 HA LYS A 38 36.456 8.823 2.962 1.00 13.22 H
+ATOM 649 HB2 LYS A 38 34.348 7.148 1.817 1.00 14.20 H
+ATOM 650 HB3 LYS A 38 35.594 7.443 0.755 1.00 14.27 H
+ATOM 651 HG2 LYS A 38 37.409 6.485 2.376 1.00 18.75 H
+ATOM 652 HG3 LYS A 38 36.049 5.955 3.369 1.00 17.95 H
+ATOM 653 HD2 LYS A 38 35.216 4.451 1.494 1.00 20.99 H
+ATOM 654 HD3 LYS A 38 36.531 4.849 0.453 1.00 21.24 H
+ATOM 655 HE2 LYS A 38 36.740 3.973 3.315 1.00 24.44 H
+ATOM 656 HE3 LYS A 38 36.742 2.821 1.974 1.00 24.67 H
+ATOM 657 DZ1 LYS A 38 38.697 5.072 2.091 1.00 27.28 D
+ATOM 658 DZ2 LYS A 38 38.774 3.778 3.195 1.00 28.13 D
+ATOM 659 DZ3 LYS A 38 38.960 3.393 1.688 1.00 27.94 D
+ATOM 660 N ARG A 39 35.115 10.128 0.777 1.00 9.56 N
+ATOM 661 CA ARG A 39 34.659 11.372 0.167 1.00 9.93 C
+ATOM 662 C ARG A 39 33.178 11.332 -0.259 1.00 7.40 C
+ATOM 663 O ARG A 39 32.599 12.401 -0.162 1.00 9.71 O
+ATOM 664 CB ARG A 39 35.554 11.797 -0.960 1.00 10.35 C
+ATOM 665 CG ARG A 39 36.918 12.265 -0.568 1.00 13.91 C
+ATOM 666 CD ARG A 39 37.957 12.565 -1.588 1.00 15.78 C
+ATOM 667 NE ARG A 39 38.393 11.235 -1.972 1.00 21.96 N
+ATOM 668 CZ ARG A 39 39.092 10.993 -3.114 1.00 24.68 C
+ATOM 669 NH1 ARG A 39 39.486 11.979 -3.942 1.00 25.19 N
+ATOM 670 NH2 ARG A 39 39.446 9.734 -3.428 1.00 26.22 N
+ATOM 671 D ARG A 39 35.813 9.575 0.318 1.00 11.76 D
+ATOM 672 HA ARG A 39 34.712 12.168 0.950 1.00 8.89 H
+ATOM 673 HB2 ARG A 39 35.629 10.967 -1.690 1.00 11.16 H
+ATOM 674 HB3 ARG A 39 35.017 12.458 -1.640 1.00 11.51 H
+ATOM 675 HG2 ARG A 39 36.981 13.025 0.221 1.00 12.33 H
+ATOM 676 HG3 ARG A 39 37.355 11.538 0.099 1.00 11.94 H
+ATOM 677 HD2 ARG A 39 37.373 13.009 -2.423 1.00 17.32 H
+ATOM 678 HD3 ARG A 39 38.645 13.283 -1.256 1.00 17.71 H
+ATOM 679 DE ARG A 39 38.164 10.450 -1.415 1.00 22.92 D
+ATOM 680 DH11 ARG A 39 40.007 11.665 -4.784 1.00 24.97 D
+ATOM 681 DH12 ARG A 39 39.258 12.965 -3.814 1.00 24.43 D
+ATOM 682 DH21 ARG A 39 39.244 8.893 -2.906 1.00 25.17 D
+ATOM 683 DH22 ARG A 39 39.963 9.580 -4.300 1.00 25.13 D
+ATOM 684 N ASN A 40 32.662 10.208 -0.618 1.00 7.80 N
+ATOM 685 CA ASN A 40 31.235 10.157 -1.075 1.00 7.75 C
+ATOM 686 C ASN A 40 30.363 9.898 0.175 1.00 7.34 C
+ATOM 687 O ASN A 40 29.830 8.807 0.431 1.00 7.64 O
+ATOM 688 CB ASN A 40 31.158 9.006 -2.072 1.00 8.94 C
+ATOM 689 CG ASN A 40 29.799 9.033 -2.770 1.00 8.97 C
+ATOM 690 OD1 ASN A 40 29.002 9.968 -2.653 1.00 9.17 O
+ATOM 691 ND2 ASN A 40 29.533 8.007 -3.503 1.00 10.14 N
+ATOM 692 D ASN A 40 33.214 9.377 -0.662 1.00 8.50 D
+ATOM 693 HA ASN A 40 31.097 11.126 -1.506 1.00 9.50 H
+ATOM 694 HB2 ASN A 40 31.986 9.096 -2.796 1.00 7.95 H
+ATOM 695 HB3 ASN A 40 31.442 8.069 -1.533 1.00 8.39 H
+ATOM 696 DD21 ASN A 40 30.286 7.249 -3.480 1.00 13.15 D
+ATOM 697 DD22 ASN A 40 28.694 7.778 -4.043 1.00 12.66 D
+ATOM 698 N ASN A 41 30.329 10.926 0.929 1.00 7.27 N
+ATOM 699 CA ASN A 41 29.680 10.998 2.281 1.00 8.28 C
+ATOM 700 C ASN A 41 29.441 12.481 2.513 1.00 7.79 C
+ATOM 701 O ASN A 41 30.374 13.253 2.640 1.00 9.89 O
+ATOM 702 CB ASN A 41 30.579 10.298 3.287 1.00 9.05 C
+ATOM 703 CG ASN A 41 30.097 10.342 4.770 1.00 10.15 C
+ATOM 704 OD1 ASN A 41 29.353 11.223 5.157 1.00 11.10 O
+ATOM 705 ND2 ASN A 41 30.593 9.396 5.525 1.00 10.18 N
+ATOM 706 D ASN A 41 30.784 11.813 0.848 1.00 8.27 D
+ATOM 707 HA ASN A 41 28.831 10.413 2.219 1.00 7.51 H
+ATOM 708 HB2 ASN A 41 30.842 9.286 3.128 1.00 10.20 H
+ATOM 709 HB3 ASN A 41 31.523 10.823 3.352 1.00 9.86 H
+ATOM 710 DD21 ASN A 41 30.296 9.403 6.524 1.00 11.65 D
+ATOM 711 DD22 ASN A 41 31.216 8.687 5.150 1.00 9.99 D
+ATOM 712 N PHE A 42 28.153 12.815 2.580 1.00 7.78 N
+ATOM 713 CA PHE A 42 27.732 14.188 2.696 1.00 9.51 C
+ATOM 714 C PHE A 42 26.649 14.315 3.805 1.00 10.10 C
+ATOM 715 O PHE A 42 25.856 13.419 4.021 1.00 9.63 O
+ATOM 716 CB PHE A 42 27.054 14.595 1.345 1.00 11.02 C
+ATOM 717 CG PHE A 42 27.916 14.462 0.140 1.00 10.38 C
+ATOM 718 CD1 PHE A 42 27.953 13.294 -0.602 1.00 11.42 C
+ATOM 719 CD2 PHE A 42 28.752 15.525 -0.138 1.00 11.42 C
+ATOM 720 CE1 PHE A 42 28.783 13.173 -1.704 1.00 10.82 C
+ATOM 721 CE2 PHE A 42 29.615 15.424 -1.250 1.00 11.73 C
+ATOM 722 CZ PHE A 42 29.599 14.241 -1.990 1.00 11.68 C
+ATOM 723 H PHE A 42 27.398 12.157 2.411 1.00 9.18 H
+ATOM 724 HA PHE A 42 28.527 14.889 2.741 1.00 10.24 H
+ATOM 725 HB2 PHE A 42 26.350 13.759 1.326 1.00 9.92 H
+ATOM 726 HB3 PHE A 42 26.487 15.501 1.444 1.00 10.03 H
+ATOM 727 HD1 PHE A 42 27.341 12.513 -0.316 1.00 11.59 H
+ATOM 728 HD2 PHE A 42 28.699 16.440 0.415 1.00 11.56 H
+ATOM 729 HE1 PHE A 42 28.840 12.308 -2.293 1.00 11.54 H
+ATOM 730 HE2 PHE A 42 30.188 16.207 -1.556 1.00 11.41 H
+ATOM 731 HZ PHE A 42 30.224 14.157 -2.851 1.00 10.58 H
+ATOM 732 N LYS A 43 26.654 15.523 4.326 1.00 13.15 N
+ATOM 733 CA LYS A 43 25.670 15.810 5.399 1.00 15.31 C
+ATOM 734 C LYS A 43 24.360 16.291 4.876 1.00 14.98 C
+ATOM 735 O LYS A 43 23.386 16.226 5.649 1.00 16.56 O
+ATOM 736 CB LYS A 43 26.188 16.720 6.512 1.00 17.44 C
+ATOM 737 CG LYS A 43 27.318 16.084 7.335 1.00 19.58 C
+ATOM 738 CD LYS A 43 27.843 17.081 8.391 1.00 22.85 C
+ATOM 739 CE LYS A 43 29.236 16.576 8.669 1.00 24.99 C
+ATOM 740 NZ LYS A 43 29.962 17.327 9.705 1.00 27.16 N
+ATOM 741 D LYS A 43 27.344 16.221 4.047 1.00 11.41 D
+ATOM 742 HA LYS A 43 25.458 14.851 5.822 1.00 14.17 H
+ATOM 743 HB2 LYS A 43 26.587 17.609 5.990 1.00 17.47 H
+ATOM 744 HB3 LYS A 43 25.404 16.946 7.222 1.00 17.90 H
+ATOM 745 HG2 LYS A 43 27.027 15.200 7.891 1.00 20.31 H
+ATOM 746 HG3 LYS A 43 28.203 15.916 6.737 1.00 20.28 H
+ATOM 747 HD2 LYS A 43 28.122 17.991 7.798 1.00 22.17 H
+ATOM 748 HD3 LYS A 43 27.135 17.420 9.101 1.00 22.77 H
+ATOM 749 HE2 LYS A 43 29.175 15.510 8.907 1.00 24.93 H
+ATOM 750 HE3 LYS A 43 29.805 16.640 7.728 1.00 25.66 H
+ATOM 751 DZ1 LYS A 43 29.318 17.242 10.520 1.00 26.85 D
+ATOM 752 DZ2 LYS A 43 30.949 17.000 9.856 1.00 27.02 D
+ATOM 753 DZ3 LYS A 43 30.127 18.313 9.416 1.00 27.47 D
+ATOM 754 N SER A 44 24.337 16.734 3.622 1.00 15.47 N
+ATOM 755 CA SER A 44 23.068 17.191 3.061 1.00 15.09 C
+ATOM 756 C SER A 44 22.980 16.742 1.594 1.00 14.56 C
+ATOM 757 O SER A 44 24.015 16.567 0.916 1.00 13.03 O
+ATOM 758 CB SER A 44 22.880 18.711 3.060 1.00 15.63 C
+ATOM 759 OG SER A 44 23.822 19.258 2.193 1.00 16.91 O
+ATOM 760 D SER A 44 25.180 16.751 3.053 1.00 15.56 D
+ATOM 761 HA SER A 44 22.206 16.804 3.574 1.00 15.83 H
+ATOM 762 HB2 SER A 44 21.900 18.919 2.598 1.00 16.01 H
+ATOM 763 HB3 SER A 44 22.965 19.264 4.004 1.00 15.86 H
+ATOM 764 DG SER A 44 24.248 20.035 2.505 1.00 19.57 D
+ATOM 765 N ALA A 45 21.747 16.565 1.233 1.00 14.50 N
+ATOM 766 CA ALA A 45 21.452 16.202 -0.192 1.00 15.49 C
+ATOM 767 C ALA A 45 21.889 17.264 -1.204 1.00 14.13 C
+ATOM 768 O ALA A 45 22.320 16.959 -2.338 1.00 13.28 O
+ATOM 769 CB ALA A 45 19.991 15.849 -0.356 1.00 16.34 C
+ATOM 770 D ALA A 45 20.954 16.674 1.802 1.00 15.14 D
+ATOM 771 HA ALA A 45 22.244 15.481 -0.310 1.00 14.31 H
+ATOM 772 HB1 ALA A 45 19.319 16.642 -0.038 1.00 15.97 H
+ATOM 773 HB2 ALA A 45 19.800 15.524 -1.385 1.00 16.04 H
+ATOM 774 HB3 ALA A 45 19.794 14.988 0.281 1.00 16.24 H
+ATOM 775 N GLU A 46 21.835 18.530 -0.819 1.00 14.30 N
+ATOM 776 CA GLU A 46 22.235 19.620 -1.652 1.00 16.73 C
+ATOM 777 C GLU A 46 23.740 19.554 -1.891 1.00 14.46 C
+ATOM 778 O GLU A 46 24.137 19.730 -3.053 1.00 14.56 O
+ATOM 779 CB GLU A 46 21.766 20.869 -0.865 1.00 21.56 C
+ATOM 780 CG GLU A 46 20.367 20.737 -0.179 1.00 26.75 C
+ATOM 781 CD GLU A 46 19.919 19.894 0.994 1.00 29.54 C
+ATOM 782 OE1 GLU A 46 19.414 18.784 1.212 1.00 32.40 O
+ATOM 783 OE2 GLU A 46 19.912 20.253 2.202 1.00 34.26 O
+ATOM 784 D GLU A 46 21.514 18.770 0.081 1.00 15.94 D
+ATOM 785 HA GLU A 46 21.885 19.789 -2.644 1.00 17.10 H
+ATOM 786 HB2 GLU A 46 22.360 20.677 0.079 1.00 21.05 H
+ATOM 787 HB3 GLU A 46 22.360 21.702 -1.159 1.00 21.64 H
+ATOM 788 HG2 GLU A 46 20.001 21.722 0.047 1.00 26.97 H
+ATOM 789 HG3 GLU A 46 19.803 20.281 -0.976 1.00 26.35 H
+ATOM 790 N ASP A 47 24.537 19.331 -0.858 1.00 14.10 N
+ATOM 791 CA ASP A 47 25.961 19.288 -1.082 1.00 13.93 C
+ATOM 792 C ASP A 47 26.280 18.071 -1.961 1.00 11.78 C
+ATOM 793 O ASP A 47 27.149 18.165 -2.795 1.00 12.10 O
+ATOM 794 CB ASP A 47 26.695 18.778 0.111 1.00 18.61 C
+ATOM 795 CG ASP A 47 27.499 19.674 0.972 1.00 25.48 C
+ATOM 796 OD1 ASP A 47 26.759 20.572 1.375 1.00 29.01 O
+ATOM 797 OD2 ASP A 47 28.655 19.195 1.020 1.00 27.88 O
+ATOM 798 D ASP A 47 24.173 19.185 0.045 1.00 14.90 D
+ATOM 799 HA ASP A 47 26.388 20.193 -1.435 1.00 14.65 H
+ATOM 800 HB2 ASP A 47 26.126 18.142 0.783 1.00 18.57 H
+ATOM 801 HB3 ASP A 47 27.390 17.949 -0.167 1.00 19.69 H
+ATOM 802 N CYS A 48 25.605 16.956 -1.732 1.00 10.22 N
+ATOM 803 CA CYS A 48 25.822 15.753 -2.493 1.00 10.57 C
+ATOM 804 C CYS A 48 25.591 15.998 -3.994 1.00 11.23 C
+ATOM 805 O CYS A 48 26.397 15.689 -4.871 1.00 11.33 O
+ATOM 806 CB CYS A 48 24.941 14.644 -1.926 1.00 9.71 C
+ATOM 807 SG CYS A 48 25.055 13.060 -2.815 1.00 10.82 S
+ATOM 808 D CYS A 48 24.881 16.926 -1.041 1.00 11.98 D
+ATOM 809 HA CYS A 48 26.840 15.447 -2.313 1.00 9.86 H
+ATOM 810 HB2 CYS A 48 25.207 14.370 -0.935 1.00 9.50 H
+ATOM 811 HB3 CYS A 48 23.907 14.950 -1.834 1.00 10.27 H
+ATOM 812 N MET A 49 24.405 16.565 -4.212 1.00 12.19 N
+ATOM 813 CA MET A 49 23.975 16.860 -5.592 1.00 15.04 C
+ATOM 814 C MET A 49 24.865 17.909 -6.259 1.00 15.23 C
+ATOM 815 O MET A 49 25.254 17.714 -7.432 1.00 16.42 O
+ATOM 816 CB MET A 49 22.481 17.237 -5.692 1.00 16.60 C
+ATOM 817 CG AMET A 49 21.619 16.002 -5.527 0.65 16.58 C
+ATOM 818 CG BMET A 49 21.536 16.149 -5.278 0.35 19.07 C
+ATOM 819 SD AMET A 49 21.684 14.673 -6.752 0.65 17.21 S
+ATOM 820 SD BMET A 49 19.845 16.563 -5.694 0.35 21.60 S
+ATOM 821 CE AMET A 49 20.896 15.481 -8.152 0.65 17.25 C
+ATOM 822 CE BMET A 49 19.639 18.241 -5.038 0.35 20.98 C
+ATOM 823 D MET A 49 23.741 16.776 -3.521 1.00 11.71 D
+ATOM 824 HA MET A 49 24.027 15.986 -6.232 1.00 14.64 H
+ATOM 825 HB2 MET A 49 22.275 18.123 -5.117 1.00 16.08 H
+ATOM 826 HB3 MET A 49 22.460 17.461 -6.770 1.00 15.52 H
+ATOM 827 HG2AMET A 49 22.023 15.418 -4.676 0.65 16.82 H
+ATOM 828 HG2BMET A 49 21.648 15.214 -5.841 0.35 19.25 H
+ATOM 829 HG3AMET A 49 20.574 16.201 -5.322 0.65 16.79 H
+ATOM 830 HG3BMET A 49 21.552 15.928 -4.213 0.35 19.04 H
+ATOM 831 HE1AMET A 49 21.506 16.358 -8.341 0.65 17.36 H
+ATOM 832 HE1BMET A 49 20.257 18.263 -4.174 0.35 20.84 H
+ATOM 833 HE2AMET A 49 21.243 14.908 -9.046 0.65 16.78 H
+ATOM 834 HE2BMET A 49 20.012 18.845 -5.860 0.35 20.71 H
+ATOM 835 HE3AMET A 49 19.853 15.441 -8.108 0.65 17.36 H
+ATOM 836 HE3BMET A 49 18.576 18.325 -4.893 0.35 20.87 H
+ATOM 837 N ARG A 50 25.206 18.931 -5.556 1.00 17.25 N
+ATOM 838 CA ARG A 50 26.111 19.970 -6.044 1.00 19.58 C
+ATOM 839 C ARG A 50 27.493 19.419 -6.400 1.00 19.14 C
+ATOM 840 O ARG A 50 28.105 19.894 -7.379 1.00 18.79 O
+ATOM 841 CB ARG A 50 26.365 20.989 -4.925 1.00 21.70 C
+ATOM 842 CG ARG A 50 27.106 22.225 -5.375 1.00 24.59 C
+ATOM 843 CD ARG A 50 26.494 23.431 -4.716 1.00 26.49 C
+ATOM 844 NE ARG A 50 26.503 23.143 -3.308 1.00 30.03 N
+ATOM 845 CZ ARG A 50 25.536 23.635 -2.543 1.00 30.47 C
+ATOM 846 NH1 ARG A 50 24.554 24.368 -3.034 1.00 31.82 N
+ATOM 847 NH2 ARG A 50 25.533 23.348 -1.271 1.00 30.70 N
+ATOM 848 D ARG A 50 24.877 19.095 -4.635 1.00 17.26 D
+ATOM 849 HA ARG A 50 25.631 20.419 -6.896 1.00 19.36 H
+ATOM 850 HB2 ARG A 50 25.336 21.264 -4.675 1.00 21.99 H
+ATOM 851 HB3 ARG A 50 26.827 20.450 -4.106 1.00 22.43 H
+ATOM 852 HG2 ARG A 50 28.119 22.368 -5.525 1.00 24.05 H
+ATOM 853 HG3 ARG A 50 26.672 22.362 -6.390 1.00 23.86 H
+ATOM 854 HD2 ARG A 50 27.053 24.242 -5.072 1.00 27.41 H
+ATOM 855 HD3 ARG A 50 25.499 23.574 -5.080 1.00 27.53 H
+ATOM 856 DE ARG A 50 27.225 22.565 -2.844 1.00 30.30 D
+ATOM 857 DH11 ARG A 50 23.854 24.661 -2.321 1.00 30.67 D
+ATOM 858 DH12 ARG A 50 24.517 24.609 -4.036 1.00 30.96 D
+ATOM 859 DH21 ARG A 50 26.264 22.781 -0.865 1.00 31.15 D
+ATOM 860 DH22 ARG A 50 24.762 23.749 -0.724 1.00 31.05 D
+ATOM 861 N THR A 51 28.014 18.446 -5.647 1.00 16.27 N
+ATOM 862 CA THR A 51 29.317 17.889 -5.933 1.00 15.50 C
+ATOM 863 C THR A 51 29.360 16.811 -7.019 1.00 14.44 C
+ATOM 864 O THR A 51 30.323 16.753 -7.836 1.00 14.74 O
+ATOM 865 CB THR A 51 29.884 17.308 -4.599 1.00 16.69 C
+ATOM 866 OG1 THR A 51 29.915 18.356 -3.628 1.00 17.09 O
+ATOM 867 CG2 THR A 51 31.252 16.617 -4.794 1.00 16.12 C
+ATOM 868 D THR A 51 27.440 18.111 -4.892 1.00 18.36 D
+ATOM 869 HA THR A 51 30.069 18.613 -6.258 1.00 15.14 H
+ATOM 870 HB THR A 51 29.173 16.550 -4.194 1.00 16.74 H
+ATOM 871 DG1 THR A 51 29.012 18.597 -3.318 1.00 16.70 D
+ATOM 872 HG21 THR A 51 31.801 17.152 -5.610 1.00 17.37 H
+ATOM 873 HG22 THR A 51 31.759 16.514 -3.853 1.00 17.09 H
+ATOM 874 HG23 THR A 51 31.026 15.693 -5.309 1.00 17.52 H
+ATOM 875 N CYS A 52 28.364 15.919 -6.980 1.00 12.64 N
+ATOM 876 CA CYS A 52 28.337 14.779 -7.839 1.00 14.57 C
+ATOM 877 C CYS A 52 27.258 14.663 -8.899 1.00 16.68 C
+ATOM 878 O CYS A 52 27.484 13.831 -9.733 1.00 17.00 O
+ATOM 879 CB CYS A 52 28.265 13.520 -6.968 1.00 13.88 C
+ATOM 880 SG CYS A 52 29.664 13.161 -5.893 1.00 13.03 S
+ATOM 881 D CYS A 52 27.614 15.974 -6.323 1.00 14.99 D
+ATOM 882 HA CYS A 52 29.253 14.775 -8.417 1.00 14.34 H
+ATOM 883 HB2 CYS A 52 27.388 13.519 -6.349 1.00 13.38 H
+ATOM 884 HB3 CYS A 52 28.059 12.720 -7.695 1.00 13.88 H
+ATOM 885 N GLY A 53 26.248 15.435 -8.766 1.00 22.23 N
+ATOM 886 CA GLY A 53 25.221 15.180 -9.791 1.00 26.06 C
+ATOM 887 C GLY A 53 25.286 15.905 -11.139 1.00 29.57 C
+ATOM 888 O GLY A 53 26.220 16.540 -11.584 1.00 31.26 O
+ATOM 889 D GLY A 53 26.124 16.072 -8.024 1.00 18.76 D
+ATOM 890 HA2 GLY A 53 25.526 14.160 -10.093 1.00 25.90 H
+ATOM 891 HA3 GLY A 53 24.206 15.027 -9.457 1.00 26.16 H
+TER 910 ALA A 58
+HETATM 911 P PO4 A 70 32.672 12.772 10.325 0.65 25.52 P
+HETATM 912 O1 PO4 A 70 33.530 14.005 10.556 0.65 26.69 O
+HETATM 913 O2 PO4 A 70 31.499 12.810 11.272 0.65 25.31 O
+HETATM 914 O3 PO4 A 70 32.136 12.729 8.909 0.65 24.51 O
+HETATM 915 O4 PO4 A 70 33.561 11.570 10.555 0.65 23.64 O
+HETATM 916 UNK UNX A 324 23.599 13.195 -7.043 1.00 45.42 X
+HETATM 917 O DOD A 80 23.194 15.839 8.222 0.40 22.37 O
+HETATM 918 D1 DOD A 80 23.286 16.842 8.165 0.40 22.61 D
+HETATM 919 D2 DOD A 80 24.153 15.561 8.326 0.40 22.60 D
+HETATM 920 O DOD A 101 22.510 21.082 -4.729 1.00 36.16 O
+HETATM 921 D1 DOD A 101 21.831 21.235 -5.370 1.00 35.79 D
+HETATM 922 D2 DOD A 101 23.104 20.367 -4.949 1.00 35.47 D
+HETATM 923 O DOD A 102 32.400 2.989 17.428 0.80 18.44 O
+HETATM 924 D1 DOD A 102 33.257 2.902 16.959 0.80 19.80 D
+HETATM 925 D2 DOD A 102 32.345 2.270 18.071 0.80 19.39 D
+HETATM 926 O DOD A 105 32.325 18.662 -7.849 1.00 32.19 O
+HETATM 927 D1 DOD A 105 31.835 17.834 -8.008 1.00 30.47 D
+HETATM 928 D2 DOD A 105 31.833 19.268 -8.402 1.00 30.09 D
+HETATM 929 O DOD A 110 37.328 8.721 -0.765 0.85 24.80 O
+HETATM 930 D1 DOD A 110 37.884 7.962 -0.994 0.85 28.72 D
+HETATM 931 D2 DOD A 110 36.474 8.348 -1.051 0.85 28.38 D
+HETATM 932 O DOD A 111 32.894 6.077 -0.473 1.00 17.11 O
+HETATM 933 D1 DOD A 111 33.120 6.673 -1.189 1.00 17.18 D
+HETATM 934 D2 DOD A 111 32.082 5.642 -0.714 1.00 18.37 D
+HETATM 935 O DOD A 112 31.242 6.845 1.776 1.00 12.53 O
+HETATM 936 D1 DOD A 112 31.797 6.338 1.211 1.00 12.31 D
+HETATM 937 D2 DOD A 112 30.886 7.631 1.374 1.00 11.82 D
+HETATM 938 O DOD A 113 32.081 7.266 4.248 1.00 10.62 O
+HETATM 939 D1 DOD A 113 31.885 7.136 3.273 1.00 10.81 D
+HETATM 940 D2 DOD A 113 31.780 6.400 4.490 1.00 10.32 D
+HETATM 941 O DOD A 116 21.627 2.820 1.964 0.45 18.18 O
+HETATM 942 D1 DOD A 116 22.311 2.168 1.795 0.45 15.16 D
+HETATM 943 D2 DOD A 116 21.898 3.682 1.661 0.45 13.72 D
+HETATM 944 O DOD A 117 23.450 1.914 4.826 0.85 21.21 O
+HETATM 945 D1 DOD A 117 24.325 1.628 5.014 0.85 18.34 D
+HETATM 946 D2 DOD A 117 22.978 2.382 5.498 0.85 16.27 D
+HETATM 947 O DOD A 119 24.933 8.699 -12.566 1.00 26.51 O
+HETATM 948 D1 DOD A 119 25.519 9.416 -12.334 1.00 24.40 D
+HETATM 949 D2 DOD A 119 25.041 7.808 -12.205 1.00 23.04 D
+HETATM 950 O DOD A 121 27.178 1.079 11.930 1.00 44.15 O
+HETATM 951 D1 DOD A 121 27.529 1.514 12.731 1.00 41.94 D
+HETATM 952 D2 DOD A 121 27.890 1.374 11.346 1.00 42.42 D
+HETATM 953 O DOD A 122 32.824 4.006 10.705 1.00 11.08 O
+HETATM 954 D1 DOD A 122 32.037 4.312 10.212 1.00 14.93 D
+HETATM 955 D2 DOD A 122 33.527 4.614 10.375 1.00 12.63 D
+HETATM 956 O DOD A 125 23.228 10.145 14.693 1.00 37.43 O
+HETATM 957 D1 DOD A 125 23.474 11.090 14.612 1.00 38.73 D
+HETATM 958 D2 DOD A 125 23.557 9.618 15.413 1.00 38.14 D
+HETATM 959 O DOD A 126 21.709 13.163 -11.285 1.00 45.53 O
+HETATM 960 D1 DOD A 126 21.371 12.655 -10.542 1.00 40.21 D
+HETATM 961 D2 DOD A 126 22.643 12.914 -11.319 1.00 40.01 D
+HETATM 962 O DOD A 127 25.304 13.841 10.064 1.00 31.39 O
+HETATM 963 D1 DOD A 127 24.713 13.795 9.294 1.00 29.74 D
+HETATM 964 D2 DOD A 127 24.901 13.162 10.650 1.00 30.13 D
+HETATM 965 O DOD A 129 21.978 10.502 12.070 1.00 22.99 O
+HETATM 966 D1 DOD A 129 21.026 10.401 12.238 1.00 21.72 D
+HETATM 967 D2 DOD A 129 22.220 11.424 12.257 1.00 22.25 D
+HETATM 968 O DOD A 133 37.476 9.724 11.502 0.75 22.01 O
+HETATM 969 D1 DOD A 133 37.584 9.982 12.425 0.75 19.51 D
+HETATM 970 D2 DOD A 133 36.539 9.976 11.345 0.75 19.51 D
+HETATM 971 O DOD A 134 34.490 11.060 -13.079 0.70 44.32 O
+HETATM 972 D1 DOD A 134 34.746 11.987 -12.978 0.70 42.77 D
+HETATM 973 D2 DOD A 134 33.653 10.980 -12.612 0.70 42.52 D
+HETATM 974 O DOD A 138 28.177 17.517 3.360 1.00 25.45 O
+HETATM 975 D1 DOD A 138 27.742 18.283 3.058 1.00 23.32 D
+HETATM 976 D2 DOD A 138 29.101 17.401 3.251 1.00 23.72 D
+HETATM 977 O DOD A 140 30.541 15.267 12.774 1.00 36.43 O
+HETATM 978 D1 DOD A 140 29.677 15.607 12.991 1.00 36.77 D
+HETATM 979 D2 DOD A 140 31.088 15.976 12.426 1.00 36.78 D
+HETATM 980 O DOD A 143 28.284 5.454 -6.397 1.00 27.22 O
+HETATM 981 D1 DOD A 143 28.234 4.659 -5.833 1.00 32.37 D
+HETATM 982 D2 DOD A 143 27.991 6.122 -5.773 1.00 31.67 D
+HETATM 983 O DOD A 144 17.474 21.217 4.158 1.00 42.30 O
+HETATM 984 D1 DOD A 144 18.268 20.904 3.726 1.00 40.47 D
+HETATM 985 D2 DOD A 144 16.993 21.816 3.609 1.00 40.56 D
+HETATM 986 O DOD A 145 38.592 14.977 -3.873 1.00 29.91 O
+HETATM 987 D1 DOD A 145 37.993 15.743 -3.880 1.00 31.95 D
+HETATM 988 D2 DOD A 145 38.520 14.611 -4.764 1.00 33.00 D
+HETATM 989 O DOD A 146 39.369 6.894 -8.744 1.00 41.67 O
+HETATM 990 D1 DOD A 146 39.454 6.652 -9.672 1.00 36.52 D
+HETATM 991 D2 DOD A 146 40.233 6.697 -8.383 1.00 37.22 D
+HETATM 992 O DOD A 156 30.562 -0.831 11.569 0.85 29.85 O
+HETATM 993 D1 DOD A 156 30.253 0.047 11.849 0.85 31.06 D
+HETATM 994 D2 DOD A 156 30.819 -0.652 10.650 0.85 30.89 D
+HETATM 995 O DOD A 157 35.840 10.917 9.802 1.00 23.72 O
+HETATM 996 D1 DOD A 157 35.118 11.562 9.768 1.00 25.45 D
+HETATM 997 D2 DOD A 157 36.435 11.166 9.095 1.00 25.05 D
+HETATM 998 O DOD A 158 32.417 -0.400 5.440 0.50 21.01 O
+HETATM 999 D1 DOD A 158 33.309 -0.402 5.914 0.50 20.94 D
+HETATM 1000 D2 DOD A 158 31.836 -0.783 6.158 0.50 20.72 D
+HETATM 1001 O DOD A 159 30.427 -0.255 3.808 0.50 26.42 O
+HETATM 1002 D1 DOD A 159 30.982 -0.258 2.963 0.50 26.94 D
+HETATM 1003 D2 DOD A 159 31.146 -0.594 4.435 0.50 26.51 D
+HETATM 1004 O DOD A 160 36.062 5.979 -8.634 1.00 41.31 O
+HETATM 1005 D1 DOD A 160 35.305 6.506 -8.327 1.00 40.68 D
+HETATM 1006 D2 DOD A 160 36.596 5.892 -7.843 1.00 40.44 D
+HETATM 1007 O DOD A 200 19.702 17.251 3.159 1.00 19.29 O
+HETATM 1008 D1 DOD A 200 18.842 16.821 3.395 1.00 20.94 D
+HETATM 1009 D2 DOD A 200 20.251 16.690 3.724 1.00 21.48 D
+HETATM 1010 O DOD A 201 38.290 5.419 5.139 0.45 14.23 O
+HETATM 1011 D1 DOD A 201 38.695 6.270 5.301 0.45 11.92 D
+HETATM 1012 D2 DOD A 201 38.934 4.728 5.353 0.45 12.39 D
+HETATM 1013 O DOD A 202 20.841 18.058 5.892 1.00 42.73 O
+HETATM 1014 D1 DOD A 202 20.670 18.727 5.224 1.00 41.57 D
+HETATM 1015 D2 DOD A 202 20.910 17.173 5.525 1.00 41.34 D
+HETATM 1016 O DOD A 203 35.858 -1.262 7.228 1.00 26.79 O
+HETATM 1017 D1 DOD A 203 36.279 -0.389 7.191 1.00 24.31 D
+HETATM 1018 D2 DOD A 203 36.182 -1.468 8.110 1.00 25.43 D
+HETATM 1019 O DOD A 204 39.380 8.361 4.115 0.70 28.37 O
+HETATM 1020 D1 DOD A 204 39.408 7.760 3.358 0.70 29.87 D
+HETATM 1021 D2 DOD A 204 38.462 8.655 4.217 0.70 30.08 D
+HETATM 1022 O DOD A 205 19.638 4.554 4.804 1.00 41.42 O
+HETATM 1023 D1 DOD A 205 18.798 4.746 4.362 1.00 41.56 D
+HETATM 1024 D2 DOD A 205 19.565 3.636 5.102 1.00 41.35 D
+HETATM 1025 O DOD A 209 27.016 14.177 11.548 0.55 23.66 O
+HETATM 1026 D1 DOD A 209 26.247 13.668 11.322 0.55 23.22 D
+HETATM 1027 D2 DOD A 209 27.150 14.829 10.861 0.55 23.19 D
+HETATM 1028 O DOD A 210 32.524 1.944 -8.668 0.55 28.00 O
+HETATM 1029 D1 DOD A 210 32.097 1.168 -8.326 0.55 24.83 D
+HETATM 1030 D2 DOD A 210 33.318 2.192 -8.183 0.55 24.43 D
+HETATM 1031 O DOD A 211 30.420 20.407 -9.327 1.00 50.37 O
+HETATM 1032 D1 DOD A 211 30.380 19.438 -9.416 1.00 50.49 D
+HETATM 1033 D2 DOD A 211 29.504 20.587 -9.585 1.00 50.62 D
+HETATM 1034 O DOD A 212 38.417 11.372 -7.271 1.00 37.18 O
+HETATM 1035 D1 DOD A 212 38.648 12.325 -7.203 1.00 35.24 D
+HETATM 1036 D2 DOD A 212 39.030 10.978 -6.635 1.00 35.81 D
+HETATM 1037 O DOD A 214 15.928 7.068 -4.160 0.80 33.49 O
+HETATM 1038 D1 DOD A 214 15.833 6.849 -5.089 0.80 30.73 D
+HETATM 1039 D2 DOD A 214 15.838 7.998 -3.965 0.80 30.42 D
+HETATM 1040 O DOD A 216 20.369 6.458 13.462 0.75 29.01 O
+HETATM 1041 D1 DOD A 216 20.426 6.571 14.416 0.75 29.73 D
+HETATM 1042 D2 DOD A 216 21.310 6.715 13.308 0.75 30.07 D
+HETATM 1043 O DOD A 217 20.372 9.135 14.450 1.00 45.82 O
+HETATM 1044 D1 DOD A 217 20.014 9.262 13.565 1.00 47.54 D
+HETATM 1045 D2 DOD A 217 20.713 8.233 14.501 1.00 46.99 D
+HETATM 1046 O DOD A 218 34.848 -2.506 13.144 0.60 23.45 O
+HETATM 1047 D1 DOD A 218 35.761 -2.257 13.315 0.60 24.59 D
+HETATM 1048 D2 DOD A 218 34.364 -1.952 13.777 0.60 23.86 D
+HETATM 1049 O DOD A 219 18.689 3.099 -6.988 0.65 32.86 O
+HETATM 1050 D1 DOD A 219 18.183 2.627 -6.333 0.65 31.27 D
+HETATM 1051 D2 DOD A 219 19.292 2.483 -7.421 0.65 31.44 D
+HETATM 1052 O DOD A 220 34.306 13.635 6.574 0.70 44.72 O
+HETATM 1053 D1 DOD A 220 34.435 13.156 7.403 0.70 43.71 D
+HETATM 1054 D2 DOD A 220 33.907 14.473 6.837 0.70 43.25 D
+HETATM 1055 O DOD A 223 39.704 6.653 -0.920 0.70 27.12 O
+HETATM 1056 D1 DOD A 223 39.839 5.695 -0.886 0.70 27.44 D
+HETATM 1057 D2 DOD A 223 40.073 6.944 -0.069 0.70 26.30 D
+HETATM 1058 O DOD A 225 35.835 1.799 -4.168 0.70 22.62 O
+HETATM 1059 D1 DOD A 225 35.195 1.203 -4.651 0.70 21.80 D
+HETATM 1060 D2 DOD A 225 35.838 1.670 -3.184 0.70 22.59 D
+HETATM 1061 O DOD A 302 23.473 14.023 7.697 0.50 17.94 O
+HETATM 1062 D1 DOD A 302 23.104 13.994 6.796 0.50 18.22 D
+HETATM 1063 D2 DOD A 302 23.692 13.105 7.863 0.50 18.44 D
+HETATM 1064 O DOD A 304 17.425 18.515 0.940 0.60 20.11 O
+HETATM 1065 D1 DOD A 304 16.690 18.065 1.361 0.60 20.79 D
+HETATM 1066 D2 DOD A 304 18.107 18.630 1.602 0.60 21.21 D
+HETATM 1067 O DOD A 310 30.817 21.189 -4.297 0.75 33.44 O
+HETATM 1068 D1 DOD A 310 31.670 21.225 -4.770 0.75 33.45 D
+HETATM 1069 D2 DOD A 310 30.745 20.286 -3.971 0.75 33.90 D
+HETATM 1070 O DOD A 311 29.101 21.433 -2.694 0.75 39.78 O
+HETATM 1071 D1 DOD A 311 28.810 20.773 -3.335 0.75 40.82 D
+HETATM 1072 D2 DOD A 311 29.404 20.908 -1.940 0.75 41.00 D
+HETATM 1073 O DOD A 312 34.385 2.967 -0.675 0.75 49.17 O
+HETATM 1074 D1 DOD A 312 33.896 2.264 -0.231 0.75 49.99 D
+HETATM 1075 D2 DOD A 312 35.282 2.635 -0.820 0.75 50.11 D
+HETATM 1076 O DOD A 313 22.760 12.894 9.757 0.75 34.76 O
+HETATM 1077 D1 DOD A 313 23.725 12.886 9.820 0.75 32.32 D
+HETATM 1078 D2 DOD A 313 22.695 12.328 8.975 0.75 32.33 D
+HETATM 1079 O DOD A 314 29.184 16.951 -10.815 1.00 50.56 O
+HETATM 1080 D1 DOD A 314 28.486 16.392 -11.157 1.00 49.79 D
+HETATM 1081 D2 DOD A 314 29.843 17.006 -11.516 1.00 50.11 D
+HETATM 1082 O DOD A 315 37.208 17.290 -2.722 0.75 35.00 O
+HETATM 1083 D1 DOD A 315 36.748 17.851 -2.066 0.75 33.32 D
+HETATM 1084 D2 DOD A 315 37.034 16.398 -2.381 0.75 33.28 D
+HETATM 1085 O DOD A 316 39.924 5.096 15.153 0.75 91.84 O
+HETATM 1086 D1 DOD A 316 40.240 5.673 15.857 0.75 91.50 D
+HETATM 1087 D2 DOD A 316 39.075 4.751 15.456 0.75 91.50 D
+HETATM 1088 O DOD A 317 24.792 1.584 -6.585 1.00 53.91 O
+HETATM 1089 D1 DOD A 317 24.014 2.025 -6.941 1.00 52.72 D
+HETATM 1090 D2 DOD A 317 25.404 2.307 -6.419 1.00 53.49 D
+HETATM 1091 O DOD A 318 29.052 21.202 9.370 0.75 46.66 O
+HETATM 1092 D1 DOD A 318 28.463 20.601 9.828 0.75 44.03 D
+HETATM 1093 D2 DOD A 318 29.833 20.748 9.033 0.75 44.42 D
+HETATM 1094 O DOD A 319 31.855 0.163 0.605 0.75 42.28 O
+HETATM 1095 D1 DOD A 319 30.944 -0.153 0.702 0.75 40.63 D
+HETATM 1096 D2 DOD A 319 31.809 1.074 0.885 0.75 40.72 D
+HETATM 1097 O DOD A 320 17.490 9.671 -3.504 0.75 50.06 O
+HETATM 1098 D1 DOD A 320 17.844 10.566 -3.494 0.75 49.93 D
+HETATM 1099 D2 DOD A 320 16.796 9.717 -2.837 0.75 50.26 D
+HETATM 1100 O DOD A 321 23.571 -0.806 13.870 0.50 28.53 O
+HETATM 1101 D1 DOD A 321 24.067 -1.107 14.640 0.50 28.83 D
+HETATM 1102 D2 DOD A 321 23.508 -1.626 13.366 0.50 27.58 D
+HETATM 1103 O DOD A 322 30.284 21.588 -6.518 0.75 52.32 O
+HETATM 1104 D1 DOD A 322 30.165 22.574 -6.795 0.75 50.92 D
+HETATM 1105 D2 DOD A 322 29.362 21.275 -6.636 0.75 50.63 D
+CONECT 78 880
+CONECT 215 599
+CONECT 487 807
+CONECT 599 215
+CONECT 807 487
+CONECT 880 78
+CONECT 911 912 913 914 915
+CONECT 912 911
+CONECT 913 911
+CONECT 914 911
+CONECT 915 911
+MASTER 356 2 2 2 3 0 3 6 523 1 11 5
+END
diff --git a/docs/examples/bpt1/data/config.ini b/docs/examples/bpt1/data/config.ini
index d44c73e864e8bd02fd7001d889628e9bd9f5766b..0cbbc7e985deefed4415ba5b32dc8436a9fa09c1 100644
--- a/docs/examples/bpt1/data/config.ini
+++ b/docs/examples/bpt1/data/config.ini
@@ -8,9 +8,9 @@ n_factor: 1.0
# ARIA project parameters
# -----------------------
host_command: sbatch -t 06:00:00
-host_executable: /path/to/cns1.21.exe
-cns_executable: /path/to/cns1.21.exe
-temp_root: /tmp
+host_executable: /PATH/TO/CNS
+cns_executable: /PATH/TO/CNS
+temp_root: /PATH/TO/TMP
# Protocol parameters
# -------------------
rama_potential_enabled: yes
@@ -19,7 +19,7 @@ md_parameters_steps_high: 20000
md_parameters_steps_cool1: 100000
md_parameters_steps_cool2: 80000
md_parameters_random_seed: 89764443
-procheck_executable: /path/to/procheck
-whatif_executable: /path/to/whatif
+procheck_executable: /PATH/TO/PROCHECK
+whatif_executable: /PATH/TO/WHATIF
clustering_enabled: yes
clustering_nclusters: 2
diff --git a/docs/examples/malecoli/data/MALE_ECOLI.fa b/docs/examples/malecoli/data/MALE_ECOLI.fa
new file mode 100644
index 0000000000000000000000000000000000000000..5690d0fbefd1e830e01f1b93ebfed48a5372b1f8
--- /dev/null
+++ b/docs/examples/malecoli/data/MALE_ECOLI.fa
@@ -0,0 +1,8 @@
+>/baycells/home/fallain/Projects/ariaec/data/2017-04-ECNMR/MALE_ECOLI/MALE_ECOLI.native.aligned | chain A | 370 aa
+KIEEGKLVIWINGDKGYNGLAEVGKKFEKDTGIKVTVEHPDKLEEKFPQVAATGDGPDII
+FWAHDRFGGYAQSGLLAEITPDKAFQDKLYPFTWDAVRYNGKLIAYPIAVEALSLIYNKD
+LLPNPPKTWEEIPALDKELKAKGKSALMFNLQEPYFTWPLIAADGGYAFKYENGKYDIKD
+VGVDNAGAKAGLTFLVDLIKNKHMNADTDYSIAEAAFNKGETAMTINGPWAWSNIDTSKV
+NYGVTVLPTFKGQPSKPFVGVLSAGINAASPNKELAKEFLENYLLTDEGLEAVNKDKPLG
+AVALKSYEEELAKDPRIAATMENAQKGEIMPNIPQMSAFWYAVRTAVINAASGRQTVDEA
+LKDAQTRITK
diff --git a/docs/examples/malecoli/data/MALE_ECOLI.native.aligned.pdb b/docs/examples/malecoli/data/MALE_ECOLI.native.aligned.pdb
new file mode 100644
index 0000000000000000000000000000000000000000..4a25b8ad25b389462bab0b40f846b9794241ff9f
--- /dev/null
+++ b/docs/examples/malecoli/data/MALE_ECOLI.native.aligned.pdb
@@ -0,0 +1,2864 @@
+ATOM 1 N LYS A 1 -2.124 -25.318 -20.806 1.00 51.32 N
+ATOM 2 CA LYS A 1 -3.141 -24.729 -21.724 1.00 51.45 C
+ATOM 3 C LYS A 1 -2.638 -23.339 -22.101 1.00 50.89 C
+ATOM 4 O LYS A 1 -3.062 -22.299 -21.598 1.00 51.44 O
+ATOM 5 CB LYS A 1 -4.503 -24.710 -21.074 1.00 51.33 C
+ATOM 6 N ILE A 2 -1.665 -23.374 -22.989 1.00 50.70 N
+ATOM 7 CA ILE A 2 -0.973 -22.184 -23.500 1.00 48.87 C
+ATOM 8 C ILE A 2 -1.790 -21.520 -24.579 1.00 47.23 C
+ATOM 9 O ILE A 2 -1.270 -21.402 -25.709 1.00 48.71 O
+ATOM 10 CB ILE A 2 0.395 -22.660 -24.042 1.00 50.18 C
+ATOM 11 N GLU A 3 -3.002 -21.113 -24.275 1.00 44.56 N
+ATOM 12 CA GLU A 3 -3.876 -20.449 -25.259 1.00 42.95 C
+ATOM 13 C GLU A 3 -3.166 -19.899 -26.479 1.00 41.29 C
+ATOM 14 O GLU A 3 -3.599 -20.276 -27.609 1.00 43.76 O
+ATOM 15 CB GLU A 3 -4.765 -19.441 -24.547 1.00 45.09 C
+ATOM 16 N GLU A 4 -2.158 -19.067 -26.438 1.00 38.11 N
+ATOM 17 CA GLU A 4 -1.457 -18.557 -27.617 1.00 36.54 C
+ATOM 18 C GLU A 4 -2.266 -17.693 -28.584 1.00 36.01 C
+ATOM 19 O GLU A 4 -3.388 -18.021 -29.018 1.00 35.53 O
+ATOM 20 CB GLU A 4 -0.864 -19.719 -28.414 1.00 35.47 C
+ATOM 21 N GLY A 5 -1.642 -16.579 -28.951 1.00 35.12 N
+ATOM 22 CA GLY A 5 -2.163 -15.578 -29.877 1.00 35.75 C
+ATOM 23 C GLY A 5 -3.353 -14.780 -29.356 1.00 35.63 C
+ATOM 24 O GLY A 5 -4.142 -14.134 -30.089 1.00 35.57 O
+ATOM 25 N LYS A 6 -3.447 -14.830 -28.033 1.00 34.98 N
+ATOM 26 CA LYS A 6 -4.461 -14.188 -27.228 1.00 32.33 C
+ATOM 27 C LYS A 6 -3.807 -13.584 -25.981 1.00 29.76 C
+ATOM 28 O LYS A 6 -2.703 -13.984 -25.633 1.00 28.40 O
+ATOM 29 CB LYS A 6 -5.488 -15.166 -26.682 1.00 34.33 C
+ATOM 30 CG LYS A 6 -6.784 -15.168 -27.493 1.00 38.99 C
+ATOM 31 CD LYS A 6 -7.992 -15.092 -26.542 1.00 42.14 C
+ATOM 32 CE LYS A 6 -8.381 -13.629 -26.335 1.00 44.25 C
+ATOM 33 NZ LYS A 6 -7.164 -12.806 -26.086 1.00 44.57 N
+ATOM 34 N LEU A 7 -4.590 -12.669 -25.432 1.00 27.32 N
+ATOM 35 CA LEU A 7 -4.172 -12.003 -24.190 1.00 26.28 C
+ATOM 36 C LEU A 7 -5.317 -12.208 -23.205 1.00 26.33 C
+ATOM 37 O LEU A 7 -6.470 -12.005 -23.599 1.00 26.86 O
+ATOM 38 CB LEU A 7 -3.650 -10.607 -24.438 1.00 24.91 C
+ATOM 39 CG LEU A 7 -2.144 -10.418 -24.511 1.00 23.75 C
+ATOM 40 CD1 LEU A 7 -1.695 -9.010 -24.172 1.00 23.92 C
+ATOM 41 CD2 LEU A 7 -1.475 -11.367 -23.512 1.00 24.65 C
+ATOM 42 N VAL A 8 -4.966 -12.680 -22.008 1.00 26.32 N
+ATOM 43 CA VAL A 8 -5.958 -12.897 -20.935 1.00 25.44 C
+ATOM 44 C VAL A 8 -5.296 -12.303 -19.675 1.00 24.15 C
+ATOM 45 O VAL A 8 -4.167 -12.603 -19.321 1.00 22.66 O
+ATOM 46 CB VAL A 8 -6.577 -14.267 -20.867 1.00 26.03 C
+ATOM 47 CG1 VAL A 8 -5.767 -15.413 -21.459 1.00 28.11 C
+ATOM 48 CG2 VAL A 8 -6.935 -14.667 -19.421 1.00 28.26 C
+ATOM 49 N ILE A 9 -6.042 -11.352 -19.127 1.00 24.59 N
+ATOM 50 CA ILE A 9 -5.676 -10.569 -17.955 1.00 22.58 C
+ATOM 51 C ILE A 9 -6.674 -10.836 -16.827 1.00 22.77 C
+ATOM 52 O ILE A 9 -7.874 -10.979 -17.068 1.00 22.60 O
+ATOM 53 CB ILE A 9 -5.613 -9.050 -18.261 1.00 22.61 C
+ATOM 54 CG1 ILE A 9 -4.594 -8.768 -19.409 1.00 23.31 C
+ATOM 55 CG2 ILE A 9 -5.309 -8.178 -17.031 1.00 22.30 C
+ATOM 56 CD1 ILE A 9 -5.017 -7.414 -20.110 1.00 22.47 C
+ATOM 57 N TRP A 10 -6.091 -10.914 -15.659 1.00 23.13 N
+ATOM 58 CA TRP A 10 -6.822 -11.155 -14.406 1.00 22.41 C
+ATOM 59 C TRP A 10 -6.579 -9.935 -13.502 1.00 22.62 C
+ATOM 60 O TRP A 10 -5.418 -9.607 -13.190 1.00 21.39 O
+ATOM 61 CB TRP A 10 -6.278 -12.422 -13.790 1.00 23.44 C
+ATOM 62 CG TRP A 10 -6.951 -13.696 -14.159 1.00 24.26 C
+ATOM 63 CD1 TRP A 10 -7.800 -13.928 -15.188 1.00 23.93 C
+ATOM 64 CD2 TRP A 10 -6.823 -14.937 -13.431 1.00 25.53 C
+ATOM 65 NE1 TRP A 10 -8.234 -15.229 -15.139 1.00 25.49 N
+ATOM 66 CE2 TRP A 10 -7.650 -15.876 -14.089 1.00 26.47 C
+ATOM 67 CE3 TRP A 10 -6.098 -15.332 -12.296 1.00 25.67 C
+ATOM 68 CZ2 TRP A 10 -7.759 -17.195 -13.647 1.00 26.92 C
+ATOM 69 CZ3 TRP A 10 -6.196 -16.638 -11.876 1.00 25.12 C
+ATOM 70 CH2 TRP A 10 -7.013 -17.557 -12.522 1.00 26.35 C
+ATOM 71 N ILE A 11 -7.698 -9.321 -13.162 1.00 23.14 N
+ATOM 72 CA ILE A 11 -7.669 -8.132 -12.281 1.00 23.52 C
+ATOM 73 C ILE A 11 -8.754 -8.237 -11.216 1.00 24.82 C
+ATOM 74 O ILE A 11 -9.856 -8.722 -11.553 1.00 25.03 O
+ATOM 75 CB ILE A 11 -7.806 -6.836 -13.172 1.00 21.02 C
+ATOM 76 CG1 ILE A 11 -7.086 -5.668 -12.454 1.00 19.38 C
+ATOM 77 CG2 ILE A 11 -9.252 -6.535 -13.561 1.00 19.84 C
+ATOM 78 CD1 ILE A 11 -7.233 -4.286 -13.135 1.00 19.15 C
+ATOM 79 N ASN A 12 -8.495 -7.771 -9.999 1.00 26.96 N
+ATOM 80 CA ASN A 12 -9.507 -7.810 -8.940 1.00 28.86 C
+ATOM 81 C ASN A 12 -10.765 -7.048 -9.399 1.00 30.80 C
+ATOM 82 O ASN A 12 -10.622 -6.085 -10.162 1.00 30.41 O
+ATOM 83 CB ASN A 12 -9.030 -7.228 -7.617 1.00 28.83 C
+ATOM 84 CG ASN A 12 -9.845 -7.849 -6.474 1.00 28.57 C
+ATOM 85 OD1 ASN A 12 -10.750 -8.661 -6.711 1.00 29.79 O
+ATOM 86 ND2 ASN A 12 -9.500 -7.504 -5.243 1.00 30.18 N
+ATOM 87 N GLY A 13 -11.906 -7.468 -8.889 1.00 32.05 N
+ATOM 88 CA GLY A 13 -13.197 -6.896 -9.190 1.00 33.50 C
+ATOM 89 C GLY A 13 -13.462 -5.452 -8.800 1.00 33.70 C
+ATOM 90 O GLY A 13 -14.344 -4.801 -9.405 1.00 34.42 O
+ATOM 91 N ASP A 14 -12.769 -4.937 -7.827 1.00 32.79 N
+ATOM 92 CA ASP A 14 -12.870 -3.598 -7.297 1.00 31.84 C
+ATOM 93 C ASP A 14 -11.906 -2.658 -8.007 1.00 32.03 C
+ATOM 94 O ASP A 14 -11.453 -1.657 -7.394 1.00 33.51 O
+ATOM 95 CB ASP A 14 -12.603 -3.654 -5.774 1.00 33.53 C
+ATOM 96 CG ASP A 14 -11.118 -3.830 -5.531 1.00 35.36 C
+ATOM 97 OD1 ASP A 14 -10.498 -4.573 -6.333 1.00 36.40 O
+ATOM 98 OD2 ASP A 14 -10.550 -3.210 -4.623 1.00 39.90 O
+ATOM 99 N LYS A 15 -11.587 -2.977 -9.253 1.00 29.82 N
+ATOM 100 CA LYS A 15 -10.671 -2.128 -10.046 1.00 26.47 C
+ATOM 101 C LYS A 15 -11.292 -1.755 -11.393 1.00 24.09 C
+ATOM 102 O LYS A 15 -12.366 -2.214 -11.781 1.00 23.15 O
+ATOM 103 CB LYS A 15 -9.299 -2.753 -10.223 1.00 27.82 C
+ATOM 104 CG LYS A 15 -8.923 -3.655 -9.041 1.00 28.44 C
+ATOM 105 CD LYS A 15 -8.453 -2.805 -7.881 1.00 28.03 C
+ATOM 106 CE LYS A 15 -6.961 -2.640 -7.971 1.00 27.93 C
+ATOM 107 NZ LYS A 15 -6.585 -1.397 -7.270 1.00 32.00 N
+ATOM 108 N GLY A 16 -10.581 -0.901 -12.097 1.00 24.30 N
+ATOM 109 CA GLY A 16 -11.037 -0.388 -13.379 1.00 26.57 C
+ATOM 110 C GLY A 16 -10.905 -1.368 -14.526 1.00 27.74 C
+ATOM 111 O GLY A 16 -10.259 -1.071 -15.550 1.00 27.87 O
+ATOM 112 N TYR A 17 -11.584 -2.489 -14.379 1.00 28.24 N
+ATOM 113 CA TYR A 17 -11.562 -3.564 -15.369 1.00 29.46 C
+ATOM 114 C TYR A 17 -12.293 -3.285 -16.652 1.00 30.43 C
+ATOM 115 O TYR A 17 -12.081 -4.006 -17.660 1.00 31.30 O
+ATOM 116 CB TYR A 17 -11.966 -4.854 -14.666 1.00 31.24 C
+ATOM 117 CG TYR A 17 -13.377 -4.990 -14.200 1.00 33.61 C
+ATOM 118 CD1 TYR A 17 -14.366 -5.358 -15.117 1.00 33.73 C
+ATOM 119 CD2 TYR A 17 -13.752 -4.772 -12.868 1.00 36.58 C
+ATOM 120 CE1 TYR A 17 -15.690 -5.514 -14.720 1.00 35.18 C
+ATOM 121 CE2 TYR A 17 -15.084 -4.904 -12.462 1.00 35.91 C
+ATOM 122 CZ TYR A 17 -16.040 -5.292 -13.390 1.00 36.23 C
+ATOM 123 OH TYR A 17 -17.364 -5.477 -13.065 1.00 37.22 O
+ATOM 124 N ASN A 18 -13.107 -2.247 -16.726 1.00 31.87 N
+ATOM 125 CA ASN A 18 -13.808 -1.923 -17.994 1.00 31.21 C
+ATOM 126 C ASN A 18 -12.896 -0.954 -18.766 1.00 31.10 C
+ATOM 127 O ASN A 18 -12.791 -0.977 -19.996 1.00 31.15 O
+ATOM 128 CB ASN A 18 -15.205 -1.396 -17.821 1.00 32.51 C
+ATOM 129 CG ASN A 18 -16.168 -2.330 -17.125 1.00 33.41 C
+ATOM 130 OD1 ASN A 18 -16.463 -2.104 -15.945 1.00 35.65 O
+ATOM 131 ND2 ASN A 18 -16.646 -3.329 -17.858 1.00 34.47 N
+ATOM 132 N GLY A 19 -12.247 -0.119 -17.968 1.00 30.98 N
+ATOM 133 CA GLY A 19 -11.334 0.864 -18.613 1.00 31.21 C
+ATOM 134 C GLY A 19 -10.195 0.067 -19.249 1.00 31.94 C
+ATOM 135 O GLY A 19 -9.743 0.371 -20.351 1.00 32.56 O
+ATOM 136 N LEU A 20 -9.731 -0.893 -18.473 1.00 31.61 N
+ATOM 137 CA LEU A 20 -8.648 -1.800 -18.831 1.00 30.75 C
+ATOM 138 C LEU A 20 -9.020 -2.530 -20.126 1.00 30.04 C
+ATOM 139 O LEU A 20 -8.117 -2.723 -20.955 1.00 30.47 O
+ATOM 140 CB LEU A 20 -8.308 -2.718 -17.629 1.00 30.29 C
+ATOM 141 CG LEU A 20 -7.160 -3.702 -17.796 1.00 28.16 C
+ATOM 142 CD1 LEU A 20 -5.911 -2.984 -18.295 1.00 28.73 C
+ATOM 143 CD2 LEU A 20 -6.844 -4.393 -16.499 1.00 26.84 C
+ATOM 144 N ALA A 21 -10.278 -2.887 -20.262 1.00 29.49 N
+ATOM 145 CA ALA A 21 -10.793 -3.564 -21.456 1.00 30.94 C
+ATOM 146 C ALA A 21 -10.700 -2.664 -22.685 1.00 31.79 C
+ATOM 147 O ALA A 21 -10.246 -3.124 -23.744 1.00 33.65 O
+ATOM 148 CB ALA A 21 -12.226 -4.033 -21.278 1.00 30.13 C
+ATOM 149 N GLU A 22 -11.101 -1.426 -22.574 1.00 32.77 N
+ATOM 150 CA GLU A 22 -11.043 -0.451 -23.657 1.00 34.03 C
+ATOM 151 C GLU A 22 -9.608 -0.304 -24.159 1.00 32.43 C
+ATOM 152 O GLU A 22 -9.407 0.013 -25.346 1.00 32.83 O
+ATOM 153 CB GLU A 22 -11.546 0.947 -23.295 1.00 37.28 C
+ATOM 154 CG GLU A 22 -13.020 1.297 -23.515 1.00 43.00 C
+ATOM 155 CD GLU A 22 -13.662 0.891 -24.810 1.00 45.81 C
+ATOM 156 OE1 GLU A 22 -13.443 1.694 -25.763 1.00 47.16 O
+ATOM 157 OE2 GLU A 22 -14.339 -0.131 -24.974 1.00 47.54 O
+ATOM 158 N VAL A 23 -8.646 -0.503 -23.274 1.00 30.16 N
+ATOM 159 CA VAL A 23 -7.217 -0.414 -23.622 1.00 28.00 C
+ATOM 160 C VAL A 23 -6.871 -1.669 -24.483 1.00 28.71 C
+ATOM 161 O VAL A 23 -6.013 -1.632 -25.356 1.00 27.27 O
+ATOM 162 CB VAL A 23 -6.281 -0.357 -22.414 1.00 25.98 C
+ATOM 163 CG1 VAL A 23 -4.827 -0.207 -22.867 1.00 23.75 C
+ATOM 164 CG2 VAL A 23 -6.603 0.704 -21.372 1.00 26.20 C
+ATOM 165 N GLY A 24 -7.590 -2.705 -24.116 1.00 29.46 N
+ATOM 166 CA GLY A 24 -7.525 -4.044 -24.679 1.00 32.30 C
+ATOM 167 C GLY A 24 -8.054 -4.023 -26.108 1.00 34.11 C
+ATOM 168 O GLY A 24 -7.502 -4.696 -26.997 1.00 34.75 O
+ATOM 169 N LYS A 25 -9.101 -3.239 -26.267 1.00 35.00 N
+ATOM 170 CA LYS A 25 -9.763 -3.034 -27.567 1.00 35.37 C
+ATOM 171 C LYS A 25 -8.817 -2.218 -28.436 1.00 35.59 C
+ATOM 172 O LYS A 25 -8.693 -2.457 -29.646 1.00 37.20 O
+ATOM 173 CB LYS A 25 -11.069 -2.280 -27.406 1.00 36.42 C
+ATOM 174 CG LYS A 25 -12.058 -2.941 -26.456 1.00 37.93 C
+ATOM 175 CD LYS A 25 -13.040 -3.860 -27.122 1.00 41.18 C
+ATOM 176 CE LYS A 25 -14.019 -3.158 -28.065 1.00 42.53 C
+ATOM 177 NZ LYS A 25 -15.089 -4.105 -28.533 1.00 41.31 N
+ATOM 178 N LYS A 26 -8.181 -1.255 -27.778 1.00 35.21 N
+ATOM 179 CA LYS A 26 -7.234 -0.378 -28.486 1.00 34.92 C
+ATOM 180 C LYS A 26 -6.127 -1.279 -29.034 1.00 33.97 C
+ATOM 181 O LYS A 26 -5.779 -1.167 -30.209 1.00 34.26 O
+ATOM 182 CB LYS A 26 -6.671 0.759 -27.669 1.00 36.57 C
+ATOM 183 CG LYS A 26 -5.341 1.313 -28.228 1.00 39.87 C
+ATOM 184 CD LYS A 26 -5.598 2.295 -29.337 1.00 43.66 C
+ATOM 185 CE LYS A 26 -4.594 2.388 -30.468 1.00 44.53 C
+ATOM 186 NZ LYS A 26 -5.314 2.825 -31.727 1.00 45.19 N
+ATOM 187 N PHE A 27 -5.624 -2.150 -28.174 1.00 31.83 N
+ATOM 188 CA PHE A 27 -4.550 -3.061 -28.577 1.00 30.42 C
+ATOM 189 C PHE A 27 -4.970 -3.892 -29.798 1.00 31.69 C
+ATOM 190 O PHE A 27 -4.174 -4.044 -30.732 1.00 31.10 O
+ATOM 191 CB PHE A 27 -4.099 -3.967 -27.448 1.00 27.12 C
+ATOM 192 CG PHE A 27 -2.912 -4.836 -27.740 1.00 23.96 C
+ATOM 193 CD1 PHE A 27 -1.656 -4.271 -27.947 1.00 23.24 C
+ATOM 194 CD2 PHE A 27 -3.062 -6.227 -27.792 1.00 22.43 C
+ATOM 195 CE1 PHE A 27 -0.532 -5.057 -28.193 1.00 23.60 C
+ATOM 196 CE2 PHE A 27 -1.958 -7.028 -28.023 1.00 21.21 C
+ATOM 197 CZ PHE A 27 -0.708 -6.463 -28.221 1.00 22.74 C
+ATOM 198 N GLU A 28 -6.163 -4.414 -29.711 1.00 33.40 N
+ATOM 199 CA GLU A 28 -6.761 -5.273 -30.722 1.00 36.81 C
+ATOM 200 C GLU A 28 -6.845 -4.617 -32.094 1.00 39.61 C
+ATOM 201 O GLU A 28 -6.929 -5.317 -33.138 1.00 40.67 O
+ATOM 202 CB GLU A 28 -8.130 -5.741 -30.301 1.00 36.75 C
+ATOM 203 CG GLU A 28 -8.933 -6.662 -31.204 1.00 39.13 C
+ATOM 204 CD GLU A 28 -10.312 -6.896 -30.651 1.00 42.26 C
+ATOM 205 OE1 GLU A 28 -10.350 -7.778 -29.767 1.00 44.93 O
+ATOM 206 OE2 GLU A 28 -11.307 -6.266 -30.980 1.00 45.48 O
+ATOM 207 N LYS A 29 -6.790 -3.299 -32.097 1.00 40.77 N
+ATOM 208 CA LYS A 29 -6.861 -2.508 -33.334 1.00 42.46 C
+ATOM 209 C LYS A 29 -5.533 -2.413 -34.045 1.00 42.07 C
+ATOM 210 O LYS A 29 -5.512 -2.462 -35.306 1.00 43.64 O
+ATOM 211 CB LYS A 29 -7.422 -1.123 -33.056 1.00 45.17 C
+ATOM 212 CG LYS A 29 -7.935 -0.323 -34.237 1.00 46.89 C
+ATOM 213 CD LYS A 29 -9.303 0.277 -33.947 1.00 48.58 C
+ATOM 214 CE LYS A 29 -10.416 -0.731 -34.190 1.00 50.30 C
+ATOM 215 NZ LYS A 29 -11.632 -0.037 -34.718 1.00 50.76 N
+ATOM 216 N ASP A 30 -4.420 -2.274 -33.354 1.00 40.65 N
+ATOM 217 CA ASP A 30 -3.138 -2.161 -34.082 1.00 39.44 C
+ATOM 218 C ASP A 30 -2.514 -3.557 -34.257 1.00 38.41 C
+ATOM 219 O ASP A 30 -1.488 -3.642 -34.952 1.00 38.06 O
+ATOM 220 CB ASP A 30 -2.164 -1.199 -33.413 1.00 39.61 C
+ATOM 221 CG ASP A 30 -2.700 0.103 -32.889 1.00 39.55 C
+ATOM 222 OD1 ASP A 30 -3.892 0.411 -33.044 1.00 39.70 O
+ATOM 223 OD2 ASP A 30 -1.878 0.854 -32.296 1.00 39.81 O
+ATOM 224 N THR A 31 -3.138 -4.548 -33.657 1.00 36.40 N
+ATOM 225 CA THR A 31 -2.593 -5.901 -33.622 1.00 35.35 C
+ATOM 226 C THR A 31 -3.442 -7.056 -34.049 1.00 34.14 C
+ATOM 227 O THR A 31 -2.863 -8.144 -34.352 1.00 34.92 O
+ATOM 228 CB THR A 31 -2.113 -6.102 -32.088 1.00 35.01 C
+ATOM 229 OG1 THR A 31 -1.157 -4.996 -31.895 1.00 37.91 O
+ATOM 230 CG2 THR A 31 -1.473 -7.422 -31.752 1.00 35.89 C
+ATOM 231 N GLY A 32 -4.752 -6.955 -34.037 1.00 31.92 N
+ATOM 232 CA GLY A 32 -5.563 -8.131 -34.422 1.00 32.12 C
+ATOM 233 C GLY A 32 -5.631 -9.160 -33.304 1.00 32.07 C
+ATOM 234 O GLY A 32 -6.437 -10.123 -33.341 1.00 31.23 O
+ATOM 235 N ILE A 33 -4.803 -8.944 -32.282 1.00 33.50 N
+ATOM 236 CA ILE A 33 -4.779 -9.834 -31.112 1.00 34.12 C
+ATOM 237 C ILE A 33 -5.878 -9.412 -30.122 1.00 33.43 C
+ATOM 238 O ILE A 33 -5.958 -8.254 -29.755 1.00 33.05 O
+ATOM 239 CB ILE A 33 -3.397 -9.968 -30.393 1.00 34.11 C
+ATOM 240 CG1 ILE A 33 -2.348 -10.580 -31.381 1.00 34.29 C
+ATOM 241 CG2 ILE A 33 -3.468 -10.830 -29.100 1.00 31.50 C
+ATOM 242 CD1 ILE A 33 -2.802 -11.990 -31.889 1.00 34.86 C
+ATOM 243 N LYS A 34 -6.634 -10.401 -29.720 1.00 34.33 N
+ATOM 244 CA LYS A 34 -7.702 -10.237 -28.738 1.00 35.89 C
+ATOM 245 C LYS A 34 -7.117 -10.243 -27.312 1.00 34.70 C
+ATOM 246 O LYS A 34 -6.146 -10.940 -26.953 1.00 32.63 O
+ATOM 247 CB LYS A 34 -8.755 -11.344 -28.846 1.00 38.21 C
+ATOM 248 CG LYS A 34 -9.187 -11.538 -30.312 1.00 44.76 C
+ATOM 249 CD LYS A 34 -10.208 -12.658 -30.460 1.00 50.10 C
+ATOM 250 CE LYS A 34 -9.560 -13.998 -30.818 1.00 52.94 C
+ATOM 251 NZ LYS A 34 -9.287 -14.826 -29.603 1.00 53.84 N
+ATOM 252 N VAL A 35 -7.724 -9.345 -26.543 1.00 33.37 N
+ATOM 253 CA VAL A 35 -7.394 -9.175 -25.118 1.00 32.15 C
+ATOM 254 C VAL A 35 -8.676 -9.659 -24.428 1.00 31.61 C
+ATOM 255 O VAL A 35 -9.683 -9.801 -25.131 1.00 33.94 O
+ATOM 256 CB VAL A 35 -6.882 -7.821 -24.707 1.00 31.26 C
+ATOM 257 CG1 VAL A 35 -6.382 -7.786 -23.250 1.00 30.28 C
+ATOM 258 CG2 VAL A 35 -5.762 -7.306 -25.598 1.00 31.19 C
+ATOM 259 N THR A 36 -8.565 -9.989 -23.180 1.00 31.42 N
+ATOM 260 CA THR A 36 -9.658 -10.475 -22.357 1.00 30.35 C
+ATOM 261 C THR A 36 -9.266 -10.241 -20.879 1.00 28.75 C
+ATOM 262 O THR A 36 -8.248 -10.797 -20.462 1.00 27.78 O
+ATOM 263 CB THR A 36 -9.957 -12.020 -22.506 1.00 31.08 C
+ATOM 264 OG1 THR A 36 -9.899 -12.362 -23.898 1.00 30.73 O
+ATOM 265 CG2 THR A 36 -11.269 -12.431 -21.814 1.00 31.31 C
+ATOM 266 N VAL A 37 -10.088 -9.454 -20.243 1.00 27.98 N
+ATOM 267 CA VAL A 37 -9.917 -9.102 -18.829 1.00 28.62 C
+ATOM 268 C VAL A 37 -11.022 -9.832 -18.047 1.00 27.52 C
+ATOM 269 O VAL A 37 -12.171 -9.765 -18.471 1.00 25.59 O
+ATOM 270 CB VAL A 37 -10.032 -7.578 -18.591 1.00 29.96 C
+ATOM 271 CG1 VAL A 37 -9.798 -7.232 -17.117 1.00 29.20 C
+ATOM 272 CG2 VAL A 37 -9.172 -6.751 -19.521 1.00 28.66 C
+ATOM 273 N GLU A 38 -10.619 -10.473 -16.971 1.00 28.22 N
+ATOM 274 CA GLU A 38 -11.556 -11.182 -16.090 1.00 29.29 C
+ATOM 275 C GLU A 38 -11.244 -10.737 -14.667 1.00 30.54 C
+ATOM 276 O GLU A 38 -10.136 -10.264 -14.411 1.00 30.68 O
+ATOM 277 CB GLU A 38 -11.441 -12.693 -16.197 1.00 30.17 C
+ATOM 278 CG GLU A 38 -11.247 -13.209 -17.624 1.00 32.27 C
+ATOM 279 CD GLU A 38 -11.133 -14.679 -17.798 1.00 34.02 C
+ATOM 280 OE1 GLU A 38 -10.246 -15.347 -17.284 1.00 36.69 O
+ATOM 281 OE2 GLU A 38 -12.028 -15.140 -18.530 1.00 35.18 O
+ATOM 282 N HIS A 39 -12.211 -10.923 -13.810 1.00 33.16 N
+ATOM 283 CA HIS A 39 -12.125 -10.564 -12.376 1.00 35.48 C
+ATOM 284 C HIS A 39 -12.760 -11.657 -11.515 1.00 36.48 C
+ATOM 285 O HIS A 39 -13.822 -11.485 -10.895 1.00 37.03 O
+ATOM 286 CB HIS A 39 -12.806 -9.181 -12.106 1.00 35.39 C
+ATOM 287 CG HIS A 39 -14.001 -9.013 -13.002 1.00 36.87 C
+ATOM 288 ND1 HIS A 39 -15.293 -9.273 -12.609 1.00 37.23 N
+ATOM 289 CD2 HIS A 39 -14.067 -8.659 -14.301 1.00 37.20 C
+ATOM 290 CE1 HIS A 39 -16.116 -9.088 -13.628 1.00 37.42 C
+ATOM 291 NE2 HIS A 39 -15.392 -8.735 -14.659 1.00 38.49 N
+ATOM 292 N PRO A 40 -12.099 -12.812 -11.505 1.00 37.82 N
+ATOM 293 CA PRO A 40 -12.583 -13.965 -10.754 1.00 39.02 C
+ATOM 294 C PRO A 40 -12.393 -13.728 -9.272 1.00 39.46 C
+ATOM 295 O PRO A 40 -11.379 -13.151 -8.875 1.00 39.59 O
+ATOM 296 CB PRO A 40 -11.727 -15.136 -11.271 1.00 38.36 C
+ATOM 297 CG PRO A 40 -10.425 -14.476 -11.614 1.00 37.45 C
+ATOM 298 CD PRO A 40 -10.837 -13.128 -12.189 1.00 37.33 C
+ATOM 299 N ASP A 41 -13.382 -14.195 -8.528 1.00 41.74 N
+ATOM 300 CA ASP A 41 -13.358 -14.103 -7.050 1.00 42.65 C
+ATOM 301 C ASP A 41 -12.075 -14.856 -6.632 1.00 42.37 C
+ATOM 302 O ASP A 41 -11.672 -15.841 -7.279 1.00 43.36 O
+ATOM 303 CB ASP A 41 -14.573 -14.744 -6.391 1.00 44.11 C
+ATOM 304 CG ASP A 41 -15.929 -14.147 -6.633 1.00 46.86 C
+ATOM 305 OD1 ASP A 41 -16.106 -12.965 -6.191 1.00 49.34 O
+ATOM 306 OD2 ASP A 41 -16.848 -14.779 -7.217 1.00 47.35 O
+ATOM 307 N LYS A 42 -11.473 -14.374 -5.572 1.00 41.59 N
+ATOM 308 CA LYS A 42 -10.286 -15.070 -5.056 1.00 39.95 C
+ATOM 309 C LYS A 42 -9.191 -15.338 -6.046 1.00 37.51 C
+ATOM 310 O LYS A 42 -8.517 -16.376 -5.887 1.00 37.01 O
+ATOM 311 CB LYS A 42 -10.825 -16.438 -4.538 1.00 41.54 C
+ATOM 312 CG LYS A 42 -11.743 -16.189 -3.297 1.00 44.11 C
+ATOM 313 CD LYS A 42 -10.825 -15.837 -2.119 1.00 45.62 C
+ATOM 314 CE LYS A 42 -11.552 -15.498 -0.841 1.00 45.51 C
+ATOM 315 NZ LYS A 42 -10.598 -14.821 0.081 1.00 46.32 N
+ATOM 316 N LEU A 43 -8.953 -14.455 -6.980 1.00 35.54 N
+ATOM 317 CA LEU A 43 -7.913 -14.602 -8.000 1.00 33.66 C
+ATOM 318 C LEU A 43 -6.536 -14.721 -7.385 1.00 33.41 C
+ATOM 319 O LEU A 43 -5.639 -15.376 -7.964 1.00 35.64 O
+ATOM 320 CB LEU A 43 -8.041 -13.460 -9.016 1.00 33.22 C
+ATOM 321 CG LEU A 43 -7.371 -12.122 -8.862 1.00 30.71 C
+ATOM 322 CD1 LEU A 43 -5.876 -12.115 -9.162 1.00 30.25 C
+ATOM 323 CD2 LEU A 43 -8.020 -11.155 -9.860 1.00 32.39 C
+ATOM 324 N GLU A 44 -6.305 -14.086 -6.268 1.00 32.49 N
+ATOM 325 CA GLU A 44 -4.987 -14.116 -5.622 1.00 32.43 C
+ATOM 326 C GLU A 44 -4.696 -15.514 -5.104 1.00 32.18 C
+ATOM 327 O GLU A 44 -3.534 -15.851 -4.817 1.00 32.55 O
+ATOM 328 CB GLU A 44 -4.886 -13.113 -4.483 1.00 34.55 C
+ATOM 329 CG GLU A 44 -5.597 -13.474 -3.182 1.00 36.87 C
+ATOM 330 CD GLU A 44 -7.008 -13.054 -2.986 1.00 38.49 C
+ATOM 331 OE1 GLU A 44 -7.700 -12.941 -4.017 1.00 38.74 O
+ATOM 332 OE2 GLU A 44 -7.471 -12.816 -1.866 1.00 41.46 O
+ATOM 333 N GLU A 45 -5.721 -16.332 -4.977 1.00 31.53 N
+ATOM 334 CA GLU A 45 -5.507 -17.702 -4.496 1.00 32.51 C
+ATOM 335 C GLU A 45 -5.581 -18.728 -5.609 1.00 31.34 C
+ATOM 336 O GLU A 45 -4.917 -19.765 -5.563 1.00 31.84 O
+ATOM 337 CB GLU A 45 -6.462 -18.123 -3.387 1.00 34.10 C
+ATOM 338 CG GLU A 45 -5.900 -17.931 -1.960 1.00 38.67 C
+ATOM 339 CD GLU A 45 -6.636 -16.876 -1.173 1.00 41.38 C
+ATOM 340 OE1 GLU A 45 -7.872 -16.802 -1.210 1.00 42.61 O
+ATOM 341 OE2 GLU A 45 -5.832 -16.172 -0.526 1.00 42.30 O
+ATOM 342 N LYS A 46 -6.393 -18.461 -6.587 1.00 30.98 N
+ATOM 343 CA LYS A 46 -6.596 -19.304 -7.753 1.00 31.07 C
+ATOM 344 C LYS A 46 -5.366 -19.254 -8.642 1.00 29.95 C
+ATOM 345 O LYS A 46 -5.002 -20.294 -9.230 1.00 31.12 O
+ATOM 346 CB LYS A 46 -7.843 -18.873 -8.556 1.00 33.46 C
+ATOM 347 CG LYS A 46 -9.123 -19.172 -7.760 1.00 36.73 C
+ATOM 348 CD LYS A 46 -10.423 -19.014 -8.501 1.00 38.36 C
+ATOM 349 CE LYS A 46 -11.656 -19.339 -7.670 1.00 38.90 C
+ATOM 350 NZ LYS A 46 -12.798 -18.451 -8.061 1.00 39.33 N
+ATOM 351 N PHE A 47 -4.741 -18.078 -8.722 1.00 27.92 N
+ATOM 352 CA PHE A 47 -3.565 -17.930 -9.575 1.00 26.53 C
+ATOM 353 C PHE A 47 -2.533 -19.028 -9.291 1.00 28.23 C
+ATOM 354 O PHE A 47 -2.211 -19.785 -10.215 1.00 29.21 O
+ATOM 355 CB PHE A 47 -2.926 -16.558 -9.670 1.00 22.31 C
+ATOM 356 CG PHE A 47 -1.737 -16.451 -10.586 1.00 20.12 C
+ATOM 357 CD1 PHE A 47 -1.877 -16.408 -11.969 1.00 17.43 C
+ATOM 358 CD2 PHE A 47 -0.443 -16.404 -10.065 1.00 18.16 C
+ATOM 359 CE1 PHE A 47 -0.773 -16.280 -12.807 1.00 14.87 C
+ATOM 360 CE2 PHE A 47 0.672 -16.307 -10.876 1.00 16.84 C
+ATOM 361 CZ PHE A 47 0.499 -16.227 -12.257 1.00 15.84 C
+ATOM 362 N PRO A 48 -1.993 -19.080 -8.087 1.00 28.94 N
+ATOM 363 CA PRO A 48 -0.975 -20.063 -7.721 1.00 28.28 C
+ATOM 364 C PRO A 48 -1.401 -21.486 -7.996 1.00 27.99 C
+ATOM 365 O PRO A 48 -0.564 -22.339 -8.358 1.00 28.14 O
+ATOM 366 CB PRO A 48 -0.674 -19.761 -6.260 1.00 27.70 C
+ATOM 367 CG PRO A 48 -1.885 -19.032 -5.754 1.00 26.78 C
+ATOM 368 CD PRO A 48 -2.335 -18.195 -6.940 1.00 27.45 C
+ATOM 369 N GLN A 49 -2.675 -21.767 -7.858 1.00 28.50 N
+ATOM 370 CA GLN A 49 -3.175 -23.120 -8.097 1.00 29.69 C
+ATOM 371 C GLN A 49 -3.172 -23.408 -9.586 1.00 29.78 C
+ATOM 372 O GLN A 49 -2.490 -24.409 -9.947 1.00 32.10 O
+ATOM 373 CB GLN A 49 -4.462 -23.471 -7.384 1.00 32.08 C
+ATOM 374 CG GLN A 49 -5.750 -23.109 -8.068 1.00 36.65 C
+ATOM 375 CD GLN A 49 -7.001 -23.334 -7.259 1.00 39.01 C
+ATOM 376 OE1 GLN A 49 -6.998 -23.451 -6.024 1.00 39.43 O
+ATOM 377 NE2 GLN A 49 -8.143 -23.376 -7.970 1.00 39.39 N
+ATOM 378 N VAL A 50 -3.833 -22.635 -10.420 1.00 27.99 N
+ATOM 379 CA VAL A 50 -3.870 -22.897 -11.867 1.00 26.13 C
+ATOM 380 C VAL A 50 -2.522 -22.769 -12.566 1.00 26.41 C
+ATOM 381 O VAL A 50 -2.223 -23.538 -13.498 1.00 24.72 O
+ATOM 382 CB VAL A 50 -4.996 -22.102 -12.543 1.00 23.95 C
+ATOM 383 CG1 VAL A 50 -6.316 -22.268 -11.814 1.00 23.71 C
+ATOM 384 CG2 VAL A 50 -4.658 -20.638 -12.757 1.00 25.56 C
+ATOM 385 N ALA A 51 -1.701 -21.832 -12.165 1.00 27.16 N
+ATOM 386 CA ALA A 51 -0.395 -21.572 -12.753 1.00 28.21 C
+ATOM 387 C ALA A 51 0.613 -22.676 -12.473 1.00 30.45 C
+ATOM 388 O ALA A 51 1.510 -22.976 -13.316 1.00 31.34 O
+ATOM 389 CB ALA A 51 0.105 -20.195 -12.323 1.00 25.41 C
+ATOM 390 N ALA A 52 0.545 -23.276 -11.293 1.00 31.58 N
+ATOM 391 CA ALA A 52 1.490 -24.357 -10.944 1.00 32.98 C
+ATOM 392 C ALA A 52 1.453 -25.410 -12.053 1.00 34.68 C
+ATOM 393 O ALA A 52 2.484 -26.043 -12.338 1.00 36.77 O
+ATOM 394 CB ALA A 52 1.228 -24.938 -9.560 1.00 31.57 C
+ATOM 395 N THR A 53 0.306 -25.563 -12.694 1.00 35.09 N
+ATOM 396 CA THR A 53 0.107 -26.524 -13.772 1.00 35.19 C
+ATOM 397 C THR A 53 0.058 -25.918 -15.167 1.00 34.43 C
+ATOM 398 O THR A 53 -0.675 -26.414 -16.047 1.00 34.89 O
+ATOM 399 CB THR A 53 -1.154 -27.422 -13.481 1.00 35.60 C
+ATOM 400 OG1 THR A 53 -2.335 -26.639 -13.823 1.00 36.90 O
+ATOM 401 CG2 THR A 53 -1.203 -27.888 -12.025 1.00 37.12 C
+ATOM 402 N GLY A 54 0.843 -24.874 -15.378 1.00 33.57 N
+ATOM 403 CA GLY A 54 0.961 -24.186 -16.642 1.00 32.24 C
+ATOM 404 C GLY A 54 -0.322 -23.573 -17.161 1.00 32.52 C
+ATOM 405 O GLY A 54 -0.465 -23.345 -18.396 1.00 32.83 O
+ATOM 406 N ASP A 55 -1.242 -23.264 -16.265 1.00 31.65 N
+ATOM 407 CA ASP A 55 -2.499 -22.608 -16.643 1.00 31.10 C
+ATOM 408 C ASP A 55 -2.493 -21.148 -16.109 1.00 29.35 C
+ATOM 409 O ASP A 55 -1.469 -20.587 -15.702 1.00 28.26 O
+ATOM 410 CB ASP A 55 -3.714 -23.385 -16.218 1.00 34.92 C
+ATOM 411 CG ASP A 55 -4.098 -24.568 -17.069 1.00 38.56 C
+ATOM 412 OD1 ASP A 55 -3.347 -25.565 -17.074 1.00 40.50 O
+ATOM 413 OD2 ASP A 55 -5.195 -24.474 -17.681 1.00 40.18 O
+ATOM 414 N GLY A 56 -3.702 -20.606 -16.155 1.00 28.82 N
+ATOM 415 CA GLY A 56 -4.057 -19.258 -15.729 1.00 28.20 C
+ATOM 416 C GLY A 56 -3.928 -18.233 -16.861 1.00 28.26 C
+ATOM 417 O GLY A 56 -3.835 -18.590 -18.066 1.00 28.61 O
+ATOM 418 N PRO A 57 -3.899 -16.964 -16.466 1.00 25.31 N
+ATOM 419 CA PRO A 57 -3.783 -15.849 -17.410 1.00 21.36 C
+ATOM 420 C PRO A 57 -2.340 -15.558 -17.727 1.00 19.54 C
+ATOM 421 O PRO A 57 -1.401 -15.990 -17.058 1.00 19.98 O
+ATOM 422 CB PRO A 57 -4.410 -14.702 -16.585 1.00 22.46 C
+ATOM 423 CG PRO A 57 -3.664 -14.964 -15.262 1.00 23.54 C
+ATOM 424 CD PRO A 57 -3.994 -16.475 -15.074 1.00 24.39 C
+ATOM 425 N ASP A 58 -2.191 -14.765 -18.771 1.00 18.44 N
+ATOM 426 CA ASP A 58 -0.913 -14.290 -19.310 1.00 17.40 C
+ATOM 427 C ASP A 58 -0.325 -13.278 -18.352 1.00 17.81 C
+ATOM 428 O ASP A 58 0.860 -13.204 -18.016 1.00 18.84 O
+ATOM 429 CB ASP A 58 -1.228 -13.704 -20.712 1.00 19.46 C
+ATOM 430 CG ASP A 58 -1.553 -14.832 -21.708 1.00 20.04 C
+ATOM 431 OD1 ASP A 58 -0.478 -15.375 -22.110 1.00 20.44 O
+ATOM 432 OD2 ASP A 58 -2.709 -15.186 -21.971 1.00 20.58 O
+ATOM 433 N ILE A 59 -1.284 -12.451 -17.892 1.00 19.67 N
+ATOM 434 CA ILE A 59 -0.964 -11.373 -16.922 1.00 18.88 C
+ATOM 435 C ILE A 59 -1.907 -11.340 -15.752 1.00 17.23 C
+ATOM 436 O ILE A 59 -3.120 -11.552 -15.864 1.00 17.58 O
+ATOM 437 CB ILE A 59 -0.745 -10.080 -17.746 1.00 22.55 C
+ATOM 438 CG1 ILE A 59 -1.595 -8.888 -17.243 1.00 22.65 C
+ATOM 439 CG2 ILE A 59 -0.769 -10.231 -19.291 1.00 23.26 C
+ATOM 440 CD1 ILE A 59 -0.623 -7.811 -16.615 1.00 23.01 C
+ATOM 441 N ILE A 60 -1.339 -11.072 -14.587 1.00 17.45 N
+ATOM 442 CA ILE A 60 -2.120 -10.992 -13.319 1.00 17.83 C
+ATOM 443 C ILE A 60 -1.920 -9.617 -12.684 1.00 15.43 C
+ATOM 444 O ILE A 60 -0.802 -9.120 -12.639 1.00 15.87 O
+ATOM 445 CB ILE A 60 -1.779 -12.143 -12.289 1.00 17.81 C
+ATOM 446 CG1 ILE A 60 -2.900 -12.279 -11.215 1.00 19.56 C
+ATOM 447 CG2 ILE A 60 -0.422 -12.045 -11.564 1.00 17.78 C
+ATOM 448 CD1 ILE A 60 -2.674 -11.364 -9.978 1.00 25.63 C
+ATOM 449 N PHE A 61 -3.006 -9.054 -12.156 1.00 15.58 N
+ATOM 450 CA PHE A 61 -2.833 -7.734 -11.446 1.00 14.83 C
+ATOM 451 C PHE A 61 -3.030 -7.939 -9.933 1.00 14.66 C
+ATOM 452 O PHE A 61 -4.106 -8.425 -9.591 1.00 16.37 O
+ATOM 453 CB PHE A 61 -3.799 -6.702 -11.985 1.00 12.12 C
+ATOM 454 CG PHE A 61 -3.308 -6.012 -13.238 1.00 11.97 C
+ATOM 455 CD1 PHE A 61 -3.595 -6.598 -14.485 1.00 12.46 C
+ATOM 456 CD2 PHE A 61 -2.572 -4.852 -13.133 1.00 11.31 C
+ATOM 457 CE1 PHE A 61 -3.196 -5.968 -15.658 1.00 9.17 C
+ATOM 458 CE2 PHE A 61 -2.134 -4.222 -14.274 1.00 12.79 C
+ATOM 459 CZ PHE A 61 -2.452 -4.775 -15.528 1.00 11.94 C
+ATOM 460 N TRP A 62 -2.042 -7.574 -9.142 1.00 15.25 N
+ATOM 461 CA TRP A 62 -2.190 -7.686 -7.676 1.00 15.72 C
+ATOM 462 C TRP A 62 -1.151 -6.842 -6.979 1.00 14.92 C
+ATOM 463 O TRP A 62 -0.127 -6.540 -7.565 1.00 14.16 O
+ATOM 464 CB TRP A 62 -2.099 -9.144 -7.200 1.00 18.18 C
+ATOM 465 CG TRP A 62 -2.680 -9.247 -5.804 1.00 20.32 C
+ATOM 466 CD1 TRP A 62 -2.054 -9.183 -4.597 1.00 19.82 C
+ATOM 467 CD2 TRP A 62 -4.091 -9.381 -5.558 1.00 18.32 C
+ATOM 468 NE1 TRP A 62 -3.014 -9.308 -3.587 1.00 19.52 N
+ATOM 469 CE2 TRP A 62 -4.251 -9.430 -4.163 1.00 18.73 C
+ATOM 470 CE3 TRP A 62 -5.197 -9.459 -6.387 1.00 16.85 C
+ATOM 471 CZ2 TRP A 62 -5.502 -9.540 -3.608 1.00 19.56 C
+ATOM 472 CZ3 TRP A 62 -6.449 -9.611 -5.842 1.00 19.86 C
+ATOM 473 CH2 TRP A 62 -6.595 -9.634 -4.457 1.00 20.49 C
+ATOM 474 N ALA A 63 -1.414 -6.503 -5.717 1.00 17.49 N
+ATOM 475 CA ALA A 63 -0.464 -5.666 -4.926 1.00 16.16 C
+ATOM 476 C ALA A 63 0.831 -6.452 -4.885 1.00 15.16 C
+ATOM 477 O ALA A 63 0.751 -7.701 -4.848 1.00 16.36 O
+ATOM 478 CB ALA A 63 -1.101 -5.346 -3.590 1.00 18.09 C
+ATOM 479 N HIS A 64 1.949 -5.792 -4.863 1.00 16.14 N
+ATOM 480 CA HIS A 64 3.253 -6.413 -4.962 1.00 20.06 C
+ATOM 481 C HIS A 64 3.664 -7.419 -3.916 1.00 23.55 C
+ATOM 482 O HIS A 64 4.494 -8.331 -4.184 1.00 24.17 O
+ATOM 483 CB HIS A 64 4.405 -5.367 -5.075 1.00 20.46 C
+ATOM 484 CG HIS A 64 4.588 -4.654 -3.779 1.00 23.27 C
+ATOM 485 ND1 HIS A 64 5.742 -4.716 -3.026 1.00 24.96 N
+ATOM 486 CD2 HIS A 64 3.719 -3.870 -3.094 1.00 23.13 C
+ATOM 487 CE1 HIS A 64 5.575 -3.964 -1.930 1.00 25.14 C
+ATOM 488 NE2 HIS A 64 4.351 -3.445 -1.958 1.00 25.42 N
+ATOM 489 N ASP A 65 3.125 -7.235 -2.715 1.00 24.25 N
+ATOM 490 CA ASP A 65 3.540 -8.130 -1.608 1.00 24.83 C
+ATOM 491 C ASP A 65 3.207 -9.575 -1.877 1.00 25.11 C
+ATOM 492 O ASP A 65 3.905 -10.440 -1.284 1.00 26.23 O
+ATOM 493 CB ASP A 65 3.130 -7.447 -0.304 1.00 23.91 C
+ATOM 494 CG ASP A 65 1.652 -7.468 -0.099 1.00 23.84 C
+ATOM 495 OD1 ASP A 65 0.853 -7.152 -0.977 1.00 25.23 O
+ATOM 496 OD2 ASP A 65 1.250 -7.888 1.009 1.00 26.91 O
+ATOM 497 N ARG A 66 2.265 -9.932 -2.723 1.00 25.56 N
+ATOM 498 CA ARG A 66 1.953 -11.344 -2.998 1.00 27.02 C
+ATOM 499 C ARG A 66 2.913 -11.951 -4.048 1.00 26.94 C
+ATOM 500 O ARG A 66 3.133 -13.171 -4.086 1.00 26.97 O
+ATOM 501 CB ARG A 66 0.555 -11.620 -3.505 1.00 29.14 C
+ATOM 502 CG ARG A 66 -0.569 -11.495 -2.539 1.00 36.73 C
+ATOM 503 CD ARG A 66 -0.484 -12.375 -1.337 1.00 42.43 C
+ATOM 504 NE ARG A 66 -1.476 -13.452 -1.456 1.00 48.39 N
+ATOM 505 CZ ARG A 66 -1.110 -14.707 -1.790 1.00 51.09 C
+ATOM 506 NH1 ARG A 66 0.192 -14.995 -1.938 1.00 51.09 N
+ATOM 507 NH2 ARG A 66 -2.058 -15.650 -1.942 1.00 52.57 N
+ATOM 508 N PHE A 67 3.462 -11.078 -4.851 1.00 25.28 N
+ATOM 509 CA PHE A 67 4.379 -11.434 -5.917 1.00 24.49 C
+ATOM 510 C PHE A 67 5.631 -12.140 -5.459 1.00 24.93 C
+ATOM 511 O PHE A 67 6.257 -12.850 -6.299 1.00 26.26 O
+ATOM 512 CB PHE A 67 4.657 -10.202 -6.819 1.00 21.77 C
+ATOM 513 CG PHE A 67 3.585 -9.931 -7.831 1.00 20.19 C
+ATOM 514 CD1 PHE A 67 2.254 -10.284 -7.601 1.00 20.09 C
+ATOM 515 CD2 PHE A 67 3.927 -9.308 -9.042 1.00 20.35 C
+ATOM 516 CE1 PHE A 67 1.244 -10.025 -8.528 1.00 19.24 C
+ATOM 517 CE2 PHE A 67 2.950 -9.065 -9.988 1.00 19.28 C
+ATOM 518 CZ PHE A 67 1.633 -9.414 -9.736 1.00 17.97 C
+ATOM 519 N GLY A 68 6.063 -11.988 -4.235 1.00 24.31 N
+ATOM 520 CA GLY A 68 7.292 -12.649 -3.745 1.00 23.35 C
+ATOM 521 C GLY A 68 6.991 -14.133 -3.530 1.00 24.04 C
+ATOM 522 O GLY A 68 7.887 -14.985 -3.709 1.00 26.43 O
+ATOM 523 N GLY A 69 5.782 -14.460 -3.147 1.00 23.72 N
+ATOM 524 CA GLY A 69 5.381 -15.848 -2.915 1.00 24.41 C
+ATOM 525 C GLY A 69 5.294 -16.600 -4.249 1.00 25.46 C
+ATOM 526 O GLY A 69 5.695 -17.744 -4.389 1.00 24.85 O
+ATOM 527 N TYR A 70 4.730 -15.937 -5.225 1.00 25.41 N
+ATOM 528 CA TYR A 70 4.527 -16.400 -6.598 1.00 24.47 C
+ATOM 529 C TYR A 70 5.869 -16.694 -7.273 1.00 24.42 C
+ATOM 530 O TYR A 70 6.043 -17.735 -7.909 1.00 24.07 O
+ATOM 531 CB TYR A 70 3.824 -15.270 -7.371 1.00 22.66 C
+ATOM 532 CG TYR A 70 2.377 -15.082 -7.008 1.00 21.70 C
+ATOM 533 CD1 TYR A 70 1.670 -15.945 -6.190 1.00 19.73 C
+ATOM 534 CD2 TYR A 70 1.688 -13.972 -7.534 1.00 20.77 C
+ATOM 535 CE1 TYR A 70 0.317 -15.732 -5.914 1.00 18.97 C
+ATOM 536 CE2 TYR A 70 0.334 -13.780 -7.273 1.00 20.30 C
+ATOM 537 CZ TYR A 70 -0.347 -14.656 -6.439 1.00 19.87 C
+ATOM 538 OH TYR A 70 -1.675 -14.453 -6.174 1.00 21.01 O
+ATOM 539 N ALA A 71 6.752 -15.743 -7.112 1.00 24.08 N
+ATOM 540 CA ALA A 71 8.091 -15.784 -7.670 1.00 26.80 C
+ATOM 541 C ALA A 71 8.970 -16.859 -7.040 1.00 28.25 C
+ATOM 542 O ALA A 71 9.970 -17.328 -7.627 1.00 28.05 O
+ATOM 543 CB ALA A 71 8.770 -14.420 -7.476 1.00 25.74 C
+ATOM 544 N GLN A 72 8.632 -17.172 -5.792 1.00 28.58 N
+ATOM 545 CA GLN A 72 9.490 -18.178 -5.094 1.00 29.20 C
+ATOM 546 C GLN A 72 9.233 -19.510 -5.774 1.00 27.48 C
+ATOM 547 O GLN A 72 10.196 -20.278 -5.911 1.00 30.04 O
+ATOM 548 CB GLN A 72 9.373 -18.107 -3.602 1.00 32.03 C
+ATOM 549 CG GLN A 72 8.919 -19.371 -2.881 1.00 34.66 C
+ATOM 550 CD GLN A 72 9.408 -19.298 -1.446 1.00 36.49 C
+ATOM 551 OE1 GLN A 72 10.601 -19.172 -1.206 1.00 37.05 O
+ATOM 552 NE2 GLN A 72 8.443 -19.346 -0.557 1.00 38.76 N
+ATOM 553 N SER A 73 8.021 -19.714 -6.203 1.00 25.05 N
+ATOM 554 CA SER A 73 7.521 -20.868 -6.914 1.00 23.08 C
+ATOM 555 C SER A 73 7.692 -20.794 -8.439 1.00 21.66 C
+ATOM 556 O SER A 73 7.079 -21.621 -9.134 1.00 21.26 O
+ATOM 557 CB SER A 73 6.008 -20.998 -6.635 1.00 24.06 C
+ATOM 558 OG SER A 73 5.882 -21.512 -5.325 1.00 25.82 O
+ATOM 559 N GLY A 74 8.432 -19.849 -8.915 1.00 20.06 N
+ATOM 560 CA GLY A 74 8.721 -19.584 -10.322 1.00 20.88 C
+ATOM 561 C GLY A 74 7.503 -19.463 -11.195 1.00 20.76 C
+ATOM 562 O GLY A 74 7.501 -19.971 -12.328 1.00 21.38 O
+ATOM 563 N LEU A 75 6.478 -18.749 -10.729 1.00 19.30 N
+ATOM 564 CA LEU A 75 5.206 -18.576 -11.428 1.00 17.99 C
+ATOM 565 C LEU A 75 5.140 -17.335 -12.330 1.00 16.41 C
+ATOM 566 O LEU A 75 4.241 -17.230 -13.154 1.00 15.93 O
+ATOM 567 CB LEU A 75 4.095 -18.541 -10.368 1.00 17.43 C
+ATOM 568 CG LEU A 75 3.844 -19.753 -9.510 1.00 16.62 C
+ATOM 569 CD1 LEU A 75 2.631 -19.473 -8.610 1.00 18.19 C
+ATOM 570 CD2 LEU A 75 3.511 -20.950 -10.413 1.00 15.95 C
+ATOM 571 N LEU A 76 6.064 -16.448 -12.130 1.00 16.49 N
+ATOM 572 CA LEU A 76 6.154 -15.194 -12.827 1.00 17.95 C
+ATOM 573 C LEU A 76 7.348 -15.109 -13.758 1.00 19.31 C
+ATOM 574 O LEU A 76 8.489 -15.391 -13.324 1.00 22.10 O
+ATOM 575 CB LEU A 76 6.219 -14.097 -11.724 1.00 16.58 C
+ATOM 576 CG LEU A 76 5.002 -13.847 -10.883 1.00 15.86 C
+ATOM 577 CD1 LEU A 76 5.179 -12.485 -10.168 1.00 17.89 C
+ATOM 578 CD2 LEU A 76 3.700 -13.833 -11.640 1.00 14.46 C
+ATOM 579 N ALA A 77 7.150 -14.642 -14.980 1.00 18.91 N
+ATOM 580 CA ALA A 77 8.312 -14.502 -15.869 1.00 19.49 C
+ATOM 581 C ALA A 77 9.098 -13.269 -15.494 1.00 20.30 C
+ATOM 582 O ALA A 77 8.462 -12.270 -15.134 1.00 22.49 O
+ATOM 583 CB ALA A 77 7.788 -14.321 -17.286 1.00 18.62 C
+ATOM 584 N GLU A 78 10.402 -13.307 -15.637 1.00 22.02 N
+ATOM 585 CA GLU A 78 11.257 -12.149 -15.390 1.00 23.73 C
+ATOM 586 C GLU A 78 11.063 -11.139 -16.523 1.00 23.87 C
+ATOM 587 O GLU A 78 10.875 -11.480 -17.712 1.00 23.80 O
+ATOM 588 CB GLU A 78 12.740 -12.463 -15.288 1.00 26.42 C
+ATOM 589 CG GLU A 78 13.626 -11.278 -14.876 1.00 30.00 C
+ATOM 590 CD GLU A 78 15.067 -11.454 -15.266 1.00 33.24 C
+ATOM 591 OE1 GLU A 78 15.457 -12.555 -15.620 1.00 34.76 O
+ATOM 592 OE2 GLU A 78 15.756 -10.406 -15.189 1.00 35.70 O
+ATOM 593 N ILE A 79 11.083 -9.869 -16.137 1.00 24.11 N
+ATOM 594 CA ILE A 79 10.865 -8.787 -17.114 1.00 22.88 C
+ATOM 595 C ILE A 79 12.165 -8.066 -17.354 1.00 25.18 C
+ATOM 596 O ILE A 79 13.076 -7.947 -16.507 1.00 26.59 O
+ATOM 597 CB ILE A 79 9.615 -7.908 -16.748 1.00 20.12 C
+ATOM 598 CG1 ILE A 79 9.875 -6.950 -15.597 1.00 19.29 C
+ATOM 599 CG2 ILE A 79 8.341 -8.751 -16.489 1.00 18.77 C
+ATOM 600 CD1 ILE A 79 9.271 -5.540 -15.695 1.00 18.57 C
+ATOM 601 N THR A 80 12.257 -7.547 -18.558 1.00 28.91 N
+ATOM 602 CA THR A 80 13.440 -6.802 -19.008 1.00 32.37 C
+ATOM 603 C THR A 80 13.067 -5.522 -19.743 1.00 33.67 C
+ATOM 604 O THR A 80 13.094 -5.514 -21.007 1.00 35.08 O
+ATOM 605 CB THR A 80 14.210 -7.783 -20.007 1.00 33.45 C
+ATOM 606 OG1 THR A 80 13.090 -8.272 -20.853 1.00 32.55 O
+ATOM 607 CG2 THR A 80 14.999 -8.885 -19.327 1.00 34.86 C
+ATOM 608 N PRO A 81 12.705 -4.489 -18.998 1.00 33.48 N
+ATOM 609 CA PRO A 81 12.362 -3.196 -19.622 1.00 31.80 C
+ATOM 610 C PRO A 81 13.724 -2.552 -19.867 1.00 31.28 C
+ATOM 611 O PRO A 81 14.677 -2.973 -19.195 1.00 29.60 O
+ATOM 612 CB PRO A 81 11.529 -2.503 -18.561 1.00 33.14 C
+ATOM 613 CG PRO A 81 12.012 -3.051 -17.239 1.00 31.41 C
+ATOM 614 CD PRO A 81 12.621 -4.406 -17.534 1.00 32.62 C
+ATOM 615 N ASP A 82 13.756 -1.604 -20.762 1.00 32.98 N
+ATOM 616 CA ASP A 82 15.002 -0.871 -21.097 1.00 35.36 C
+ATOM 617 C ASP A 82 15.119 0.341 -20.167 1.00 35.09 C
+ATOM 618 O ASP A 82 14.117 0.858 -19.645 1.00 34.23 O
+ATOM 619 CB ASP A 82 15.009 -0.545 -22.592 1.00 38.86 C
+ATOM 620 CG ASP A 82 14.164 0.655 -22.983 1.00 43.44 C
+ATOM 621 OD1 ASP A 82 12.913 0.622 -23.082 1.00 44.63 O
+ATOM 622 OD2 ASP A 82 14.827 1.723 -23.204 1.00 46.62 O
+ATOM 623 N LYS A 83 16.346 0.797 -19.976 1.00 34.82 N
+ATOM 624 CA LYS A 83 16.630 1.932 -19.110 1.00 36.07 C
+ATOM 625 C LYS A 83 15.675 3.082 -19.377 1.00 37.15 C
+ATOM 626 O LYS A 83 15.277 3.737 -18.402 1.00 39.90 O
+ATOM 627 CB LYS A 83 18.032 2.476 -19.187 1.00 36.07 C
+ATOM 628 CG LYS A 83 18.934 2.274 -17.973 1.00 37.98 C
+ATOM 629 CD LYS A 83 20.032 3.326 -17.962 1.00 41.30 C
+ATOM 630 CE LYS A 83 21.236 3.029 -17.108 1.00 42.29 C
+ATOM 631 NZ LYS A 83 20.970 3.295 -15.661 1.00 43.42 N
+ATOM 632 N ALA A 84 15.334 3.335 -20.613 1.00 37.31 N
+ATOM 633 CA ALA A 84 14.468 4.448 -21.009 1.00 36.98 C
+ATOM 634 C ALA A 84 13.004 4.246 -20.654 1.00 36.19 C
+ATOM 635 O ALA A 84 12.242 5.236 -20.631 1.00 36.85 O
+ATOM 636 CB ALA A 84 14.636 4.753 -22.498 1.00 39.58 C
+ATOM 637 N PHE A 85 12.601 2.995 -20.472 1.00 32.97 N
+ATOM 638 CA PHE A 85 11.219 2.707 -20.058 1.00 29.65 C
+ATOM 639 C PHE A 85 11.284 2.836 -18.510 1.00 30.28 C
+ATOM 640 O PHE A 85 10.423 3.381 -17.835 1.00 30.22 O
+ATOM 641 CB PHE A 85 10.686 1.358 -20.480 1.00 26.87 C
+ATOM 642 CG PHE A 85 9.274 1.160 -20.002 1.00 24.75 C
+ATOM 643 CD1 PHE A 85 8.236 1.897 -20.536 1.00 23.80 C
+ATOM 644 CD2 PHE A 85 9.019 0.291 -18.952 1.00 24.17 C
+ATOM 645 CE1 PHE A 85 6.922 1.747 -20.095 1.00 24.25 C
+ATOM 646 CE2 PHE A 85 7.711 0.131 -18.490 1.00 22.89 C
+ATOM 647 CZ PHE A 85 6.667 0.853 -19.043 1.00 22.79 C
+ATOM 648 N GLN A 86 12.393 2.340 -17.987 1.00 29.63 N
+ATOM 649 CA GLN A 86 12.606 2.389 -16.536 1.00 30.43 C
+ATOM 650 C GLN A 86 12.559 3.825 -16.036 1.00 30.90 C
+ATOM 651 O GLN A 86 11.875 4.060 -15.004 1.00 31.28 O
+ATOM 652 CB GLN A 86 13.825 1.563 -16.130 1.00 32.17 C
+ATOM 653 CG GLN A 86 13.544 0.051 -16.193 1.00 32.86 C
+ATOM 654 CD GLN A 86 14.779 -0.701 -15.775 1.00 35.25 C
+ATOM 655 OE1 GLN A 86 15.509 -1.343 -16.539 1.00 36.66 O
+ATOM 656 NE2 GLN A 86 15.078 -0.568 -14.487 1.00 35.75 N
+ATOM 657 N ASP A 87 13.215 4.768 -16.660 1.00 29.65 N
+ATOM 658 CA ASP A 87 13.231 6.181 -16.315 1.00 29.54 C
+ATOM 659 C ASP A 87 11.849 6.830 -16.452 1.00 28.13 C
+ATOM 660 O ASP A 87 11.725 8.053 -16.175 1.00 29.60 O
+ATOM 661 CB ASP A 87 14.217 7.000 -17.147 1.00 31.73 C
+ATOM 662 CG ASP A 87 15.655 6.812 -16.736 1.00 36.53 C
+ATOM 663 OD1 ASP A 87 16.001 5.779 -16.108 1.00 40.19 O
+ATOM 664 OD2 ASP A 87 16.451 7.727 -17.067 1.00 38.64 O
+ATOM 665 N LYS A 88 10.855 6.089 -16.855 1.00 26.04 N
+ATOM 666 CA LYS A 88 9.514 6.670 -16.981 1.00 25.99 C
+ATOM 667 C LYS A 88 8.633 6.437 -15.753 1.00 25.14 C
+ATOM 668 O LYS A 88 7.481 6.892 -15.729 1.00 25.66 O
+ATOM 669 CB LYS A 88 8.826 6.141 -18.227 1.00 26.55 C
+ATOM 670 CG LYS A 88 9.541 6.628 -19.508 1.00 26.94 C
+ATOM 671 CD LYS A 88 8.499 6.698 -20.619 1.00 29.77 C
+ATOM 672 CE LYS A 88 9.133 6.418 -21.982 1.00 32.30 C
+ATOM 673 NZ LYS A 88 8.133 5.598 -22.750 1.00 35.39 N
+ATOM 674 N LEU A 89 9.126 5.696 -14.804 1.00 24.10 N
+ATOM 675 CA LEU A 89 8.425 5.375 -13.562 1.00 23.30 C
+ATOM 676 C LEU A 89 9.338 5.832 -12.406 1.00 24.35 C
+ATOM 677 O LEU A 89 10.573 6.016 -12.536 1.00 24.40 O
+ATOM 678 CB LEU A 89 8.007 3.955 -13.480 1.00 23.09 C
+ATOM 679 CG LEU A 89 7.618 3.010 -14.553 1.00 24.87 C
+ATOM 680 CD1 LEU A 89 6.901 1.786 -13.933 1.00 25.88 C
+ATOM 681 CD2 LEU A 89 6.724 3.596 -15.631 1.00 25.65 C
+ATOM 682 N TYR A 90 8.644 6.056 -11.282 1.00 23.14 N
+ATOM 683 CA TYR A 90 9.404 6.523 -10.088 1.00 21.93 C
+ATOM 684 C TYR A 90 10.311 5.385 -9.681 1.00 22.11 C
+ATOM 685 O TYR A 90 9.843 4.230 -9.623 1.00 22.79 O
+ATOM 686 CB TYR A 90 8.362 6.905 -9.019 1.00 22.97 C
+ATOM 687 CG TYR A 90 7.582 8.164 -9.289 1.00 19.47 C
+ATOM 688 CD1 TYR A 90 8.148 9.405 -9.055 1.00 21.41 C
+ATOM 689 CD2 TYR A 90 6.286 8.090 -9.791 1.00 20.87 C
+ATOM 690 CE1 TYR A 90 7.429 10.582 -9.307 1.00 23.16 C
+ATOM 691 CE2 TYR A 90 5.541 9.243 -10.039 1.00 21.42 C
+ATOM 692 CZ TYR A 90 6.127 10.475 -9.776 1.00 24.09 C
+ATOM 693 OH TYR A 90 5.428 11.644 -10.005 1.00 28.30 O
+ATOM 694 N PRO A 91 11.561 5.719 -9.402 1.00 22.90 N
+ATOM 695 CA PRO A 91 12.598 4.749 -9.032 1.00 23.58 C
+ATOM 696 C PRO A 91 12.224 3.801 -7.914 1.00 24.13 C
+ATOM 697 O PRO A 91 12.295 2.558 -7.971 1.00 23.70 O
+ATOM 698 CB PRO A 91 13.823 5.596 -8.681 1.00 23.79 C
+ATOM 699 CG PRO A 91 13.622 6.858 -9.471 1.00 22.98 C
+ATOM 700 CD PRO A 91 12.112 7.081 -9.488 1.00 23.37 C
+ATOM 701 N PHE A 92 11.756 4.443 -6.850 1.00 23.00 N
+ATOM 702 CA PHE A 92 11.351 3.697 -5.655 1.00 20.89 C
+ATOM 703 C PHE A 92 10.453 2.545 -6.046 1.00 19.46 C
+ATOM 704 O PHE A 92 10.654 1.478 -5.454 1.00 20.58 O
+ATOM 705 CB PHE A 92 10.817 4.642 -4.589 1.00 20.50 C
+ATOM 706 CG PHE A 92 9.397 5.070 -4.745 1.00 18.61 C
+ATOM 707 CD1 PHE A 92 8.376 4.266 -4.252 1.00 17.64 C
+ATOM 708 CD2 PHE A 92 9.103 6.290 -5.366 1.00 18.71 C
+ATOM 709 CE1 PHE A 92 7.034 4.645 -4.404 1.00 17.42 C
+ATOM 710 CE2 PHE A 92 7.792 6.683 -5.503 1.00 16.77 C
+ATOM 711 CZ PHE A 92 6.764 5.873 -5.032 1.00 18.33 C
+ATOM 712 N THR A 93 9.532 2.700 -6.958 1.00 18.89 N
+ATOM 713 CA THR A 93 8.599 1.678 -7.395 1.00 18.73 C
+ATOM 714 C THR A 93 9.188 0.438 -8.058 1.00 19.94 C
+ATOM 715 O THR A 93 8.497 -0.610 -8.081 1.00 19.13 O
+ATOM 716 CB THR A 93 7.407 2.239 -8.270 1.00 19.48 C
+ATOM 717 OG1 THR A 93 7.940 2.569 -9.596 1.00 18.20 O
+ATOM 718 CG2 THR A 93 6.733 3.445 -7.593 1.00 18.59 C
+ATOM 719 N TRP A 94 10.413 0.530 -8.541 1.00 20.91 N
+ATOM 720 CA TRP A 94 11.053 -0.659 -9.168 1.00 22.42 C
+ATOM 721 C TRP A 94 11.516 -1.619 -8.077 1.00 22.91 C
+ATOM 722 O TRP A 94 11.463 -2.851 -8.268 1.00 24.73 O
+ATOM 723 CB TRP A 94 12.125 -0.277 -10.156 1.00 20.95 C
+ATOM 724 CG TRP A 94 11.659 0.299 -11.444 1.00 20.26 C
+ATOM 725 CD1 TRP A 94 11.838 1.575 -11.909 1.00 19.80 C
+ATOM 726 CD2 TRP A 94 10.943 -0.400 -12.475 1.00 19.93 C
+ATOM 727 NE1 TRP A 94 11.276 1.725 -13.153 1.00 17.79 N
+ATOM 728 CE2 TRP A 94 10.720 0.542 -13.537 1.00 18.57 C
+ATOM 729 CE3 TRP A 94 10.479 -1.708 -12.590 1.00 19.37 C
+ATOM 730 CZ2 TRP A 94 10.059 0.206 -14.709 1.00 17.01 C
+ATOM 731 CZ3 TRP A 94 9.808 -2.039 -13.765 1.00 18.74 C
+ATOM 732 CH2 TRP A 94 9.613 -1.101 -14.803 1.00 18.81 C
+ATOM 733 N ASP A 95 11.950 -1.085 -6.950 1.00 23.10 N
+ATOM 734 CA ASP A 95 12.361 -1.910 -5.812 1.00 24.33 C
+ATOM 735 C ASP A 95 11.193 -2.709 -5.217 1.00 23.32 C
+ATOM 736 O ASP A 95 11.441 -3.626 -4.406 1.00 24.82 O
+ATOM 737 CB ASP A 95 13.006 -1.072 -4.718 1.00 26.47 C
+ATOM 738 CG ASP A 95 14.271 -0.455 -5.245 1.00 29.31 C
+ATOM 739 OD1 ASP A 95 14.136 0.134 -6.332 1.00 34.05 O
+ATOM 740 OD2 ASP A 95 15.334 -0.581 -4.635 1.00 34.77 O
+ATOM 741 N ALA A 96 9.980 -2.379 -5.589 1.00 21.11 N
+ATOM 742 CA ALA A 96 8.814 -3.068 -5.063 1.00 20.70 C
+ATOM 743 C ALA A 96 8.612 -4.402 -5.778 1.00 20.74 C
+ATOM 744 O ALA A 96 7.937 -5.294 -5.275 1.00 19.54 O
+ATOM 745 CB ALA A 96 7.559 -2.190 -5.247 1.00 19.12 C
+ATOM 746 N VAL A 97 9.172 -4.421 -6.988 1.00 22.21 N
+ATOM 747 CA VAL A 97 9.002 -5.560 -7.898 1.00 22.85 C
+ATOM 748 C VAL A 97 10.243 -6.376 -8.191 1.00 23.70 C
+ATOM 749 O VAL A 97 10.202 -7.209 -9.113 1.00 25.28 O
+ATOM 750 CB VAL A 97 8.231 -5.063 -9.141 1.00 21.85 C
+ATOM 751 CG1 VAL A 97 6.738 -4.926 -8.945 1.00 19.89 C
+ATOM 752 CG2 VAL A 97 8.829 -3.762 -9.647 1.00 21.42 C
+ATOM 753 N ARG A 98 11.310 -6.224 -7.492 1.00 24.06 N
+ATOM 754 CA ARG A 98 12.514 -7.025 -7.583 1.00 27.50 C
+ATOM 755 C ARG A 98 12.407 -8.182 -6.546 1.00 30.53 C
+ATOM 756 O ARG A 98 12.241 -7.922 -5.335 1.00 31.60 O
+ATOM 757 CB ARG A 98 13.763 -6.270 -7.187 1.00 26.76 C
+ATOM 758 CG ARG A 98 14.325 -5.325 -8.210 1.00 31.16 C
+ATOM 759 CD ARG A 98 15.712 -4.953 -7.769 1.00 35.75 C
+ATOM 760 NE ARG A 98 15.817 -3.500 -7.678 1.00 40.08 N
+ATOM 761 CZ ARG A 98 15.928 -2.730 -8.760 1.00 42.86 C
+ATOM 762 NH1 ARG A 98 16.005 -3.344 -9.948 1.00 43.60 N
+ATOM 763 NH2 ARG A 98 15.999 -1.402 -8.665 1.00 44.59 N
+ATOM 764 N TYR A 99 12.515 -9.403 -7.006 1.00 32.32 N
+ATOM 765 CA TYR A 99 12.499 -10.590 -6.154 1.00 34.20 C
+ATOM 766 C TYR A 99 13.848 -11.297 -6.341 1.00 35.79 C
+ATOM 767 O TYR A 99 14.251 -11.581 -7.496 1.00 35.64 O
+ATOM 768 CB TYR A 99 11.351 -11.584 -6.428 1.00 33.71 C
+ATOM 769 CG TYR A 99 11.426 -12.695 -5.382 1.00 36.62 C
+ATOM 770 CD1 TYR A 99 12.191 -13.832 -5.574 1.00 36.77 C
+ATOM 771 CD2 TYR A 99 10.747 -12.553 -4.166 1.00 37.02 C
+ATOM 772 CE1 TYR A 99 12.277 -14.822 -4.605 1.00 38.52 C
+ATOM 773 CE2 TYR A 99 10.829 -13.519 -3.175 1.00 38.22 C
+ATOM 774 CZ TYR A 99 11.601 -14.659 -3.401 1.00 38.53 C
+ATOM 775 OH TYR A 99 11.696 -15.634 -2.455 1.00 38.83 O
+ATOM 776 N ASN A 100 14.547 -11.545 -5.252 1.00 38.02 N
+ATOM 777 CA ASN A 100 15.849 -12.268 -5.433 1.00 40.78 C
+ATOM 778 C ASN A 100 16.724 -11.518 -6.436 1.00 41.15 C
+ATOM 779 O ASN A 100 17.458 -12.148 -7.228 1.00 40.95 O
+ATOM 780 CB ASN A 100 15.532 -13.666 -5.964 1.00 43.69 C
+ATOM 781 CG ASN A 100 16.117 -14.838 -5.234 1.00 46.03 C
+ATOM 782 OD1 ASN A 100 17.321 -14.929 -4.955 1.00 47.42 O
+ATOM 783 ND2 ASN A 100 15.228 -15.808 -4.915 1.00 48.07 N
+ATOM 784 N GLY A 101 16.614 -10.208 -6.433 1.00 42.11 N
+ATOM 785 CA GLY A 101 17.398 -9.344 -7.330 1.00 40.92 C
+ATOM 786 C GLY A 101 16.957 -9.345 -8.779 1.00 40.14 C
+ATOM 787 O GLY A 101 17.729 -8.870 -9.640 1.00 41.23 O
+ATOM 788 N LYS A 102 15.763 -9.837 -9.052 1.00 38.60 N
+ATOM 789 CA LYS A 102 15.190 -9.909 -10.393 1.00 35.41 C
+ATOM 790 C LYS A 102 13.837 -9.216 -10.501 1.00 32.29 C
+ATOM 791 O LYS A 102 12.977 -9.380 -9.619 1.00 33.52 O
+ATOM 792 CB LYS A 102 14.964 -11.371 -10.792 1.00 37.66 C
+ATOM 793 CG LYS A 102 16.256 -12.134 -11.074 1.00 40.87 C
+ATOM 794 CD LYS A 102 16.137 -12.922 -12.374 1.00 43.18 C
+ATOM 795 CE LYS A 102 15.009 -13.939 -12.397 1.00 44.19 C
+ATOM 796 NZ LYS A 102 14.820 -14.410 -13.821 1.00 44.67 N
+ATOM 797 N LEU A 103 13.647 -8.533 -11.616 1.00 27.93 N
+ATOM 798 CA LEU A 103 12.408 -7.805 -11.950 1.00 21.55 C
+ATOM 799 C LEU A 103 11.336 -8.802 -12.319 1.00 19.55 C
+ATOM 800 O LEU A 103 11.517 -9.488 -13.340 1.00 20.11 O
+ATOM 801 CB LEU A 103 12.730 -6.796 -13.048 1.00 22.44 C
+ATOM 802 CG LEU A 103 12.917 -5.365 -12.583 1.00 22.55 C
+ATOM 803 CD1 LEU A 103 14.050 -4.671 -13.280 1.00 24.36 C
+ATOM 804 CD2 LEU A 103 11.609 -4.657 -12.886 1.00 24.23 C
+ATOM 805 N ILE A 104 10.269 -8.827 -11.525 1.00 14.59 N
+ATOM 806 CA ILE A 104 9.201 -9.766 -11.774 1.00 13.29 C
+ATOM 807 C ILE A 104 7.859 -9.193 -12.133 1.00 9.37 C
+ATOM 808 O ILE A 104 6.901 -9.990 -12.296 1.00 8.10 O
+ATOM 809 CB ILE A 104 9.006 -10.835 -10.603 1.00 16.89 C
+ATOM 810 CG1 ILE A 104 9.040 -10.112 -9.243 1.00 16.19 C
+ATOM 811 CG2 ILE A 104 9.939 -12.059 -10.739 1.00 19.84 C
+ATOM 812 CD1 ILE A 104 7.624 -9.665 -8.790 1.00 17.31 C
+ATOM 813 N ALA A 105 7.755 -7.891 -12.254 1.00 9.70 N
+ATOM 814 CA ALA A 105 6.424 -7.325 -12.604 1.00 10.46 C
+ATOM 815 C ALA A 105 6.559 -5.840 -12.869 1.00 10.26 C
+ATOM 816 O ALA A 105 7.610 -5.238 -12.597 1.00 10.12 O
+ATOM 817 CB ALA A 105 5.482 -7.599 -11.427 1.00 12.35 C
+ATOM 818 N TYR A 106 5.484 -5.313 -13.397 1.00 10.96 N
+ATOM 819 CA TYR A 106 5.498 -3.871 -13.692 1.00 13.88 C
+ATOM 820 C TYR A 106 4.666 -3.141 -12.626 1.00 13.61 C
+ATOM 821 O TYR A 106 3.497 -3.526 -12.486 1.00 16.43 O
+ATOM 822 CB TYR A 106 4.804 -3.552 -15.061 1.00 13.58 C
+ATOM 823 CG TYR A 106 5.631 -3.940 -16.270 1.00 17.26 C
+ATOM 824 CD1 TYR A 106 6.664 -3.154 -16.752 1.00 17.30 C
+ATOM 825 CD2 TYR A 106 5.324 -5.165 -16.893 1.00 19.01 C
+ATOM 826 CE1 TYR A 106 7.419 -3.532 -17.882 1.00 18.61 C
+ATOM 827 CE2 TYR A 106 6.062 -5.553 -18.013 1.00 21.03 C
+ATOM 828 CZ TYR A 106 7.091 -4.742 -18.492 1.00 20.69 C
+ATOM 829 OH TYR A 106 7.801 -5.167 -19.591 1.00 20.32 O
+ATOM 830 N PRO A 107 5.236 -2.101 -12.112 1.00 15.82 N
+ATOM 831 CA PRO A 107 4.534 -1.248 -11.124 1.00 15.50 C
+ATOM 832 C PRO A 107 3.439 -0.410 -11.763 1.00 16.38 C
+ATOM 833 O PRO A 107 3.862 0.364 -12.672 1.00 18.24 O
+ATOM 834 CB PRO A 107 5.648 -0.336 -10.620 1.00 16.09 C
+ATOM 835 CG PRO A 107 6.950 -0.699 -11.248 1.00 14.66 C
+ATOM 836 CD PRO A 107 6.628 -1.658 -12.349 1.00 16.04 C
+ATOM 837 N ILE A 108 2.200 -0.419 -11.378 1.00 14.55 N
+ATOM 838 CA ILE A 108 1.084 0.362 -11.856 1.00 14.36 C
+ATOM 839 C ILE A 108 0.733 1.606 -11.003 1.00 14.83 C
+ATOM 840 O ILE A 108 1.111 2.738 -11.292 1.00 13.37 O
+ATOM 841 CB ILE A 108 -0.197 -0.524 -12.035 1.00 13.06 C
+ATOM 842 CG1 ILE A 108 0.217 -1.874 -12.701 1.00 15.77 C
+ATOM 843 CG2 ILE A 108 -1.269 0.228 -12.843 1.00 13.12 C
+ATOM 844 CD1 ILE A 108 1.079 -1.726 -13.965 1.00 12.96 C
+ATOM 845 N ALA A 109 0.052 1.323 -9.909 1.00 15.46 N
+ATOM 846 CA ALA A 109 -0.417 2.266 -8.889 1.00 16.24 C
+ATOM 847 C ALA A 109 0.346 2.138 -7.576 1.00 17.18 C
+ATOM 848 O ALA A 109 0.989 1.121 -7.274 1.00 17.21 O
+ATOM 849 CB ALA A 109 -1.919 2.057 -8.745 1.00 14.90 C
+ATOM 850 N VAL A 110 0.349 3.223 -6.788 1.00 17.04 N
+ATOM 851 CA VAL A 110 1.080 3.272 -5.491 1.00 16.18 C
+ATOM 852 C VAL A 110 0.113 3.684 -4.376 1.00 16.74 C
+ATOM 853 O VAL A 110 -0.615 4.684 -4.570 1.00 17.54 O
+ATOM 854 CB VAL A 110 2.245 4.244 -5.669 1.00 16.97 C
+ATOM 855 CG1 VAL A 110 2.969 4.622 -4.372 1.00 17.78 C
+ATOM 856 CG2 VAL A 110 3.264 3.773 -6.699 1.00 15.93 C
+ATOM 857 N GLU A 111 0.071 2.971 -3.267 1.00 15.23 N
+ATOM 858 CA GLU A 111 -0.827 3.301 -2.129 1.00 13.90 C
+ATOM 859 C GLU A 111 -0.029 3.438 -0.851 1.00 12.43 C
+ATOM 860 O GLU A 111 1.010 2.836 -0.639 1.00 13.10 O
+ATOM 861 CB GLU A 111 -1.870 2.247 -1.864 1.00 15.10 C
+ATOM 862 CG GLU A 111 -3.137 2.405 -2.690 1.00 18.74 C
+ATOM 863 CD GLU A 111 -4.159 1.348 -2.407 1.00 23.37 C
+ATOM 864 OE1 GLU A 111 -3.880 0.312 -1.830 1.00 23.84 O
+ATOM 865 OE2 GLU A 111 -5.289 1.706 -2.864 1.00 26.27 O
+ATOM 866 N ALA A 112 -0.505 4.341 -0.007 1.00 13.27 N
+ATOM 867 CA ALA A 112 0.157 4.601 1.296 1.00 9.67 C
+ATOM 868 C ALA A 112 -0.882 5.316 2.160 1.00 11.21 C
+ATOM 869 O ALA A 112 -1.876 5.859 1.619 1.00 10.92 O
+ATOM 870 CB ALA A 112 1.440 5.320 1.038 1.00 7.45 C
+ATOM 871 N LEU A 113 -0.733 5.223 3.484 1.00 10.86 N
+ATOM 872 CA LEU A 113 -1.727 5.884 4.376 1.00 10.43 C
+ATOM 873 C LEU A 113 -1.441 7.395 4.370 1.00 7.86 C
+ATOM 874 O LEU A 113 -0.288 7.771 4.226 1.00 8.76 O
+ATOM 875 CB LEU A 113 -1.528 5.369 5.797 1.00 7.90 C
+ATOM 876 CG LEU A 113 -2.042 4.041 6.247 1.00 8.00 C
+ATOM 877 CD1 LEU A 113 -1.682 3.792 7.724 1.00 7.14 C
+ATOM 878 CD2 LEU A 113 -3.529 3.898 6.035 1.00 6.51 C
+ATOM 879 N SER A 114 -2.524 8.103 4.695 1.00 9.35 N
+ATOM 880 CA SER A 114 -2.372 9.570 4.813 1.00 9.18 C
+ATOM 881 C SER A 114 -3.123 10.080 6.069 1.00 9.35 C
+ATOM 882 O SER A 114 -4.035 9.359 6.458 1.00 9.63 O
+ATOM 883 CB SER A 114 -3.100 10.209 3.598 1.00 11.35 C
+ATOM 884 OG SER A 114 -2.093 10.345 2.561 1.00 12.36 O
+ATOM 885 N LEU A 115 -2.782 11.287 6.440 1.00 10.21 N
+ATOM 886 CA LEU A 115 -3.528 11.974 7.545 1.00 12.11 C
+ATOM 887 C LEU A 115 -4.763 12.662 7.010 1.00 11.65 C
+ATOM 888 O LEU A 115 -4.627 13.711 6.359 1.00 14.84 O
+ATOM 889 CB LEU A 115 -2.493 12.938 8.134 1.00 13.66 C
+ATOM 890 CG LEU A 115 -2.871 13.686 9.443 1.00 17.28 C
+ATOM 891 CD1 LEU A 115 -3.385 15.073 9.082 1.00 18.64 C
+ATOM 892 CD2 LEU A 115 -3.915 12.887 10.212 1.00 15.66 C
+ATOM 893 N ILE A 116 -5.966 12.259 7.186 1.00 11.16 N
+ATOM 894 CA ILE A 116 -7.213 12.821 6.725 1.00 13.58 C
+ATOM 895 C ILE A 116 -7.809 13.738 7.798 1.00 17.80 C
+ATOM 896 O ILE A 116 -7.941 13.242 8.928 1.00 18.92 O
+ATOM 897 CB ILE A 116 -8.209 11.658 6.371 1.00 13.38 C
+ATOM 898 CG1 ILE A 116 -7.554 10.711 5.289 1.00 11.12 C
+ATOM 899 CG2 ILE A 116 -9.602 12.170 5.930 1.00 15.23 C
+ATOM 900 CD1 ILE A 116 -8.454 9.493 4.978 1.00 10.29 C
+ATOM 901 N TYR A 117 -8.194 14.958 7.565 1.00 18.38 N
+ATOM 902 CA TYR A 117 -8.731 15.769 8.691 1.00 18.96 C
+ATOM 903 C TYR A 117 -10.000 16.469 8.287 1.00 20.94 C
+ATOM 904 O TYR A 117 -10.365 16.638 7.121 1.00 19.10 O
+ATOM 905 CB TYR A 117 -7.638 16.674 9.267 1.00 20.43 C
+ATOM 906 CG TYR A 117 -7.218 17.767 8.327 1.00 24.47 C
+ATOM 907 CD1 TYR A 117 -6.185 17.511 7.398 1.00 25.33 C
+ATOM 908 CD2 TYR A 117 -7.848 19.001 8.298 1.00 25.00 C
+ATOM 909 CE1 TYR A 117 -5.811 18.470 6.468 1.00 25.16 C
+ATOM 910 CE2 TYR A 117 -7.472 19.981 7.381 1.00 26.64 C
+ATOM 911 CZ TYR A 117 -6.465 19.691 6.467 1.00 27.15 C
+ATOM 912 OH TYR A 117 -6.069 20.610 5.535 1.00 30.28 O
+ATOM 913 N ASN A 118 -10.730 16.869 9.330 1.00 21.94 N
+ATOM 914 CA ASN A 118 -12.002 17.567 9.215 1.00 22.38 C
+ATOM 915 C ASN A 118 -11.640 19.056 9.257 1.00 23.73 C
+ATOM 916 O ASN A 118 -11.237 19.529 10.299 1.00 22.85 O
+ATOM 917 CB ASN A 118 -12.962 17.174 10.337 1.00 24.14 C
+ATOM 918 CG ASN A 118 -14.312 17.816 10.032 1.00 24.36 C
+ATOM 919 OD1 ASN A 118 -14.295 18.907 9.425 1.00 26.67 O
+ATOM 920 ND2 ASN A 118 -15.391 17.154 10.413 1.00 23.48 N
+ATOM 921 N LYS A 119 -11.779 19.641 8.091 1.00 24.83 N
+ATOM 922 CA LYS A 119 -11.443 21.011 7.766 1.00 25.74 C
+ATOM 923 C LYS A 119 -12.197 22.034 8.617 1.00 27.40 C
+ATOM 924 O LYS A 119 -11.632 23.129 8.860 1.00 27.05 O
+ATOM 925 CB LYS A 119 -11.725 21.311 6.291 1.00 26.47 C
+ATOM 926 CG LYS A 119 -10.576 22.007 5.581 1.00 27.90 C
+ATOM 927 CD LYS A 119 -9.837 21.046 4.659 1.00 27.86 C
+ATOM 928 CE LYS A 119 -10.656 20.756 3.410 1.00 27.23 C
+ATOM 929 NZ LYS A 119 -10.138 21.635 2.316 1.00 30.67 N
+ATOM 930 N ASP A 120 -13.389 21.619 8.979 1.00 27.43 N
+ATOM 931 CA ASP A 120 -14.349 22.353 9.793 1.00 28.90 C
+ATOM 932 C ASP A 120 -13.902 22.451 11.248 1.00 28.76 C
+ATOM 933 O ASP A 120 -13.836 23.564 11.792 1.00 30.60 O
+ATOM 934 CB ASP A 120 -15.766 21.769 9.648 1.00 28.73 C
+ATOM 935 CG ASP A 120 -16.385 21.997 8.279 1.00 28.91 C
+ATOM 936 OD1 ASP A 120 -15.840 22.885 7.575 1.00 30.87 O
+ATOM 937 OD2 ASP A 120 -17.371 21.353 7.877 1.00 28.55 O
+ATOM 938 N LEU A 121 -13.601 21.351 11.875 1.00 28.70 N
+ATOM 939 CA LEU A 121 -13.143 21.248 13.258 1.00 27.28 C
+ATOM 940 C LEU A 121 -11.685 21.647 13.421 1.00 27.14 C
+ATOM 941 O LEU A 121 -11.265 22.108 14.497 1.00 26.46 O
+ATOM 942 CB LEU A 121 -13.297 19.767 13.632 1.00 26.60 C
+ATOM 943 CG LEU A 121 -14.611 19.280 14.156 1.00 28.65 C
+ATOM 944 CD1 LEU A 121 -15.787 19.892 13.409 1.00 31.15 C
+ATOM 945 CD2 LEU A 121 -14.651 17.751 14.020 1.00 28.79 C
+ATOM 946 N LEU A 122 -10.934 21.398 12.355 1.00 27.35 N
+ATOM 947 CA LEU A 122 -9.485 21.627 12.388 1.00 29.05 C
+ATOM 948 C LEU A 122 -9.002 22.252 11.108 1.00 32.97 C
+ATOM 949 O LEU A 122 -8.551 21.584 10.165 1.00 34.02 O
+ATOM 950 CB LEU A 122 -8.882 20.256 12.714 1.00 28.74 C
+ATOM 951 CG LEU A 122 -7.433 20.098 13.098 1.00 29.25 C
+ATOM 952 CD1 LEU A 122 -7.024 20.926 14.311 1.00 28.67 C
+ATOM 953 CD2 LEU A 122 -7.215 18.606 13.392 1.00 30.29 C
+ATOM 954 N PRO A 123 -9.076 23.573 11.112 1.00 36.21 N
+ATOM 955 CA PRO A 123 -8.674 24.403 9.974 1.00 38.13 C
+ATOM 956 C PRO A 123 -7.227 24.207 9.544 1.00 38.37 C
+ATOM 957 O PRO A 123 -6.821 24.598 8.435 1.00 38.43 O
+ATOM 958 CB PRO A 123 -8.917 25.845 10.479 1.00 38.44 C
+ATOM 959 CG PRO A 123 -10.037 25.662 11.491 1.00 38.67 C
+ATOM 960 CD PRO A 123 -9.626 24.390 12.228 1.00 37.05 C
+ATOM 961 N ASN A 124 -6.430 23.648 10.431 1.00 38.41 N
+ATOM 962 CA ASN A 124 -5.006 23.399 10.126 1.00 38.47 C
+ATOM 963 C ASN A 124 -4.596 22.117 10.843 1.00 36.54 C
+ATOM 964 O ASN A 124 -4.812 22.019 12.057 1.00 38.01 O
+ATOM 965 CB ASN A 124 -4.153 24.629 10.433 1.00 40.43 C
+ATOM 966 CG ASN A 124 -3.766 25.269 9.100 1.00 43.04 C
+ATOM 967 OD1 ASN A 124 -2.578 25.284 8.724 1.00 45.47 O
+ATOM 968 ND2 ASN A 124 -4.815 25.708 8.409 1.00 43.10 N
+ATOM 969 N PRO A 125 -4.052 21.198 10.081 1.00 34.09 N
+ATOM 970 CA PRO A 125 -3.638 19.917 10.636 1.00 31.09 C
+ATOM 971 C PRO A 125 -2.317 20.090 11.366 1.00 28.26 C
+ATOM 972 O PRO A 125 -1.487 20.903 10.949 1.00 27.27 O
+ATOM 973 CB PRO A 125 -3.475 19.026 9.387 1.00 31.26 C
+ATOM 974 CG PRO A 125 -2.800 20.038 8.460 1.00 33.10 C
+ATOM 975 CD PRO A 125 -3.749 21.263 8.637 1.00 33.98 C
+ATOM 976 N PRO A 126 -2.188 19.242 12.383 1.00 26.76 N
+ATOM 977 CA PRO A 126 -0.979 19.174 13.194 1.00 25.96 C
+ATOM 978 C PRO A 126 0.208 18.669 12.371 1.00 26.11 C
+ATOM 979 O PRO A 126 0.069 17.675 11.628 1.00 26.21 O
+ATOM 980 CB PRO A 126 -1.305 18.141 14.262 1.00 26.12 C
+ATOM 981 CG PRO A 126 -2.644 17.561 13.958 1.00 26.93 C
+ATOM 982 CD PRO A 126 -3.237 18.273 12.779 1.00 25.37 C
+ATOM 983 N LYS A 127 1.364 19.257 12.554 1.00 25.52 N
+ATOM 984 CA LYS A 127 2.525 18.794 11.778 1.00 26.87 C
+ATOM 985 C LYS A 127 3.426 17.870 12.550 1.00 25.93 C
+ATOM 986 O LYS A 127 4.371 17.242 12.060 1.00 23.87 O
+ATOM 987 CB LYS A 127 3.166 19.980 11.091 1.00 30.43 C
+ATOM 988 CG LYS A 127 2.730 20.210 9.615 1.00 34.98 C
+ATOM 989 CD LYS A 127 1.531 19.393 9.163 1.00 38.69 C
+ATOM 990 CE LYS A 127 1.783 17.945 8.761 1.00 38.72 C
+ATOM 991 NZ LYS A 127 0.501 17.183 8.632 1.00 37.10 N
+ATOM 992 N THR A 128 3.037 17.687 13.787 1.00 25.54 N
+ATOM 993 CA THR A 128 3.697 16.918 14.841 1.00 23.57 C
+ATOM 994 C THR A 128 2.812 15.936 15.551 1.00 21.95 C
+ATOM 995 O THR A 128 1.582 16.182 15.740 1.00 22.10 O
+ATOM 996 CB THR A 128 4.227 18.029 15.871 1.00 24.38 C
+ATOM 997 OG1 THR A 128 5.166 18.789 15.013 1.00 28.30 O
+ATOM 998 CG2 THR A 128 4.833 17.575 17.148 1.00 24.95 C
+ATOM 999 N TRP A 129 3.409 14.777 15.890 1.00 19.82 N
+ATOM 1000 CA TRP A 129 2.597 13.772 16.622 1.00 19.28 C
+ATOM 1001 C TRP A 129 2.519 14.253 18.109 1.00 16.70 C
+ATOM 1002 O TRP A 129 1.541 14.017 18.778 1.00 17.19 O
+ATOM 1003 CB TRP A 129 3.155 12.378 16.615 1.00 17.83 C
+ATOM 1004 CG TRP A 129 2.785 11.421 15.574 1.00 16.69 C
+ATOM 1005 CD1 TRP A 129 3.558 11.090 14.475 1.00 15.99 C
+ATOM 1006 CD2 TRP A 129 1.586 10.642 15.472 1.00 16.90 C
+ATOM 1007 NE1 TRP A 129 2.895 10.161 13.706 1.00 14.76 N
+ATOM 1008 CE2 TRP A 129 1.692 9.856 14.298 1.00 14.25 C
+ATOM 1009 CE3 TRP A 129 0.436 10.547 16.226 1.00 16.89 C
+ATOM 1010 CZ2 TRP A 129 0.695 9.001 13.892 1.00 14.92 C
+ATOM 1011 CZ3 TRP A 129 -0.562 9.668 15.836 1.00 17.64 C
+ATOM 1012 CH2 TRP A 129 -0.421 8.896 14.684 1.00 16.03 C
+ATOM 1013 N GLU A 130 3.608 14.814 18.531 1.00 17.86 N
+ATOM 1014 CA GLU A 130 3.826 15.288 19.891 1.00 21.41 C
+ATOM 1015 C GLU A 130 2.789 16.314 20.339 1.00 22.80 C
+ATOM 1016 O GLU A 130 2.482 16.406 21.525 1.00 23.19 O
+ATOM 1017 CB GLU A 130 5.187 15.971 20.068 1.00 19.44 C
+ATOM 1018 CG GLU A 130 6.387 15.060 20.019 1.00 20.85 C
+ATOM 1019 CD GLU A 130 6.973 14.685 18.689 1.00 21.25 C
+ATOM 1020 OE1 GLU A 130 6.183 14.647 17.749 1.00 20.41 O
+ATOM 1021 OE2 GLU A 130 8.171 14.438 18.584 1.00 22.98 O
+ATOM 1022 N GLU A 131 2.301 17.053 19.365 1.00 22.74 N
+ATOM 1023 CA GLU A 131 1.332 18.120 19.587 1.00 22.02 C
+ATOM 1024 C GLU A 131 -0.089 17.670 19.511 1.00 21.13 C
+ATOM 1025 O GLU A 131 -1.005 18.515 19.576 1.00 22.06 O
+ATOM 1026 CB GLU A 131 1.646 19.237 18.608 1.00 23.49 C
+ATOM 1027 CG GLU A 131 0.945 19.382 17.275 1.00 25.79 C
+ATOM 1028 CD GLU A 131 1.501 20.480 16.396 1.00 26.68 C
+ATOM 1029 OE1 GLU A 131 2.641 20.505 15.984 1.00 30.03 O
+ATOM 1030 OE2 GLU A 131 0.697 21.385 16.143 1.00 26.50 O
+ATOM 1031 N ILE A 132 -0.339 16.364 19.413 1.00 20.47 N
+ATOM 1032 CA ILE A 132 -1.725 15.886 19.329 1.00 19.81 C
+ATOM 1033 C ILE A 132 -2.399 15.753 20.679 1.00 20.35 C
+ATOM 1034 O ILE A 132 -3.627 15.962 20.809 1.00 21.53 O
+ATOM 1035 CB ILE A 132 -1.828 14.610 18.430 1.00 20.56 C
+ATOM 1036 CG1 ILE A 132 -1.345 15.013 16.999 1.00 20.60 C
+ATOM 1037 CG2 ILE A 132 -3.226 13.944 18.442 1.00 17.40 C
+ATOM 1038 CD1 ILE A 132 -1.592 13.875 15.976 1.00 23.02 C
+ATOM 1039 N PRO A 133 -1.666 15.374 21.686 1.00 20.77 N
+ATOM 1040 CA PRO A 133 -2.248 15.220 23.042 1.00 21.51 C
+ATOM 1041 C PRO A 133 -2.878 16.518 23.481 1.00 21.59 C
+ATOM 1042 O PRO A 133 -4.014 16.467 23.983 1.00 24.12 O
+ATOM 1043 CB PRO A 133 -1.103 14.664 23.857 1.00 22.31 C
+ATOM 1044 CG PRO A 133 -0.219 13.981 22.834 1.00 22.73 C
+ATOM 1045 CD PRO A 133 -0.234 15.028 21.691 1.00 21.66 C
+ATOM 1046 N ALA A 134 -2.278 17.656 23.251 1.00 21.20 N
+ATOM 1047 CA ALA A 134 -2.811 18.973 23.594 1.00 22.48 C
+ATOM 1048 C ALA A 134 -4.077 19.317 22.834 1.00 23.50 C
+ATOM 1049 O ALA A 134 -5.068 19.864 23.345 1.00 23.53 O
+ATOM 1050 CB ALA A 134 -1.781 20.080 23.344 1.00 22.17 C
+ATOM 1051 N LEU A 135 -4.039 19.010 21.544 1.00 23.50 N
+ATOM 1052 CA LEU A 135 -5.138 19.244 20.618 1.00 21.93 C
+ATOM 1053 C LEU A 135 -6.395 18.511 21.035 1.00 20.30 C
+ATOM 1054 O LEU A 135 -7.515 18.905 20.719 1.00 19.41 O
+ATOM 1055 CB LEU A 135 -4.676 18.629 19.253 1.00 24.42 C
+ATOM 1056 CG LEU A 135 -5.176 19.389 18.047 1.00 26.69 C
+ATOM 1057 CD1 LEU A 135 -3.972 20.037 17.362 1.00 30.45 C
+ATOM 1058 CD2 LEU A 135 -5.871 18.426 17.090 1.00 28.71 C
+ATOM 1059 N ASP A 136 -6.108 17.358 21.629 1.00 19.83 N
+ATOM 1060 CA ASP A 136 -7.212 16.468 22.064 1.00 20.99 C
+ATOM 1061 C ASP A 136 -7.941 17.127 23.251 1.00 21.85 C
+ATOM 1062 O ASP A 136 -9.174 17.115 23.234 1.00 19.85 O
+ATOM 1063 CB ASP A 136 -6.721 15.055 22.322 1.00 18.85 C
+ATOM 1064 CG ASP A 136 -7.839 14.080 22.586 1.00 19.75 C
+ATOM 1065 OD1 ASP A 136 -8.801 13.943 21.812 1.00 21.52 O
+ATOM 1066 OD2 ASP A 136 -7.774 13.423 23.649 1.00 20.39 O
+ATOM 1067 N LYS A 137 -7.121 17.646 24.176 1.00 24.56 N
+ATOM 1068 CA LYS A 137 -7.745 18.277 25.380 1.00 27.04 C
+ATOM 1069 C LYS A 137 -8.433 19.559 24.921 1.00 27.83 C
+ATOM 1070 O LYS A 137 -9.581 19.866 25.306 1.00 27.90 O
+ATOM 1071 CB LYS A 137 -6.878 18.435 26.566 1.00 28.05 C
+ATOM 1072 CG LYS A 137 -5.416 18.704 26.445 1.00 31.35 C
+ATOM 1073 CD LYS A 137 -4.963 20.051 26.930 1.00 35.42 C
+ATOM 1074 CE LYS A 137 -5.460 21.221 26.068 1.00 37.42 C
+ATOM 1075 NZ LYS A 137 -4.587 22.401 26.357 1.00 38.18 N
+ATOM 1076 N GLU A 138 -7.750 20.228 24.010 1.00 28.31 N
+ATOM 1077 CA GLU A 138 -8.264 21.467 23.405 1.00 27.64 C
+ATOM 1078 C GLU A 138 -9.582 21.216 22.703 1.00 26.40 C
+ATOM 1079 O GLU A 138 -10.516 22.028 22.786 1.00 26.47 O
+ATOM 1080 CB GLU A 138 -7.262 21.960 22.386 1.00 31.25 C
+ATOM 1081 CG GLU A 138 -6.917 23.444 22.370 1.00 35.75 C
+ATOM 1082 CD GLU A 138 -7.533 24.174 21.204 1.00 37.97 C
+ATOM 1083 OE1 GLU A 138 -8.783 24.068 21.195 1.00 39.64 O
+ATOM 1084 OE2 GLU A 138 -6.849 24.765 20.388 1.00 39.74 O
+ATOM 1085 N LEU A 139 -9.687 20.098 22.013 1.00 24.59 N
+ATOM 1086 CA LEU A 139 -10.882 19.726 21.263 1.00 23.51 C
+ATOM 1087 C LEU A 139 -11.890 19.021 22.141 1.00 22.35 C
+ATOM 1088 O LEU A 139 -13.088 19.040 21.848 1.00 21.96 O
+ATOM 1089 CB LEU A 139 -10.495 18.886 20.024 1.00 23.98 C
+ATOM 1090 CG LEU A 139 -10.492 19.612 18.684 1.00 23.79 C
+ATOM 1091 CD1 LEU A 139 -9.430 19.023 17.764 1.00 23.17 C
+ATOM 1092 CD2 LEU A 139 -11.851 19.389 18.029 1.00 24.27 C
+ATOM 1093 N LYS A 140 -11.419 18.370 23.178 1.00 22.58 N
+ATOM 1094 CA LYS A 140 -12.356 17.655 24.069 1.00 23.82 C
+ATOM 1095 C LYS A 140 -13.213 18.624 24.874 1.00 22.58 C
+ATOM 1096 O LYS A 140 -14.298 18.242 25.321 1.00 22.22 O
+ATOM 1097 CB LYS A 140 -11.665 16.632 24.940 1.00 24.12 C
+ATOM 1098 CG LYS A 140 -12.135 15.186 24.578 1.00 25.22 C
+ATOM 1099 CD LYS A 140 -10.895 14.339 24.393 1.00 24.73 C
+ATOM 1100 CE LYS A 140 -11.245 12.868 24.212 1.00 25.73 C
+ATOM 1101 NZ LYS A 140 -9.941 12.123 24.328 1.00 27.17 N
+ATOM 1102 N ALA A 141 -12.740 19.843 24.971 1.00 22.73 N
+ATOM 1103 CA ALA A 141 -13.435 20.914 25.682 1.00 23.60 C
+ATOM 1104 C ALA A 141 -14.723 21.262 24.971 1.00 25.85 C
+ATOM 1105 O ALA A 141 -15.612 21.894 25.584 1.00 27.42 O
+ATOM 1106 CB ALA A 141 -12.542 22.126 25.869 1.00 22.91 C
+ATOM 1107 N LYS A 142 -14.844 20.864 23.710 1.00 26.47 N
+ATOM 1108 CA LYS A 142 -16.054 21.141 22.933 1.00 27.64 C
+ATOM 1109 C LYS A 142 -16.801 19.867 22.585 1.00 27.57 C
+ATOM 1110 O LYS A 142 -17.754 19.945 21.783 1.00 28.07 O
+ATOM 1111 CB LYS A 142 -15.868 21.954 21.677 1.00 30.50 C
+ATOM 1112 CG LYS A 142 -14.754 21.492 20.731 1.00 33.53 C
+ATOM 1113 CD LYS A 142 -14.518 22.584 19.668 1.00 36.30 C
+ATOM 1114 CE LYS A 142 -13.085 22.638 19.221 1.00 37.67 C
+ATOM 1115 NZ LYS A 142 -12.279 23.726 19.814 1.00 38.54 N
+ATOM 1116 N GLY A 143 -16.401 18.750 23.163 1.00 27.63 N
+ATOM 1117 CA GLY A 143 -17.085 17.486 22.911 1.00 28.87 C
+ATOM 1118 C GLY A 143 -16.543 16.636 21.764 1.00 29.38 C
+ATOM 1119 O GLY A 143 -17.199 15.582 21.526 1.00 30.76 O
+ATOM 1120 N LYS A 144 -15.434 16.980 21.153 1.00 27.56 N
+ATOM 1121 CA LYS A 144 -14.803 16.276 20.043 1.00 27.38 C
+ATOM 1122 C LYS A 144 -13.430 15.730 20.381 1.00 25.98 C
+ATOM 1123 O LYS A 144 -12.735 16.332 21.212 1.00 28.93 O
+ATOM 1124 CB LYS A 144 -14.538 17.243 18.850 1.00 28.51 C
+ATOM 1125 CG LYS A 144 -15.746 18.022 18.333 1.00 28.19 C
+ATOM 1126 CD LYS A 144 -16.932 17.104 18.062 1.00 29.69 C
+ATOM 1127 CE LYS A 144 -18.128 17.816 17.472 1.00 30.67 C
+ATOM 1128 NZ LYS A 144 -19.164 16.809 17.060 1.00 31.97 N
+ATOM 1129 N SER A 145 -12.997 14.666 19.716 1.00 25.74 N
+ATOM 1130 CA SER A 145 -11.648 14.104 19.917 1.00 23.31 C
+ATOM 1131 C SER A 145 -10.766 14.597 18.757 1.00 22.82 C
+ATOM 1132 O SER A 145 -11.227 15.083 17.722 1.00 22.99 O
+ATOM 1133 CB SER A 145 -11.548 12.613 20.042 1.00 24.09 C
+ATOM 1134 OG SER A 145 -12.540 11.880 19.380 1.00 24.97 O
+ATOM 1135 N ALA A 146 -9.481 14.478 18.996 1.00 21.80 N
+ATOM 1136 CA ALA A 146 -8.448 14.844 18.062 1.00 21.29 C
+ATOM 1137 C ALA A 146 -8.287 13.771 16.958 1.00 24.33 C
+ATOM 1138 O ALA A 146 -8.506 14.078 15.761 1.00 25.02 O
+ATOM 1139 CB ALA A 146 -7.136 15.075 18.755 1.00 17.91 C
+ATOM 1140 N LEU A 147 -7.919 12.561 17.367 1.00 24.27 N
+ATOM 1141 CA LEU A 147 -7.600 11.496 16.393 1.00 24.34 C
+ATOM 1142 C LEU A 147 -8.281 10.191 16.635 1.00 25.00 C
+ATOM 1143 O LEU A 147 -8.613 9.877 17.807 1.00 26.58 O
+ATOM 1144 CB LEU A 147 -6.050 11.422 16.440 1.00 21.15 C
+ATOM 1145 CG LEU A 147 -5.411 10.321 15.636 1.00 19.47 C
+ATOM 1146 CD1 LEU A 147 -5.558 10.617 14.157 1.00 18.08 C
+ATOM 1147 CD2 LEU A 147 -3.936 10.223 15.990 1.00 18.42 C
+ATOM 1148 N MET A 148 -8.466 9.413 15.588 1.00 24.42 N
+ATOM 1149 CA MET A 148 -9.139 8.095 15.728 1.00 23.56 C
+ATOM 1150 C MET A 148 -8.742 7.183 14.571 1.00 22.89 C
+ATOM 1151 O MET A 148 -9.181 7.517 13.451 1.00 21.36 O
+ATOM 1152 CB MET A 148 -10.615 8.419 15.731 1.00 26.69 C
+ATOM 1153 CG MET A 148 -11.492 7.323 16.222 1.00 31.69 C
+ATOM 1154 SD MET A 148 -12.228 7.958 17.801 1.00 35.32 S
+ATOM 1155 CE MET A 148 -12.760 6.374 18.477 1.00 36.01 C
+ATOM 1156 N PHE A 149 -7.976 6.151 14.800 1.00 20.22 N
+ATOM 1157 CA PHE A 149 -7.545 5.229 13.723 1.00 21.13 C
+ATOM 1158 C PHE A 149 -7.568 3.765 14.154 1.00 21.50 C
+ATOM 1159 O PHE A 149 -7.739 3.474 15.331 1.00 20.29 O
+ATOM 1160 CB PHE A 149 -6.206 5.620 13.204 1.00 19.51 C
+ATOM 1161 CG PHE A 149 -4.929 5.516 13.923 1.00 21.03 C
+ATOM 1162 CD1 PHE A 149 -4.544 6.482 14.862 1.00 22.66 C
+ATOM 1163 CD2 PHE A 149 -4.019 4.508 13.617 1.00 20.09 C
+ATOM 1164 CE1 PHE A 149 -3.306 6.406 15.504 1.00 22.84 C
+ATOM 1165 CE2 PHE A 149 -2.791 4.436 14.222 1.00 21.25 C
+ATOM 1166 CZ PHE A 149 -2.419 5.371 15.179 1.00 21.61 C
+ATOM 1167 N ASN A 150 -7.360 2.875 13.182 1.00 22.49 N
+ATOM 1168 CA ASN A 150 -7.332 1.411 13.453 1.00 21.93 C
+ATOM 1169 C ASN A 150 -6.101 1.063 14.270 1.00 21.16 C
+ATOM 1170 O ASN A 150 -4.963 1.171 13.799 1.00 20.82 O
+ATOM 1171 CB ASN A 150 -7.408 0.615 12.131 1.00 24.44 C
+ATOM 1172 CG ASN A 150 -7.668 -0.848 12.377 1.00 26.75 C
+ATOM 1173 OD1 ASN A 150 -7.986 -1.309 13.492 1.00 25.67 O
+ATOM 1174 ND2 ASN A 150 -7.561 -1.673 11.339 1.00 29.32 N
+ATOM 1175 N LEU A 151 -6.297 0.633 15.502 1.00 21.61 N
+ATOM 1176 CA LEU A 151 -5.194 0.305 16.410 1.00 23.42 C
+ATOM 1177 C LEU A 151 -4.951 -1.199 16.461 1.00 23.05 C
+ATOM 1178 O LEU A 151 -3.933 -1.650 16.946 1.00 23.26 O
+ATOM 1179 CB LEU A 151 -5.562 0.857 17.813 1.00 24.81 C
+ATOM 1180 CG LEU A 151 -5.464 2.364 18.033 1.00 24.41 C
+ATOM 1181 CD1 LEU A 151 -5.682 2.701 19.513 1.00 24.76 C
+ATOM 1182 CD2 LEU A 151 -4.076 2.834 17.607 1.00 22.64 C
+ATOM 1183 N GLN A 152 -5.910 -1.926 15.971 1.00 23.90 N
+ATOM 1184 CA GLN A 152 -5.941 -3.379 15.966 1.00 25.76 C
+ATOM 1185 C GLN A 152 -5.091 -4.030 14.902 1.00 26.51 C
+ATOM 1186 O GLN A 152 -5.010 -5.282 14.853 1.00 28.22 O
+ATOM 1187 CB GLN A 152 -7.430 -3.800 15.798 1.00 25.78 C
+ATOM 1188 CG GLN A 152 -8.286 -3.307 16.957 1.00 31.52 C
+ATOM 1189 CD GLN A 152 -7.652 -3.588 18.311 1.00 34.41 C
+ATOM 1190 OE1 GLN A 152 -7.822 -4.670 18.880 1.00 38.91 O
+ATOM 1191 NE2 GLN A 152 -6.873 -2.668 18.893 1.00 35.66 N
+ATOM 1192 N GLU A 153 -4.469 -3.205 14.085 1.00 24.75 N
+ATOM 1193 CA GLU A 153 -3.714 -3.679 12.935 1.00 23.05 C
+ATOM 1194 C GLU A 153 -2.392 -3.002 12.761 1.00 20.91 C
+ATOM 1195 O GLU A 153 -2.330 -1.770 12.654 1.00 22.79 O
+ATOM 1196 CB GLU A 153 -4.548 -3.357 11.664 1.00 26.49 C
+ATOM 1197 CG GLU A 153 -4.280 -4.243 10.464 1.00 28.59 C
+ATOM 1198 CD GLU A 153 -4.612 -5.682 10.791 1.00 30.68 C
+ATOM 1199 OE1 GLU A 153 -5.750 -6.079 10.883 1.00 31.33 O
+ATOM 1200 OE2 GLU A 153 -3.550 -6.321 11.011 1.00 33.70 O
+ATOM 1201 N PRO A 154 -1.363 -3.830 12.685 1.00 18.92 N
+ATOM 1202 CA PRO A 154 0.001 -3.334 12.548 1.00 18.55 C
+ATOM 1203 C PRO A 154 0.235 -2.367 11.400 1.00 17.86 C
+ATOM 1204 O PRO A 154 1.064 -1.426 11.438 1.00 18.05 O
+ATOM 1205 CB PRO A 154 0.828 -4.599 12.587 1.00 17.98 C
+ATOM 1206 CG PRO A 154 -0.096 -5.754 12.351 1.00 17.42 C
+ATOM 1207 CD PRO A 154 -1.442 -5.296 12.844 1.00 17.42 C
+ATOM 1208 N TYR A 155 -0.491 -2.595 10.318 1.00 18.36 N
+ATOM 1209 CA TYR A 155 -0.397 -1.753 9.095 1.00 17.80 C
+ATOM 1210 C TYR A 155 -0.623 -0.283 9.470 1.00 16.03 C
+ATOM 1211 O TYR A 155 0.134 0.601 9.037 1.00 16.70 O
+ATOM 1212 CB TYR A 155 -1.362 -2.315 8.017 1.00 16.69 C
+ATOM 1213 CG TYR A 155 -1.338 -1.555 6.708 1.00 17.39 C
+ATOM 1214 CD1 TYR A 155 -0.393 -1.782 5.722 1.00 19.21 C
+ATOM 1215 CD2 TYR A 155 -2.300 -0.567 6.456 1.00 17.66 C
+ATOM 1216 CE1 TYR A 155 -0.361 -1.017 4.531 1.00 18.51 C
+ATOM 1217 CE2 TYR A 155 -2.303 0.187 5.291 1.00 18.08 C
+ATOM 1218 CZ TYR A 155 -1.336 -0.040 4.317 1.00 19.70 C
+ATOM 1219 OH TYR A 155 -1.389 0.731 3.186 1.00 18.99 O
+ATOM 1220 N PHE A 156 -1.626 -0.036 10.278 1.00 15.26 N
+ATOM 1221 CA PHE A 156 -2.102 1.250 10.771 1.00 14.90 C
+ATOM 1222 C PHE A 156 -1.246 1.910 11.832 1.00 14.73 C
+ATOM 1223 O PHE A 156 -1.082 3.148 11.880 1.00 14.36 O
+ATOM 1224 CB PHE A 156 -3.581 1.138 11.108 1.00 15.01 C
+ATOM 1225 CG PHE A 156 -4.542 1.066 9.960 1.00 15.37 C
+ATOM 1226 CD1 PHE A 156 -4.791 -0.139 9.311 1.00 15.49 C
+ATOM 1227 CD2 PHE A 156 -5.204 2.228 9.522 1.00 16.77 C
+ATOM 1228 CE1 PHE A 156 -5.682 -0.183 8.234 1.00 17.14 C
+ATOM 1229 CE2 PHE A 156 -6.121 2.197 8.464 1.00 14.94 C
+ATOM 1230 CZ PHE A 156 -6.354 0.973 7.834 1.00 16.48 C
+ATOM 1231 N THR A 157 -0.574 1.137 12.669 1.00 15.90 N
+ATOM 1232 CA THR A 157 0.280 1.669 13.703 1.00 16.23 C
+ATOM 1233 C THR A 157 1.711 1.752 13.299 1.00 17.76 C
+ATOM 1234 O THR A 157 2.436 2.550 13.970 1.00 20.23 O
+ATOM 1235 CB THR A 157 0.119 0.956 15.106 1.00 18.77 C
+ATOM 1236 OG1 THR A 157 0.361 -0.463 14.939 1.00 20.58 O
+ATOM 1237 CG2 THR A 157 -1.276 1.166 15.760 1.00 20.09 C
+ATOM 1238 N TRP A 158 2.192 1.020 12.300 1.00 17.01 N
+ATOM 1239 CA TRP A 158 3.612 1.091 11.894 1.00 14.94 C
+ATOM 1240 C TRP A 158 4.163 2.449 11.558 1.00 14.79 C
+ATOM 1241 O TRP A 158 5.348 2.761 11.931 1.00 16.90 O
+ATOM 1242 CB TRP A 158 3.806 0.131 10.666 1.00 15.94 C
+ATOM 1243 CG TRP A 158 5.252 -0.022 10.315 1.00 14.61 C
+ATOM 1244 CD1 TRP A 158 5.969 0.399 9.240 1.00 14.37 C
+ATOM 1245 CD2 TRP A 158 6.190 -0.712 11.184 1.00 16.93 C
+ATOM 1246 NE1 TRP A 158 7.293 0.032 9.367 1.00 14.26 N
+ATOM 1247 CE2 TRP A 158 7.441 -0.679 10.534 1.00 16.83 C
+ATOM 1248 CE3 TRP A 158 6.037 -1.363 12.416 1.00 16.67 C
+ATOM 1249 CZ2 TRP A 158 8.566 -1.262 11.113 1.00 18.63 C
+ATOM 1250 CZ3 TRP A 158 7.161 -1.905 12.985 1.00 16.24 C
+ATOM 1251 CH2 TRP A 158 8.404 -1.867 12.355 1.00 17.51 C
+ATOM 1252 N PRO A 159 3.447 3.301 10.799 1.00 12.09 N
+ATOM 1253 CA PRO A 159 3.973 4.627 10.447 1.00 11.24 C
+ATOM 1254 C PRO A 159 4.661 5.338 11.613 1.00 11.14 C
+ATOM 1255 O PRO A 159 5.696 6.027 11.530 1.00 9.47 O
+ATOM 1256 CB PRO A 159 2.760 5.374 9.911 1.00 7.87 C
+ATOM 1257 CG PRO A 159 1.686 4.398 9.650 1.00 9.41 C
+ATOM 1258 CD PRO A 159 2.108 3.074 10.263 1.00 9.33 C
+ATOM 1259 N LEU A 160 4.017 5.221 12.783 1.00 13.60 N
+ATOM 1260 CA LEU A 160 4.533 5.889 13.995 1.00 14.29 C
+ATOM 1261 C LEU A 160 5.686 5.110 14.603 1.00 14.56 C
+ATOM 1262 O LEU A 160 6.735 5.668 14.998 1.00 14.66 O
+ATOM 1263 CB LEU A 160 3.326 6.132 14.934 1.00 13.17 C
+ATOM 1264 CG LEU A 160 3.724 6.551 16.346 1.00 12.39 C
+ATOM 1265 CD1 LEU A 160 4.659 7.744 16.313 1.00 12.11 C
+ATOM 1266 CD2 LEU A 160 2.479 6.842 17.173 1.00 11.61 C
+ATOM 1267 N ILE A 161 5.473 3.783 14.689 1.00 16.11 N
+ATOM 1268 CA ILE A 161 6.519 2.940 15.282 1.00 16.75 C
+ATOM 1269 C ILE A 161 7.803 3.047 14.487 1.00 19.40 C
+ATOM 1270 O ILE A 161 8.888 3.077 15.113 1.00 21.63 O
+ATOM 1271 CB ILE A 161 6.083 1.464 15.549 1.00 16.34 C
+ATOM 1272 CG1 ILE A 161 4.902 1.378 16.517 1.00 15.30 C
+ATOM 1273 CG2 ILE A 161 7.330 0.668 16.037 1.00 16.25 C
+ATOM 1274 CD1 ILE A 161 4.044 0.093 16.395 1.00 17.83 C
+ATOM 1275 N ALA A 162 7.702 3.119 13.173 1.00 19.52 N
+ATOM 1276 CA ALA A 162 8.910 3.210 12.334 1.00 19.98 C
+ATOM 1277 C ALA A 162 9.434 4.612 12.214 1.00 20.49 C
+ATOM 1278 O ALA A 162 10.593 4.820 11.769 1.00 22.81 O
+ATOM 1279 CB ALA A 162 8.647 2.574 10.963 1.00 18.95 C
+ATOM 1280 N ALA A 163 8.690 5.618 12.574 1.00 21.56 N
+ATOM 1281 CA ALA A 163 9.116 7.026 12.484 1.00 21.75 C
+ATOM 1282 C ALA A 163 10.560 7.293 12.839 1.00 21.53 C
+ATOM 1283 O ALA A 163 11.316 7.955 12.097 1.00 21.36 O
+ATOM 1284 CB ALA A 163 8.178 7.905 13.343 1.00 20.57 C
+ATOM 1285 N ASP A 164 10.978 6.799 13.991 1.00 22.69 N
+ATOM 1286 CA ASP A 164 12.319 7.037 14.522 1.00 23.10 C
+ATOM 1287 C ASP A 164 13.342 5.949 14.436 1.00 23.26 C
+ATOM 1288 O ASP A 164 14.365 5.978 15.183 1.00 24.14 O
+ATOM 1289 CB ASP A 164 12.068 7.564 15.955 1.00 25.20 C
+ATOM 1290 CG ASP A 164 13.289 8.225 16.551 1.00 27.06 C
+ATOM 1291 OD1 ASP A 164 13.894 9.126 15.936 1.00 29.03 O
+ATOM 1292 OD2 ASP A 164 13.615 7.742 17.667 1.00 28.35 O
+ATOM 1293 N GLY A 165 13.204 4.952 13.575 1.00 24.47 N
+ATOM 1294 CA GLY A 165 14.251 3.938 13.459 1.00 23.30 C
+ATOM 1295 C GLY A 165 13.817 2.557 13.128 1.00 23.85 C
+ATOM 1296 O GLY A 165 14.677 1.747 12.683 1.00 25.70 O
+ATOM 1297 N GLY A 166 12.571 2.241 13.358 1.00 23.70 N
+ATOM 1298 CA GLY A 166 12.002 0.918 13.119 1.00 23.92 C
+ATOM 1299 C GLY A 166 11.942 0.590 11.634 1.00 24.68 C
+ATOM 1300 O GLY A 166 11.831 1.461 10.767 1.00 24.15 O
+ATOM 1301 N TYR A 167 11.992 -0.702 11.366 1.00 25.84 N
+ATOM 1302 CA TYR A 167 11.918 -1.310 10.030 1.00 25.77 C
+ATOM 1303 C TYR A 167 11.552 -2.788 10.202 1.00 25.08 C
+ATOM 1304 O TYR A 167 11.615 -3.283 11.339 1.00 25.84 O
+ATOM 1305 CB TYR A 167 13.154 -1.139 9.165 1.00 25.60 C
+ATOM 1306 CG TYR A 167 14.449 -1.638 9.753 1.00 26.05 C
+ATOM 1307 CD1 TYR A 167 15.228 -0.766 10.537 1.00 26.52 C
+ATOM 1308 CD2 TYR A 167 14.905 -2.934 9.539 1.00 24.14 C
+ATOM 1309 CE1 TYR A 167 16.421 -1.187 11.108 1.00 25.48 C
+ATOM 1310 CE2 TYR A 167 16.088 -3.372 10.114 1.00 23.59 C
+ATOM 1311 CZ TYR A 167 16.829 -2.503 10.872 1.00 24.85 C
+ATOM 1312 OH TYR A 167 18.008 -2.928 11.396 1.00 28.32 O
+ATOM 1313 N ALA A 168 11.144 -3.408 9.119 1.00 23.77 N
+ATOM 1314 CA ALA A 168 10.744 -4.830 9.153 1.00 23.55 C
+ATOM 1315 C ALA A 168 11.997 -5.672 8.913 1.00 25.41 C
+ATOM 1316 O ALA A 168 12.449 -6.406 9.812 1.00 25.85 O
+ATOM 1317 CB ALA A 168 9.633 -5.064 8.176 1.00 20.85 C
+ATOM 1318 N PHE A 169 12.557 -5.497 7.717 1.00 26.14 N
+ATOM 1319 CA PHE A 169 13.769 -6.152 7.227 1.00 26.06 C
+ATOM 1320 C PHE A 169 14.660 -5.161 6.485 1.00 26.94 C
+ATOM 1321 O PHE A 169 14.145 -4.366 5.683 1.00 29.03 O
+ATOM 1322 CB PHE A 169 13.460 -7.352 6.334 1.00 25.00 C
+ATOM 1323 CG PHE A 169 12.606 -8.434 6.899 1.00 24.23 C
+ATOM 1324 CD1 PHE A 169 13.187 -9.452 7.673 1.00 24.48 C
+ATOM 1325 CD2 PHE A 169 11.236 -8.462 6.681 1.00 24.88 C
+ATOM 1326 CE1 PHE A 169 12.415 -10.459 8.217 1.00 23.05 C
+ATOM 1327 CE2 PHE A 169 10.434 -9.487 7.197 1.00 25.41 C
+ATOM 1328 CZ PHE A 169 11.051 -10.500 7.965 1.00 24.26 C
+ATOM 1329 N LYS A 170 15.946 -5.262 6.695 1.00 29.92 N
+ATOM 1330 CA LYS A 170 16.962 -4.432 6.048 1.00 33.66 C
+ATOM 1331 C LYS A 170 17.144 -4.745 4.561 1.00 36.90 C
+ATOM 1332 O LYS A 170 17.318 -5.899 4.149 1.00 36.92 O
+ATOM 1333 CB LYS A 170 18.331 -4.589 6.702 1.00 32.76 C
+ATOM 1334 CG LYS A 170 19.225 -3.343 6.566 1.00 34.15 C
+ATOM 1335 CD LYS A 170 18.592 -2.142 7.243 1.00 35.76 C
+ATOM 1336 CE LYS A 170 19.490 -0.947 7.389 1.00 35.97 C
+ATOM 1337 NZ LYS A 170 20.032 -0.826 8.767 1.00 36.52 N
+ATOM 1338 N TYR A 171 17.121 -3.701 3.769 1.00 40.34 N
+ATOM 1339 CA TYR A 171 17.303 -3.689 2.309 1.00 44.37 C
+ATOM 1340 C TYR A 171 18.607 -2.896 2.086 1.00 48.15 C
+ATOM 1341 O TYR A 171 18.642 -1.652 2.088 1.00 49.74 O
+ATOM 1342 CB TYR A 171 16.131 -3.066 1.586 1.00 42.78 C
+ATOM 1343 CG TYR A 171 15.864 -3.348 0.133 1.00 40.21 C
+ATOM 1344 CD1 TYR A 171 15.184 -4.490 -0.296 1.00 39.31 C
+ATOM 1345 CD2 TYR A 171 16.236 -2.435 -0.844 1.00 39.57 C
+ATOM 1346 CE1 TYR A 171 14.906 -4.735 -1.636 1.00 39.97 C
+ATOM 1347 CE2 TYR A 171 15.964 -2.647 -2.191 1.00 39.75 C
+ATOM 1348 CZ TYR A 171 15.305 -3.802 -2.591 1.00 39.58 C
+ATOM 1349 OH TYR A 171 15.062 -3.965 -3.928 1.00 38.94 O
+ATOM 1350 N GLU A 172 19.659 -3.681 1.961 1.00 51.98 N
+ATOM 1351 CA GLU A 172 21.021 -3.155 1.796 1.00 55.22 C
+ATOM 1352 C GLU A 172 21.440 -3.145 0.340 1.00 56.24 C
+ATOM 1353 O GLU A 172 22.536 -2.616 0.005 1.00 56.60 O
+ATOM 1354 CB GLU A 172 22.007 -3.990 2.626 1.00 56.52 C
+ATOM 1355 CG GLU A 172 23.476 -3.620 2.700 1.00 60.01 C
+ATOM 1356 CD GLU A 172 23.825 -2.163 2.744 1.00 62.50 C
+ATOM 1357 OE1 GLU A 172 23.010 -1.298 3.060 1.00 63.74 O
+ATOM 1358 OE2 GLU A 172 25.014 -1.891 2.413 1.00 63.91 O
+ATOM 1359 N ASN A 173 20.572 -3.707 -0.525 1.00 56.44 N
+ATOM 1360 CA ASN A 173 20.968 -3.770 -1.947 1.00 56.97 C
+ATOM 1361 C ASN A 173 19.880 -4.144 -2.926 1.00 55.09 C
+ATOM 1362 O ASN A 173 19.831 -3.554 -4.038 1.00 55.97 O
+ATOM 1363 CB ASN A 173 22.227 -4.670 -2.072 1.00 59.47 C
+ATOM 1364 CG ASN A 173 22.328 -5.777 -1.034 1.00 62.17 C
+ATOM 1365 OD1 ASN A 173 21.302 -6.289 -0.518 1.00 63.11 O
+ATOM 1366 ND2 ASN A 173 23.570 -6.157 -0.695 1.00 62.14 N
+ATOM 1367 N GLY A 174 19.061 -5.116 -2.606 1.00 52.93 N
+ATOM 1368 CA GLY A 174 17.999 -5.549 -3.566 1.00 50.16 C
+ATOM 1369 C GLY A 174 17.488 -6.898 -3.042 1.00 48.43 C
+ATOM 1370 O GLY A 174 16.612 -7.565 -3.602 1.00 48.46 O
+ATOM 1371 N LYS A 175 18.119 -7.233 -1.933 1.00 47.12 N
+ATOM 1372 CA LYS A 175 17.816 -8.444 -1.165 1.00 45.31 C
+ATOM 1373 C LYS A 175 17.486 -7.955 0.260 1.00 42.47 C
+ATOM 1374 O LYS A 175 18.042 -6.923 0.690 1.00 40.82 O
+ATOM 1375 CB LYS A 175 18.966 -9.438 -1.119 1.00 47.01 C
+ATOM 1376 CG LYS A 175 18.954 -10.529 -2.187 1.00 48.85 C
+ATOM 1377 CD LYS A 175 17.574 -11.152 -2.357 1.00 51.24 C
+ATOM 1378 CE LYS A 175 17.204 -12.172 -1.296 1.00 52.26 C
+ATOM 1379 NZ LYS A 175 15.810 -12.673 -1.516 1.00 52.02 N
+ATOM 1380 N TYR A 176 16.609 -8.697 0.887 1.00 40.26 N
+ATOM 1381 CA TYR A 176 16.187 -8.420 2.260 1.00 39.58 C
+ATOM 1382 C TYR A 176 16.911 -9.394 3.203 1.00 40.65 C
+ATOM 1383 O TYR A 176 16.796 -10.611 2.939 1.00 42.06 O
+ATOM 1384 CB TYR A 176 14.666 -8.662 2.442 1.00 36.32 C
+ATOM 1385 CG TYR A 176 13.796 -7.548 1.945 1.00 32.65 C
+ATOM 1386 CD1 TYR A 176 13.841 -6.274 2.526 1.00 28.84 C
+ATOM 1387 CD2 TYR A 176 12.923 -7.776 0.867 1.00 31.50 C
+ATOM 1388 CE1 TYR A 176 13.025 -5.264 2.039 1.00 27.58 C
+ATOM 1389 CE2 TYR A 176 12.102 -6.763 0.367 1.00 28.28 C
+ATOM 1390 CZ TYR A 176 12.170 -5.511 0.969 1.00 27.91 C
+ATOM 1391 OH TYR A 176 11.377 -4.529 0.454 1.00 28.27 O
+ATOM 1392 N ASP A 177 17.559 -8.874 4.223 1.00 41.23 N
+ATOM 1393 CA ASP A 177 18.220 -9.728 5.234 1.00 41.32 C
+ATOM 1394 C ASP A 177 17.131 -10.144 6.239 1.00 41.79 C
+ATOM 1395 O ASP A 177 16.596 -9.311 6.969 1.00 41.80 O
+ATOM 1396 CB ASP A 177 19.418 -9.034 5.848 1.00 42.32 C
+ATOM 1397 CG ASP A 177 20.170 -9.991 6.778 1.00 43.57 C
+ATOM 1398 OD1 ASP A 177 19.700 -11.102 7.097 1.00 44.01 O
+ATOM 1399 OD2 ASP A 177 21.262 -9.557 7.175 1.00 44.77 O
+ATOM 1400 N ILE A 178 16.818 -11.421 6.233 1.00 42.69 N
+ATOM 1401 CA ILE A 178 15.775 -12.063 7.023 1.00 42.69 C
+ATOM 1402 C ILE A 178 16.117 -12.345 8.470 1.00 42.48 C
+ATOM 1403 O ILE A 178 15.379 -12.996 9.248 1.00 41.71 O
+ATOM 1404 CB ILE A 178 15.285 -13.339 6.233 1.00 44.12 C
+ATOM 1405 CG1 ILE A 178 16.128 -14.570 6.638 1.00 45.05 C
+ATOM 1406 CG2 ILE A 178 15.330 -13.101 4.688 1.00 43.73 C
+ATOM 1407 CD1 ILE A 178 15.333 -15.900 6.749 1.00 45.89 C
+ATOM 1408 N LYS A 179 17.278 -11.854 8.859 1.00 42.88 N
+ATOM 1409 CA LYS A 179 17.768 -12.028 10.237 1.00 43.27 C
+ATOM 1410 C LYS A 179 18.015 -10.643 10.824 1.00 42.59 C
+ATOM 1411 O LYS A 179 18.293 -10.536 12.035 1.00 43.25 O
+ATOM 1412 CB LYS A 179 18.985 -12.928 10.343 1.00 45.37 C
+ATOM 1413 CG LYS A 179 18.697 -14.433 10.174 1.00 47.35 C
+ATOM 1414 CD LYS A 179 17.710 -14.966 11.200 1.00 48.18 C
+ATOM 1415 CE LYS A 179 18.315 -15.565 12.443 1.00 48.69 C
+ATOM 1416 NZ LYS A 179 19.499 -14.831 12.955 1.00 48.39 N
+ATOM 1417 N ASP A 180 17.878 -9.641 9.961 1.00 40.49 N
+ATOM 1418 CA ASP A 180 18.063 -8.235 10.385 1.00 38.53 C
+ATOM 1419 C ASP A 180 16.721 -7.498 10.362 1.00 37.17 C
+ATOM 1420 O ASP A 180 16.294 -6.853 9.407 1.00 36.25 O
+ATOM 1421 CB ASP A 180 19.184 -7.609 9.570 1.00 39.83 C
+ATOM 1422 CG ASP A 180 19.417 -6.168 9.987 1.00 41.97 C
+ATOM 1423 OD1 ASP A 180 18.807 -5.769 11.006 1.00 43.71 O
+ATOM 1424 OD2 ASP A 180 20.199 -5.459 9.315 1.00 42.27 O
+ATOM 1425 N VAL A 181 16.024 -7.618 11.457 1.00 36.57 N
+ATOM 1426 CA VAL A 181 14.704 -7.097 11.836 1.00 34.83 C
+ATOM 1427 C VAL A 181 14.875 -5.905 12.778 1.00 34.81 C
+ATOM 1428 O VAL A 181 15.757 -5.880 13.661 1.00 35.36 O
+ATOM 1429 CB VAL A 181 13.936 -8.310 12.406 1.00 34.72 C
+ATOM 1430 CG1 VAL A 181 12.588 -8.046 13.035 1.00 35.43 C
+ATOM 1431 CG2 VAL A 181 13.814 -9.386 11.325 1.00 35.13 C
+ATOM 1432 N GLY A 182 14.062 -4.879 12.575 1.00 34.17 N
+ATOM 1433 CA GLY A 182 14.084 -3.628 13.325 1.00 32.48 C
+ATOM 1434 C GLY A 182 12.819 -3.309 14.098 1.00 32.41 C
+ATOM 1435 O GLY A 182 12.260 -2.206 14.011 1.00 30.56 O
+ATOM 1436 N VAL A 183 12.378 -4.272 14.866 1.00 32.70 N
+ATOM 1437 CA VAL A 183 11.171 -4.180 15.696 1.00 33.47 C
+ATOM 1438 C VAL A 183 11.566 -3.892 17.146 1.00 35.49 C
+ATOM 1439 O VAL A 183 10.764 -3.382 17.951 1.00 35.16 O
+ATOM 1440 CB VAL A 183 10.357 -5.477 15.491 1.00 31.55 C
+ATOM 1441 CG1 VAL A 183 9.313 -5.726 16.551 1.00 30.19 C
+ATOM 1442 CG2 VAL A 183 9.715 -5.511 14.111 1.00 30.64 C
+ATOM 1443 N ASP A 184 12.824 -4.189 17.455 1.00 37.92 N
+ATOM 1444 CA ASP A 184 13.370 -4.045 18.816 1.00 40.31 C
+ATOM 1445 C ASP A 184 14.395 -2.956 18.962 1.00 40.05 C
+ATOM 1446 O ASP A 184 15.170 -2.914 19.950 1.00 41.19 O
+ATOM 1447 CB ASP A 184 13.880 -5.418 19.283 1.00 43.60 C
+ATOM 1448 CG ASP A 184 14.025 -5.594 20.768 1.00 47.03 C
+ATOM 1449 OD1 ASP A 184 14.154 -4.570 21.491 1.00 50.98 O
+ATOM 1450 OD2 ASP A 184 14.028 -6.726 21.299 1.00 49.07 O
+ATOM 1451 N ASN A 185 14.466 -2.019 18.030 1.00 40.41 N
+ATOM 1452 CA ASN A 185 15.505 -0.972 18.274 1.00 40.46 C
+ATOM 1453 C ASN A 185 14.857 0.145 19.111 1.00 40.70 C
+ATOM 1454 O ASN A 185 13.719 0.038 19.595 1.00 40.93 O
+ATOM 1455 CB ASN A 185 16.270 -0.613 17.039 1.00 40.17 C
+ATOM 1456 CG ASN A 185 15.424 0.052 15.978 1.00 39.09 C
+ATOM 1457 OD1 ASN A 185 14.196 0.014 16.074 1.00 39.34 O
+ATOM 1458 ND2 ASN A 185 16.120 0.643 15.020 1.00 40.90 N
+ATOM 1459 N ALA A 186 15.668 1.166 19.299 1.00 39.80 N
+ATOM 1460 CA ALA A 186 15.407 2.373 20.056 1.00 38.97 C
+ATOM 1461 C ALA A 186 14.211 3.135 19.482 1.00 37.43 C
+ATOM 1462 O ALA A 186 13.291 3.513 20.234 1.00 38.43 O
+ATOM 1463 CB ALA A 186 16.664 3.246 20.024 1.00 40.42 C
+ATOM 1464 N GLY A 187 14.266 3.295 18.171 1.00 34.75 N
+ATOM 1465 CA GLY A 187 13.236 3.983 17.420 1.00 30.64 C
+ATOM 1466 C GLY A 187 11.871 3.353 17.570 1.00 28.74 C
+ATOM 1467 O GLY A 187 10.882 4.084 17.747 1.00 30.62 O
+ATOM 1468 N ALA A 188 11.760 2.061 17.473 1.00 25.86 N
+ATOM 1469 CA ALA A 188 10.480 1.355 17.586 1.00 25.12 C
+ATOM 1470 C ALA A 188 9.862 1.471 18.972 1.00 25.26 C
+ATOM 1471 O ALA A 188 8.627 1.447 19.174 1.00 23.50 O
+ATOM 1472 CB ALA A 188 10.762 -0.112 17.231 1.00 25.61 C
+ATOM 1473 N LYS A 189 10.746 1.535 19.966 1.00 26.26 N
+ATOM 1474 CA LYS A 189 10.330 1.624 21.383 1.00 26.90 C
+ATOM 1475 C LYS A 189 9.826 3.042 21.648 1.00 25.08 C
+ATOM 1476 O LYS A 189 8.786 3.193 22.305 1.00 25.86 O
+ATOM 1477 CB LYS A 189 11.458 1.269 22.340 1.00 29.70 C
+ATOM 1478 CG LYS A 189 11.321 -0.188 22.833 1.00 32.71 C
+ATOM 1479 CD LYS A 189 12.674 -0.831 23.022 1.00 37.06 C
+ATOM 1480 CE LYS A 189 13.598 -0.061 23.959 1.00 40.19 C
+ATOM 1481 NZ LYS A 189 15.028 -0.410 23.618 1.00 42.66 N
+ATOM 1482 N ALA A 190 10.584 3.975 21.094 1.00 23.05 N
+ATOM 1483 CA ALA A 190 10.255 5.398 21.216 1.00 21.43 C
+ATOM 1484 C ALA A 190 8.863 5.572 20.654 1.00 22.04 C
+ATOM 1485 O ALA A 190 7.991 6.102 21.367 1.00 24.24 O
+ATOM 1486 CB ALA A 190 11.258 6.307 20.549 1.00 20.94 C
+ATOM 1487 N GLY A 191 8.610 5.087 19.445 1.00 21.23 N
+ATOM 1488 CA GLY A 191 7.301 5.201 18.821 1.00 19.84 C
+ATOM 1489 C GLY A 191 6.190 4.416 19.446 1.00 19.63 C
+ATOM 1490 O GLY A 191 5.002 4.853 19.474 1.00 22.35 O
+ATOM 1491 N LEU A 192 6.455 3.197 19.925 1.00 19.44 N
+ATOM 1492 CA LEU A 192 5.391 2.386 20.511 1.00 19.08 C
+ATOM 1493 C LEU A 192 4.999 2.942 21.893 1.00 21.08 C
+ATOM 1494 O LEU A 192 3.844 2.814 22.324 1.00 21.16 O
+ATOM 1495 CB LEU A 192 5.809 0.912 20.565 1.00 17.52 C
+ATOM 1496 CG LEU A 192 4.723 0.034 21.176 1.00 15.24 C
+ATOM 1497 CD1 LEU A 192 3.404 0.150 20.419 1.00 15.48 C
+ATOM 1498 CD2 LEU A 192 5.179 -1.396 21.206 1.00 17.52 C
+ATOM 1499 N THR A 193 5.984 3.499 22.542 1.00 22.76 N
+ATOM 1500 CA THR A 193 5.826 4.106 23.870 1.00 25.35 C
+ATOM 1501 C THR A 193 4.937 5.345 23.737 1.00 25.25 C
+ATOM 1502 O THR A 193 3.988 5.468 24.526 1.00 25.99 O
+ATOM 1503 CB THR A 193 7.217 4.433 24.525 1.00 27.15 C
+ATOM 1504 OG1 THR A 193 7.883 3.130 24.688 1.00 30.38 O
+ATOM 1505 CG2 THR A 193 7.131 5.165 25.874 1.00 28.80 C
+ATOM 1506 N PHE A 194 5.216 6.174 22.749 1.00 24.46 N
+ATOM 1507 CA PHE A 194 4.413 7.388 22.495 1.00 24.25 C
+ATOM 1508 C PHE A 194 2.950 7.012 22.319 1.00 24.97 C
+ATOM 1509 O PHE A 194 2.025 7.644 22.878 1.00 26.00 O
+ATOM 1510 CB PHE A 194 4.941 8.223 21.329 1.00 22.37 C
+ATOM 1511 CG PHE A 194 4.200 9.514 21.134 1.00 21.27 C
+ATOM 1512 CD1 PHE A 194 3.031 9.534 20.358 1.00 23.02 C
+ATOM 1513 CD2 PHE A 194 4.622 10.684 21.721 1.00 19.80 C
+ATOM 1514 CE1 PHE A 194 2.273 10.684 20.165 1.00 20.76 C
+ATOM 1515 CE2 PHE A 194 3.889 11.861 21.540 1.00 21.31 C
+ATOM 1516 CZ PHE A 194 2.712 11.860 20.762 1.00 21.80 C
+ATOM 1517 N LEU A 195 2.743 5.959 21.539 1.00 25.68 N
+ATOM 1518 CA LEU A 195 1.403 5.438 21.243 1.00 25.82 C
+ATOM 1519 C LEU A 195 0.693 4.919 22.481 1.00 27.55 C
+ATOM 1520 O LEU A 195 -0.553 5.048 22.606 1.00 28.50 O
+ATOM 1521 CB LEU A 195 1.590 4.342 20.142 1.00 26.45 C
+ATOM 1522 CG LEU A 195 0.312 3.583 19.808 1.00 26.52 C
+ATOM 1523 CD1 LEU A 195 -0.601 4.492 18.981 1.00 29.13 C
+ATOM 1524 CD2 LEU A 195 0.599 2.302 19.050 1.00 27.19 C
+ATOM 1525 N VAL A 196 1.470 4.281 23.365 1.00 28.08 N
+ATOM 1526 CA VAL A 196 0.892 3.687 24.585 1.00 27.57 C
+ATOM 1527 C VAL A 196 0.359 4.819 25.462 1.00 26.53 C
+ATOM 1528 O VAL A 196 -0.762 4.714 25.945 1.00 26.23 O
+ATOM 1529 CB VAL A 196 1.841 2.733 25.302 1.00 29.18 C
+ATOM 1530 CG1 VAL A 196 1.163 2.096 26.523 1.00 28.57 C
+ATOM 1531 CG2 VAL A 196 2.359 1.612 24.408 1.00 30.85 C
+ATOM 1532 N ASP A 197 1.172 5.841 25.570 1.00 27.86 N
+ATOM 1533 CA ASP A 197 0.859 7.059 26.332 1.00 29.20 C
+ATOM 1534 C ASP A 197 -0.481 7.669 25.910 1.00 27.99 C
+ATOM 1535 O ASP A 197 -1.234 8.124 26.785 1.00 28.16 O
+ATOM 1536 CB ASP A 197 1.974 8.097 26.283 1.00 30.75 C
+ATOM 1537 CG ASP A 197 3.205 7.718 27.067 1.00 34.36 C
+ATOM 1538 OD1 ASP A 197 3.367 6.541 27.473 1.00 36.78 O
+ATOM 1539 OD2 ASP A 197 4.042 8.632 27.279 1.00 36.96 O
+ATOM 1540 N LEU A 198 -0.740 7.697 24.618 1.00 26.89 N
+ATOM 1541 CA LEU A 198 -1.963 8.264 24.071 1.00 25.62 C
+ATOM 1542 C LEU A 198 -3.167 7.496 24.579 1.00 26.96 C
+ATOM 1543 O LEU A 198 -4.227 8.075 24.769 1.00 27.75 O
+ATOM 1544 CB LEU A 198 -1.889 8.249 22.546 1.00 24.76 C
+ATOM 1545 CG LEU A 198 -1.091 9.338 21.871 1.00 20.72 C
+ATOM 1546 CD1 LEU A 198 -1.042 9.031 20.374 1.00 21.29 C
+ATOM 1547 CD2 LEU A 198 -1.788 10.666 22.159 1.00 19.30 C
+ATOM 1548 N ILE A 199 -2.946 6.207 24.725 1.00 28.75 N
+ATOM 1549 CA ILE A 199 -4.016 5.302 25.198 1.00 31.00 C
+ATOM 1550 C ILE A 199 -4.246 5.443 26.703 1.00 32.60 C
+ATOM 1551 O ILE A 199 -5.404 5.441 27.156 1.00 33.34 O
+ATOM 1552 CB ILE A 199 -3.624 3.840 24.777 1.00 32.03 C
+ATOM 1553 CG1 ILE A 199 -3.386 3.838 23.244 1.00 31.80 C
+ATOM 1554 CG2 ILE A 199 -4.671 2.805 25.245 1.00 32.21 C
+ATOM 1555 CD1 ILE A 199 -3.231 2.407 22.654 1.00 34.62 C
+ATOM 1556 N LYS A 200 -3.156 5.563 27.428 1.00 32.95 N
+ATOM 1557 CA LYS A 200 -3.099 5.709 28.869 1.00 34.49 C
+ATOM 1558 C LYS A 200 -3.576 7.075 29.385 1.00 35.37 C
+ATOM 1559 O LYS A 200 -3.944 7.154 30.598 1.00 36.61 O
+ATOM 1560 CB LYS A 200 -1.688 5.518 29.400 1.00 34.42 C
+ATOM 1561 CG LYS A 200 -1.251 4.111 29.709 1.00 34.83 C
+ATOM 1562 CD LYS A 200 0.222 3.999 29.985 1.00 36.40 C
+ATOM 1563 CE LYS A 200 0.875 5.151 30.695 1.00 38.27 C
+ATOM 1564 NZ LYS A 200 1.234 6.247 29.770 1.00 39.07 N
+ATOM 1565 N ASN A 201 -3.511 8.095 28.541 1.00 33.28 N
+ATOM 1566 CA ASN A 201 -3.954 9.434 28.929 1.00 31.71 C
+ATOM 1567 C ASN A 201 -5.329 9.714 28.315 1.00 31.85 C
+ATOM 1568 O ASN A 201 -5.693 10.873 28.121 1.00 32.42 O
+ATOM 1569 CB ASN A 201 -2.940 10.492 28.588 1.00 33.08 C
+ATOM 1570 CG ASN A 201 -1.599 10.236 29.245 1.00 34.56 C
+ATOM 1571 OD1 ASN A 201 -0.557 10.587 28.658 1.00 36.93 O
+ATOM 1572 ND2 ASN A 201 -1.611 9.647 30.435 1.00 35.19 N
+ATOM 1573 N LYS A 202 -6.023 8.640 28.032 1.00 31.55 N
+ATOM 1574 CA LYS A 202 -7.358 8.581 27.485 1.00 30.72 C
+ATOM 1575 C LYS A 202 -7.535 9.448 26.257 1.00 30.36 C
+ATOM 1576 O LYS A 202 -8.656 9.857 25.924 1.00 30.83 O
+ATOM 1577 CB LYS A 202 -8.404 8.956 28.534 1.00 32.53 C
+ATOM 1578 CG LYS A 202 -8.278 8.086 29.812 1.00 33.69 C
+ATOM 1579 CD LYS A 202 -8.577 6.645 29.435 1.00 37.91 C
+ATOM 1580 CE LYS A 202 -9.331 5.894 30.523 1.00 40.01 C
+ATOM 1581 NZ LYS A 202 -8.364 5.661 31.647 1.00 42.98 N
+ATOM 1582 N HIS A 203 -6.439 9.697 25.583 1.00 30.55 N
+ATOM 1583 CA HIS A 203 -6.427 10.477 24.336 1.00 31.62 C
+ATOM 1584 C HIS A 203 -6.809 9.533 23.166 1.00 32.69 C
+ATOM 1585 O HIS A 203 -7.081 10.041 22.072 1.00 33.13 O
+ATOM 1586 CB HIS A 203 -5.115 11.106 23.941 1.00 29.56 C
+ATOM 1587 CG HIS A 203 -4.630 12.215 24.777 1.00 26.95 C
+ATOM 1588 ND1 HIS A 203 -3.382 12.215 25.362 1.00 26.33 N
+ATOM 1589 CD2 HIS A 203 -5.224 13.390 25.067 1.00 25.63 C
+ATOM 1590 CE1 HIS A 203 -3.227 13.379 25.990 1.00 27.28 C
+ATOM 1591 NE2 HIS A 203 -4.315 14.111 25.804 1.00 27.09 N
+ATOM 1592 N MET A 204 -6.771 8.264 23.481 1.00 33.08 N
+ATOM 1593 CA MET A 204 -7.097 7.160 22.601 1.00 33.32 C
+ATOM 1594 C MET A 204 -7.526 5.936 23.444 1.00 32.00 C
+ATOM 1595 O MET A 204 -7.058 5.696 24.544 1.00 31.74 O
+ATOM 1596 CB MET A 204 -5.969 6.792 21.641 1.00 33.49 C
+ATOM 1597 CG MET A 204 -5.822 7.815 20.541 1.00 35.88 C
+ATOM 1598 SD MET A 204 -5.375 6.886 19.031 1.00 37.26 S
+ATOM 1599 CE MET A 204 -6.970 6.076 18.716 1.00 34.49 C
+ATOM 1600 N ASN A 205 -8.413 5.206 22.844 1.00 32.57 N
+ATOM 1601 CA ASN A 205 -9.087 3.999 23.218 1.00 32.56 C
+ATOM 1602 C ASN A 205 -8.361 2.795 22.596 1.00 32.69 C
+ATOM 1603 O ASN A 205 -8.194 2.786 21.362 1.00 31.45 O
+ATOM 1604 CB ASN A 205 -10.522 4.043 22.653 1.00 35.14 C
+ATOM 1605 CG ASN A 205 -11.458 3.312 23.596 1.00 37.58 C
+ATOM 1606 OD1 ASN A 205 -11.329 3.636 24.790 1.00 39.83 O
+ATOM 1607 ND2 ASN A 205 -12.305 2.414 23.100 1.00 39.00 N
+ATOM 1608 N ALA A 206 -8.046 1.830 23.438 1.00 31.25 N
+ATOM 1609 CA ALA A 206 -7.327 0.637 23.009 1.00 30.63 C
+ATOM 1610 C ALA A 206 -8.078 -0.274 22.077 1.00 31.07 C
+ATOM 1611 O ALA A 206 -7.374 -1.014 21.333 1.00 31.41 O
+ATOM 1612 CB ALA A 206 -6.732 -0.090 24.197 1.00 29.26 C
+ATOM 1613 N ASP A 207 -9.397 -0.275 22.033 1.00 31.44 N
+ATOM 1614 CA ASP A 207 -10.088 -1.201 21.108 1.00 31.89 C
+ATOM 1615 C ASP A 207 -10.685 -0.527 19.881 1.00 29.98 C
+ATOM 1616 O ASP A 207 -11.599 -1.116 19.263 1.00 29.00 O
+ATOM 1617 CB ASP A 207 -11.054 -2.123 21.809 1.00 35.00 C
+ATOM 1618 CG ASP A 207 -12.034 -1.467 22.742 1.00 38.32 C
+ATOM 1619 OD1 ASP A 207 -12.435 -0.310 22.530 1.00 40.71 O
+ATOM 1620 OD2 ASP A 207 -12.387 -2.194 23.720 1.00 40.37 O
+ATOM 1621 N THR A 208 -10.143 0.638 19.566 1.00 28.49 N
+ATOM 1622 CA THR A 208 -10.637 1.366 18.367 1.00 27.03 C
+ATOM 1623 C THR A 208 -10.235 0.550 17.141 1.00 25.99 C
+ATOM 1624 O THR A 208 -9.016 0.356 16.971 1.00 26.08 O
+ATOM 1625 CB THR A 208 -10.063 2.823 18.288 1.00 26.57 C
+ATOM 1626 OG1 THR A 208 -10.670 3.564 19.407 1.00 28.02 O
+ATOM 1627 CG2 THR A 208 -10.391 3.497 16.962 1.00 26.08 C
+ATOM 1628 N ASP A 209 -11.208 0.093 16.401 1.00 24.85 N
+ATOM 1629 CA ASP A 209 -10.951 -0.706 15.193 1.00 24.65 C
+ATOM 1630 C ASP A 209 -11.263 0.166 13.960 1.00 24.64 C
+ATOM 1631 O ASP A 209 -11.597 1.357 14.056 1.00 25.57 O
+ATOM 1632 CB ASP A 209 -11.664 -2.031 15.227 1.00 23.15 C
+ATOM 1633 CG ASP A 209 -13.154 -1.996 15.292 1.00 24.37 C
+ATOM 1634 OD1 ASP A 209 -13.746 -0.950 14.921 1.00 27.19 O
+ATOM 1635 OD2 ASP A 209 -13.836 -2.960 15.695 1.00 25.22 O
+ATOM 1636 N TYR A 210 -11.128 -0.454 12.798 1.00 24.32 N
+ATOM 1637 CA TYR A 210 -11.367 0.196 11.529 1.00 22.49 C
+ATOM 1638 C TYR A 210 -12.742 0.864 11.485 1.00 22.44 C
+ATOM 1639 O TYR A 210 -12.879 2.046 11.161 1.00 22.32 O
+ATOM 1640 CB TYR A 210 -11.317 -0.829 10.368 1.00 21.66 C
+ATOM 1641 CG TYR A 210 -11.381 -0.105 9.023 1.00 21.29 C
+ATOM 1642 CD1 TYR A 210 -12.568 0.247 8.405 1.00 21.35 C
+ATOM 1643 CD2 TYR A 210 -10.172 0.233 8.405 1.00 22.18 C
+ATOM 1644 CE1 TYR A 210 -12.575 0.903 7.187 1.00 23.02 C
+ATOM 1645 CE2 TYR A 210 -10.160 0.906 7.190 1.00 25.03 C
+ATOM 1646 CZ TYR A 210 -11.367 1.227 6.594 1.00 23.90 C
+ATOM 1647 OH TYR A 210 -11.280 1.888 5.386 1.00 27.32 O
+ATOM 1648 N SER A 211 -13.746 0.041 11.738 1.00 24.24 N
+ATOM 1649 CA SER A 211 -15.122 0.529 11.674 1.00 26.52 C
+ATOM 1650 C SER A 211 -15.425 1.593 12.705 1.00 27.31 C
+ATOM 1651 O SER A 211 -16.319 2.416 12.404 1.00 29.16 O
+ATOM 1652 CB SER A 211 -16.187 -0.533 11.663 1.00 29.43 C
+ATOM 1653 OG SER A 211 -15.819 -1.737 12.283 1.00 34.72 O
+ATOM 1654 N ILE A 212 -14.761 1.583 13.848 1.00 27.82 N
+ATOM 1655 CA ILE A 212 -15.014 2.583 14.888 1.00 25.38 C
+ATOM 1656 C ILE A 212 -14.391 3.909 14.494 1.00 25.15 C
+ATOM 1657 O ILE A 212 -15.108 4.902 14.688 1.00 26.86 O
+ATOM 1658 CB ILE A 212 -14.585 2.153 16.314 1.00 26.69 C
+ATOM 1659 CG1 ILE A 212 -15.495 0.991 16.812 1.00 26.82 C
+ATOM 1660 CG2 ILE A 212 -14.571 3.306 17.354 1.00 25.07 C
+ATOM 1661 CD1 ILE A 212 -14.827 0.319 18.070 1.00 27.19 C
+ATOM 1662 N ALA A 213 -13.166 3.911 14.019 1.00 23.46 N
+ATOM 1663 CA ALA A 213 -12.505 5.151 13.608 1.00 22.01 C
+ATOM 1664 C ALA A 213 -13.177 5.774 12.398 1.00 23.40 C
+ATOM 1665 O ALA A 213 -13.150 7.014 12.212 1.00 24.05 O
+ATOM 1666 CB ALA A 213 -11.037 4.881 13.413 1.00 21.49 C
+ATOM 1667 N GLU A 214 -13.796 4.973 11.554 1.00 23.80 N
+ATOM 1668 CA GLU A 214 -14.475 5.451 10.341 1.00 25.14 C
+ATOM 1669 C GLU A 214 -15.782 6.144 10.662 1.00 25.18 C
+ATOM 1670 O GLU A 214 -16.066 7.272 10.223 1.00 25.64 O
+ATOM 1671 CB GLU A 214 -14.759 4.311 9.371 1.00 26.04 C
+ATOM 1672 CG GLU A 214 -15.609 4.623 8.164 1.00 28.91 C
+ATOM 1673 CD GLU A 214 -15.530 3.656 7.017 1.00 30.85 C
+ATOM 1674 OE1 GLU A 214 -16.162 2.624 6.914 1.00 30.01 O
+ATOM 1675 OE2 GLU A 214 -14.729 4.079 6.140 1.00 33.40 O
+ATOM 1676 N ALA A 215 -16.579 5.468 11.467 1.00 25.47 N
+ATOM 1677 CA ALA A 215 -17.879 5.987 11.938 1.00 25.57 C
+ATOM 1678 C ALA A 215 -17.680 7.363 12.586 1.00 24.86 C
+ATOM 1679 O ALA A 215 -18.375 8.329 12.206 1.00 24.88 O
+ATOM 1680 CB ALA A 215 -18.517 4.988 12.893 1.00 25.48 C
+ATOM 1681 N ALA A 216 -16.737 7.448 13.510 1.00 23.97 N
+ATOM 1682 CA ALA A 216 -16.372 8.643 14.229 1.00 23.95 C
+ATOM 1683 C ALA A 216 -15.964 9.804 13.338 1.00 24.73 C
+ATOM 1684 O ALA A 216 -16.477 10.928 13.548 1.00 24.72 O
+ATOM 1685 CB ALA A 216 -15.240 8.389 15.246 1.00 22.50 C
+ATOM 1686 N PHE A 217 -15.045 9.585 12.378 1.00 24.44 N
+ATOM 1687 CA PHE A 217 -14.559 10.691 11.530 1.00 22.40 C
+ATOM 1688 C PHE A 217 -15.699 11.256 10.671 1.00 22.37 C
+ATOM 1689 O PHE A 217 -15.835 12.470 10.523 1.00 21.49 O
+ATOM 1690 CB PHE A 217 -13.371 10.302 10.614 1.00 19.96 C
+ATOM 1691 CG PHE A 217 -12.945 11.468 9.759 1.00 16.77 C
+ATOM 1692 CD1 PHE A 217 -12.084 12.443 10.249 1.00 14.42 C
+ATOM 1693 CD2 PHE A 217 -13.414 11.589 8.438 1.00 17.44 C
+ATOM 1694 CE1 PHE A 217 -11.697 13.513 9.453 1.00 13.89 C
+ATOM 1695 CE2 PHE A 217 -13.064 12.686 7.647 1.00 15.55 C
+ATOM 1696 CZ PHE A 217 -12.191 13.652 8.157 1.00 14.45 C
+ATOM 1697 N ASN A 218 -16.400 10.277 10.140 1.00 23.07 N
+ATOM 1698 CA ASN A 218 -17.489 10.408 9.207 1.00 24.43 C
+ATOM 1699 C ASN A 218 -18.768 11.017 9.732 1.00 26.44 C
+ATOM 1700 O ASN A 218 -19.603 11.541 8.932 1.00 26.59 O
+ATOM 1701 CB ASN A 218 -17.739 9.065 8.505 1.00 24.68 C
+ATOM 1702 CG ASN A 218 -16.695 8.755 7.452 1.00 23.54 C
+ATOM 1703 OD1 ASN A 218 -16.884 7.758 6.736 1.00 26.05 O
+ATOM 1704 ND2 ASN A 218 -15.621 9.517 7.370 1.00 24.10 N
+ATOM 1705 N LYS A 219 -18.913 10.894 11.042 1.00 27.30 N
+ATOM 1706 CA LYS A 219 -20.136 11.491 11.643 1.00 27.50 C
+ATOM 1707 C LYS A 219 -19.758 12.878 12.139 1.00 27.07 C
+ATOM 1708 O LYS A 219 -20.628 13.649 12.566 1.00 29.30 O
+ATOM 1709 CB LYS A 219 -20.703 10.573 12.703 1.00 27.34 C
+ATOM 1710 CG LYS A 219 -21.391 9.343 12.103 1.00 28.54 C
+ATOM 1711 CD LYS A 219 -22.184 8.534 13.087 1.00 29.88 C
+ATOM 1712 CE LYS A 219 -21.520 8.289 14.417 1.00 32.34 C
+ATOM 1713 NZ LYS A 219 -22.227 7.221 15.172 1.00 33.26 N
+ATOM 1714 N GLY A 220 -18.490 13.208 12.074 1.00 25.77 N
+ATOM 1715 CA GLY A 220 -17.955 14.472 12.514 1.00 27.47 C
+ATOM 1716 C GLY A 220 -17.480 14.521 13.958 1.00 28.54 C
+ATOM 1717 O GLY A 220 -16.952 15.579 14.408 1.00 30.21 O
+ATOM 1718 N GLU A 221 -17.570 13.451 14.704 1.00 27.74 N
+ATOM 1719 CA GLU A 221 -17.151 13.352 16.099 1.00 27.58 C
+ATOM 1720 C GLU A 221 -15.678 13.566 16.307 1.00 26.27 C
+ATOM 1721 O GLU A 221 -15.246 14.341 17.198 1.00 27.11 O
+ATOM 1722 CB GLU A 221 -17.599 12.003 16.647 1.00 29.90 C
+ATOM 1723 CG GLU A 221 -19.019 11.550 16.246 1.00 34.03 C
+ATOM 1724 CD GLU A 221 -19.334 10.173 16.745 1.00 37.33 C
+ATOM 1725 OE1 GLU A 221 -18.435 9.458 17.197 1.00 39.48 O
+ATOM 1726 OE2 GLU A 221 -20.526 9.803 16.681 1.00 39.14 O
+ATOM 1727 N THR A 222 -14.808 12.949 15.532 1.00 24.67 N
+ATOM 1728 CA THR A 222 -13.353 13.157 15.702 1.00 22.28 C
+ATOM 1729 C THR A 222 -12.822 14.066 14.607 1.00 22.03 C
+ATOM 1730 O THR A 222 -13.411 14.133 13.494 1.00 22.47 O
+ATOM 1731 CB THR A 222 -12.613 11.780 15.824 1.00 20.30 C
+ATOM 1732 OG1 THR A 222 -11.248 12.149 16.128 1.00 22.09 O
+ATOM 1733 CG2 THR A 222 -12.659 10.894 14.589 1.00 21.95 C
+ATOM 1734 N ALA A 223 -11.720 14.765 14.853 1.00 21.18 N
+ATOM 1735 CA ALA A 223 -11.162 15.687 13.882 1.00 22.46 C
+ATOM 1736 C ALA A 223 -10.109 15.161 12.923 1.00 23.87 C
+ATOM 1737 O ALA A 223 -9.770 15.894 11.957 1.00 23.59 O
+ATOM 1738 CB ALA A 223 -10.644 16.924 14.605 1.00 21.76 C
+ATOM 1739 N MET A 224 -9.522 13.998 13.118 1.00 22.90 N
+ATOM 1740 CA MET A 224 -8.484 13.449 12.225 1.00 19.53 C
+ATOM 1741 C MET A 224 -8.769 11.965 12.141 1.00 19.45 C
+ATOM 1742 O MET A 224 -9.636 11.470 12.880 1.00 19.60 O
+ATOM 1743 CB MET A 224 -7.064 13.706 12.669 1.00 18.38 C
+ATOM 1744 CG MET A 224 -6.852 15.178 12.799 1.00 17.65 C
+ATOM 1745 SD MET A 224 -5.127 15.581 13.006 1.00 20.98 S
+ATOM 1746 CE MET A 224 -4.845 15.295 14.756 1.00 22.62 C
+ATOM 1747 N THR A 225 -8.050 11.343 11.240 1.00 18.15 N
+ATOM 1748 CA THR A 225 -8.108 9.889 11.010 1.00 16.05 C
+ATOM 1749 C THR A 225 -6.876 9.536 10.185 1.00 15.19 C
+ATOM 1750 O THR A 225 -6.127 10.430 9.743 1.00 12.51 O
+ATOM 1751 CB THR A 225 -9.481 9.386 10.510 1.00 14.62 C
+ATOM 1752 OG1 THR A 225 -9.471 7.941 10.781 1.00 15.05 O
+ATOM 1753 CG2 THR A 225 -9.845 9.540 9.036 1.00 14.89 C
+ATOM 1754 N ILE A 226 -6.581 8.249 10.148 1.00 17.12 N
+ATOM 1755 CA ILE A 226 -5.439 7.721 9.345 1.00 13.71 C
+ATOM 1756 C ILE A 226 -6.078 6.654 8.470 1.00 14.71 C
+ATOM 1757 O ILE A 226 -6.696 5.691 8.955 1.00 13.44 O
+ATOM 1758 CB ILE A 226 -4.214 7.337 10.174 1.00 15.14 C
+ATOM 1759 CG1 ILE A 226 -3.583 8.617 10.789 1.00 13.30 C
+ATOM 1760 CG2 ILE A 226 -3.094 6.597 9.329 1.00 15.23 C
+ATOM 1761 CD1 ILE A 226 -2.387 8.372 11.735 1.00 10.85 C
+ATOM 1762 N ASN A 227 -6.015 6.929 7.135 1.00 14.50 N
+ATOM 1763 CA ASN A 227 -6.623 5.954 6.195 1.00 13.96 C
+ATOM 1764 C ASN A 227 -5.990 6.107 4.801 1.00 15.07 C
+ATOM 1765 O ASN A 227 -5.135 6.982 4.576 1.00 15.74 O
+ATOM 1766 CB ASN A 227 -8.135 6.009 6.154 1.00 15.52 C
+ATOM 1767 CG ASN A 227 -8.740 4.623 6.304 1.00 16.19 C
+ATOM 1768 OD1 ASN A 227 -8.063 3.666 5.887 1.00 17.88 O
+ATOM 1769 ND2 ASN A 227 -9.927 4.465 6.847 1.00 17.44 N
+ATOM 1770 N GLY A 228 -6.429 5.188 3.960 1.00 16.21 N
+ATOM 1771 CA GLY A 228 -5.910 5.136 2.567 1.00 14.33 C
+ATOM 1772 C GLY A 228 -6.960 5.486 1.539 1.00 12.90 C
+ATOM 1773 O GLY A 228 -8.134 5.655 1.900 1.00 12.18 O
+ATOM 1774 N PRO A 229 -6.500 5.453 0.260 1.00 12.28 N
+ATOM 1775 CA PRO A 229 -7.295 5.821 -0.895 1.00 13.91 C
+ATOM 1776 C PRO A 229 -8.600 5.116 -1.003 1.00 15.46 C
+ATOM 1777 O PRO A 229 -9.604 5.685 -1.448 1.00 19.43 O
+ATOM 1778 CB PRO A 229 -6.358 5.653 -2.069 1.00 12.55 C
+ATOM 1779 CG PRO A 229 -5.000 5.926 -1.481 1.00 11.26 C
+ATOM 1780 CD PRO A 229 -5.104 5.246 -0.133 1.00 11.72 C
+ATOM 1781 N TRP A 230 -8.603 3.877 -0.583 1.00 16.55 N
+ATOM 1782 CA TRP A 230 -9.789 3.035 -0.566 1.00 16.81 C
+ATOM 1783 C TRP A 230 -10.905 3.604 0.290 1.00 18.95 C
+ATOM 1784 O TRP A 230 -12.089 3.188 0.118 1.00 19.46 O
+ATOM 1785 CB TRP A 230 -9.333 1.623 -0.064 1.00 18.26 C
+ATOM 1786 CG TRP A 230 -8.714 1.624 1.316 1.00 14.64 C
+ATOM 1787 CD1 TRP A 230 -9.402 1.630 2.508 1.00 12.74 C
+ATOM 1788 CD2 TRP A 230 -7.313 1.619 1.641 1.00 13.03 C
+ATOM 1789 NE1 TRP A 230 -8.497 1.647 3.530 1.00 12.78 N
+ATOM 1790 CE2 TRP A 230 -7.220 1.661 3.052 1.00 11.85 C
+ATOM 1791 CE3 TRP A 230 -6.142 1.645 0.908 1.00 11.11 C
+ATOM 1792 CZ2 TRP A 230 -6.006 1.681 3.704 1.00 11.63 C
+ATOM 1793 CZ3 TRP A 230 -4.922 1.670 1.583 1.00 13.25 C
+ATOM 1794 CH2 TRP A 230 -4.833 1.696 2.975 1.00 12.50 C
+ATOM 1795 N ALA A 231 -10.589 4.457 1.252 1.00 21.02 N
+ATOM 1796 CA ALA A 231 -11.522 5.030 2.229 1.00 22.29 C
+ATOM 1797 C ALA A 231 -12.248 6.321 1.870 1.00 22.80 C
+ATOM 1798 O ALA A 231 -13.311 6.621 2.467 1.00 23.10 O
+ATOM 1799 CB ALA A 231 -10.665 5.323 3.498 1.00 23.95 C
+ATOM 1800 N TRP A 232 -11.714 7.075 0.947 1.00 22.67 N
+ATOM 1801 CA TRP A 232 -12.218 8.339 0.449 1.00 24.10 C
+ATOM 1802 C TRP A 232 -13.668 8.251 -0.011 1.00 27.02 C
+ATOM 1803 O TRP A 232 -14.503 9.151 0.252 1.00 27.81 O
+ATOM 1804 CB TRP A 232 -11.315 8.876 -0.660 1.00 21.57 C
+ATOM 1805 CG TRP A 232 -9.898 9.121 -0.312 1.00 19.58 C
+ATOM 1806 CD1 TRP A 232 -9.348 9.167 0.934 1.00 17.76 C
+ATOM 1807 CD2 TRP A 232 -8.814 9.367 -1.223 1.00 18.56 C
+ATOM 1808 NE1 TRP A 232 -8.009 9.437 0.852 1.00 19.54 N
+ATOM 1809 CE2 TRP A 232 -7.655 9.557 -0.466 1.00 18.41 C
+ATOM 1810 CE3 TRP A 232 -8.738 9.437 -2.627 1.00 21.03 C
+ATOM 1811 CZ2 TRP A 232 -6.416 9.812 -1.030 1.00 19.28 C
+ATOM 1812 CZ3 TRP A 232 -7.516 9.707 -3.204 1.00 20.05 C
+ATOM 1813 CH2 TRP A 232 -6.372 9.894 -2.434 1.00 21.63 C
+ATOM 1814 N SER A 233 -13.970 7.174 -0.708 1.00 29.21 N
+ATOM 1815 CA SER A 233 -15.306 6.974 -1.264 1.00 31.56 C
+ATOM 1816 C SER A 233 -16.425 7.090 -0.256 1.00 32.43 C
+ATOM 1817 O SER A 233 -17.558 7.495 -0.609 1.00 35.23 O
+ATOM 1818 CB SER A 233 -15.385 5.616 -1.967 1.00 32.89 C
+ATOM 1819 OG SER A 233 -16.669 5.037 -1.708 1.00 36.66 O
+ATOM 1820 N ASN A 234 -16.178 6.669 0.964 1.00 32.69 N
+ATOM 1821 CA ASN A 234 -17.169 6.683 2.042 1.00 31.22 C
+ATOM 1822 C ASN A 234 -17.303 8.058 2.703 1.00 28.97 C
+ATOM 1823 O ASN A 234 -18.393 8.288 3.241 1.00 29.70 O
+ATOM 1824 CB ASN A 234 -16.881 5.618 3.090 1.00 34.52 C
+ATOM 1825 CG ASN A 234 -17.157 4.207 2.640 1.00 35.31 C
+ATOM 1826 OD1 ASN A 234 -18.253 3.708 2.842 1.00 37.63 O
+ATOM 1827 ND2 ASN A 234 -16.126 3.609 2.053 1.00 38.52 N
+ATOM 1828 N ILE A 235 -16.260 8.827 2.727 1.00 27.53 N
+ATOM 1829 CA ILE A 235 -16.262 10.160 3.329 1.00 27.83 C
+ATOM 1830 C ILE A 235 -17.040 11.124 2.431 1.00 28.77 C
+ATOM 1831 O ILE A 235 -17.760 12.023 2.884 1.00 29.35 O
+ATOM 1832 CB ILE A 235 -14.828 10.701 3.616 1.00 25.64 C
+ATOM 1833 CG1 ILE A 235 -13.928 9.647 4.317 1.00 22.05 C
+ATOM 1834 CG2 ILE A 235 -14.887 12.020 4.452 1.00 27.13 C
+ATOM 1835 CD1 ILE A 235 -12.443 10.148 4.388 1.00 19.87 C
+ATOM 1836 N ASP A 236 -16.842 10.915 1.140 1.00 30.55 N
+ATOM 1837 CA ASP A 236 -17.573 11.771 0.152 1.00 32.87 C
+ATOM 1838 C ASP A 236 -19.064 11.653 0.518 1.00 34.87 C
+ATOM 1839 O ASP A 236 -19.749 12.639 0.839 1.00 35.75 O
+ATOM 1840 CB ASP A 236 -17.183 11.357 -1.238 1.00 32.66 C
+ATOM 1841 CG ASP A 236 -15.764 11.630 -1.657 1.00 30.77 C
+ATOM 1842 OD1 ASP A 236 -15.031 12.418 -1.047 1.00 29.91 O
+ATOM 1843 OD2 ASP A 236 -15.346 11.043 -2.671 1.00 34.13 O
+ATOM 1844 N THR A 237 -19.526 10.427 0.538 1.00 36.66 N
+ATOM 1845 CA THR A 237 -20.889 10.035 0.893 1.00 39.17 C
+ATOM 1846 C THR A 237 -21.363 10.656 2.214 1.00 41.62 C
+ATOM 1847 O THR A 237 -22.537 11.127 2.339 1.00 42.75 O
+ATOM 1848 CB THR A 237 -20.997 8.455 0.961 1.00 38.06 C
+ATOM 1849 OG1 THR A 237 -20.759 7.981 -0.391 1.00 38.65 O
+ATOM 1850 CG2 THR A 237 -22.302 7.905 1.512 1.00 37.55 C
+ATOM 1851 N SER A 238 -20.453 10.629 3.175 1.00 42.22 N
+ATOM 1852 CA SER A 238 -20.649 11.121 4.539 1.00 42.82 C
+ATOM 1853 C SER A 238 -20.849 12.635 4.549 1.00 43.52 C
+ATOM 1854 O SER A 238 -21.404 13.192 5.523 1.00 45.02 O
+ATOM 1855 CB SER A 238 -19.543 10.674 5.483 1.00 42.42 C
+ATOM 1856 OG SER A 238 -18.547 11.704 5.554 1.00 41.95 O
+ATOM 1857 N LYS A 239 -20.440 13.305 3.492 1.00 43.43 N
+ATOM 1858 CA LYS A 239 -20.593 14.743 3.277 1.00 42.09 C
+ATOM 1859 C LYS A 239 -19.703 15.633 4.108 1.00 40.67 C
+ATOM 1860 O LYS A 239 -19.958 16.858 4.135 1.00 41.13 O
+ATOM 1861 CB LYS A 239 -22.068 15.181 3.424 1.00 42.92 C
+ATOM 1862 CG LYS A 239 -22.921 14.793 2.217 1.00 44.28 C
+ATOM 1863 CD LYS A 239 -24.319 14.307 2.557 1.00 45.99 C
+ATOM 1864 CE LYS A 239 -24.939 13.471 1.445 1.00 47.02 C
+ATOM 1865 NZ LYS A 239 -26.402 13.703 1.282 1.00 45.55 N
+ATOM 1866 N VAL A 240 -18.674 15.069 4.712 1.00 38.63 N
+ATOM 1867 CA VAL A 240 -17.715 15.805 5.574 1.00 35.79 C
+ATOM 1868 C VAL A 240 -16.773 16.614 4.694 1.00 34.67 C
+ATOM 1869 O VAL A 240 -16.482 16.178 3.560 1.00 35.51 O
+ATOM 1870 CB VAL A 240 -17.035 14.832 6.570 1.00 34.77 C
+ATOM 1871 CG1 VAL A 240 -16.017 15.470 7.502 1.00 32.07 C
+ATOM 1872 CG2 VAL A 240 -18.035 14.055 7.410 1.00 34.75 C
+ATOM 1873 N ASN A 241 -16.311 17.749 5.196 1.00 32.46 N
+ATOM 1874 CA ASN A 241 -15.393 18.621 4.449 1.00 31.16 C
+ATOM 1875 C ASN A 241 -13.959 18.272 4.809 1.00 29.31 C
+ATOM 1876 O ASN A 241 -13.357 19.030 5.596 1.00 28.97 O
+ATOM 1877 CB ASN A 241 -15.733 20.088 4.637 1.00 33.51 C
+ATOM 1878 CG ASN A 241 -14.780 21.076 4.013 1.00 35.26 C
+ATOM 1879 OD1 ASN A 241 -13.830 20.734 3.283 1.00 38.09 O
+ATOM 1880 ND2 ASN A 241 -14.991 22.375 4.290 1.00 36.61 N
+ATOM 1881 N TYR A 242 -13.427 17.222 4.181 1.00 26.67 N
+ATOM 1882 CA TYR A 242 -12.054 16.801 4.534 1.00 23.46 C
+ATOM 1883 C TYR A 242 -10.939 17.215 3.623 1.00 22.31 C
+ATOM 1884 O TYR A 242 -11.160 17.574 2.462 1.00 24.37 O
+ATOM 1885 CB TYR A 242 -12.057 15.274 4.698 1.00 24.97 C
+ATOM 1886 CG TYR A 242 -12.260 14.513 3.407 1.00 25.80 C
+ATOM 1887 CD1 TYR A 242 -13.506 14.425 2.823 1.00 25.62 C
+ATOM 1888 CD2 TYR A 242 -11.181 13.859 2.790 1.00 27.21 C
+ATOM 1889 CE1 TYR A 242 -13.699 13.695 1.653 1.00 28.47 C
+ATOM 1890 CE2 TYR A 242 -11.351 13.131 1.617 1.00 28.01 C
+ATOM 1891 CZ TYR A 242 -12.624 13.057 1.052 1.00 29.42 C
+ATOM 1892 OH TYR A 242 -12.869 12.357 -0.113 1.00 29.05 O
+ATOM 1893 N GLY A 243 -9.732 17.149 4.125 1.00 19.33 N
+ATOM 1894 CA GLY A 243 -8.459 17.422 3.460 1.00 16.55 C
+ATOM 1895 C GLY A 243 -7.634 16.132 3.736 1.00 17.73 C
+ATOM 1896 O GLY A 243 -8.010 15.360 4.634 1.00 16.34 O
+ATOM 1897 N VAL A 244 -6.588 15.911 2.972 1.00 17.14 N
+ATOM 1898 CA VAL A 244 -5.667 14.768 3.072 1.00 13.16 C
+ATOM 1899 C VAL A 244 -4.272 15.350 3.029 1.00 12.52 C
+ATOM 1900 O VAL A 244 -4.034 16.070 2.026 1.00 16.66 O
+ATOM 1901 CB VAL A 244 -5.925 13.767 1.935 1.00 14.26 C
+ATOM 1902 CG1 VAL A 244 -4.923 12.608 1.983 1.00 13.70 C
+ATOM 1903 CG2 VAL A 244 -7.356 13.280 1.910 1.00 11.87 C
+ATOM 1904 N THR A 245 -3.392 15.122 3.947 1.00 10.78 N
+ATOM 1905 CA THR A 245 -2.066 15.738 3.935 1.00 10.74 C
+ATOM 1906 C THR A 245 -1.009 14.789 4.399 1.00 11.27 C
+ATOM 1907 O THR A 245 -1.322 13.612 4.714 1.00 12.26 O
+ATOM 1908 CB THR A 245 -2.217 17.036 4.847 1.00 12.71 C
+ATOM 1909 OG1 THR A 245 -0.944 17.740 4.881 1.00 17.22 O
+ATOM 1910 CG2 THR A 245 -2.762 16.655 6.223 1.00 12.17 C
+ATOM 1911 N VAL A 246 0.222 15.213 4.485 1.00 12.10 N
+ATOM 1912 CA VAL A 246 1.301 14.348 4.962 1.00 15.43 C
+ATOM 1913 C VAL A 246 1.088 13.915 6.400 1.00 16.21 C
+ATOM 1914 O VAL A 246 0.389 14.617 7.151 1.00 19.02 O
+ATOM 1915 CB VAL A 246 2.649 15.042 4.694 1.00 15.34 C
+ATOM 1916 CG1 VAL A 246 2.677 15.470 3.223 1.00 16.10 C
+ATOM 1917 CG2 VAL A 246 2.877 16.249 5.571 1.00 17.76 C
+ATOM 1918 N LEU A 247 1.692 12.814 6.772 1.00 16.20 N
+ATOM 1919 CA LEU A 247 1.631 12.288 8.146 1.00 17.15 C
+ATOM 1920 C LEU A 247 2.531 13.133 9.044 1.00 17.59 C
+ATOM 1921 O LEU A 247 3.573 13.698 8.630 1.00 18.76 O
+ATOM 1922 CB LEU A 247 1.954 10.789 8.139 1.00 14.86 C
+ATOM 1923 CG LEU A 247 0.931 9.858 7.540 1.00 14.65 C
+ATOM 1924 CD1 LEU A 247 1.487 8.434 7.418 1.00 14.71 C
+ATOM 1925 CD2 LEU A 247 -0.333 9.810 8.368 1.00 11.22 C
+ATOM 1926 N PRO A 248 2.124 13.216 10.332 1.00 15.92 N
+ATOM 1927 CA PRO A 248 2.896 14.027 11.269 1.00 14.88 C
+ATOM 1928 C PRO A 248 4.237 13.367 11.460 1.00 15.84 C
+ATOM 1929 O PRO A 248 4.362 12.168 11.170 1.00 18.13 O
+ATOM 1930 CB PRO A 248 2.019 14.114 12.484 1.00 14.08 C
+ATOM 1931 CG PRO A 248 0.788 13.312 12.267 1.00 15.19 C
+ATOM 1932 CD PRO A 248 0.936 12.601 10.928 1.00 14.52 C
+ATOM 1933 N THR A 249 5.205 14.120 11.900 1.00 16.68 N
+ATOM 1934 CA THR A 249 6.545 13.691 12.224 1.00 18.64 C
+ATOM 1935 C THR A 249 6.595 13.266 13.694 1.00 20.35 C
+ATOM 1936 O THR A 249 5.656 13.653 14.454 1.00 20.36 O
+ATOM 1937 CB THR A 249 7.594 14.813 11.928 1.00 19.91 C
+ATOM 1938 OG1 THR A 249 7.365 15.853 12.926 1.00 21.34 O
+ATOM 1939 CG2 THR A 249 7.536 15.293 10.463 1.00 18.07 C
+ATOM 1940 N PHE A 250 7.568 12.456 14.053 1.00 19.67 N
+ATOM 1941 CA PHE A 250 7.760 11.949 15.411 1.00 20.17 C
+ATOM 1942 C PHE A 250 9.248 12.133 15.703 1.00 22.47 C
+ATOM 1943 O PHE A 250 10.039 11.470 15.043 1.00 23.42 O
+ATOM 1944 CB PHE A 250 7.387 10.526 15.712 1.00 20.98 C
+ATOM 1945 CG PHE A 250 7.510 10.122 17.151 1.00 22.32 C
+ATOM 1946 CD1 PHE A 250 7.019 10.976 18.154 1.00 22.10 C
+ATOM 1947 CD2 PHE A 250 8.081 8.907 17.522 1.00 23.14 C
+ATOM 1948 CE1 PHE A 250 7.120 10.622 19.495 1.00 21.73 C
+ATOM 1949 CE2 PHE A 250 8.190 8.543 18.880 1.00 23.04 C
+ATOM 1950 CZ PHE A 250 7.690 9.405 19.850 1.00 21.82 C
+ATOM 1951 N LYS A 251 9.506 13.027 16.632 1.00 23.66 N
+ATOM 1952 CA LYS A 251 10.884 13.325 17.006 1.00 24.80 C
+ATOM 1953 C LYS A 251 11.568 14.014 15.829 1.00 25.74 C
+ATOM 1954 O LYS A 251 12.772 13.780 15.692 1.00 27.18 O
+ATOM 1955 CB LYS A 251 11.711 12.082 17.277 1.00 25.18 C
+ATOM 1956 CG LYS A 251 11.340 11.419 18.609 1.00 27.76 C
+ATOM 1957 CD LYS A 251 12.623 11.133 19.355 1.00 32.17 C
+ATOM 1958 CE LYS A 251 12.426 10.254 20.583 1.00 34.78 C
+ATOM 1959 NZ LYS A 251 13.821 9.810 20.986 1.00 39.09 N
+ATOM 1960 N GLY A 252 10.767 14.754 15.089 1.00 25.60 N
+ATOM 1961 CA GLY A 252 11.244 15.462 13.904 1.00 25.04 C
+ATOM 1962 C GLY A 252 11.524 14.536 12.727 1.00 25.94 C
+ATOM 1963 O GLY A 252 12.098 15.013 11.729 1.00 26.12 O
+ATOM 1964 N GLN A 253 11.147 13.278 12.811 1.00 25.38 N
+ATOM 1965 CA GLN A 253 11.353 12.279 11.759 1.00 25.07 C
+ATOM 1966 C GLN A 253 10.007 11.915 11.168 1.00 23.86 C
+ATOM 1967 O GLN A 253 8.992 11.737 11.858 1.00 24.81 O
+ATOM 1968 CB GLN A 253 12.093 11.040 12.280 1.00 27.82 C
+ATOM 1969 CG GLN A 253 13.546 11.336 12.704 1.00 30.48 C
+ATOM 1970 CD GLN A 253 14.417 11.563 11.493 1.00 32.21 C
+ATOM 1971 OE1 GLN A 253 14.086 11.067 10.418 1.00 35.47 O
+ATOM 1972 NE2 GLN A 253 15.497 12.309 11.624 1.00 33.33 N
+ATOM 1973 N PRO A 254 10.003 11.720 9.836 1.00 21.86 N
+ATOM 1974 CA PRO A 254 8.752 11.400 9.148 1.00 19.63 C
+ATOM 1975 C PRO A 254 8.113 10.115 9.598 1.00 17.57 C
+ATOM 1976 O PRO A 254 8.821 9.210 10.016 1.00 19.91 O
+ATOM 1977 CB PRO A 254 9.099 11.509 7.666 1.00 20.93 C
+ATOM 1978 CG PRO A 254 10.477 12.038 7.567 1.00 20.63 C
+ATOM 1979 CD PRO A 254 11.127 11.926 8.923 1.00 20.28 C
+ATOM 1980 N SER A 255 6.805 10.043 9.557 1.00 17.64 N
+ATOM 1981 CA SER A 255 6.037 8.803 9.861 1.00 19.26 C
+ATOM 1982 C SER A 255 6.367 7.876 8.652 1.00 19.88 C
+ATOM 1983 O SER A 255 6.474 8.412 7.508 1.00 19.11 O
+ATOM 1984 CB SER A 255 4.555 9.050 9.953 1.00 19.99 C
+ATOM 1985 OG SER A 255 4.090 9.646 11.133 1.00 21.40 O
+ATOM 1986 N LYS A 256 6.541 6.602 8.856 1.00 19.85 N
+ATOM 1987 CA LYS A 256 6.937 5.685 7.736 1.00 17.58 C
+ATOM 1988 C LYS A 256 5.870 4.680 7.429 1.00 15.26 C
+ATOM 1989 O LYS A 256 5.893 3.559 7.954 1.00 15.97 O
+ATOM 1990 CB LYS A 256 8.205 4.919 8.093 1.00 20.29 C
+ATOM 1991 CG LYS A 256 9.530 5.636 7.787 1.00 22.21 C
+ATOM 1992 CD LYS A 256 10.514 4.581 7.231 1.00 27.78 C
+ATOM 1993 CE LYS A 256 11.023 3.648 8.311 1.00 32.88 C
+ATOM 1994 NZ LYS A 256 11.280 2.241 7.875 1.00 32.88 N
+ATOM 1995 N PRO A 257 4.930 5.097 6.594 1.00 13.81 N
+ATOM 1996 CA PRO A 257 3.814 4.216 6.207 1.00 14.33 C
+ATOM 1997 C PRO A 257 4.367 3.120 5.271 1.00 14.73 C
+ATOM 1998 O PRO A 257 5.387 3.370 4.604 1.00 15.39 O
+ATOM 1999 CB PRO A 257 2.805 5.167 5.593 1.00 12.93 C
+ATOM 2000 CG PRO A 257 3.638 6.241 4.971 1.00 11.50 C
+ATOM 2001 CD PRO A 257 4.823 6.394 5.910 1.00 14.78 C
+ATOM 2002 N PHE A 258 3.743 1.971 5.329 1.00 14.70 N
+ATOM 2003 CA PHE A 258 4.166 0.850 4.436 1.00 17.59 C
+ATOM 2004 C PHE A 258 3.694 1.267 3.029 1.00 17.82 C
+ATOM 2005 O PHE A 258 2.653 1.968 2.983 1.00 18.43 O
+ATOM 2006 CB PHE A 258 3.484 -0.483 4.818 1.00 15.69 C
+ATOM 2007 CG PHE A 258 4.227 -1.294 5.817 1.00 17.66 C
+ATOM 2008 CD1 PHE A 258 5.538 -1.712 5.543 1.00 15.89 C
+ATOM 2009 CD2 PHE A 258 3.633 -1.618 7.050 1.00 17.82 C
+ATOM 2010 CE1 PHE A 258 6.235 -2.445 6.481 1.00 16.73 C
+ATOM 2011 CE2 PHE A 258 4.341 -2.371 7.989 1.00 14.93 C
+ATOM 2012 CZ PHE A 258 5.645 -2.780 7.700 1.00 15.63 C
+ATOM 2013 N VAL A 259 4.400 0.825 1.982 1.00 17.95 N
+ATOM 2014 CA VAL A 259 3.871 1.235 0.637 1.00 17.64 C
+ATOM 2015 C VAL A 259 3.416 -0.011 -0.137 1.00 15.92 C
+ATOM 2016 O VAL A 259 4.196 -0.977 -0.071 1.00 16.60 O
+ATOM 2017 CB VAL A 259 4.916 2.042 -0.155 1.00 17.64 C
+ATOM 2018 CG1 VAL A 259 4.404 2.494 -1.502 1.00 16.47 C
+ATOM 2019 CG2 VAL A 259 5.442 3.183 0.711 1.00 19.99 C
+ATOM 2020 N GLY A 260 2.274 0.060 -0.755 1.00 14.46 N
+ATOM 2021 CA GLY A 260 1.763 -1.070 -1.580 1.00 14.26 C
+ATOM 2022 C GLY A 260 1.779 -0.616 -3.049 1.00 13.77 C
+ATOM 2023 O GLY A 260 1.340 0.491 -3.399 1.00 12.62 O
+ATOM 2024 N VAL A 261 2.334 -1.454 -3.920 1.00 12.89 N
+ATOM 2025 CA VAL A 261 2.348 -1.101 -5.386 1.00 12.03 C
+ATOM 2026 C VAL A 261 1.482 -2.069 -6.175 1.00 10.08 C
+ATOM 2027 O VAL A 261 1.630 -3.302 -6.093 1.00 11.67 O
+ATOM 2028 CB VAL A 261 3.791 -0.985 -5.883 1.00 11.82 C
+ATOM 2029 CG1 VAL A 261 3.892 -0.568 -7.360 1.00 11.97 C
+ATOM 2030 CG2 VAL A 261 4.649 -0.037 -5.060 1.00 12.36 C
+ATOM 2031 N LEU A 262 0.496 -1.607 -6.888 1.00 10.73 N
+ATOM 2032 CA LEU A 262 -0.369 -2.475 -7.734 1.00 11.60 C
+ATOM 2033 C LEU A 262 0.650 -2.874 -8.855 1.00 12.67 C
+ATOM 2034 O LEU A 262 1.401 -1.953 -9.255 1.00 12.60 O
+ATOM 2035 CB LEU A 262 -1.513 -1.745 -8.330 1.00 11.31 C
+ATOM 2036 CG LEU A 262 -2.819 -2.401 -8.621 1.00 11.21 C
+ATOM 2037 CD1 LEU A 262 -3.385 -1.867 -9.921 1.00 11.96 C
+ATOM 2038 CD2 LEU A 262 -2.774 -3.911 -8.627 1.00 13.79 C
+ATOM 2039 N SER A 263 0.673 -4.133 -9.152 1.00 12.03 N
+ATOM 2040 CA SER A 263 1.688 -4.581 -10.162 1.00 13.64 C
+ATOM 2041 C SER A 263 1.094 -5.512 -11.172 1.00 11.71 C
+ATOM 2042 O SER A 263 0.066 -6.156 -10.888 1.00 12.82 O
+ATOM 2043 CB SER A 263 2.777 -5.281 -9.298 1.00 14.10 C
+ATOM 2044 OG SER A 263 3.348 -4.294 -8.481 1.00 15.60 O
+ATOM 2045 N ALA A 264 1.738 -5.601 -12.336 1.00 13.00 N
+ATOM 2046 CA ALA A 264 1.208 -6.544 -13.374 1.00 10.76 C
+ATOM 2047 C ALA A 264 2.356 -7.503 -13.658 1.00 9.74 C
+ATOM 2048 O ALA A 264 3.488 -7.062 -13.832 1.00 10.44 O
+ATOM 2049 CB ALA A 264 0.786 -5.758 -14.581 1.00 10.75 C
+ATOM 2050 N GLY A 265 2.087 -8.782 -13.567 1.00 11.40 N
+ATOM 2051 CA GLY A 265 3.160 -9.784 -13.781 1.00 11.30 C
+ATOM 2052 C GLY A 265 2.648 -10.697 -14.879 1.00 13.69 C
+ATOM 2053 O GLY A 265 1.440 -10.823 -15.082 1.00 14.61 O
+ATOM 2054 N ILE A 266 3.621 -11.298 -15.549 1.00 17.41 N
+ATOM 2055 CA ILE A 266 3.370 -12.220 -16.684 1.00 16.87 C
+ATOM 2056 C ILE A 266 3.606 -13.660 -16.213 1.00 15.25 C
+ATOM 2057 O ILE A 266 4.648 -13.945 -15.603 1.00 15.84 O
+ATOM 2058 CB ILE A 266 4.317 -11.825 -17.896 1.00 17.80 C
+ATOM 2059 CG1 ILE A 266 4.011 -10.392 -18.416 1.00 19.65 C
+ATOM 2060 CG2 ILE A 266 4.243 -12.825 -19.091 1.00 18.33 C
+ATOM 2061 CD1 ILE A 266 5.091 -9.795 -19.384 1.00 19.30 C
+ATOM 2062 N ASN A 267 2.652 -14.500 -16.485 1.00 15.23 N
+ATOM 2063 CA ASN A 267 2.714 -15.947 -16.162 1.00 16.74 C
+ATOM 2064 C ASN A 267 3.971 -16.512 -16.828 1.00 19.38 C
+ATOM 2065 O ASN A 267 4.275 -16.260 -18.018 1.00 18.70 O
+ATOM 2066 CB ASN A 267 1.406 -16.598 -16.623 1.00 16.44 C
+ATOM 2067 CG ASN A 267 1.177 -17.966 -16.015 1.00 16.11 C
+ATOM 2068 OD1 ASN A 267 2.178 -18.577 -15.616 1.00 17.91 O
+ATOM 2069 ND2 ASN A 267 -0.048 -18.465 -15.937 1.00 16.10 N
+ATOM 2070 N ALA A 268 4.754 -17.246 -16.063 1.00 21.48 N
+ATOM 2071 CA ALA A 268 6.017 -17.863 -16.534 1.00 22.50 C
+ATOM 2072 C ALA A 268 5.667 -18.871 -17.653 1.00 23.46 C
+ATOM 2073 O ALA A 268 6.477 -19.166 -18.553 1.00 23.67 O
+ATOM 2074 CB ALA A 268 6.748 -18.520 -15.376 1.00 21.04 C
+ATOM 2075 N ALA A 269 4.440 -19.352 -17.591 1.00 23.35 N
+ATOM 2076 CA ALA A 269 3.896 -20.305 -18.528 1.00 24.63 C
+ATOM 2077 C ALA A 269 3.319 -19.602 -19.750 1.00 27.00 C
+ATOM 2078 O ALA A 269 3.029 -20.332 -20.748 1.00 29.08 O
+ATOM 2079 CB ALA A 269 2.811 -21.173 -17.892 1.00 23.90 C
+ATOM 2080 N SER A 270 3.143 -18.268 -19.747 1.00 25.27 N
+ATOM 2081 CA SER A 270 2.560 -17.695 -20.958 1.00 23.42 C
+ATOM 2082 C SER A 270 3.483 -17.915 -22.181 1.00 22.02 C
+ATOM 2083 O SER A 270 4.701 -17.670 -22.127 1.00 21.70 O
+ATOM 2084 CB SER A 270 2.238 -16.196 -20.873 1.00 20.56 C
+ATOM 2085 N PRO A 271 2.823 -18.316 -23.242 1.00 20.92 N
+ATOM 2086 CA PRO A 271 3.475 -18.434 -24.544 1.00 23.24 C
+ATOM 2087 C PRO A 271 3.563 -17.017 -25.163 1.00 24.94 C
+ATOM 2088 O PRO A 271 4.390 -16.674 -26.049 1.00 26.14 O
+ATOM 2089 CB PRO A 271 2.529 -19.332 -25.336 1.00 22.22 C
+ATOM 2090 CG PRO A 271 1.381 -19.675 -24.448 1.00 20.68 C
+ATOM 2091 CD PRO A 271 1.396 -18.625 -23.356 1.00 20.57 C
+ATOM 2092 N ASN A 272 2.707 -16.117 -24.671 1.00 24.37 N
+ATOM 2093 CA ASN A 272 2.520 -14.745 -25.117 1.00 21.16 C
+ATOM 2094 C ASN A 272 3.316 -13.663 -24.430 1.00 20.82 C
+ATOM 2095 O ASN A 272 2.794 -12.496 -24.419 1.00 23.21 O
+ATOM 2096 CB ASN A 272 1.002 -14.409 -25.030 1.00 19.52 C
+ATOM 2097 CG ASN A 272 0.153 -15.483 -25.628 1.00 20.61 C
+ATOM 2098 OD1 ASN A 272 0.294 -15.821 -26.830 1.00 24.59 O
+ATOM 2099 ND2 ASN A 272 -0.756 -16.112 -24.915 1.00 19.74 N
+ATOM 2100 N LYS A 273 4.492 -13.932 -23.932 1.00 18.97 N
+ATOM 2101 CA LYS A 273 5.298 -12.976 -23.207 1.00 18.19 C
+ATOM 2102 C LYS A 273 5.658 -11.690 -23.901 1.00 19.71 C
+ATOM 2103 O LYS A 273 5.780 -10.614 -23.244 1.00 18.45 O
+ATOM 2104 CB LYS A 273 6.595 -13.602 -22.657 1.00 17.33 C
+ATOM 2105 CG LYS A 273 6.279 -14.761 -21.669 1.00 19.17 C
+ATOM 2106 CD LYS A 273 7.583 -15.210 -21.018 1.00 19.31 C
+ATOM 2107 CE LYS A 273 7.518 -16.454 -20.202 1.00 17.26 C
+ATOM 2108 NZ LYS A 273 6.759 -17.522 -20.874 1.00 23.40 N
+ATOM 2109 N GLU A 274 5.935 -11.765 -25.201 1.00 20.00 N
+ATOM 2110 CA GLU A 274 6.357 -10.537 -25.903 1.00 20.30 C
+ATOM 2111 C GLU A 274 5.141 -9.677 -26.175 1.00 17.23 C
+ATOM 2112 O GLU A 274 5.289 -8.452 -26.171 1.00 16.88 O
+ATOM 2113 CB GLU A 274 7.204 -10.798 -27.123 1.00 24.35 C
+ATOM 2114 CG GLU A 274 8.558 -10.078 -27.147 1.00 33.14 C
+ATOM 2115 CD GLU A 274 8.695 -8.611 -27.448 1.00 37.08 C
+ATOM 2116 OE1 GLU A 274 7.681 -7.914 -27.119 1.00 39.81 O
+ATOM 2117 OE2 GLU A 274 9.719 -8.079 -27.945 1.00 36.83 O
+ATOM 2118 N LEU A 275 4.000 -10.316 -26.340 1.00 15.50 N
+ATOM 2119 CA LEU A 275 2.725 -9.652 -26.580 1.00 15.68 C
+ATOM 2120 C LEU A 275 2.347 -8.850 -25.320 1.00 16.42 C
+ATOM 2121 O LEU A 275 1.922 -7.702 -25.399 1.00 16.07 O
+ATOM 2122 CB LEU A 275 1.624 -10.630 -26.983 1.00 15.04 C
+ATOM 2123 CG LEU A 275 1.368 -10.954 -28.461 1.00 14.34 C
+ATOM 2124 CD1 LEU A 275 0.368 -12.095 -28.594 1.00 11.91 C
+ATOM 2125 CD2 LEU A 275 0.810 -9.723 -29.155 1.00 13.34 C
+ATOM 2126 N ALA A 276 2.482 -9.526 -24.207 1.00 16.88 N
+ATOM 2127 CA ALA A 276 2.168 -8.928 -22.870 1.00 17.78 C
+ATOM 2128 C ALA A 276 3.089 -7.768 -22.572 1.00 17.51 C
+ATOM 2129 O ALA A 276 2.660 -6.696 -22.134 1.00 17.72 O
+ATOM 2130 CB ALA A 276 2.278 -10.046 -21.818 1.00 18.06 C
+ATOM 2131 N LYS A 277 4.357 -7.926 -22.820 1.00 18.58 N
+ATOM 2132 CA LYS A 277 5.386 -6.906 -22.630 1.00 19.75 C
+ATOM 2133 C LYS A 277 5.063 -5.668 -23.449 1.00 21.66 C
+ATOM 2134 O LYS A 277 5.305 -4.516 -23.066 1.00 23.23 O
+ATOM 2135 CB LYS A 277 6.758 -7.397 -23.069 1.00 20.08 C
+ATOM 2136 CG LYS A 277 7.735 -6.277 -23.455 1.00 19.92 C
+ATOM 2137 CD LYS A 277 8.994 -6.902 -24.018 1.00 22.69 C
+ATOM 2138 CE LYS A 277 10.256 -6.485 -23.355 1.00 26.39 C
+ATOM 2139 NZ LYS A 277 10.540 -5.060 -23.547 1.00 30.08 N
+ATOM 2140 N GLU A 278 4.551 -5.932 -24.633 1.00 23.12 N
+ATOM 2141 CA GLU A 278 4.191 -4.863 -25.585 1.00 23.20 C
+ATOM 2142 C GLU A 278 2.963 -4.111 -25.069 1.00 21.26 C
+ATOM 2143 O GLU A 278 2.886 -2.878 -25.057 1.00 19.80 O
+ATOM 2144 CB GLU A 278 3.877 -5.484 -26.964 1.00 24.73 C
+ATOM 2145 CG GLU A 278 3.666 -4.501 -28.115 1.00 27.52 C
+ATOM 2146 CD GLU A 278 4.753 -3.541 -28.454 1.00 26.92 C
+ATOM 2147 OE1 GLU A 278 5.960 -3.587 -28.310 1.00 28.50 O
+ATOM 2148 OE2 GLU A 278 4.222 -2.528 -28.969 1.00 29.23 O
+ATOM 2149 N PHE A 279 1.963 -4.894 -24.684 1.00 19.50 N
+ATOM 2150 CA PHE A 279 0.717 -4.323 -24.196 1.00 19.36 C
+ATOM 2151 C PHE A 279 0.939 -3.514 -22.918 1.00 20.23 C
+ATOM 2152 O PHE A 279 0.309 -2.449 -22.819 1.00 22.13 O
+ATOM 2153 CB PHE A 279 -0.399 -5.311 -24.076 1.00 20.68 C
+ATOM 2154 CG PHE A 279 -1.611 -4.857 -23.315 1.00 20.47 C
+ATOM 2155 CD1 PHE A 279 -1.564 -4.746 -21.913 1.00 21.68 C
+ATOM 2156 CD2 PHE A 279 -2.809 -4.614 -23.973 1.00 20.90 C
+ATOM 2157 CE1 PHE A 279 -2.683 -4.350 -21.216 1.00 20.68 C
+ATOM 2158 CE2 PHE A 279 -3.962 -4.234 -23.297 1.00 22.63 C
+ATOM 2159 CZ PHE A 279 -3.882 -4.091 -21.883 1.00 22.26 C
+ATOM 2160 N LEU A 280 1.754 -3.968 -22.009 1.00 20.09 N
+ATOM 2161 CA LEU A 280 2.027 -3.274 -20.754 1.00 19.67 C
+ATOM 2162 C LEU A 280 2.863 -2.028 -20.948 1.00 20.56 C
+ATOM 2163 O LEU A 280 2.430 -0.910 -20.620 1.00 21.29 O
+ATOM 2164 CB LEU A 280 2.675 -4.255 -19.763 1.00 17.12 C
+ATOM 2165 CG LEU A 280 1.796 -5.377 -19.234 1.00 16.58 C
+ATOM 2166 CD1 LEU A 280 2.609 -6.412 -18.477 1.00 15.34 C
+ATOM 2167 CD2 LEU A 280 0.740 -4.746 -18.364 1.00 16.01 C
+ATOM 2168 N GLU A 281 4.082 -2.213 -21.434 1.00 20.76 N
+ATOM 2169 CA GLU A 281 4.949 -1.045 -21.619 1.00 21.81 C
+ATOM 2170 C GLU A 281 4.430 0.013 -22.569 1.00 21.97 C
+ATOM 2171 O GLU A 281 4.754 1.205 -22.348 1.00 21.75 O
+ATOM 2172 CB GLU A 281 6.357 -1.438 -22.071 1.00 21.73 C
+ATOM 2173 CG GLU A 281 7.018 -2.645 -21.403 1.00 22.85 C
+ATOM 2174 CD GLU A 281 8.501 -2.704 -21.639 1.00 22.93 C
+ATOM 2175 OE1 GLU A 281 9.043 -2.064 -22.542 1.00 26.40 O
+ATOM 2176 OE2 GLU A 281 9.145 -3.401 -20.857 1.00 20.85 O
+ATOM 2177 N ASN A 282 3.683 -0.353 -23.613 1.00 22.72 N
+ATOM 2178 CA ASN A 282 3.227 0.628 -24.603 1.00 23.17 C
+ATOM 2179 C ASN A 282 1.735 0.828 -24.712 1.00 22.39 C
+ATOM 2180 O ASN A 282 1.350 1.748 -25.510 1.00 24.47 O
+ATOM 2181 CB ASN A 282 3.866 0.402 -25.989 1.00 23.82 C
+ATOM 2182 CG ASN A 282 5.346 0.401 -26.064 1.00 23.76 C
+ATOM 2183 OD1 ASN A 282 6.132 1.253 -25.629 1.00 26.19 O
+ATOM 2184 ND2 ASN A 282 5.883 -0.653 -26.722 1.00 28.58 N
+ATOM 2185 N TYR A 283 0.900 0.103 -24.022 1.00 20.54 N
+ATOM 2186 CA TYR A 283 -0.524 0.401 -24.168 1.00 20.22 C
+ATOM 2187 C TYR A 283 -1.122 0.897 -22.847 1.00 19.88 C
+ATOM 2188 O TYR A 283 -1.881 1.887 -22.801 1.00 18.95 O
+ATOM 2189 CB TYR A 283 -1.305 -0.801 -24.714 1.00 21.79 C
+ATOM 2190 CG TYR A 283 -1.212 -0.848 -26.235 1.00 21.89 C
+ATOM 2191 CD1 TYR A 283 0.021 -0.998 -26.857 1.00 22.35 C
+ATOM 2192 CD2 TYR A 283 -2.364 -0.737 -26.989 1.00 22.34 C
+ATOM 2193 CE1 TYR A 283 0.112 -1.016 -28.244 1.00 23.35 C
+ATOM 2194 CE2 TYR A 283 -2.297 -0.764 -28.385 1.00 24.86 C
+ATOM 2195 CZ TYR A 283 -1.058 -0.927 -28.987 1.00 24.68 C
+ATOM 2196 OH TYR A 283 -1.051 -0.992 -30.360 1.00 26.20 O
+ATOM 2197 N LEU A 284 -0.764 0.139 -21.812 1.00 18.95 N
+ATOM 2198 CA LEU A 284 -1.245 0.466 -20.458 1.00 17.72 C
+ATOM 2199 C LEU A 284 -0.376 1.524 -19.810 1.00 15.66 C
+ATOM 2200 O LEU A 284 -0.878 2.558 -19.313 1.00 17.59 O
+ATOM 2201 CB LEU A 284 -1.395 -0.867 -19.693 1.00 17.63 C
+ATOM 2202 CG LEU A 284 -1.898 -0.691 -18.260 1.00 20.12 C
+ATOM 2203 CD1 LEU A 284 -3.411 -0.440 -18.236 1.00 19.43 C
+ATOM 2204 CD2 LEU A 284 -1.537 -1.871 -17.368 1.00 18.31 C
+ATOM 2205 N LEU A 285 0.911 1.366 -19.780 1.00 15.19 N
+ATOM 2206 CA LEU A 285 1.813 2.303 -19.115 1.00 15.36 C
+ATOM 2207 C LEU A 285 2.082 3.576 -19.896 1.00 16.28 C
+ATOM 2208 O LEU A 285 3.242 4.004 -20.056 1.00 17.20 O
+ATOM 2209 CB LEU A 285 3.000 1.548 -18.590 1.00 17.16 C
+ATOM 2210 CG LEU A 285 3.194 0.923 -17.235 1.00 18.94 C
+ATOM 2211 CD1 LEU A 285 2.654 1.827 -16.114 1.00 17.82 C
+ATOM 2212 CD2 LEU A 285 2.580 -0.462 -17.149 1.00 18.88 C
+ATOM 2213 N THR A 286 1.025 4.244 -20.267 1.00 18.49 N
+ATOM 2214 CA THR A 286 1.013 5.535 -21.009 1.00 19.60 C
+ATOM 2215 C THR A 286 -0.079 6.417 -20.396 1.00 19.36 C
+ATOM 2216 O THR A 286 -0.986 5.879 -19.735 1.00 19.98 O
+ATOM 2217 CB THR A 286 0.673 5.296 -22.550 1.00 18.53 C
+ATOM 2218 OG1 THR A 286 -0.691 4.761 -22.672 1.00 17.61 O
+ATOM 2219 CG2 THR A 286 1.685 4.370 -23.249 1.00 19.97 C
+ATOM 2220 N ASP A 287 -0.079 7.688 -20.721 1.00 21.25 N
+ATOM 2221 CA ASP A 287 -1.101 8.636 -20.225 1.00 20.75 C
+ATOM 2222 C ASP A 287 -2.484 8.230 -20.652 1.00 21.31 C
+ATOM 2223 O ASP A 287 -3.424 8.187 -19.838 1.00 22.41 O
+ATOM 2224 CB ASP A 287 -0.709 10.053 -20.578 1.00 22.22 C
+ATOM 2225 CG ASP A 287 0.567 10.508 -19.947 1.00 25.11 C
+ATOM 2226 OD1 ASP A 287 0.693 10.444 -18.716 1.00 29.71 O
+ATOM 2227 OD2 ASP A 287 1.502 10.979 -20.621 1.00 28.59 O
+ATOM 2228 N GLU A 288 -2.693 7.907 -21.916 1.00 22.87 N
+ATOM 2229 CA GLU A 288 -3.996 7.501 -22.439 1.00 22.93 C
+ATOM 2230 C GLU A 288 -4.479 6.193 -21.828 1.00 21.32 C
+ATOM 2231 O GLU A 288 -5.697 5.929 -21.741 1.00 22.02 O
+ATOM 2232 CB GLU A 288 -4.026 7.333 -23.965 1.00 26.51 C
+ATOM 2233 CG GLU A 288 -2.847 7.754 -24.811 1.00 32.43 C
+ATOM 2234 CD GLU A 288 -1.761 6.725 -24.994 1.00 37.33 C
+ATOM 2235 OE1 GLU A 288 -1.962 5.548 -25.299 1.00 39.72 O
+ATOM 2236 OE2 GLU A 288 -0.591 7.187 -24.819 1.00 38.82 O
+ATOM 2237 N GLY A 289 -3.568 5.353 -21.433 1.00 21.34 N
+ATOM 2238 CA GLY A 289 -3.809 4.039 -20.827 1.00 19.83 C
+ATOM 2239 C GLY A 289 -4.227 4.133 -19.356 1.00 18.01 C
+ATOM 2240 O GLY A 289 -5.270 3.588 -19.017 1.00 19.76 O
+ATOM 2241 N LEU A 290 -3.440 4.753 -18.520 1.00 19.61 N
+ATOM 2242 CA LEU A 290 -3.750 4.933 -17.077 1.00 18.68 C
+ATOM 2243 C LEU A 290 -5.011 5.772 -16.976 1.00 21.51 C
+ATOM 2244 O LEU A 290 -5.868 5.602 -16.098 1.00 22.58 O
+ATOM 2245 CB LEU A 290 -2.516 5.494 -16.381 1.00 18.13 C
+ATOM 2246 CG LEU A 290 -1.275 4.620 -16.278 1.00 17.93 C
+ATOM 2247 CD1 LEU A 290 -0.148 5.270 -15.525 1.00 16.48 C
+ATOM 2248 CD2 LEU A 290 -1.577 3.248 -15.666 1.00 16.74 C
+ATOM 2249 N GLU A 291 -5.218 6.670 -17.938 1.00 22.06 N
+ATOM 2250 CA GLU A 291 -6.416 7.512 -17.935 1.00 22.29 C
+ATOM 2251 C GLU A 291 -7.676 6.730 -18.187 1.00 23.60 C
+ATOM 2252 O GLU A 291 -8.747 7.021 -17.591 1.00 25.54 O
+ATOM 2253 CB GLU A 291 -6.325 8.581 -18.992 1.00 23.96 C
+ATOM 2254 CG GLU A 291 -7.583 9.406 -19.228 1.00 28.26 C
+ATOM 2255 CD GLU A 291 -7.353 10.615 -20.104 1.00 32.30 C
+ATOM 2256 OE1 GLU A 291 -6.137 10.797 -20.391 1.00 32.69 O
+ATOM 2257 OE2 GLU A 291 -8.302 11.306 -20.451 1.00 35.51 O
+ATOM 2258 N ALA A 292 -7.600 5.752 -19.073 1.00 23.64 N
+ATOM 2259 CA ALA A 292 -8.739 4.906 -19.439 1.00 23.09 C
+ATOM 2260 C ALA A 292 -9.178 3.994 -18.308 1.00 23.44 C
+ATOM 2261 O ALA A 292 -10.372 3.674 -18.257 1.00 24.37 O
+ATOM 2262 CB ALA A 292 -8.450 4.067 -20.693 1.00 22.65 C
+ATOM 2263 N VAL A 293 -8.265 3.531 -17.494 1.00 23.67 N
+ATOM 2264 CA VAL A 293 -8.620 2.639 -16.365 1.00 25.92 C
+ATOM 2265 C VAL A 293 -9.159 3.529 -15.213 1.00 26.27 C
+ATOM 2266 O VAL A 293 -10.163 3.236 -14.576 1.00 25.83 O
+ATOM 2267 CB VAL A 293 -7.390 1.826 -15.887 1.00 26.23 C
+ATOM 2268 CG1 VAL A 293 -7.748 0.872 -14.760 1.00 25.10 C
+ATOM 2269 CG2 VAL A 293 -6.651 1.092 -16.999 1.00 25.49 C
+ATOM 2270 N ASN A 294 -8.405 4.596 -15.040 1.00 27.98 N
+ATOM 2271 CA ASN A 294 -8.640 5.629 -14.018 1.00 30.01 C
+ATOM 2272 C ASN A 294 -10.039 6.207 -14.171 1.00 31.97 C
+ATOM 2273 O ASN A 294 -10.753 6.274 -13.137 1.00 34.53 O
+ATOM 2274 CB ASN A 294 -7.498 6.615 -13.957 1.00 27.56 C
+ATOM 2275 CG ASN A 294 -7.663 7.632 -12.846 1.00 28.47 C
+ATOM 2276 OD1 ASN A 294 -7.005 7.545 -11.815 1.00 27.48 O
+ATOM 2277 ND2 ASN A 294 -8.549 8.585 -13.117 1.00 29.00 N
+ATOM 2278 N LYS A 295 -10.441 6.565 -15.381 1.00 32.68 N
+ATOM 2279 CA LYS A 295 -11.806 7.099 -15.559 1.00 34.03 C
+ATOM 2280 C LYS A 295 -12.839 6.087 -15.088 1.00 33.67 C
+ATOM 2281 O LYS A 295 -13.931 6.466 -14.626 1.00 34.73 O
+ATOM 2282 CB LYS A 295 -12.082 7.463 -17.010 1.00 36.79 C
+ATOM 2283 CG LYS A 295 -11.167 8.600 -17.497 1.00 39.98 C
+ATOM 2284 CD LYS A 295 -10.948 8.531 -18.998 1.00 43.23 C
+ATOM 2285 CE LYS A 295 -12.205 8.544 -19.836 1.00 44.84 C
+ATOM 2286 NZ LYS A 295 -12.533 7.235 -20.435 1.00 44.73 N
+ATOM 2287 N ASP A 296 -12.496 4.813 -15.180 1.00 32.12 N
+ATOM 2288 CA ASP A 296 -13.408 3.736 -14.771 1.00 31.60 C
+ATOM 2289 C ASP A 296 -13.435 3.599 -13.245 1.00 31.63 C
+ATOM 2290 O ASP A 296 -14.504 3.383 -12.617 1.00 31.50 O
+ATOM 2291 CB ASP A 296 -13.061 2.434 -15.482 1.00 32.70 C
+ATOM 2292 CG ASP A 296 -13.929 1.278 -15.085 1.00 34.65 C
+ATOM 2293 OD1 ASP A 296 -15.115 1.457 -14.713 1.00 36.85 O
+ATOM 2294 OD2 ASP A 296 -13.468 0.128 -15.123 1.00 38.24 O
+ATOM 2295 N LYS A 297 -12.234 3.698 -12.704 1.00 29.92 N
+ATOM 2296 CA LYS A 297 -12.056 3.567 -11.244 1.00 29.44 C
+ATOM 2297 C LYS A 297 -10.654 4.079 -10.961 1.00 28.32 C
+ATOM 2298 O LYS A 297 -9.694 3.605 -11.569 1.00 29.21 O
+ATOM 2299 CB LYS A 297 -12.198 2.160 -10.751 1.00 32.53 C
+ATOM 2300 CG LYS A 297 -12.622 2.014 -9.292 1.00 35.88 C
+ATOM 2301 CD LYS A 297 -13.438 0.736 -9.092 1.00 39.07 C
+ATOM 2302 CE LYS A 297 -14.844 0.890 -9.624 1.00 40.87 C
+ATOM 2303 NZ LYS A 297 -15.731 -0.143 -8.994 1.00 44.40 N
+ATOM 2304 N PRO A 298 -10.633 5.054 -10.083 1.00 27.25 N
+ATOM 2305 CA PRO A 298 -9.392 5.731 -9.694 1.00 26.06 C
+ATOM 2306 C PRO A 298 -8.367 4.741 -9.210 1.00 23.96 C
+ATOM 2307 O PRO A 298 -8.770 3.767 -8.548 1.00 24.85 O
+ATOM 2308 CB PRO A 298 -9.821 6.799 -8.701 1.00 26.45 C
+ATOM 2309 CG PRO A 298 -11.126 6.259 -8.158 1.00 27.75 C
+ATOM 2310 CD PRO A 298 -11.797 5.644 -9.382 1.00 27.51 C
+ATOM 2311 N LEU A 299 -7.131 5.015 -9.547 1.00 22.22 N
+ATOM 2312 CA LEU A 299 -5.980 4.202 -9.211 1.00 21.81 C
+ATOM 2313 C LEU A 299 -5.216 4.747 -7.996 1.00 20.82 C
+ATOM 2314 O LEU A 299 -4.405 4.038 -7.381 1.00 21.14 O
+ATOM 2315 CB LEU A 299 -5.056 4.148 -10.454 1.00 20.75 C
+ATOM 2316 CG LEU A 299 -5.503 3.413 -11.700 1.00 18.48 C
+ATOM 2317 CD1 LEU A 299 -4.505 3.655 -12.845 1.00 17.90 C
+ATOM 2318 CD2 LEU A 299 -5.586 1.921 -11.386 1.00 19.49 C
+ATOM 2319 N GLY A 300 -5.446 6.017 -7.719 1.00 19.09 N
+ATOM 2320 CA GLY A 300 -4.734 6.725 -6.650 1.00 16.88 C
+ATOM 2321 C GLY A 300 -3.553 7.392 -7.360 1.00 15.42 C
+ATOM 2322 O GLY A 300 -3.692 8.005 -8.422 1.00 16.79 O
+ATOM 2323 N ALA A 301 -2.404 7.251 -6.750 1.00 14.96 N
+ATOM 2324 CA ALA A 301 -1.144 7.776 -7.270 1.00 13.95 C
+ATOM 2325 C ALA A 301 -0.658 6.652 -8.215 1.00 13.92 C
+ATOM 2326 O ALA A 301 -0.881 5.478 -7.868 1.00 11.96 O
+ATOM 2327 CB ALA A 301 -0.184 8.047 -6.142 1.00 14.63 C
+ATOM 2328 N VAL A 302 -0.091 7.082 -9.337 1.00 14.82 N
+ATOM 2329 CA VAL A 302 0.403 6.079 -10.336 1.00 12.89 C
+ATOM 2330 C VAL A 302 1.900 6.031 -10.358 1.00 12.89 C
+ATOM 2331 O VAL A 302 2.566 6.934 -9.814 1.00 15.77 O
+ATOM 2332 CB VAL A 302 -0.324 6.320 -11.678 1.00 9.39 C
+ATOM 2333 CG1 VAL A 302 -1.804 6.077 -11.652 1.00 5.89 C
+ATOM 2334 CG2 VAL A 302 0.092 7.625 -12.274 1.00 7.96 C
+ATOM 2335 N ALA A 303 2.531 5.016 -10.986 1.00 13.53 N
+ATOM 2336 CA ALA A 303 4.019 5.024 -10.981 1.00 13.04 C
+ATOM 2337 C ALA A 303 4.592 5.777 -12.170 1.00 12.47 C
+ATOM 2338 O ALA A 303 5.786 6.089 -12.148 1.00 14.44 O
+ATOM 2339 CB ALA A 303 4.553 3.583 -10.969 1.00 15.20 C
+ATOM 2340 N LEU A 304 3.764 6.020 -13.152 1.00 15.13 N
+ATOM 2341 CA LEU A 304 4.145 6.725 -14.409 1.00 14.98 C
+ATOM 2342 C LEU A 304 4.285 8.201 -14.083 1.00 14.31 C
+ATOM 2343 O LEU A 304 3.254 8.838 -13.869 1.00 15.14 O
+ATOM 2344 CB LEU A 304 3.007 6.458 -15.412 1.00 16.10 C
+ATOM 2345 CG LEU A 304 3.213 6.988 -16.847 1.00 16.08 C
+ATOM 2346 CD1 LEU A 304 4.404 6.318 -17.503 1.00 17.51 C
+ATOM 2347 CD2 LEU A 304 1.936 6.696 -17.628 1.00 16.56 C
+ATOM 2348 N LYS A 305 5.507 8.670 -14.042 1.00 16.74 N
+ATOM 2349 CA LYS A 305 5.796 10.070 -13.725 1.00 18.95 C
+ATOM 2350 C LYS A 305 4.940 11.058 -14.492 1.00 21.72 C
+ATOM 2351 O LYS A 305 4.314 11.991 -13.931 1.00 23.90 O
+ATOM 2352 CB LYS A 305 7.278 10.414 -13.944 1.00 16.59 C
+ATOM 2353 CG LYS A 305 8.131 9.627 -12.958 1.00 15.69 C
+ATOM 2354 CD LYS A 305 9.530 10.161 -12.883 1.00 18.35 C
+ATOM 2355 CE LYS A 305 10.518 9.370 -13.754 1.00 20.68 C
+ATOM 2356 NZ LYS A 305 11.914 9.814 -13.459 1.00 20.61 N
+ATOM 2357 N SER A 306 4.880 10.865 -15.811 1.00 22.93 N
+ATOM 2358 CA SER A 306 4.145 11.787 -16.676 1.00 20.35 C
+ATOM 2359 C SER A 306 2.716 11.932 -16.201 1.00 18.97 C
+ATOM 2360 O SER A 306 2.196 13.064 -16.083 1.00 19.55 O
+ATOM 2361 CB SER A 306 4.262 11.441 -18.150 1.00 19.68 C
+ATOM 2362 OG SER A 306 3.301 10.492 -18.624 1.00 21.91 O
+ATOM 2363 N TYR A 307 2.041 10.824 -16.015 1.00 17.09 N
+ATOM 2364 CA TYR A 307 0.616 10.943 -15.650 1.00 18.19 C
+ATOM 2365 C TYR A 307 0.459 11.344 -14.173 1.00 19.64 C
+ATOM 2366 O TYR A 307 -0.602 11.884 -13.812 1.00 20.97 O
+ATOM 2367 CB TYR A 307 -0.120 9.659 -15.936 1.00 16.19 C
+ATOM 2368 CG TYR A 307 -1.614 9.678 -15.878 1.00 15.55 C
+ATOM 2369 CD1 TYR A 307 -2.340 10.672 -16.557 1.00 16.11 C
+ATOM 2370 CD2 TYR A 307 -2.322 8.699 -15.178 1.00 16.15 C
+ATOM 2371 CE1 TYR A 307 -3.736 10.676 -16.544 1.00 14.13 C
+ATOM 2372 CE2 TYR A 307 -3.719 8.699 -15.141 1.00 15.69 C
+ATOM 2373 CZ TYR A 307 -4.390 9.695 -15.855 1.00 15.09 C
+ATOM 2374 OH TYR A 307 -5.768 9.664 -15.830 1.00 20.22 O
+ATOM 2375 N GLU A 308 1.483 11.008 -13.400 1.00 20.59 N
+ATOM 2376 CA GLU A 308 1.382 11.317 -11.965 1.00 22.00 C
+ATOM 2377 C GLU A 308 1.231 12.824 -11.889 1.00 23.58 C
+ATOM 2378 O GLU A 308 0.229 13.283 -11.304 1.00 26.85 O
+ATOM 2379 CB GLU A 308 2.538 10.849 -11.113 1.00 20.46 C
+ATOM 2380 CG GLU A 308 2.496 10.918 -9.601 1.00 17.39 C
+ATOM 2381 CD GLU A 308 1.200 10.851 -8.897 1.00 15.31 C
+ATOM 2382 OE1 GLU A 308 0.284 10.189 -9.375 1.00 13.95 O
+ATOM 2383 OE2 GLU A 308 1.036 11.445 -7.815 1.00 17.29 O
+ATOM 2384 N GLU A 309 2.179 13.528 -12.461 1.00 24.64 N
+ATOM 2385 CA GLU A 309 2.142 15.007 -12.439 1.00 25.03 C
+ATOM 2386 C GLU A 309 0.785 15.570 -12.723 1.00 24.56 C
+ATOM 2387 O GLU A 309 0.389 16.560 -12.049 1.00 26.81 O
+ATOM 2388 CB GLU A 309 3.222 15.624 -13.310 1.00 27.26 C
+ATOM 2389 CG GLU A 309 4.652 15.385 -12.758 1.00 32.06 C
+ATOM 2390 CD GLU A 309 5.804 15.700 -13.657 1.00 34.62 C
+ATOM 2391 OE1 GLU A 309 5.411 15.932 -14.829 1.00 36.39 O
+ATOM 2392 OE2 GLU A 309 6.988 15.752 -13.321 1.00 36.91 O
+ATOM 2393 N GLU A 310 -0.025 15.013 -13.586 1.00 22.03 N
+ATOM 2394 CA GLU A 310 -1.342 15.574 -13.843 1.00 20.69 C
+ATOM 2395 C GLU A 310 -2.359 15.206 -12.798 1.00 20.22 C
+ATOM 2396 O GLU A 310 -3.374 15.899 -12.565 1.00 21.45 O
+ATOM 2397 CB GLU A 310 -1.858 15.077 -15.191 1.00 24.40 C
+ATOM 2398 CG GLU A 310 -3.183 15.664 -15.666 1.00 32.27 C
+ATOM 2399 CD GLU A 310 -3.152 17.142 -16.012 1.00 35.94 C
+ATOM 2400 OE1 GLU A 310 -1.950 17.544 -16.098 1.00 36.34 O
+ATOM 2401 OE2 GLU A 310 -4.197 17.803 -16.189 1.00 38.40 O
+ATOM 2402 N LEU A 311 -2.199 14.040 -12.211 1.00 17.59 N
+ATOM 2403 CA LEU A 311 -3.109 13.526 -11.197 1.00 16.13 C
+ATOM 2404 C LEU A 311 -2.904 14.259 -9.845 1.00 14.65 C
+ATOM 2405 O LEU A 311 -3.847 14.431 -9.091 1.00 15.99 O
+ATOM 2406 CB LEU A 311 -2.837 12.020 -11.040 1.00 16.78 C
+ATOM 2407 CG LEU A 311 -3.393 11.036 -12.021 1.00 13.55 C
+ATOM 2408 CD1 LEU A 311 -3.139 9.599 -11.521 1.00 15.68 C
+ATOM 2409 CD2 LEU A 311 -4.883 11.251 -12.162 1.00 14.69 C
+ATOM 2410 N ALA A 312 -1.686 14.599 -9.582 1.00 12.29 N
+ATOM 2411 CA ALA A 312 -1.236 15.274 -8.396 1.00 14.89 C
+ATOM 2412 C ALA A 312 -1.768 16.707 -8.301 1.00 18.79 C
+ATOM 2413 O ALA A 312 -1.206 17.568 -7.574 1.00 20.46 O
+ATOM 2414 CB ALA A 312 0.282 15.170 -8.381 1.00 11.85 C
+ATOM 2415 N LYS A 313 -2.809 17.010 -9.048 1.00 20.33 N
+ATOM 2416 CA LYS A 313 -3.492 18.320 -9.082 1.00 20.42 C
+ATOM 2417 C LYS A 313 -4.658 18.193 -8.088 1.00 19.66 C
+ATOM 2418 O LYS A 313 -5.359 19.134 -7.735 1.00 20.71 O
+ATOM 2419 CB LYS A 313 -4.011 18.750 -10.426 1.00 21.20 C
+ATOM 2420 CG LYS A 313 -2.934 19.186 -11.464 1.00 21.40 C
+ATOM 2421 CD LYS A 313 -3.586 19.015 -12.833 1.00 22.95 C
+ATOM 2422 CE LYS A 313 -3.510 20.244 -13.673 1.00 22.56 C
+ATOM 2423 NZ LYS A 313 -2.104 20.554 -13.994 1.00 25.64 N
+ATOM 2424 N ASP A 314 -4.876 16.965 -7.717 1.00 18.62 N
+ATOM 2425 CA ASP A 314 -5.842 16.567 -6.674 1.00 19.31 C
+ATOM 2426 C ASP A 314 -4.889 16.403 -5.453 1.00 19.23 C
+ATOM 2427 O ASP A 314 -3.973 15.550 -5.431 1.00 19.02 O
+ATOM 2428 CB ASP A 314 -6.623 15.337 -6.960 1.00 20.27 C
+ATOM 2429 CG ASP A 314 -7.495 14.901 -5.811 1.00 23.47 C
+ATOM 2430 OD1 ASP A 314 -7.023 15.189 -4.688 1.00 27.63 O
+ATOM 2431 OD2 ASP A 314 -8.583 14.317 -5.920 1.00 25.19 O
+ATOM 2432 N PRO A 315 -5.115 17.307 -4.515 1.00 18.38 N
+ATOM 2433 CA PRO A 315 -4.255 17.303 -3.294 1.00 16.57 C
+ATOM 2434 C PRO A 315 -4.357 15.959 -2.605 1.00 13.66 C
+ATOM 2435 O PRO A 315 -3.370 15.522 -2.008 1.00 13.42 O
+ATOM 2436 CB PRO A 315 -4.635 18.551 -2.558 1.00 16.71 C
+ATOM 2437 CG PRO A 315 -6.035 18.847 -3.011 1.00 17.95 C
+ATOM 2438 CD PRO A 315 -6.123 18.351 -4.455 1.00 17.87 C
+ATOM 2439 N ARG A 316 -5.455 15.253 -2.704 1.00 13.33 N
+ATOM 2440 CA ARG A 316 -5.518 13.922 -2.056 1.00 13.94 C
+ATOM 2441 C ARG A 316 -4.475 12.993 -2.656 1.00 15.28 C
+ATOM 2442 O ARG A 316 -3.886 12.161 -1.926 1.00 16.20 O
+ATOM 2443 CB ARG A 316 -6.901 13.310 -2.119 1.00 14.27 C
+ATOM 2444 CG ARG A 316 -7.984 14.284 -1.646 1.00 15.98 C
+ATOM 2445 CD ARG A 316 -9.303 13.636 -1.862 1.00 19.79 C
+ATOM 2446 NE ARG A 316 -9.505 13.465 -3.291 1.00 20.73 N
+ATOM 2447 CZ ARG A 316 -10.495 12.829 -3.885 1.00 21.88 C
+ATOM 2448 NH1 ARG A 316 -11.482 12.190 -3.287 1.00 20.89 N
+ATOM 2449 NH2 ARG A 316 -10.513 12.861 -5.239 1.00 25.46 N
+ATOM 2450 N ILE A 317 -4.252 13.136 -3.975 1.00 14.55 N
+ATOM 2451 CA ILE A 317 -3.262 12.257 -4.636 1.00 12.63 C
+ATOM 2452 C ILE A 317 -1.853 12.695 -4.376 1.00 10.55 C
+ATOM 2453 O ILE A 317 -0.998 11.833 -4.139 1.00 12.61 O
+ATOM 2454 CB ILE A 317 -3.533 11.997 -6.156 1.00 14.22 C
+ATOM 2455 CG1 ILE A 317 -4.354 10.734 -6.311 1.00 14.66 C
+ATOM 2456 CG2 ILE A 317 -2.176 11.867 -6.930 1.00 13.21 C
+ATOM 2457 CD1 ILE A 317 -5.821 10.611 -6.069 1.00 16.66 C
+ATOM 2458 N ALA A 318 -1.599 13.986 -4.389 1.00 10.78 N
+ATOM 2459 CA ALA A 318 -0.233 14.447 -4.154 1.00 10.12 C
+ATOM 2460 C ALA A 318 0.242 14.038 -2.759 1.00 11.76 C
+ATOM 2461 O ALA A 318 1.438 13.832 -2.538 1.00 13.12 O
+ATOM 2462 CB ALA A 318 -0.152 15.958 -4.341 1.00 9.96 C
+ATOM 2463 N ALA A 319 -0.704 14.010 -1.845 1.00 13.81 N
+ATOM 2464 CA ALA A 319 -0.407 13.680 -0.435 1.00 16.21 C
+ATOM 2465 C ALA A 319 -0.116 12.188 -0.347 1.00 15.03 C
+ATOM 2466 O ALA A 319 0.867 11.916 0.354 1.00 19.55 O
+ATOM 2467 CB ALA A 319 -1.460 14.104 0.557 1.00 16.25 C
+ATOM 2468 N THR A 320 -0.872 11.378 -1.036 1.00 16.88 N
+ATOM 2469 CA THR A 320 -0.614 9.917 -1.040 1.00 16.12 C
+ATOM 2470 C THR A 320 0.817 9.646 -1.510 1.00 16.44 C
+ATOM 2471 O THR A 320 1.564 8.873 -0.879 1.00 17.87 O
+ATOM 2472 CB THR A 320 -1.661 9.124 -1.880 1.00 15.18 C
+ATOM 2473 OG1 THR A 320 -2.982 9.496 -1.369 1.00 15.40 O
+ATOM 2474 CG2 THR A 320 -1.438 7.597 -1.867 1.00 15.53 C
+ATOM 2475 N MET A 321 1.234 10.302 -2.603 1.00 14.89 N
+ATOM 2476 CA MET A 321 2.581 10.117 -3.130 1.00 13.01 C
+ATOM 2477 C MET A 321 3.610 10.612 -2.170 1.00 14.22 C
+ATOM 2478 O MET A 321 4.657 9.972 -1.984 1.00 14.79 O
+ATOM 2479 CB MET A 321 2.732 10.682 -4.527 1.00 14.65 C
+ATOM 2480 CG MET A 321 4.107 10.548 -5.113 1.00 14.04 C
+ATOM 2481 SD MET A 321 4.481 8.818 -5.475 1.00 17.50 S
+ATOM 2482 CE MET A 321 3.097 8.270 -6.395 1.00 13.94 C
+ATOM 2483 N GLU A 322 3.387 11.780 -1.573 1.00 16.56 N
+ATOM 2484 CA GLU A 322 4.338 12.357 -0.617 1.00 16.26 C
+ATOM 2485 C GLU A 322 4.584 11.366 0.536 1.00 14.27 C
+ATOM 2486 O GLU A 322 5.719 11.157 0.947 1.00 15.11 O
+ATOM 2487 CB GLU A 322 3.927 13.702 -0.015 1.00 19.21 C
+ATOM 2488 CG GLU A 322 4.984 14.302 0.931 1.00 25.60 C
+ATOM 2489 CD GLU A 322 5.040 15.781 1.148 1.00 28.64 C
+ATOM 2490 OE1 GLU A 322 4.028 16.403 0.727 1.00 29.95 O
+ATOM 2491 OE2 GLU A 322 5.979 16.340 1.725 1.00 30.31 O
+ATOM 2492 N ASN A 323 3.548 10.735 0.974 1.00 13.63 N
+ATOM 2493 CA ASN A 323 3.571 9.768 2.072 1.00 14.87 C
+ATOM 2494 C ASN A 323 4.276 8.475 1.659 1.00 15.58 C
+ATOM 2495 O ASN A 323 4.973 7.838 2.467 1.00 15.44 O
+ATOM 2496 CB ASN A 323 2.161 9.589 2.651 1.00 12.15 C
+ATOM 2497 CG ASN A 323 1.780 10.673 3.697 1.00 10.59 C
+ATOM 2498 OD1 ASN A 323 2.576 11.119 4.520 1.00 10.53 O
+ATOM 2499 ND2 ASN A 323 0.548 11.085 3.597 1.00 9.09 N
+ATOM 2500 N ALA A 324 4.063 8.084 0.415 1.00 18.34 N
+ATOM 2501 CA ALA A 324 4.683 6.856 -0.133 1.00 19.00 C
+ATOM 2502 C ALA A 324 6.155 7.101 -0.352 1.00 20.43 C
+ATOM 2503 O ALA A 324 6.962 6.165 -0.196 1.00 23.09 O
+ATOM 2504 CB ALA A 324 3.932 6.348 -1.332 1.00 18.72 C
+ATOM 2505 N GLN A 325 6.584 8.314 -0.628 1.00 21.55 N
+ATOM 2506 CA GLN A 325 7.999 8.633 -0.845 1.00 23.34 C
+ATOM 2507 C GLN A 325 8.798 8.711 0.436 1.00 23.74 C
+ATOM 2508 O GLN A 325 10.016 8.957 0.442 1.00 24.70 O
+ATOM 2509 CB GLN A 325 8.158 9.987 -1.576 1.00 26.08 C
+ATOM 2510 CG GLN A 325 7.551 9.898 -2.967 1.00 29.93 C
+ATOM 2511 CD GLN A 325 7.843 11.074 -3.855 1.00 32.22 C
+ATOM 2512 OE1 GLN A 325 8.888 11.717 -3.720 1.00 34.90 O
+ATOM 2513 NE2 GLN A 325 6.901 11.314 -4.776 1.00 31.74 N
+ATOM 2514 N LYS A 326 8.086 8.573 1.532 1.00 24.60 N
+ATOM 2515 CA LYS A 326 8.660 8.620 2.886 1.00 23.15 C
+ATOM 2516 C LYS A 326 8.482 7.291 3.634 1.00 20.99 C
+ATOM 2517 O LYS A 326 9.155 7.062 4.653 1.00 21.70 O
+ATOM 2518 CB LYS A 326 8.059 9.795 3.671 1.00 25.54 C
+ATOM 2519 CG LYS A 326 8.100 11.099 2.872 1.00 26.42 C
+ATOM 2520 CD LYS A 326 8.837 12.201 3.596 1.00 29.34 C
+ATOM 2521 CE LYS A 326 8.499 13.591 3.060 1.00 31.96 C
+ATOM 2522 NZ LYS A 326 9.429 13.950 1.925 1.00 33.49 N
+ATOM 2523 N GLY A 327 7.650 6.449 3.120 1.00 18.16 N
+ATOM 2524 CA GLY A 327 7.246 5.166 3.572 1.00 18.83 C
+ATOM 2525 C GLY A 327 8.255 4.048 3.419 1.00 18.66 C
+ATOM 2526 O GLY A 327 9.418 4.179 3.048 1.00 19.81 O
+ATOM 2527 N GLU A 328 7.797 2.862 3.736 1.00 17.87 N
+ATOM 2528 CA GLU A 328 8.652 1.662 3.699 1.00 18.71 C
+ATOM 2529 C GLU A 328 8.011 0.635 2.804 1.00 18.52 C
+ATOM 2530 O GLU A 328 6.896 0.114 3.053 1.00 18.47 O
+ATOM 2531 CB GLU A 328 8.905 1.136 5.122 1.00 18.60 C
+ATOM 2532 CG GLU A 328 9.130 -0.328 5.349 1.00 22.14 C
+ATOM 2533 CD GLU A 328 9.834 -0.849 6.555 1.00 24.59 C
+ATOM 2534 OE1 GLU A 328 9.534 -0.160 7.568 1.00 24.88 O
+ATOM 2535 OE2 GLU A 328 10.578 -1.820 6.596 1.00 22.93 O
+ATOM 2536 N ILE A 329 8.722 0.386 1.678 1.00 19.18 N
+ATOM 2537 CA ILE A 329 8.171 -0.622 0.744 1.00 17.05 C
+ATOM 2538 C ILE A 329 7.928 -1.883 1.587 1.00 16.81 C
+ATOM 2539 O ILE A 329 8.846 -2.342 2.267 1.00 18.12 O
+ATOM 2540 CB ILE A 329 9.111 -0.945 -0.449 1.00 18.32 C
+ATOM 2541 CG1 ILE A 329 9.497 0.352 -1.215 1.00 18.95 C
+ATOM 2542 CG2 ILE A 329 8.478 -2.024 -1.361 1.00 17.22 C
+ATOM 2543 CD1 ILE A 329 8.288 0.951 -1.977 1.00 22.78 C
+ATOM 2544 N MET A 330 6.737 -2.349 1.520 1.00 17.90 N
+ATOM 2545 CA MET A 330 6.285 -3.572 2.230 1.00 20.60 C
+ATOM 2546 C MET A 330 7.084 -4.716 1.625 1.00 23.56 C
+ATOM 2547 O MET A 330 6.944 -5.018 0.421 1.00 24.31 O
+ATOM 2548 CB MET A 330 4.797 -3.617 1.990 1.00 18.73 C
+ATOM 2549 CG MET A 330 3.997 -4.696 2.535 1.00 20.37 C
+ATOM 2550 SD MET A 330 2.310 -4.076 2.863 1.00 24.46 S
+ATOM 2551 CE MET A 330 1.711 -3.677 1.226 1.00 23.65 C
+ATOM 2552 N PRO A 331 7.962 -5.312 2.410 1.00 25.16 N
+ATOM 2553 CA PRO A 331 8.786 -6.451 1.928 1.00 25.05 C
+ATOM 2554 C PRO A 331 7.881 -7.540 1.391 1.00 24.59 C
+ATOM 2555 O PRO A 331 6.782 -7.801 1.894 1.00 23.14 O
+ATOM 2556 CB PRO A 331 9.676 -6.768 3.103 1.00 26.43 C
+ATOM 2557 CG PRO A 331 9.686 -5.495 3.964 1.00 25.70 C
+ATOM 2558 CD PRO A 331 8.238 -5.008 3.833 1.00 25.57 C
+ATOM 2559 N ASN A 332 8.319 -8.178 0.300 1.00 27.37 N
+ATOM 2560 CA ASN A 332 7.574 -9.238 -0.396 1.00 29.89 C
+ATOM 2561 C ASN A 332 8.047 -10.657 -0.090 1.00 32.49 C
+ATOM 2562 O ASN A 332 7.550 -11.618 -0.743 1.00 33.92 O
+ATOM 2563 CB ASN A 332 7.519 -8.965 -1.915 1.00 29.31 C
+ATOM 2564 CG ASN A 332 8.881 -9.047 -2.571 1.00 30.45 C
+ATOM 2565 OD1 ASN A 332 9.905 -9.312 -1.918 1.00 28.97 O
+ATOM 2566 ND2 ASN A 332 8.952 -8.780 -3.899 1.00 31.61 N
+ATOM 2567 N ILE A 333 8.941 -10.818 0.867 1.00 33.68 N
+ATOM 2568 CA ILE A 333 9.477 -12.140 1.268 1.00 33.31 C
+ATOM 2569 C ILE A 333 8.447 -12.848 2.122 1.00 35.59 C
+ATOM 2570 O ILE A 333 7.529 -12.213 2.709 1.00 36.92 O
+ATOM 2571 CB ILE A 333 10.899 -11.923 1.861 1.00 31.73 C
+ATOM 2572 CG1 ILE A 333 10.770 -11.144 3.192 1.00 31.10 C
+ATOM 2573 CG2 ILE A 333 11.886 -11.247 0.864 1.00 28.19 C
+ATOM 2574 CD1 ILE A 333 12.134 -10.607 3.729 1.00 32.50 C
+ATOM 2575 N PRO A 334 8.503 -14.180 2.156 1.00 37.07 N
+ATOM 2576 CA PRO A 334 7.535 -15.012 2.907 1.00 36.15 C
+ATOM 2577 C PRO A 334 7.582 -14.803 4.404 1.00 34.99 C
+ATOM 2578 O PRO A 334 6.611 -15.055 5.122 1.00 35.23 O
+ATOM 2579 CB PRO A 334 7.848 -16.441 2.496 1.00 37.09 C
+ATOM 2580 CG PRO A 334 9.210 -16.431 1.871 1.00 36.95 C
+ATOM 2581 CD PRO A 334 9.525 -15.001 1.471 1.00 37.38 C
+ATOM 2582 N GLN A 335 8.716 -14.331 4.885 1.00 34.75 N
+ATOM 2583 CA GLN A 335 8.981 -14.018 6.284 1.00 33.23 C
+ATOM 2584 C GLN A 335 8.039 -12.901 6.755 1.00 32.41 C
+ATOM 2585 O GLN A 335 7.857 -12.698 7.975 1.00 32.02 O
+ATOM 2586 CB GLN A 335 10.437 -13.597 6.487 1.00 34.37 C
+ATOM 2587 CG GLN A 335 11.444 -14.662 6.678 1.00 38.93 C
+ATOM 2588 CD GLN A 335 12.091 -15.300 5.485 1.00 41.86 C
+ATOM 2589 OE1 GLN A 335 13.161 -14.915 4.990 1.00 43.14 O
+ATOM 2590 NE2 GLN A 335 11.491 -16.382 4.985 1.00 43.69 N
+ATOM 2591 N MET A 336 7.447 -12.160 5.830 1.00 30.01 N
+ATOM 2592 CA MET A 336 6.554 -11.075 6.234 1.00 29.50 C
+ATOM 2593 C MET A 336 5.343 -11.581 6.992 1.00 29.48 C
+ATOM 2594 O MET A 336 4.761 -10.796 7.779 1.00 29.86 O
+ATOM 2595 CB MET A 336 6.153 -10.142 5.094 1.00 26.76 C
+ATOM 2596 CG MET A 336 7.208 -9.092 4.904 1.00 25.48 C
+ATOM 2597 SD MET A 336 7.109 -7.855 6.234 1.00 25.91 S
+ATOM 2598 CE MET A 336 5.635 -6.946 5.761 1.00 22.50 C
+ATOM 2599 N SER A 337 4.945 -12.819 6.769 1.00 29.24 N
+ATOM 2600 CA SER A 337 3.741 -13.347 7.456 1.00 28.46 C
+ATOM 2601 C SER A 337 4.067 -13.572 8.931 1.00 28.60 C
+ATOM 2602 O SER A 337 3.137 -13.668 9.741 1.00 30.68 O
+ATOM 2603 CB SER A 337 3.207 -14.583 6.781 1.00 28.93 C
+ATOM 2604 OG SER A 337 4.331 -15.216 6.148 1.00 31.74 O
+ATOM 2605 N ALA A 338 5.337 -13.591 9.222 1.00 27.87 N
+ATOM 2606 CA ALA A 338 5.920 -13.754 10.539 1.00 27.27 C
+ATOM 2607 C ALA A 338 5.933 -12.439 11.335 1.00 26.45 C
+ATOM 2608 O ALA A 338 5.797 -12.438 12.565 1.00 26.33 O
+ATOM 2609 CB ALA A 338 7.368 -14.231 10.369 1.00 27.48 C
+ATOM 2610 N PHE A 339 6.147 -11.356 10.624 1.00 25.13 N
+ATOM 2611 CA PHE A 339 6.209 -9.983 11.135 1.00 23.08 C
+ATOM 2612 C PHE A 339 4.806 -9.486 11.464 1.00 22.80 C
+ATOM 2613 O PHE A 339 4.574 -8.910 12.547 1.00 21.32 O
+ATOM 2614 CB PHE A 339 6.993 -9.061 10.216 1.00 22.73 C
+ATOM 2615 CG PHE A 339 6.810 -7.584 10.421 1.00 21.23 C
+ATOM 2616 CD1 PHE A 339 5.622 -6.956 10.060 1.00 21.69 C
+ATOM 2617 CD2 PHE A 339 7.842 -6.817 10.943 1.00 20.97 C
+ATOM 2618 CE1 PHE A 339 5.428 -5.593 10.255 1.00 18.93 C
+ATOM 2619 CE2 PHE A 339 7.705 -5.448 11.132 1.00 19.84 C
+ATOM 2620 CZ PHE A 339 6.491 -4.865 10.780 1.00 20.24 C
+ATOM 2621 N TRP A 340 3.878 -9.725 10.544 1.00 22.78 N
+ATOM 2622 CA TRP A 340 2.511 -9.254 10.792 1.00 24.14 C
+ATOM 2623 C TRP A 340 2.077 -9.730 12.173 1.00 25.36 C
+ATOM 2624 O TRP A 340 2.090 -8.983 13.141 1.00 25.60 O
+ATOM 2625 CB TRP A 340 1.560 -9.581 9.681 1.00 24.97 C
+ATOM 2626 CG TRP A 340 1.901 -8.985 8.358 1.00 27.90 C
+ATOM 2627 CD1 TRP A 340 2.147 -9.681 7.195 1.00 27.61 C
+ATOM 2628 CD2 TRP A 340 2.046 -7.585 8.049 1.00 27.84 C
+ATOM 2629 NE1 TRP A 340 2.398 -8.785 6.190 1.00 29.27 N
+ATOM 2630 CE2 TRP A 340 2.362 -7.503 6.674 1.00 28.52 C
+ATOM 2631 CE3 TRP A 340 1.939 -6.416 8.789 1.00 26.80 C
+ATOM 2632 CZ2 TRP A 340 2.561 -6.292 6.025 1.00 29.10 C
+ATOM 2633 CZ3 TRP A 340 2.146 -5.205 8.150 1.00 26.45 C
+ATOM 2634 CH2 TRP A 340 2.455 -5.131 6.789 1.00 28.14 C
+ATOM 2635 N TYR A 341 1.727 -10.977 12.201 1.00 27.88 N
+ATOM 2636 CA TYR A 341 1.243 -11.775 13.341 1.00 29.68 C
+ATOM 2637 C TYR A 341 1.871 -11.404 14.668 1.00 27.64 C
+ATOM 2638 O TYR A 341 1.152 -11.219 15.657 1.00 25.85 O
+ATOM 2639 CB TYR A 341 1.370 -13.239 12.905 1.00 33.73 C
+ATOM 2640 CG TYR A 341 1.351 -14.332 13.919 1.00 39.37 C
+ATOM 2641 CD1 TYR A 341 2.435 -14.479 14.799 1.00 41.76 C
+ATOM 2642 CD2 TYR A 341 0.297 -15.255 14.005 1.00 41.20 C
+ATOM 2643 CE1 TYR A 341 2.460 -15.470 15.769 1.00 44.70 C
+ATOM 2644 CE2 TYR A 341 0.311 -16.283 14.948 1.00 45.19 C
+ATOM 2645 CZ TYR A 341 1.404 -16.372 15.823 1.00 46.66 C
+ATOM 2646 OH TYR A 341 1.485 -17.353 16.789 1.00 50.61 O
+ATOM 2647 N ALA A 342 3.165 -11.291 14.730 1.00 26.67 N
+ATOM 2648 CA ALA A 342 3.986 -10.953 15.877 1.00 27.26 C
+ATOM 2649 C ALA A 342 3.915 -9.480 16.258 1.00 27.53 C
+ATOM 2650 O ALA A 342 4.004 -9.112 17.443 1.00 27.59 O
+ATOM 2651 CB ALA A 342 5.451 -11.346 15.599 1.00 24.26 C
+ATOM 2652 N VAL A 343 3.806 -8.624 15.249 1.00 27.79 N
+ATOM 2653 CA VAL A 343 3.705 -7.152 15.481 1.00 26.27 C
+ATOM 2654 C VAL A 343 2.284 -6.830 15.945 1.00 25.95 C
+ATOM 2655 O VAL A 343 2.093 -5.982 16.848 1.00 26.31 O
+ATOM 2656 CB VAL A 343 4.279 -6.349 14.324 1.00 24.74 C
+ATOM 2657 CG1 VAL A 343 3.896 -4.872 14.380 1.00 24.56 C
+ATOM 2658 CG2 VAL A 343 5.800 -6.461 14.269 1.00 22.92 C
+ATOM 2659 N ARG A 344 1.303 -7.560 15.449 1.00 24.41 N
+ATOM 2660 CA ARG A 344 -0.091 -7.366 15.864 1.00 25.33 C
+ATOM 2661 C ARG A 344 -0.223 -7.646 17.371 1.00 25.18 C
+ATOM 2662 O ARG A 344 -1.088 -7.114 18.075 1.00 24.66 O
+ATOM 2663 CB ARG A 344 -1.036 -8.273 15.073 1.00 25.45 C
+ATOM 2664 CG ARG A 344 -2.510 -8.130 15.357 1.00 27.85 C
+ATOM 2665 CD ARG A 344 -3.439 -8.313 14.221 1.00 31.60 C
+ATOM 2666 NE ARG A 344 -3.289 -9.544 13.504 1.00 35.94 N
+ATOM 2667 CZ ARG A 344 -2.687 -9.855 12.358 1.00 38.34 C
+ATOM 2668 NH1 ARG A 344 -2.152 -8.946 11.534 1.00 38.52 N
+ATOM 2669 NH2 ARG A 344 -2.643 -11.142 11.945 1.00 40.16 N
+ATOM 2670 N THR A 345 0.634 -8.538 17.826 1.00 25.46 N
+ATOM 2671 CA THR A 345 0.667 -9.021 19.206 1.00 24.82 C
+ATOM 2672 C THR A 345 1.434 -8.081 20.109 1.00 23.20 C
+ATOM 2673 O THR A 345 0.865 -7.688 21.143 1.00 25.61 O
+ATOM 2674 CB THR A 345 1.161 -10.509 19.306 1.00 24.16 C
+ATOM 2675 OG1 THR A 345 0.031 -11.311 18.823 1.00 25.69 O
+ATOM 2676 CG2 THR A 345 1.563 -10.938 20.724 1.00 25.25 C
+ATOM 2677 N ALA A 346 2.629 -7.745 19.729 1.00 22.37 N
+ATOM 2678 CA ALA A 346 3.472 -6.836 20.479 1.00 22.92 C
+ATOM 2679 C ALA A 346 2.715 -5.557 20.787 1.00 24.38 C
+ATOM 2680 O ALA A 346 2.786 -5.024 21.894 1.00 25.74 O
+ATOM 2681 CB ALA A 346 4.746 -6.496 19.711 1.00 23.04 C
+ATOM 2682 N VAL A 347 2.008 -5.055 19.785 1.00 25.65 N
+ATOM 2683 CA VAL A 347 1.278 -3.797 19.945 1.00 25.56 C
+ATOM 2684 C VAL A 347 0.055 -3.978 20.824 1.00 26.33 C
+ATOM 2685 O VAL A 347 -0.142 -3.115 21.709 1.00 27.26 O
+ATOM 2686 CB VAL A 347 1.019 -3.062 18.623 1.00 25.07 C
+ATOM 2687 CG1 VAL A 347 0.228 -1.757 18.809 1.00 26.98 C
+ATOM 2688 CG2 VAL A 347 2.266 -2.694 17.840 1.00 24.18 C
+ATOM 2689 N ILE A 348 -0.765 -4.965 20.606 1.00 26.27 N
+ATOM 2690 CA ILE A 348 -2.001 -5.119 21.391 1.00 26.75 C
+ATOM 2691 C ILE A 348 -1.787 -5.296 22.879 1.00 28.90 C
+ATOM 2692 O ILE A 348 -2.591 -4.875 23.717 1.00 28.15 O
+ATOM 2693 CB ILE A 348 -2.787 -6.305 20.742 1.00 26.00 C
+ATOM 2694 CG1 ILE A 348 -3.564 -5.729 19.546 1.00 25.19 C
+ATOM 2695 CG2 ILE A 348 -3.637 -7.076 21.772 1.00 25.65 C
+ATOM 2696 CD1 ILE A 348 -4.777 -6.575 19.095 1.00 25.29 C
+ATOM 2697 N ASN A 349 -0.710 -5.968 23.209 1.00 32.01 N
+ATOM 2698 CA ASN A 349 -0.273 -6.292 24.565 1.00 33.93 C
+ATOM 2699 C ASN A 349 0.234 -5.037 25.286 1.00 34.76 C
+ATOM 2700 O ASN A 349 0.030 -4.908 26.497 1.00 35.81 O
+ATOM 2701 CB ASN A 349 0.794 -7.375 24.545 1.00 33.52 C
+ATOM 2702 CG ASN A 349 0.336 -8.786 24.226 1.00 33.38 C
+ATOM 2703 OD1 ASN A 349 -0.844 -9.090 23.982 1.00 32.45 O
+ATOM 2704 ND2 ASN A 349 1.352 -9.676 24.246 1.00 32.09 N
+ATOM 2705 N ALA A 350 0.919 -4.194 24.559 1.00 36.26 N
+ATOM 2706 CA ALA A 350 1.493 -2.952 25.062 1.00 38.25 C
+ATOM 2707 C ALA A 350 0.401 -1.922 25.355 1.00 40.13 C
+ATOM 2708 O ALA A 350 0.509 -1.116 26.306 1.00 40.56 O
+ATOM 2709 CB ALA A 350 2.494 -2.411 24.040 1.00 37.37 C
+ATOM 2710 N ALA A 351 -0.614 -1.939 24.519 1.00 41.47 N
+ATOM 2711 CA ALA A 351 -1.777 -1.051 24.545 1.00 43.03 C
+ATOM 2712 C ALA A 351 -2.788 -1.477 25.603 1.00 44.28 C
+ATOM 2713 O ALA A 351 -3.743 -0.737 25.916 1.00 45.31 O
+ATOM 2714 CB ALA A 351 -2.464 -0.999 23.167 1.00 41.60 C
+ATOM 2715 N SER A 352 -2.591 -2.677 26.136 1.00 44.90 N
+ATOM 2716 CA SER A 352 -3.517 -3.149 27.192 1.00 45.62 C
+ATOM 2717 C SER A 352 -2.753 -3.545 28.446 1.00 46.24 C
+ATOM 2718 O SER A 352 -3.227 -4.323 29.299 1.00 47.38 O
+ATOM 2719 CB SER A 352 -4.471 -4.163 26.640 1.00 45.52 C
+ATOM 2720 OG SER A 352 -3.836 -5.152 25.876 1.00 48.04 O
+ATOM 2721 N GLY A 353 -1.563 -2.986 28.646 1.00 45.96 N
+ATOM 2722 CA GLY A 353 -0.728 -3.246 29.808 1.00 45.12 C
+ATOM 2723 C GLY A 353 -0.430 -4.714 30.030 1.00 45.05 C
+ATOM 2724 O GLY A 353 0.253 -5.034 31.038 1.00 45.84 O
+ATOM 2725 N ARG A 354 -0.865 -5.593 29.139 1.00 44.41 N
+ATOM 2726 CA ARG A 354 -0.589 -7.038 29.265 1.00 43.86 C
+ATOM 2727 C ARG A 354 0.900 -7.337 29.120 1.00 41.34 C
+ATOM 2728 O ARG A 354 1.351 -8.475 29.299 1.00 41.24 O
+ATOM 2729 CB ARG A 354 -1.404 -7.900 28.295 1.00 47.08 C
+ATOM 2730 CG ARG A 354 -1.302 -9.406 28.527 1.00 51.76 C
+ATOM 2731 CD ARG A 354 -1.999 -10.233 27.525 1.00 55.55 C
+ATOM 2732 NE ARG A 354 -3.242 -10.842 27.960 1.00 59.88 N
+ATOM 2733 CZ ARG A 354 -4.377 -10.822 27.245 1.00 62.76 C
+ATOM 2734 NH1 ARG A 354 -4.411 -10.141 26.083 1.00 63.93 N
+ATOM 2735 NH2 ARG A 354 -5.514 -11.411 27.636 1.00 63.55 N
+ATOM 2736 N GLN A 355 1.669 -6.318 28.823 1.00 39.13 N
+ATOM 2737 CA GLN A 355 3.139 -6.454 28.650 1.00 37.99 C
+ATOM 2738 C GLN A 355 3.672 -5.046 28.396 1.00 37.84 C
+ATOM 2739 O GLN A 355 2.939 -4.256 27.758 1.00 38.00 O
+ATOM 2740 CB GLN A 355 3.413 -7.411 27.514 1.00 38.91 C
+ATOM 2741 CG GLN A 355 4.675 -8.214 27.483 1.00 38.70 C
+ATOM 2742 CD GLN A 355 4.821 -9.094 26.260 1.00 39.52 C
+ATOM 2743 OE1 GLN A 355 3.884 -9.580 25.621 1.00 40.49 O
+ATOM 2744 NE2 GLN A 355 6.075 -9.308 25.860 1.00 40.93 N
+ATOM 2745 N THR A 356 4.858 -4.733 28.886 1.00 37.24 N
+ATOM 2746 CA THR A 356 5.436 -3.398 28.673 1.00 37.57 C
+ATOM 2747 C THR A 356 5.851 -3.259 27.202 1.00 37.07 C
+ATOM 2748 O THR A 356 5.638 -4.186 26.405 1.00 37.26 O
+ATOM 2749 CB THR A 356 6.632 -3.003 29.612 1.00 38.26 C
+ATOM 2750 OG1 THR A 356 7.803 -3.850 29.374 1.00 37.71 O
+ATOM 2751 CG2 THR A 356 6.214 -2.961 31.096 1.00 39.31 C
+ATOM 2752 N VAL A 357 6.450 -2.116 26.922 1.00 36.52 N
+ATOM 2753 CA VAL A 357 6.915 -1.835 25.547 1.00 35.91 C
+ATOM 2754 C VAL A 357 8.155 -2.698 25.269 1.00 36.40 C
+ATOM 2755 O VAL A 357 8.199 -3.355 24.216 1.00 35.89 O
+ATOM 2756 CB VAL A 357 7.087 -0.332 25.281 1.00 32.99 C
+ATOM 2757 CG1 VAL A 357 7.809 -0.050 23.975 1.00 30.05 C
+ATOM 2758 CG2 VAL A 357 5.741 0.372 25.325 1.00 32.12 C
+ATOM 2759 N ASP A 358 9.069 -2.662 26.224 1.00 36.66 N
+ATOM 2760 CA ASP A 358 10.314 -3.406 26.132 1.00 38.30 C
+ATOM 2761 C ASP A 358 10.049 -4.918 26.123 1.00 38.07 C
+ATOM 2762 O ASP A 358 10.872 -5.658 25.532 1.00 39.60 O
+ATOM 2763 CB ASP A 358 11.355 -2.968 27.159 1.00 40.83 C
+ATOM 2764 CG ASP A 358 11.279 -1.526 27.603 1.00 43.18 C
+ATOM 2765 OD1 ASP A 358 10.406 -1.241 28.464 1.00 46.45 O
+ATOM 2766 OD2 ASP A 358 12.077 -0.696 27.103 1.00 43.35 O
+ATOM 2767 N GLU A 359 8.969 -5.390 26.698 1.00 37.50 N
+ATOM 2768 CA GLU A 359 8.699 -6.832 26.733 1.00 37.43 C
+ATOM 2769 C GLU A 359 8.138 -7.347 25.410 1.00 35.73 C
+ATOM 2770 O GLU A 359 8.565 -8.364 24.868 1.00 34.05 O
+ATOM 2771 CB GLU A 359 7.666 -7.185 27.791 1.00 41.86 C
+ATOM 2772 CG GLU A 359 7.950 -7.047 29.253 1.00 49.01 C
+ATOM 2773 CD GLU A 359 6.864 -6.627 30.206 1.00 52.65 C
+ATOM 2774 OE1 GLU A 359 5.768 -7.235 30.114 1.00 53.38 O
+ATOM 2775 OE2 GLU A 359 7.069 -5.728 31.027 1.00 54.33 O
+ATOM 2776 N ALA A 360 7.118 -6.626 24.978 1.00 34.26 N
+ATOM 2777 CA ALA A 360 6.360 -6.902 23.753 1.00 33.23 C
+ATOM 2778 C ALA A 360 7.234 -6.871 22.508 1.00 31.38 C
+ATOM 2779 O ALA A 360 7.227 -7.856 21.745 1.00 31.72 O
+ATOM 2780 CB ALA A 360 5.133 -6.013 23.686 1.00 32.60 C
+ATOM 2781 N LEU A 361 8.007 -5.828 22.326 1.00 31.30 N
+ATOM 2782 CA LEU A 361 8.892 -5.689 21.170 1.00 31.96 C
+ATOM 2783 C LEU A 361 9.964 -6.769 21.161 1.00 32.84 C
+ATOM 2784 O LEU A 361 10.186 -7.338 20.075 1.00 32.63 O
+ATOM 2785 CB LEU A 361 9.416 -4.267 20.997 1.00 29.54 C
+ATOM 2786 CG LEU A 361 8.408 -3.235 20.483 1.00 28.89 C
+ATOM 2787 CD1 LEU A 361 9.110 -1.912 20.228 1.00 29.30 C
+ATOM 2788 CD2 LEU A 361 7.712 -3.745 19.244 1.00 26.51 C
+ATOM 2789 N LYS A 362 10.553 -7.026 22.306 1.00 33.83 N
+ATOM 2790 CA LYS A 362 11.613 -8.051 22.434 1.00 34.70 C
+ATOM 2791 C LYS A 362 11.113 -9.436 22.064 1.00 33.15 C
+ATOM 2792 O LYS A 362 11.785 -10.154 21.297 1.00 33.05 O
+ATOM 2793 CB LYS A 362 12.313 -7.990 23.766 1.00 37.36 C
+ATOM 2794 CG LYS A 362 12.951 -9.252 24.336 1.00 39.03 C
+ATOM 2795 CD LYS A 362 13.636 -8.962 25.680 1.00 40.11 C
+ATOM 2796 CE LYS A 362 12.713 -9.153 26.877 1.00 39.21 C
+ATOM 2797 NZ LYS A 362 11.845 -10.342 26.654 1.00 38.64 N
+ATOM 2798 N ASP A 363 9.960 -9.825 22.541 1.00 33.44 N
+ATOM 2799 CA ASP A 363 9.410 -11.143 22.216 1.00 34.70 C
+ATOM 2800 C ASP A 363 8.865 -11.149 20.778 1.00 33.83 C
+ATOM 2801 O ASP A 363 8.480 -12.237 20.337 1.00 34.55 O
+ATOM 2802 CB ASP A 363 8.284 -11.574 23.132 1.00 38.59 C
+ATOM 2803 CG ASP A 363 8.506 -11.493 24.616 1.00 41.58 C
+ATOM 2804 OD1 ASP A 363 9.605 -11.689 25.159 1.00 43.58 O
+ATOM 2805 OD2 ASP A 363 7.439 -11.239 25.254 1.00 43.35 O
+ATOM 2806 N ALA A 364 8.719 -9.992 20.200 1.00 32.78 N
+ATOM 2807 CA ALA A 364 8.170 -9.856 18.846 1.00 31.85 C
+ATOM 2808 C ALA A 364 9.291 -10.189 17.857 1.00 31.85 C
+ATOM 2809 O ALA A 364 9.097 -10.889 16.873 1.00 30.85 O
+ATOM 2810 CB ALA A 364 7.707 -8.422 18.619 1.00 32.04 C
+ATOM 2811 N GLN A 365 10.429 -9.628 18.207 1.00 32.41 N
+ATOM 2812 CA GLN A 365 11.653 -9.742 17.451 1.00 33.90 C
+ATOM 2813 C GLN A 365 12.184 -11.162 17.455 1.00 35.51 C
+ATOM 2814 O GLN A 365 12.668 -11.616 16.392 1.00 37.25 O
+ATOM 2815 CB GLN A 365 12.758 -8.754 17.840 1.00 34.46 C
+ATOM 2816 CG GLN A 365 14.057 -9.087 17.127 1.00 35.39 C
+ATOM 2817 CD GLN A 365 14.654 -7.941 16.371 1.00 35.62 C
+ATOM 2818 OE1 GLN A 365 13.966 -7.034 15.932 1.00 36.10 O
+ATOM 2819 NE2 GLN A 365 15.980 -8.018 16.221 1.00 36.94 N
+ATOM 2820 N THR A 366 12.119 -11.803 18.606 1.00 35.58 N
+ATOM 2821 CA THR A 366 12.632 -13.201 18.658 1.00 34.97 C
+ATOM 2822 C THR A 366 11.709 -14.021 17.778 1.00 34.68 C
+ATOM 2823 O THR A 366 12.183 -14.775 16.910 1.00 35.11 O
+ATOM 2824 CB THR A 366 12.865 -13.674 20.125 1.00 35.69 C
+ATOM 2825 OG1 THR A 366 11.549 -14.027 20.661 1.00 36.93 O
+ATOM 2826 CG2 THR A 366 13.559 -12.635 21.029 1.00 34.95 C
+ATOM 2827 N ARG A 367 10.412 -13.846 17.918 1.00 34.52 N
+ATOM 2828 CA ARG A 367 9.448 -14.562 17.080 1.00 35.84 C
+ATOM 2829 C ARG A 367 9.740 -14.423 15.587 1.00 36.26 C
+ATOM 2830 O ARG A 367 9.686 -15.432 14.856 1.00 35.78 O
+ATOM 2831 CB ARG A 367 8.008 -14.172 17.402 1.00 37.22 C
+ATOM 2832 CG ARG A 367 7.565 -14.664 18.771 1.00 42.77 C
+ATOM 2833 CD ARG A 367 6.262 -15.388 18.688 1.00 48.18 C
+ATOM 2834 NE ARG A 367 5.168 -14.757 19.379 1.00 52.73 N
+ATOM 2835 CZ ARG A 367 4.695 -14.975 20.602 1.00 55.43 C
+ATOM 2836 NH1 ARG A 367 5.201 -15.902 21.430 1.00 56.52 N
+ATOM 2837 NH2 ARG A 367 3.646 -14.256 21.053 1.00 56.58 N
+ATOM 2838 N ILE A 368 10.017 -13.228 15.097 1.00 36.76 N
+ATOM 2839 CA ILE A 368 10.279 -12.897 13.707 1.00 36.60 C
+ATOM 2840 C ILE A 368 11.576 -13.492 13.177 1.00 37.58 C
+ATOM 2841 O ILE A 368 11.484 -14.118 12.113 1.00 38.38 O
+ATOM 2842 CB ILE A 368 10.212 -11.358 13.394 1.00 34.71 C
+ATOM 2843 CG1 ILE A 368 8.856 -10.750 13.813 1.00 34.33 C
+ATOM 2844 CG2 ILE A 368 10.478 -11.079 11.883 1.00 34.17 C
+ATOM 2845 CD1 ILE A 368 8.812 -9.189 13.745 1.00 32.35 C
+ATOM 2846 N THR A 369 12.704 -13.268 13.799 1.00 39.66 N
+ATOM 2847 CA THR A 369 14.008 -13.784 13.366 1.00 42.79 C
+ATOM 2848 C THR A 369 14.273 -15.191 13.941 1.00 45.75 C
+ATOM 2849 O THR A 369 15.435 -15.596 14.128 1.00 46.25 O
+ATOM 2850 CB THR A 369 15.218 -12.861 13.788 1.00 41.49 C
+ATOM 2851 OG1 THR A 369 14.986 -12.539 15.192 1.00 41.13 O
+ATOM 2852 CG2 THR A 369 15.460 -11.621 12.954 1.00 41.92 C
+ATOM 2853 N LYS A 370 13.187 -15.871 14.252 1.00 48.47 N
+ATOM 2854 CA LYS A 370 13.181 -17.223 14.836 1.00 49.92 C
+ATOM 2855 C LYS A 370 13.385 -18.205 13.674 1.00 51.13 C
+ATOM 2856 O LYS A 370 12.344 -18.848 13.366 1.00 52.03 O
+ATOM 2857 CB LYS A 370 11.854 -17.548 15.503 1.00 50.75 C
+ATOM 2858 CG LYS A 370 11.790 -18.743 16.423 1.00 52.26 C
+ATOM 2859 CD LYS A 370 12.044 -18.370 17.881 1.00 54.25 C
+ATOM 2860 CE LYS A 370 13.499 -18.071 18.194 1.00 55.06 C
+ATOM 2861 NZ LYS A 370 14.151 -19.231 18.859 1.00 55.17 N
+ATOM 2862 OXT LYS A 370 14.519 -18.195 13.160 1.00 52.19 O
+TER 2862 LYS A 370
+END
diff --git a/docs/examples/malecoli/data/ariaproject_nmr.xml b/docs/examples/malecoli/data/ariaproject_nmr.xml
new file mode 100644
index 0000000000000000000000000000000000000000..f76e96e1b85f75eb775789423e9094291e90e8cf
--- /dev/null
+++ b/docs/examples/malecoli/data/ariaproject_nmr.xml
@@ -0,0 +1,179 @@
+<!DOCTYPE project SYSTEM "project1.0.dtd">
+<project name="MALE_ECOLI" version="1.0" author="" date="" description="" comment="" references="" working_directory="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI" temp_root="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI" run="1" file_root="MALE_ECOLI" cache="yes" cleanup="yes">
+ <data>
+ <ccpn_model filename=""/>
+ <molecule file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/xml/sequence.xml" format="xml" ccpn_id="">
+ <linkage_definition name="automatic" filename=""/>
+ <parameter_definition name="automatic" filename=""/>
+ <topology_definition name="automatic" filename=""/>
+ </molecule>
+ <spectrum enabled="yes" use_assignments="yes" trust_assigned_peaks="no" structural_rules="no" filter_diagonal_peaks="yes" filter_unassigned_peaks="no">
+ <shifts file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/xml/n20_cs.xml" format="xml" ccpn_id="" default_shift_error="0.0" use_shift_error="yes"/>
+ <peaks file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/xml/n20_peaks.xml" format="xml" ccpn_id="" peak_size="volume" freq_window_proton1="0.025" freq_window_hetero1="0.3" freq_window_proton2="0.04" freq_window_hetero2="0.5" use_bounds="no">
+ <lower_bound_correction value="0.0" enabled="no"/>
+ <upper_bound_correction value="6.0" enabled="no"/>
+ </peaks>
+ <experiment_data molecule_correlation_time="0.0" spectrum_mixing_time="0.0" spectrometer_frequency="0.0" ambiguity_type="intra"/>
+ </spectrum>
+ <spectrum enabled="yes" use_assignments="yes" trust_assigned_peaks="no" structural_rules="no" filter_diagonal_peaks="yes" filter_unassigned_peaks="no">
+ <shifts file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/xml/c_redo_cs.xml" format="xml" ccpn_id="" default_shift_error="0.0" use_shift_error="yes"/>
+ <peaks file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/xml/c_redo_peaks.xml" format="xml" ccpn_id="" peak_size="volume" freq_window_proton1="0.025" freq_window_hetero1="0.3" freq_window_proton2="0.04" freq_window_hetero2="0.5" use_bounds="no">
+ <lower_bound_correction value="0.0" enabled="no"/>
+ <upper_bound_correction value="6.0" enabled="no"/>
+ </peaks>
+ <experiment_data molecule_correlation_time="0.0" spectrum_mixing_time="0.0" spectrometer_frequency="0.0" ambiguity_type="intra"/>
+ </spectrum>
+ <spectrum enabled="yes" use_assignments="yes" trust_assigned_peaks="no" structural_rules="no" filter_diagonal_peaks="yes" filter_unassigned_peaks="no">
+ <shifts file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/xml/cc20_cs.xml" format="xml" ccpn_id="" default_shift_error="0.0" use_shift_error="yes"/>
+ <peaks file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/xml/cc20_peaks.xml" format="xml" ccpn_id="" peak_size="volume" freq_window_proton1="999.0" freq_window_hetero1="0.3" freq_window_proton2="0.03" freq_window_hetero2="0.3" use_bounds="no">
+ <lower_bound_correction value="0.0" enabled="no"/>
+ <upper_bound_correction value="6.0" enabled="no"/>
+ </peaks>
+ <experiment_data molecule_correlation_time="0.0" spectrum_mixing_time="0.0" spectrometer_frequency="0.0" ambiguity_type="intra"/>
+ </spectrum>
+ <spectrum enabled="yes" use_assignments="yes" trust_assigned_peaks="no" structural_rules="no" filter_diagonal_peaks="yes" filter_unassigned_peaks="no">
+ <shifts file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/xml/nn20_cs.xml" format="xml" ccpn_id="" default_shift_error="0.0" use_shift_error="yes"/>
+ <peaks file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/xml/nn20_peaks.xml" format="xml" ccpn_id="" peak_size="volume" freq_window_proton1="999.0" freq_window_hetero1="0.3" freq_window_proton2="0.03" freq_window_hetero2="0.3" use_bounds="no">
+ <lower_bound_correction value="0.0" enabled="no"/>
+ <upper_bound_correction value="6.0" enabled="no"/>
+ </peaks>
+ <experiment_data molecule_correlation_time="0.0" spectrum_mixing_time="0.0" spectrometer_frequency="0.0" ambiguity_type="intra"/>
+ </spectrum>
+ <spectrum enabled="yes" use_assignments="yes" trust_assigned_peaks="no" structural_rules="no" filter_diagonal_peaks="yes" filter_unassigned_peaks="no">
+ <shifts file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/xml/cn0_cs.xml" format="xml" ccpn_id="" default_shift_error="0.0" use_shift_error="yes"/>
+ <peaks file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/xml/cn0_peaks.xml" format="xml" ccpn_id="" peak_size="volume" freq_window_proton1="999.0" freq_window_hetero1="0.3" freq_window_proton2="0.03" freq_window_hetero2="0.3" use_bounds="no">
+ <lower_bound_correction value="0.0" enabled="no"/>
+ <upper_bound_correction value="6.0" enabled="no"/>
+ </peaks>
+ <experiment_data molecule_correlation_time="0.0" spectrum_mixing_time="0.0" spectrometer_frequency="0.0" ambiguity_type="intra"/>
+ </spectrum>
+ <spectrum enabled="yes" use_assignments="yes" trust_assigned_peaks="no" structural_rules="no" filter_diagonal_peaks="yes" filter_unassigned_peaks="no">
+ <shifts file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/xml/nc0_cs.xml" format="xml" ccpn_id="" default_shift_error="0.0" use_shift_error="yes"/>
+ <peaks file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/xml/nc0_peaks.xml" format="xml" ccpn_id="" peak_size="volume" freq_window_proton1="999.0" freq_window_hetero1="0.3" freq_window_proton2="0.03" freq_window_hetero2="0.3" use_bounds="no">
+ <lower_bound_correction value="0.0" enabled="no"/>
+ <upper_bound_correction value="6.0" enabled="no"/>
+ </peaks>
+ <experiment_data molecule_correlation_time="0.0" spectrum_mixing_time="0.0" spectrometer_frequency="0.0" ambiguity_type="intra"/>
+ </spectrum>
+ <rdcs file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/gel_exp.tbl" format="tbl" ccpn_id="" enabled="yes" parameter_class="1"/>
+ <dihedrals file="/baycells/home/fallain/Workspace/These/data/2017-04-ECNMR/MALE_ECOLI/talos.tbl" format="tbl" ccpn_id="" enabled="yes" data_type="standard"/>
+ <symmetry enabled="no" method="standard" n_monomers="1" symmetry_type="None" ncs_enabled="no" packing_enabled="no"/>
+ <initial_structure file="" format="iupac" ccpn_id="" enabled="no"/>
+ </data>
+ <structure_generation engine="cns">
+ <cns local_executable="/baycells/home/bardiaux/Progs/aria2.3.2_hbdb/cns1.21_aria_logn_hbdb_linux_x86_64_intel.exe" keep_output="no" keep_restraint_files="yes" create_psf_file="yes" generate_template="yes" nonbonded_parameters="PROLSQ">
+ <annealing_parameters>
+ <unambiguous_restraints first_iteration="0" k_hot="10.0" k_cool1_initial="10.0" k_cool1_final="50.0" k_cool2="50.0"/>
+ <ambiguous_restraints first_iteration="0" k_hot="10.0" k_cool1_initial="10.0" k_cool1_final="50.0" k_cool2="50.0"/>
+ <hbond_restraints first_iteration="0" k_hot="10.0" k_cool1_initial="10.0" k_cool1_final="50.0" k_cool2="50.0"/>
+ <dihedral_restraints k_hot="5.0" k_cool1="25.0" k_cool2="200.0"/>
+ <karplus_restraints parameter_class="1" a="6.98" b="-1.38" c="1.72" d="-60.0" k_hot="0.0" k_cool1="0.2" k_cool2="1.0"/>
+ <karplus_restraints parameter_class="2" a="6.98" b="-1.38" c="1.72" d="-60.0" k_hot="0.0" k_cool1="0.2" k_cool2="1.0"/>
+ <karplus_restraints parameter_class="3" a="6.98" b="-1.38" c="1.72" d="-60.0" k_hot="0.0" k_cool1="0.2" k_cool2="1.0"/>
+ <karplus_restraints parameter_class="4" a="6.98" b="-1.38" c="1.72" d="-60.0" k_hot="0.0" k_cool1="0.2" k_cool2="1.0"/>
+ <karplus_restraints parameter_class="5" a="6.98" b="-1.38" c="1.72" d="-60.0" k_hot="0.0" k_cool1="0.2" k_cool2="1.0"/>
+ <rdc_restraints parameter_class="1" method="SANI" first_iteration="4" k_hot="0.0" k_cool1="0.02" k_cool2="0.5" r="0.157" d="17.536" border_hot_initial="0.1" border_hot_final="40.0" border_cool1_initial="40.0" border_cool1_final="40.0" border_cool2_initial="40.0" border_cool2_final="40.0" center_hot_initial="0.1" center_hot_final="0.1" center_cool1_initial="10.0" center_cool1_final="10.0" center_cool2_initial="10.0" center_cool2_final="10.0"/>
+ <rdc_restraints parameter_class="2" method="SANI" first_iteration="0" k_hot="0.0" k_cool1="0.2" k_cool2="1.0" r="0.4" d="8.0" border_hot_initial="0.1" border_hot_final="40.0" border_cool1_initial="40.0" border_cool1_final="40.0" border_cool2_initial="40.0" border_cool2_final="40.0" center_hot_initial="0.1" center_hot_final="0.1" center_cool1_initial="10.0" center_cool1_final="10.0" center_cool2_initial="10.0" center_cool2_final="10.0"/>
+ <rdc_restraints parameter_class="3" method="SANI" first_iteration="0" k_hot="0.0" k_cool1="0.2" k_cool2="1.0" r="0.4" d="8.0" border_hot_initial="0.1" border_hot_final="40.0" border_cool1_initial="40.0" border_cool1_final="40.0" border_cool2_initial="40.0" border_cool2_final="40.0" center_hot_initial="0.1" center_hot_final="0.1" center_cool1_initial="10.0" center_cool1_final="10.0" center_cool2_initial="10.0" center_cool2_final="10.0"/>
+ <rdc_restraints parameter_class="4" method="SANI" first_iteration="0" k_hot="0.0" k_cool1="0.2" k_cool2="1.0" r="0.4" d="8.0" border_hot_initial="0.1" border_hot_final="40.0" border_cool1_initial="40.0" border_cool1_final="40.0" border_cool2_initial="40.0" border_cool2_final="40.0" center_hot_initial="0.1" center_hot_final="0.1" center_cool1_initial="10.0" center_cool1_final="10.0" center_cool2_initial="10.0" center_cool2_final="10.0"/>
+ <rdc_restraints parameter_class="5" method="SANI" first_iteration="0" k_hot="0.0" k_cool1="0.2" k_cool2="1.0" r="0.4" d="8.0" border_hot_initial="0.1" border_hot_final="40.0" border_cool1_initial="40.0" border_cool1_final="40.0" border_cool2_initial="40.0" border_cool2_final="40.0" center_hot_initial="0.1" center_hot_final="0.1" center_cool1_initial="10.0" center_cool1_final="10.0" center_cool2_initial="10.0" center_cool2_final="10.0"/>
+ <flat_bottom_harmonic_wall m_rswitch_hot="0.5" m_rswitch_cool1="0.5" m_rswitch_cool2="0.5" rswitch_hot="0.5" rswitch_cool1="0.5" rswitch_cool2="0.5" m_asymptote_hot="-1.0" m_asymptote_cool1="-1.0" m_asymptote_cool2="-0.1" asymptote_hot="1.0" asymptote_cool1="1.0" asymptote_cool2="0.1"/>
+ <symmetry_restraints k_packing_hot="15.0" k_packing_cool1="10.0" k_packing_cool2="5.0" last_iteration_packing="8" k_ncs="50.0"/>
+ <logharmonic_potential enabled="no" use_auto_weight="no" weight_unambig="25.0" weight_ambig="25.0" weight_hbond="25.0"/>
+ <rama_potential enabled="no" weight_rama="1.0"/>
+ </annealing_parameters>
+ <md_parameters dynamics="torsion" random_seed="89764443" tad_temp_high="10000.0" tad_timestep_factor="9.0" cartesian_temp_high="2000.0" cartesian_first_iteration="0" timestep="0.003" temp_cool1_final="1000.0" temp_cool2_final="50.0" steps_high="20000" steps_refine="4000" steps_cool1="30000" steps_cool2="30000"/>
+ </cns>
+ <job_manager default_command="csh -f">
+ <host enabled="yes" command="qsub -@ /Bis/home/bardiaux/sge_options.sge" executable="" n_cpu="60" use_absolute_path="yes"/>
+ </job_manager>
+ </structure_generation>
+ <protocol floating_assignment="yes">
+ <iteration number="0" n_structures="100" sort_criterion="total_energy" n_best_structures="15" n_kept_structures="0">
+ <assignment/>
+ <merging method="combination4_4"/>
+ <calibration relaxation_matrix="no" distance_cutoff="6.0" estimator="ratio_of_averages" error_estimator="distance"/>
+ <violation_analysis sigma_mode="fix" violation_tolerance="1000.0" violation_threshold="0.5"/>
+ <partial_assignment weight_threshold="1.0" max_contributions="20"/>
+ <network_anchoring high_residue_threshold="4.0" enabled="yes" min_residue_threshold="1.0" min_atom_threshold="0.25"/>
+ </iteration>
+ <iteration number="1" n_structures="100" sort_criterion="total_energy" n_best_structures="15" n_kept_structures="0">
+ <assignment/>
+ <merging method="combination4_4"/>
+ <calibration relaxation_matrix="no" distance_cutoff="6.0" estimator="ratio_of_averages" error_estimator="distance"/>
+ <violation_analysis sigma_mode="fix" violation_tolerance="5.0" violation_threshold="0.5"/>
+ <partial_assignment weight_threshold="0.9999" max_contributions="20"/>
+ <network_anchoring high_residue_threshold="4.0" enabled="yes" min_residue_threshold="1.0" min_atom_threshold="0.25"/>
+ </iteration>
+ <iteration number="2" n_structures="100" sort_criterion="total_energy" n_best_structures="15" n_kept_structures="0">
+ <assignment/>
+ <merging method="combination4_4"/>
+ <calibration relaxation_matrix="no" distance_cutoff="6.0" estimator="ratio_of_averages" error_estimator="distance"/>
+ <violation_analysis sigma_mode="fix" violation_tolerance="3.0" violation_threshold="0.5"/>
+ <partial_assignment weight_threshold="0.999" max_contributions="20"/>
+ <network_anchoring high_residue_threshold="4.0" enabled="no" min_residue_threshold="1.0" min_atom_threshold="0.25"/>
+ </iteration>
+ <iteration number="3" n_structures="100" sort_criterion="total_energy" n_best_structures="15" n_kept_structures="0">
+ <assignment/>
+ <merging method="standard"/>
+ <calibration relaxation_matrix="no" distance_cutoff="6.0" estimator="ratio_of_averages" error_estimator="distance"/>
+ <violation_analysis sigma_mode="fix" violation_tolerance="1.0" violation_threshold="0.5"/>
+ <partial_assignment weight_threshold="0.99" max_contributions="20"/>
+ <network_anchoring high_residue_threshold="4.0" enabled="no" min_residue_threshold="1.0" min_atom_threshold="0.25"/>
+ </iteration>
+ <iteration number="4" n_structures="100" sort_criterion="total_energy" n_best_structures="15" n_kept_structures="0">
+ <assignment/>
+ <merging method="standard"/>
+ <calibration relaxation_matrix="no" distance_cutoff="6.0" estimator="ratio_of_averages" error_estimator="distance"/>
+ <violation_analysis sigma_mode="fix" violation_tolerance="1.0" violation_threshold="0.5"/>
+ <partial_assignment weight_threshold="0.98" max_contributions="20"/>
+ <network_anchoring high_residue_threshold="4.0" enabled="no" min_residue_threshold="1.0" min_atom_threshold="0.25"/>
+ </iteration>
+ <iteration number="5" n_structures="100" sort_criterion="total_energy" n_best_structures="15" n_kept_structures="0">
+ <assignment/>
+ <merging method="standard"/>
+ <calibration relaxation_matrix="no" distance_cutoff="6.0" estimator="ratio_of_averages" error_estimator="distance"/>
+ <violation_analysis sigma_mode="fix" violation_tolerance="1.0" violation_threshold="0.5"/>
+ <partial_assignment weight_threshold="0.96" max_contributions="20"/>
+ <network_anchoring high_residue_threshold="4.0" enabled="no" min_residue_threshold="1.0" min_atom_threshold="0.25"/>
+ </iteration>
+ <iteration number="6" n_structures="100" sort_criterion="total_energy" n_best_structures="15" n_kept_structures="0">
+ <assignment/>
+ <merging method="standard"/>
+ <calibration relaxation_matrix="no" distance_cutoff="6.0" estimator="ratio_of_averages" error_estimator="distance"/>
+ <violation_analysis sigma_mode="fix" violation_tolerance="0.1" violation_threshold="0.5"/>
+ <partial_assignment weight_threshold="0.93" max_contributions="20"/>
+ <network_anchoring high_residue_threshold="4.0" enabled="no" min_residue_threshold="1.0" min_atom_threshold="0.25"/>
+ </iteration>
+ <iteration number="7" n_structures="100" sort_criterion="total_energy" n_best_structures="15" n_kept_structures="0">
+ <assignment/>
+ <merging method="standard"/>
+ <calibration relaxation_matrix="no" distance_cutoff="6.0" estimator="ratio_of_averages" error_estimator="distance"/>
+ <violation_analysis sigma_mode="fix" violation_tolerance="0.1" violation_threshold="0.5"/>
+ <partial_assignment weight_threshold="0.9" max_contributions="20"/>
+ <network_anchoring high_residue_threshold="4.0" enabled="no" min_residue_threshold="1.0" min_atom_threshold="0.25"/>
+ </iteration>
+ <iteration number="8" n_structures="100" sort_criterion="total_energy" n_best_structures="15" n_kept_structures="0">
+ <assignment/>
+ <merging method="standard"/>
+ <calibration relaxation_matrix="no" distance_cutoff="6.0" estimator="ratio_of_averages" error_estimator="distance"/>
+ <violation_analysis sigma_mode="fix" violation_tolerance="0.1" violation_threshold="0.5"/>
+ <partial_assignment weight_threshold="0.8" max_contributions="20"/>
+ <network_anchoring high_residue_threshold="4.0" enabled="no" min_residue_threshold="1.0" min_atom_threshold="0.25"/>
+ </iteration>
+ <water_refinement solvent="water" n_structures="15" enabled="yes" write_solvent_molecules="no"/>
+ </protocol>
+ <analysis>
+ <structures_analysis enabled="yes"/>
+ <procheck executable="procheck" enabled="yes"/>
+ <prosa executable="prosa" enabled="yes"/>
+ <whatif executable="whatif" enabled="yes"/>
+ <clashlist executable="" enabled="no"/>
+ </analysis>
+ <report>
+ <ccpn export_assignments="no" export_noe_restraint_list="no" export_structures="no"/>
+ <molmol enabled="yes"/>
+ <noe_restraint_list pickle_output="no" text_output="yes" xml_output="no"/>
+ <spectra write_assigned="no" write_assigned_force="no" iteration="last" write_unambiguous_only="yes"/>
+ </report>
+</project>
\ No newline at end of file
diff --git a/docs/examples/malecoli/data/config.ini b/docs/examples/malecoli/data/config.ini
index 24ad5a6944b251d2ec59dc4315ee8ec7dd1e225c..48140315fe22d2046597db042f03867c9de09d7d 100644
--- a/docs/examples/malecoli/data/config.ini
+++ b/docs/examples/malecoli/data/config.ini
@@ -8,9 +8,9 @@ n_factor: 1.0
# ARIA project parameters
# -----------------------
host_command: sbatch -t 06:00:00
-host_executable: /path/to/cns1.21.exe
-cns_executable: /path/to/cns1.21.exe
-temp_root: /path/to/tempdir
+host_executable: /baycells/home/fallain/Applications/CNS/cns1.21_aria_logn_hbdb_linux_x86_64_intel.exe
+cns_executable: /baycells/home/fallain/Applications/CNS/cns1.21_aria_logn_hbdb_linux_x86_64_intel.exe
+temp_root: /baycells/scratch/fallain/tmp
# Protocol parameters
# -------------------
rama_potential_enabled: yes
diff --git a/docs/examples/malecoli/data/tbl/gel_exp.tbl b/docs/examples/malecoli/data/tbl/gel_exp.tbl
new file mode 100644
index 0000000000000000000000000000000000000000..7445e57f5b0ca2d04d746def24b7b80a70de9d56
--- /dev/null
+++ b/docs/examples/malecoli/data/tbl/gel_exp.tbl
@@ -0,0 +1,1682 @@
+! 17.536 0.157
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 3 and name HN) (resid 3 and name N) 5.750 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 4 and name HN) (resid 4 and name N) 0.180 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 5 and name HN) (resid 5 and name N) -1.160 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 6 and name HN) (resid 6 and name N) -10.260 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 7 and name HN) (resid 7 and name N) -12.800 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 8 and name HN) (resid 8 and name N) -12.030 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 9 and name HN) (resid 9 and name N) -12.810 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 10 and name HN) (resid 10 and name N) -18.950 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 11 and name HN) (resid 11 and name N) -13.700 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 12 and name HN) (resid 12 and name N) -12.100 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 13 and name HN) (resid 13 and name N) -15.690 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 14 and name HN) (resid 14 and name N) -12.380 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 15 and name HN) (resid 15 and name N) 5.540 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 16 and name HN) (resid 16 and name N) -5.210 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 17 and name HN) (resid 17 and name N) 6.710 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 18 and name HN) (resid 18 and name N) 29.830 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 19 and name HN) (resid 19 and name N) 24.360 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 20 and name HN) (resid 20 and name N) 11.190 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 21 and name HN) (resid 21 and name N) 11.380 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 22 and name HN) (resid 22 and name N) 32.220 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 23 and name HN) (resid 23 and name N) 16.890 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 24 and name HN) (resid 24 and name N) 15.620 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 25 and name HN) (resid 25 and name N) 25.650 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 26 and name HN) (resid 26 and name N) 31.690 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 27 and name HN) (resid 27 and name N) 21.040 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 28 and name HN) (resid 28 and name N) 19.590 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 29 and name HN) (resid 29 and name N) 32.610 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 31 and name HN) (resid 31 and name N) 13.700 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 32 and name HN) (resid 32 and name N) 10.750 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 35 and name HN) (resid 35 and name N) -12.830 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 36 and name HN) (resid 36 and name N) -12.680 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 37 and name HN) (resid 37 and name N) -11.250 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 38 and name HN) (resid 38 and name N) -15.990 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 39 and name HN) (resid 39 and name N) -10.930 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 42 and name HN) (resid 42 and name N) 11.810 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 43 and name HN) (resid 43 and name N) -7.380 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 44 and name HN) (resid 44 and name N) 10.540 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 47 and name HN) (resid 47 and name N) 16.240 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 49 and name HN) (resid 49 and name N) 1.940 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 50 and name HN) (resid 50 and name N) 15.890 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 51 and name HN) (resid 51 and name N) 32.420 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 52 and name HN) (resid 52 and name N) 11.250 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 53 and name HN) (resid 53 and name N) 11.600 5.000
+
+assign ( resid 999 and name OO)
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+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 55 and name HN) (resid 55 and name N) 1.770 5.000
+
+assign ( resid 999 and name OO)
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+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 56 and name HN) (resid 56 and name N) -2.520 5.000
+
+assign ( resid 999 and name OO)
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+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 58 and name HN) (resid 58 and name N) -10.470 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 59 and name HN) (resid 59 and name N) -16.490 5.000
+
+assign ( resid 999 and name OO)
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+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 60 and name HN) (resid 60 and name N) -20.030 5.000
+
+assign ( resid 999 and name OO)
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+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 61 and name HN) (resid 61 and name N) -17.400 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 62 and name HN) (resid 62 and name N) -22.860 5.000
+
+assign ( resid 999 and name OO)
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+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 63 and name HN) (resid 63 and name N) -19.020 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 64 and name HN) (resid 64 and name N) -11.500 5.000
+
+assign ( resid 999 and name OO)
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+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 65 and name HN) (resid 65 and name N) -4.250 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 66 and name HN) (resid 66 and name N) -10.470 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 67 and name HN) (resid 67 and name N) 3.080 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 68 and name HN) (resid 68 and name N) 21.500 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 69 and name HN) (resid 69 and name N) 10.520 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 72 and name HN) (resid 72 and name N) 16.410 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 73 and name HN) (resid 73 and name N) -1.880 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 74 and name HN) (resid 74 and name N) 15.310 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 75 and name HN) (resid 75 and name N) 33.540 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 76 and name HN) (resid 76 and name N) -3.330 5.000
+
+assign ( resid 999 and name OO)
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+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 77 and name HN) (resid 77 and name N) -14.440 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 80 and name HN) (resid 80 and name N) 6.660 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 82 and name HN) (resid 82 and name N) 8.730 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 84 and name HN) (resid 84 and name N) 25.260 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 85 and name HN) (resid 85 and name N) 9.280 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 87 and name HN) (resid 87 and name N) 21.440 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 88 and name HN) (resid 88 and name N) 16.540 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 89 and name HN) (resid 89 and name N) -7.860 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 93 and name HN) (resid 93 and name N) -15.370 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 94 and name HN) (resid 94 and name N) -14.090 5.000
+
+assign ( resid 999 and name OO)
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+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 95 and name HN) (resid 95 and name N) -2.360 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 96 and name HN) (resid 96 and name N) -11.760 5.000
+
+assign ( resid 999 and name OO)
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+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 97 and name HN) (resid 97 and name N) -19.280 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 98 and name HN) (resid 98 and name N) 31.860 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 99 and name HN) (resid 99 and name N) 25.580 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 102 and name HN) (resid 102 and name N) -8.140 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 103 and name HN) (resid 103 and name N) 12.260 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 105 and name HN) (resid 105 and name N) -14.470 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 106 and name HN) (resid 106 and name N) -12.810 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 108 and name HN) (resid 108 and name N) -9.830 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 109 and name HN) (resid 109 and name N) -15.010 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 111 and name HN) (resid 111 and name N) -7.130 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 112 and name HN) (resid 112 and name N) -13.140 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 113 and name HN) (resid 113 and name N) -12.710 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 114 and name HN) (resid 114 and name N) -18.590 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 115 and name HN) (resid 115 and name N) -20.130 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 116 and name HN) (resid 116 and name N) -11.080 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 117 and name HN) (resid 117 and name N) 4.570 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 118 and name HN) (resid 118 and name N) 9.860 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 119 and name HN) (resid 119 and name N) 30.110 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 120 and name HN) (resid 120 and name N) 6.500 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 121 and name HN) (resid 121 and name N) 23.450 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 124 and name HN) (resid 124 and name N) -1.830 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 127 and name HN) (resid 127 and name N) 24.970 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 128 and name HN) (resid 128 and name N) 2.550 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 129 and name HN) (resid 129 and name N) -8.400 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 130 and name HN) (resid 130 and name N) -13.340 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 134 and name HN) (resid 134 and name N) -14.740 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 135 and name HN) (resid 135 and name N) -5.650 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 136 and name HN) (resid 136 and name N) -14.360 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 137 and name HN) (resid 137 and name N) -18.430 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 139 and name HN) (resid 139 and name N) -12.680 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 140 and name HN) (resid 140 and name N) -14.660 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 141 and name HN) (resid 141 and name N) -19.620 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 143 and name HN) (resid 143 and name N) 14.670 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 144 and name HN) (resid 144 and name N) 15.190 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 145 and name HN) (resid 145 and name N) 21.820 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 146 and name HN) (resid 146 and name N) 13.340 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 147 and name HN) (resid 147 and name N) 11.190 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 148 and name HN) (resid 148 and name N) -0.420 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 149 and name HN) (resid 149 and name N) 7.220 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 150 and name HN) (resid 150 and name N) 6.750 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 151 and name HN) (resid 151 and name N) -10.940 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 152 and name HN) (resid 152 and name N) -8.860 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 153 and name HN) (resid 153 and name N) -3.640 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 156 and name HN) (resid 156 and name N) -18.720 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 157 and name HN) (resid 157 and name N) -0.720 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 158 and name HN) (resid 158 and name N) 10.720 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 160 and name HN) (resid 160 and name N) -15.170 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 161 and name HN) (resid 161 and name N) 7.730 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 162 and name HN) (resid 162 and name N) -2.000 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 163 and name HN) (resid 163 and name N) -17.540 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 164 and name HN) (resid 164 and name N) -17.440 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 165 and name HN) (resid 165 and name N) -0.050 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 166 and name HN) (resid 166 and name N) -6.570 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 167 and name HN) (resid 167 and name N) -9.480 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 168 and name HN) (resid 168 and name N) -6.470 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 169 and name HN) (resid 169 and name N) -5.310 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 170 and name HN) (resid 170 and name N) -7.960 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 171 and name HN) (resid 171 and name N) 12.580 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 172 and name HN) (resid 172 and name N) 4.130 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 174 and name HN) (resid 174 and name N) 10.480 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 175 and name HN) (resid 175 and name N) 10.730 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 176 and name HN) (resid 176 and name N) 22.370 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 177 and name HN) (resid 177 and name N) 4.510 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 178 and name HN) (resid 178 and name N) 17.860 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 180 and name HN) (resid 180 and name N) 25.860 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 181 and name HN) (resid 181 and name N) 1.630 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 182 and name HN) (resid 182 and name N) 15.360 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 183 and name HN) (resid 183 and name N) -0.350 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 184 and name HN) (resid 184 and name N) 11.140 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 185 and name HN) (resid 185 and name N) 1.190 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 187 and name HN) (resid 187 and name N) 3.270 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 188 and name HN) (resid 188 and name N) -9.290 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 189 and name HN) (resid 189 and name N) -15.670 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 190 and name HN) (resid 190 and name N) -7.980 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 191 and name HN) (resid 191 and name N) -0.490 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 194 and name HN) (resid 194 and name N) -1.380 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 195 and name HN) (resid 195 and name N) -3.660 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 196 and name HN) (resid 196 and name N) -13.640 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 198 and name HN) (resid 198 and name N) 7.190 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 199 and name HN) (resid 199 and name N) -9.580 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 200 and name HN) (resid 200 and name N) -12.020 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 201 and name HN) (resid 201 and name N) 3.860 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 202 and name HN) (resid 202 and name N) -3.560 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 204 and name HN) (resid 204 and name N) 3.900 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 205 and name HN) (resid 205 and name N) 10.190 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 207 and name HN) (resid 207 and name N) 16.530 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 208 and name HN) (resid 208 and name N) 19.640 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 209 and name HN) (resid 209 and name N) -17.030 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 210 and name HN) (resid 210 and name N) -3.900 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 211 and name HN) (resid 211 and name N) -10.970 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 212 and name HN) (resid 212 and name N) -12.930 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 213 and name HN) (resid 213 and name N) -2.280 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 217 and name HN) (resid 217 and name N) 0.330 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 220 and name HN) (resid 220 and name N) 7.130 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 221 and name HN) (resid 221 and name N) 25.550 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 222 and name HN) (resid 222 and name N) 25.850 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 223 and name HN) (resid 223 and name N) 21.170 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 224 and name HN) (resid 224 and name N) 1.400 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 225 and name HN) (resid 225 and name N) -14.070 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 226 and name HN) (resid 226 and name N) -19.340 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 227 and name HN) (resid 227 and name N) -20.650 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 228 and name HN) (resid 228 and name N) -19.300 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 240 and name HN) (resid 240 and name N) -7.340 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 243 and name HN) (resid 243 and name N) 8.940 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 244 and name HN) (resid 244 and name N) -10.230 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 245 and name HN) (resid 245 and name N) -13.970 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 246 and name HN) (resid 246 and name N) -7.610 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 247 and name HN) (resid 247 and name N) 17.190 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 249 and name HN) (resid 249 and name N) 1.760 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 250 and name HN) (resid 250 and name N) 4.140 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 251 and name HN) (resid 251 and name N) 2.030 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 252 and name HN) (resid 252 and name N) -19.530 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 253 and name HN) (resid 253 and name N) -8.880 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 256 and name HN) (resid 256 and name N) 2.510 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 258 and name HN) (resid 258 and name N) -12.180 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 259 and name HN) (resid 259 and name N) -15.700 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 260 and name HN) (resid 260 and name N) -6.570 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 261 and name HN) (resid 261 and name N) -13.490 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 262 and name HN) (resid 262 and name N) -9.500 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 263 and name HN) (resid 263 and name N) -17.280 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 264 and name HN) (resid 264 and name N) -21.950 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 265 and name HN) (resid 265 and name N) -17.760 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 266 and name HN) (resid 266 and name N) -12.680 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 267 and name HN) (resid 267 and name N) -9.180 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 268 and name HN) (resid 268 and name N) 21.980 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 269 and name HN) (resid 269 and name N) 15.580 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 270 and name HN) (resid 270 and name N) 20.790 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 272 and name HN) (resid 272 and name N) 11.440 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 273 and name HN) (resid 273 and name N) -0.270 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 275 and name HN) (resid 275 and name N) -3.130 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 277 and name HN) (resid 277 and name N) 13.350 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 278 and name HN) (resid 278 and name N) 10.280 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 279 and name HN) (resid 279 and name N) -1.340 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 280 and name HN) (resid 280 and name N) 0.160 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 281 and name HN) (resid 281 and name N) 15.910 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 282 and name HN) (resid 282 and name N) 0.010 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 283 and name HN) (resid 283 and name N) -10.970 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 284 and name HN) (resid 284 and name N) 2.720 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 285 and name HN) (resid 285 and name N) 13.250 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 286 and name HN) (resid 286 and name N) -18.330 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 287 and name HN) (resid 287 and name N) -14.590 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 288 and name HN) (resid 288 and name N) -2.830 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 289 and name HN) (resid 289 and name N) -17.760 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 292 and name HN) (resid 292 and name N) -0.610 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 293 and name HN) (resid 293 and name N) -16.810 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 294 and name HN) (resid 294 and name N) -11.370 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 295 and name HN) (resid 295 and name N) 15.790 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 296 and name HN) (resid 296 and name N) -9.500 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 297 and name HN) (resid 297 and name N) -3.440 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 299 and name HN) (resid 299 and name N) -7.840 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 300 and name HN) (resid 300 and name N) -8.390 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 301 and name HN) (resid 301 and name N) -8.650 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 302 and name HN) (resid 302 and name N) -10.230 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 303 and name HN) (resid 303 and name N) -6.650 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 304 and name HN) (resid 304 and name N) -19.400 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 305 and name HN) (resid 305 and name N) -2.600 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 306 and name HN) (resid 306 and name N) 13.280 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 307 and name HN) (resid 307 and name N) 1.110 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 308 and name HN) (resid 308 and name N) -1.840 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 309 and name HN) (resid 309 and name N) 17.380 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 310 and name HN) (resid 310 and name N) 11.890 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 311 and name HN) (resid 311 and name N) 7.450 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 312 and name HN) (resid 312 and name N) 5.370 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 314 and name HN) (resid 314 and name N) 11.500 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 316 and name HN) (resid 316 and name N) 3.230 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 317 and name HN) (resid 317 and name N) -12.840 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 318 and name HN) (resid 318 and name N) -9.900 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 319 and name HN) (resid 319 and name N) -14.490 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 320 and name HN) (resid 320 and name N) -5.060 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 322 and name HN) (resid 322 and name N) -13.840 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 323 and name HN) (resid 323 and name N) -8.240 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 325 and name HN) (resid 325 and name N) -10.410 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 326 and name HN) (resid 326 and name N) -15.370 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 327 and name HN) (resid 327 and name N) 11.620 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 328 and name HN) (resid 328 and name N) -15.350 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 329 and name HN) (resid 329 and name N) -19.610 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 330 and name HN) (resid 330 and name N) -8.990 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 332 and name HN) (resid 332 and name N) -20.670 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 333 and name HN) (resid 333 and name N) 18.430 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 335 and name HN) (resid 335 and name N) -12.230 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 336 and name HN) (resid 336 and name N) 25.780 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 338 and name HN) (resid 338 and name N) 1.350 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 339 and name HN) (resid 339 and name N) 22.010 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 340 and name HN) (resid 340 and name N) 28.340 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 341 and name HN) (resid 341 and name N) 17.310 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 342 and name HN) (resid 342 and name N) 13.000 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 343 and name HN) (resid 343 and name N) 29.750 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 345 and name HN) (resid 345 and name N) 18.210 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 346 and name HN) (resid 346 and name N) 19.490 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 348 and name HN) (resid 348 and name N) 27.140 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 349 and name HN) (resid 349 and name N) 17.540 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 350 and name HN) (resid 350 and name N) 22.710 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 351 and name HN) (resid 351 and name N) 31.740 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 352 and name HN) (resid 352 and name N) 17.000 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 353 and name HN) (resid 353 and name N) -5.960 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 354 and name HN) (resid 354 and name N) 10.240 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 355 and name HN) (resid 355 and name N) -8.990 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 356 and name HN) (resid 356 and name N) -11.740 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 358 and name HN) (resid 358 and name N) 29.840 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 359 and name HN) (resid 359 and name N) 14.750 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 360 and name HN) (resid 360 and name N) 20.390 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 361 and name HN) (resid 361 and name N) 31.430 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 363 and name HN) (resid 363 and name N) 16.810 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 365 and name HN) (resid 365 and name N) 32.750 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 367 and name HN) (resid 367 and name N) 15.690 5.000
+
+assign ( resid 999 and name OO)
+ ( resid 999 and name Z )
+ ( resid 999 and name X )
+ ( resid 999 and name Y )
+ ( resid 370 and name HN) (resid 370 and name N) -3.390 5.000
+
diff --git a/docs/examples/malecoli/data/tbl/talos.tbl b/docs/examples/malecoli/data/tbl/talos.tbl
new file mode 100644
index 0000000000000000000000000000000000000000..25c65d139d50bddcf87f93132fdf619f6543cdb7
--- /dev/null
+++ b/docs/examples/malecoli/data/tbl/talos.tbl
@@ -0,0 +1,1917 @@
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+ ASSIGN (segid " A" and resid 321 and name N ) (segid " A" and resid 321 and name CA )
+ (segid " A" and resid 321 and name C ) (segid " A" and resid 322 and name N ) 1.00 -36.60 20.00 2
+
+ ASSIGN (segid " A" and resid 321 and name C ) (segid " A" and resid 322 and name N )
+ (segid " A" and resid 322 and name CA ) (segid " A" and resid 322 and name C ) 1.00 -65.80 20.00 2
+
+ ASSIGN (segid " A" and resid 322 and name N ) (segid " A" and resid 322 and name CA )
+ (segid " A" and resid 322 and name C ) (segid " A" and resid 323 and name N ) 1.00 -40.90 20.00 2
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+ ASSIGN (segid " A" and resid 322 and name C ) (segid " A" and resid 323 and name N )
+ (segid " A" and resid 323 and name CA ) (segid " A" and resid 323 and name C ) 1.00 -65.10 20.00 2
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+ ASSIGN (segid " A" and resid 323 and name N ) (segid " A" and resid 323 and name CA )
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+ ASSIGN (segid " A" and resid 323 and name C ) (segid " A" and resid 324 and name N )
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+ ASSIGN (segid " A" and resid 324 and name N ) (segid " A" and resid 324 and name CA )
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+ ASSIGN (segid " A" and resid 324 and name C ) (segid " A" and resid 325 and name N )
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+ ASSIGN (segid " A" and resid 325 and name N ) (segid " A" and resid 325 and name CA )
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+ ASSIGN (segid " A" and resid 325 and name C ) (segid " A" and resid 326 and name N )
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+ ASSIGN (segid " A" and resid 328 and name N ) (segid " A" and resid 328 and name CA )
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+ ASSIGN (segid " A" and resid 332 and name N ) (segid " A" and resid 332 and name CA )
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+ ASSIGN (segid " A" and resid 334 and name N ) (segid " A" and resid 334 and name CA )
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+ ASSIGN (segid " A" and resid 334 and name C ) (segid " A" and resid 335 and name N )
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+ ASSIGN (segid " A" and resid 335 and name C ) (segid " A" and resid 336 and name N )
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+ ASSIGN (segid " A" and resid 336 and name C ) (segid " A" and resid 337 and name N )
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+ ASSIGN (segid " A" and resid 337 and name N ) (segid " A" and resid 337 and name CA )
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+ ASSIGN (segid " A" and resid 338 and name N ) (segid " A" and resid 338 and name CA )
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+ ASSIGN (segid " A" and resid 339 and name N ) (segid " A" and resid 339 and name CA )
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+ ASSIGN (segid " A" and resid 339 and name C ) (segid " A" and resid 340 and name N )
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+ ASSIGN (segid " A" and resid 340 and name N ) (segid " A" and resid 340 and name CA )
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+ ASSIGN (segid " A" and resid 340 and name C ) (segid " A" and resid 341 and name N )
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+ ASSIGN (segid " A" and resid 341 and name N ) (segid " A" and resid 341 and name CA )
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+ ASSIGN (segid " A" and resid 341 and name C ) (segid " A" and resid 342 and name N )
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+ ASSIGN (segid " A" and resid 342 and name N ) (segid " A" and resid 342 and name CA )
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+ ASSIGN (segid " A" and resid 342 and name C ) (segid " A" and resid 343 and name N )
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+ ASSIGN (segid " A" and resid 343 and name N ) (segid " A" and resid 343 and name CA )
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+ ASSIGN (segid " A" and resid 343 and name C ) (segid " A" and resid 344 and name N )
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+ ASSIGN (segid " A" and resid 344 and name N ) (segid " A" and resid 344 and name CA )
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+ ASSIGN (segid " A" and resid 344 and name C ) (segid " A" and resid 345 and name N )
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+ ASSIGN (segid " A" and resid 345 and name N ) (segid " A" and resid 345 and name CA )
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+ ASSIGN (segid " A" and resid 345 and name C ) (segid " A" and resid 346 and name N )
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+ ASSIGN (segid " A" and resid 346 and name N ) (segid " A" and resid 346 and name CA )
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+ ASSIGN (segid " A" and resid 346 and name C ) (segid " A" and resid 347 and name N )
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+ ASSIGN (segid " A" and resid 347 and name N ) (segid " A" and resid 347 and name CA )
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+ ASSIGN (segid " A" and resid 347 and name C ) (segid " A" and resid 348 and name N )
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+ ASSIGN (segid " A" and resid 348 and name N ) (segid " A" and resid 348 and name CA )
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+ ASSIGN (segid " A" and resid 348 and name C ) (segid " A" and resid 349 and name N )
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+ ASSIGN (segid " A" and resid 349 and name N ) (segid " A" and resid 349 and name CA )
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+ ASSIGN (segid " A" and resid 349 and name C ) (segid " A" and resid 350 and name N )
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+
+ ASSIGN (segid " A" and resid 350 and name N ) (segid " A" and resid 350 and name CA )
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+ ASSIGN (segid " A" and resid 350 and name C ) (segid " A" and resid 351 and name N )
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+ ASSIGN (segid " A" and resid 351 and name N ) (segid " A" and resid 351 and name CA )
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+ ASSIGN (segid " A" and resid 351 and name C ) (segid " A" and resid 352 and name N )
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+ ASSIGN (segid " A" and resid 352 and name N ) (segid " A" and resid 352 and name CA )
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+ ASSIGN (segid " A" and resid 352 and name C ) (segid " A" and resid 353 and name N )
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+ ASSIGN (segid " A" and resid 353 and name N ) (segid " A" and resid 353 and name CA )
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+ ASSIGN (segid " A" and resid 353 and name C ) (segid " A" and resid 354 and name N )
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+ ASSIGN (segid " A" and resid 354 and name N ) (segid " A" and resid 354 and name CA )
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+ ASSIGN (segid " A" and resid 354 and name C ) (segid " A" and resid 355 and name N )
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+ ASSIGN (segid " A" and resid 355 and name N ) (segid " A" and resid 355 and name CA )
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+ ASSIGN (segid " A" and resid 355 and name C ) (segid " A" and resid 356 and name N )
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+ ASSIGN (segid " A" and resid 356 and name N ) (segid " A" and resid 356 and name CA )
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+ ASSIGN (segid " A" and resid 356 and name C ) (segid " A" and resid 357 and name N )
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+ ASSIGN (segid " A" and resid 357 and name N ) (segid " A" and resid 357 and name CA )
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+ ASSIGN (segid " A" and resid 357 and name C ) (segid " A" and resid 358 and name N )
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+ ASSIGN (segid " A" and resid 358 and name N ) (segid " A" and resid 358 and name CA )
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+ ASSIGN (segid " A" and resid 358 and name C ) (segid " A" and resid 359 and name N )
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+ ASSIGN (segid " A" and resid 359 and name N ) (segid " A" and resid 359 and name CA )
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+ ASSIGN (segid " A" and resid 359 and name C ) (segid " A" and resid 360 and name N )
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+ ASSIGN (segid " A" and resid 360 and name N ) (segid " A" and resid 360 and name CA )
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+ ASSIGN (segid " A" and resid 360 and name C ) (segid " A" and resid 361 and name N )
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+ ASSIGN (segid " A" and resid 361 and name N ) (segid " A" and resid 361 and name CA )
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+ ASSIGN (segid " A" and resid 361 and name C ) (segid " A" and resid 362 and name N )
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+ ASSIGN (segid " A" and resid 362 and name N ) (segid " A" and resid 362 and name CA )
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+ ASSIGN (segid " A" and resid 363 and name N ) (segid " A" and resid 363 and name CA )
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+ ASSIGN (segid " A" and resid 363 and name C ) (segid " A" and resid 364 and name N )
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+ ASSIGN (segid " A" and resid 364 and name N ) (segid " A" and resid 364 and name CA )
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+ ASSIGN (segid " A" and resid 366 and name N ) (segid " A" and resid 366 and name CA )
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+ ASSIGN (segid " A" and resid 366 and name C ) (segid " A" and resid 367 and name N )
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+ ASSIGN (segid " A" and resid 367 and name N ) (segid " A" and resid 367 and name CA )
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+ ASSIGN (segid " A" and resid 367 and name C ) (segid " A" and resid 368 and name N )
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+
+ ASSIGN (segid " A" and resid 368 and name N ) (segid " A" and resid 368 and name CA )
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+
+ ASSIGN (segid " A" and resid 368 and name C ) (segid " A" and resid 369 and name N )
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+ ASSIGN (segid " A" and resid 369 and name N ) (segid " A" and resid 369 and name CA )
+ (segid " A" and resid 369 and name C ) (segid " A" and resid 370 and name N ) 1.00 -7.10 37.40 2
+
diff --git a/docs/examples/malecoli/data/xml/c_redo_cs.xml b/docs/examples/malecoli/data/xml/c_redo_cs.xml
new file mode 100644
index 0000000000000000000000000000000000000000..bcb3d46b809ec3f250726022e42af6cd1ed9b115
--- /dev/null
+++ b/docs/examples/malecoli/data/xml/c_redo_cs.xml
@@ -0,0 +1,31373 @@
+<!DOCTYPE chemical_shift_list SYSTEM "chemical_shift_list1.0.dtd">
+<chemical_shift_list>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="1" name="HZ1"/>
+ <atom segid=" A" residue="1" name="HZ2"/>
+ <atom segid=" A" residue="1" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="1" name="H1"/>
+ <atom segid=" A" residue="1" name="H2"/>
+ <atom segid=" A" residue="1" name="H3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="C"/>
+ <chemical_shift value="176.453" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CB"/>
+ <chemical_shift value="32.88" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CA"/>
+ <chemical_shift value="56.408" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="2" name="HG21"/>
+ <atom segid=" A" residue="2" name="HG22"/>
+ <atom segid=" A" residue="2" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.402" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="2" name="HD11"/>
+ <atom segid=" A" residue="2" name="HD12"/>
+ <atom segid=" A" residue="2" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.402" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="C"/>
+ <chemical_shift value="176.016" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CB"/>
+ <chemical_shift value="38.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CA"/>
+ <chemical_shift value="62.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="N"/>
+ <chemical_shift value="123.415" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CD1"/>
+ <chemical_shift value="13.054" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="H"/>
+ <chemical_shift value="7.988" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="C"/>
+ <chemical_shift value="176.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CB"/>
+ <chemical_shift value="31.187" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CA"/>
+ <chemical_shift value="56.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="N"/>
+ <chemical_shift value="126.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="H"/>
+ <chemical_shift value="8.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="C"/>
+ <chemical_shift value="177.433" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CB"/>
+ <chemical_shift value="30.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CA"/>
+ <chemical_shift value="56.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="N"/>
+ <chemical_shift value="124.204" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="H"/>
+ <chemical_shift value="8.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="C"/>
+ <chemical_shift value="172.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="H"/>
+ <chemical_shift value="8.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="CA"/>
+ <chemical_shift value="45.937" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="N"/>
+ <chemical_shift value="111.348" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="6" name="HZ1"/>
+ <atom segid=" A" residue="6" name="HZ2"/>
+ <atom segid=" A" residue="6" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CB"/>
+ <chemical_shift value="35.109" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="C"/>
+ <chemical_shift value="173.108" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="H"/>
+ <chemical_shift value="7.582" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CA"/>
+ <chemical_shift value="54.965" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="N"/>
+ <chemical_shift value="118.91" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="7" name="HD21"/>
+ <atom segid=" A" residue="7" name="HD22"/>
+ <atom segid=" A" residue="7" name="HD23"/>
+ <chemical_shift value="0.615" error="0.0"/>
+ <chemical_shift value="0.267" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="7" name="HD11"/>
+ <atom segid=" A" residue="7" name="HD12"/>
+ <atom segid=" A" residue="7" name="HD13"/>
+ <chemical_shift value="0.615" error="0.0"/>
+ <chemical_shift value="0.267" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="C"/>
+ <chemical_shift value="175.788" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CB"/>
+ <chemical_shift value="46.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CA"/>
+ <chemical_shift value="53.365" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="N"/>
+ <chemical_shift value="116.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CD1"/>
+ <chemical_shift value="25.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CD2"/>
+ <chemical_shift value="24.064" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="H"/>
+ <chemical_shift value="8.231" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="8" name="HG21"/>
+ <atom segid=" A" residue="8" name="HG22"/>
+ <atom segid=" A" residue="8" name="HG23"/>
+ <chemical_shift value="0.923" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="8" name="HG11"/>
+ <atom segid=" A" residue="8" name="HG12"/>
+ <atom segid=" A" residue="8" name="HG13"/>
+ <chemical_shift value="0.923" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="C"/>
+ <chemical_shift value="176.033" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CB"/>
+ <chemical_shift value="33.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CA"/>
+ <chemical_shift value="61.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="N"/>
+ <chemical_shift value="125.474" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CG1"/>
+ <chemical_shift value="20.962" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="H"/>
+ <chemical_shift value="10.155" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CG2"/>
+ <chemical_shift value="21.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="9" name="HG21"/>
+ <atom segid=" A" residue="9" name="HG22"/>
+ <atom segid=" A" residue="9" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.346" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="9" name="HD11"/>
+ <atom segid=" A" residue="9" name="HD12"/>
+ <atom segid=" A" residue="9" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.346" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="C"/>
+ <chemical_shift value="174.901" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CB"/>
+ <chemical_shift value="40.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CA"/>
+ <chemical_shift value="59.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="N"/>
+ <chemical_shift value="128.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CD1"/>
+ <chemical_shift value="14.523" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="H"/>
+ <chemical_shift value="9.114" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="H"/>
+ <chemical_shift value="9.032" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="C"/>
+ <chemical_shift value="174.116" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CB"/>
+ <chemical_shift value="32.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CA"/>
+ <chemical_shift value="54.451" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="N"/>
+ <chemical_shift value="126.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="11" name="HG21"/>
+ <atom segid=" A" residue="11" name="HG22"/>
+ <atom segid=" A" residue="11" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.107" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="11" name="HD11"/>
+ <atom segid=" A" residue="11" name="HD12"/>
+ <atom segid=" A" residue="11" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.107" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="C"/>
+ <chemical_shift value="171.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CB"/>
+ <chemical_shift value="41.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CA"/>
+ <chemical_shift value="59.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="N"/>
+ <chemical_shift value="122.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CD1"/>
+ <chemical_shift value="13.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="H"/>
+ <chemical_shift value="8.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="C"/>
+ <chemical_shift value="177.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CB"/>
+ <chemical_shift value="39.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CA"/>
+ <chemical_shift value="54.628" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="N"/>
+ <chemical_shift value="122.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="H"/>
+ <chemical_shift value="8.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="C"/>
+ <chemical_shift value="173.365" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="H"/>
+ <chemical_shift value="8.288" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="CA"/>
+ <chemical_shift value="46.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="N"/>
+ <chemical_shift value="106.789" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="C"/>
+ <chemical_shift value="176.544" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CB"/>
+ <chemical_shift value="39.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CA"/>
+ <chemical_shift value="53.217" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="N"/>
+ <chemical_shift value="117.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="H"/>
+ <chemical_shift value="7.99" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="15" name="HZ1"/>
+ <atom segid=" A" residue="15" name="HZ2"/>
+ <atom segid=" A" residue="15" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CB"/>
+ <chemical_shift value="32.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="C"/>
+ <chemical_shift value="177.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="H"/>
+ <chemical_shift value="7.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CA"/>
+ <chemical_shift value="53.23" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="N"/>
+ <chemical_shift value="118.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="C"/>
+ <chemical_shift value="175.872" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="H"/>
+ <chemical_shift value="8.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="CA"/>
+ <chemical_shift value="48.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="N"/>
+ <chemical_shift value="108.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="17" name="HD1"/>
+ <atom segid=" A" residue="17" name="HD2"/>
+ <atom segid=" A" residue="17" name="HE1"/>
+ <atom segid=" A" residue="17" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="C"/>
+ <chemical_shift value="177.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CB"/>
+ <chemical_shift value="37.646" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CA"/>
+ <chemical_shift value="59.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="N"/>
+ <chemical_shift value="120.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="H"/>
+ <chemical_shift value="8.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="C"/>
+ <chemical_shift value="179.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CB"/>
+ <chemical_shift value="37.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CA"/>
+ <chemical_shift value="56.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="N"/>
+ <chemical_shift value="123.761" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="H"/>
+ <chemical_shift value="8.109" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="C"/>
+ <chemical_shift value="176.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="H"/>
+ <chemical_shift value="9.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="CA"/>
+ <chemical_shift value="47.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="N"/>
+ <chemical_shift value="111.77" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="20" name="HD21"/>
+ <atom segid=" A" residue="20" name="HD22"/>
+ <atom segid=" A" residue="20" name="HD23"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="20" name="HD11"/>
+ <atom segid=" A" residue="20" name="HD12"/>
+ <atom segid=" A" residue="20" name="HD13"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="C"/>
+ <chemical_shift value="178.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CB"/>
+ <chemical_shift value="41.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CA"/>
+ <chemical_shift value="57.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="N"/>
+ <chemical_shift value="121.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CD1"/>
+ <chemical_shift value="24.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CD2"/>
+ <chemical_shift value="26.879" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="21" name="HB1"/>
+ <atom segid=" A" residue="21" name="HB2"/>
+ <atom segid=" A" residue="21" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="C"/>
+ <chemical_shift value="180.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="CB"/>
+ <chemical_shift value="17.478" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="CA"/>
+ <chemical_shift value="55.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="N"/>
+ <chemical_shift value="121.303" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="H"/>
+ <chemical_shift value="8.143" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="C"/>
+ <chemical_shift value="180.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CB"/>
+ <chemical_shift value="28.487" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CA"/>
+ <chemical_shift value="59.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="N"/>
+ <chemical_shift value="120.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="H"/>
+ <chemical_shift value="7.825" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="23" name="HG21"/>
+ <atom segid=" A" residue="23" name="HG22"/>
+ <atom segid=" A" residue="23" name="HG23"/>
+ <chemical_shift value="1.252" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="23" name="HG11"/>
+ <atom segid=" A" residue="23" name="HG12"/>
+ <atom segid=" A" residue="23" name="HG13"/>
+ <chemical_shift value="1.252" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="C"/>
+ <chemical_shift value="179.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CB"/>
+ <chemical_shift value="31.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CA"/>
+ <chemical_shift value="66.874" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="N"/>
+ <chemical_shift value="123.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CG1"/>
+ <chemical_shift value="22.314" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="H"/>
+ <chemical_shift value="7.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CG2"/>
+ <chemical_shift value="23.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="C"/>
+ <chemical_shift value="175.393" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="H"/>
+ <chemical_shift value="8.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="CA"/>
+ <chemical_shift value="47.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="N"/>
+ <chemical_shift value="106.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="25" name="HZ1"/>
+ <atom segid=" A" residue="25" name="HZ2"/>
+ <atom segid=" A" residue="25" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CB"/>
+ <chemical_shift value="31.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="C"/>
+ <chemical_shift value="179.664" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="H"/>
+ <chemical_shift value="8.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CA"/>
+ <chemical_shift value="59.448" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="N"/>
+ <chemical_shift value="123.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="26" name="HZ1"/>
+ <atom segid=" A" residue="26" name="HZ2"/>
+ <atom segid=" A" residue="26" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CB"/>
+ <chemical_shift value="31.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="C"/>
+ <chemical_shift value="178.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="H"/>
+ <chemical_shift value="7.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CA"/>
+ <chemical_shift value="59.777" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="N"/>
+ <chemical_shift value="123.048" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="27" name="HD1"/>
+ <atom segid=" A" residue="27" name="HD2"/>
+ <atom segid=" A" residue="27" name="HE1"/>
+ <atom segid=" A" residue="27" name="HE2"/>
+ <atom segid=" A" residue="27" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="C"/>
+ <chemical_shift value="179.166" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CB"/>
+ <chemical_shift value="39.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CA"/>
+ <chemical_shift value="61.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="N"/>
+ <chemical_shift value="120.111" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="H"/>
+ <chemical_shift value="8.131" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="C"/>
+ <chemical_shift value="180.031" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CB"/>
+ <chemical_shift value="29.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CA"/>
+ <chemical_shift value="59.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="N"/>
+ <chemical_shift value="124.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="H"/>
+ <chemical_shift value="8.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="29" name="HZ1"/>
+ <atom segid=" A" residue="29" name="HZ2"/>
+ <atom segid=" A" residue="29" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CB"/>
+ <chemical_shift value="31.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="H"/>
+ <chemical_shift value="8.151" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CA"/>
+ <chemical_shift value="59.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="N"/>
+ <chemical_shift value="122.162" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="C"/>
+ <chemical_shift value="178.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CB"/>
+ <chemical_shift value="41.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CA"/>
+ <chemical_shift value="56.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="N"/>
+ <chemical_shift value="116.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="H"/>
+ <chemical_shift value="7.615" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="31" name="HG21"/>
+ <atom segid=" A" residue="31" name="HG22"/>
+ <atom segid=" A" residue="31" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="C"/>
+ <chemical_shift value="176.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CB"/>
+ <chemical_shift value="72.293" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CA"/>
+ <chemical_shift value="62.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="N"/>
+ <chemical_shift value="107.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="H"/>
+ <chemical_shift value="7.929" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="C"/>
+ <chemical_shift value="173.645" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="H"/>
+ <chemical_shift value="8.6" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="CA"/>
+ <chemical_shift value="45.563" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="N"/>
+ <chemical_shift value="112.884" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="33" name="HG21"/>
+ <atom segid=" A" residue="33" name="HG22"/>
+ <atom segid=" A" residue="33" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.574" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="33" name="HD11"/>
+ <atom segid=" A" residue="33" name="HD12"/>
+ <atom segid=" A" residue="33" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.574" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="C"/>
+ <chemical_shift value="173.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CB"/>
+ <chemical_shift value="35.66" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CA"/>
+ <chemical_shift value="59.048" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="N"/>
+ <chemical_shift value="124.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CD1"/>
+ <chemical_shift value="10.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="H"/>
+ <chemical_shift value="7.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="34" name="HZ1"/>
+ <atom segid=" A" residue="34" name="HZ2"/>
+ <atom segid=" A" residue="34" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CB"/>
+ <chemical_shift value="32.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="C"/>
+ <chemical_shift value="175.675" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="H"/>
+ <chemical_shift value="7.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CA"/>
+ <chemical_shift value="56.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="N"/>
+ <chemical_shift value="125.011" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="35" name="HG21"/>
+ <atom segid=" A" residue="35" name="HG22"/>
+ <atom segid=" A" residue="35" name="HG23"/>
+ <chemical_shift value="0.776" error="0.0"/>
+ <chemical_shift value="0.331" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="35" name="HG11"/>
+ <atom segid=" A" residue="35" name="HG12"/>
+ <atom segid=" A" residue="35" name="HG13"/>
+ <chemical_shift value="0.776" error="0.0"/>
+ <chemical_shift value="0.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="C"/>
+ <chemical_shift value="175.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CB"/>
+ <chemical_shift value="33.372" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CA"/>
+ <chemical_shift value="61.064" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="N"/>
+ <chemical_shift value="124.42" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CG1"/>
+ <chemical_shift value="20.685" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="H"/>
+ <chemical_shift value="8.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CG2"/>
+ <chemical_shift value="22.478" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="36" name="HG21"/>
+ <atom segid=" A" residue="36" name="HG22"/>
+ <atom segid=" A" residue="36" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="C"/>
+ <chemical_shift value="172.762" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CB"/>
+ <chemical_shift value="70.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CA"/>
+ <chemical_shift value="61.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="N"/>
+ <chemical_shift value="125.312" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="H"/>
+ <chemical_shift value="9.176" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="37" name="HG21"/>
+ <atom segid=" A" residue="37" name="HG22"/>
+ <atom segid=" A" residue="37" name="HG23"/>
+ <chemical_shift value="0.766" error="0.0"/>
+ <chemical_shift value="0.951" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="37" name="HG11"/>
+ <atom segid=" A" residue="37" name="HG12"/>
+ <atom segid=" A" residue="37" name="HG13"/>
+ <chemical_shift value="0.766" error="0.0"/>
+ <chemical_shift value="0.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="C"/>
+ <chemical_shift value="175.348" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CB"/>
+ <chemical_shift value="32.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CA"/>
+ <chemical_shift value="61.689" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="N"/>
+ <chemical_shift value="127.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CG1"/>
+ <chemical_shift value="22.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="H"/>
+ <chemical_shift value="8.921" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CG2"/>
+ <chemical_shift value="20.673" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="C"/>
+ <chemical_shift value="173.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CB"/>
+ <chemical_shift value="33.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CA"/>
+ <chemical_shift value="54.475" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="N"/>
+ <chemical_shift value="127.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="H"/>
+ <chemical_shift value="9.644" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CB"/>
+ <chemical_shift value="28.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CA"/>
+ <chemical_shift value="51.527" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="N"/>
+ <chemical_shift value="115.306" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="H"/>
+ <chemical_shift value="8.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="C"/>
+ <chemical_shift value="176.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CB"/>
+ <chemical_shift value="30.665" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CA"/>
+ <chemical_shift value="62.226" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="C"/>
+ <chemical_shift value="176.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CB"/>
+ <chemical_shift value="41.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CA"/>
+ <chemical_shift value="54.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="N"/>
+ <chemical_shift value="121.165" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="H"/>
+ <chemical_shift value="8.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="42" name="HZ1"/>
+ <atom segid=" A" residue="42" name="HZ2"/>
+ <atom segid=" A" residue="42" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CB"/>
+ <chemical_shift value="29.442" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="C"/>
+ <chemical_shift value="178.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="H"/>
+ <chemical_shift value="8.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CA"/>
+ <chemical_shift value="56.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="N"/>
+ <chemical_shift value="119.242" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="43" name="HD21"/>
+ <atom segid=" A" residue="43" name="HD22"/>
+ <atom segid=" A" residue="43" name="HD23"/>
+ <chemical_shift value="1.133" error="0.0"/>
+ <chemical_shift value="1.101" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="43" name="HD11"/>
+ <atom segid=" A" residue="43" name="HD12"/>
+ <atom segid=" A" residue="43" name="HD13"/>
+ <chemical_shift value="1.133" error="0.0"/>
+ <chemical_shift value="1.101" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="C"/>
+ <chemical_shift value="175.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CB"/>
+ <chemical_shift value="40.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CA"/>
+ <chemical_shift value="59.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="N"/>
+ <chemical_shift value="120.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CD1"/>
+ <chemical_shift value="26.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CD2"/>
+ <chemical_shift value="26.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="H"/>
+ <chemical_shift value="7.387" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="C"/>
+ <chemical_shift value="178.284" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CB"/>
+ <chemical_shift value="24.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CA"/>
+ <chemical_shift value="57.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="N"/>
+ <chemical_shift value="123.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="H"/>
+ <chemical_shift value="10.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="C"/>
+ <chemical_shift value="178.462" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CB"/>
+ <chemical_shift value="29.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CA"/>
+ <chemical_shift value="56.456" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="N"/>
+ <chemical_shift value="120.295" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="H"/>
+ <chemical_shift value="7.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="46" name="HZ1"/>
+ <atom segid=" A" residue="46" name="HZ2"/>
+ <atom segid=" A" residue="46" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CB"/>
+ <chemical_shift value="33.277" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="C"/>
+ <chemical_shift value="179.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="H"/>
+ <chemical_shift value="8.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CA"/>
+ <chemical_shift value="58.611" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="N"/>
+ <chemical_shift value="120.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="47" name="HD1"/>
+ <atom segid=" A" residue="47" name="HD2"/>
+ <atom segid=" A" residue="47" name="HE1"/>
+ <atom segid=" A" residue="47" name="HE2"/>
+ <atom segid=" A" residue="47" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CB"/>
+ <chemical_shift value="36.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CA"/>
+ <chemical_shift value="63.747" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="N"/>
+ <chemical_shift value="116.928" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="H"/>
+ <chemical_shift value="8.655" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="C"/>
+ <chemical_shift value="178.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CB"/>
+ <chemical_shift value="30.015" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CA"/>
+ <chemical_shift value="65.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="C"/>
+ <chemical_shift value="178.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CB"/>
+ <chemical_shift value="28.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CA"/>
+ <chemical_shift value="58.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="N"/>
+ <chemical_shift value="115.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="H"/>
+ <chemical_shift value="6.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="50" name="HG21"/>
+ <atom segid=" A" residue="50" name="HG22"/>
+ <atom segid=" A" residue="50" name="HG23"/>
+ <chemical_shift value="0.906" error="0.0"/>
+ <chemical_shift value="0.967" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="50" name="HG11"/>
+ <atom segid=" A" residue="50" name="HG12"/>
+ <atom segid=" A" residue="50" name="HG13"/>
+ <chemical_shift value="0.906" error="0.0"/>
+ <chemical_shift value="0.967" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="C"/>
+ <chemical_shift value="178.512" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CB"/>
+ <chemical_shift value="32.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CA"/>
+ <chemical_shift value="62.603" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="N"/>
+ <chemical_shift value="111.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CG1"/>
+ <chemical_shift value="21.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="H"/>
+ <chemical_shift value="7.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CG2"/>
+ <chemical_shift value="19.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="51" name="HB1"/>
+ <atom segid=" A" residue="51" name="HB2"/>
+ <atom segid=" A" residue="51" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="C"/>
+ <chemical_shift value="180.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="CB"/>
+ <chemical_shift value="17.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="CA"/>
+ <chemical_shift value="54.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="N"/>
+ <chemical_shift value="125.692" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="H"/>
+ <chemical_shift value="8.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="52" name="HB1"/>
+ <atom segid=" A" residue="52" name="HB2"/>
+ <atom segid=" A" residue="52" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="C"/>
+ <chemical_shift value="178.618" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="CB"/>
+ <chemical_shift value="18.146" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="CA"/>
+ <chemical_shift value="53.841" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="N"/>
+ <chemical_shift value="118.243" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="H"/>
+ <chemical_shift value="7.396" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="53" name="HG21"/>
+ <atom segid=" A" residue="53" name="HG22"/>
+ <atom segid=" A" residue="53" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="C"/>
+ <chemical_shift value="175.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CB"/>
+ <chemical_shift value="69.75" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CA"/>
+ <chemical_shift value="61.307" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="N"/>
+ <chemical_shift value="106.045" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="H"/>
+ <chemical_shift value="7.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="C"/>
+ <chemical_shift value="172.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="H"/>
+ <chemical_shift value="7.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="CA"/>
+ <chemical_shift value="45.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="N"/>
+ <chemical_shift value="109.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="C"/>
+ <chemical_shift value="174.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CB"/>
+ <chemical_shift value="43.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CA"/>
+ <chemical_shift value="52.778" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="N"/>
+ <chemical_shift value="119.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="H"/>
+ <chemical_shift value="7.395" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="H"/>
+ <chemical_shift value="8.332" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="CA"/>
+ <chemical_shift value="43.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="N"/>
+ <chemical_shift value="105.496" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="C"/>
+ <chemical_shift value="175.448" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CB"/>
+ <chemical_shift value="30.658" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CA"/>
+ <chemical_shift value="61.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="C"/>
+ <chemical_shift value="176.037" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CB"/>
+ <chemical_shift value="43.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CA"/>
+ <chemical_shift value="58.668" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="N"/>
+ <chemical_shift value="117.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="H"/>
+ <chemical_shift value="8.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="59" name="HG21"/>
+ <atom segid=" A" residue="59" name="HG22"/>
+ <atom segid=" A" residue="59" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.735" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="59" name="HD11"/>
+ <atom segid=" A" residue="59" name="HD12"/>
+ <atom segid=" A" residue="59" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.735" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="C"/>
+ <chemical_shift value="173.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CB"/>
+ <chemical_shift value="42.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CA"/>
+ <chemical_shift value="58.982" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="N"/>
+ <chemical_shift value="114.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CD1"/>
+ <chemical_shift value="13.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="H"/>
+ <chemical_shift value="7.631" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="60" name="HG21"/>
+ <atom segid=" A" residue="60" name="HG22"/>
+ <atom segid=" A" residue="60" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.452" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="60" name="HD11"/>
+ <atom segid=" A" residue="60" name="HD12"/>
+ <atom segid=" A" residue="60" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="C"/>
+ <chemical_shift value="172.929" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CB"/>
+ <chemical_shift value="41.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CA"/>
+ <chemical_shift value="58.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="N"/>
+ <chemical_shift value="124.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CD1"/>
+ <chemical_shift value="14.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="H"/>
+ <chemical_shift value="8.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="61" name="HD1"/>
+ <atom segid=" A" residue="61" name="HD2"/>
+ <atom segid=" A" residue="61" name="HE1"/>
+ <atom segid=" A" residue="61" name="HE2"/>
+ <atom segid=" A" residue="61" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="C"/>
+ <chemical_shift value="176.742" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CB"/>
+ <chemical_shift value="41.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CA"/>
+ <chemical_shift value="55.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="N"/>
+ <chemical_shift value="126.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="H"/>
+ <chemical_shift value="8.603" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="H"/>
+ <chemical_shift value="9.181" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="C"/>
+ <chemical_shift value="173.771" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CB"/>
+ <chemical_shift value="31.813" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CA"/>
+ <chemical_shift value="57.786" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="N"/>
+ <chemical_shift value="121.356" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="63" name="HB1"/>
+ <atom segid=" A" residue="63" name="HB2"/>
+ <atom segid=" A" residue="63" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="C"/>
+ <chemical_shift value="179.957" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="CB"/>
+ <chemical_shift value="18.639" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="CA"/>
+ <chemical_shift value="54.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="N"/>
+ <chemical_shift value="125.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="H"/>
+ <chemical_shift value="6.296" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="C"/>
+ <chemical_shift value="178.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CB"/>
+ <chemical_shift value="30.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CA"/>
+ <chemical_shift value="60.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="N"/>
+ <chemical_shift value="115.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="H"/>
+ <chemical_shift value="8.028" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="C"/>
+ <chemical_shift value="177.968" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CB"/>
+ <chemical_shift value="39.5" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CA"/>
+ <chemical_shift value="57.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="N"/>
+ <chemical_shift value="119.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="H"/>
+ <chemical_shift value="7.721" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CB"/>
+ <chemical_shift value="29.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="C"/>
+ <chemical_shift value="177.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="H"/>
+ <chemical_shift value="6.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CA"/>
+ <chemical_shift value="55.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="N"/>
+ <chemical_shift value="116.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="67" name="HD1"/>
+ <atom segid=" A" residue="67" name="HD2"/>
+ <atom segid=" A" residue="67" name="HE1"/>
+ <atom segid=" A" residue="67" name="HE2"/>
+ <atom segid=" A" residue="67" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="C"/>
+ <chemical_shift value="177.883" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CB"/>
+ <chemical_shift value="36.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CA"/>
+ <chemical_shift value="58.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="N"/>
+ <chemical_shift value="116.954" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="H"/>
+ <chemical_shift value="7.688" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="C"/>
+ <chemical_shift value="175.81" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="H"/>
+ <chemical_shift value="7.272" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="CA"/>
+ <chemical_shift value="47.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="N"/>
+ <chemical_shift value="107.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="C"/>
+ <chemical_shift value="177.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="H"/>
+ <chemical_shift value="7.651" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="CA"/>
+ <chemical_shift value="47.089" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="N"/>
+ <chemical_shift value="107.532" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="70" name="HD1"/>
+ <atom segid=" A" residue="70" name="HD2"/>
+ <atom segid=" A" residue="70" name="HE1"/>
+ <atom segid=" A" residue="70" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="C"/>
+ <chemical_shift value="178.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CB"/>
+ <chemical_shift value="35.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CA"/>
+ <chemical_shift value="57.372" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="N"/>
+ <chemical_shift value="119.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="H"/>
+ <chemical_shift value="6.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="71" name="HB1"/>
+ <atom segid=" A" residue="71" name="HB2"/>
+ <atom segid=" A" residue="71" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="C"/>
+ <chemical_shift value="182.277" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="CB"/>
+ <chemical_shift value="18.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="CA"/>
+ <chemical_shift value="54.487" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="N"/>
+ <chemical_shift value="122.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="H"/>
+ <chemical_shift value="8.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="C"/>
+ <chemical_shift value="177.85" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CB"/>
+ <chemical_shift value="27.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CA"/>
+ <chemical_shift value="58.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="N"/>
+ <chemical_shift value="122.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="H"/>
+ <chemical_shift value="8.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="C"/>
+ <chemical_shift value="173.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="CB"/>
+ <chemical_shift value="64.148" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="CA"/>
+ <chemical_shift value="59.274" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="N"/>
+ <chemical_shift value="112.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="H"/>
+ <chemical_shift value="7.362" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="C"/>
+ <chemical_shift value="176.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="H"/>
+ <chemical_shift value="8.083" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="CA"/>
+ <chemical_shift value="46.341" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="N"/>
+ <chemical_shift value="109.4" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="75" name="HD22"/>
+ <atom segid=" A" residue="75" name="HD23"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="75" name="HD11"/>
+ <atom segid=" A" residue="75" name="HD12"/>
+ <atom segid=" A" residue="75" name="HD13"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="C"/>
+ <chemical_shift value="177.608" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CB"/>
+ <chemical_shift value="42.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CA"/>
+ <chemical_shift value="55.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="N"/>
+ <chemical_shift value="113.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CD1"/>
+ <chemical_shift value="25.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CD2"/>
+ <chemical_shift value="20.664" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="H"/>
+ <chemical_shift value="7.815" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="76" name="HD22"/>
+ <atom segid=" A" residue="76" name="HD23"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.897" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="76" name="HD11"/>
+ <atom segid=" A" residue="76" name="HD12"/>
+ <atom segid=" A" residue="76" name="HD13"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="C"/>
+ <chemical_shift value="176.782" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CB"/>
+ <chemical_shift value="43.798" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CA"/>
+ <chemical_shift value="52.794" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="N"/>
+ <chemical_shift value="115.902" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CD1"/>
+ <chemical_shift value="27.43" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CD2"/>
+ <chemical_shift value="21.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="H"/>
+ <chemical_shift value="7.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="77" name="HB2"/>
+ <atom segid=" A" residue="77" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="C"/>
+ <chemical_shift value="176.398" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="CB"/>
+ <chemical_shift value="19.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="CA"/>
+ <chemical_shift value="51.102" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="N"/>
+ <chemical_shift value="125.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="H"/>
+ <chemical_shift value="9.007" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="C"/>
+ <chemical_shift value="176.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CB"/>
+ <chemical_shift value="29.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CA"/>
+ <chemical_shift value="56.426" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="N"/>
+ <chemical_shift value="120.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="H"/>
+ <chemical_shift value="8.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
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+ <atom segid=" A" residue="79" name="HG22"/>
+ <atom segid=" A" residue="79" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.161" error="0.0"/>
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+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="79" name="HD11"/>
+ <atom segid=" A" residue="79" name="HD12"/>
+ <atom segid=" A" residue="79" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.161" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="C"/>
+ <chemical_shift value="175.746" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CB"/>
+ <chemical_shift value="38.941" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CA"/>
+ <chemical_shift value="59.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="N"/>
+ <chemical_shift value="122.859" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CD1"/>
+ <chemical_shift value="12.313" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="H"/>
+ <chemical_shift value="8.176" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="80" name="HG21"/>
+ <atom segid=" A" residue="80" name="HG22"/>
+ <atom segid=" A" residue="80" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CB"/>
+ <chemical_shift value="69.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CA"/>
+ <chemical_shift value="57.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="N"/>
+ <chemical_shift value="112.766" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="H"/>
+ <chemical_shift value="8.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="C"/>
+ <chemical_shift value="177.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CB"/>
+ <chemical_shift value="31.586" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CA"/>
+ <chemical_shift value="62.548" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CB"/>
+ <chemical_shift value="41.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CA"/>
+ <chemical_shift value="53.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="N"/>
+ <chemical_shift value="123.843" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="H"/>
+ <chemical_shift value="9.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="83" name="HZ1"/>
+ <atom segid=" A" residue="83" name="HZ2"/>
+ <atom segid=" A" residue="83" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CB"/>
+ <chemical_shift value="31.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="C"/>
+ <chemical_shift value="177.708" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CA"/>
+ <chemical_shift value="59.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="84" name="HB1"/>
+ <atom segid=" A" residue="84" name="HB2"/>
+ <atom segid=" A" residue="84" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="C"/>
+ <chemical_shift value="180.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="CB"/>
+ <chemical_shift value="17.553" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="CA"/>
+ <chemical_shift value="54.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="N"/>
+ <chemical_shift value="119.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="H"/>
+ <chemical_shift value="8.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="85" name="HD1"/>
+ <atom segid=" A" residue="85" name="HD2"/>
+ <atom segid=" A" residue="85" name="HE1"/>
+ <atom segid=" A" residue="85" name="HE2"/>
+ <atom segid=" A" residue="85" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="C"/>
+ <chemical_shift value="178.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CB"/>
+ <chemical_shift value="39.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CA"/>
+ <chemical_shift value="62.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="N"/>
+ <chemical_shift value="118.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="H"/>
+ <chemical_shift value="7.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="C"/>
+ <chemical_shift value="180.14" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CB"/>
+ <chemical_shift value="28.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CA"/>
+ <chemical_shift value="59.616" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="N"/>
+ <chemical_shift value="117.272" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="H"/>
+ <chemical_shift value="8.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="C"/>
+ <chemical_shift value="176.576" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CB"/>
+ <chemical_shift value="40.956" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CA"/>
+ <chemical_shift value="56.177" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="N"/>
+ <chemical_shift value="116.913" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="H"/>
+ <chemical_shift value="8.053" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="88" name="HZ1"/>
+ <atom segid=" A" residue="88" name="HZ2"/>
+ <atom segid=" A" residue="88" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CB"/>
+ <chemical_shift value="31.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="C"/>
+ <chemical_shift value="176.797" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="H"/>
+ <chemical_shift value="7.816" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CA"/>
+ <chemical_shift value="58.402" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="N"/>
+ <chemical_shift value="117.299" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="89" name="HD21"/>
+ <atom segid=" A" residue="89" name="HD22"/>
+ <atom segid=" A" residue="89" name="HD23"/>
+ <chemical_shift value="0.484" error="0.0"/>
+ <chemical_shift value="0.526" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="89" name="HD11"/>
+ <atom segid=" A" residue="89" name="HD12"/>
+ <atom segid=" A" residue="89" name="HD13"/>
+ <chemical_shift value="0.484" error="0.0"/>
+ <chemical_shift value="0.526" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="C"/>
+ <chemical_shift value="176.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CB"/>
+ <chemical_shift value="42.609" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CA"/>
+ <chemical_shift value="53.55" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="N"/>
+ <chemical_shift value="120.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CD1"/>
+ <chemical_shift value="26.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CD2"/>
+ <chemical_shift value="25.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="H"/>
+ <chemical_shift value="7.661" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="90" name="HD1"/>
+ <atom segid=" A" residue="90" name="HD2"/>
+ <atom segid=" A" residue="90" name="HE1"/>
+ <atom segid=" A" residue="90" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CB"/>
+ <chemical_shift value="38.921" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CA"/>
+ <chemical_shift value="59.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="N"/>
+ <chemical_shift value="116.748" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="H"/>
+ <chemical_shift value="7.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="C"/>
+ <chemical_shift value="179.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CB"/>
+ <chemical_shift value="31.38" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CA"/>
+ <chemical_shift value="66.902" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="92" name="HD1"/>
+ <atom segid=" A" residue="92" name="HD2"/>
+ <atom segid=" A" residue="92" name="HE1"/>
+ <atom segid=" A" residue="92" name="HE2"/>
+ <atom segid=" A" residue="92" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="C"/>
+ <chemical_shift value="176.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CB"/>
+ <chemical_shift value="36.63" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CA"/>
+ <chemical_shift value="59.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="N"/>
+ <chemical_shift value="112.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="H"/>
+ <chemical_shift value="8.01" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="93" name="HG21"/>
+ <atom segid=" A" residue="93" name="HG22"/>
+ <atom segid=" A" residue="93" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="C"/>
+ <chemical_shift value="176.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CB"/>
+ <chemical_shift value="67.099" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CA"/>
+ <chemical_shift value="64.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="N"/>
+ <chemical_shift value="111.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="H"/>
+ <chemical_shift value="7.099" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="H"/>
+ <chemical_shift value="6.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="C"/>
+ <chemical_shift value="178.465" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CB"/>
+ <chemical_shift value="29.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CA"/>
+ <chemical_shift value="58.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="N"/>
+ <chemical_shift value="120.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="C"/>
+ <chemical_shift value="178.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CB"/>
+ <chemical_shift value="39.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CA"/>
+ <chemical_shift value="57.436" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="N"/>
+ <chemical_shift value="115.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="H"/>
+ <chemical_shift value="7.31" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="96" name="HB1"/>
+ <atom segid=" A" residue="96" name="HB2"/>
+ <atom segid=" A" residue="96" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="C"/>
+ <chemical_shift value="177.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="CB"/>
+ <chemical_shift value="17.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="CA"/>
+ <chemical_shift value="54.0" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="N"/>
+ <chemical_shift value="118.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="H"/>
+ <chemical_shift value="6.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="97" name="HG21"/>
+ <atom segid=" A" residue="97" name="HG22"/>
+ <atom segid=" A" residue="97" name="HG23"/>
+ <chemical_shift value="1.347" error="0.0"/>
+ <chemical_shift value="0.578" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="97" name="HG11"/>
+ <atom segid=" A" residue="97" name="HG12"/>
+ <atom segid=" A" residue="97" name="HG13"/>
+ <chemical_shift value="1.347" error="0.0"/>
+ <chemical_shift value="0.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="C"/>
+ <chemical_shift value="172.577" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CB"/>
+ <chemical_shift value="30.785" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CA"/>
+ <chemical_shift value="59.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="N"/>
+ <chemical_shift value="106.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CG1"/>
+ <chemical_shift value="22.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="H"/>
+ <chemical_shift value="7.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CG2"/>
+ <chemical_shift value="19.363" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CB"/>
+ <chemical_shift value="31.357" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="C"/>
+ <chemical_shift value="176.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="H"/>
+ <chemical_shift value="7.049" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CA"/>
+ <chemical_shift value="55.065" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="N"/>
+ <chemical_shift value="121.675" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="99" name="HD1"/>
+ <atom segid=" A" residue="99" name="HD2"/>
+ <atom segid=" A" residue="99" name="HE1"/>
+ <atom segid=" A" residue="99" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CB"/>
+ <chemical_shift value="41.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CA"/>
+ <chemical_shift value="58.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="N"/>
+ <chemical_shift value="127.473" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="H"/>
+ <chemical_shift value="9.707" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="C"/>
+ <chemical_shift value="175.4" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CB"/>
+ <chemical_shift value="37.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CA"/>
+ <chemical_shift value="53.907" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="C"/>
+ <chemical_shift value="173.987" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="H"/>
+ <chemical_shift value="8.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="CA"/>
+ <chemical_shift value="45.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="N"/>
+ <chemical_shift value="102.283" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="102" name="HZ1"/>
+ <atom segid=" A" residue="102" name="HZ2"/>
+ <atom segid=" A" residue="102" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CB"/>
+ <chemical_shift value="34.731" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="C"/>
+ <chemical_shift value="175.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="H"/>
+ <chemical_shift value="7.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CA"/>
+ <chemical_shift value="54.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="N"/>
+ <chemical_shift value="121.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="103" name="HD21"/>
+ <atom segid=" A" residue="103" name="HD22"/>
+ <atom segid=" A" residue="103" name="HD23"/>
+ <chemical_shift value="0.972" error="0.0"/>
+ <chemical_shift value="0.49" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="103" name="HD11"/>
+ <atom segid=" A" residue="103" name="HD12"/>
+ <atom segid=" A" residue="103" name="HD13"/>
+ <chemical_shift value="0.972" error="0.0"/>
+ <chemical_shift value="0.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="C"/>
+ <chemical_shift value="178.524" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CB"/>
+ <chemical_shift value="42.179" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CA"/>
+ <chemical_shift value="55.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="N"/>
+ <chemical_shift value="123.232" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CD1"/>
+ <chemical_shift value="24.748" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CD2"/>
+ <chemical_shift value="24.1" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="H"/>
+ <chemical_shift value="8.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="104" name="HG21"/>
+ <atom segid=" A" residue="104" name="HG22"/>
+ <atom segid=" A" residue="104" name="HG23"/>
+ <chemical_shift value="0.889" error="0.0"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="104" name="HD11"/>
+ <atom segid=" A" residue="104" name="HD12"/>
+ <atom segid=" A" residue="104" name="HD13"/>
+ <chemical_shift value="0.889" error="0.0"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="C"/>
+ <chemical_shift value="175.468" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CB"/>
+ <chemical_shift value="39.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CA"/>
+ <chemical_shift value="59.655" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="N"/>
+ <chemical_shift value="112.793" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CD1"/>
+ <chemical_shift value="14.779" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="H"/>
+ <chemical_shift value="8.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CG2"/>
+ <chemical_shift value="19.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="105" name="HB1"/>
+ <atom segid=" A" residue="105" name="HB2"/>
+ <atom segid=" A" residue="105" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="C"/>
+ <chemical_shift value="173.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="CB"/>
+ <chemical_shift value="22.111" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="CA"/>
+ <chemical_shift value="52.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="N"/>
+ <chemical_shift value="117.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="H"/>
+ <chemical_shift value="7.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="106" name="HD1"/>
+ <atom segid=" A" residue="106" name="HD2"/>
+ <atom segid=" A" residue="106" name="HE1"/>
+ <atom segid=" A" residue="106" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CB"/>
+ <chemical_shift value="39.931" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CA"/>
+ <chemical_shift value="56.214" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="N"/>
+ <chemical_shift value="113.919" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="H"/>
+ <chemical_shift value="8.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="C"/>
+ <chemical_shift value="174.609" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CB"/>
+ <chemical_shift value="32.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CA"/>
+ <chemical_shift value="62.281" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="108" name="HG21"/>
+ <atom segid=" A" residue="108" name="HG22"/>
+ <atom segid=" A" residue="108" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.637" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="108" name="HD11"/>
+ <atom segid=" A" residue="108" name="HD12"/>
+ <atom segid=" A" residue="108" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.637" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="C"/>
+ <chemical_shift value="176.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CB"/>
+ <chemical_shift value="37.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CA"/>
+ <chemical_shift value="60.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="N"/>
+ <chemical_shift value="115.381" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CD1"/>
+ <chemical_shift value="9.981" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="H"/>
+ <chemical_shift value="8.515" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="109" name="HB1"/>
+ <atom segid=" A" residue="109" name="HB2"/>
+ <atom segid=" A" residue="109" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="C"/>
+ <chemical_shift value="174.628" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="CB"/>
+ <chemical_shift value="23.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="CA"/>
+ <chemical_shift value="50.761" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="N"/>
+ <chemical_shift value="118.162" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="H"/>
+ <chemical_shift value="7.854" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="110" name="HG21"/>
+ <atom segid=" A" residue="110" name="HG22"/>
+ <atom segid=" A" residue="110" name="HG23"/>
+ <chemical_shift value="0.476" error="0.0"/>
+ <chemical_shift value="0.767" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="110" name="HG11"/>
+ <atom segid=" A" residue="110" name="HG12"/>
+ <atom segid=" A" residue="110" name="HG13"/>
+ <chemical_shift value="0.476" error="0.0"/>
+ <chemical_shift value="0.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="C"/>
+ <chemical_shift value="173.634" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CB"/>
+ <chemical_shift value="34.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CA"/>
+ <chemical_shift value="62.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="N"/>
+ <chemical_shift value="121.428" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CG1"/>
+ <chemical_shift value="20.954" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="H"/>
+ <chemical_shift value="8.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CG2"/>
+ <chemical_shift value="20.424" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="C"/>
+ <chemical_shift value="173.917" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CB"/>
+ <chemical_shift value="32.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CA"/>
+ <chemical_shift value="54.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="N"/>
+ <chemical_shift value="123.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="H"/>
+ <chemical_shift value="9.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="112" name="HB1"/>
+ <atom segid=" A" residue="112" name="HB2"/>
+ <atom segid=" A" residue="112" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="C"/>
+ <chemical_shift value="176.641" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="CB"/>
+ <chemical_shift value="22.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="CA"/>
+ <chemical_shift value="50.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="N"/>
+ <chemical_shift value="117.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="H"/>
+ <chemical_shift value="6.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="113" name="HD21"/>
+ <atom segid=" A" residue="113" name="HD22"/>
+ <atom segid=" A" residue="113" name="HD23"/>
+ <chemical_shift value="0.854" error="0.0"/>
+ <chemical_shift value="0.691" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="113" name="HD11"/>
+ <atom segid=" A" residue="113" name="HD12"/>
+ <atom segid=" A" residue="113" name="HD13"/>
+ <chemical_shift value="0.854" error="0.0"/>
+ <chemical_shift value="0.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="C"/>
+ <chemical_shift value="173.598" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CB"/>
+ <chemical_shift value="43.367" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CA"/>
+ <chemical_shift value="55.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="N"/>
+ <chemical_shift value="123.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CD1"/>
+ <chemical_shift value="26.792" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CD2"/>
+ <chemical_shift value="23.625" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="H"/>
+ <chemical_shift value="8.457" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="C"/>
+ <chemical_shift value="172.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="CB"/>
+ <chemical_shift value="67.447" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="CA"/>
+ <chemical_shift value="57.265" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="N"/>
+ <chemical_shift value="108.174" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="H"/>
+ <chemical_shift value="7.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="115" name="HD21"/>
+ <atom segid=" A" residue="115" name="HD22"/>
+ <atom segid=" A" residue="115" name="HD23"/>
+ <chemical_shift value="0.587" error="0.0"/>
+ <chemical_shift value="0.684" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="115" name="HD11"/>
+ <atom segid=" A" residue="115" name="HD12"/>
+ <atom segid=" A" residue="115" name="HD13"/>
+ <chemical_shift value="0.587" error="0.0"/>
+ <chemical_shift value="0.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="C"/>
+ <chemical_shift value="174.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CB"/>
+ <chemical_shift value="43.729" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CA"/>
+ <chemical_shift value="54.482" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="N"/>
+ <chemical_shift value="122.319" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CD1"/>
+ <chemical_shift value="22.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CD2"/>
+ <chemical_shift value="24.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="H"/>
+ <chemical_shift value="7.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="116" name="HG21"/>
+ <atom segid=" A" residue="116" name="HG22"/>
+ <atom segid=" A" residue="116" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.459" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="116" name="HD11"/>
+ <atom segid=" A" residue="116" name="HD12"/>
+ <atom segid=" A" residue="116" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.459" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="C"/>
+ <chemical_shift value="174.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CB"/>
+ <chemical_shift value="38.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CA"/>
+ <chemical_shift value="60.103" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="N"/>
+ <chemical_shift value="129.611" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CD1"/>
+ <chemical_shift value="13.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="H"/>
+ <chemical_shift value="8.667" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="117" name="HD1"/>
+ <atom segid=" A" residue="117" name="HD2"/>
+ <atom segid=" A" residue="117" name="HE1"/>
+ <atom segid=" A" residue="117" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="C"/>
+ <chemical_shift value="172.945" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CB"/>
+ <chemical_shift value="42.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CA"/>
+ <chemical_shift value="54.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="N"/>
+ <chemical_shift value="121.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="H"/>
+ <chemical_shift value="9.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="C"/>
+ <chemical_shift value="175.772" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CB"/>
+ <chemical_shift value="37.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CA"/>
+ <chemical_shift value="52.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="N"/>
+ <chemical_shift value="121.187" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="H"/>
+ <chemical_shift value="9.303" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="119" name="HZ1"/>
+ <atom segid=" A" residue="119" name="HZ2"/>
+ <atom segid=" A" residue="119" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CB"/>
+ <chemical_shift value="32.435" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="C"/>
+ <chemical_shift value="177.723" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="H"/>
+ <chemical_shift value="8.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CA"/>
+ <chemical_shift value="58.733" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="N"/>
+ <chemical_shift value="125.522" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="C"/>
+ <chemical_shift value="177.651" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CB"/>
+ <chemical_shift value="40.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CA"/>
+ <chemical_shift value="56.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="N"/>
+ <chemical_shift value="115.687" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="121" name="HD21"/>
+ <atom segid=" A" residue="121" name="HD22"/>
+ <atom segid=" A" residue="121" name="HD23"/>
+ <chemical_shift value="0.779" error="0.0"/>
+ <chemical_shift value="0.665" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="121" name="HD11"/>
+ <atom segid=" A" residue="121" name="HD12"/>
+ <atom segid=" A" residue="121" name="HD13"/>
+ <chemical_shift value="0.779" error="0.0"/>
+ <chemical_shift value="0.665" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="C"/>
+ <chemical_shift value="176.749" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CB"/>
+ <chemical_shift value="44.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CA"/>
+ <chemical_shift value="55.765" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="N"/>
+ <chemical_shift value="117.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CD1"/>
+ <chemical_shift value="24.729" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CD2"/>
+ <chemical_shift value="22.791" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="H"/>
+ <chemical_shift value="7.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="122" name="HD21"/>
+ <atom segid=" A" residue="122" name="HD22"/>
+ <atom segid=" A" residue="122" name="HD23"/>
+ <chemical_shift value="0.937" error="0.0"/>
+ <chemical_shift value="0.93" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="122" name="HD11"/>
+ <atom segid=" A" residue="122" name="HD12"/>
+ <atom segid=" A" residue="122" name="HD13"/>
+ <chemical_shift value="0.937" error="0.0"/>
+ <chemical_shift value="0.93" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CB"/>
+ <chemical_shift value="44.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CA"/>
+ <chemical_shift value="51.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="N"/>
+ <chemical_shift value="119.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CD1"/>
+ <chemical_shift value="25.548" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CD2"/>
+ <chemical_shift value="26.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="C"/>
+ <chemical_shift value="176.075" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CB"/>
+ <chemical_shift value="31.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CA"/>
+ <chemical_shift value="62.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="127" name="HZ1"/>
+ <atom segid=" A" residue="127" name="HZ2"/>
+ <atom segid=" A" residue="127" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CB"/>
+ <chemical_shift value="33.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="C"/>
+ <chemical_shift value="177.427" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="H"/>
+ <chemical_shift value="8.137" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CA"/>
+ <chemical_shift value="56.778" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="N"/>
+ <chemical_shift value="118.457" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="128" name="HG21"/>
+ <atom segid=" A" residue="128" name="HG22"/>
+ <atom segid=" A" residue="128" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="C"/>
+ <chemical_shift value="174.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CB"/>
+ <chemical_shift value="71.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CA"/>
+ <chemical_shift value="60.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="N"/>
+ <chemical_shift value="108.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="H"/>
+ <chemical_shift value="10.183" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="C"/>
+ <chemical_shift value="179.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CB"/>
+ <chemical_shift value="28.48" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CA"/>
+ <chemical_shift value="60.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="N"/>
+ <chemical_shift value="123.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="C"/>
+ <chemical_shift value="178.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CB"/>
+ <chemical_shift value="28.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CA"/>
+ <chemical_shift value="61.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="N"/>
+ <chemical_shift value="118.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="H"/>
+ <chemical_shift value="10.583" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="C"/>
+ <chemical_shift value="176.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CB"/>
+ <chemical_shift value="31.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CA"/>
+ <chemical_shift value="57.205" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="N"/>
+ <chemical_shift value="116.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="H"/>
+ <chemical_shift value="7.606" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="132" name="HG21"/>
+ <atom segid=" A" residue="132" name="HG22"/>
+ <atom segid=" A" residue="132" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.56" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="132" name="HD11"/>
+ <atom segid=" A" residue="132" name="HD12"/>
+ <atom segid=" A" residue="132" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CB"/>
+ <chemical_shift value="33.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CA"/>
+ <chemical_shift value="66.928" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="N"/>
+ <chemical_shift value="121.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CD1"/>
+ <chemical_shift value="12.36" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="H"/>
+ <chemical_shift value="8.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="C"/>
+ <chemical_shift value="177.795" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CB"/>
+ <chemical_shift value="30.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CA"/>
+ <chemical_shift value="67.059" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="134" name="HB1"/>
+ <atom segid=" A" residue="134" name="HB2"/>
+ <atom segid=" A" residue="134" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="C"/>
+ <chemical_shift value="181.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="CB"/>
+ <chemical_shift value="17.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="CA"/>
+ <chemical_shift value="55.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="N"/>
+ <chemical_shift value="118.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="H"/>
+ <chemical_shift value="7.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="135" name="HD21"/>
+ <atom segid=" A" residue="135" name="HD22"/>
+ <atom segid=" A" residue="135" name="HD23"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ <chemical_shift value="0.888" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="135" name="HD11"/>
+ <atom segid=" A" residue="135" name="HD12"/>
+ <atom segid=" A" residue="135" name="HD13"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ <chemical_shift value="0.888" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="C"/>
+ <chemical_shift value="179.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CB"/>
+ <chemical_shift value="42.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CA"/>
+ <chemical_shift value="57.396" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="N"/>
+ <chemical_shift value="120.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CD1"/>
+ <chemical_shift value="24.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CD2"/>
+ <chemical_shift value="24.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="H"/>
+ <chemical_shift value="7.6" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="C"/>
+ <chemical_shift value="177.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CB"/>
+ <chemical_shift value="41.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CA"/>
+ <chemical_shift value="58.901" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="N"/>
+ <chemical_shift value="118.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="H"/>
+ <chemical_shift value="8.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="137" name="HZ1"/>
+ <atom segid=" A" residue="137" name="HZ2"/>
+ <atom segid=" A" residue="137" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CB"/>
+ <chemical_shift value="31.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="C"/>
+ <chemical_shift value="179.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="H"/>
+ <chemical_shift value="8.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CA"/>
+ <chemical_shift value="60.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="N"/>
+ <chemical_shift value="117.342" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="C"/>
+ <chemical_shift value="179.799" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CB"/>
+ <chemical_shift value="29.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CA"/>
+ <chemical_shift value="59.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="N"/>
+ <chemical_shift value="118.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="H"/>
+ <chemical_shift value="7.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="139" name="HD21"/>
+ <atom segid=" A" residue="139" name="HD22"/>
+ <atom segid=" A" residue="139" name="HD23"/>
+ <chemical_shift value="0.852" error="0.0"/>
+ <chemical_shift value="0.787" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="139" name="HD11"/>
+ <atom segid=" A" residue="139" name="HD12"/>
+ <atom segid=" A" residue="139" name="HD13"/>
+ <chemical_shift value="0.852" error="0.0"/>
+ <chemical_shift value="0.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="C"/>
+ <chemical_shift value="180.721" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CB"/>
+ <chemical_shift value="40.311" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CA"/>
+ <chemical_shift value="58.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="N"/>
+ <chemical_shift value="121.279" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CD1"/>
+ <chemical_shift value="25.914" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CD2"/>
+ <chemical_shift value="22.927" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="H"/>
+ <chemical_shift value="8.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="140" name="HZ1"/>
+ <atom segid=" A" residue="140" name="HZ2"/>
+ <atom segid=" A" residue="140" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CB"/>
+ <chemical_shift value="31.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="C"/>
+ <chemical_shift value="181.621" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="H"/>
+ <chemical_shift value="9.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CA"/>
+ <chemical_shift value="58.851" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="N"/>
+ <chemical_shift value="124.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="141" name="HB1"/>
+ <atom segid=" A" residue="141" name="HB2"/>
+ <atom segid=" A" residue="141" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="C"/>
+ <chemical_shift value="178.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="CB"/>
+ <chemical_shift value="17.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="CA"/>
+ <chemical_shift value="54.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="N"/>
+ <chemical_shift value="122.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="H"/>
+ <chemical_shift value="7.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="142" name="HZ1"/>
+ <atom segid=" A" residue="142" name="HZ2"/>
+ <atom segid=" A" residue="142" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CB"/>
+ <chemical_shift value="32.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="C"/>
+ <chemical_shift value="176.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="H"/>
+ <chemical_shift value="7.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CA"/>
+ <chemical_shift value="55.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="N"/>
+ <chemical_shift value="115.794" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="C"/>
+ <chemical_shift value="174.318" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="H"/>
+ <chemical_shift value="7.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="CA"/>
+ <chemical_shift value="46.128" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="N"/>
+ <chemical_shift value="107.82" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="144" name="HZ1"/>
+ <atom segid=" A" residue="144" name="HZ2"/>
+ <atom segid=" A" residue="144" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CB"/>
+ <chemical_shift value="35.01" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="C"/>
+ <chemical_shift value="173.812" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="H"/>
+ <chemical_shift value="7.86" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CA"/>
+ <chemical_shift value="53.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="N"/>
+ <chemical_shift value="119.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="C"/>
+ <chemical_shift value="174.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="CB"/>
+ <chemical_shift value="66.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="CA"/>
+ <chemical_shift value="56.884" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="N"/>
+ <chemical_shift value="109.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="H"/>
+ <chemical_shift value="7.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="146" name="HB1"/>
+ <atom segid=" A" residue="146" name="HB2"/>
+ <atom segid=" A" residue="146" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="C"/>
+ <chemical_shift value="175.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="CB"/>
+ <chemical_shift value="17.973" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="CA"/>
+ <chemical_shift value="55.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="N"/>
+ <chemical_shift value="122.791" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="H"/>
+ <chemical_shift value="9.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="147" name="HD21"/>
+ <atom segid=" A" residue="147" name="HD22"/>
+ <atom segid=" A" residue="147" name="HD23"/>
+ <chemical_shift value="0.936" error="0.0"/>
+ <chemical_shift value="0.683" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="147" name="HD11"/>
+ <atom segid=" A" residue="147" name="HD12"/>
+ <atom segid=" A" residue="147" name="HD13"/>
+ <chemical_shift value="0.936" error="0.0"/>
+ <chemical_shift value="0.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="C"/>
+ <chemical_shift value="175.05" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CB"/>
+ <chemical_shift value="45.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CA"/>
+ <chemical_shift value="54.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="N"/>
+ <chemical_shift value="116.868" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CD1"/>
+ <chemical_shift value="22.5" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CD2"/>
+ <chemical_shift value="27.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="H"/>
+ <chemical_shift value="8.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="148" name="HE1"/>
+ <atom segid=" A" residue="148" name="HE2"/>
+ <atom segid=" A" residue="148" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="C"/>
+ <chemical_shift value="174.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CB"/>
+ <chemical_shift value="37.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CA"/>
+ <chemical_shift value="55.8" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="N"/>
+ <chemical_shift value="121.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="H"/>
+ <chemical_shift value="8.179" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="149" name="HD2"/>
+ <atom segid=" A" residue="149" name="HE1"/>
+ <atom segid=" A" residue="149" name="HE2"/>
+ <atom segid=" A" residue="149" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="171.59" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CB"/>
+ <chemical_shift value="41.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CA"/>
+ <chemical_shift value="55.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="N"/>
+ <chemical_shift value="120.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="H"/>
+ <chemical_shift value="8.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="C"/>
+ <chemical_shift value="172.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="37.305" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CA"/>
+ <chemical_shift value="53.341" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="N"/>
+ <chemical_shift value="116.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="8.671" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="151" name="HD22"/>
+ <atom segid=" A" residue="151" name="HD23"/>
+ <chemical_shift value="0.135" error="0.0"/>
+ <chemical_shift value="0.744" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="151" name="HD11"/>
+ <atom segid=" A" residue="151" name="HD12"/>
+ <atom segid=" A" residue="151" name="HD13"/>
+ <chemical_shift value="0.135" error="0.0"/>
+ <chemical_shift value="0.744" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="41.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CA"/>
+ <chemical_shift value="54.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="122.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="26.232" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="23.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="7.286" error="0.0"/>
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="C"/>
+ <chemical_shift value="176.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CB"/>
+ <chemical_shift value="28.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CA"/>
+ <chemical_shift value="55.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="N"/>
+ <chemical_shift value="113.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="H"/>
+ <chemical_shift value="7.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CB"/>
+ <chemical_shift value="32.958" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CA"/>
+ <chemical_shift value="51.537" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="N"/>
+ <chemical_shift value="113.572" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="H"/>
+ <chemical_shift value="6.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="C"/>
+ <chemical_shift value="176.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CB"/>
+ <chemical_shift value="31.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CA"/>
+ <chemical_shift value="63.731" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="155" name="HD1"/>
+ <atom segid=" A" residue="155" name="HD2"/>
+ <atom segid=" A" residue="155" name="HE1"/>
+ <atom segid=" A" residue="155" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="C"/>
+ <chemical_shift value="176.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CB"/>
+ <chemical_shift value="40.447" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CA"/>
+ <chemical_shift value="62.679" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="N"/>
+ <chemical_shift value="117.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="H"/>
+ <chemical_shift value="7.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="156" name="HD1"/>
+ <atom segid=" A" residue="156" name="HD2"/>
+ <atom segid=" A" residue="156" name="HE1"/>
+ <atom segid=" A" residue="156" name="HE2"/>
+ <atom segid=" A" residue="156" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="C"/>
+ <chemical_shift value="176.222" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CB"/>
+ <chemical_shift value="41.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CA"/>
+ <chemical_shift value="60.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="N"/>
+ <chemical_shift value="112.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="H"/>
+ <chemical_shift value="8.045" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="157" name="HG21"/>
+ <atom segid=" A" residue="157" name="HG22"/>
+ <atom segid=" A" residue="157" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="C"/>
+ <chemical_shift value="176.039" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CB"/>
+ <chemical_shift value="69.29" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CA"/>
+ <chemical_shift value="63.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="N"/>
+ <chemical_shift value="106.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="H"/>
+ <chemical_shift value="7.59" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CB"/>
+ <chemical_shift value="28.509" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CA"/>
+ <chemical_shift value="60.968" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="N"/>
+ <chemical_shift value="124.195" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="C"/>
+ <chemical_shift value="178.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CB"/>
+ <chemical_shift value="30.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CA"/>
+ <chemical_shift value="65.931" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="160" name="HD21"/>
+ <atom segid=" A" residue="160" name="HD22"/>
+ <atom segid=" A" residue="160" name="HD23"/>
+ <chemical_shift value="-0.302" error="0.0"/>
+ <chemical_shift value="-1.003" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="160" name="HD11"/>
+ <atom segid=" A" residue="160" name="HD12"/>
+ <atom segid=" A" residue="160" name="HD13"/>
+ <chemical_shift value="-0.302" error="0.0"/>
+ <chemical_shift value="-1.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="C"/>
+ <chemical_shift value="176.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CB"/>
+ <chemical_shift value="42.223" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CA"/>
+ <chemical_shift value="56.069" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="N"/>
+ <chemical_shift value="111.624" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CD1"/>
+ <chemical_shift value="19.602" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CD2"/>
+ <chemical_shift value="25.084" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="H"/>
+ <chemical_shift value="6.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="161" name="HG21"/>
+ <atom segid=" A" residue="161" name="HG22"/>
+ <atom segid=" A" residue="161" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.76" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="161" name="HD11"/>
+ <atom segid=" A" residue="161" name="HD12"/>
+ <atom segid=" A" residue="161" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="C"/>
+ <chemical_shift value="175.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CB"/>
+ <chemical_shift value="37.395" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CA"/>
+ <chemical_shift value="65.625" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="N"/>
+ <chemical_shift value="119.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CD1"/>
+ <chemical_shift value="13.081" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="H"/>
+ <chemical_shift value="6.955" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="162" name="HB1"/>
+ <atom segid=" A" residue="162" name="HB2"/>
+ <atom segid=" A" residue="162" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="C"/>
+ <chemical_shift value="179.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="CB"/>
+ <chemical_shift value="18.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="CA"/>
+ <chemical_shift value="52.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="N"/>
+ <chemical_shift value="115.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="H"/>
+ <chemical_shift value="8.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="163" name="HB1"/>
+ <atom segid=" A" residue="163" name="HB2"/>
+ <atom segid=" A" residue="163" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="C"/>
+ <chemical_shift value="178.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="CB"/>
+ <chemical_shift value="19.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="CA"/>
+ <chemical_shift value="56.425" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="N"/>
+ <chemical_shift value="120.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="H"/>
+ <chemical_shift value="6.668" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="C"/>
+ <chemical_shift value="176.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CB"/>
+ <chemical_shift value="42.538" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CA"/>
+ <chemical_shift value="53.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="N"/>
+ <chemical_shift value="115.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="H"/>
+ <chemical_shift value="9.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="C"/>
+ <chemical_shift value="175.607" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="H"/>
+ <chemical_shift value="7.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="CA"/>
+ <chemical_shift value="45.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="N"/>
+ <chemical_shift value="103.622" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="C"/>
+ <chemical_shift value="172.227" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="H"/>
+ <chemical_shift value="7.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="CA"/>
+ <chemical_shift value="45.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="N"/>
+ <chemical_shift value="108.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="167" name="HD1"/>
+ <atom segid=" A" residue="167" name="HD2"/>
+ <atom segid=" A" residue="167" name="HE1"/>
+ <atom segid=" A" residue="167" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="C"/>
+ <chemical_shift value="173.273" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CB"/>
+ <chemical_shift value="39.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CA"/>
+ <chemical_shift value="57.657" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="N"/>
+ <chemical_shift value="115.865" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="H"/>
+ <chemical_shift value="8.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="168" name="HB1"/>
+ <atom segid=" A" residue="168" name="HB2"/>
+ <atom segid=" A" residue="168" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="C"/>
+ <chemical_shift value="173.012" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="CB"/>
+ <chemical_shift value="16.475" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="CA"/>
+ <chemical_shift value="53.124" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="N"/>
+ <chemical_shift value="124.0" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="H"/>
+ <chemical_shift value="10.209" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="169" name="HD1"/>
+ <atom segid=" A" residue="169" name="HD2"/>
+ <atom segid=" A" residue="169" name="HE1"/>
+ <atom segid=" A" residue="169" name="HE2"/>
+ <atom segid=" A" residue="169" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="C"/>
+ <chemical_shift value="176.744" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CB"/>
+ <chemical_shift value="42.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CA"/>
+ <chemical_shift value="55.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="N"/>
+ <chemical_shift value="108.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="H"/>
+ <chemical_shift value="6.324" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="170" name="HZ1"/>
+ <atom segid=" A" residue="170" name="HZ2"/>
+ <atom segid=" A" residue="170" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CB"/>
+ <chemical_shift value="32.355" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="C"/>
+ <chemical_shift value="174.716" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="H"/>
+ <chemical_shift value="8.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CA"/>
+ <chemical_shift value="57.027" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="N"/>
+ <chemical_shift value="125.705" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="171" name="HD1"/>
+ <atom segid=" A" residue="171" name="HD2"/>
+ <atom segid=" A" residue="171" name="HE1"/>
+ <atom segid=" A" residue="171" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="C"/>
+ <chemical_shift value="175.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CB"/>
+ <chemical_shift value="39.896" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CA"/>
+ <chemical_shift value="56.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="N"/>
+ <chemical_shift value="129.707" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="H"/>
+ <chemical_shift value="8.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CB"/>
+ <chemical_shift value="32.477" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CA"/>
+ <chemical_shift value="55.981" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="N"/>
+ <chemical_shift value="126.797" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="H"/>
+ <chemical_shift value="8.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="C"/>
+ <chemical_shift value="175.432" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CB"/>
+ <chemical_shift value="37.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CA"/>
+ <chemical_shift value="54.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="C"/>
+ <chemical_shift value="173.294" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="H"/>
+ <chemical_shift value="7.52" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="CA"/>
+ <chemical_shift value="45.705" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="N"/>
+ <chemical_shift value="102.08" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="175" name="HZ1"/>
+ <atom segid=" A" residue="175" name="HZ2"/>
+ <atom segid=" A" residue="175" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CB"/>
+ <chemical_shift value="35.233" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="C"/>
+ <chemical_shift value="174.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="H"/>
+ <chemical_shift value="7.107" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CA"/>
+ <chemical_shift value="54.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="N"/>
+ <chemical_shift value="118.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="176" name="HD1"/>
+ <atom segid=" A" residue="176" name="HD2"/>
+ <atom segid=" A" residue="176" name="HE1"/>
+ <atom segid=" A" residue="176" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="C"/>
+ <chemical_shift value="176.262" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CB"/>
+ <chemical_shift value="39.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CA"/>
+ <chemical_shift value="58.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="N"/>
+ <chemical_shift value="120.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="H"/>
+ <chemical_shift value="8.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="C"/>
+ <chemical_shift value="177.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CB"/>
+ <chemical_shift value="41.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CA"/>
+ <chemical_shift value="52.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="N"/>
+ <chemical_shift value="124.051" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="H"/>
+ <chemical_shift value="9.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="178" name="HG21"/>
+ <atom segid=" A" residue="178" name="HG22"/>
+ <atom segid=" A" residue="178" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.853" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="178" name="HD11"/>
+ <atom segid=" A" residue="178" name="HD12"/>
+ <atom segid=" A" residue="178" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="C"/>
+ <chemical_shift value="175.849" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CB"/>
+ <chemical_shift value="36.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CA"/>
+ <chemical_shift value="63.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="N"/>
+ <chemical_shift value="117.051" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CD1"/>
+ <chemical_shift value="13.905" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="H"/>
+ <chemical_shift value="7.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="179" name="HZ1"/>
+ <atom segid=" A" residue="179" name="HZ2"/>
+ <atom segid=" A" residue="179" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CB"/>
+ <chemical_shift value="31.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="C"/>
+ <chemical_shift value="176.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="H"/>
+ <chemical_shift value="8.302" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CA"/>
+ <chemical_shift value="54.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="N"/>
+ <chemical_shift value="116.075" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="C"/>
+ <chemical_shift value="172.993" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CB"/>
+ <chemical_shift value="40.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CA"/>
+ <chemical_shift value="53.425" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="N"/>
+ <chemical_shift value="123.259" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="H"/>
+ <chemical_shift value="7.754" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="181" name="HG21"/>
+ <atom segid=" A" residue="181" name="HG22"/>
+ <atom segid=" A" residue="181" name="HG23"/>
+ <chemical_shift value="0.711" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="181" name="HG11"/>
+ <atom segid=" A" residue="181" name="HG12"/>
+ <atom segid=" A" residue="181" name="HG13"/>
+ <chemical_shift value="0.711" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="C"/>
+ <chemical_shift value="176.899" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CB"/>
+ <chemical_shift value="35.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CA"/>
+ <chemical_shift value="59.481" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="N"/>
+ <chemical_shift value="122.883" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CG1"/>
+ <chemical_shift value="21.539" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="H"/>
+ <chemical_shift value="7.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CG2"/>
+ <chemical_shift value="22.538" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="C"/>
+ <chemical_shift value="174.259" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="H"/>
+ <chemical_shift value="7.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="CA"/>
+ <chemical_shift value="46.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="N"/>
+ <chemical_shift value="120.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="183" name="HG21"/>
+ <atom segid=" A" residue="183" name="HG22"/>
+ <atom segid=" A" residue="183" name="HG23"/>
+ <chemical_shift value="0.841" error="0.0"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="183" name="HG11"/>
+ <atom segid=" A" residue="183" name="HG12"/>
+ <atom segid=" A" residue="183" name="HG13"/>
+ <chemical_shift value="0.841" error="0.0"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="C"/>
+ <chemical_shift value="173.292" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CB"/>
+ <chemical_shift value="32.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CA"/>
+ <chemical_shift value="63.489" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="N"/>
+ <chemical_shift value="114.266" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CG1"/>
+ <chemical_shift value="22.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="H"/>
+ <chemical_shift value="6.757" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CG2"/>
+ <chemical_shift value="22.42" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="C"/>
+ <chemical_shift value="176.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CB"/>
+ <chemical_shift value="39.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CA"/>
+ <chemical_shift value="51.67" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="N"/>
+ <chemical_shift value="114.851" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="H"/>
+ <chemical_shift value="7.835" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CB"/>
+ <chemical_shift value="39.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CA"/>
+ <chemical_shift value="51.688" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="N"/>
+ <chemical_shift value="116.3" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="H"/>
+ <chemical_shift value="6.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="186" name="HB1"/>
+ <atom segid=" A" residue="186" name="HB2"/>
+ <atom segid=" A" residue="186" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="C"/>
+ <chemical_shift value="180.525" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="CB"/>
+ <chemical_shift value="18.22" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="CA"/>
+ <chemical_shift value="55.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="C"/>
+ <chemical_shift value="176.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="H"/>
+ <chemical_shift value="8.385" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="CA"/>
+ <chemical_shift value="47.366" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="N"/>
+ <chemical_shift value="109.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="188" name="HB1"/>
+ <atom segid=" A" residue="188" name="HB2"/>
+ <atom segid=" A" residue="188" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="C"/>
+ <chemical_shift value="180.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="CB"/>
+ <chemical_shift value="18.399" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="CA"/>
+ <chemical_shift value="54.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="N"/>
+ <chemical_shift value="127.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="H"/>
+ <chemical_shift value="8.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="189" name="HZ1"/>
+ <atom segid=" A" residue="189" name="HZ2"/>
+ <atom segid=" A" residue="189" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CB"/>
+ <chemical_shift value="31.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="C"/>
+ <chemical_shift value="180.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="H"/>
+ <chemical_shift value="7.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CA"/>
+ <chemical_shift value="59.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="N"/>
+ <chemical_shift value="115.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="190" name="HB1"/>
+ <atom segid=" A" residue="190" name="HB2"/>
+ <atom segid=" A" residue="190" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="C"/>
+ <chemical_shift value="181.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="CB"/>
+ <chemical_shift value="17.89" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="CA"/>
+ <chemical_shift value="55.835" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="N"/>
+ <chemical_shift value="124.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="H"/>
+ <chemical_shift value="8.224" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="C"/>
+ <chemical_shift value="174.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="H"/>
+ <chemical_shift value="8.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="CA"/>
+ <chemical_shift value="47.937" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="N"/>
+ <chemical_shift value="107.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="192" name="HD21"/>
+ <atom segid=" A" residue="192" name="HD22"/>
+ <atom segid=" A" residue="192" name="HD23"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="1.085" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="192" name="HD11"/>
+ <atom segid=" A" residue="192" name="HD12"/>
+ <atom segid=" A" residue="192" name="HD13"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="1.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="C"/>
+ <chemical_shift value="178.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CB"/>
+ <chemical_shift value="40.218" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CA"/>
+ <chemical_shift value="57.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="N"/>
+ <chemical_shift value="121.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CD1"/>
+ <chemical_shift value="24.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CD2"/>
+ <chemical_shift value="25.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="H"/>
+ <chemical_shift value="8.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="193" name="HG21"/>
+ <atom segid=" A" residue="193" name="HG22"/>
+ <atom segid=" A" residue="193" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="C"/>
+ <chemical_shift value="175.23" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CB"/>
+ <chemical_shift value="69.081" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CA"/>
+ <chemical_shift value="67.423" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="N"/>
+ <chemical_shift value="116.486" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="H"/>
+ <chemical_shift value="8.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="194" name="HD1"/>
+ <atom segid=" A" residue="194" name="HD2"/>
+ <atom segid=" A" residue="194" name="HE1"/>
+ <atom segid=" A" residue="194" name="HE2"/>
+ <atom segid=" A" residue="194" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="C"/>
+ <chemical_shift value="177.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CB"/>
+ <chemical_shift value="39.196" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CA"/>
+ <chemical_shift value="62.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="N"/>
+ <chemical_shift value="122.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="H"/>
+ <chemical_shift value="7.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="195" name="HD22"/>
+ <atom segid=" A" residue="195" name="HD23"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="195" name="HD11"/>
+ <atom segid=" A" residue="195" name="HD12"/>
+ <atom segid=" A" residue="195" name="HD13"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="C"/>
+ <chemical_shift value="178.132" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CB"/>
+ <chemical_shift value="41.352" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CA"/>
+ <chemical_shift value="58.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="N"/>
+ <chemical_shift value="119.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CD1"/>
+ <chemical_shift value="23.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CD2"/>
+ <chemical_shift value="25.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="H"/>
+ <chemical_shift value="7.712" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="196" name="HG21"/>
+ <atom segid=" A" residue="196" name="HG22"/>
+ <atom segid=" A" residue="196" name="HG23"/>
+ <chemical_shift value="0.856" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="196" name="HG11"/>
+ <atom segid=" A" residue="196" name="HG12"/>
+ <atom segid=" A" residue="196" name="HG13"/>
+ <chemical_shift value="0.856" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="C"/>
+ <chemical_shift value="178.464" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CB"/>
+ <chemical_shift value="31.053" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CA"/>
+ <chemical_shift value="67.271" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="N"/>
+ <chemical_shift value="117.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CG1"/>
+ <chemical_shift value="21.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="H"/>
+ <chemical_shift value="8.589" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CG2"/>
+ <chemical_shift value="23.319" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="C"/>
+ <chemical_shift value="179.361" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CB"/>
+ <chemical_shift value="39.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CA"/>
+ <chemical_shift value="58.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="N"/>
+ <chemical_shift value="122.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="H"/>
+ <chemical_shift value="8.58" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="198" name="HD21"/>
+ <atom segid=" A" residue="198" name="HD22"/>
+ <atom segid=" A" residue="198" name="HD23"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="1.018" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="198" name="HD11"/>
+ <atom segid=" A" residue="198" name="HD12"/>
+ <atom segid=" A" residue="198" name="HD13"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="1.018" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="C"/>
+ <chemical_shift value="179.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CB"/>
+ <chemical_shift value="42.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CA"/>
+ <chemical_shift value="58.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="N"/>
+ <chemical_shift value="120.213" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CD1"/>
+ <chemical_shift value="25.598" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CD2"/>
+ <chemical_shift value="23.461" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="H"/>
+ <chemical_shift value="7.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="199" name="HG21"/>
+ <atom segid=" A" residue="199" name="HG22"/>
+ <atom segid=" A" residue="199" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.743" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="199" name="HD11"/>
+ <atom segid=" A" residue="199" name="HD12"/>
+ <atom segid=" A" residue="199" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.743" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="C"/>
+ <chemical_shift value="181.156" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CB"/>
+ <chemical_shift value="38.209" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CA"/>
+ <chemical_shift value="63.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="N"/>
+ <chemical_shift value="119.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CD1"/>
+ <chemical_shift value="14.222" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="H"/>
+ <chemical_shift value="7.434" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="200" name="HZ1"/>
+ <atom segid=" A" residue="200" name="HZ2"/>
+ <atom segid=" A" residue="200" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CB"/>
+ <chemical_shift value="32.127" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="C"/>
+ <chemical_shift value="178.834" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="H"/>
+ <chemical_shift value="9.393" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CA"/>
+ <chemical_shift value="59.943" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="N"/>
+ <chemical_shift value="124.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="C"/>
+ <chemical_shift value="173.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CB"/>
+ <chemical_shift value="38.686" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CA"/>
+ <chemical_shift value="53.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="N"/>
+ <chemical_shift value="113.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="H"/>
+ <chemical_shift value="8.004" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="202" name="HZ2"/>
+ <atom segid=" A" residue="202" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CB"/>
+ <chemical_shift value="27.266" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="C"/>
+ <chemical_shift value="175.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="H"/>
+ <chemical_shift value="7.932" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CA"/>
+ <chemical_shift value="57.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="N"/>
+ <chemical_shift value="111.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="C"/>
+ <chemical_shift value="175.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CB"/>
+ <chemical_shift value="28.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CA"/>
+ <chemical_shift value="57.268" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="N"/>
+ <chemical_shift value="116.235" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="H"/>
+ <chemical_shift value="8.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="204" name="HE1"/>
+ <atom segid=" A" residue="204" name="HE2"/>
+ <atom segid=" A" residue="204" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="C"/>
+ <chemical_shift value="173.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CB"/>
+ <chemical_shift value="37.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CA"/>
+ <chemical_shift value="54.646" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="N"/>
+ <chemical_shift value="114.03" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="H"/>
+ <chemical_shift value="7.477" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="C"/>
+ <chemical_shift value="176.088" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CB"/>
+ <chemical_shift value="40.287" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CA"/>
+ <chemical_shift value="52.185" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="N"/>
+ <chemical_shift value="118.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="H"/>
+ <chemical_shift value="8.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="206" name="HB1"/>
+ <atom segid=" A" residue="206" name="HB2"/>
+ <atom segid=" A" residue="206" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="C"/>
+ <chemical_shift value="176.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="CB"/>
+ <chemical_shift value="18.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="CA"/>
+ <chemical_shift value="54.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="N"/>
+ <chemical_shift value="125.067" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="H"/>
+ <chemical_shift value="9.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="C"/>
+ <chemical_shift value="176.539" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CB"/>
+ <chemical_shift value="39.943" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CA"/>
+ <chemical_shift value="53.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="N"/>
+ <chemical_shift value="112.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="H"/>
+ <chemical_shift value="8.172" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="208" name="HG21"/>
+ <atom segid=" A" residue="208" name="HG22"/>
+ <atom segid=" A" residue="208" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="C"/>
+ <chemical_shift value="173.305" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CB"/>
+ <chemical_shift value="69.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CA"/>
+ <chemical_shift value="66.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="N"/>
+ <chemical_shift value="116.637" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="H"/>
+ <chemical_shift value="7.344" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="C"/>
+ <chemical_shift value="175.818" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CB"/>
+ <chemical_shift value="42.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CA"/>
+ <chemical_shift value="51.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="N"/>
+ <chemical_shift value="130.935" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="H"/>
+ <chemical_shift value="6.982" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="210" name="HD1"/>
+ <atom segid=" A" residue="210" name="HD2"/>
+ <atom segid=" A" residue="210" name="HE1"/>
+ <atom segid=" A" residue="210" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="C"/>
+ <chemical_shift value="178.37" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CB"/>
+ <chemical_shift value="39.077" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CA"/>
+ <chemical_shift value="63.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="N"/>
+ <chemical_shift value="117.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="H"/>
+ <chemical_shift value="7.858" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="C"/>
+ <chemical_shift value="177.629" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="CB"/>
+ <chemical_shift value="63.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="CA"/>
+ <chemical_shift value="61.419" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="N"/>
+ <chemical_shift value="114.682" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="H"/>
+ <chemical_shift value="8.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="212" name="HG21"/>
+ <atom segid=" A" residue="212" name="HG22"/>
+ <atom segid=" A" residue="212" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.867" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="212" name="HD11"/>
+ <atom segid=" A" residue="212" name="HD12"/>
+ <atom segid=" A" residue="212" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="C"/>
+ <chemical_shift value="179.021" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CB"/>
+ <chemical_shift value="38.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CA"/>
+ <chemical_shift value="65.023" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="N"/>
+ <chemical_shift value="124.45" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CD1"/>
+ <chemical_shift value="13.11" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="H"/>
+ <chemical_shift value="8.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="213" name="HB1"/>
+ <atom segid=" A" residue="213" name="HB2"/>
+ <atom segid=" A" residue="213" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="C"/>
+ <chemical_shift value="177.865" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="CB"/>
+ <chemical_shift value="17.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="CA"/>
+ <chemical_shift value="55.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="N"/>
+ <chemical_shift value="120.747" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="H"/>
+ <chemical_shift value="7.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="C"/>
+ <chemical_shift value="178.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CB"/>
+ <chemical_shift value="29.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CA"/>
+ <chemical_shift value="58.941" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="N"/>
+ <chemical_shift value="117.551" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="215" name="HB1"/>
+ <atom segid=" A" residue="215" name="HB2"/>
+ <atom segid=" A" residue="215" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="C"/>
+ <chemical_shift value="179.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="CB"/>
+ <chemical_shift value="18.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="CA"/>
+ <chemical_shift value="54.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="N"/>
+ <chemical_shift value="119.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="H"/>
+ <chemical_shift value="7.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="216" name="HB1"/>
+ <atom segid=" A" residue="216" name="HB2"/>
+ <atom segid=" A" residue="216" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="C"/>
+ <chemical_shift value="180.736" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="CB"/>
+ <chemical_shift value="19.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="CA"/>
+ <chemical_shift value="55.247" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="N"/>
+ <chemical_shift value="117.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="H"/>
+ <chemical_shift value="7.789" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="217" name="HD1"/>
+ <atom segid=" A" residue="217" name="HD2"/>
+ <atom segid=" A" residue="217" name="HE1"/>
+ <atom segid=" A" residue="217" name="HE2"/>
+ <atom segid=" A" residue="217" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CB"/>
+ <chemical_shift value="38.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CA"/>
+ <chemical_shift value="62.919" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="N"/>
+ <chemical_shift value="119.446" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="H"/>
+ <chemical_shift value="8.338" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="C"/>
+ <chemical_shift value="176.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CB"/>
+ <chemical_shift value="36.484" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CA"/>
+ <chemical_shift value="55.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="219" name="HZ1"/>
+ <atom segid=" A" residue="219" name="HZ2"/>
+ <atom segid=" A" residue="219" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CB"/>
+ <chemical_shift value="32.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="C"/>
+ <chemical_shift value="177.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="H"/>
+ <chemical_shift value="7.713" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CA"/>
+ <chemical_shift value="56.131" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="N"/>
+ <chemical_shift value="116.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="C"/>
+ <chemical_shift value="175.309" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="H"/>
+ <chemical_shift value="7.717" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="CA"/>
+ <chemical_shift value="46.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="N"/>
+ <chemical_shift value="108.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="C"/>
+ <chemical_shift value="175.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CB"/>
+ <chemical_shift value="30.469" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CA"/>
+ <chemical_shift value="57.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="N"/>
+ <chemical_shift value="116.369" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="H"/>
+ <chemical_shift value="8.382" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="222" name="HG21"/>
+ <atom segid=" A" residue="222" name="HG22"/>
+ <atom segid=" A" residue="222" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="C"/>
+ <chemical_shift value="172.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CB"/>
+ <chemical_shift value="70.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CA"/>
+ <chemical_shift value="58.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="N"/>
+ <chemical_shift value="110.551" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="H"/>
+ <chemical_shift value="6.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="223" name="HB1"/>
+ <atom segid=" A" residue="223" name="HB2"/>
+ <atom segid=" A" residue="223" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="C"/>
+ <chemical_shift value="176.461" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="CB"/>
+ <chemical_shift value="20.427" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="CA"/>
+ <chemical_shift value="54.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="N"/>
+ <chemical_shift value="127.376" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="H"/>
+ <chemical_shift value="8.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="224" name="HE1"/>
+ <atom segid=" A" residue="224" name="HE2"/>
+ <atom segid=" A" residue="224" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="C"/>
+ <chemical_shift value="173.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CB"/>
+ <chemical_shift value="40.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CA"/>
+ <chemical_shift value="54.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="N"/>
+ <chemical_shift value="114.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="H"/>
+ <chemical_shift value="8.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="225" name="HG21"/>
+ <atom segid=" A" residue="225" name="HG22"/>
+ <atom segid=" A" residue="225" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="C"/>
+ <chemical_shift value="171.424" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CB"/>
+ <chemical_shift value="71.023" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CA"/>
+ <chemical_shift value="59.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="N"/>
+ <chemical_shift value="113.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="H"/>
+ <chemical_shift value="9.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="226" name="HG21"/>
+ <atom segid=" A" residue="226" name="HG22"/>
+ <atom segid=" A" residue="226" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.06" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="226" name="HD11"/>
+ <atom segid=" A" residue="226" name="HD12"/>
+ <atom segid=" A" residue="226" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.06" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="C"/>
+ <chemical_shift value="174.82" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CB"/>
+ <chemical_shift value="40.344" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CA"/>
+ <chemical_shift value="60.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="N"/>
+ <chemical_shift value="122.714" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CD1"/>
+ <chemical_shift value="11.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="H"/>
+ <chemical_shift value="7.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="C"/>
+ <chemical_shift value="175.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CB"/>
+ <chemical_shift value="42.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CA"/>
+ <chemical_shift value="52.466" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="N"/>
+ <chemical_shift value="121.906" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="H"/>
+ <chemical_shift value="8.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="H"/>
+ <chemical_shift value="8.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="CA"/>
+ <chemical_shift value="42.27" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="N"/>
+ <chemical_shift value="110.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CB"/>
+ <chemical_shift value="29.552" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CA"/>
+ <chemical_shift value="62.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="H"/>
+ <chemical_shift value="5.923" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CB"/>
+ <chemical_shift value="26.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CA"/>
+ <chemical_shift value="59.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="N"/>
+ <chemical_shift value="111.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="231" name="HB1"/>
+ <atom segid=" A" residue="231" name="HB2"/>
+ <atom segid=" A" residue="231" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="CB"/>
+ <chemical_shift value="19.11" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="CA"/>
+ <chemical_shift value="52.168" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="N"/>
+ <chemical_shift value="125.512" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="H"/>
+ <chemical_shift value="6.975" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="H"/>
+ <chemical_shift value="7.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CB"/>
+ <chemical_shift value="28.673" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CA"/>
+ <chemical_shift value="58.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="N"/>
+ <chemical_shift value="118.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="235" name="HG21"/>
+ <atom segid=" A" residue="235" name="HG22"/>
+ <atom segid=" A" residue="235" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="235" name="HD11"/>
+ <atom segid=" A" residue="235" name="HD12"/>
+ <atom segid=" A" residue="235" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="237" name="HG21"/>
+ <atom segid=" A" residue="237" name="HG22"/>
+ <atom segid=" A" residue="237" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="239" name="HZ1"/>
+ <atom segid=" A" residue="239" name="HZ2"/>
+ <atom segid=" A" residue="239" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="240" name="HG21"/>
+ <atom segid=" A" residue="240" name="HG22"/>
+ <atom segid=" A" residue="240" name="HG23"/>
+ <atom segid=" A" residue="240" name="HG11"/>
+ <atom segid=" A" residue="240" name="HG12"/>
+ <atom segid=" A" residue="240" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CB"/>
+ <chemical_shift value="37.371" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="242" name="HD1"/>
+ <atom segid=" A" residue="242" name="HD2"/>
+ <atom segid=" A" residue="242" name="HE1"/>
+ <atom segid=" A" residue="242" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="C"/>
+ <chemical_shift value="174.489" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CB"/>
+ <chemical_shift value="41.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CA"/>
+ <chemical_shift value="54.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="N"/>
+ <chemical_shift value="121.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="C"/>
+ <chemical_shift value="171.154" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="H"/>
+ <chemical_shift value="8.494" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="CA"/>
+ <chemical_shift value="42.935" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="N"/>
+ <chemical_shift value="107.501" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="244" name="HG21"/>
+ <atom segid=" A" residue="244" name="HG22"/>
+ <atom segid=" A" residue="244" name="HG23"/>
+ <chemical_shift value="0.636" error="0.0"/>
+ <chemical_shift value="1.072" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="244" name="HG11"/>
+ <atom segid=" A" residue="244" name="HG12"/>
+ <atom segid=" A" residue="244" name="HG13"/>
+ <chemical_shift value="0.636" error="0.0"/>
+ <chemical_shift value="1.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="C"/>
+ <chemical_shift value="174.872" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CB"/>
+ <chemical_shift value="34.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CA"/>
+ <chemical_shift value="61.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="N"/>
+ <chemical_shift value="120.896" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CG1"/>
+ <chemical_shift value="22.083" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="H"/>
+ <chemical_shift value="8.229" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CG2"/>
+ <chemical_shift value="21.606" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="245" name="HG21"/>
+ <atom segid=" A" residue="245" name="HG22"/>
+ <atom segid=" A" residue="245" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="C"/>
+ <chemical_shift value="174.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CB"/>
+ <chemical_shift value="71.559" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CA"/>
+ <chemical_shift value="59.071" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="N"/>
+ <chemical_shift value="119.808" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="H"/>
+ <chemical_shift value="9.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="246" name="HG21"/>
+ <atom segid=" A" residue="246" name="HG22"/>
+ <atom segid=" A" residue="246" name="HG23"/>
+ <chemical_shift value="0.983" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="246" name="HG11"/>
+ <atom segid=" A" residue="246" name="HG12"/>
+ <atom segid=" A" residue="246" name="HG13"/>
+ <chemical_shift value="0.983" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="C"/>
+ <chemical_shift value="175.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CB"/>
+ <chemical_shift value="32.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CA"/>
+ <chemical_shift value="62.433" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="N"/>
+ <chemical_shift value="123.607" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CG1"/>
+ <chemical_shift value="20.441" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CG2"/>
+ <chemical_shift value="21.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="247" name="HD21"/>
+ <atom segid=" A" residue="247" name="HD22"/>
+ <atom segid=" A" residue="247" name="HD23"/>
+ <chemical_shift value="0.645" error="0.0"/>
+ <chemical_shift value="0.663" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="247" name="HD11"/>
+ <atom segid=" A" residue="247" name="HD12"/>
+ <atom segid=" A" residue="247" name="HD13"/>
+ <chemical_shift value="0.645" error="0.0"/>
+ <chemical_shift value="0.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CB"/>
+ <chemical_shift value="40.229" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CA"/>
+ <chemical_shift value="54.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="N"/>
+ <chemical_shift value="125.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CD1"/>
+ <chemical_shift value="25.833" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CD2"/>
+ <chemical_shift value="23.824" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="H"/>
+ <chemical_shift value="8.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="C"/>
+ <chemical_shift value="175.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CB"/>
+ <chemical_shift value="30.183" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CA"/>
+ <chemical_shift value="61.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="249" name="HG21"/>
+ <atom segid=" A" residue="249" name="HG22"/>
+ <atom segid=" A" residue="249" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="C"/>
+ <chemical_shift value="174.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CB"/>
+ <chemical_shift value="71.441" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CA"/>
+ <chemical_shift value="61.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="N"/>
+ <chemical_shift value="111.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="H"/>
+ <chemical_shift value="8.815" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="250" name="HD1"/>
+ <atom segid=" A" residue="250" name="HD2"/>
+ <atom segid=" A" residue="250" name="HE1"/>
+ <atom segid=" A" residue="250" name="HE2"/>
+ <atom segid=" A" residue="250" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="C"/>
+ <chemical_shift value="174.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CB"/>
+ <chemical_shift value="41.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CA"/>
+ <chemical_shift value="56.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="N"/>
+ <chemical_shift value="121.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="H"/>
+ <chemical_shift value="9.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="251" name="HZ1"/>
+ <atom segid=" A" residue="251" name="HZ2"/>
+ <atom segid=" A" residue="251" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CB"/>
+ <chemical_shift value="28.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="C"/>
+ <chemical_shift value="177.723" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="H"/>
+ <chemical_shift value="10.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CA"/>
+ <chemical_shift value="57.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="N"/>
+ <chemical_shift value="129.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="C"/>
+ <chemical_shift value="173.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="H"/>
+ <chemical_shift value="9.031" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="CA"/>
+ <chemical_shift value="45.086" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="N"/>
+ <chemical_shift value="103.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CB"/>
+ <chemical_shift value="29.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CA"/>
+ <chemical_shift value="52.486" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="N"/>
+ <chemical_shift value="122.357" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="H"/>
+ <chemical_shift value="8.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="C"/>
+ <chemical_shift value="178.676" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CB"/>
+ <chemical_shift value="31.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CA"/>
+ <chemical_shift value="62.977" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="C"/>
+ <chemical_shift value="173.658" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="CB"/>
+ <chemical_shift value="64.942" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="CA"/>
+ <chemical_shift value="62.323" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="N"/>
+ <chemical_shift value="117.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="H"/>
+ <chemical_shift value="8.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="256" name="HZ1"/>
+ <atom segid=" A" residue="256" name="HZ2"/>
+ <atom segid=" A" residue="256" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CB"/>
+ <chemical_shift value="33.307" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="H"/>
+ <chemical_shift value="7.639" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CA"/>
+ <chemical_shift value="53.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="N"/>
+ <chemical_shift value="123.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="C"/>
+ <chemical_shift value="177.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CB"/>
+ <chemical_shift value="31.379" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CA"/>
+ <chemical_shift value="62.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="258" name="HD1"/>
+ <atom segid=" A" residue="258" name="HD2"/>
+ <atom segid=" A" residue="258" name="HE1"/>
+ <atom segid=" A" residue="258" name="HE2"/>
+ <atom segid=" A" residue="258" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="C"/>
+ <chemical_shift value="177.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CB"/>
+ <chemical_shift value="40.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CA"/>
+ <chemical_shift value="58.534" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="N"/>
+ <chemical_shift value="118.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="H"/>
+ <chemical_shift value="9.265" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="259" name="HG21"/>
+ <atom segid=" A" residue="259" name="HG22"/>
+ <atom segid=" A" residue="259" name="HG23"/>
+ <chemical_shift value="0.98" error="0.0"/>
+ <chemical_shift value="0.925" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="259" name="HG11"/>
+ <atom segid=" A" residue="259" name="HG12"/>
+ <atom segid=" A" residue="259" name="HG13"/>
+ <chemical_shift value="0.98" error="0.0"/>
+ <chemical_shift value="0.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="C"/>
+ <chemical_shift value="176.569" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CB"/>
+ <chemical_shift value="33.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CA"/>
+ <chemical_shift value="62.078" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="N"/>
+ <chemical_shift value="121.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CG1"/>
+ <chemical_shift value="21.509" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="H"/>
+ <chemical_shift value="8.777" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CG2"/>
+ <chemical_shift value="22.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="C"/>
+ <chemical_shift value="171.463" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="H"/>
+ <chemical_shift value="8.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="CA"/>
+ <chemical_shift value="44.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="N"/>
+ <chemical_shift value="116.16" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="261" name="HG21"/>
+ <atom segid=" A" residue="261" name="HG22"/>
+ <atom segid=" A" residue="261" name="HG23"/>
+ <chemical_shift value="0.565" error="0.0"/>
+ <chemical_shift value="0.679" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="261" name="HG11"/>
+ <atom segid=" A" residue="261" name="HG12"/>
+ <atom segid=" A" residue="261" name="HG13"/>
+ <chemical_shift value="0.565" error="0.0"/>
+ <chemical_shift value="0.679" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="C"/>
+ <chemical_shift value="179.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CB"/>
+ <chemical_shift value="32.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CA"/>
+ <chemical_shift value="60.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="N"/>
+ <chemical_shift value="128.971" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CG1"/>
+ <chemical_shift value="20.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="H"/>
+ <chemical_shift value="11.175" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CG2"/>
+ <chemical_shift value="20.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="262" name="HD21"/>
+ <atom segid=" A" residue="262" name="HD22"/>
+ <atom segid=" A" residue="262" name="HD23"/>
+ <chemical_shift value="0.885" error="0.0"/>
+ <chemical_shift value="0.806" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="262" name="HD11"/>
+ <atom segid=" A" residue="262" name="HD12"/>
+ <atom segid=" A" residue="262" name="HD13"/>
+ <chemical_shift value="0.885" error="0.0"/>
+ <chemical_shift value="0.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="C"/>
+ <chemical_shift value="175.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CB"/>
+ <chemical_shift value="41.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CA"/>
+ <chemical_shift value="56.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="N"/>
+ <chemical_shift value="134.056" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CD1"/>
+ <chemical_shift value="22.681" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CD2"/>
+ <chemical_shift value="25.314" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="H"/>
+ <chemical_shift value="8.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="C"/>
+ <chemical_shift value="170.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="CB"/>
+ <chemical_shift value="66.154" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="CA"/>
+ <chemical_shift value="58.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="N"/>
+ <chemical_shift value="126.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="H"/>
+ <chemical_shift value="8.77" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="264" name="HB1"/>
+ <atom segid=" A" residue="264" name="HB2"/>
+ <atom segid=" A" residue="264" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="C"/>
+ <chemical_shift value="176.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="CB"/>
+ <chemical_shift value="20.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="CA"/>
+ <chemical_shift value="49.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="N"/>
+ <chemical_shift value="123.788" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="H"/>
+ <chemical_shift value="9.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="C"/>
+ <chemical_shift value="171.119" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="H"/>
+ <chemical_shift value="9.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="CA"/>
+ <chemical_shift value="42.908" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="N"/>
+ <chemical_shift value="110.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="266" name="HG21"/>
+ <atom segid=" A" residue="266" name="HG22"/>
+ <atom segid=" A" residue="266" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.915" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="266" name="HD11"/>
+ <atom segid=" A" residue="266" name="HD12"/>
+ <atom segid=" A" residue="266" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.915" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="C"/>
+ <chemical_shift value="175.264" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CB"/>
+ <chemical_shift value="39.519" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CA"/>
+ <chemical_shift value="59.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="N"/>
+ <chemical_shift value="123.632" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CD1"/>
+ <chemical_shift value="13.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="H"/>
+ <chemical_shift value="10.299" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="C"/>
+ <chemical_shift value="177.436" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CB"/>
+ <chemical_shift value="38.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CA"/>
+ <chemical_shift value="53.657" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="N"/>
+ <chemical_shift value="125.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="H"/>
+ <chemical_shift value="8.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="268" name="HB1"/>
+ <atom segid=" A" residue="268" name="HB2"/>
+ <atom segid=" A" residue="268" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="C"/>
+ <chemical_shift value="178.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="CB"/>
+ <chemical_shift value="17.854" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="CA"/>
+ <chemical_shift value="55.511" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="N"/>
+ <chemical_shift value="131.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="H"/>
+ <chemical_shift value="8.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="269" name="HB1"/>
+ <atom segid=" A" residue="269" name="HB2"/>
+ <atom segid=" A" residue="269" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="C"/>
+ <chemical_shift value="178.117" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="CB"/>
+ <chemical_shift value="18.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="CA"/>
+ <chemical_shift value="51.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="N"/>
+ <chemical_shift value="117.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="CB"/>
+ <chemical_shift value="64.366" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="CA"/>
+ <chemical_shift value="56.356" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="N"/>
+ <chemical_shift value="112.93" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="H"/>
+ <chemical_shift value="7.621" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="C"/>
+ <chemical_shift value="175.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CB"/>
+ <chemical_shift value="30.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CA"/>
+ <chemical_shift value="63.726" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="C"/>
+ <chemical_shift value="176.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CB"/>
+ <chemical_shift value="40.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CA"/>
+ <chemical_shift value="52.889" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="N"/>
+ <chemical_shift value="119.716" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="H"/>
+ <chemical_shift value="8.881" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="273" name="HZ1"/>
+ <atom segid=" A" residue="273" name="HZ2"/>
+ <atom segid=" A" residue="273" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CB"/>
+ <chemical_shift value="31.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="C"/>
+ <chemical_shift value="179.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="H"/>
+ <chemical_shift value="7.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CA"/>
+ <chemical_shift value="61.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="N"/>
+ <chemical_shift value="119.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="C"/>
+ <chemical_shift value="179.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CB"/>
+ <chemical_shift value="27.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CA"/>
+ <chemical_shift value="59.973" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="N"/>
+ <chemical_shift value="118.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="H"/>
+ <chemical_shift value="8.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="275" name="HD21"/>
+ <atom segid=" A" residue="275" name="HD22"/>
+ <atom segid=" A" residue="275" name="HD23"/>
+ <chemical_shift value="0.947" error="0.0"/>
+ <chemical_shift value="0.933" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="275" name="HD11"/>
+ <atom segid=" A" residue="275" name="HD12"/>
+ <atom segid=" A" residue="275" name="HD13"/>
+ <chemical_shift value="0.947" error="0.0"/>
+ <chemical_shift value="0.933" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="C"/>
+ <chemical_shift value="178.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CB"/>
+ <chemical_shift value="42.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CA"/>
+ <chemical_shift value="57.369" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="N"/>
+ <chemical_shift value="120.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CD1"/>
+ <chemical_shift value="25.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CD2"/>
+ <chemical_shift value="22.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="H"/>
+ <chemical_shift value="7.385" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="276" name="HB1"/>
+ <atom segid=" A" residue="276" name="HB2"/>
+ <atom segid=" A" residue="276" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="C"/>
+ <chemical_shift value="178.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="CB"/>
+ <chemical_shift value="17.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="CA"/>
+ <chemical_shift value="55.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="N"/>
+ <chemical_shift value="120.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="H"/>
+ <chemical_shift value="8.405" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="277" name="HZ1"/>
+ <atom segid=" A" residue="277" name="HZ2"/>
+ <atom segid=" A" residue="277" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CB"/>
+ <chemical_shift value="32.345" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="C"/>
+ <chemical_shift value="177.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="H"/>
+ <chemical_shift value="7.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CA"/>
+ <chemical_shift value="60.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="N"/>
+ <chemical_shift value="118.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="C"/>
+ <chemical_shift value="179.24" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CB"/>
+ <chemical_shift value="29.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CA"/>
+ <chemical_shift value="59.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="N"/>
+ <chemical_shift value="118.647" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="H"/>
+ <chemical_shift value="7.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="279" name="HD1"/>
+ <atom segid=" A" residue="279" name="HD2"/>
+ <atom segid=" A" residue="279" name="HE1"/>
+ <atom segid=" A" residue="279" name="HE2"/>
+ <atom segid=" A" residue="279" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="C"/>
+ <chemical_shift value="177.602" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CB"/>
+ <chemical_shift value="38.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CA"/>
+ <chemical_shift value="61.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="N"/>
+ <chemical_shift value="118.378" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="280" name="HD21"/>
+ <atom segid=" A" residue="280" name="HD22"/>
+ <atom segid=" A" residue="280" name="HD23"/>
+ <chemical_shift value="0.71" error="0.0"/>
+ <chemical_shift value="0.672" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="280" name="HD11"/>
+ <atom segid=" A" residue="280" name="HD12"/>
+ <atom segid=" A" residue="280" name="HD13"/>
+ <chemical_shift value="0.71" error="0.0"/>
+ <chemical_shift value="0.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="C"/>
+ <chemical_shift value="177.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CB"/>
+ <chemical_shift value="40.671" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CA"/>
+ <chemical_shift value="58.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="N"/>
+ <chemical_shift value="120.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CD1"/>
+ <chemical_shift value="25.779" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CD2"/>
+ <chemical_shift value="23.405" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="H"/>
+ <chemical_shift value="8.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="C"/>
+ <chemical_shift value="177.096" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CB"/>
+ <chemical_shift value="29.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CA"/>
+ <chemical_shift value="59.622" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="N"/>
+ <chemical_shift value="112.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="H"/>
+ <chemical_shift value="8.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="C"/>
+ <chemical_shift value="175.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CB"/>
+ <chemical_shift value="38.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CA"/>
+ <chemical_shift value="53.164" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="N"/>
+ <chemical_shift value="108.811" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="H"/>
+ <chemical_shift value="7.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="283" name="HD1"/>
+ <atom segid=" A" residue="283" name="HD2"/>
+ <atom segid=" A" residue="283" name="HE1"/>
+ <atom segid=" A" residue="283" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="C"/>
+ <chemical_shift value="176.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CB"/>
+ <chemical_shift value="38.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CA"/>
+ <chemical_shift value="59.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="N"/>
+ <chemical_shift value="116.373" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="H"/>
+ <chemical_shift value="7.164" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="284" name="HD21"/>
+ <atom segid=" A" residue="284" name="HD22"/>
+ <atom segid=" A" residue="284" name="HD23"/>
+ <chemical_shift value="1.039" error="0.0"/>
+ <chemical_shift value="0.843" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="284" name="HD11"/>
+ <atom segid=" A" residue="284" name="HD12"/>
+ <atom segid=" A" residue="284" name="HD13"/>
+ <chemical_shift value="1.039" error="0.0"/>
+ <chemical_shift value="0.843" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="C"/>
+ <chemical_shift value="176.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CB"/>
+ <chemical_shift value="41.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CA"/>
+ <chemical_shift value="58.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="N"/>
+ <chemical_shift value="121.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CD1"/>
+ <chemical_shift value="23.945" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CD2"/>
+ <chemical_shift value="27.398" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="H"/>
+ <chemical_shift value="8.101" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="285" name="HD21"/>
+ <atom segid=" A" residue="285" name="HD22"/>
+ <atom segid=" A" residue="285" name="HD23"/>
+ <chemical_shift value="1.119" error="0.0"/>
+ <chemical_shift value="1.052" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="285" name="HD11"/>
+ <atom segid=" A" residue="285" name="HD12"/>
+ <atom segid=" A" residue="285" name="HD13"/>
+ <chemical_shift value="1.119" error="0.0"/>
+ <chemical_shift value="1.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="C"/>
+ <chemical_shift value="174.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CB"/>
+ <chemical_shift value="38.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CA"/>
+ <chemical_shift value="54.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="N"/>
+ <chemical_shift value="119.204" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CD1"/>
+ <chemical_shift value="25.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CD2"/>
+ <chemical_shift value="24.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="H"/>
+ <chemical_shift value="7.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="286" name="HG21"/>
+ <atom segid=" A" residue="286" name="HG22"/>
+ <atom segid=" A" residue="286" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="C"/>
+ <chemical_shift value="174.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CB"/>
+ <chemical_shift value="73.569" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CA"/>
+ <chemical_shift value="59.007" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="N"/>
+ <chemical_shift value="108.713" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="H"/>
+ <chemical_shift value="8.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="C"/>
+ <chemical_shift value="177.87" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CB"/>
+ <chemical_shift value="39.534" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CA"/>
+ <chemical_shift value="58.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="N"/>
+ <chemical_shift value="122.217" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="H"/>
+ <chemical_shift value="8.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="C"/>
+ <chemical_shift value="180.161" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CB"/>
+ <chemical_shift value="29.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CA"/>
+ <chemical_shift value="59.339" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="N"/>
+ <chemical_shift value="115.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="H"/>
+ <chemical_shift value="8.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="C"/>
+ <chemical_shift value="175.256" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="H"/>
+ <chemical_shift value="8.328" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="CA"/>
+ <chemical_shift value="46.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="N"/>
+ <chemical_shift value="112.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="290" name="HD21"/>
+ <atom segid=" A" residue="290" name="HD22"/>
+ <atom segid=" A" residue="290" name="HD23"/>
+ <chemical_shift value="0.792" error="0.0"/>
+ <chemical_shift value="1.074" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="290" name="HD11"/>
+ <atom segid=" A" residue="290" name="HD12"/>
+ <atom segid=" A" residue="290" name="HD13"/>
+ <chemical_shift value="0.792" error="0.0"/>
+ <chemical_shift value="1.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="C"/>
+ <chemical_shift value="179.873" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CB"/>
+ <chemical_shift value="41.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CA"/>
+ <chemical_shift value="57.262" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="N"/>
+ <chemical_shift value="119.553" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CD1"/>
+ <chemical_shift value="27.886" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CD2"/>
+ <chemical_shift value="21.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="H"/>
+ <chemical_shift value="8.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="C"/>
+ <chemical_shift value="178.136" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CB"/>
+ <chemical_shift value="29.033" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CA"/>
+ <chemical_shift value="59.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="N"/>
+ <chemical_shift value="120.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="H"/>
+ <chemical_shift value="7.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="292" name="HB1"/>
+ <atom segid=" A" residue="292" name="HB2"/>
+ <atom segid=" A" residue="292" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="C"/>
+ <chemical_shift value="180.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="CB"/>
+ <chemical_shift value="17.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="CA"/>
+ <chemical_shift value="55.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="N"/>
+ <chemical_shift value="119.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="H"/>
+ <chemical_shift value="7.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="293" name="HG21"/>
+ <atom segid=" A" residue="293" name="HG22"/>
+ <atom segid=" A" residue="293" name="HG23"/>
+ <chemical_shift value="0.901" error="0.0"/>
+ <chemical_shift value="1.004" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="293" name="HG11"/>
+ <atom segid=" A" residue="293" name="HG12"/>
+ <atom segid=" A" residue="293" name="HG13"/>
+ <chemical_shift value="0.901" error="0.0"/>
+ <chemical_shift value="1.004" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="C"/>
+ <chemical_shift value="177.079" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CB"/>
+ <chemical_shift value="32.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CA"/>
+ <chemical_shift value="67.318" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="N"/>
+ <chemical_shift value="115.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CG1"/>
+ <chemical_shift value="21.422" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="H"/>
+ <chemical_shift value="7.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CG2"/>
+ <chemical_shift value="22.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="C"/>
+ <chemical_shift value="176.45" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CB"/>
+ <chemical_shift value="40.911" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CA"/>
+ <chemical_shift value="56.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="N"/>
+ <chemical_shift value="117.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="H"/>
+ <chemical_shift value="8.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="295" name="HZ1"/>
+ <atom segid=" A" residue="295" name="HZ2"/>
+ <atom segid=" A" residue="295" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CB"/>
+ <chemical_shift value="31.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="C"/>
+ <chemical_shift value="177.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CA"/>
+ <chemical_shift value="58.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="N"/>
+ <chemical_shift value="115.927" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="C"/>
+ <chemical_shift value="176.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CB"/>
+ <chemical_shift value="41.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CA"/>
+ <chemical_shift value="56.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="N"/>
+ <chemical_shift value="118.991" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="H"/>
+ <chemical_shift value="7.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="297" name="HZ1"/>
+ <atom segid=" A" residue="297" name="HZ2"/>
+ <atom segid=" A" residue="297" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CB"/>
+ <chemical_shift value="34.952" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="H"/>
+ <chemical_shift value="7.654" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CA"/>
+ <chemical_shift value="52.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="N"/>
+ <chemical_shift value="115.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="C"/>
+ <chemical_shift value="178.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CB"/>
+ <chemical_shift value="31.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CA"/>
+ <chemical_shift value="63.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="299" name="HD21"/>
+ <atom segid=" A" residue="299" name="HD22"/>
+ <atom segid=" A" residue="299" name="HD23"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="299" name="HD11"/>
+ <atom segid=" A" residue="299" name="HD12"/>
+ <atom segid=" A" residue="299" name="HD13"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="C"/>
+ <chemical_shift value="177.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CB"/>
+ <chemical_shift value="43.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CA"/>
+ <chemical_shift value="55.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="N"/>
+ <chemical_shift value="121.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CD1"/>
+ <chemical_shift value="26.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CD2"/>
+ <chemical_shift value="22.958" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="H"/>
+ <chemical_shift value="8.532" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="C"/>
+ <chemical_shift value="174.043" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="H"/>
+ <chemical_shift value="8.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="CA"/>
+ <chemical_shift value="44.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="N"/>
+ <chemical_shift value="103.351" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="301" name="HB1"/>
+ <atom segid=" A" residue="301" name="HB2"/>
+ <atom segid=" A" residue="301" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="C"/>
+ <chemical_shift value="177.667" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="CB"/>
+ <chemical_shift value="19.844" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="CA"/>
+ <chemical_shift value="51.558" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="N"/>
+ <chemical_shift value="123.834" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="H"/>
+ <chemical_shift value="7.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="302" name="HG21"/>
+ <atom segid=" A" residue="302" name="HG22"/>
+ <atom segid=" A" residue="302" name="HG23"/>
+ <chemical_shift value="1.262" error="0.0"/>
+ <chemical_shift value="1.059" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="302" name="HG11"/>
+ <atom segid=" A" residue="302" name="HG12"/>
+ <atom segid=" A" residue="302" name="HG13"/>
+ <chemical_shift value="1.262" error="0.0"/>
+ <chemical_shift value="1.059" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="C"/>
+ <chemical_shift value="174.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CB"/>
+ <chemical_shift value="35.614" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CA"/>
+ <chemical_shift value="59.9" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="N"/>
+ <chemical_shift value="110.163" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CG1"/>
+ <chemical_shift value="22.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="H"/>
+ <chemical_shift value="8.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CG2"/>
+ <chemical_shift value="19.07" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="303" name="HB1"/>
+ <atom segid=" A" residue="303" name="HB2"/>
+ <atom segid=" A" residue="303" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="C"/>
+ <chemical_shift value="175.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="CB"/>
+ <chemical_shift value="19.491" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="CA"/>
+ <chemical_shift value="53.039" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="N"/>
+ <chemical_shift value="117.932" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="H"/>
+ <chemical_shift value="7.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="304" name="HD22"/>
+ <atom segid=" A" residue="304" name="HD23"/>
+ <chemical_shift value="0.702" error="0.0"/>
+ <chemical_shift value="0.848" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="304" name="HD11"/>
+ <atom segid=" A" residue="304" name="HD12"/>
+ <atom segid=" A" residue="304" name="HD13"/>
+ <chemical_shift value="0.702" error="0.0"/>
+ <chemical_shift value="0.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="C"/>
+ <chemical_shift value="175.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CB"/>
+ <chemical_shift value="44.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CA"/>
+ <chemical_shift value="54.335" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="N"/>
+ <chemical_shift value="114.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CD1"/>
+ <chemical_shift value="24.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CD2"/>
+ <chemical_shift value="26.586" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="H"/>
+ <chemical_shift value="6.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="305" name="HZ1"/>
+ <atom segid=" A" residue="305" name="HZ2"/>
+ <atom segid=" A" residue="305" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CB"/>
+ <chemical_shift value="31.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="C"/>
+ <chemical_shift value="178.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="H"/>
+ <chemical_shift value="8.043" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CA"/>
+ <chemical_shift value="60.428" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="N"/>
+ <chemical_shift value="129.631" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="C"/>
+ <chemical_shift value="176.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="CB"/>
+ <chemical_shift value="60.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="CA"/>
+ <chemical_shift value="61.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="N"/>
+ <chemical_shift value="111.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="H"/>
+ <chemical_shift value="8.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="307" name="HD1"/>
+ <atom segid=" A" residue="307" name="HD2"/>
+ <atom segid=" A" residue="307" name="HE1"/>
+ <atom segid=" A" residue="307" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="C"/>
+ <chemical_shift value="177.811" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CB"/>
+ <chemical_shift value="38.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CA"/>
+ <chemical_shift value="58.904" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="N"/>
+ <chemical_shift value="122.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="H"/>
+ <chemical_shift value="6.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="C"/>
+ <chemical_shift value="177.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CB"/>
+ <chemical_shift value="26.173" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CA"/>
+ <chemical_shift value="58.466" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="N"/>
+ <chemical_shift value="122.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="H"/>
+ <chemical_shift value="8.473" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="C"/>
+ <chemical_shift value="178.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CB"/>
+ <chemical_shift value="28.862" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CA"/>
+ <chemical_shift value="58.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="N"/>
+ <chemical_shift value="114.962" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="H"/>
+ <chemical_shift value="7.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="C"/>
+ <chemical_shift value="178.868" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CB"/>
+ <chemical_shift value="29.333" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CA"/>
+ <chemical_shift value="57.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="N"/>
+ <chemical_shift value="116.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="H"/>
+ <chemical_shift value="7.092" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="311" name="HD21"/>
+ <atom segid=" A" residue="311" name="HD22"/>
+ <atom segid=" A" residue="311" name="HD23"/>
+ <chemical_shift value="0.797" error="0.0"/>
+ <chemical_shift value="0.87" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="311" name="HD11"/>
+ <atom segid=" A" residue="311" name="HD12"/>
+ <atom segid=" A" residue="311" name="HD13"/>
+ <chemical_shift value="0.797" error="0.0"/>
+ <chemical_shift value="0.87" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="C"/>
+ <chemical_shift value="179.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CB"/>
+ <chemical_shift value="41.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CA"/>
+ <chemical_shift value="57.324" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="N"/>
+ <chemical_shift value="120.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CD1"/>
+ <chemical_shift value="26.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CD2"/>
+ <chemical_shift value="22.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="H"/>
+ <chemical_shift value="8.021" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="312" name="HB1"/>
+ <atom segid=" A" residue="312" name="HB2"/>
+ <atom segid=" A" residue="312" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="C"/>
+ <chemical_shift value="174.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="CB"/>
+ <chemical_shift value="17.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="CA"/>
+ <chemical_shift value="54.037" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="N"/>
+ <chemical_shift value="114.676" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="H"/>
+ <chemical_shift value="8.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="313" name="HZ1"/>
+ <atom segid=" A" residue="313" name="HZ2"/>
+ <atom segid=" A" residue="313" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CB"/>
+ <chemical_shift value="31.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="C"/>
+ <chemical_shift value="177.97" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="H"/>
+ <chemical_shift value="6.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CA"/>
+ <chemical_shift value="58.418" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="N"/>
+ <chemical_shift value="119.315" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CB"/>
+ <chemical_shift value="41.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CA"/>
+ <chemical_shift value="50.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="N"/>
+ <chemical_shift value="121.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="H"/>
+ <chemical_shift value="8.311" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="C"/>
+ <chemical_shift value="179.227" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CB"/>
+ <chemical_shift value="32.168" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CA"/>
+ <chemical_shift value="64.525" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CB"/>
+ <chemical_shift value="29.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="C"/>
+ <chemical_shift value="179.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="H"/>
+ <chemical_shift value="8.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CA"/>
+ <chemical_shift value="58.813" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="N"/>
+ <chemical_shift value="116.913" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="317" name="HG21"/>
+ <atom segid=" A" residue="317" name="HG22"/>
+ <atom segid=" A" residue="317" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="1.118" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="317" name="HD11"/>
+ <atom segid=" A" residue="317" name="HD12"/>
+ <atom segid=" A" residue="317" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="1.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="C"/>
+ <chemical_shift value="178.067" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CB"/>
+ <chemical_shift value="35.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CA"/>
+ <chemical_shift value="64.418" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="N"/>
+ <chemical_shift value="123.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CD1"/>
+ <chemical_shift value="12.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="H"/>
+ <chemical_shift value="7.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="318" name="HB1"/>
+ <atom segid=" A" residue="318" name="HB2"/>
+ <atom segid=" A" residue="318" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="C"/>
+ <chemical_shift value="181.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="CB"/>
+ <chemical_shift value="17.268" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="CA"/>
+ <chemical_shift value="56.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="N"/>
+ <chemical_shift value="123.335" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="H"/>
+ <chemical_shift value="7.906" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="319" name="HB1"/>
+ <atom segid=" A" residue="319" name="HB2"/>
+ <atom segid=" A" residue="319" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="C"/>
+ <chemical_shift value="178.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="CB"/>
+ <chemical_shift value="17.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="CA"/>
+ <chemical_shift value="55.519" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="N"/>
+ <chemical_shift value="118.979" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="H"/>
+ <chemical_shift value="8.086" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="320" name="HG21"/>
+ <atom segid=" A" residue="320" name="HG22"/>
+ <atom segid=" A" residue="320" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="C"/>
+ <chemical_shift value="175.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="CB"/>
+ <chemical_shift value="69.151" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="CA"/>
+ <chemical_shift value="67.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="N"/>
+ <chemical_shift value="114.58" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="H"/>
+ <chemical_shift value="7.358" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="321" name="HE2"/>
+ <atom segid=" A" residue="321" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="C"/>
+ <chemical_shift value="177.825" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CB"/>
+ <chemical_shift value="30.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CA"/>
+ <chemical_shift value="56.766" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="N"/>
+ <chemical_shift value="118.804" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="H"/>
+ <chemical_shift value="8.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="C"/>
+ <chemical_shift value="179.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CB"/>
+ <chemical_shift value="28.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CA"/>
+ <chemical_shift value="59.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="N"/>
+ <chemical_shift value="122.177" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="H"/>
+ <chemical_shift value="8.267" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="39.313" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="CA"/>
+ <chemical_shift value="57.124" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="N"/>
+ <chemical_shift value="115.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="H"/>
+ <chemical_shift value="8.207" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="324" name="HB2"/>
+ <atom segid=" A" residue="324" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="180.381" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="CB"/>
+ <chemical_shift value="17.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="CA"/>
+ <chemical_shift value="54.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="N"/>
+ <chemical_shift value="119.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="H"/>
+ <chemical_shift value="8.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="C"/>
+ <chemical_shift value="177.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CB"/>
+ <chemical_shift value="27.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CA"/>
+ <chemical_shift value="58.414" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="N"/>
+ <chemical_shift value="116.35" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="H"/>
+ <chemical_shift value="8.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="326" name="HZ1"/>
+ <atom segid=" A" residue="326" name="HZ2"/>
+ <atom segid=" A" residue="326" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CB"/>
+ <chemical_shift value="32.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="C"/>
+ <chemical_shift value="176.163" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="H"/>
+ <chemical_shift value="7.079" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CA"/>
+ <chemical_shift value="56.011" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="N"/>
+ <chemical_shift value="117.692" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="C"/>
+ <chemical_shift value="172.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="H"/>
+ <chemical_shift value="7.293" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="CA"/>
+ <chemical_shift value="44.518" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="N"/>
+ <chemical_shift value="106.636" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="C"/>
+ <chemical_shift value="176.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CB"/>
+ <chemical_shift value="32.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CA"/>
+ <chemical_shift value="54.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="N"/>
+ <chemical_shift value="121.098" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="H"/>
+ <chemical_shift value="8.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="329" name="HG21"/>
+ <atom segid=" A" residue="329" name="HG22"/>
+ <atom segid=" A" residue="329" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.821" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="329" name="HD11"/>
+ <atom segid=" A" residue="329" name="HD12"/>
+ <atom segid=" A" residue="329" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="C"/>
+ <chemical_shift value="178.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CB"/>
+ <chemical_shift value="37.812" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CA"/>
+ <chemical_shift value="62.15" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="N"/>
+ <chemical_shift value="127.522" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CD1"/>
+ <chemical_shift value="12.362" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="H"/>
+ <chemical_shift value="9.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="330" name="HE1"/>
+ <atom segid=" A" residue="330" name="HE2"/>
+ <atom segid=" A" residue="330" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CB"/>
+ <chemical_shift value="34.295" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CA"/>
+ <chemical_shift value="56.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="N"/>
+ <chemical_shift value="124.379" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="H"/>
+ <chemical_shift value="8.502" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="C"/>
+ <chemical_shift value="175.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CB"/>
+ <chemical_shift value="31.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CA"/>
+ <chemical_shift value="63.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="C"/>
+ <chemical_shift value="175.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CB"/>
+ <chemical_shift value="38.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CA"/>
+ <chemical_shift value="51.443" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="N"/>
+ <chemical_shift value="117.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="H"/>
+ <chemical_shift value="7.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="333" name="HG21"/>
+ <atom segid=" A" residue="333" name="HG22"/>
+ <atom segid=" A" residue="333" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="-0.138" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="333" name="HD11"/>
+ <atom segid=" A" residue="333" name="HD12"/>
+ <atom segid=" A" residue="333" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="-0.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CB"/>
+ <chemical_shift value="36.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CA"/>
+ <chemical_shift value="59.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="N"/>
+ <chemical_shift value="108.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CD1"/>
+ <chemical_shift value="12.253" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="H"/>
+ <chemical_shift value="6.382" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="C"/>
+ <chemical_shift value="178.686" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CB"/>
+ <chemical_shift value="31.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CA"/>
+ <chemical_shift value="65.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="C"/>
+ <chemical_shift value="177.018" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CB"/>
+ <chemical_shift value="26.389" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CA"/>
+ <chemical_shift value="59.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="N"/>
+ <chemical_shift value="116.31" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="336" name="HE1"/>
+ <atom segid=" A" residue="336" name="HE2"/>
+ <atom segid=" A" residue="336" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="C"/>
+ <chemical_shift value="177.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CB"/>
+ <chemical_shift value="30.289" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CA"/>
+ <chemical_shift value="56.084" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="N"/>
+ <chemical_shift value="118.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="H"/>
+ <chemical_shift value="7.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="C"/>
+ <chemical_shift value="177.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="CB"/>
+ <chemical_shift value="60.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="CA"/>
+ <chemical_shift value="62.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="N"/>
+ <chemical_shift value="113.543" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="H"/>
+ <chemical_shift value="7.924" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="338" name="HB1"/>
+ <atom segid=" A" residue="338" name="HB2"/>
+ <atom segid=" A" residue="338" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="C"/>
+ <chemical_shift value="180.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="CB"/>
+ <chemical_shift value="18.545" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="CA"/>
+ <chemical_shift value="54.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="N"/>
+ <chemical_shift value="122.856" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="H"/>
+ <chemical_shift value="7.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="339" name="HD1"/>
+ <atom segid=" A" residue="339" name="HD2"/>
+ <atom segid=" A" residue="339" name="HE1"/>
+ <atom segid=" A" residue="339" name="HE2"/>
+ <atom segid=" A" residue="339" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="C"/>
+ <chemical_shift value="176.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CB"/>
+ <chemical_shift value="38.827" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CA"/>
+ <chemical_shift value="61.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="N"/>
+ <chemical_shift value="118.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="H"/>
+ <chemical_shift value="7.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="H"/>
+ <chemical_shift value="8.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="C"/>
+ <chemical_shift value="179.128" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CB"/>
+ <chemical_shift value="30.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CA"/>
+ <chemical_shift value="59.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="N"/>
+ <chemical_shift value="118.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="341" name="HD1"/>
+ <atom segid=" A" residue="341" name="HD2"/>
+ <atom segid=" A" residue="341" name="HE1"/>
+ <atom segid=" A" residue="341" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="C"/>
+ <chemical_shift value="178.712" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CB"/>
+ <chemical_shift value="38.306" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CA"/>
+ <chemical_shift value="61.558" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="N"/>
+ <chemical_shift value="114.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="H"/>
+ <chemical_shift value="7.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="342" name="HB1"/>
+ <atom segid=" A" residue="342" name="HB2"/>
+ <atom segid=" A" residue="342" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="C"/>
+ <chemical_shift value="180.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="CB"/>
+ <chemical_shift value="19.012" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="CA"/>
+ <chemical_shift value="55.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="N"/>
+ <chemical_shift value="121.914" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="H"/>
+ <chemical_shift value="8.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="343" name="HG21"/>
+ <atom segid=" A" residue="343" name="HG22"/>
+ <atom segid=" A" residue="343" name="HG23"/>
+ <chemical_shift value="0.168" error="0.0"/>
+ <chemical_shift value="0.863" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="343" name="HG11"/>
+ <atom segid=" A" residue="343" name="HG12"/>
+ <atom segid=" A" residue="343" name="HG13"/>
+ <chemical_shift value="0.168" error="0.0"/>
+ <chemical_shift value="0.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="C"/>
+ <chemical_shift value="177.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CB"/>
+ <chemical_shift value="31.022" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CA"/>
+ <chemical_shift value="66.924" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="N"/>
+ <chemical_shift value="118.57" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CG1"/>
+ <chemical_shift value="21.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="H"/>
+ <chemical_shift value="8.63" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CG2"/>
+ <chemical_shift value="23.236" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CB"/>
+ <chemical_shift value="29.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="C"/>
+ <chemical_shift value="178.506" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="H"/>
+ <chemical_shift value="8.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CA"/>
+ <chemical_shift value="60.236" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="N"/>
+ <chemical_shift value="120.769" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="345" name="HG21"/>
+ <atom segid=" A" residue="345" name="HG22"/>
+ <atom segid=" A" residue="345" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="C"/>
+ <chemical_shift value="175.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CB"/>
+ <chemical_shift value="69.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CA"/>
+ <chemical_shift value="66.564" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="N"/>
+ <chemical_shift value="113.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="H"/>
+ <chemical_shift value="7.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="346" name="HB1"/>
+ <atom segid=" A" residue="346" name="HB2"/>
+ <atom segid=" A" residue="346" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="C"/>
+ <chemical_shift value="179.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="CB"/>
+ <chemical_shift value="18.537" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="CA"/>
+ <chemical_shift value="55.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="N"/>
+ <chemical_shift value="122.933" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="H"/>
+ <chemical_shift value="7.805" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="347" name="HG21"/>
+ <atom segid=" A" residue="347" name="HG22"/>
+ <atom segid=" A" residue="347" name="HG23"/>
+ <chemical_shift value="1.043" error="0.0"/>
+ <chemical_shift value="0.918" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="347" name="HG11"/>
+ <atom segid=" A" residue="347" name="HG12"/>
+ <atom segid=" A" residue="347" name="HG13"/>
+ <chemical_shift value="1.043" error="0.0"/>
+ <chemical_shift value="0.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="C"/>
+ <chemical_shift value="178.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CB"/>
+ <chemical_shift value="31.336" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CA"/>
+ <chemical_shift value="67.494" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="N"/>
+ <chemical_shift value="115.988" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CG1"/>
+ <chemical_shift value="20.468" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CG2"/>
+ <chemical_shift value="22.282" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="348" name="HG21"/>
+ <atom segid=" A" residue="348" name="HG22"/>
+ <atom segid=" A" residue="348" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.869" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="348" name="HD11"/>
+ <atom segid=" A" residue="348" name="HD12"/>
+ <atom segid=" A" residue="348" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.869" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="C"/>
+ <chemical_shift value="180.338" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CB"/>
+ <chemical_shift value="37.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CA"/>
+ <chemical_shift value="65.054" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="N"/>
+ <chemical_shift value="118.38" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CD1"/>
+ <chemical_shift value="12.965" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="H"/>
+ <chemical_shift value="7.771" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="C"/>
+ <chemical_shift value="178.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CB"/>
+ <chemical_shift value="37.166" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CA"/>
+ <chemical_shift value="55.948" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="N"/>
+ <chemical_shift value="121.103" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="H"/>
+ <chemical_shift value="8.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="350" name="HB1"/>
+ <atom segid=" A" residue="350" name="HB2"/>
+ <atom segid=" A" residue="350" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="C"/>
+ <chemical_shift value="181.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="CB"/>
+ <chemical_shift value="17.998" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="CA"/>
+ <chemical_shift value="54.159" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="N"/>
+ <chemical_shift value="122.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="H"/>
+ <chemical_shift value="8.52" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="351" name="HB2"/>
+ <atom segid=" A" residue="351" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="C"/>
+ <chemical_shift value="178.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="CB"/>
+ <chemical_shift value="18.028" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="CA"/>
+ <chemical_shift value="55.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="N"/>
+ <chemical_shift value="121.112" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="H"/>
+ <chemical_shift value="9.165" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="C"/>
+ <chemical_shift value="175.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="CB"/>
+ <chemical_shift value="64.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="CA"/>
+ <chemical_shift value="58.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="N"/>
+ <chemical_shift value="107.997" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="H"/>
+ <chemical_shift value="7.88" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="C"/>
+ <chemical_shift value="174.546" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="H"/>
+ <chemical_shift value="7.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="CA"/>
+ <chemical_shift value="45.785" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="N"/>
+ <chemical_shift value="109.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CB"/>
+ <chemical_shift value="30.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="C"/>
+ <chemical_shift value="176.819" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="H"/>
+ <chemical_shift value="8.225" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CA"/>
+ <chemical_shift value="58.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="N"/>
+ <chemical_shift value="121.096" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="C"/>
+ <chemical_shift value="176.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CB"/>
+ <chemical_shift value="36.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CA"/>
+ <chemical_shift value="54.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="N"/>
+ <chemical_shift value="113.634" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="H"/>
+ <chemical_shift value="7.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="356" name="HG21"/>
+ <atom segid=" A" residue="356" name="HG22"/>
+ <atom segid=" A" residue="356" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="C"/>
+ <chemical_shift value="174.887" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CB"/>
+ <chemical_shift value="70.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CA"/>
+ <chemical_shift value="61.464" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="N"/>
+ <chemical_shift value="111.798" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="H"/>
+ <chemical_shift value="8.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="357" name="HG21"/>
+ <atom segid=" A" residue="357" name="HG22"/>
+ <atom segid=" A" residue="357" name="HG23"/>
+ <chemical_shift value="1.045" error="0.0"/>
+ <chemical_shift value="0.991" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="357" name="HG11"/>
+ <atom segid=" A" residue="357" name="HG12"/>
+ <atom segid=" A" residue="357" name="HG13"/>
+ <chemical_shift value="1.045" error="0.0"/>
+ <chemical_shift value="0.991" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="C"/>
+ <chemical_shift value="177.155" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CB"/>
+ <chemical_shift value="31.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CA"/>
+ <chemical_shift value="67.861" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="N"/>
+ <chemical_shift value="121.363" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CG1"/>
+ <chemical_shift value="21.315" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="H"/>
+ <chemical_shift value="8.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CG2"/>
+ <chemical_shift value="23.401" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="C"/>
+ <chemical_shift value="178.907" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CB"/>
+ <chemical_shift value="40.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CA"/>
+ <chemical_shift value="57.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="N"/>
+ <chemical_shift value="115.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="H"/>
+ <chemical_shift value="8.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="C"/>
+ <chemical_shift value="178.618" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CB"/>
+ <chemical_shift value="29.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CA"/>
+ <chemical_shift value="58.759" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="N"/>
+ <chemical_shift value="118.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="H"/>
+ <chemical_shift value="7.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="360" name="HB1"/>
+ <atom segid=" A" residue="360" name="HB2"/>
+ <atom segid=" A" residue="360" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="C"/>
+ <chemical_shift value="181.584" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="CB"/>
+ <chemical_shift value="18.27" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="CA"/>
+ <chemical_shift value="54.768" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="N"/>
+ <chemical_shift value="121.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="H"/>
+ <chemical_shift value="8.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="361" name="HD21"/>
+ <atom segid=" A" residue="361" name="HD22"/>
+ <atom segid=" A" residue="361" name="HD23"/>
+ <chemical_shift value="0.722" error="0.0"/>
+ <chemical_shift value="0.892" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="361" name="HD11"/>
+ <atom segid=" A" residue="361" name="HD12"/>
+ <atom segid=" A" residue="361" name="HD13"/>
+ <chemical_shift value="0.722" error="0.0"/>
+ <chemical_shift value="0.892" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="C"/>
+ <chemical_shift value="178.899" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CB"/>
+ <chemical_shift value="39.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CA"/>
+ <chemical_shift value="57.465" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="N"/>
+ <chemical_shift value="116.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CD1"/>
+ <chemical_shift value="25.264" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CD2"/>
+ <chemical_shift value="19.605" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="H"/>
+ <chemical_shift value="8.078" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="362" name="HZ1"/>
+ <atom segid=" A" residue="362" name="HZ2"/>
+ <atom segid=" A" residue="362" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CB"/>
+ <chemical_shift value="31.531" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="C"/>
+ <chemical_shift value="179.903" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="H"/>
+ <chemical_shift value="7.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CA"/>
+ <chemical_shift value="59.792" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="N"/>
+ <chemical_shift value="121.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="C"/>
+ <chemical_shift value="178.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CB"/>
+ <chemical_shift value="40.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CA"/>
+ <chemical_shift value="57.231" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="N"/>
+ <chemical_shift value="120.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="H"/>
+ <chemical_shift value="8.145" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="364" name="HB1"/>
+ <atom segid=" A" residue="364" name="HB2"/>
+ <atom segid=" A" residue="364" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="C"/>
+ <chemical_shift value="178.422" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="CB"/>
+ <chemical_shift value="17.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="CA"/>
+ <chemical_shift value="55.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="N"/>
+ <chemical_shift value="121.446" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="H"/>
+ <chemical_shift value="7.735" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="C"/>
+ <chemical_shift value="179.207" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CB"/>
+ <chemical_shift value="27.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CA"/>
+ <chemical_shift value="60.224" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="N"/>
+ <chemical_shift value="118.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="H"/>
+ <chemical_shift value="8.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="366" name="HG21"/>
+ <atom segid=" A" residue="366" name="HG22"/>
+ <atom segid=" A" residue="366" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="C"/>
+ <chemical_shift value="175.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CB"/>
+ <chemical_shift value="69.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CA"/>
+ <chemical_shift value="66.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="N"/>
+ <chemical_shift value="115.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="H"/>
+ <chemical_shift value="8.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CB"/>
+ <chemical_shift value="29.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="C"/>
+ <chemical_shift value="178.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="H"/>
+ <chemical_shift value="7.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CA"/>
+ <chemical_shift value="58.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="N"/>
+ <chemical_shift value="120.123" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="368" name="HG21"/>
+ <atom segid=" A" residue="368" name="HG22"/>
+ <atom segid=" A" residue="368" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.693" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="368" name="HD11"/>
+ <atom segid=" A" residue="368" name="HD12"/>
+ <atom segid=" A" residue="368" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.693" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="C"/>
+ <chemical_shift value="177.188" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CB"/>
+ <chemical_shift value="38.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CA"/>
+ <chemical_shift value="65.05" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="N"/>
+ <chemical_shift value="117.397" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CD1"/>
+ <chemical_shift value="15.285" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="H"/>
+ <chemical_shift value="8.005" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="369" name="HG21"/>
+ <atom segid=" A" residue="369" name="HG22"/>
+ <atom segid=" A" residue="369" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="C"/>
+ <chemical_shift value="174.309" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CB"/>
+ <chemical_shift value="70.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CA"/>
+ <chemical_shift value="62.641" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="N"/>
+ <chemical_shift value="107.043" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="H"/>
+ <chemical_shift value="7.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="370" name="HZ1"/>
+ <atom segid=" A" residue="370" name="HZ2"/>
+ <atom segid=" A" residue="370" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="O'"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="O''"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CB"/>
+ <chemical_shift value="32.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="H"/>
+ <chemical_shift value="7.399" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CA"/>
+ <chemical_shift value="59.013" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="N"/>
+ <chemical_shift value="128.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+</chemical_shift_list>
\ No newline at end of file
diff --git a/docs/examples/malecoli/data/xml/c_redo_peaks.xml b/docs/examples/malecoli/data/xml/c_redo_peaks.xml
new file mode 100644
index 0000000000000000000000000000000000000000..a4f911f5d8b39b96dbbd24a0747d5a2404837c17
--- /dev/null
+++ b/docs/examples/malecoli/data/xml/c_redo_peaks.xml
@@ -0,0 +1,16467 @@
+<!DOCTYPE spectrum SYSTEM "noesy_spectrum1.0.dtd">
+<spectrum name="c_redo">
+ <peak number="1" reliable="no" ambiguity="">
+ <volume value="15700000.0" error="0"/>
+ <intensity value="15700000.0" error="0"/>
+ <proton1>
+ <shift value="0.559" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.562" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="12.279" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2" reliable="no" ambiguity="">
+ <volume value="10600000.0" error="0"/>
+ <intensity value="10600000.0" error="0"/>
+ <proton1>
+ <shift value="0.392" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.394" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="12.992" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="3" reliable="no" ambiguity="">
+ <volume value="34800000.0" error="0"/>
+ <intensity value="34800000.0" error="0"/>
+ <proton1>
+ <shift value="0.95" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.95" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="22.463" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="4" reliable="no" ambiguity="">
+ <volume value="44900000.0" error="0"/>
+ <intensity value="44900000.0" error="0"/>
+ <proton1>
+ <shift value="0.932" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.935" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="25.257" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="5" reliable="no" ambiguity="">
+ <volume value="26900000.0" error="0"/>
+ <intensity value="26900000.0" error="0"/>
+ <proton1>
+ <shift value="0.94" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.935" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="26.796" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="6" reliable="no" ambiguity="">
+ <volume value="7290000.0" error="0"/>
+ <intensity value="7290000.0" error="0"/>
+ <proton1>
+ <shift value="0.636" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.64" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="9.884" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="7" reliable="no" ambiguity="">
+ <volume value="5840000.0" error="0"/>
+ <intensity value="5840000.0" error="0"/>
+ <proton1>
+ <shift value="0.263" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.265" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="25.143" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="8" reliable="no" ambiguity="">
+ <volume value="6490000.0" error="0"/>
+ <intensity value="6490000.0" error="0"/>
+ <proton1>
+ <shift value="0.345" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.343" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="14.42" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="9" reliable="no" ambiguity="">
+ <volume value="4510000.0" error="0"/>
+ <intensity value="4510000.0" error="0"/>
+ <proton1>
+ <shift value="0.102" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.103" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="13.014" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="10" reliable="no" ambiguity="">
+ <volume value="20400000.0" error="0"/>
+ <intensity value="20400000.0" error="0"/>
+ <proton1>
+ <shift value="0.844" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.86" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="25.119" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="11" reliable="no" ambiguity="">
+ <volume value="18800000.0" error="0"/>
+ <intensity value="18800000.0" error="0"/>
+ <proton1>
+ <shift value="0.572" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.576" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="10.009" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="12" reliable="no" ambiguity="">
+ <volume value="14900000.0" error="0"/>
+ <intensity value="14900000.0" error="0"/>
+ <proton1>
+ <shift value="1.104" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="1.113" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="26.548" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="13" reliable="no" ambiguity="">
+ <volume value="15600000.0" error="0"/>
+ <intensity value="15600000.0" error="0"/>
+ <proton1>
+ <shift value="0.738" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.742" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="13.999" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="14" reliable="no" ambiguity="">
+ <volume value="13300000.0" error="0"/>
+ <intensity value="13300000.0" error="0"/>
+ <proton1>
+ <shift value="0.46" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.462" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="14.476" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="15" reliable="no" ambiguity="">
+ <volume value="367000.0" error="0"/>
+ <intensity value="367000.0" error="0"/>
+ <proton1>
+ <shift value="8.671" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.652" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="25.521" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="16" reliable="no" ambiguity="">
+ <volume value="25200000.0" error="0"/>
+ <intensity value="25200000.0" error="0"/>
+ <proton1>
+ <shift value="0.657" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.663" error=""/>
+ </proton2>
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+ </peak>
+ <peak number="1027" reliable="no" ambiguity="">
+ <volume value="777000.0" error="0"/>
+ <intensity value="777000.0" error="0"/>
+ <proton1>
+ <shift value="0.635" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.802" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="10.0" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1028" reliable="no" ambiguity="">
+ <volume value="1430000.0" error="0"/>
+ <intensity value="1430000.0" error="0"/>
+ <proton1>
+ <shift value="0.633" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="1.12" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="10.0" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1029" reliable="no" ambiguity="">
+ <volume value="1580000.0" error="0"/>
+ <intensity value="1580000.0" error="0"/>
+ <proton1>
+ <shift value="0.736" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.892" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="13.973" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+</spectrum>
\ No newline at end of file
diff --git a/docs/examples/malecoli/data/xml/cc20_cs.xml b/docs/examples/malecoli/data/xml/cc20_cs.xml
new file mode 100644
index 0000000000000000000000000000000000000000..bcb3d46b809ec3f250726022e42af6cd1ed9b115
--- /dev/null
+++ b/docs/examples/malecoli/data/xml/cc20_cs.xml
@@ -0,0 +1,31373 @@
+<!DOCTYPE chemical_shift_list SYSTEM "chemical_shift_list1.0.dtd">
+<chemical_shift_list>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="1" name="HZ1"/>
+ <atom segid=" A" residue="1" name="HZ2"/>
+ <atom segid=" A" residue="1" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="1" name="H1"/>
+ <atom segid=" A" residue="1" name="H2"/>
+ <atom segid=" A" residue="1" name="H3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="C"/>
+ <chemical_shift value="176.453" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CB"/>
+ <chemical_shift value="32.88" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CA"/>
+ <chemical_shift value="56.408" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="2" name="HG21"/>
+ <atom segid=" A" residue="2" name="HG22"/>
+ <atom segid=" A" residue="2" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.402" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="2" name="HD11"/>
+ <atom segid=" A" residue="2" name="HD12"/>
+ <atom segid=" A" residue="2" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.402" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="C"/>
+ <chemical_shift value="176.016" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CB"/>
+ <chemical_shift value="38.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CA"/>
+ <chemical_shift value="62.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="N"/>
+ <chemical_shift value="123.415" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CD1"/>
+ <chemical_shift value="13.054" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="H"/>
+ <chemical_shift value="7.988" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="C"/>
+ <chemical_shift value="176.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CB"/>
+ <chemical_shift value="31.187" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CA"/>
+ <chemical_shift value="56.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="N"/>
+ <chemical_shift value="126.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="H"/>
+ <chemical_shift value="8.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="C"/>
+ <chemical_shift value="177.433" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CB"/>
+ <chemical_shift value="30.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CA"/>
+ <chemical_shift value="56.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="N"/>
+ <chemical_shift value="124.204" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="H"/>
+ <chemical_shift value="8.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="C"/>
+ <chemical_shift value="172.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="H"/>
+ <chemical_shift value="8.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="CA"/>
+ <chemical_shift value="45.937" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="N"/>
+ <chemical_shift value="111.348" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="6" name="HZ1"/>
+ <atom segid=" A" residue="6" name="HZ2"/>
+ <atom segid=" A" residue="6" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CB"/>
+ <chemical_shift value="35.109" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="C"/>
+ <chemical_shift value="173.108" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="H"/>
+ <chemical_shift value="7.582" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CA"/>
+ <chemical_shift value="54.965" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="N"/>
+ <chemical_shift value="118.91" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="7" name="HD21"/>
+ <atom segid=" A" residue="7" name="HD22"/>
+ <atom segid=" A" residue="7" name="HD23"/>
+ <chemical_shift value="0.615" error="0.0"/>
+ <chemical_shift value="0.267" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="7" name="HD11"/>
+ <atom segid=" A" residue="7" name="HD12"/>
+ <atom segid=" A" residue="7" name="HD13"/>
+ <chemical_shift value="0.615" error="0.0"/>
+ <chemical_shift value="0.267" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="C"/>
+ <chemical_shift value="175.788" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CB"/>
+ <chemical_shift value="46.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CA"/>
+ <chemical_shift value="53.365" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="N"/>
+ <chemical_shift value="116.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CD1"/>
+ <chemical_shift value="25.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CD2"/>
+ <chemical_shift value="24.064" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="H"/>
+ <chemical_shift value="8.231" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="8" name="HG21"/>
+ <atom segid=" A" residue="8" name="HG22"/>
+ <atom segid=" A" residue="8" name="HG23"/>
+ <chemical_shift value="0.923" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="8" name="HG11"/>
+ <atom segid=" A" residue="8" name="HG12"/>
+ <atom segid=" A" residue="8" name="HG13"/>
+ <chemical_shift value="0.923" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="C"/>
+ <chemical_shift value="176.033" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CB"/>
+ <chemical_shift value="33.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CA"/>
+ <chemical_shift value="61.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="N"/>
+ <chemical_shift value="125.474" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CG1"/>
+ <chemical_shift value="20.962" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="H"/>
+ <chemical_shift value="10.155" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CG2"/>
+ <chemical_shift value="21.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="9" name="HG21"/>
+ <atom segid=" A" residue="9" name="HG22"/>
+ <atom segid=" A" residue="9" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.346" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="9" name="HD11"/>
+ <atom segid=" A" residue="9" name="HD12"/>
+ <atom segid=" A" residue="9" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.346" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="C"/>
+ <chemical_shift value="174.901" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CB"/>
+ <chemical_shift value="40.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CA"/>
+ <chemical_shift value="59.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="N"/>
+ <chemical_shift value="128.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CD1"/>
+ <chemical_shift value="14.523" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="H"/>
+ <chemical_shift value="9.114" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="H"/>
+ <chemical_shift value="9.032" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="C"/>
+ <chemical_shift value="174.116" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CB"/>
+ <chemical_shift value="32.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CA"/>
+ <chemical_shift value="54.451" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="N"/>
+ <chemical_shift value="126.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="11" name="HG21"/>
+ <atom segid=" A" residue="11" name="HG22"/>
+ <atom segid=" A" residue="11" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.107" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="11" name="HD11"/>
+ <atom segid=" A" residue="11" name="HD12"/>
+ <atom segid=" A" residue="11" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.107" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="C"/>
+ <chemical_shift value="171.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CB"/>
+ <chemical_shift value="41.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CA"/>
+ <chemical_shift value="59.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="N"/>
+ <chemical_shift value="122.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CD1"/>
+ <chemical_shift value="13.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="H"/>
+ <chemical_shift value="8.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="C"/>
+ <chemical_shift value="177.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CB"/>
+ <chemical_shift value="39.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CA"/>
+ <chemical_shift value="54.628" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="N"/>
+ <chemical_shift value="122.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="H"/>
+ <chemical_shift value="8.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="C"/>
+ <chemical_shift value="173.365" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="H"/>
+ <chemical_shift value="8.288" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="CA"/>
+ <chemical_shift value="46.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="N"/>
+ <chemical_shift value="106.789" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="C"/>
+ <chemical_shift value="176.544" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CB"/>
+ <chemical_shift value="39.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CA"/>
+ <chemical_shift value="53.217" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="N"/>
+ <chemical_shift value="117.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="H"/>
+ <chemical_shift value="7.99" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="15" name="HZ1"/>
+ <atom segid=" A" residue="15" name="HZ2"/>
+ <atom segid=" A" residue="15" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CB"/>
+ <chemical_shift value="32.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="C"/>
+ <chemical_shift value="177.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="H"/>
+ <chemical_shift value="7.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CA"/>
+ <chemical_shift value="53.23" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="N"/>
+ <chemical_shift value="118.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="C"/>
+ <chemical_shift value="175.872" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="H"/>
+ <chemical_shift value="8.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="CA"/>
+ <chemical_shift value="48.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="N"/>
+ <chemical_shift value="108.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="17" name="HD1"/>
+ <atom segid=" A" residue="17" name="HD2"/>
+ <atom segid=" A" residue="17" name="HE1"/>
+ <atom segid=" A" residue="17" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="C"/>
+ <chemical_shift value="177.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CB"/>
+ <chemical_shift value="37.646" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CA"/>
+ <chemical_shift value="59.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="N"/>
+ <chemical_shift value="120.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="H"/>
+ <chemical_shift value="8.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="C"/>
+ <chemical_shift value="179.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CB"/>
+ <chemical_shift value="37.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CA"/>
+ <chemical_shift value="56.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="N"/>
+ <chemical_shift value="123.761" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="H"/>
+ <chemical_shift value="8.109" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="C"/>
+ <chemical_shift value="176.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="H"/>
+ <chemical_shift value="9.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="CA"/>
+ <chemical_shift value="47.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="N"/>
+ <chemical_shift value="111.77" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="20" name="HD21"/>
+ <atom segid=" A" residue="20" name="HD22"/>
+ <atom segid=" A" residue="20" name="HD23"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="20" name="HD11"/>
+ <atom segid=" A" residue="20" name="HD12"/>
+ <atom segid=" A" residue="20" name="HD13"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="C"/>
+ <chemical_shift value="178.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CB"/>
+ <chemical_shift value="41.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CA"/>
+ <chemical_shift value="57.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="N"/>
+ <chemical_shift value="121.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CD1"/>
+ <chemical_shift value="24.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CD2"/>
+ <chemical_shift value="26.879" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="21" name="HB1"/>
+ <atom segid=" A" residue="21" name="HB2"/>
+ <atom segid=" A" residue="21" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="C"/>
+ <chemical_shift value="180.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="CB"/>
+ <chemical_shift value="17.478" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="CA"/>
+ <chemical_shift value="55.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="N"/>
+ <chemical_shift value="121.303" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="H"/>
+ <chemical_shift value="8.143" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="C"/>
+ <chemical_shift value="180.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CB"/>
+ <chemical_shift value="28.487" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CA"/>
+ <chemical_shift value="59.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="N"/>
+ <chemical_shift value="120.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="H"/>
+ <chemical_shift value="7.825" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="23" name="HG21"/>
+ <atom segid=" A" residue="23" name="HG22"/>
+ <atom segid=" A" residue="23" name="HG23"/>
+ <chemical_shift value="1.252" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="23" name="HG11"/>
+ <atom segid=" A" residue="23" name="HG12"/>
+ <atom segid=" A" residue="23" name="HG13"/>
+ <chemical_shift value="1.252" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="C"/>
+ <chemical_shift value="179.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CB"/>
+ <chemical_shift value="31.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CA"/>
+ <chemical_shift value="66.874" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="N"/>
+ <chemical_shift value="123.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CG1"/>
+ <chemical_shift value="22.314" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="H"/>
+ <chemical_shift value="7.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CG2"/>
+ <chemical_shift value="23.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="C"/>
+ <chemical_shift value="175.393" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="H"/>
+ <chemical_shift value="8.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="CA"/>
+ <chemical_shift value="47.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="N"/>
+ <chemical_shift value="106.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="25" name="HZ1"/>
+ <atom segid=" A" residue="25" name="HZ2"/>
+ <atom segid=" A" residue="25" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CB"/>
+ <chemical_shift value="31.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="C"/>
+ <chemical_shift value="179.664" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="H"/>
+ <chemical_shift value="8.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CA"/>
+ <chemical_shift value="59.448" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="N"/>
+ <chemical_shift value="123.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="26" name="HZ1"/>
+ <atom segid=" A" residue="26" name="HZ2"/>
+ <atom segid=" A" residue="26" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CB"/>
+ <chemical_shift value="31.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="C"/>
+ <chemical_shift value="178.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="H"/>
+ <chemical_shift value="7.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CA"/>
+ <chemical_shift value="59.777" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="N"/>
+ <chemical_shift value="123.048" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="27" name="HD1"/>
+ <atom segid=" A" residue="27" name="HD2"/>
+ <atom segid=" A" residue="27" name="HE1"/>
+ <atom segid=" A" residue="27" name="HE2"/>
+ <atom segid=" A" residue="27" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="C"/>
+ <chemical_shift value="179.166" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CB"/>
+ <chemical_shift value="39.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CA"/>
+ <chemical_shift value="61.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="N"/>
+ <chemical_shift value="120.111" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="H"/>
+ <chemical_shift value="8.131" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="C"/>
+ <chemical_shift value="180.031" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CB"/>
+ <chemical_shift value="29.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CA"/>
+ <chemical_shift value="59.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="N"/>
+ <chemical_shift value="124.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="H"/>
+ <chemical_shift value="8.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="29" name="HZ1"/>
+ <atom segid=" A" residue="29" name="HZ2"/>
+ <atom segid=" A" residue="29" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CB"/>
+ <chemical_shift value="31.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="H"/>
+ <chemical_shift value="8.151" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CA"/>
+ <chemical_shift value="59.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="N"/>
+ <chemical_shift value="122.162" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="C"/>
+ <chemical_shift value="178.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CB"/>
+ <chemical_shift value="41.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CA"/>
+ <chemical_shift value="56.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="N"/>
+ <chemical_shift value="116.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="H"/>
+ <chemical_shift value="7.615" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="31" name="HG21"/>
+ <atom segid=" A" residue="31" name="HG22"/>
+ <atom segid=" A" residue="31" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="C"/>
+ <chemical_shift value="176.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CB"/>
+ <chemical_shift value="72.293" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CA"/>
+ <chemical_shift value="62.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="N"/>
+ <chemical_shift value="107.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="H"/>
+ <chemical_shift value="7.929" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="C"/>
+ <chemical_shift value="173.645" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="H"/>
+ <chemical_shift value="8.6" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="CA"/>
+ <chemical_shift value="45.563" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="N"/>
+ <chemical_shift value="112.884" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="33" name="HG21"/>
+ <atom segid=" A" residue="33" name="HG22"/>
+ <atom segid=" A" residue="33" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.574" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="33" name="HD11"/>
+ <atom segid=" A" residue="33" name="HD12"/>
+ <atom segid=" A" residue="33" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.574" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="C"/>
+ <chemical_shift value="173.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CB"/>
+ <chemical_shift value="35.66" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CA"/>
+ <chemical_shift value="59.048" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="N"/>
+ <chemical_shift value="124.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CD1"/>
+ <chemical_shift value="10.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="H"/>
+ <chemical_shift value="7.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="34" name="HZ1"/>
+ <atom segid=" A" residue="34" name="HZ2"/>
+ <atom segid=" A" residue="34" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CB"/>
+ <chemical_shift value="32.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="C"/>
+ <chemical_shift value="175.675" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="H"/>
+ <chemical_shift value="7.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CA"/>
+ <chemical_shift value="56.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="N"/>
+ <chemical_shift value="125.011" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="35" name="HG21"/>
+ <atom segid=" A" residue="35" name="HG22"/>
+ <atom segid=" A" residue="35" name="HG23"/>
+ <chemical_shift value="0.776" error="0.0"/>
+ <chemical_shift value="0.331" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="35" name="HG11"/>
+ <atom segid=" A" residue="35" name="HG12"/>
+ <atom segid=" A" residue="35" name="HG13"/>
+ <chemical_shift value="0.776" error="0.0"/>
+ <chemical_shift value="0.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="C"/>
+ <chemical_shift value="175.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CB"/>
+ <chemical_shift value="33.372" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CA"/>
+ <chemical_shift value="61.064" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="N"/>
+ <chemical_shift value="124.42" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CG1"/>
+ <chemical_shift value="20.685" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="H"/>
+ <chemical_shift value="8.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CG2"/>
+ <chemical_shift value="22.478" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="36" name="HG21"/>
+ <atom segid=" A" residue="36" name="HG22"/>
+ <atom segid=" A" residue="36" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="C"/>
+ <chemical_shift value="172.762" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CB"/>
+ <chemical_shift value="70.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CA"/>
+ <chemical_shift value="61.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="N"/>
+ <chemical_shift value="125.312" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="H"/>
+ <chemical_shift value="9.176" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="37" name="HG21"/>
+ <atom segid=" A" residue="37" name="HG22"/>
+ <atom segid=" A" residue="37" name="HG23"/>
+ <chemical_shift value="0.766" error="0.0"/>
+ <chemical_shift value="0.951" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="37" name="HG11"/>
+ <atom segid=" A" residue="37" name="HG12"/>
+ <atom segid=" A" residue="37" name="HG13"/>
+ <chemical_shift value="0.766" error="0.0"/>
+ <chemical_shift value="0.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="C"/>
+ <chemical_shift value="175.348" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CB"/>
+ <chemical_shift value="32.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CA"/>
+ <chemical_shift value="61.689" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="N"/>
+ <chemical_shift value="127.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CG1"/>
+ <chemical_shift value="22.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="H"/>
+ <chemical_shift value="8.921" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CG2"/>
+ <chemical_shift value="20.673" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="C"/>
+ <chemical_shift value="173.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CB"/>
+ <chemical_shift value="33.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CA"/>
+ <chemical_shift value="54.475" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="N"/>
+ <chemical_shift value="127.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="H"/>
+ <chemical_shift value="9.644" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CB"/>
+ <chemical_shift value="28.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CA"/>
+ <chemical_shift value="51.527" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="N"/>
+ <chemical_shift value="115.306" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="H"/>
+ <chemical_shift value="8.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="C"/>
+ <chemical_shift value="176.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CB"/>
+ <chemical_shift value="30.665" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CA"/>
+ <chemical_shift value="62.226" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="C"/>
+ <chemical_shift value="176.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CB"/>
+ <chemical_shift value="41.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CA"/>
+ <chemical_shift value="54.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="N"/>
+ <chemical_shift value="121.165" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="H"/>
+ <chemical_shift value="8.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="42" name="HZ1"/>
+ <atom segid=" A" residue="42" name="HZ2"/>
+ <atom segid=" A" residue="42" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CB"/>
+ <chemical_shift value="29.442" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="C"/>
+ <chemical_shift value="178.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="H"/>
+ <chemical_shift value="8.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CA"/>
+ <chemical_shift value="56.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="N"/>
+ <chemical_shift value="119.242" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="43" name="HD21"/>
+ <atom segid=" A" residue="43" name="HD22"/>
+ <atom segid=" A" residue="43" name="HD23"/>
+ <chemical_shift value="1.133" error="0.0"/>
+ <chemical_shift value="1.101" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="43" name="HD11"/>
+ <atom segid=" A" residue="43" name="HD12"/>
+ <atom segid=" A" residue="43" name="HD13"/>
+ <chemical_shift value="1.133" error="0.0"/>
+ <chemical_shift value="1.101" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="C"/>
+ <chemical_shift value="175.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CB"/>
+ <chemical_shift value="40.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CA"/>
+ <chemical_shift value="59.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="N"/>
+ <chemical_shift value="120.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CD1"/>
+ <chemical_shift value="26.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CD2"/>
+ <chemical_shift value="26.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="H"/>
+ <chemical_shift value="7.387" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="C"/>
+ <chemical_shift value="178.284" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CB"/>
+ <chemical_shift value="24.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CA"/>
+ <chemical_shift value="57.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="N"/>
+ <chemical_shift value="123.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="H"/>
+ <chemical_shift value="10.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="C"/>
+ <chemical_shift value="178.462" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CB"/>
+ <chemical_shift value="29.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CA"/>
+ <chemical_shift value="56.456" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="N"/>
+ <chemical_shift value="120.295" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="H"/>
+ <chemical_shift value="7.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="46" name="HZ1"/>
+ <atom segid=" A" residue="46" name="HZ2"/>
+ <atom segid=" A" residue="46" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CB"/>
+ <chemical_shift value="33.277" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="C"/>
+ <chemical_shift value="179.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="H"/>
+ <chemical_shift value="8.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CA"/>
+ <chemical_shift value="58.611" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="N"/>
+ <chemical_shift value="120.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="47" name="HD1"/>
+ <atom segid=" A" residue="47" name="HD2"/>
+ <atom segid=" A" residue="47" name="HE1"/>
+ <atom segid=" A" residue="47" name="HE2"/>
+ <atom segid=" A" residue="47" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CB"/>
+ <chemical_shift value="36.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CA"/>
+ <chemical_shift value="63.747" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="N"/>
+ <chemical_shift value="116.928" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="H"/>
+ <chemical_shift value="8.655" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="C"/>
+ <chemical_shift value="178.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CB"/>
+ <chemical_shift value="30.015" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CA"/>
+ <chemical_shift value="65.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="C"/>
+ <chemical_shift value="178.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CB"/>
+ <chemical_shift value="28.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CA"/>
+ <chemical_shift value="58.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="N"/>
+ <chemical_shift value="115.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="H"/>
+ <chemical_shift value="6.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="50" name="HG21"/>
+ <atom segid=" A" residue="50" name="HG22"/>
+ <atom segid=" A" residue="50" name="HG23"/>
+ <chemical_shift value="0.906" error="0.0"/>
+ <chemical_shift value="0.967" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="50" name="HG11"/>
+ <atom segid=" A" residue="50" name="HG12"/>
+ <atom segid=" A" residue="50" name="HG13"/>
+ <chemical_shift value="0.906" error="0.0"/>
+ <chemical_shift value="0.967" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="C"/>
+ <chemical_shift value="178.512" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CB"/>
+ <chemical_shift value="32.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CA"/>
+ <chemical_shift value="62.603" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="N"/>
+ <chemical_shift value="111.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CG1"/>
+ <chemical_shift value="21.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="H"/>
+ <chemical_shift value="7.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CG2"/>
+ <chemical_shift value="19.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="51" name="HB1"/>
+ <atom segid=" A" residue="51" name="HB2"/>
+ <atom segid=" A" residue="51" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="C"/>
+ <chemical_shift value="180.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="CB"/>
+ <chemical_shift value="17.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="CA"/>
+ <chemical_shift value="54.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="N"/>
+ <chemical_shift value="125.692" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="H"/>
+ <chemical_shift value="8.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="52" name="HB1"/>
+ <atom segid=" A" residue="52" name="HB2"/>
+ <atom segid=" A" residue="52" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="C"/>
+ <chemical_shift value="178.618" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="CB"/>
+ <chemical_shift value="18.146" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="CA"/>
+ <chemical_shift value="53.841" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="N"/>
+ <chemical_shift value="118.243" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="H"/>
+ <chemical_shift value="7.396" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="53" name="HG21"/>
+ <atom segid=" A" residue="53" name="HG22"/>
+ <atom segid=" A" residue="53" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="C"/>
+ <chemical_shift value="175.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CB"/>
+ <chemical_shift value="69.75" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CA"/>
+ <chemical_shift value="61.307" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="N"/>
+ <chemical_shift value="106.045" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="H"/>
+ <chemical_shift value="7.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="C"/>
+ <chemical_shift value="172.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="H"/>
+ <chemical_shift value="7.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="CA"/>
+ <chemical_shift value="45.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="N"/>
+ <chemical_shift value="109.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="C"/>
+ <chemical_shift value="174.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CB"/>
+ <chemical_shift value="43.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CA"/>
+ <chemical_shift value="52.778" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="N"/>
+ <chemical_shift value="119.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="H"/>
+ <chemical_shift value="7.395" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="H"/>
+ <chemical_shift value="8.332" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="CA"/>
+ <chemical_shift value="43.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="N"/>
+ <chemical_shift value="105.496" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="C"/>
+ <chemical_shift value="175.448" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CB"/>
+ <chemical_shift value="30.658" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CA"/>
+ <chemical_shift value="61.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="C"/>
+ <chemical_shift value="176.037" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CB"/>
+ <chemical_shift value="43.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CA"/>
+ <chemical_shift value="58.668" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="N"/>
+ <chemical_shift value="117.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="H"/>
+ <chemical_shift value="8.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="59" name="HG21"/>
+ <atom segid=" A" residue="59" name="HG22"/>
+ <atom segid=" A" residue="59" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.735" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="59" name="HD11"/>
+ <atom segid=" A" residue="59" name="HD12"/>
+ <atom segid=" A" residue="59" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.735" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="C"/>
+ <chemical_shift value="173.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CB"/>
+ <chemical_shift value="42.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CA"/>
+ <chemical_shift value="58.982" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="N"/>
+ <chemical_shift value="114.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CD1"/>
+ <chemical_shift value="13.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="H"/>
+ <chemical_shift value="7.631" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="60" name="HG21"/>
+ <atom segid=" A" residue="60" name="HG22"/>
+ <atom segid=" A" residue="60" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.452" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="60" name="HD11"/>
+ <atom segid=" A" residue="60" name="HD12"/>
+ <atom segid=" A" residue="60" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="C"/>
+ <chemical_shift value="172.929" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CB"/>
+ <chemical_shift value="41.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CA"/>
+ <chemical_shift value="58.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="N"/>
+ <chemical_shift value="124.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CD1"/>
+ <chemical_shift value="14.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="H"/>
+ <chemical_shift value="8.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="61" name="HD1"/>
+ <atom segid=" A" residue="61" name="HD2"/>
+ <atom segid=" A" residue="61" name="HE1"/>
+ <atom segid=" A" residue="61" name="HE2"/>
+ <atom segid=" A" residue="61" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="C"/>
+ <chemical_shift value="176.742" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CB"/>
+ <chemical_shift value="41.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CA"/>
+ <chemical_shift value="55.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="N"/>
+ <chemical_shift value="126.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="H"/>
+ <chemical_shift value="8.603" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="H"/>
+ <chemical_shift value="9.181" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="C"/>
+ <chemical_shift value="173.771" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CB"/>
+ <chemical_shift value="31.813" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CA"/>
+ <chemical_shift value="57.786" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="N"/>
+ <chemical_shift value="121.356" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="63" name="HB1"/>
+ <atom segid=" A" residue="63" name="HB2"/>
+ <atom segid=" A" residue="63" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="C"/>
+ <chemical_shift value="179.957" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="CB"/>
+ <chemical_shift value="18.639" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="CA"/>
+ <chemical_shift value="54.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="N"/>
+ <chemical_shift value="125.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="H"/>
+ <chemical_shift value="6.296" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="C"/>
+ <chemical_shift value="178.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CB"/>
+ <chemical_shift value="30.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CA"/>
+ <chemical_shift value="60.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="N"/>
+ <chemical_shift value="115.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="H"/>
+ <chemical_shift value="8.028" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="C"/>
+ <chemical_shift value="177.968" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CB"/>
+ <chemical_shift value="39.5" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CA"/>
+ <chemical_shift value="57.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="N"/>
+ <chemical_shift value="119.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="H"/>
+ <chemical_shift value="7.721" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CB"/>
+ <chemical_shift value="29.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="C"/>
+ <chemical_shift value="177.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="H"/>
+ <chemical_shift value="6.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CA"/>
+ <chemical_shift value="55.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="N"/>
+ <chemical_shift value="116.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="67" name="HD1"/>
+ <atom segid=" A" residue="67" name="HD2"/>
+ <atom segid=" A" residue="67" name="HE1"/>
+ <atom segid=" A" residue="67" name="HE2"/>
+ <atom segid=" A" residue="67" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="C"/>
+ <chemical_shift value="177.883" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CB"/>
+ <chemical_shift value="36.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CA"/>
+ <chemical_shift value="58.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="N"/>
+ <chemical_shift value="116.954" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="H"/>
+ <chemical_shift value="7.688" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="C"/>
+ <chemical_shift value="175.81" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="H"/>
+ <chemical_shift value="7.272" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="CA"/>
+ <chemical_shift value="47.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="N"/>
+ <chemical_shift value="107.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="C"/>
+ <chemical_shift value="177.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="H"/>
+ <chemical_shift value="7.651" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="CA"/>
+ <chemical_shift value="47.089" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="N"/>
+ <chemical_shift value="107.532" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="70" name="HD1"/>
+ <atom segid=" A" residue="70" name="HD2"/>
+ <atom segid=" A" residue="70" name="HE1"/>
+ <atom segid=" A" residue="70" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="C"/>
+ <chemical_shift value="178.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CB"/>
+ <chemical_shift value="35.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CA"/>
+ <chemical_shift value="57.372" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="N"/>
+ <chemical_shift value="119.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="H"/>
+ <chemical_shift value="6.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="71" name="HB1"/>
+ <atom segid=" A" residue="71" name="HB2"/>
+ <atom segid=" A" residue="71" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="C"/>
+ <chemical_shift value="182.277" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="CB"/>
+ <chemical_shift value="18.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="CA"/>
+ <chemical_shift value="54.487" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="N"/>
+ <chemical_shift value="122.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="H"/>
+ <chemical_shift value="8.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="C"/>
+ <chemical_shift value="177.85" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CB"/>
+ <chemical_shift value="27.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CA"/>
+ <chemical_shift value="58.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="N"/>
+ <chemical_shift value="122.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="H"/>
+ <chemical_shift value="8.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="C"/>
+ <chemical_shift value="173.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="CB"/>
+ <chemical_shift value="64.148" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="CA"/>
+ <chemical_shift value="59.274" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="N"/>
+ <chemical_shift value="112.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="H"/>
+ <chemical_shift value="7.362" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="C"/>
+ <chemical_shift value="176.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="H"/>
+ <chemical_shift value="8.083" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="CA"/>
+ <chemical_shift value="46.341" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="N"/>
+ <chemical_shift value="109.4" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="75" name="HD22"/>
+ <atom segid=" A" residue="75" name="HD23"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="75" name="HD11"/>
+ <atom segid=" A" residue="75" name="HD12"/>
+ <atom segid=" A" residue="75" name="HD13"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="C"/>
+ <chemical_shift value="177.608" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CB"/>
+ <chemical_shift value="42.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CA"/>
+ <chemical_shift value="55.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="N"/>
+ <chemical_shift value="113.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CD1"/>
+ <chemical_shift value="25.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CD2"/>
+ <chemical_shift value="20.664" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="H"/>
+ <chemical_shift value="7.815" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="76" name="HD22"/>
+ <atom segid=" A" residue="76" name="HD23"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.897" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="76" name="HD11"/>
+ <atom segid=" A" residue="76" name="HD12"/>
+ <atom segid=" A" residue="76" name="HD13"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="C"/>
+ <chemical_shift value="176.782" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CB"/>
+ <chemical_shift value="43.798" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CA"/>
+ <chemical_shift value="52.794" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="N"/>
+ <chemical_shift value="115.902" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CD1"/>
+ <chemical_shift value="27.43" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CD2"/>
+ <chemical_shift value="21.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="H"/>
+ <chemical_shift value="7.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="77" name="HB1"/>
+ <atom segid=" A" residue="77" name="HB2"/>
+ <atom segid=" A" residue="77" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="C"/>
+ <chemical_shift value="176.398" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="CB"/>
+ <chemical_shift value="19.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="CA"/>
+ <chemical_shift value="51.102" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="N"/>
+ <chemical_shift value="125.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="H"/>
+ <chemical_shift value="9.007" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="C"/>
+ <chemical_shift value="176.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CB"/>
+ <chemical_shift value="29.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CA"/>
+ <chemical_shift value="56.426" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="N"/>
+ <chemical_shift value="120.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="H"/>
+ <chemical_shift value="8.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="79" name="HG21"/>
+ <atom segid=" A" residue="79" name="HG22"/>
+ <atom segid=" A" residue="79" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.161" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="79" name="HD11"/>
+ <atom segid=" A" residue="79" name="HD12"/>
+ <atom segid=" A" residue="79" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.161" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="C"/>
+ <chemical_shift value="175.746" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CB"/>
+ <chemical_shift value="38.941" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CA"/>
+ <chemical_shift value="59.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="N"/>
+ <chemical_shift value="122.859" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CD1"/>
+ <chemical_shift value="12.313" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="H"/>
+ <chemical_shift value="8.176" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="80" name="HG21"/>
+ <atom segid=" A" residue="80" name="HG22"/>
+ <atom segid=" A" residue="80" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CB"/>
+ <chemical_shift value="69.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CA"/>
+ <chemical_shift value="57.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="N"/>
+ <chemical_shift value="112.766" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="H"/>
+ <chemical_shift value="8.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="C"/>
+ <chemical_shift value="177.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CB"/>
+ <chemical_shift value="31.586" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CA"/>
+ <chemical_shift value="62.548" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CB"/>
+ <chemical_shift value="41.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CA"/>
+ <chemical_shift value="53.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="N"/>
+ <chemical_shift value="123.843" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="H"/>
+ <chemical_shift value="9.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="83" name="HZ1"/>
+ <atom segid=" A" residue="83" name="HZ2"/>
+ <atom segid=" A" residue="83" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CB"/>
+ <chemical_shift value="31.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="C"/>
+ <chemical_shift value="177.708" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CA"/>
+ <chemical_shift value="59.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="84" name="HB1"/>
+ <atom segid=" A" residue="84" name="HB2"/>
+ <atom segid=" A" residue="84" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="C"/>
+ <chemical_shift value="180.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="CB"/>
+ <chemical_shift value="17.553" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="CA"/>
+ <chemical_shift value="54.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="N"/>
+ <chemical_shift value="119.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="H"/>
+ <chemical_shift value="8.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="85" name="HD1"/>
+ <atom segid=" A" residue="85" name="HD2"/>
+ <atom segid=" A" residue="85" name="HE1"/>
+ <atom segid=" A" residue="85" name="HE2"/>
+ <atom segid=" A" residue="85" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="C"/>
+ <chemical_shift value="178.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CB"/>
+ <chemical_shift value="39.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CA"/>
+ <chemical_shift value="62.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="N"/>
+ <chemical_shift value="118.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="H"/>
+ <chemical_shift value="7.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="C"/>
+ <chemical_shift value="180.14" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CB"/>
+ <chemical_shift value="28.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CA"/>
+ <chemical_shift value="59.616" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="N"/>
+ <chemical_shift value="117.272" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="H"/>
+ <chemical_shift value="8.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="C"/>
+ <chemical_shift value="176.576" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CB"/>
+ <chemical_shift value="40.956" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CA"/>
+ <chemical_shift value="56.177" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="N"/>
+ <chemical_shift value="116.913" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="H"/>
+ <chemical_shift value="8.053" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="88" name="HZ1"/>
+ <atom segid=" A" residue="88" name="HZ2"/>
+ <atom segid=" A" residue="88" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CB"/>
+ <chemical_shift value="31.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="C"/>
+ <chemical_shift value="176.797" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="H"/>
+ <chemical_shift value="7.816" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CA"/>
+ <chemical_shift value="58.402" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="N"/>
+ <chemical_shift value="117.299" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="89" name="HD21"/>
+ <atom segid=" A" residue="89" name="HD22"/>
+ <atom segid=" A" residue="89" name="HD23"/>
+ <chemical_shift value="0.484" error="0.0"/>
+ <chemical_shift value="0.526" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="89" name="HD11"/>
+ <atom segid=" A" residue="89" name="HD12"/>
+ <atom segid=" A" residue="89" name="HD13"/>
+ <chemical_shift value="0.484" error="0.0"/>
+ <chemical_shift value="0.526" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="C"/>
+ <chemical_shift value="176.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CB"/>
+ <chemical_shift value="42.609" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CA"/>
+ <chemical_shift value="53.55" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="N"/>
+ <chemical_shift value="120.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CD1"/>
+ <chemical_shift value="26.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CD2"/>
+ <chemical_shift value="25.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="H"/>
+ <chemical_shift value="7.661" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="90" name="HD1"/>
+ <atom segid=" A" residue="90" name="HD2"/>
+ <atom segid=" A" residue="90" name="HE1"/>
+ <atom segid=" A" residue="90" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CB"/>
+ <chemical_shift value="38.921" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CA"/>
+ <chemical_shift value="59.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="N"/>
+ <chemical_shift value="116.748" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="H"/>
+ <chemical_shift value="7.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="C"/>
+ <chemical_shift value="179.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CB"/>
+ <chemical_shift value="31.38" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CA"/>
+ <chemical_shift value="66.902" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="92" name="HD1"/>
+ <atom segid=" A" residue="92" name="HD2"/>
+ <atom segid=" A" residue="92" name="HE1"/>
+ <atom segid=" A" residue="92" name="HE2"/>
+ <atom segid=" A" residue="92" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="C"/>
+ <chemical_shift value="176.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CB"/>
+ <chemical_shift value="36.63" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CA"/>
+ <chemical_shift value="59.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="N"/>
+ <chemical_shift value="112.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="H"/>
+ <chemical_shift value="8.01" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="93" name="HG21"/>
+ <atom segid=" A" residue="93" name="HG22"/>
+ <atom segid=" A" residue="93" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="C"/>
+ <chemical_shift value="176.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CB"/>
+ <chemical_shift value="67.099" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CA"/>
+ <chemical_shift value="64.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="N"/>
+ <chemical_shift value="111.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="H"/>
+ <chemical_shift value="7.099" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="H"/>
+ <chemical_shift value="6.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="C"/>
+ <chemical_shift value="178.465" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CB"/>
+ <chemical_shift value="29.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CA"/>
+ <chemical_shift value="58.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="N"/>
+ <chemical_shift value="120.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="C"/>
+ <chemical_shift value="178.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CB"/>
+ <chemical_shift value="39.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CA"/>
+ <chemical_shift value="57.436" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="N"/>
+ <chemical_shift value="115.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="H"/>
+ <chemical_shift value="7.31" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="96" name="HB1"/>
+ <atom segid=" A" residue="96" name="HB2"/>
+ <atom segid=" A" residue="96" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="C"/>
+ <chemical_shift value="177.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="CB"/>
+ <chemical_shift value="17.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="CA"/>
+ <chemical_shift value="54.0" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="N"/>
+ <chemical_shift value="118.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="H"/>
+ <chemical_shift value="6.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="97" name="HG21"/>
+ <atom segid=" A" residue="97" name="HG22"/>
+ <atom segid=" A" residue="97" name="HG23"/>
+ <chemical_shift value="1.347" error="0.0"/>
+ <chemical_shift value="0.578" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="97" name="HG11"/>
+ <atom segid=" A" residue="97" name="HG12"/>
+ <atom segid=" A" residue="97" name="HG13"/>
+ <chemical_shift value="1.347" error="0.0"/>
+ <chemical_shift value="0.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="C"/>
+ <chemical_shift value="172.577" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CB"/>
+ <chemical_shift value="30.785" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CA"/>
+ <chemical_shift value="59.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="N"/>
+ <chemical_shift value="106.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CG1"/>
+ <chemical_shift value="22.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="H"/>
+ <chemical_shift value="7.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CG2"/>
+ <chemical_shift value="19.363" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CB"/>
+ <chemical_shift value="31.357" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="C"/>
+ <chemical_shift value="176.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="H"/>
+ <chemical_shift value="7.049" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CA"/>
+ <chemical_shift value="55.065" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="N"/>
+ <chemical_shift value="121.675" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="99" name="HD1"/>
+ <atom segid=" A" residue="99" name="HD2"/>
+ <atom segid=" A" residue="99" name="HE1"/>
+ <atom segid=" A" residue="99" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CB"/>
+ <chemical_shift value="41.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CA"/>
+ <chemical_shift value="58.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="N"/>
+ <chemical_shift value="127.473" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="H"/>
+ <chemical_shift value="9.707" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="C"/>
+ <chemical_shift value="175.4" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CB"/>
+ <chemical_shift value="37.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CA"/>
+ <chemical_shift value="53.907" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="C"/>
+ <chemical_shift value="173.987" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="H"/>
+ <chemical_shift value="8.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="CA"/>
+ <chemical_shift value="45.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="N"/>
+ <chemical_shift value="102.283" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="102" name="HZ1"/>
+ <atom segid=" A" residue="102" name="HZ2"/>
+ <atom segid=" A" residue="102" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CB"/>
+ <chemical_shift value="34.731" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="C"/>
+ <chemical_shift value="175.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="H"/>
+ <chemical_shift value="7.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CA"/>
+ <chemical_shift value="54.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="N"/>
+ <chemical_shift value="121.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="103" name="HD21"/>
+ <atom segid=" A" residue="103" name="HD22"/>
+ <atom segid=" A" residue="103" name="HD23"/>
+ <chemical_shift value="0.972" error="0.0"/>
+ <chemical_shift value="0.49" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="103" name="HD11"/>
+ <atom segid=" A" residue="103" name="HD12"/>
+ <atom segid=" A" residue="103" name="HD13"/>
+ <chemical_shift value="0.972" error="0.0"/>
+ <chemical_shift value="0.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="C"/>
+ <chemical_shift value="178.524" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CB"/>
+ <chemical_shift value="42.179" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CA"/>
+ <chemical_shift value="55.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="N"/>
+ <chemical_shift value="123.232" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CD1"/>
+ <chemical_shift value="24.748" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CD2"/>
+ <chemical_shift value="24.1" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="H"/>
+ <chemical_shift value="8.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="104" name="HG21"/>
+ <atom segid=" A" residue="104" name="HG22"/>
+ <atom segid=" A" residue="104" name="HG23"/>
+ <chemical_shift value="0.889" error="0.0"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="104" name="HD11"/>
+ <atom segid=" A" residue="104" name="HD12"/>
+ <atom segid=" A" residue="104" name="HD13"/>
+ <chemical_shift value="0.889" error="0.0"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="C"/>
+ <chemical_shift value="175.468" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CB"/>
+ <chemical_shift value="39.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CA"/>
+ <chemical_shift value="59.655" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="N"/>
+ <chemical_shift value="112.793" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CD1"/>
+ <chemical_shift value="14.779" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="H"/>
+ <chemical_shift value="8.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CG2"/>
+ <chemical_shift value="19.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="105" name="HB1"/>
+ <atom segid=" A" residue="105" name="HB2"/>
+ <atom segid=" A" residue="105" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="C"/>
+ <chemical_shift value="173.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="CB"/>
+ <chemical_shift value="22.111" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="CA"/>
+ <chemical_shift value="52.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="N"/>
+ <chemical_shift value="117.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="H"/>
+ <chemical_shift value="7.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="106" name="HD1"/>
+ <atom segid=" A" residue="106" name="HD2"/>
+ <atom segid=" A" residue="106" name="HE1"/>
+ <atom segid=" A" residue="106" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CB"/>
+ <chemical_shift value="39.931" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CA"/>
+ <chemical_shift value="56.214" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="N"/>
+ <chemical_shift value="113.919" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="H"/>
+ <chemical_shift value="8.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="C"/>
+ <chemical_shift value="174.609" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CB"/>
+ <chemical_shift value="32.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CA"/>
+ <chemical_shift value="62.281" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="108" name="HG21"/>
+ <atom segid=" A" residue="108" name="HG22"/>
+ <atom segid=" A" residue="108" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.637" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="108" name="HD11"/>
+ <atom segid=" A" residue="108" name="HD12"/>
+ <atom segid=" A" residue="108" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.637" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="C"/>
+ <chemical_shift value="176.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CB"/>
+ <chemical_shift value="37.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CA"/>
+ <chemical_shift value="60.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="N"/>
+ <chemical_shift value="115.381" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CD1"/>
+ <chemical_shift value="9.981" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="H"/>
+ <chemical_shift value="8.515" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="109" name="HB1"/>
+ <atom segid=" A" residue="109" name="HB2"/>
+ <atom segid=" A" residue="109" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="C"/>
+ <chemical_shift value="174.628" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="CB"/>
+ <chemical_shift value="23.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="CA"/>
+ <chemical_shift value="50.761" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="N"/>
+ <chemical_shift value="118.162" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="H"/>
+ <chemical_shift value="7.854" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="110" name="HG21"/>
+ <atom segid=" A" residue="110" name="HG22"/>
+ <atom segid=" A" residue="110" name="HG23"/>
+ <chemical_shift value="0.476" error="0.0"/>
+ <chemical_shift value="0.767" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="110" name="HG11"/>
+ <atom segid=" A" residue="110" name="HG12"/>
+ <atom segid=" A" residue="110" name="HG13"/>
+ <chemical_shift value="0.476" error="0.0"/>
+ <chemical_shift value="0.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="C"/>
+ <chemical_shift value="173.634" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CB"/>
+ <chemical_shift value="34.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CA"/>
+ <chemical_shift value="62.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="N"/>
+ <chemical_shift value="121.428" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CG1"/>
+ <chemical_shift value="20.954" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="H"/>
+ <chemical_shift value="8.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CG2"/>
+ <chemical_shift value="20.424" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="C"/>
+ <chemical_shift value="173.917" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CB"/>
+ <chemical_shift value="32.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CA"/>
+ <chemical_shift value="54.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="N"/>
+ <chemical_shift value="123.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="H"/>
+ <chemical_shift value="9.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="112" name="HB1"/>
+ <atom segid=" A" residue="112" name="HB2"/>
+ <atom segid=" A" residue="112" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="C"/>
+ <chemical_shift value="176.641" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="CB"/>
+ <chemical_shift value="22.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="CA"/>
+ <chemical_shift value="50.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="N"/>
+ <chemical_shift value="117.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="H"/>
+ <chemical_shift value="6.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="113" name="HD21"/>
+ <atom segid=" A" residue="113" name="HD22"/>
+ <atom segid=" A" residue="113" name="HD23"/>
+ <chemical_shift value="0.854" error="0.0"/>
+ <chemical_shift value="0.691" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="113" name="HD11"/>
+ <atom segid=" A" residue="113" name="HD12"/>
+ <atom segid=" A" residue="113" name="HD13"/>
+ <chemical_shift value="0.854" error="0.0"/>
+ <chemical_shift value="0.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="C"/>
+ <chemical_shift value="173.598" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CB"/>
+ <chemical_shift value="43.367" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CA"/>
+ <chemical_shift value="55.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="N"/>
+ <chemical_shift value="123.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CD1"/>
+ <chemical_shift value="26.792" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CD2"/>
+ <chemical_shift value="23.625" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="H"/>
+ <chemical_shift value="8.457" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="C"/>
+ <chemical_shift value="172.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="CB"/>
+ <chemical_shift value="67.447" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="CA"/>
+ <chemical_shift value="57.265" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="N"/>
+ <chemical_shift value="108.174" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="H"/>
+ <chemical_shift value="7.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="115" name="HD21"/>
+ <atom segid=" A" residue="115" name="HD22"/>
+ <atom segid=" A" residue="115" name="HD23"/>
+ <chemical_shift value="0.587" error="0.0"/>
+ <chemical_shift value="0.684" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="115" name="HD11"/>
+ <atom segid=" A" residue="115" name="HD12"/>
+ <atom segid=" A" residue="115" name="HD13"/>
+ <chemical_shift value="0.587" error="0.0"/>
+ <chemical_shift value="0.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="C"/>
+ <chemical_shift value="174.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CB"/>
+ <chemical_shift value="43.729" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CA"/>
+ <chemical_shift value="54.482" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="N"/>
+ <chemical_shift value="122.319" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CD1"/>
+ <chemical_shift value="22.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CD2"/>
+ <chemical_shift value="24.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="H"/>
+ <chemical_shift value="7.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="116" name="HG21"/>
+ <atom segid=" A" residue="116" name="HG22"/>
+ <atom segid=" A" residue="116" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.459" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="116" name="HD11"/>
+ <atom segid=" A" residue="116" name="HD12"/>
+ <atom segid=" A" residue="116" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.459" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="C"/>
+ <chemical_shift value="174.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CB"/>
+ <chemical_shift value="38.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CA"/>
+ <chemical_shift value="60.103" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="N"/>
+ <chemical_shift value="129.611" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CD1"/>
+ <chemical_shift value="13.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="H"/>
+ <chemical_shift value="8.667" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="117" name="HD1"/>
+ <atom segid=" A" residue="117" name="HD2"/>
+ <atom segid=" A" residue="117" name="HE1"/>
+ <atom segid=" A" residue="117" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="C"/>
+ <chemical_shift value="172.945" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CB"/>
+ <chemical_shift value="42.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CA"/>
+ <chemical_shift value="54.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="N"/>
+ <chemical_shift value="121.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="H"/>
+ <chemical_shift value="9.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="C"/>
+ <chemical_shift value="175.772" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CB"/>
+ <chemical_shift value="37.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CA"/>
+ <chemical_shift value="52.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="N"/>
+ <chemical_shift value="121.187" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="H"/>
+ <chemical_shift value="9.303" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="119" name="HZ1"/>
+ <atom segid=" A" residue="119" name="HZ2"/>
+ <atom segid=" A" residue="119" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CB"/>
+ <chemical_shift value="32.435" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="C"/>
+ <chemical_shift value="177.723" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="H"/>
+ <chemical_shift value="8.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CA"/>
+ <chemical_shift value="58.733" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="N"/>
+ <chemical_shift value="125.522" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="C"/>
+ <chemical_shift value="177.651" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CB"/>
+ <chemical_shift value="40.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CA"/>
+ <chemical_shift value="56.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="N"/>
+ <chemical_shift value="115.687" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="121" name="HD21"/>
+ <atom segid=" A" residue="121" name="HD22"/>
+ <atom segid=" A" residue="121" name="HD23"/>
+ <chemical_shift value="0.779" error="0.0"/>
+ <chemical_shift value="0.665" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="121" name="HD11"/>
+ <atom segid=" A" residue="121" name="HD12"/>
+ <atom segid=" A" residue="121" name="HD13"/>
+ <chemical_shift value="0.779" error="0.0"/>
+ <chemical_shift value="0.665" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="C"/>
+ <chemical_shift value="176.749" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CB"/>
+ <chemical_shift value="44.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CA"/>
+ <chemical_shift value="55.765" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="N"/>
+ <chemical_shift value="117.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CD1"/>
+ <chemical_shift value="24.729" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CD2"/>
+ <chemical_shift value="22.791" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="H"/>
+ <chemical_shift value="7.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="122" name="HD21"/>
+ <atom segid=" A" residue="122" name="HD22"/>
+ <atom segid=" A" residue="122" name="HD23"/>
+ <chemical_shift value="0.937" error="0.0"/>
+ <chemical_shift value="0.93" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="122" name="HD11"/>
+ <atom segid=" A" residue="122" name="HD12"/>
+ <atom segid=" A" residue="122" name="HD13"/>
+ <chemical_shift value="0.937" error="0.0"/>
+ <chemical_shift value="0.93" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CB"/>
+ <chemical_shift value="44.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CA"/>
+ <chemical_shift value="51.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="N"/>
+ <chemical_shift value="119.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CD1"/>
+ <chemical_shift value="25.548" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CD2"/>
+ <chemical_shift value="26.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="C"/>
+ <chemical_shift value="176.075" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CB"/>
+ <chemical_shift value="31.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CA"/>
+ <chemical_shift value="62.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="127" name="HZ1"/>
+ <atom segid=" A" residue="127" name="HZ2"/>
+ <atom segid=" A" residue="127" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CB"/>
+ <chemical_shift value="33.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="C"/>
+ <chemical_shift value="177.427" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="H"/>
+ <chemical_shift value="8.137" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CA"/>
+ <chemical_shift value="56.778" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="N"/>
+ <chemical_shift value="118.457" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="128" name="HG21"/>
+ <atom segid=" A" residue="128" name="HG22"/>
+ <atom segid=" A" residue="128" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="C"/>
+ <chemical_shift value="174.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CB"/>
+ <chemical_shift value="71.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CA"/>
+ <chemical_shift value="60.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="N"/>
+ <chemical_shift value="108.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="H"/>
+ <chemical_shift value="10.183" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="C"/>
+ <chemical_shift value="179.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CB"/>
+ <chemical_shift value="28.48" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CA"/>
+ <chemical_shift value="60.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="N"/>
+ <chemical_shift value="123.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="C"/>
+ <chemical_shift value="178.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CB"/>
+ <chemical_shift value="28.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CA"/>
+ <chemical_shift value="61.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="N"/>
+ <chemical_shift value="118.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="H"/>
+ <chemical_shift value="10.583" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="C"/>
+ <chemical_shift value="176.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CB"/>
+ <chemical_shift value="31.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CA"/>
+ <chemical_shift value="57.205" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="N"/>
+ <chemical_shift value="116.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="H"/>
+ <chemical_shift value="7.606" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="132" name="HG21"/>
+ <atom segid=" A" residue="132" name="HG22"/>
+ <atom segid=" A" residue="132" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.56" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="132" name="HD11"/>
+ <atom segid=" A" residue="132" name="HD12"/>
+ <atom segid=" A" residue="132" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CB"/>
+ <chemical_shift value="33.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CA"/>
+ <chemical_shift value="66.928" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="N"/>
+ <chemical_shift value="121.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CD1"/>
+ <chemical_shift value="12.36" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="H"/>
+ <chemical_shift value="8.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="C"/>
+ <chemical_shift value="177.795" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CB"/>
+ <chemical_shift value="30.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CA"/>
+ <chemical_shift value="67.059" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="134" name="HB1"/>
+ <atom segid=" A" residue="134" name="HB2"/>
+ <atom segid=" A" residue="134" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="C"/>
+ <chemical_shift value="181.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="CB"/>
+ <chemical_shift value="17.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="CA"/>
+ <chemical_shift value="55.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="N"/>
+ <chemical_shift value="118.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="H"/>
+ <chemical_shift value="7.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="135" name="HD21"/>
+ <atom segid=" A" residue="135" name="HD22"/>
+ <atom segid=" A" residue="135" name="HD23"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ <chemical_shift value="0.888" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="135" name="HD11"/>
+ <atom segid=" A" residue="135" name="HD12"/>
+ <atom segid=" A" residue="135" name="HD13"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ <chemical_shift value="0.888" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="C"/>
+ <chemical_shift value="179.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CB"/>
+ <chemical_shift value="42.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CA"/>
+ <chemical_shift value="57.396" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="N"/>
+ <chemical_shift value="120.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CD1"/>
+ <chemical_shift value="24.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CD2"/>
+ <chemical_shift value="24.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="H"/>
+ <chemical_shift value="7.6" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="C"/>
+ <chemical_shift value="177.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CB"/>
+ <chemical_shift value="41.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CA"/>
+ <chemical_shift value="58.901" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="N"/>
+ <chemical_shift value="118.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="H"/>
+ <chemical_shift value="8.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="137" name="HZ1"/>
+ <atom segid=" A" residue="137" name="HZ2"/>
+ <atom segid=" A" residue="137" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CB"/>
+ <chemical_shift value="31.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="C"/>
+ <chemical_shift value="179.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="H"/>
+ <chemical_shift value="8.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CA"/>
+ <chemical_shift value="60.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="N"/>
+ <chemical_shift value="117.342" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="C"/>
+ <chemical_shift value="179.799" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CB"/>
+ <chemical_shift value="29.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CA"/>
+ <chemical_shift value="59.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="N"/>
+ <chemical_shift value="118.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="H"/>
+ <chemical_shift value="7.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="139" name="HD21"/>
+ <atom segid=" A" residue="139" name="HD22"/>
+ <atom segid=" A" residue="139" name="HD23"/>
+ <chemical_shift value="0.852" error="0.0"/>
+ <chemical_shift value="0.787" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="139" name="HD11"/>
+ <atom segid=" A" residue="139" name="HD12"/>
+ <atom segid=" A" residue="139" name="HD13"/>
+ <chemical_shift value="0.852" error="0.0"/>
+ <chemical_shift value="0.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="C"/>
+ <chemical_shift value="180.721" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CB"/>
+ <chemical_shift value="40.311" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CA"/>
+ <chemical_shift value="58.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="N"/>
+ <chemical_shift value="121.279" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CD1"/>
+ <chemical_shift value="25.914" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CD2"/>
+ <chemical_shift value="22.927" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="H"/>
+ <chemical_shift value="8.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="140" name="HZ1"/>
+ <atom segid=" A" residue="140" name="HZ2"/>
+ <atom segid=" A" residue="140" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CB"/>
+ <chemical_shift value="31.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="C"/>
+ <chemical_shift value="181.621" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="H"/>
+ <chemical_shift value="9.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CA"/>
+ <chemical_shift value="58.851" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="N"/>
+ <chemical_shift value="124.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="141" name="HB1"/>
+ <atom segid=" A" residue="141" name="HB2"/>
+ <atom segid=" A" residue="141" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="C"/>
+ <chemical_shift value="178.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="CB"/>
+ <chemical_shift value="17.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="CA"/>
+ <chemical_shift value="54.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="N"/>
+ <chemical_shift value="122.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="H"/>
+ <chemical_shift value="7.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="142" name="HZ1"/>
+ <atom segid=" A" residue="142" name="HZ2"/>
+ <atom segid=" A" residue="142" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CB"/>
+ <chemical_shift value="32.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="C"/>
+ <chemical_shift value="176.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="H"/>
+ <chemical_shift value="7.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CA"/>
+ <chemical_shift value="55.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="N"/>
+ <chemical_shift value="115.794" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="C"/>
+ <chemical_shift value="174.318" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="H"/>
+ <chemical_shift value="7.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="CA"/>
+ <chemical_shift value="46.128" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="N"/>
+ <chemical_shift value="107.82" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="144" name="HZ1"/>
+ <atom segid=" A" residue="144" name="HZ2"/>
+ <atom segid=" A" residue="144" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CB"/>
+ <chemical_shift value="35.01" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="C"/>
+ <chemical_shift value="173.812" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="H"/>
+ <chemical_shift value="7.86" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CA"/>
+ <chemical_shift value="53.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="N"/>
+ <chemical_shift value="119.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="C"/>
+ <chemical_shift value="174.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="CB"/>
+ <chemical_shift value="66.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="CA"/>
+ <chemical_shift value="56.884" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="N"/>
+ <chemical_shift value="109.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="H"/>
+ <chemical_shift value="7.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="146" name="HB1"/>
+ <atom segid=" A" residue="146" name="HB2"/>
+ <atom segid=" A" residue="146" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="C"/>
+ <chemical_shift value="175.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="CB"/>
+ <chemical_shift value="17.973" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="CA"/>
+ <chemical_shift value="55.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="N"/>
+ <chemical_shift value="122.791" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="H"/>
+ <chemical_shift value="9.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="147" name="HD21"/>
+ <atom segid=" A" residue="147" name="HD22"/>
+ <atom segid=" A" residue="147" name="HD23"/>
+ <chemical_shift value="0.936" error="0.0"/>
+ <chemical_shift value="0.683" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="147" name="HD11"/>
+ <atom segid=" A" residue="147" name="HD12"/>
+ <atom segid=" A" residue="147" name="HD13"/>
+ <chemical_shift value="0.936" error="0.0"/>
+ <chemical_shift value="0.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="C"/>
+ <chemical_shift value="175.05" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CB"/>
+ <chemical_shift value="45.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CA"/>
+ <chemical_shift value="54.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="N"/>
+ <chemical_shift value="116.868" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CD1"/>
+ <chemical_shift value="22.5" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CD2"/>
+ <chemical_shift value="27.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="H"/>
+ <chemical_shift value="8.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="148" name="HE1"/>
+ <atom segid=" A" residue="148" name="HE2"/>
+ <atom segid=" A" residue="148" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="C"/>
+ <chemical_shift value="174.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CB"/>
+ <chemical_shift value="37.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CA"/>
+ <chemical_shift value="55.8" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="N"/>
+ <chemical_shift value="121.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="H"/>
+ <chemical_shift value="8.179" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="149" name="HD1"/>
+ <atom segid=" A" residue="149" name="HD2"/>
+ <atom segid=" A" residue="149" name="HE1"/>
+ <atom segid=" A" residue="149" name="HE2"/>
+ <atom segid=" A" residue="149" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="C"/>
+ <chemical_shift value="171.59" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CB"/>
+ <chemical_shift value="41.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CA"/>
+ <chemical_shift value="55.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="N"/>
+ <chemical_shift value="120.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="H"/>
+ <chemical_shift value="8.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="C"/>
+ <chemical_shift value="172.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CB"/>
+ <chemical_shift value="37.305" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CA"/>
+ <chemical_shift value="53.341" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="N"/>
+ <chemical_shift value="116.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="H"/>
+ <chemical_shift value="8.671" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="151" name="HD21"/>
+ <atom segid=" A" residue="151" name="HD22"/>
+ <atom segid=" A" residue="151" name="HD23"/>
+ <chemical_shift value="0.135" error="0.0"/>
+ <chemical_shift value="0.744" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="151" name="HD11"/>
+ <atom segid=" A" residue="151" name="HD12"/>
+ <atom segid=" A" residue="151" name="HD13"/>
+ <chemical_shift value="0.135" error="0.0"/>
+ <chemical_shift value="0.744" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="C"/>
+ <chemical_shift value="177.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CB"/>
+ <chemical_shift value="41.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CA"/>
+ <chemical_shift value="54.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="N"/>
+ <chemical_shift value="122.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CD1"/>
+ <chemical_shift value="26.232" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CD2"/>
+ <chemical_shift value="23.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="H"/>
+ <chemical_shift value="7.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="C"/>
+ <chemical_shift value="176.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CB"/>
+ <chemical_shift value="28.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CA"/>
+ <chemical_shift value="55.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="N"/>
+ <chemical_shift value="113.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="H"/>
+ <chemical_shift value="7.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CB"/>
+ <chemical_shift value="32.958" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CA"/>
+ <chemical_shift value="51.537" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="N"/>
+ <chemical_shift value="113.572" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="H"/>
+ <chemical_shift value="6.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="C"/>
+ <chemical_shift value="176.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CB"/>
+ <chemical_shift value="31.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CA"/>
+ <chemical_shift value="63.731" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="155" name="HD1"/>
+ <atom segid=" A" residue="155" name="HD2"/>
+ <atom segid=" A" residue="155" name="HE1"/>
+ <atom segid=" A" residue="155" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="C"/>
+ <chemical_shift value="176.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CB"/>
+ <chemical_shift value="40.447" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CA"/>
+ <chemical_shift value="62.679" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="N"/>
+ <chemical_shift value="117.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="H"/>
+ <chemical_shift value="7.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="156" name="HD1"/>
+ <atom segid=" A" residue="156" name="HD2"/>
+ <atom segid=" A" residue="156" name="HE1"/>
+ <atom segid=" A" residue="156" name="HE2"/>
+ <atom segid=" A" residue="156" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="C"/>
+ <chemical_shift value="176.222" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CB"/>
+ <chemical_shift value="41.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CA"/>
+ <chemical_shift value="60.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="N"/>
+ <chemical_shift value="112.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="H"/>
+ <chemical_shift value="8.045" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="157" name="HG21"/>
+ <atom segid=" A" residue="157" name="HG22"/>
+ <atom segid=" A" residue="157" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="C"/>
+ <chemical_shift value="176.039" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CB"/>
+ <chemical_shift value="69.29" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CA"/>
+ <chemical_shift value="63.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="N"/>
+ <chemical_shift value="106.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="H"/>
+ <chemical_shift value="7.59" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CB"/>
+ <chemical_shift value="28.509" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CA"/>
+ <chemical_shift value="60.968" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="N"/>
+ <chemical_shift value="124.195" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="C"/>
+ <chemical_shift value="178.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CB"/>
+ <chemical_shift value="30.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CA"/>
+ <chemical_shift value="65.931" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="160" name="HD21"/>
+ <atom segid=" A" residue="160" name="HD22"/>
+ <atom segid=" A" residue="160" name="HD23"/>
+ <chemical_shift value="-0.302" error="0.0"/>
+ <chemical_shift value="-1.003" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="160" name="HD11"/>
+ <atom segid=" A" residue="160" name="HD12"/>
+ <atom segid=" A" residue="160" name="HD13"/>
+ <chemical_shift value="-0.302" error="0.0"/>
+ <chemical_shift value="-1.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="C"/>
+ <chemical_shift value="176.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CB"/>
+ <chemical_shift value="42.223" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CA"/>
+ <chemical_shift value="56.069" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="N"/>
+ <chemical_shift value="111.624" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CD1"/>
+ <chemical_shift value="19.602" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CD2"/>
+ <chemical_shift value="25.084" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="H"/>
+ <chemical_shift value="6.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="161" name="HG21"/>
+ <atom segid=" A" residue="161" name="HG22"/>
+ <atom segid=" A" residue="161" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.76" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="161" name="HD11"/>
+ <atom segid=" A" residue="161" name="HD12"/>
+ <atom segid=" A" residue="161" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="C"/>
+ <chemical_shift value="175.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CB"/>
+ <chemical_shift value="37.395" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CA"/>
+ <chemical_shift value="65.625" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="N"/>
+ <chemical_shift value="119.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CD1"/>
+ <chemical_shift value="13.081" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="H"/>
+ <chemical_shift value="6.955" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="162" name="HB1"/>
+ <atom segid=" A" residue="162" name="HB2"/>
+ <atom segid=" A" residue="162" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="C"/>
+ <chemical_shift value="179.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="CB"/>
+ <chemical_shift value="18.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="CA"/>
+ <chemical_shift value="52.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="N"/>
+ <chemical_shift value="115.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="H"/>
+ <chemical_shift value="8.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="163" name="HB1"/>
+ <atom segid=" A" residue="163" name="HB2"/>
+ <atom segid=" A" residue="163" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="C"/>
+ <chemical_shift value="178.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="CB"/>
+ <chemical_shift value="19.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="CA"/>
+ <chemical_shift value="56.425" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="N"/>
+ <chemical_shift value="120.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="H"/>
+ <chemical_shift value="6.668" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="C"/>
+ <chemical_shift value="176.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CB"/>
+ <chemical_shift value="42.538" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CA"/>
+ <chemical_shift value="53.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="N"/>
+ <chemical_shift value="115.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="H"/>
+ <chemical_shift value="9.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="C"/>
+ <chemical_shift value="175.607" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="H"/>
+ <chemical_shift value="7.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="CA"/>
+ <chemical_shift value="45.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="N"/>
+ <chemical_shift value="103.622" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="C"/>
+ <chemical_shift value="172.227" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="H"/>
+ <chemical_shift value="7.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="CA"/>
+ <chemical_shift value="45.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="N"/>
+ <chemical_shift value="108.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="167" name="HD1"/>
+ <atom segid=" A" residue="167" name="HD2"/>
+ <atom segid=" A" residue="167" name="HE1"/>
+ <atom segid=" A" residue="167" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="C"/>
+ <chemical_shift value="173.273" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CB"/>
+ <chemical_shift value="39.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CA"/>
+ <chemical_shift value="57.657" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="N"/>
+ <chemical_shift value="115.865" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="H"/>
+ <chemical_shift value="8.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="168" name="HB1"/>
+ <atom segid=" A" residue="168" name="HB2"/>
+ <atom segid=" A" residue="168" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="C"/>
+ <chemical_shift value="173.012" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="CB"/>
+ <chemical_shift value="16.475" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="CA"/>
+ <chemical_shift value="53.124" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="N"/>
+ <chemical_shift value="124.0" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="H"/>
+ <chemical_shift value="10.209" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="169" name="HD1"/>
+ <atom segid=" A" residue="169" name="HD2"/>
+ <atom segid=" A" residue="169" name="HE1"/>
+ <atom segid=" A" residue="169" name="HE2"/>
+ <atom segid=" A" residue="169" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="C"/>
+ <chemical_shift value="176.744" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CB"/>
+ <chemical_shift value="42.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CA"/>
+ <chemical_shift value="55.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="N"/>
+ <chemical_shift value="108.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="H"/>
+ <chemical_shift value="6.324" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="170" name="HZ1"/>
+ <atom segid=" A" residue="170" name="HZ2"/>
+ <atom segid=" A" residue="170" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CB"/>
+ <chemical_shift value="32.355" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="C"/>
+ <chemical_shift value="174.716" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="H"/>
+ <chemical_shift value="8.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CA"/>
+ <chemical_shift value="57.027" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="N"/>
+ <chemical_shift value="125.705" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="171" name="HD2"/>
+ <atom segid=" A" residue="171" name="HE1"/>
+ <atom segid=" A" residue="171" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="C"/>
+ <chemical_shift value="175.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CB"/>
+ <chemical_shift value="39.896" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CA"/>
+ <chemical_shift value="56.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="N"/>
+ <chemical_shift value="129.707" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="H"/>
+ <chemical_shift value="8.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CB"/>
+ <chemical_shift value="32.477" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CA"/>
+ <chemical_shift value="55.981" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="N"/>
+ <chemical_shift value="126.797" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="H"/>
+ <chemical_shift value="8.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="C"/>
+ <chemical_shift value="175.432" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CB"/>
+ <chemical_shift value="37.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CA"/>
+ <chemical_shift value="54.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="C"/>
+ <chemical_shift value="173.294" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="H"/>
+ <chemical_shift value="7.52" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="CA"/>
+ <chemical_shift value="45.705" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="N"/>
+ <chemical_shift value="102.08" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="175" name="HZ1"/>
+ <atom segid=" A" residue="175" name="HZ2"/>
+ <atom segid=" A" residue="175" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CB"/>
+ <chemical_shift value="35.233" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="C"/>
+ <chemical_shift value="174.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="H"/>
+ <chemical_shift value="7.107" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CA"/>
+ <chemical_shift value="54.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="N"/>
+ <chemical_shift value="118.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="176" name="HD1"/>
+ <atom segid=" A" residue="176" name="HD2"/>
+ <atom segid=" A" residue="176" name="HE1"/>
+ <atom segid=" A" residue="176" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="C"/>
+ <chemical_shift value="176.262" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CB"/>
+ <chemical_shift value="39.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CA"/>
+ <chemical_shift value="58.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="N"/>
+ <chemical_shift value="120.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="H"/>
+ <chemical_shift value="8.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="C"/>
+ <chemical_shift value="177.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CB"/>
+ <chemical_shift value="41.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CA"/>
+ <chemical_shift value="52.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="N"/>
+ <chemical_shift value="124.051" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="H"/>
+ <chemical_shift value="9.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="178" name="HG21"/>
+ <atom segid=" A" residue="178" name="HG22"/>
+ <atom segid=" A" residue="178" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.853" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="178" name="HD11"/>
+ <atom segid=" A" residue="178" name="HD12"/>
+ <atom segid=" A" residue="178" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="C"/>
+ <chemical_shift value="175.849" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CB"/>
+ <chemical_shift value="36.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CA"/>
+ <chemical_shift value="63.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="N"/>
+ <chemical_shift value="117.051" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CD1"/>
+ <chemical_shift value="13.905" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="H"/>
+ <chemical_shift value="7.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="179" name="HZ1"/>
+ <atom segid=" A" residue="179" name="HZ2"/>
+ <atom segid=" A" residue="179" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CB"/>
+ <chemical_shift value="31.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="C"/>
+ <chemical_shift value="176.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="H"/>
+ <chemical_shift value="8.302" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CA"/>
+ <chemical_shift value="54.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="N"/>
+ <chemical_shift value="116.075" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="C"/>
+ <chemical_shift value="172.993" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CB"/>
+ <chemical_shift value="40.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CA"/>
+ <chemical_shift value="53.425" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="N"/>
+ <chemical_shift value="123.259" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="H"/>
+ <chemical_shift value="7.754" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="181" name="HG21"/>
+ <atom segid=" A" residue="181" name="HG22"/>
+ <atom segid=" A" residue="181" name="HG23"/>
+ <chemical_shift value="0.711" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="181" name="HG11"/>
+ <atom segid=" A" residue="181" name="HG12"/>
+ <atom segid=" A" residue="181" name="HG13"/>
+ <chemical_shift value="0.711" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="C"/>
+ <chemical_shift value="176.899" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CB"/>
+ <chemical_shift value="35.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CA"/>
+ <chemical_shift value="59.481" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="N"/>
+ <chemical_shift value="122.883" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CG1"/>
+ <chemical_shift value="21.539" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="H"/>
+ <chemical_shift value="7.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CG2"/>
+ <chemical_shift value="22.538" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="C"/>
+ <chemical_shift value="174.259" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="H"/>
+ <chemical_shift value="7.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="CA"/>
+ <chemical_shift value="46.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="N"/>
+ <chemical_shift value="120.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="183" name="HG21"/>
+ <atom segid=" A" residue="183" name="HG22"/>
+ <atom segid=" A" residue="183" name="HG23"/>
+ <chemical_shift value="0.841" error="0.0"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="183" name="HG11"/>
+ <atom segid=" A" residue="183" name="HG12"/>
+ <atom segid=" A" residue="183" name="HG13"/>
+ <chemical_shift value="0.841" error="0.0"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="C"/>
+ <chemical_shift value="173.292" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CB"/>
+ <chemical_shift value="32.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CA"/>
+ <chemical_shift value="63.489" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="N"/>
+ <chemical_shift value="114.266" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CG1"/>
+ <chemical_shift value="22.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="H"/>
+ <chemical_shift value="6.757" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CG2"/>
+ <chemical_shift value="22.42" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="C"/>
+ <chemical_shift value="176.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CB"/>
+ <chemical_shift value="39.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CA"/>
+ <chemical_shift value="51.67" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="N"/>
+ <chemical_shift value="114.851" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="H"/>
+ <chemical_shift value="7.835" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CB"/>
+ <chemical_shift value="39.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CA"/>
+ <chemical_shift value="51.688" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="N"/>
+ <chemical_shift value="116.3" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="H"/>
+ <chemical_shift value="6.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="186" name="HB1"/>
+ <atom segid=" A" residue="186" name="HB2"/>
+ <atom segid=" A" residue="186" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="C"/>
+ <chemical_shift value="180.525" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="CB"/>
+ <chemical_shift value="18.22" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="CA"/>
+ <chemical_shift value="55.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="C"/>
+ <chemical_shift value="176.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="H"/>
+ <chemical_shift value="8.385" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="CA"/>
+ <chemical_shift value="47.366" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="N"/>
+ <chemical_shift value="109.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="188" name="HB1"/>
+ <atom segid=" A" residue="188" name="HB2"/>
+ <atom segid=" A" residue="188" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="C"/>
+ <chemical_shift value="180.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="CB"/>
+ <chemical_shift value="18.399" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="CA"/>
+ <chemical_shift value="54.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="N"/>
+ <chemical_shift value="127.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="H"/>
+ <chemical_shift value="8.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="189" name="HZ1"/>
+ <atom segid=" A" residue="189" name="HZ2"/>
+ <atom segid=" A" residue="189" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CB"/>
+ <chemical_shift value="31.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="C"/>
+ <chemical_shift value="180.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="H"/>
+ <chemical_shift value="7.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CA"/>
+ <chemical_shift value="59.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="N"/>
+ <chemical_shift value="115.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="190" name="HB1"/>
+ <atom segid=" A" residue="190" name="HB2"/>
+ <atom segid=" A" residue="190" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="C"/>
+ <chemical_shift value="181.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="CB"/>
+ <chemical_shift value="17.89" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="CA"/>
+ <chemical_shift value="55.835" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="N"/>
+ <chemical_shift value="124.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="H"/>
+ <chemical_shift value="8.224" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="C"/>
+ <chemical_shift value="174.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="H"/>
+ <chemical_shift value="8.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="CA"/>
+ <chemical_shift value="47.937" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="N"/>
+ <chemical_shift value="107.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="192" name="HD21"/>
+ <atom segid=" A" residue="192" name="HD22"/>
+ <atom segid=" A" residue="192" name="HD23"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="1.085" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="192" name="HD11"/>
+ <atom segid=" A" residue="192" name="HD12"/>
+ <atom segid=" A" residue="192" name="HD13"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="1.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="C"/>
+ <chemical_shift value="178.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CB"/>
+ <chemical_shift value="40.218" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CA"/>
+ <chemical_shift value="57.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="N"/>
+ <chemical_shift value="121.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CD1"/>
+ <chemical_shift value="24.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CD2"/>
+ <chemical_shift value="25.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="H"/>
+ <chemical_shift value="8.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="193" name="HG21"/>
+ <atom segid=" A" residue="193" name="HG22"/>
+ <atom segid=" A" residue="193" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="C"/>
+ <chemical_shift value="175.23" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CB"/>
+ <chemical_shift value="69.081" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CA"/>
+ <chemical_shift value="67.423" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="N"/>
+ <chemical_shift value="116.486" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="H"/>
+ <chemical_shift value="8.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="194" name="HD1"/>
+ <atom segid=" A" residue="194" name="HD2"/>
+ <atom segid=" A" residue="194" name="HE1"/>
+ <atom segid=" A" residue="194" name="HE2"/>
+ <atom segid=" A" residue="194" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="C"/>
+ <chemical_shift value="177.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CB"/>
+ <chemical_shift value="39.196" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CA"/>
+ <chemical_shift value="62.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="N"/>
+ <chemical_shift value="122.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="H"/>
+ <chemical_shift value="7.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="195" name="HD21"/>
+ <atom segid=" A" residue="195" name="HD22"/>
+ <atom segid=" A" residue="195" name="HD23"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="195" name="HD11"/>
+ <atom segid=" A" residue="195" name="HD12"/>
+ <atom segid=" A" residue="195" name="HD13"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="C"/>
+ <chemical_shift value="178.132" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CB"/>
+ <chemical_shift value="41.352" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CA"/>
+ <chemical_shift value="58.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="N"/>
+ <chemical_shift value="119.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CD1"/>
+ <chemical_shift value="23.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CD2"/>
+ <chemical_shift value="25.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="H"/>
+ <chemical_shift value="7.712" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="196" name="HG21"/>
+ <atom segid=" A" residue="196" name="HG22"/>
+ <atom segid=" A" residue="196" name="HG23"/>
+ <chemical_shift value="0.856" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="196" name="HG11"/>
+ <atom segid=" A" residue="196" name="HG12"/>
+ <atom segid=" A" residue="196" name="HG13"/>
+ <chemical_shift value="0.856" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="C"/>
+ <chemical_shift value="178.464" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CB"/>
+ <chemical_shift value="31.053" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CA"/>
+ <chemical_shift value="67.271" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="N"/>
+ <chemical_shift value="117.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CG1"/>
+ <chemical_shift value="21.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="H"/>
+ <chemical_shift value="8.589" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CG2"/>
+ <chemical_shift value="23.319" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="C"/>
+ <chemical_shift value="179.361" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CB"/>
+ <chemical_shift value="39.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CA"/>
+ <chemical_shift value="58.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="N"/>
+ <chemical_shift value="122.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="H"/>
+ <chemical_shift value="8.58" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="198" name="HD21"/>
+ <atom segid=" A" residue="198" name="HD22"/>
+ <atom segid=" A" residue="198" name="HD23"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="1.018" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="198" name="HD11"/>
+ <atom segid=" A" residue="198" name="HD12"/>
+ <atom segid=" A" residue="198" name="HD13"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="1.018" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="C"/>
+ <chemical_shift value="179.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CB"/>
+ <chemical_shift value="42.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CA"/>
+ <chemical_shift value="58.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="N"/>
+ <chemical_shift value="120.213" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CD1"/>
+ <chemical_shift value="25.598" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CD2"/>
+ <chemical_shift value="23.461" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="H"/>
+ <chemical_shift value="7.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="199" name="HG21"/>
+ <atom segid=" A" residue="199" name="HG22"/>
+ <atom segid=" A" residue="199" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.743" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="199" name="HD11"/>
+ <atom segid=" A" residue="199" name="HD12"/>
+ <atom segid=" A" residue="199" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.743" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="C"/>
+ <chemical_shift value="181.156" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CB"/>
+ <chemical_shift value="38.209" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CA"/>
+ <chemical_shift value="63.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="N"/>
+ <chemical_shift value="119.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CD1"/>
+ <chemical_shift value="14.222" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="H"/>
+ <chemical_shift value="7.434" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="200" name="HZ1"/>
+ <atom segid=" A" residue="200" name="HZ2"/>
+ <atom segid=" A" residue="200" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CB"/>
+ <chemical_shift value="32.127" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="C"/>
+ <chemical_shift value="178.834" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="H"/>
+ <chemical_shift value="9.393" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CA"/>
+ <chemical_shift value="59.943" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="N"/>
+ <chemical_shift value="124.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="C"/>
+ <chemical_shift value="173.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CB"/>
+ <chemical_shift value="38.686" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CA"/>
+ <chemical_shift value="53.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="N"/>
+ <chemical_shift value="113.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="H"/>
+ <chemical_shift value="8.004" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="202" name="HZ1"/>
+ <atom segid=" A" residue="202" name="HZ2"/>
+ <atom segid=" A" residue="202" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CB"/>
+ <chemical_shift value="27.266" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="C"/>
+ <chemical_shift value="175.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="H"/>
+ <chemical_shift value="7.932" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CA"/>
+ <chemical_shift value="57.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="N"/>
+ <chemical_shift value="111.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="C"/>
+ <chemical_shift value="175.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CB"/>
+ <chemical_shift value="28.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CA"/>
+ <chemical_shift value="57.268" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="N"/>
+ <chemical_shift value="116.235" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="H"/>
+ <chemical_shift value="8.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="204" name="HE1"/>
+ <atom segid=" A" residue="204" name="HE2"/>
+ <atom segid=" A" residue="204" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="C"/>
+ <chemical_shift value="173.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CB"/>
+ <chemical_shift value="37.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CA"/>
+ <chemical_shift value="54.646" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="N"/>
+ <chemical_shift value="114.03" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="H"/>
+ <chemical_shift value="7.477" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="C"/>
+ <chemical_shift value="176.088" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CB"/>
+ <chemical_shift value="40.287" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CA"/>
+ <chemical_shift value="52.185" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="N"/>
+ <chemical_shift value="118.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="H"/>
+ <chemical_shift value="8.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="206" name="HB1"/>
+ <atom segid=" A" residue="206" name="HB2"/>
+ <atom segid=" A" residue="206" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="C"/>
+ <chemical_shift value="176.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="CB"/>
+ <chemical_shift value="18.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="CA"/>
+ <chemical_shift value="54.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="N"/>
+ <chemical_shift value="125.067" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="H"/>
+ <chemical_shift value="9.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="C"/>
+ <chemical_shift value="176.539" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CB"/>
+ <chemical_shift value="39.943" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CA"/>
+ <chemical_shift value="53.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="N"/>
+ <chemical_shift value="112.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="H"/>
+ <chemical_shift value="8.172" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="208" name="HG21"/>
+ <atom segid=" A" residue="208" name="HG22"/>
+ <atom segid=" A" residue="208" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="C"/>
+ <chemical_shift value="173.305" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CB"/>
+ <chemical_shift value="69.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CA"/>
+ <chemical_shift value="66.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="N"/>
+ <chemical_shift value="116.637" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="H"/>
+ <chemical_shift value="7.344" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="C"/>
+ <chemical_shift value="175.818" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CB"/>
+ <chemical_shift value="42.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CA"/>
+ <chemical_shift value="51.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="N"/>
+ <chemical_shift value="130.935" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="H"/>
+ <chemical_shift value="6.982" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="210" name="HD1"/>
+ <atom segid=" A" residue="210" name="HD2"/>
+ <atom segid=" A" residue="210" name="HE1"/>
+ <atom segid=" A" residue="210" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="C"/>
+ <chemical_shift value="178.37" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CB"/>
+ <chemical_shift value="39.077" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CA"/>
+ <chemical_shift value="63.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="N"/>
+ <chemical_shift value="117.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="H"/>
+ <chemical_shift value="7.858" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="C"/>
+ <chemical_shift value="177.629" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="CB"/>
+ <chemical_shift value="63.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="CA"/>
+ <chemical_shift value="61.419" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="N"/>
+ <chemical_shift value="114.682" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="H"/>
+ <chemical_shift value="8.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="212" name="HG21"/>
+ <atom segid=" A" residue="212" name="HG22"/>
+ <atom segid=" A" residue="212" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.867" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="212" name="HD11"/>
+ <atom segid=" A" residue="212" name="HD12"/>
+ <atom segid=" A" residue="212" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="C"/>
+ <chemical_shift value="179.021" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CB"/>
+ <chemical_shift value="38.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CA"/>
+ <chemical_shift value="65.023" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="N"/>
+ <chemical_shift value="124.45" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CD1"/>
+ <chemical_shift value="13.11" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="H"/>
+ <chemical_shift value="8.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="213" name="HB1"/>
+ <atom segid=" A" residue="213" name="HB2"/>
+ <atom segid=" A" residue="213" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="C"/>
+ <chemical_shift value="177.865" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="CB"/>
+ <chemical_shift value="17.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="CA"/>
+ <chemical_shift value="55.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="N"/>
+ <chemical_shift value="120.747" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="H"/>
+ <chemical_shift value="7.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="C"/>
+ <chemical_shift value="178.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CB"/>
+ <chemical_shift value="29.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CA"/>
+ <chemical_shift value="58.941" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="N"/>
+ <chemical_shift value="117.551" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="215" name="HB1"/>
+ <atom segid=" A" residue="215" name="HB2"/>
+ <atom segid=" A" residue="215" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="C"/>
+ <chemical_shift value="179.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="CB"/>
+ <chemical_shift value="18.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="CA"/>
+ <chemical_shift value="54.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="N"/>
+ <chemical_shift value="119.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="H"/>
+ <chemical_shift value="7.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="216" name="HB1"/>
+ <atom segid=" A" residue="216" name="HB2"/>
+ <atom segid=" A" residue="216" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="C"/>
+ <chemical_shift value="180.736" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="CB"/>
+ <chemical_shift value="19.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="CA"/>
+ <chemical_shift value="55.247" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="N"/>
+ <chemical_shift value="117.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="H"/>
+ <chemical_shift value="7.789" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="217" name="HD1"/>
+ <atom segid=" A" residue="217" name="HD2"/>
+ <atom segid=" A" residue="217" name="HE1"/>
+ <atom segid=" A" residue="217" name="HE2"/>
+ <atom segid=" A" residue="217" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CB"/>
+ <chemical_shift value="38.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CA"/>
+ <chemical_shift value="62.919" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="N"/>
+ <chemical_shift value="119.446" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="H"/>
+ <chemical_shift value="8.338" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="C"/>
+ <chemical_shift value="176.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CB"/>
+ <chemical_shift value="36.484" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CA"/>
+ <chemical_shift value="55.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="219" name="HZ1"/>
+ <atom segid=" A" residue="219" name="HZ2"/>
+ <atom segid=" A" residue="219" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CB"/>
+ <chemical_shift value="32.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="C"/>
+ <chemical_shift value="177.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="H"/>
+ <chemical_shift value="7.713" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CA"/>
+ <chemical_shift value="56.131" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="N"/>
+ <chemical_shift value="116.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="C"/>
+ <chemical_shift value="175.309" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="H"/>
+ <chemical_shift value="7.717" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="CA"/>
+ <chemical_shift value="46.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="N"/>
+ <chemical_shift value="108.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="C"/>
+ <chemical_shift value="175.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CB"/>
+ <chemical_shift value="30.469" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CA"/>
+ <chemical_shift value="57.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="N"/>
+ <chemical_shift value="116.369" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="H"/>
+ <chemical_shift value="8.382" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="222" name="HG21"/>
+ <atom segid=" A" residue="222" name="HG22"/>
+ <atom segid=" A" residue="222" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="C"/>
+ <chemical_shift value="172.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CB"/>
+ <chemical_shift value="70.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CA"/>
+ <chemical_shift value="58.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="N"/>
+ <chemical_shift value="110.551" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="H"/>
+ <chemical_shift value="6.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="223" name="HB1"/>
+ <atom segid=" A" residue="223" name="HB2"/>
+ <atom segid=" A" residue="223" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="C"/>
+ <chemical_shift value="176.461" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="CB"/>
+ <chemical_shift value="20.427" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="CA"/>
+ <chemical_shift value="54.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="N"/>
+ <chemical_shift value="127.376" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="H"/>
+ <chemical_shift value="8.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="224" name="HE1"/>
+ <atom segid=" A" residue="224" name="HE2"/>
+ <atom segid=" A" residue="224" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="C"/>
+ <chemical_shift value="173.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CB"/>
+ <chemical_shift value="40.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CA"/>
+ <chemical_shift value="54.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="N"/>
+ <chemical_shift value="114.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="H"/>
+ <chemical_shift value="8.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="225" name="HG21"/>
+ <atom segid=" A" residue="225" name="HG22"/>
+ <atom segid=" A" residue="225" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="C"/>
+ <chemical_shift value="171.424" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CB"/>
+ <chemical_shift value="71.023" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CA"/>
+ <chemical_shift value="59.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="N"/>
+ <chemical_shift value="113.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="H"/>
+ <chemical_shift value="9.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="226" name="HG21"/>
+ <atom segid=" A" residue="226" name="HG22"/>
+ <atom segid=" A" residue="226" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.06" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="226" name="HD11"/>
+ <atom segid=" A" residue="226" name="HD12"/>
+ <atom segid=" A" residue="226" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.06" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="C"/>
+ <chemical_shift value="174.82" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CB"/>
+ <chemical_shift value="40.344" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CA"/>
+ <chemical_shift value="60.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="N"/>
+ <chemical_shift value="122.714" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CD1"/>
+ <chemical_shift value="11.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="H"/>
+ <chemical_shift value="7.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="C"/>
+ <chemical_shift value="175.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CB"/>
+ <chemical_shift value="42.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CA"/>
+ <chemical_shift value="52.466" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="N"/>
+ <chemical_shift value="121.906" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="H"/>
+ <chemical_shift value="8.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="H"/>
+ <chemical_shift value="8.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="CA"/>
+ <chemical_shift value="42.27" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="N"/>
+ <chemical_shift value="110.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CB"/>
+ <chemical_shift value="29.552" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CA"/>
+ <chemical_shift value="62.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="H"/>
+ <chemical_shift value="5.923" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CB"/>
+ <chemical_shift value="26.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CA"/>
+ <chemical_shift value="59.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="N"/>
+ <chemical_shift value="111.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="231" name="HB1"/>
+ <atom segid=" A" residue="231" name="HB2"/>
+ <atom segid=" A" residue="231" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="CB"/>
+ <chemical_shift value="19.11" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="CA"/>
+ <chemical_shift value="52.168" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="N"/>
+ <chemical_shift value="125.512" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="H"/>
+ <chemical_shift value="6.975" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="H"/>
+ <chemical_shift value="7.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CB"/>
+ <chemical_shift value="28.673" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CA"/>
+ <chemical_shift value="58.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="N"/>
+ <chemical_shift value="118.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="235" name="HG21"/>
+ <atom segid=" A" residue="235" name="HG22"/>
+ <atom segid=" A" residue="235" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="235" name="HD11"/>
+ <atom segid=" A" residue="235" name="HD12"/>
+ <atom segid=" A" residue="235" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="237" name="HG21"/>
+ <atom segid=" A" residue="237" name="HG22"/>
+ <atom segid=" A" residue="237" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="239" name="HZ1"/>
+ <atom segid=" A" residue="239" name="HZ2"/>
+ <atom segid=" A" residue="239" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="240" name="HG21"/>
+ <atom segid=" A" residue="240" name="HG22"/>
+ <atom segid=" A" residue="240" name="HG23"/>
+ <atom segid=" A" residue="240" name="HG11"/>
+ <atom segid=" A" residue="240" name="HG12"/>
+ <atom segid=" A" residue="240" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CB"/>
+ <chemical_shift value="37.371" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="242" name="HD1"/>
+ <atom segid=" A" residue="242" name="HD2"/>
+ <atom segid=" A" residue="242" name="HE1"/>
+ <atom segid=" A" residue="242" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="C"/>
+ <chemical_shift value="174.489" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CB"/>
+ <chemical_shift value="41.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CA"/>
+ <chemical_shift value="54.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="N"/>
+ <chemical_shift value="121.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="C"/>
+ <chemical_shift value="171.154" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="H"/>
+ <chemical_shift value="8.494" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="CA"/>
+ <chemical_shift value="42.935" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="N"/>
+ <chemical_shift value="107.501" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="244" name="HG21"/>
+ <atom segid=" A" residue="244" name="HG22"/>
+ <atom segid=" A" residue="244" name="HG23"/>
+ <chemical_shift value="0.636" error="0.0"/>
+ <chemical_shift value="1.072" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="244" name="HG11"/>
+ <atom segid=" A" residue="244" name="HG12"/>
+ <atom segid=" A" residue="244" name="HG13"/>
+ <chemical_shift value="0.636" error="0.0"/>
+ <chemical_shift value="1.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="C"/>
+ <chemical_shift value="174.872" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CB"/>
+ <chemical_shift value="34.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CA"/>
+ <chemical_shift value="61.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="N"/>
+ <chemical_shift value="120.896" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CG1"/>
+ <chemical_shift value="22.083" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="H"/>
+ <chemical_shift value="8.229" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CG2"/>
+ <chemical_shift value="21.606" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="245" name="HG21"/>
+ <atom segid=" A" residue="245" name="HG22"/>
+ <atom segid=" A" residue="245" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="C"/>
+ <chemical_shift value="174.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CB"/>
+ <chemical_shift value="71.559" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CA"/>
+ <chemical_shift value="59.071" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="N"/>
+ <chemical_shift value="119.808" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="H"/>
+ <chemical_shift value="9.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="246" name="HG21"/>
+ <atom segid=" A" residue="246" name="HG22"/>
+ <atom segid=" A" residue="246" name="HG23"/>
+ <chemical_shift value="0.983" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="246" name="HG11"/>
+ <atom segid=" A" residue="246" name="HG12"/>
+ <atom segid=" A" residue="246" name="HG13"/>
+ <chemical_shift value="0.983" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="C"/>
+ <chemical_shift value="175.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CB"/>
+ <chemical_shift value="32.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CA"/>
+ <chemical_shift value="62.433" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="N"/>
+ <chemical_shift value="123.607" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CG1"/>
+ <chemical_shift value="20.441" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CG2"/>
+ <chemical_shift value="21.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="247" name="HD21"/>
+ <atom segid=" A" residue="247" name="HD22"/>
+ <atom segid=" A" residue="247" name="HD23"/>
+ <chemical_shift value="0.645" error="0.0"/>
+ <chemical_shift value="0.663" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="247" name="HD11"/>
+ <atom segid=" A" residue="247" name="HD12"/>
+ <atom segid=" A" residue="247" name="HD13"/>
+ <chemical_shift value="0.645" error="0.0"/>
+ <chemical_shift value="0.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CB"/>
+ <chemical_shift value="40.229" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CA"/>
+ <chemical_shift value="54.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="N"/>
+ <chemical_shift value="125.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CD1"/>
+ <chemical_shift value="25.833" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CD2"/>
+ <chemical_shift value="23.824" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="H"/>
+ <chemical_shift value="8.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="C"/>
+ <chemical_shift value="175.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CB"/>
+ <chemical_shift value="30.183" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CA"/>
+ <chemical_shift value="61.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="249" name="HG21"/>
+ <atom segid=" A" residue="249" name="HG22"/>
+ <atom segid=" A" residue="249" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="C"/>
+ <chemical_shift value="174.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CB"/>
+ <chemical_shift value="71.441" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CA"/>
+ <chemical_shift value="61.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="N"/>
+ <chemical_shift value="111.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="H"/>
+ <chemical_shift value="8.815" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="250" name="HD1"/>
+ <atom segid=" A" residue="250" name="HD2"/>
+ <atom segid=" A" residue="250" name="HE1"/>
+ <atom segid=" A" residue="250" name="HE2"/>
+ <atom segid=" A" residue="250" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="C"/>
+ <chemical_shift value="174.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CB"/>
+ <chemical_shift value="41.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CA"/>
+ <chemical_shift value="56.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="N"/>
+ <chemical_shift value="121.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="H"/>
+ <chemical_shift value="9.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="251" name="HZ1"/>
+ <atom segid=" A" residue="251" name="HZ2"/>
+ <atom segid=" A" residue="251" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CB"/>
+ <chemical_shift value="28.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="C"/>
+ <chemical_shift value="177.723" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="H"/>
+ <chemical_shift value="10.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CA"/>
+ <chemical_shift value="57.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="N"/>
+ <chemical_shift value="129.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="C"/>
+ <chemical_shift value="173.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="H"/>
+ <chemical_shift value="9.031" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="CA"/>
+ <chemical_shift value="45.086" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="N"/>
+ <chemical_shift value="103.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CB"/>
+ <chemical_shift value="29.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CA"/>
+ <chemical_shift value="52.486" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="N"/>
+ <chemical_shift value="122.357" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="H"/>
+ <chemical_shift value="8.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="C"/>
+ <chemical_shift value="178.676" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CB"/>
+ <chemical_shift value="31.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CA"/>
+ <chemical_shift value="62.977" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="C"/>
+ <chemical_shift value="173.658" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="CB"/>
+ <chemical_shift value="64.942" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="CA"/>
+ <chemical_shift value="62.323" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="N"/>
+ <chemical_shift value="117.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="H"/>
+ <chemical_shift value="8.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="256" name="HZ1"/>
+ <atom segid=" A" residue="256" name="HZ2"/>
+ <atom segid=" A" residue="256" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CB"/>
+ <chemical_shift value="33.307" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="H"/>
+ <chemical_shift value="7.639" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CA"/>
+ <chemical_shift value="53.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="N"/>
+ <chemical_shift value="123.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="C"/>
+ <chemical_shift value="177.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CB"/>
+ <chemical_shift value="31.379" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CA"/>
+ <chemical_shift value="62.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="258" name="HD1"/>
+ <atom segid=" A" residue="258" name="HD2"/>
+ <atom segid=" A" residue="258" name="HE1"/>
+ <atom segid=" A" residue="258" name="HE2"/>
+ <atom segid=" A" residue="258" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="C"/>
+ <chemical_shift value="177.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CB"/>
+ <chemical_shift value="40.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CA"/>
+ <chemical_shift value="58.534" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="N"/>
+ <chemical_shift value="118.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="H"/>
+ <chemical_shift value="9.265" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="259" name="HG21"/>
+ <atom segid=" A" residue="259" name="HG22"/>
+ <atom segid=" A" residue="259" name="HG23"/>
+ <chemical_shift value="0.98" error="0.0"/>
+ <chemical_shift value="0.925" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="259" name="HG11"/>
+ <atom segid=" A" residue="259" name="HG12"/>
+ <atom segid=" A" residue="259" name="HG13"/>
+ <chemical_shift value="0.98" error="0.0"/>
+ <chemical_shift value="0.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="C"/>
+ <chemical_shift value="176.569" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CB"/>
+ <chemical_shift value="33.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CA"/>
+ <chemical_shift value="62.078" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="N"/>
+ <chemical_shift value="121.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CG1"/>
+ <chemical_shift value="21.509" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="H"/>
+ <chemical_shift value="8.777" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CG2"/>
+ <chemical_shift value="22.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="C"/>
+ <chemical_shift value="171.463" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="H"/>
+ <chemical_shift value="8.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="CA"/>
+ <chemical_shift value="44.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="N"/>
+ <chemical_shift value="116.16" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="261" name="HG21"/>
+ <atom segid=" A" residue="261" name="HG22"/>
+ <atom segid=" A" residue="261" name="HG23"/>
+ <chemical_shift value="0.565" error="0.0"/>
+ <chemical_shift value="0.679" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="261" name="HG11"/>
+ <atom segid=" A" residue="261" name="HG12"/>
+ <atom segid=" A" residue="261" name="HG13"/>
+ <chemical_shift value="0.565" error="0.0"/>
+ <chemical_shift value="0.679" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="C"/>
+ <chemical_shift value="179.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CB"/>
+ <chemical_shift value="32.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CA"/>
+ <chemical_shift value="60.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="N"/>
+ <chemical_shift value="128.971" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CG1"/>
+ <chemical_shift value="20.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="H"/>
+ <chemical_shift value="11.175" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CG2"/>
+ <chemical_shift value="20.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="262" name="HD21"/>
+ <atom segid=" A" residue="262" name="HD22"/>
+ <atom segid=" A" residue="262" name="HD23"/>
+ <chemical_shift value="0.885" error="0.0"/>
+ <chemical_shift value="0.806" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="262" name="HD11"/>
+ <atom segid=" A" residue="262" name="HD12"/>
+ <atom segid=" A" residue="262" name="HD13"/>
+ <chemical_shift value="0.885" error="0.0"/>
+ <chemical_shift value="0.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="C"/>
+ <chemical_shift value="175.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CB"/>
+ <chemical_shift value="41.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CA"/>
+ <chemical_shift value="56.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="N"/>
+ <chemical_shift value="134.056" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CD1"/>
+ <chemical_shift value="22.681" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CD2"/>
+ <chemical_shift value="25.314" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="H"/>
+ <chemical_shift value="8.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="C"/>
+ <chemical_shift value="170.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="CB"/>
+ <chemical_shift value="66.154" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="CA"/>
+ <chemical_shift value="58.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="N"/>
+ <chemical_shift value="126.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="H"/>
+ <chemical_shift value="8.77" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="264" name="HB1"/>
+ <atom segid=" A" residue="264" name="HB2"/>
+ <atom segid=" A" residue="264" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="C"/>
+ <chemical_shift value="176.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="CB"/>
+ <chemical_shift value="20.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="CA"/>
+ <chemical_shift value="49.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="N"/>
+ <chemical_shift value="123.788" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="H"/>
+ <chemical_shift value="9.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="C"/>
+ <chemical_shift value="171.119" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="H"/>
+ <chemical_shift value="9.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="CA"/>
+ <chemical_shift value="42.908" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="N"/>
+ <chemical_shift value="110.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="266" name="HG21"/>
+ <atom segid=" A" residue="266" name="HG22"/>
+ <atom segid=" A" residue="266" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.915" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="266" name="HD11"/>
+ <atom segid=" A" residue="266" name="HD12"/>
+ <atom segid=" A" residue="266" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.915" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="C"/>
+ <chemical_shift value="175.264" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CB"/>
+ <chemical_shift value="39.519" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CA"/>
+ <chemical_shift value="59.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="N"/>
+ <chemical_shift value="123.632" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CD1"/>
+ <chemical_shift value="13.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="H"/>
+ <chemical_shift value="10.299" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="C"/>
+ <chemical_shift value="177.436" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CB"/>
+ <chemical_shift value="38.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CA"/>
+ <chemical_shift value="53.657" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="N"/>
+ <chemical_shift value="125.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="H"/>
+ <chemical_shift value="8.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="268" name="HB1"/>
+ <atom segid=" A" residue="268" name="HB2"/>
+ <atom segid=" A" residue="268" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="C"/>
+ <chemical_shift value="178.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="CB"/>
+ <chemical_shift value="17.854" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="CA"/>
+ <chemical_shift value="55.511" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="N"/>
+ <chemical_shift value="131.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="H"/>
+ <chemical_shift value="8.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="269" name="HB1"/>
+ <atom segid=" A" residue="269" name="HB2"/>
+ <atom segid=" A" residue="269" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="C"/>
+ <chemical_shift value="178.117" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="CB"/>
+ <chemical_shift value="18.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="CA"/>
+ <chemical_shift value="51.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="N"/>
+ <chemical_shift value="117.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="CB"/>
+ <chemical_shift value="64.366" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="CA"/>
+ <chemical_shift value="56.356" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="N"/>
+ <chemical_shift value="112.93" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="H"/>
+ <chemical_shift value="7.621" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="C"/>
+ <chemical_shift value="175.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CB"/>
+ <chemical_shift value="30.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CA"/>
+ <chemical_shift value="63.726" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="C"/>
+ <chemical_shift value="176.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CB"/>
+ <chemical_shift value="40.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CA"/>
+ <chemical_shift value="52.889" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="N"/>
+ <chemical_shift value="119.716" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="H"/>
+ <chemical_shift value="8.881" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="273" name="HZ1"/>
+ <atom segid=" A" residue="273" name="HZ2"/>
+ <atom segid=" A" residue="273" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CB"/>
+ <chemical_shift value="31.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="C"/>
+ <chemical_shift value="179.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="H"/>
+ <chemical_shift value="7.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CA"/>
+ <chemical_shift value="61.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="N"/>
+ <chemical_shift value="119.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="C"/>
+ <chemical_shift value="179.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CB"/>
+ <chemical_shift value="27.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CA"/>
+ <chemical_shift value="59.973" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="N"/>
+ <chemical_shift value="118.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="H"/>
+ <chemical_shift value="8.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="275" name="HD21"/>
+ <atom segid=" A" residue="275" name="HD22"/>
+ <atom segid=" A" residue="275" name="HD23"/>
+ <chemical_shift value="0.947" error="0.0"/>
+ <chemical_shift value="0.933" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="275" name="HD11"/>
+ <atom segid=" A" residue="275" name="HD12"/>
+ <atom segid=" A" residue="275" name="HD13"/>
+ <chemical_shift value="0.947" error="0.0"/>
+ <chemical_shift value="0.933" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="C"/>
+ <chemical_shift value="178.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CB"/>
+ <chemical_shift value="42.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CA"/>
+ <chemical_shift value="57.369" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="N"/>
+ <chemical_shift value="120.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CD1"/>
+ <chemical_shift value="25.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CD2"/>
+ <chemical_shift value="22.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="H"/>
+ <chemical_shift value="7.385" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="276" name="HB1"/>
+ <atom segid=" A" residue="276" name="HB2"/>
+ <atom segid=" A" residue="276" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="C"/>
+ <chemical_shift value="178.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="CB"/>
+ <chemical_shift value="17.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="CA"/>
+ <chemical_shift value="55.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="N"/>
+ <chemical_shift value="120.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="H"/>
+ <chemical_shift value="8.405" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="277" name="HZ1"/>
+ <atom segid=" A" residue="277" name="HZ2"/>
+ <atom segid=" A" residue="277" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CB"/>
+ <chemical_shift value="32.345" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="C"/>
+ <chemical_shift value="177.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="H"/>
+ <chemical_shift value="7.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CA"/>
+ <chemical_shift value="60.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="N"/>
+ <chemical_shift value="118.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="C"/>
+ <chemical_shift value="179.24" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CB"/>
+ <chemical_shift value="29.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CA"/>
+ <chemical_shift value="59.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="N"/>
+ <chemical_shift value="118.647" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="H"/>
+ <chemical_shift value="7.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="279" name="HD1"/>
+ <atom segid=" A" residue="279" name="HD2"/>
+ <atom segid=" A" residue="279" name="HE1"/>
+ <atom segid=" A" residue="279" name="HE2"/>
+ <atom segid=" A" residue="279" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="C"/>
+ <chemical_shift value="177.602" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CB"/>
+ <chemical_shift value="38.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CA"/>
+ <chemical_shift value="61.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="N"/>
+ <chemical_shift value="118.378" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="280" name="HD21"/>
+ <atom segid=" A" residue="280" name="HD22"/>
+ <atom segid=" A" residue="280" name="HD23"/>
+ <chemical_shift value="0.71" error="0.0"/>
+ <chemical_shift value="0.672" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="280" name="HD11"/>
+ <atom segid=" A" residue="280" name="HD12"/>
+ <atom segid=" A" residue="280" name="HD13"/>
+ <chemical_shift value="0.71" error="0.0"/>
+ <chemical_shift value="0.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="C"/>
+ <chemical_shift value="177.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CB"/>
+ <chemical_shift value="40.671" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CA"/>
+ <chemical_shift value="58.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="N"/>
+ <chemical_shift value="120.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CD1"/>
+ <chemical_shift value="25.779" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CD2"/>
+ <chemical_shift value="23.405" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="H"/>
+ <chemical_shift value="8.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="C"/>
+ <chemical_shift value="177.096" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CB"/>
+ <chemical_shift value="29.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CA"/>
+ <chemical_shift value="59.622" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="N"/>
+ <chemical_shift value="112.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="H"/>
+ <chemical_shift value="8.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="C"/>
+ <chemical_shift value="175.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CB"/>
+ <chemical_shift value="38.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CA"/>
+ <chemical_shift value="53.164" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="N"/>
+ <chemical_shift value="108.811" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="H"/>
+ <chemical_shift value="7.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="283" name="HD1"/>
+ <atom segid=" A" residue="283" name="HD2"/>
+ <atom segid=" A" residue="283" name="HE1"/>
+ <atom segid=" A" residue="283" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="C"/>
+ <chemical_shift value="176.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CB"/>
+ <chemical_shift value="38.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CA"/>
+ <chemical_shift value="59.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="N"/>
+ <chemical_shift value="116.373" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="H"/>
+ <chemical_shift value="7.164" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="284" name="HD21"/>
+ <atom segid=" A" residue="284" name="HD22"/>
+ <atom segid=" A" residue="284" name="HD23"/>
+ <chemical_shift value="1.039" error="0.0"/>
+ <chemical_shift value="0.843" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="284" name="HD11"/>
+ <atom segid=" A" residue="284" name="HD12"/>
+ <atom segid=" A" residue="284" name="HD13"/>
+ <chemical_shift value="1.039" error="0.0"/>
+ <chemical_shift value="0.843" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="C"/>
+ <chemical_shift value="176.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CB"/>
+ <chemical_shift value="41.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CA"/>
+ <chemical_shift value="58.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="N"/>
+ <chemical_shift value="121.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CD1"/>
+ <chemical_shift value="23.945" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CD2"/>
+ <chemical_shift value="27.398" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="H"/>
+ <chemical_shift value="8.101" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="285" name="HD21"/>
+ <atom segid=" A" residue="285" name="HD22"/>
+ <atom segid=" A" residue="285" name="HD23"/>
+ <chemical_shift value="1.119" error="0.0"/>
+ <chemical_shift value="1.052" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="285" name="HD11"/>
+ <atom segid=" A" residue="285" name="HD12"/>
+ <atom segid=" A" residue="285" name="HD13"/>
+ <chemical_shift value="1.119" error="0.0"/>
+ <chemical_shift value="1.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="C"/>
+ <chemical_shift value="174.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CB"/>
+ <chemical_shift value="38.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CA"/>
+ <chemical_shift value="54.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="N"/>
+ <chemical_shift value="119.204" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CD1"/>
+ <chemical_shift value="25.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CD2"/>
+ <chemical_shift value="24.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="H"/>
+ <chemical_shift value="7.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="286" name="HG21"/>
+ <atom segid=" A" residue="286" name="HG22"/>
+ <atom segid=" A" residue="286" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="C"/>
+ <chemical_shift value="174.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CB"/>
+ <chemical_shift value="73.569" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CA"/>
+ <chemical_shift value="59.007" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="N"/>
+ <chemical_shift value="108.713" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="H"/>
+ <chemical_shift value="8.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="C"/>
+ <chemical_shift value="177.87" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CB"/>
+ <chemical_shift value="39.534" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CA"/>
+ <chemical_shift value="58.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="N"/>
+ <chemical_shift value="122.217" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="H"/>
+ <chemical_shift value="8.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="C"/>
+ <chemical_shift value="180.161" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CB"/>
+ <chemical_shift value="29.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CA"/>
+ <chemical_shift value="59.339" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="N"/>
+ <chemical_shift value="115.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="H"/>
+ <chemical_shift value="8.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="C"/>
+ <chemical_shift value="175.256" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="H"/>
+ <chemical_shift value="8.328" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="CA"/>
+ <chemical_shift value="46.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="N"/>
+ <chemical_shift value="112.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="290" name="HD21"/>
+ <atom segid=" A" residue="290" name="HD22"/>
+ <atom segid=" A" residue="290" name="HD23"/>
+ <chemical_shift value="0.792" error="0.0"/>
+ <chemical_shift value="1.074" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="290" name="HD11"/>
+ <atom segid=" A" residue="290" name="HD12"/>
+ <atom segid=" A" residue="290" name="HD13"/>
+ <chemical_shift value="0.792" error="0.0"/>
+ <chemical_shift value="1.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="C"/>
+ <chemical_shift value="179.873" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CB"/>
+ <chemical_shift value="41.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CA"/>
+ <chemical_shift value="57.262" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="N"/>
+ <chemical_shift value="119.553" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CD1"/>
+ <chemical_shift value="27.886" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CD2"/>
+ <chemical_shift value="21.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="H"/>
+ <chemical_shift value="8.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="C"/>
+ <chemical_shift value="178.136" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CB"/>
+ <chemical_shift value="29.033" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CA"/>
+ <chemical_shift value="59.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="N"/>
+ <chemical_shift value="120.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="H"/>
+ <chemical_shift value="7.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="292" name="HB1"/>
+ <atom segid=" A" residue="292" name="HB2"/>
+ <atom segid=" A" residue="292" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="C"/>
+ <chemical_shift value="180.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="CB"/>
+ <chemical_shift value="17.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="CA"/>
+ <chemical_shift value="55.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="N"/>
+ <chemical_shift value="119.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="H"/>
+ <chemical_shift value="7.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="293" name="HG21"/>
+ <atom segid=" A" residue="293" name="HG22"/>
+ <atom segid=" A" residue="293" name="HG23"/>
+ <chemical_shift value="0.901" error="0.0"/>
+ <chemical_shift value="1.004" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="293" name="HG11"/>
+ <atom segid=" A" residue="293" name="HG12"/>
+ <atom segid=" A" residue="293" name="HG13"/>
+ <chemical_shift value="0.901" error="0.0"/>
+ <chemical_shift value="1.004" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="C"/>
+ <chemical_shift value="177.079" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CB"/>
+ <chemical_shift value="32.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CA"/>
+ <chemical_shift value="67.318" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="N"/>
+ <chemical_shift value="115.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CG1"/>
+ <chemical_shift value="21.422" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="H"/>
+ <chemical_shift value="7.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CG2"/>
+ <chemical_shift value="22.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="C"/>
+ <chemical_shift value="176.45" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CB"/>
+ <chemical_shift value="40.911" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CA"/>
+ <chemical_shift value="56.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="N"/>
+ <chemical_shift value="117.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="H"/>
+ <chemical_shift value="8.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="295" name="HZ1"/>
+ <atom segid=" A" residue="295" name="HZ2"/>
+ <atom segid=" A" residue="295" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CB"/>
+ <chemical_shift value="31.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="C"/>
+ <chemical_shift value="177.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CA"/>
+ <chemical_shift value="58.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="N"/>
+ <chemical_shift value="115.927" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="C"/>
+ <chemical_shift value="176.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CB"/>
+ <chemical_shift value="41.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CA"/>
+ <chemical_shift value="56.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="N"/>
+ <chemical_shift value="118.991" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="H"/>
+ <chemical_shift value="7.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="297" name="HZ1"/>
+ <atom segid=" A" residue="297" name="HZ2"/>
+ <atom segid=" A" residue="297" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CB"/>
+ <chemical_shift value="34.952" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="H"/>
+ <chemical_shift value="7.654" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CA"/>
+ <chemical_shift value="52.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="N"/>
+ <chemical_shift value="115.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="178.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="31.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CA"/>
+ <chemical_shift value="63.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="299" name="HD22"/>
+ <atom segid=" A" residue="299" name="HD23"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="299" name="HD11"/>
+ <atom segid=" A" residue="299" name="HD12"/>
+ <atom segid=" A" residue="299" name="HD13"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="C"/>
+ <chemical_shift value="177.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CB"/>
+ <chemical_shift value="43.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CA"/>
+ <chemical_shift value="55.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="N"/>
+ <chemical_shift value="121.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CD1"/>
+ <chemical_shift value="26.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CD2"/>
+ <chemical_shift value="22.958" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="H"/>
+ <chemical_shift value="8.532" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="C"/>
+ <chemical_shift value="174.043" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="H"/>
+ <chemical_shift value="8.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="CA"/>
+ <chemical_shift value="44.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="N"/>
+ <chemical_shift value="103.351" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="301" name="HB1"/>
+ <atom segid=" A" residue="301" name="HB2"/>
+ <atom segid=" A" residue="301" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="C"/>
+ <chemical_shift value="177.667" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="CB"/>
+ <chemical_shift value="19.844" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="CA"/>
+ <chemical_shift value="51.558" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="N"/>
+ <chemical_shift value="123.834" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="H"/>
+ <chemical_shift value="7.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
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+ <atom segid=" A" residue="302" name="HG21"/>
+ <atom segid=" A" residue="302" name="HG22"/>
+ <atom segid=" A" residue="302" name="HG23"/>
+ <chemical_shift value="1.262" error="0.0"/>
+ <chemical_shift value="1.059" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="302" name="HG11"/>
+ <atom segid=" A" residue="302" name="HG12"/>
+ <atom segid=" A" residue="302" name="HG13"/>
+ <chemical_shift value="1.262" error="0.0"/>
+ <chemical_shift value="1.059" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="C"/>
+ <chemical_shift value="174.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CB"/>
+ <chemical_shift value="35.614" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CA"/>
+ <chemical_shift value="59.9" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="N"/>
+ <chemical_shift value="110.163" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CG1"/>
+ <chemical_shift value="22.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="H"/>
+ <chemical_shift value="8.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CG2"/>
+ <chemical_shift value="19.07" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="303" name="HB1"/>
+ <atom segid=" A" residue="303" name="HB2"/>
+ <atom segid=" A" residue="303" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="C"/>
+ <chemical_shift value="175.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="CB"/>
+ <chemical_shift value="19.491" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="CA"/>
+ <chemical_shift value="53.039" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="N"/>
+ <chemical_shift value="117.932" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="H"/>
+ <chemical_shift value="7.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="304" name="HD21"/>
+ <atom segid=" A" residue="304" name="HD22"/>
+ <atom segid=" A" residue="304" name="HD23"/>
+ <chemical_shift value="0.702" error="0.0"/>
+ <chemical_shift value="0.848" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="304" name="HD11"/>
+ <atom segid=" A" residue="304" name="HD12"/>
+ <atom segid=" A" residue="304" name="HD13"/>
+ <chemical_shift value="0.702" error="0.0"/>
+ <chemical_shift value="0.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="C"/>
+ <chemical_shift value="175.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CB"/>
+ <chemical_shift value="44.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CA"/>
+ <chemical_shift value="54.335" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="N"/>
+ <chemical_shift value="114.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CD1"/>
+ <chemical_shift value="24.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CD2"/>
+ <chemical_shift value="26.586" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="H"/>
+ <chemical_shift value="6.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="305" name="HZ1"/>
+ <atom segid=" A" residue="305" name="HZ2"/>
+ <atom segid=" A" residue="305" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CB"/>
+ <chemical_shift value="31.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="C"/>
+ <chemical_shift value="178.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="H"/>
+ <chemical_shift value="8.043" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CA"/>
+ <chemical_shift value="60.428" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="N"/>
+ <chemical_shift value="129.631" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="C"/>
+ <chemical_shift value="176.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="CB"/>
+ <chemical_shift value="60.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="CA"/>
+ <chemical_shift value="61.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="N"/>
+ <chemical_shift value="111.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="H"/>
+ <chemical_shift value="8.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="307" name="HD1"/>
+ <atom segid=" A" residue="307" name="HD2"/>
+ <atom segid=" A" residue="307" name="HE1"/>
+ <atom segid=" A" residue="307" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="C"/>
+ <chemical_shift value="177.811" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CB"/>
+ <chemical_shift value="38.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CA"/>
+ <chemical_shift value="58.904" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="N"/>
+ <chemical_shift value="122.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="H"/>
+ <chemical_shift value="6.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="C"/>
+ <chemical_shift value="177.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CB"/>
+ <chemical_shift value="26.173" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CA"/>
+ <chemical_shift value="58.466" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="N"/>
+ <chemical_shift value="122.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="H"/>
+ <chemical_shift value="8.473" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="C"/>
+ <chemical_shift value="178.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CB"/>
+ <chemical_shift value="28.862" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CA"/>
+ <chemical_shift value="58.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="N"/>
+ <chemical_shift value="114.962" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="H"/>
+ <chemical_shift value="7.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="C"/>
+ <chemical_shift value="178.868" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CB"/>
+ <chemical_shift value="29.333" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CA"/>
+ <chemical_shift value="57.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="N"/>
+ <chemical_shift value="116.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="H"/>
+ <chemical_shift value="7.092" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="311" name="HD21"/>
+ <atom segid=" A" residue="311" name="HD22"/>
+ <atom segid=" A" residue="311" name="HD23"/>
+ <chemical_shift value="0.797" error="0.0"/>
+ <chemical_shift value="0.87" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="311" name="HD11"/>
+ <atom segid=" A" residue="311" name="HD12"/>
+ <atom segid=" A" residue="311" name="HD13"/>
+ <chemical_shift value="0.797" error="0.0"/>
+ <chemical_shift value="0.87" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="C"/>
+ <chemical_shift value="179.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CB"/>
+ <chemical_shift value="41.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CA"/>
+ <chemical_shift value="57.324" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="N"/>
+ <chemical_shift value="120.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CD1"/>
+ <chemical_shift value="26.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CD2"/>
+ <chemical_shift value="22.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="H"/>
+ <chemical_shift value="8.021" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="312" name="HB1"/>
+ <atom segid=" A" residue="312" name="HB2"/>
+ <atom segid=" A" residue="312" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="C"/>
+ <chemical_shift value="174.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="CB"/>
+ <chemical_shift value="17.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="CA"/>
+ <chemical_shift value="54.037" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="N"/>
+ <chemical_shift value="114.676" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="H"/>
+ <chemical_shift value="8.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="313" name="HZ1"/>
+ <atom segid=" A" residue="313" name="HZ2"/>
+ <atom segid=" A" residue="313" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CB"/>
+ <chemical_shift value="31.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="C"/>
+ <chemical_shift value="177.97" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="H"/>
+ <chemical_shift value="6.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CA"/>
+ <chemical_shift value="58.418" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="N"/>
+ <chemical_shift value="119.315" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CB"/>
+ <chemical_shift value="41.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CA"/>
+ <chemical_shift value="50.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="N"/>
+ <chemical_shift value="121.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="H"/>
+ <chemical_shift value="8.311" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="C"/>
+ <chemical_shift value="179.227" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CB"/>
+ <chemical_shift value="32.168" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CA"/>
+ <chemical_shift value="64.525" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CB"/>
+ <chemical_shift value="29.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="C"/>
+ <chemical_shift value="179.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="H"/>
+ <chemical_shift value="8.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CA"/>
+ <chemical_shift value="58.813" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="N"/>
+ <chemical_shift value="116.913" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="317" name="HG21"/>
+ <atom segid=" A" residue="317" name="HG22"/>
+ <atom segid=" A" residue="317" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="1.118" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="317" name="HD11"/>
+ <atom segid=" A" residue="317" name="HD12"/>
+ <atom segid=" A" residue="317" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="1.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="C"/>
+ <chemical_shift value="178.067" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CB"/>
+ <chemical_shift value="35.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CA"/>
+ <chemical_shift value="64.418" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="N"/>
+ <chemical_shift value="123.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CD1"/>
+ <chemical_shift value="12.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="H"/>
+ <chemical_shift value="7.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="318" name="HB1"/>
+ <atom segid=" A" residue="318" name="HB2"/>
+ <atom segid=" A" residue="318" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="C"/>
+ <chemical_shift value="181.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="CB"/>
+ <chemical_shift value="17.268" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="CA"/>
+ <chemical_shift value="56.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="N"/>
+ <chemical_shift value="123.335" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="H"/>
+ <chemical_shift value="7.906" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="319" name="HB1"/>
+ <atom segid=" A" residue="319" name="HB2"/>
+ <atom segid=" A" residue="319" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="C"/>
+ <chemical_shift value="178.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="CB"/>
+ <chemical_shift value="17.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="CA"/>
+ <chemical_shift value="55.519" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="N"/>
+ <chemical_shift value="118.979" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="H"/>
+ <chemical_shift value="8.086" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="320" name="HG21"/>
+ <atom segid=" A" residue="320" name="HG22"/>
+ <atom segid=" A" residue="320" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="C"/>
+ <chemical_shift value="175.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="CB"/>
+ <chemical_shift value="69.151" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="CA"/>
+ <chemical_shift value="67.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="N"/>
+ <chemical_shift value="114.58" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="H"/>
+ <chemical_shift value="7.358" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="321" name="HE1"/>
+ <atom segid=" A" residue="321" name="HE2"/>
+ <atom segid=" A" residue="321" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="C"/>
+ <chemical_shift value="177.825" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CB"/>
+ <chemical_shift value="30.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CA"/>
+ <chemical_shift value="56.766" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="N"/>
+ <chemical_shift value="118.804" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="H"/>
+ <chemical_shift value="8.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="C"/>
+ <chemical_shift value="179.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CB"/>
+ <chemical_shift value="28.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CA"/>
+ <chemical_shift value="59.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="N"/>
+ <chemical_shift value="122.177" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="H"/>
+ <chemical_shift value="8.267" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="CB"/>
+ <chemical_shift value="39.313" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="CA"/>
+ <chemical_shift value="57.124" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="N"/>
+ <chemical_shift value="115.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="H"/>
+ <chemical_shift value="8.207" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="324" name="HB1"/>
+ <atom segid=" A" residue="324" name="HB2"/>
+ <atom segid=" A" residue="324" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="C"/>
+ <chemical_shift value="180.381" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="CB"/>
+ <chemical_shift value="17.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="CA"/>
+ <chemical_shift value="54.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="N"/>
+ <chemical_shift value="119.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="H"/>
+ <chemical_shift value="8.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="C"/>
+ <chemical_shift value="177.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CB"/>
+ <chemical_shift value="27.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CA"/>
+ <chemical_shift value="58.414" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="N"/>
+ <chemical_shift value="116.35" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="H"/>
+ <chemical_shift value="8.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="326" name="HZ1"/>
+ <atom segid=" A" residue="326" name="HZ2"/>
+ <atom segid=" A" residue="326" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CB"/>
+ <chemical_shift value="32.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="C"/>
+ <chemical_shift value="176.163" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="H"/>
+ <chemical_shift value="7.079" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CA"/>
+ <chemical_shift value="56.011" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="N"/>
+ <chemical_shift value="117.692" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="C"/>
+ <chemical_shift value="172.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="H"/>
+ <chemical_shift value="7.293" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="CA"/>
+ <chemical_shift value="44.518" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="N"/>
+ <chemical_shift value="106.636" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="C"/>
+ <chemical_shift value="176.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CB"/>
+ <chemical_shift value="32.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CA"/>
+ <chemical_shift value="54.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="N"/>
+ <chemical_shift value="121.098" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="H"/>
+ <chemical_shift value="8.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="329" name="HG21"/>
+ <atom segid=" A" residue="329" name="HG22"/>
+ <atom segid=" A" residue="329" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.821" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="329" name="HD11"/>
+ <atom segid=" A" residue="329" name="HD12"/>
+ <atom segid=" A" residue="329" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="C"/>
+ <chemical_shift value="178.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CB"/>
+ <chemical_shift value="37.812" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CA"/>
+ <chemical_shift value="62.15" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="N"/>
+ <chemical_shift value="127.522" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CD1"/>
+ <chemical_shift value="12.362" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="H"/>
+ <chemical_shift value="9.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="330" name="HE1"/>
+ <atom segid=" A" residue="330" name="HE2"/>
+ <atom segid=" A" residue="330" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CB"/>
+ <chemical_shift value="34.295" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CA"/>
+ <chemical_shift value="56.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="N"/>
+ <chemical_shift value="124.379" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="H"/>
+ <chemical_shift value="8.502" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="C"/>
+ <chemical_shift value="175.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CB"/>
+ <chemical_shift value="31.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CA"/>
+ <chemical_shift value="63.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="C"/>
+ <chemical_shift value="175.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CB"/>
+ <chemical_shift value="38.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CA"/>
+ <chemical_shift value="51.443" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="N"/>
+ <chemical_shift value="117.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="H"/>
+ <chemical_shift value="7.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="333" name="HG21"/>
+ <atom segid=" A" residue="333" name="HG22"/>
+ <atom segid=" A" residue="333" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="-0.138" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="333" name="HD11"/>
+ <atom segid=" A" residue="333" name="HD12"/>
+ <atom segid=" A" residue="333" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="-0.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CB"/>
+ <chemical_shift value="36.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CA"/>
+ <chemical_shift value="59.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="N"/>
+ <chemical_shift value="108.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CD1"/>
+ <chemical_shift value="12.253" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="H"/>
+ <chemical_shift value="6.382" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="C"/>
+ <chemical_shift value="178.686" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CB"/>
+ <chemical_shift value="31.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CA"/>
+ <chemical_shift value="65.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="C"/>
+ <chemical_shift value="177.018" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CB"/>
+ <chemical_shift value="26.389" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CA"/>
+ <chemical_shift value="59.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="N"/>
+ <chemical_shift value="116.31" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="336" name="HE1"/>
+ <atom segid=" A" residue="336" name="HE2"/>
+ <atom segid=" A" residue="336" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="C"/>
+ <chemical_shift value="177.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CB"/>
+ <chemical_shift value="30.289" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CA"/>
+ <chemical_shift value="56.084" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="N"/>
+ <chemical_shift value="118.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="H"/>
+ <chemical_shift value="7.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="C"/>
+ <chemical_shift value="177.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="CB"/>
+ <chemical_shift value="60.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="CA"/>
+ <chemical_shift value="62.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="N"/>
+ <chemical_shift value="113.543" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="H"/>
+ <chemical_shift value="7.924" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="338" name="HB1"/>
+ <atom segid=" A" residue="338" name="HB2"/>
+ <atom segid=" A" residue="338" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="C"/>
+ <chemical_shift value="180.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="CB"/>
+ <chemical_shift value="18.545" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="CA"/>
+ <chemical_shift value="54.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="N"/>
+ <chemical_shift value="122.856" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="H"/>
+ <chemical_shift value="7.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="339" name="HD1"/>
+ <atom segid=" A" residue="339" name="HD2"/>
+ <atom segid=" A" residue="339" name="HE1"/>
+ <atom segid=" A" residue="339" name="HE2"/>
+ <atom segid=" A" residue="339" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="C"/>
+ <chemical_shift value="176.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CB"/>
+ <chemical_shift value="38.827" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CA"/>
+ <chemical_shift value="61.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="N"/>
+ <chemical_shift value="118.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="H"/>
+ <chemical_shift value="7.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="H"/>
+ <chemical_shift value="8.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="C"/>
+ <chemical_shift value="179.128" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CB"/>
+ <chemical_shift value="30.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CA"/>
+ <chemical_shift value="59.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="N"/>
+ <chemical_shift value="118.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="341" name="HD1"/>
+ <atom segid=" A" residue="341" name="HD2"/>
+ <atom segid=" A" residue="341" name="HE1"/>
+ <atom segid=" A" residue="341" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="C"/>
+ <chemical_shift value="178.712" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CB"/>
+ <chemical_shift value="38.306" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CA"/>
+ <chemical_shift value="61.558" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="N"/>
+ <chemical_shift value="114.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="H"/>
+ <chemical_shift value="7.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="342" name="HB1"/>
+ <atom segid=" A" residue="342" name="HB2"/>
+ <atom segid=" A" residue="342" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="C"/>
+ <chemical_shift value="180.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="CB"/>
+ <chemical_shift value="19.012" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="CA"/>
+ <chemical_shift value="55.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="N"/>
+ <chemical_shift value="121.914" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="H"/>
+ <chemical_shift value="8.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="343" name="HG21"/>
+ <atom segid=" A" residue="343" name="HG22"/>
+ <atom segid=" A" residue="343" name="HG23"/>
+ <chemical_shift value="0.168" error="0.0"/>
+ <chemical_shift value="0.863" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="343" name="HG11"/>
+ <atom segid=" A" residue="343" name="HG12"/>
+ <atom segid=" A" residue="343" name="HG13"/>
+ <chemical_shift value="0.168" error="0.0"/>
+ <chemical_shift value="0.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="C"/>
+ <chemical_shift value="177.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CB"/>
+ <chemical_shift value="31.022" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CA"/>
+ <chemical_shift value="66.924" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="N"/>
+ <chemical_shift value="118.57" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CG1"/>
+ <chemical_shift value="21.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="H"/>
+ <chemical_shift value="8.63" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CG2"/>
+ <chemical_shift value="23.236" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CB"/>
+ <chemical_shift value="29.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="C"/>
+ <chemical_shift value="178.506" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="H"/>
+ <chemical_shift value="8.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CA"/>
+ <chemical_shift value="60.236" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="N"/>
+ <chemical_shift value="120.769" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="345" name="HG21"/>
+ <atom segid=" A" residue="345" name="HG22"/>
+ <atom segid=" A" residue="345" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="C"/>
+ <chemical_shift value="175.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CB"/>
+ <chemical_shift value="69.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CA"/>
+ <chemical_shift value="66.564" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="N"/>
+ <chemical_shift value="113.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="H"/>
+ <chemical_shift value="7.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="346" name="HB1"/>
+ <atom segid=" A" residue="346" name="HB2"/>
+ <atom segid=" A" residue="346" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="C"/>
+ <chemical_shift value="179.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="CB"/>
+ <chemical_shift value="18.537" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="CA"/>
+ <chemical_shift value="55.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="N"/>
+ <chemical_shift value="122.933" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="H"/>
+ <chemical_shift value="7.805" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="347" name="HG21"/>
+ <atom segid=" A" residue="347" name="HG22"/>
+ <atom segid=" A" residue="347" name="HG23"/>
+ <chemical_shift value="1.043" error="0.0"/>
+ <chemical_shift value="0.918" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="347" name="HG11"/>
+ <atom segid=" A" residue="347" name="HG12"/>
+ <atom segid=" A" residue="347" name="HG13"/>
+ <chemical_shift value="1.043" error="0.0"/>
+ <chemical_shift value="0.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="C"/>
+ <chemical_shift value="178.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CB"/>
+ <chemical_shift value="31.336" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CA"/>
+ <chemical_shift value="67.494" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="N"/>
+ <chemical_shift value="115.988" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CG1"/>
+ <chemical_shift value="20.468" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CG2"/>
+ <chemical_shift value="22.282" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="348" name="HG21"/>
+ <atom segid=" A" residue="348" name="HG22"/>
+ <atom segid=" A" residue="348" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.869" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="348" name="HD11"/>
+ <atom segid=" A" residue="348" name="HD12"/>
+ <atom segid=" A" residue="348" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.869" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="C"/>
+ <chemical_shift value="180.338" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CB"/>
+ <chemical_shift value="37.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CA"/>
+ <chemical_shift value="65.054" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="N"/>
+ <chemical_shift value="118.38" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CD1"/>
+ <chemical_shift value="12.965" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="H"/>
+ <chemical_shift value="7.771" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="C"/>
+ <chemical_shift value="178.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CB"/>
+ <chemical_shift value="37.166" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CA"/>
+ <chemical_shift value="55.948" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="N"/>
+ <chemical_shift value="121.103" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="H"/>
+ <chemical_shift value="8.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="350" name="HB1"/>
+ <atom segid=" A" residue="350" name="HB2"/>
+ <atom segid=" A" residue="350" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="C"/>
+ <chemical_shift value="181.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="CB"/>
+ <chemical_shift value="17.998" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="CA"/>
+ <chemical_shift value="54.159" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="N"/>
+ <chemical_shift value="122.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="H"/>
+ <chemical_shift value="8.52" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="351" name="HB1"/>
+ <atom segid=" A" residue="351" name="HB2"/>
+ <atom segid=" A" residue="351" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="C"/>
+ <chemical_shift value="178.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="CB"/>
+ <chemical_shift value="18.028" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="CA"/>
+ <chemical_shift value="55.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="N"/>
+ <chemical_shift value="121.112" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="H"/>
+ <chemical_shift value="9.165" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="C"/>
+ <chemical_shift value="175.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="CB"/>
+ <chemical_shift value="64.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="CA"/>
+ <chemical_shift value="58.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="N"/>
+ <chemical_shift value="107.997" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="H"/>
+ <chemical_shift value="7.88" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="C"/>
+ <chemical_shift value="174.546" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="H"/>
+ <chemical_shift value="7.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="CA"/>
+ <chemical_shift value="45.785" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="N"/>
+ <chemical_shift value="109.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CB"/>
+ <chemical_shift value="30.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="C"/>
+ <chemical_shift value="176.819" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="H"/>
+ <chemical_shift value="8.225" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CA"/>
+ <chemical_shift value="58.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="N"/>
+ <chemical_shift value="121.096" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="C"/>
+ <chemical_shift value="176.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CB"/>
+ <chemical_shift value="36.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CA"/>
+ <chemical_shift value="54.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="N"/>
+ <chemical_shift value="113.634" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="H"/>
+ <chemical_shift value="7.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="356" name="HG21"/>
+ <atom segid=" A" residue="356" name="HG22"/>
+ <atom segid=" A" residue="356" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="C"/>
+ <chemical_shift value="174.887" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CB"/>
+ <chemical_shift value="70.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CA"/>
+ <chemical_shift value="61.464" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="N"/>
+ <chemical_shift value="111.798" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="H"/>
+ <chemical_shift value="8.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="357" name="HG21"/>
+ <atom segid=" A" residue="357" name="HG22"/>
+ <atom segid=" A" residue="357" name="HG23"/>
+ <chemical_shift value="1.045" error="0.0"/>
+ <chemical_shift value="0.991" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="357" name="HG11"/>
+ <atom segid=" A" residue="357" name="HG12"/>
+ <atom segid=" A" residue="357" name="HG13"/>
+ <chemical_shift value="1.045" error="0.0"/>
+ <chemical_shift value="0.991" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="C"/>
+ <chemical_shift value="177.155" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CB"/>
+ <chemical_shift value="31.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CA"/>
+ <chemical_shift value="67.861" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="N"/>
+ <chemical_shift value="121.363" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CG1"/>
+ <chemical_shift value="21.315" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="H"/>
+ <chemical_shift value="8.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CG2"/>
+ <chemical_shift value="23.401" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="C"/>
+ <chemical_shift value="178.907" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CB"/>
+ <chemical_shift value="40.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CA"/>
+ <chemical_shift value="57.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="N"/>
+ <chemical_shift value="115.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="H"/>
+ <chemical_shift value="8.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="C"/>
+ <chemical_shift value="178.618" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CB"/>
+ <chemical_shift value="29.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CA"/>
+ <chemical_shift value="58.759" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="N"/>
+ <chemical_shift value="118.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="H"/>
+ <chemical_shift value="7.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="360" name="HB1"/>
+ <atom segid=" A" residue="360" name="HB2"/>
+ <atom segid=" A" residue="360" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="C"/>
+ <chemical_shift value="181.584" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="CB"/>
+ <chemical_shift value="18.27" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="CA"/>
+ <chemical_shift value="54.768" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="N"/>
+ <chemical_shift value="121.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="H"/>
+ <chemical_shift value="8.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="361" name="HD21"/>
+ <atom segid=" A" residue="361" name="HD22"/>
+ <atom segid=" A" residue="361" name="HD23"/>
+ <chemical_shift value="0.722" error="0.0"/>
+ <chemical_shift value="0.892" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="361" name="HD11"/>
+ <atom segid=" A" residue="361" name="HD12"/>
+ <atom segid=" A" residue="361" name="HD13"/>
+ <chemical_shift value="0.722" error="0.0"/>
+ <chemical_shift value="0.892" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="C"/>
+ <chemical_shift value="178.899" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CB"/>
+ <chemical_shift value="39.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CA"/>
+ <chemical_shift value="57.465" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="N"/>
+ <chemical_shift value="116.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CD1"/>
+ <chemical_shift value="25.264" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CD2"/>
+ <chemical_shift value="19.605" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="H"/>
+ <chemical_shift value="8.078" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="362" name="HZ1"/>
+ <atom segid=" A" residue="362" name="HZ2"/>
+ <atom segid=" A" residue="362" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CB"/>
+ <chemical_shift value="31.531" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="C"/>
+ <chemical_shift value="179.903" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="H"/>
+ <chemical_shift value="7.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CA"/>
+ <chemical_shift value="59.792" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="N"/>
+ <chemical_shift value="121.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="C"/>
+ <chemical_shift value="178.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CB"/>
+ <chemical_shift value="40.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CA"/>
+ <chemical_shift value="57.231" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="N"/>
+ <chemical_shift value="120.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="H"/>
+ <chemical_shift value="8.145" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="364" name="HB1"/>
+ <atom segid=" A" residue="364" name="HB2"/>
+ <atom segid=" A" residue="364" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="C"/>
+ <chemical_shift value="178.422" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="CB"/>
+ <chemical_shift value="17.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="CA"/>
+ <chemical_shift value="55.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="N"/>
+ <chemical_shift value="121.446" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="H"/>
+ <chemical_shift value="7.735" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="C"/>
+ <chemical_shift value="179.207" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CB"/>
+ <chemical_shift value="27.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CA"/>
+ <chemical_shift value="60.224" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="N"/>
+ <chemical_shift value="118.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="H"/>
+ <chemical_shift value="8.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="366" name="HG21"/>
+ <atom segid=" A" residue="366" name="HG22"/>
+ <atom segid=" A" residue="366" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="C"/>
+ <chemical_shift value="175.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CB"/>
+ <chemical_shift value="69.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CA"/>
+ <chemical_shift value="66.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="N"/>
+ <chemical_shift value="115.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="H"/>
+ <chemical_shift value="8.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CB"/>
+ <chemical_shift value="29.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="C"/>
+ <chemical_shift value="178.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="H"/>
+ <chemical_shift value="7.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CA"/>
+ <chemical_shift value="58.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="N"/>
+ <chemical_shift value="120.123" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="368" name="HG21"/>
+ <atom segid=" A" residue="368" name="HG22"/>
+ <atom segid=" A" residue="368" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.693" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="368" name="HD11"/>
+ <atom segid=" A" residue="368" name="HD12"/>
+ <atom segid=" A" residue="368" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.693" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="C"/>
+ <chemical_shift value="177.188" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CB"/>
+ <chemical_shift value="38.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CA"/>
+ <chemical_shift value="65.05" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="N"/>
+ <chemical_shift value="117.397" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CD1"/>
+ <chemical_shift value="15.285" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="H"/>
+ <chemical_shift value="8.005" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="369" name="HG21"/>
+ <atom segid=" A" residue="369" name="HG22"/>
+ <atom segid=" A" residue="369" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="C"/>
+ <chemical_shift value="174.309" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CB"/>
+ <chemical_shift value="70.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CA"/>
+ <chemical_shift value="62.641" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="N"/>
+ <chemical_shift value="107.043" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="H"/>
+ <chemical_shift value="7.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="370" name="HZ1"/>
+ <atom segid=" A" residue="370" name="HZ2"/>
+ <atom segid=" A" residue="370" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="O'"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="O''"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CB"/>
+ <chemical_shift value="32.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="H"/>
+ <chemical_shift value="7.399" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CA"/>
+ <chemical_shift value="59.013" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="N"/>
+ <chemical_shift value="128.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+</chemical_shift_list>
\ No newline at end of file
diff --git a/docs/examples/malecoli/data/xml/cc20_peaks.xml b/docs/examples/malecoli/data/xml/cc20_peaks.xml
new file mode 100644
index 0000000000000000000000000000000000000000..e022482682801cc0d4f0e7b034644010f0ff9de4
--- /dev/null
+++ b/docs/examples/malecoli/data/xml/cc20_peaks.xml
@@ -0,0 +1,10307 @@
+<!DOCTYPE spectrum SYSTEM "noesy_spectrum1.0.dtd">
+<spectrum name="cc20">
+ <peak number="1" reliable="no" ambiguity="">
+ <volume value="13600000.0" error="0"/>
+ <intensity value="13600000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.403" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="13.062" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="13.06" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2" reliable="no" ambiguity="">
+ <volume value="112000.0" error="0"/>
+ <intensity value="112000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.404" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="21.519" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="13.012" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="3" reliable="no" ambiguity="">
+ <volume value="4010000.0" error="0"/>
+ <intensity value="4010000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="-0.3" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="25.093" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="25.079" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="4" reliable="no" ambiguity="">
+ <volume value="759000.0" error="0"/>
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+ </hetero1>
+ <hetero2>
+ <shift value="12.49" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="617" reliable="no" ambiguity="">
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+ <proton1>
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+ </proton2>
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+ </hetero1>
+ <hetero2>
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+ </hetero2>
+ </peak>
+ <peak number="618" reliable="no" ambiguity="">
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+ <intensity value="282000.0" error="0"/>
+ <proton1>
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+ </proton1>
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+ </proton2>
+ <hetero1>
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+ </hetero1>
+ <hetero2>
+ <shift value="13.077" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="619" reliable="no" ambiguity="">
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+ <proton1>
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+ </proton1>
+ <proton2>
+ <shift value="0.722" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="23.577" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="19.638" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="620" reliable="no" ambiguity="">
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+ <intensity value="731000.0" error="0"/>
+ <proton1>
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+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
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+ </hetero1>
+ <hetero2>
+ <shift value="12.385" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="621" reliable="no" ambiguity="">
+ <volume value="1740000.0" error="0"/>
+ <intensity value="1740000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
+ <shift value="21.939" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="19.055" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="622" reliable="no" ambiguity="">
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+ <proton1>
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+ </proton1>
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+ </proton2>
+ <hetero1>
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+ </hetero1>
+ <hetero2>
+ <shift value="13.062" error=""/>
+ </hetero2>
+ </peak>
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+ <intensity value="582000.0" error="0"/>
+ <proton1>
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+ </proton1>
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+ </proton2>
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+ </hetero1>
+ <hetero2>
+ <shift value="13.767" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="624" reliable="no" ambiguity="">
+ <volume value="835000.0" error="0"/>
+ <intensity value="835000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
+ <shift value="23.366" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="13.806" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="625" reliable="no" ambiguity="">
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+ <intensity value="11400000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
+ <shift value="14.231" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="14.203" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="626" reliable="no" ambiguity="">
+ <volume value="1750000.0" error="0"/>
+ <intensity value="1750000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
+ <shift value="23.328" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="22.321" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="627" reliable="no" ambiguity="">
+ <volume value="16200000.0" error="0"/>
+ <intensity value="16200000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.836" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="22.409" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="22.379" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="628" reliable="no" ambiguity="">
+ <volume value="1110000.0" error="0"/>
+ <intensity value="1110000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
+ <shift value="21.498" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="22.382" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="629" reliable="no" ambiguity="">
+ <volume value="182000.0" error="0"/>
+ <intensity value="182000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.691" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="25.692" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="26.857" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="630" reliable="no" ambiguity="">
+ <volume value="168000.0" error="0"/>
+ <intensity value="168000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.691" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="24.284" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="26.798" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="631" reliable="no" ambiguity="">
+ <volume value="120000.0" error="0"/>
+ <intensity value="120000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.636" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="13.331" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="21.615" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="632" reliable="no" ambiguity="">
+ <volume value="98100.0" error="0"/>
+ <intensity value="98100.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.636" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="20.274" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="21.557" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="633" reliable="no" ambiguity="">
+ <volume value="152000.0" error="0"/>
+ <intensity value="152000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.585" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="12.581" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="20.931" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="634" reliable="no" ambiguity="">
+ <volume value="204000.0" error="0"/>
+ <intensity value="204000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.585" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="20.248" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="20.853" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="635" reliable="no" ambiguity="">
+ <volume value="795000.0" error="0"/>
+ <intensity value="795000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.759" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="25.196" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="22.339" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="636" reliable="no" ambiguity="">
+ <volume value="12800000.0" error="0"/>
+ <intensity value="12800000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.759" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="22.336" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="22.297" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="637" reliable="no" ambiguity="">
+ <volume value="451000.0" error="0"/>
+ <intensity value="451000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.759" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="24.018" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="22.317" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="638" reliable="no" ambiguity="">
+ <volume value="3360000.0" error="0"/>
+ <intensity value="3360000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.759" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="20.713" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="22.297" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="639" reliable="no" ambiguity="">
+ <volume value="284000.0" error="0"/>
+ <intensity value="284000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.759" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="14.513" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="22.336" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="640" reliable="no" ambiguity="">
+ <volume value="127000.0" error="0"/>
+ <intensity value="127000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.821" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="19.133" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="12.345" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="641" reliable="no" ambiguity="">
+ <volume value="789000.0" error="0"/>
+ <intensity value="789000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.792" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="20.874" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="21.823" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="642" reliable="no" ambiguity="">
+ <volume value="103000.0" error="0"/>
+ <intensity value="103000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.585" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="24.726" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="20.892" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="643" reliable="no" ambiguity="">
+ <volume value="126000.0" error="0"/>
+ <intensity value="126000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.585" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="22.751" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="20.892" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="644" reliable="no" ambiguity="">
+ <volume value="133000.0" error="0"/>
+ <intensity value="133000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.792" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="24.747" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="21.901" error=""/>
+ </hetero2>
+ </peak>
+</spectrum>
\ No newline at end of file
diff --git a/docs/examples/malecoli/data/xml/cn0_cs.xml b/docs/examples/malecoli/data/xml/cn0_cs.xml
new file mode 100644
index 0000000000000000000000000000000000000000..bcb3d46b809ec3f250726022e42af6cd1ed9b115
--- /dev/null
+++ b/docs/examples/malecoli/data/xml/cn0_cs.xml
@@ -0,0 +1,31373 @@
+<!DOCTYPE chemical_shift_list SYSTEM "chemical_shift_list1.0.dtd">
+<chemical_shift_list>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="1" name="HZ1"/>
+ <atom segid=" A" residue="1" name="HZ2"/>
+ <atom segid=" A" residue="1" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="1" name="H1"/>
+ <atom segid=" A" residue="1" name="H2"/>
+ <atom segid=" A" residue="1" name="H3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="C"/>
+ <chemical_shift value="176.453" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CB"/>
+ <chemical_shift value="32.88" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CA"/>
+ <chemical_shift value="56.408" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="2" name="HG21"/>
+ <atom segid=" A" residue="2" name="HG22"/>
+ <atom segid=" A" residue="2" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.402" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="2" name="HD11"/>
+ <atom segid=" A" residue="2" name="HD12"/>
+ <atom segid=" A" residue="2" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.402" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="C"/>
+ <chemical_shift value="176.016" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CB"/>
+ <chemical_shift value="38.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CA"/>
+ <chemical_shift value="62.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="N"/>
+ <chemical_shift value="123.415" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CD1"/>
+ <chemical_shift value="13.054" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="H"/>
+ <chemical_shift value="7.988" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="C"/>
+ <chemical_shift value="176.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CB"/>
+ <chemical_shift value="31.187" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CA"/>
+ <chemical_shift value="56.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="N"/>
+ <chemical_shift value="126.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="H"/>
+ <chemical_shift value="8.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="C"/>
+ <chemical_shift value="177.433" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CB"/>
+ <chemical_shift value="30.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CA"/>
+ <chemical_shift value="56.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="N"/>
+ <chemical_shift value="124.204" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="H"/>
+ <chemical_shift value="8.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="C"/>
+ <chemical_shift value="172.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="H"/>
+ <chemical_shift value="8.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="CA"/>
+ <chemical_shift value="45.937" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="N"/>
+ <chemical_shift value="111.348" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="6" name="HZ1"/>
+ <atom segid=" A" residue="6" name="HZ2"/>
+ <atom segid=" A" residue="6" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CB"/>
+ <chemical_shift value="35.109" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="C"/>
+ <chemical_shift value="173.108" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="H"/>
+ <chemical_shift value="7.582" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CA"/>
+ <chemical_shift value="54.965" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="N"/>
+ <chemical_shift value="118.91" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="7" name="HD22"/>
+ <atom segid=" A" residue="7" name="HD23"/>
+ <chemical_shift value="0.615" error="0.0"/>
+ <chemical_shift value="0.267" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="7" name="HD11"/>
+ <atom segid=" A" residue="7" name="HD12"/>
+ <atom segid=" A" residue="7" name="HD13"/>
+ <chemical_shift value="0.615" error="0.0"/>
+ <chemical_shift value="0.267" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="C"/>
+ <chemical_shift value="175.788" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CB"/>
+ <chemical_shift value="46.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CA"/>
+ <chemical_shift value="53.365" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="N"/>
+ <chemical_shift value="116.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CD1"/>
+ <chemical_shift value="25.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CD2"/>
+ <chemical_shift value="24.064" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="H"/>
+ <chemical_shift value="8.231" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="8" name="HG22"/>
+ <atom segid=" A" residue="8" name="HG23"/>
+ <chemical_shift value="0.923" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="8" name="HG11"/>
+ <atom segid=" A" residue="8" name="HG12"/>
+ <atom segid=" A" residue="8" name="HG13"/>
+ <chemical_shift value="0.923" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="C"/>
+ <chemical_shift value="176.033" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CB"/>
+ <chemical_shift value="33.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CA"/>
+ <chemical_shift value="61.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="N"/>
+ <chemical_shift value="125.474" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CG1"/>
+ <chemical_shift value="20.962" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="H"/>
+ <chemical_shift value="10.155" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CG2"/>
+ <chemical_shift value="21.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="9" name="HG22"/>
+ <atom segid=" A" residue="9" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.346" error="0.0"/>
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+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="9" name="HD11"/>
+ <atom segid=" A" residue="9" name="HD12"/>
+ <atom segid=" A" residue="9" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.346" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="C"/>
+ <chemical_shift value="174.901" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CB"/>
+ <chemical_shift value="40.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CA"/>
+ <chemical_shift value="59.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="N"/>
+ <chemical_shift value="128.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CD1"/>
+ <chemical_shift value="14.523" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="H"/>
+ <chemical_shift value="9.114" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="H"/>
+ <chemical_shift value="9.032" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="C"/>
+ <chemical_shift value="174.116" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CB"/>
+ <chemical_shift value="32.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CA"/>
+ <chemical_shift value="54.451" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="N"/>
+ <chemical_shift value="126.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="11" name="HG21"/>
+ <atom segid=" A" residue="11" name="HG22"/>
+ <atom segid=" A" residue="11" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.107" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="11" name="HD11"/>
+ <atom segid=" A" residue="11" name="HD12"/>
+ <atom segid=" A" residue="11" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.107" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="C"/>
+ <chemical_shift value="171.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CB"/>
+ <chemical_shift value="41.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CA"/>
+ <chemical_shift value="59.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="N"/>
+ <chemical_shift value="122.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CD1"/>
+ <chemical_shift value="13.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="H"/>
+ <chemical_shift value="8.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="C"/>
+ <chemical_shift value="177.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CB"/>
+ <chemical_shift value="39.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CA"/>
+ <chemical_shift value="54.628" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="N"/>
+ <chemical_shift value="122.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="H"/>
+ <chemical_shift value="8.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="C"/>
+ <chemical_shift value="173.365" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="H"/>
+ <chemical_shift value="8.288" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="CA"/>
+ <chemical_shift value="46.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="N"/>
+ <chemical_shift value="106.789" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="C"/>
+ <chemical_shift value="176.544" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CB"/>
+ <chemical_shift value="39.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CA"/>
+ <chemical_shift value="53.217" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="N"/>
+ <chemical_shift value="117.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="H"/>
+ <chemical_shift value="7.99" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="15" name="HZ1"/>
+ <atom segid=" A" residue="15" name="HZ2"/>
+ <atom segid=" A" residue="15" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CB"/>
+ <chemical_shift value="32.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="C"/>
+ <chemical_shift value="177.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="H"/>
+ <chemical_shift value="7.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CA"/>
+ <chemical_shift value="53.23" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="N"/>
+ <chemical_shift value="118.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="C"/>
+ <chemical_shift value="175.872" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="H"/>
+ <chemical_shift value="8.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="CA"/>
+ <chemical_shift value="48.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="N"/>
+ <chemical_shift value="108.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="17" name="HD1"/>
+ <atom segid=" A" residue="17" name="HD2"/>
+ <atom segid=" A" residue="17" name="HE1"/>
+ <atom segid=" A" residue="17" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="C"/>
+ <chemical_shift value="177.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CB"/>
+ <chemical_shift value="37.646" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CA"/>
+ <chemical_shift value="59.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="N"/>
+ <chemical_shift value="120.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="H"/>
+ <chemical_shift value="8.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="C"/>
+ <chemical_shift value="179.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CB"/>
+ <chemical_shift value="37.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CA"/>
+ <chemical_shift value="56.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="N"/>
+ <chemical_shift value="123.761" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="H"/>
+ <chemical_shift value="8.109" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="C"/>
+ <chemical_shift value="176.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="H"/>
+ <chemical_shift value="9.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="CA"/>
+ <chemical_shift value="47.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="N"/>
+ <chemical_shift value="111.77" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="20" name="HD21"/>
+ <atom segid=" A" residue="20" name="HD22"/>
+ <atom segid=" A" residue="20" name="HD23"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="20" name="HD11"/>
+ <atom segid=" A" residue="20" name="HD12"/>
+ <atom segid=" A" residue="20" name="HD13"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="C"/>
+ <chemical_shift value="178.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CB"/>
+ <chemical_shift value="41.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CA"/>
+ <chemical_shift value="57.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="N"/>
+ <chemical_shift value="121.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CD1"/>
+ <chemical_shift value="24.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CD2"/>
+ <chemical_shift value="26.879" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="21" name="HB1"/>
+ <atom segid=" A" residue="21" name="HB2"/>
+ <atom segid=" A" residue="21" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="C"/>
+ <chemical_shift value="180.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="CB"/>
+ <chemical_shift value="17.478" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="CA"/>
+ <chemical_shift value="55.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="N"/>
+ <chemical_shift value="121.303" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="H"/>
+ <chemical_shift value="8.143" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="C"/>
+ <chemical_shift value="180.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CB"/>
+ <chemical_shift value="28.487" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CA"/>
+ <chemical_shift value="59.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="N"/>
+ <chemical_shift value="120.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="H"/>
+ <chemical_shift value="7.825" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="23" name="HG21"/>
+ <atom segid=" A" residue="23" name="HG22"/>
+ <atom segid=" A" residue="23" name="HG23"/>
+ <chemical_shift value="1.252" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="23" name="HG11"/>
+ <atom segid=" A" residue="23" name="HG12"/>
+ <atom segid=" A" residue="23" name="HG13"/>
+ <chemical_shift value="1.252" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="C"/>
+ <chemical_shift value="179.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CB"/>
+ <chemical_shift value="31.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CA"/>
+ <chemical_shift value="66.874" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="N"/>
+ <chemical_shift value="123.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CG1"/>
+ <chemical_shift value="22.314" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="H"/>
+ <chemical_shift value="7.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CG2"/>
+ <chemical_shift value="23.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="C"/>
+ <chemical_shift value="175.393" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="H"/>
+ <chemical_shift value="8.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="CA"/>
+ <chemical_shift value="47.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="N"/>
+ <chemical_shift value="106.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="25" name="HZ1"/>
+ <atom segid=" A" residue="25" name="HZ2"/>
+ <atom segid=" A" residue="25" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CB"/>
+ <chemical_shift value="31.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="C"/>
+ <chemical_shift value="179.664" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="H"/>
+ <chemical_shift value="8.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CA"/>
+ <chemical_shift value="59.448" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="N"/>
+ <chemical_shift value="123.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="26" name="HZ1"/>
+ <atom segid=" A" residue="26" name="HZ2"/>
+ <atom segid=" A" residue="26" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CB"/>
+ <chemical_shift value="31.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="C"/>
+ <chemical_shift value="178.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="H"/>
+ <chemical_shift value="7.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CA"/>
+ <chemical_shift value="59.777" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="N"/>
+ <chemical_shift value="123.048" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="27" name="HD1"/>
+ <atom segid=" A" residue="27" name="HD2"/>
+ <atom segid=" A" residue="27" name="HE1"/>
+ <atom segid=" A" residue="27" name="HE2"/>
+ <atom segid=" A" residue="27" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="C"/>
+ <chemical_shift value="179.166" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CB"/>
+ <chemical_shift value="39.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CA"/>
+ <chemical_shift value="61.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="N"/>
+ <chemical_shift value="120.111" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="H"/>
+ <chemical_shift value="8.131" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="C"/>
+ <chemical_shift value="180.031" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CB"/>
+ <chemical_shift value="29.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CA"/>
+ <chemical_shift value="59.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="N"/>
+ <chemical_shift value="124.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="H"/>
+ <chemical_shift value="8.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="29" name="HZ1"/>
+ <atom segid=" A" residue="29" name="HZ2"/>
+ <atom segid=" A" residue="29" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CB"/>
+ <chemical_shift value="31.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="H"/>
+ <chemical_shift value="8.151" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CA"/>
+ <chemical_shift value="59.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="N"/>
+ <chemical_shift value="122.162" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="C"/>
+ <chemical_shift value="178.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CB"/>
+ <chemical_shift value="41.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CA"/>
+ <chemical_shift value="56.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="N"/>
+ <chemical_shift value="116.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="H"/>
+ <chemical_shift value="7.615" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="31" name="HG21"/>
+ <atom segid=" A" residue="31" name="HG22"/>
+ <atom segid=" A" residue="31" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="C"/>
+ <chemical_shift value="176.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CB"/>
+ <chemical_shift value="72.293" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CA"/>
+ <chemical_shift value="62.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="N"/>
+ <chemical_shift value="107.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="H"/>
+ <chemical_shift value="7.929" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="C"/>
+ <chemical_shift value="173.645" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="H"/>
+ <chemical_shift value="8.6" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="CA"/>
+ <chemical_shift value="45.563" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="N"/>
+ <chemical_shift value="112.884" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="33" name="HG21"/>
+ <atom segid=" A" residue="33" name="HG22"/>
+ <atom segid=" A" residue="33" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.574" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="33" name="HD11"/>
+ <atom segid=" A" residue="33" name="HD12"/>
+ <atom segid=" A" residue="33" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.574" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="C"/>
+ <chemical_shift value="173.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CB"/>
+ <chemical_shift value="35.66" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CA"/>
+ <chemical_shift value="59.048" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="N"/>
+ <chemical_shift value="124.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CD1"/>
+ <chemical_shift value="10.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="H"/>
+ <chemical_shift value="7.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="34" name="HZ1"/>
+ <atom segid=" A" residue="34" name="HZ2"/>
+ <atom segid=" A" residue="34" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CB"/>
+ <chemical_shift value="32.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="C"/>
+ <chemical_shift value="175.675" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="H"/>
+ <chemical_shift value="7.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CA"/>
+ <chemical_shift value="56.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="N"/>
+ <chemical_shift value="125.011" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="35" name="HG21"/>
+ <atom segid=" A" residue="35" name="HG22"/>
+ <atom segid=" A" residue="35" name="HG23"/>
+ <chemical_shift value="0.776" error="0.0"/>
+ <chemical_shift value="0.331" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="35" name="HG11"/>
+ <atom segid=" A" residue="35" name="HG12"/>
+ <atom segid=" A" residue="35" name="HG13"/>
+ <chemical_shift value="0.776" error="0.0"/>
+ <chemical_shift value="0.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="C"/>
+ <chemical_shift value="175.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CB"/>
+ <chemical_shift value="33.372" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CA"/>
+ <chemical_shift value="61.064" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="N"/>
+ <chemical_shift value="124.42" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CG1"/>
+ <chemical_shift value="20.685" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="H"/>
+ <chemical_shift value="8.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CG2"/>
+ <chemical_shift value="22.478" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="36" name="HG21"/>
+ <atom segid=" A" residue="36" name="HG22"/>
+ <atom segid=" A" residue="36" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="C"/>
+ <chemical_shift value="172.762" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CB"/>
+ <chemical_shift value="70.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CA"/>
+ <chemical_shift value="61.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="N"/>
+ <chemical_shift value="125.312" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="H"/>
+ <chemical_shift value="9.176" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="37" name="HG21"/>
+ <atom segid=" A" residue="37" name="HG22"/>
+ <atom segid=" A" residue="37" name="HG23"/>
+ <chemical_shift value="0.766" error="0.0"/>
+ <chemical_shift value="0.951" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="37" name="HG11"/>
+ <atom segid=" A" residue="37" name="HG12"/>
+ <atom segid=" A" residue="37" name="HG13"/>
+ <chemical_shift value="0.766" error="0.0"/>
+ <chemical_shift value="0.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="C"/>
+ <chemical_shift value="175.348" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CB"/>
+ <chemical_shift value="32.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CA"/>
+ <chemical_shift value="61.689" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="N"/>
+ <chemical_shift value="127.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CG1"/>
+ <chemical_shift value="22.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="H"/>
+ <chemical_shift value="8.921" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CG2"/>
+ <chemical_shift value="20.673" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="C"/>
+ <chemical_shift value="173.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CB"/>
+ <chemical_shift value="33.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CA"/>
+ <chemical_shift value="54.475" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="N"/>
+ <chemical_shift value="127.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="H"/>
+ <chemical_shift value="9.644" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CB"/>
+ <chemical_shift value="28.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CA"/>
+ <chemical_shift value="51.527" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="N"/>
+ <chemical_shift value="115.306" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="H"/>
+ <chemical_shift value="8.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="C"/>
+ <chemical_shift value="176.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CB"/>
+ <chemical_shift value="30.665" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CA"/>
+ <chemical_shift value="62.226" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="C"/>
+ <chemical_shift value="176.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CB"/>
+ <chemical_shift value="41.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CA"/>
+ <chemical_shift value="54.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="N"/>
+ <chemical_shift value="121.165" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="H"/>
+ <chemical_shift value="8.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="42" name="HZ1"/>
+ <atom segid=" A" residue="42" name="HZ2"/>
+ <atom segid=" A" residue="42" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CB"/>
+ <chemical_shift value="29.442" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="C"/>
+ <chemical_shift value="178.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="H"/>
+ <chemical_shift value="8.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CA"/>
+ <chemical_shift value="56.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="N"/>
+ <chemical_shift value="119.242" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="43" name="HD21"/>
+ <atom segid=" A" residue="43" name="HD22"/>
+ <atom segid=" A" residue="43" name="HD23"/>
+ <chemical_shift value="1.133" error="0.0"/>
+ <chemical_shift value="1.101" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="43" name="HD11"/>
+ <atom segid=" A" residue="43" name="HD12"/>
+ <atom segid=" A" residue="43" name="HD13"/>
+ <chemical_shift value="1.133" error="0.0"/>
+ <chemical_shift value="1.101" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="C"/>
+ <chemical_shift value="175.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CB"/>
+ <chemical_shift value="40.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CA"/>
+ <chemical_shift value="59.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="N"/>
+ <chemical_shift value="120.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CD1"/>
+ <chemical_shift value="26.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CD2"/>
+ <chemical_shift value="26.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="H"/>
+ <chemical_shift value="7.387" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="C"/>
+ <chemical_shift value="178.284" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CB"/>
+ <chemical_shift value="24.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CA"/>
+ <chemical_shift value="57.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="N"/>
+ <chemical_shift value="123.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="H"/>
+ <chemical_shift value="10.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="C"/>
+ <chemical_shift value="178.462" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CB"/>
+ <chemical_shift value="29.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CA"/>
+ <chemical_shift value="56.456" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="N"/>
+ <chemical_shift value="120.295" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="H"/>
+ <chemical_shift value="7.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="46" name="HZ1"/>
+ <atom segid=" A" residue="46" name="HZ2"/>
+ <atom segid=" A" residue="46" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CB"/>
+ <chemical_shift value="33.277" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="C"/>
+ <chemical_shift value="179.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="H"/>
+ <chemical_shift value="8.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CA"/>
+ <chemical_shift value="58.611" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="N"/>
+ <chemical_shift value="120.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="47" name="HD1"/>
+ <atom segid=" A" residue="47" name="HD2"/>
+ <atom segid=" A" residue="47" name="HE1"/>
+ <atom segid=" A" residue="47" name="HE2"/>
+ <atom segid=" A" residue="47" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CB"/>
+ <chemical_shift value="36.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CA"/>
+ <chemical_shift value="63.747" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="N"/>
+ <chemical_shift value="116.928" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="H"/>
+ <chemical_shift value="8.655" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="C"/>
+ <chemical_shift value="178.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CB"/>
+ <chemical_shift value="30.015" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CA"/>
+ <chemical_shift value="65.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="C"/>
+ <chemical_shift value="178.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CB"/>
+ <chemical_shift value="28.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CA"/>
+ <chemical_shift value="58.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="N"/>
+ <chemical_shift value="115.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="H"/>
+ <chemical_shift value="6.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="50" name="HG21"/>
+ <atom segid=" A" residue="50" name="HG22"/>
+ <atom segid=" A" residue="50" name="HG23"/>
+ <chemical_shift value="0.906" error="0.0"/>
+ <chemical_shift value="0.967" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="50" name="HG11"/>
+ <atom segid=" A" residue="50" name="HG12"/>
+ <atom segid=" A" residue="50" name="HG13"/>
+ <chemical_shift value="0.906" error="0.0"/>
+ <chemical_shift value="0.967" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="C"/>
+ <chemical_shift value="178.512" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CB"/>
+ <chemical_shift value="32.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CA"/>
+ <chemical_shift value="62.603" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="N"/>
+ <chemical_shift value="111.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CG1"/>
+ <chemical_shift value="21.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="H"/>
+ <chemical_shift value="7.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CG2"/>
+ <chemical_shift value="19.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="51" name="HB1"/>
+ <atom segid=" A" residue="51" name="HB2"/>
+ <atom segid=" A" residue="51" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="C"/>
+ <chemical_shift value="180.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="CB"/>
+ <chemical_shift value="17.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="CA"/>
+ <chemical_shift value="54.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="N"/>
+ <chemical_shift value="125.692" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="H"/>
+ <chemical_shift value="8.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="52" name="HB1"/>
+ <atom segid=" A" residue="52" name="HB2"/>
+ <atom segid=" A" residue="52" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="C"/>
+ <chemical_shift value="178.618" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="CB"/>
+ <chemical_shift value="18.146" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="CA"/>
+ <chemical_shift value="53.841" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="N"/>
+ <chemical_shift value="118.243" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="H"/>
+ <chemical_shift value="7.396" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="53" name="HG21"/>
+ <atom segid=" A" residue="53" name="HG22"/>
+ <atom segid=" A" residue="53" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="C"/>
+ <chemical_shift value="175.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CB"/>
+ <chemical_shift value="69.75" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CA"/>
+ <chemical_shift value="61.307" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="N"/>
+ <chemical_shift value="106.045" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="H"/>
+ <chemical_shift value="7.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="C"/>
+ <chemical_shift value="172.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="H"/>
+ <chemical_shift value="7.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="CA"/>
+ <chemical_shift value="45.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="N"/>
+ <chemical_shift value="109.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="174.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CB"/>
+ <chemical_shift value="43.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CA"/>
+ <chemical_shift value="52.778" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="N"/>
+ <chemical_shift value="119.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="H"/>
+ <chemical_shift value="7.395" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="H"/>
+ <chemical_shift value="8.332" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="CA"/>
+ <chemical_shift value="43.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="N"/>
+ <chemical_shift value="105.496" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="C"/>
+ <chemical_shift value="175.448" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CB"/>
+ <chemical_shift value="30.658" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CA"/>
+ <chemical_shift value="61.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="176.037" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CB"/>
+ <chemical_shift value="43.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CA"/>
+ <chemical_shift value="58.668" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="N"/>
+ <chemical_shift value="117.78" error="0.0"/>
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="H"/>
+ <chemical_shift value="8.698" error="0.0"/>
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
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+ </shift_assignment>
+ <shift_assignment method="FLOATING">
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+ <atom segid=" A" residue="59" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.735" error="0.0"/>
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+ <atom segid=" A" residue="59" name="HD12"/>
+ <atom segid=" A" residue="59" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.735" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="C"/>
+ <chemical_shift value="173.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CB"/>
+ <chemical_shift value="42.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CA"/>
+ <chemical_shift value="58.982" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="N"/>
+ <chemical_shift value="114.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CD1"/>
+ <chemical_shift value="13.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="H"/>
+ <chemical_shift value="7.631" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="60" name="HG21"/>
+ <atom segid=" A" residue="60" name="HG22"/>
+ <atom segid=" A" residue="60" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.452" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="60" name="HD11"/>
+ <atom segid=" A" residue="60" name="HD12"/>
+ <atom segid=" A" residue="60" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="C"/>
+ <chemical_shift value="172.929" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CB"/>
+ <chemical_shift value="41.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CA"/>
+ <chemical_shift value="58.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="N"/>
+ <chemical_shift value="124.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CD1"/>
+ <chemical_shift value="14.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="H"/>
+ <chemical_shift value="8.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="61" name="HD1"/>
+ <atom segid=" A" residue="61" name="HD2"/>
+ <atom segid=" A" residue="61" name="HE1"/>
+ <atom segid=" A" residue="61" name="HE2"/>
+ <atom segid=" A" residue="61" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="C"/>
+ <chemical_shift value="176.742" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CB"/>
+ <chemical_shift value="41.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CA"/>
+ <chemical_shift value="55.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="N"/>
+ <chemical_shift value="126.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="H"/>
+ <chemical_shift value="8.603" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="H"/>
+ <chemical_shift value="9.181" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="C"/>
+ <chemical_shift value="173.771" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CB"/>
+ <chemical_shift value="31.813" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CA"/>
+ <chemical_shift value="57.786" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="N"/>
+ <chemical_shift value="121.356" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="63" name="HB1"/>
+ <atom segid=" A" residue="63" name="HB2"/>
+ <atom segid=" A" residue="63" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="C"/>
+ <chemical_shift value="179.957" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="CB"/>
+ <chemical_shift value="18.639" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="CA"/>
+ <chemical_shift value="54.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="N"/>
+ <chemical_shift value="125.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="H"/>
+ <chemical_shift value="6.296" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="C"/>
+ <chemical_shift value="178.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CB"/>
+ <chemical_shift value="30.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CA"/>
+ <chemical_shift value="60.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="N"/>
+ <chemical_shift value="115.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="H"/>
+ <chemical_shift value="8.028" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="C"/>
+ <chemical_shift value="177.968" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CB"/>
+ <chemical_shift value="39.5" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CA"/>
+ <chemical_shift value="57.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="N"/>
+ <chemical_shift value="119.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="H"/>
+ <chemical_shift value="7.721" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CB"/>
+ <chemical_shift value="29.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="C"/>
+ <chemical_shift value="177.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="H"/>
+ <chemical_shift value="6.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CA"/>
+ <chemical_shift value="55.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="N"/>
+ <chemical_shift value="116.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="67" name="HD1"/>
+ <atom segid=" A" residue="67" name="HD2"/>
+ <atom segid=" A" residue="67" name="HE1"/>
+ <atom segid=" A" residue="67" name="HE2"/>
+ <atom segid=" A" residue="67" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="C"/>
+ <chemical_shift value="177.883" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CB"/>
+ <chemical_shift value="36.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CA"/>
+ <chemical_shift value="58.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="N"/>
+ <chemical_shift value="116.954" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="H"/>
+ <chemical_shift value="7.688" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="C"/>
+ <chemical_shift value="175.81" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="H"/>
+ <chemical_shift value="7.272" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="CA"/>
+ <chemical_shift value="47.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="N"/>
+ <chemical_shift value="107.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="C"/>
+ <chemical_shift value="177.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="H"/>
+ <chemical_shift value="7.651" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="CA"/>
+ <chemical_shift value="47.089" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="N"/>
+ <chemical_shift value="107.532" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="70" name="HD1"/>
+ <atom segid=" A" residue="70" name="HD2"/>
+ <atom segid=" A" residue="70" name="HE1"/>
+ <atom segid=" A" residue="70" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="C"/>
+ <chemical_shift value="178.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CB"/>
+ <chemical_shift value="35.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CA"/>
+ <chemical_shift value="57.372" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="N"/>
+ <chemical_shift value="119.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="H"/>
+ <chemical_shift value="6.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="71" name="HB1"/>
+ <atom segid=" A" residue="71" name="HB2"/>
+ <atom segid=" A" residue="71" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="C"/>
+ <chemical_shift value="182.277" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="CB"/>
+ <chemical_shift value="18.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="CA"/>
+ <chemical_shift value="54.487" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="N"/>
+ <chemical_shift value="122.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="H"/>
+ <chemical_shift value="8.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="C"/>
+ <chemical_shift value="177.85" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CB"/>
+ <chemical_shift value="27.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CA"/>
+ <chemical_shift value="58.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="N"/>
+ <chemical_shift value="122.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="H"/>
+ <chemical_shift value="8.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="C"/>
+ <chemical_shift value="173.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="CB"/>
+ <chemical_shift value="64.148" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="CA"/>
+ <chemical_shift value="59.274" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="N"/>
+ <chemical_shift value="112.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="H"/>
+ <chemical_shift value="7.362" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="C"/>
+ <chemical_shift value="176.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="H"/>
+ <chemical_shift value="8.083" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="CA"/>
+ <chemical_shift value="46.341" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="N"/>
+ <chemical_shift value="109.4" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="75" name="HD21"/>
+ <atom segid=" A" residue="75" name="HD22"/>
+ <atom segid=" A" residue="75" name="HD23"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="75" name="HD11"/>
+ <atom segid=" A" residue="75" name="HD12"/>
+ <atom segid=" A" residue="75" name="HD13"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="C"/>
+ <chemical_shift value="177.608" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CB"/>
+ <chemical_shift value="42.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CA"/>
+ <chemical_shift value="55.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="N"/>
+ <chemical_shift value="113.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CD1"/>
+ <chemical_shift value="25.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CD2"/>
+ <chemical_shift value="20.664" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="H"/>
+ <chemical_shift value="7.815" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="76" name="HD22"/>
+ <atom segid=" A" residue="76" name="HD23"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.897" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="76" name="HD11"/>
+ <atom segid=" A" residue="76" name="HD12"/>
+ <atom segid=" A" residue="76" name="HD13"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="176.782" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="43.798" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CA"/>
+ <chemical_shift value="52.794" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="N"/>
+ <chemical_shift value="115.902" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="27.43" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="21.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="7.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="77" name="HB2"/>
+ <atom segid=" A" residue="77" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="CB"/>
+ <chemical_shift value="19.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="CA"/>
+ <chemical_shift value="51.102" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="N"/>
+ <chemical_shift value="125.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="H"/>
+ <chemical_shift value="9.007" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="C"/>
+ <chemical_shift value="176.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CB"/>
+ <chemical_shift value="29.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CA"/>
+ <chemical_shift value="56.426" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="N"/>
+ <chemical_shift value="120.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="H"/>
+ <chemical_shift value="8.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
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+ <atom segid=" A" residue="79" name="HG22"/>
+ <atom segid=" A" residue="79" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.161" error="0.0"/>
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+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="79" name="HD12"/>
+ <atom segid=" A" residue="79" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.161" error="0.0"/>
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="59.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ </shift_assignment>
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+ <chemical_shift value="" error="0.0"/>
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
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+ <chemical_shift value="" error="0.0"/>
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
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+ <chemical_shift value="12.313" error="0.0"/>
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="8.176" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
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+ <chemical_shift value="" error="0.0"/>
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+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
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+ <atom segid=" A" residue="80" name="HG23"/>
+ <chemical_shift value="" error=""/>
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CB"/>
+ <chemical_shift value="69.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CA"/>
+ <chemical_shift value="57.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="N"/>
+ <chemical_shift value="112.766" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="H"/>
+ <chemical_shift value="8.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="C"/>
+ <chemical_shift value="177.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CB"/>
+ <chemical_shift value="31.586" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CA"/>
+ <chemical_shift value="62.548" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CB"/>
+ <chemical_shift value="41.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CA"/>
+ <chemical_shift value="53.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="N"/>
+ <chemical_shift value="123.843" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="H"/>
+ <chemical_shift value="9.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="83" name="HZ1"/>
+ <atom segid=" A" residue="83" name="HZ2"/>
+ <atom segid=" A" residue="83" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CB"/>
+ <chemical_shift value="31.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="C"/>
+ <chemical_shift value="177.708" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CA"/>
+ <chemical_shift value="59.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="84" name="HB1"/>
+ <atom segid=" A" residue="84" name="HB2"/>
+ <atom segid=" A" residue="84" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="C"/>
+ <chemical_shift value="180.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="CB"/>
+ <chemical_shift value="17.553" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="CA"/>
+ <chemical_shift value="54.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="N"/>
+ <chemical_shift value="119.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="H"/>
+ <chemical_shift value="8.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="85" name="HD1"/>
+ <atom segid=" A" residue="85" name="HD2"/>
+ <atom segid=" A" residue="85" name="HE1"/>
+ <atom segid=" A" residue="85" name="HE2"/>
+ <atom segid=" A" residue="85" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="C"/>
+ <chemical_shift value="178.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CB"/>
+ <chemical_shift value="39.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CA"/>
+ <chemical_shift value="62.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="N"/>
+ <chemical_shift value="118.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="H"/>
+ <chemical_shift value="7.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="C"/>
+ <chemical_shift value="180.14" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CB"/>
+ <chemical_shift value="28.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CA"/>
+ <chemical_shift value="59.616" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="N"/>
+ <chemical_shift value="117.272" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="H"/>
+ <chemical_shift value="8.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="C"/>
+ <chemical_shift value="176.576" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CB"/>
+ <chemical_shift value="40.956" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CA"/>
+ <chemical_shift value="56.177" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="N"/>
+ <chemical_shift value="116.913" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="H"/>
+ <chemical_shift value="8.053" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="88" name="HZ1"/>
+ <atom segid=" A" residue="88" name="HZ2"/>
+ <atom segid=" A" residue="88" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CB"/>
+ <chemical_shift value="31.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="C"/>
+ <chemical_shift value="176.797" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="H"/>
+ <chemical_shift value="7.816" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CA"/>
+ <chemical_shift value="58.402" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="N"/>
+ <chemical_shift value="117.299" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="89" name="HD21"/>
+ <atom segid=" A" residue="89" name="HD22"/>
+ <atom segid=" A" residue="89" name="HD23"/>
+ <chemical_shift value="0.484" error="0.0"/>
+ <chemical_shift value="0.526" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="89" name="HD11"/>
+ <atom segid=" A" residue="89" name="HD12"/>
+ <atom segid=" A" residue="89" name="HD13"/>
+ <chemical_shift value="0.484" error="0.0"/>
+ <chemical_shift value="0.526" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="C"/>
+ <chemical_shift value="176.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CB"/>
+ <chemical_shift value="42.609" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CA"/>
+ <chemical_shift value="53.55" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="N"/>
+ <chemical_shift value="120.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CD1"/>
+ <chemical_shift value="26.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CD2"/>
+ <chemical_shift value="25.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="H"/>
+ <chemical_shift value="7.661" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="90" name="HD1"/>
+ <atom segid=" A" residue="90" name="HD2"/>
+ <atom segid=" A" residue="90" name="HE1"/>
+ <atom segid=" A" residue="90" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CB"/>
+ <chemical_shift value="38.921" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CA"/>
+ <chemical_shift value="59.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="N"/>
+ <chemical_shift value="116.748" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="H"/>
+ <chemical_shift value="7.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="C"/>
+ <chemical_shift value="179.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CB"/>
+ <chemical_shift value="31.38" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CA"/>
+ <chemical_shift value="66.902" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="92" name="HD1"/>
+ <atom segid=" A" residue="92" name="HD2"/>
+ <atom segid=" A" residue="92" name="HE1"/>
+ <atom segid=" A" residue="92" name="HE2"/>
+ <atom segid=" A" residue="92" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="C"/>
+ <chemical_shift value="176.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CB"/>
+ <chemical_shift value="36.63" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CA"/>
+ <chemical_shift value="59.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="N"/>
+ <chemical_shift value="112.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="H"/>
+ <chemical_shift value="8.01" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="93" name="HG21"/>
+ <atom segid=" A" residue="93" name="HG22"/>
+ <atom segid=" A" residue="93" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="C"/>
+ <chemical_shift value="176.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CB"/>
+ <chemical_shift value="67.099" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CA"/>
+ <chemical_shift value="64.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="N"/>
+ <chemical_shift value="111.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="H"/>
+ <chemical_shift value="7.099" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="H"/>
+ <chemical_shift value="6.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="C"/>
+ <chemical_shift value="178.465" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CB"/>
+ <chemical_shift value="29.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CA"/>
+ <chemical_shift value="58.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="N"/>
+ <chemical_shift value="120.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="C"/>
+ <chemical_shift value="178.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CB"/>
+ <chemical_shift value="39.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CA"/>
+ <chemical_shift value="57.436" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="N"/>
+ <chemical_shift value="115.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="H"/>
+ <chemical_shift value="7.31" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="96" name="HB1"/>
+ <atom segid=" A" residue="96" name="HB2"/>
+ <atom segid=" A" residue="96" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="C"/>
+ <chemical_shift value="177.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="CB"/>
+ <chemical_shift value="17.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="CA"/>
+ <chemical_shift value="54.0" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="N"/>
+ <chemical_shift value="118.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="H"/>
+ <chemical_shift value="6.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="97" name="HG21"/>
+ <atom segid=" A" residue="97" name="HG22"/>
+ <atom segid=" A" residue="97" name="HG23"/>
+ <chemical_shift value="1.347" error="0.0"/>
+ <chemical_shift value="0.578" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="97" name="HG11"/>
+ <atom segid=" A" residue="97" name="HG12"/>
+ <atom segid=" A" residue="97" name="HG13"/>
+ <chemical_shift value="1.347" error="0.0"/>
+ <chemical_shift value="0.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="C"/>
+ <chemical_shift value="172.577" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CB"/>
+ <chemical_shift value="30.785" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CA"/>
+ <chemical_shift value="59.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="N"/>
+ <chemical_shift value="106.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CG1"/>
+ <chemical_shift value="22.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="H"/>
+ <chemical_shift value="7.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CG2"/>
+ <chemical_shift value="19.363" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CB"/>
+ <chemical_shift value="31.357" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="C"/>
+ <chemical_shift value="176.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="H"/>
+ <chemical_shift value="7.049" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CA"/>
+ <chemical_shift value="55.065" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="N"/>
+ <chemical_shift value="121.675" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="99" name="HD1"/>
+ <atom segid=" A" residue="99" name="HD2"/>
+ <atom segid=" A" residue="99" name="HE1"/>
+ <atom segid=" A" residue="99" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CB"/>
+ <chemical_shift value="41.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CA"/>
+ <chemical_shift value="58.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="N"/>
+ <chemical_shift value="127.473" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="H"/>
+ <chemical_shift value="9.707" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="C"/>
+ <chemical_shift value="175.4" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CB"/>
+ <chemical_shift value="37.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CA"/>
+ <chemical_shift value="53.907" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="C"/>
+ <chemical_shift value="173.987" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="H"/>
+ <chemical_shift value="8.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="CA"/>
+ <chemical_shift value="45.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="N"/>
+ <chemical_shift value="102.283" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="102" name="HZ1"/>
+ <atom segid=" A" residue="102" name="HZ2"/>
+ <atom segid=" A" residue="102" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CB"/>
+ <chemical_shift value="34.731" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="C"/>
+ <chemical_shift value="175.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="H"/>
+ <chemical_shift value="7.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CA"/>
+ <chemical_shift value="54.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="N"/>
+ <chemical_shift value="121.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="103" name="HD21"/>
+ <atom segid=" A" residue="103" name="HD22"/>
+ <atom segid=" A" residue="103" name="HD23"/>
+ <chemical_shift value="0.972" error="0.0"/>
+ <chemical_shift value="0.49" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="103" name="HD11"/>
+ <atom segid=" A" residue="103" name="HD12"/>
+ <atom segid=" A" residue="103" name="HD13"/>
+ <chemical_shift value="0.972" error="0.0"/>
+ <chemical_shift value="0.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="C"/>
+ <chemical_shift value="178.524" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CB"/>
+ <chemical_shift value="42.179" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CA"/>
+ <chemical_shift value="55.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="N"/>
+ <chemical_shift value="123.232" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CD1"/>
+ <chemical_shift value="24.748" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CD2"/>
+ <chemical_shift value="24.1" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="H"/>
+ <chemical_shift value="8.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="104" name="HG21"/>
+ <atom segid=" A" residue="104" name="HG22"/>
+ <atom segid=" A" residue="104" name="HG23"/>
+ <chemical_shift value="0.889" error="0.0"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="104" name="HD11"/>
+ <atom segid=" A" residue="104" name="HD12"/>
+ <atom segid=" A" residue="104" name="HD13"/>
+ <chemical_shift value="0.889" error="0.0"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="C"/>
+ <chemical_shift value="175.468" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CB"/>
+ <chemical_shift value="39.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CA"/>
+ <chemical_shift value="59.655" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="N"/>
+ <chemical_shift value="112.793" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CD1"/>
+ <chemical_shift value="14.779" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="H"/>
+ <chemical_shift value="8.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CG2"/>
+ <chemical_shift value="19.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="105" name="HB1"/>
+ <atom segid=" A" residue="105" name="HB2"/>
+ <atom segid=" A" residue="105" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="C"/>
+ <chemical_shift value="173.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="CB"/>
+ <chemical_shift value="22.111" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="CA"/>
+ <chemical_shift value="52.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="N"/>
+ <chemical_shift value="117.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="H"/>
+ <chemical_shift value="7.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="106" name="HD1"/>
+ <atom segid=" A" residue="106" name="HD2"/>
+ <atom segid=" A" residue="106" name="HE1"/>
+ <atom segid=" A" residue="106" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CB"/>
+ <chemical_shift value="39.931" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CA"/>
+ <chemical_shift value="56.214" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="N"/>
+ <chemical_shift value="113.919" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="H"/>
+ <chemical_shift value="8.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="C"/>
+ <chemical_shift value="174.609" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CB"/>
+ <chemical_shift value="32.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CA"/>
+ <chemical_shift value="62.281" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="108" name="HG21"/>
+ <atom segid=" A" residue="108" name="HG22"/>
+ <atom segid=" A" residue="108" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.637" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="108" name="HD11"/>
+ <atom segid=" A" residue="108" name="HD12"/>
+ <atom segid=" A" residue="108" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.637" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="C"/>
+ <chemical_shift value="176.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CB"/>
+ <chemical_shift value="37.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CA"/>
+ <chemical_shift value="60.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="N"/>
+ <chemical_shift value="115.381" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CD1"/>
+ <chemical_shift value="9.981" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="H"/>
+ <chemical_shift value="8.515" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="109" name="HB1"/>
+ <atom segid=" A" residue="109" name="HB2"/>
+ <atom segid=" A" residue="109" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="C"/>
+ <chemical_shift value="174.628" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="CB"/>
+ <chemical_shift value="23.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="CA"/>
+ <chemical_shift value="50.761" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="N"/>
+ <chemical_shift value="118.162" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="H"/>
+ <chemical_shift value="7.854" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="110" name="HG21"/>
+ <atom segid=" A" residue="110" name="HG22"/>
+ <atom segid=" A" residue="110" name="HG23"/>
+ <chemical_shift value="0.476" error="0.0"/>
+ <chemical_shift value="0.767" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="110" name="HG11"/>
+ <atom segid=" A" residue="110" name="HG12"/>
+ <atom segid=" A" residue="110" name="HG13"/>
+ <chemical_shift value="0.476" error="0.0"/>
+ <chemical_shift value="0.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="C"/>
+ <chemical_shift value="173.634" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CB"/>
+ <chemical_shift value="34.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CA"/>
+ <chemical_shift value="62.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="N"/>
+ <chemical_shift value="121.428" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CG1"/>
+ <chemical_shift value="20.954" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="H"/>
+ <chemical_shift value="8.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CG2"/>
+ <chemical_shift value="20.424" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="C"/>
+ <chemical_shift value="173.917" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CB"/>
+ <chemical_shift value="32.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CA"/>
+ <chemical_shift value="54.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="N"/>
+ <chemical_shift value="123.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="H"/>
+ <chemical_shift value="9.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="112" name="HB1"/>
+ <atom segid=" A" residue="112" name="HB2"/>
+ <atom segid=" A" residue="112" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="C"/>
+ <chemical_shift value="176.641" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="CB"/>
+ <chemical_shift value="22.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="CA"/>
+ <chemical_shift value="50.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="N"/>
+ <chemical_shift value="117.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="H"/>
+ <chemical_shift value="6.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="113" name="HD21"/>
+ <atom segid=" A" residue="113" name="HD22"/>
+ <atom segid=" A" residue="113" name="HD23"/>
+ <chemical_shift value="0.854" error="0.0"/>
+ <chemical_shift value="0.691" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="113" name="HD11"/>
+ <atom segid=" A" residue="113" name="HD12"/>
+ <atom segid=" A" residue="113" name="HD13"/>
+ <chemical_shift value="0.854" error="0.0"/>
+ <chemical_shift value="0.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="C"/>
+ <chemical_shift value="173.598" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CB"/>
+ <chemical_shift value="43.367" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CA"/>
+ <chemical_shift value="55.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="N"/>
+ <chemical_shift value="123.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CD1"/>
+ <chemical_shift value="26.792" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CD2"/>
+ <chemical_shift value="23.625" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="H"/>
+ <chemical_shift value="8.457" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="C"/>
+ <chemical_shift value="172.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="CB"/>
+ <chemical_shift value="67.447" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="CA"/>
+ <chemical_shift value="57.265" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="N"/>
+ <chemical_shift value="108.174" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="H"/>
+ <chemical_shift value="7.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="115" name="HD21"/>
+ <atom segid=" A" residue="115" name="HD22"/>
+ <atom segid=" A" residue="115" name="HD23"/>
+ <chemical_shift value="0.587" error="0.0"/>
+ <chemical_shift value="0.684" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="115" name="HD11"/>
+ <atom segid=" A" residue="115" name="HD12"/>
+ <atom segid=" A" residue="115" name="HD13"/>
+ <chemical_shift value="0.587" error="0.0"/>
+ <chemical_shift value="0.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="C"/>
+ <chemical_shift value="174.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CB"/>
+ <chemical_shift value="43.729" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CA"/>
+ <chemical_shift value="54.482" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="N"/>
+ <chemical_shift value="122.319" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CD1"/>
+ <chemical_shift value="22.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CD2"/>
+ <chemical_shift value="24.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="H"/>
+ <chemical_shift value="7.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="116" name="HG21"/>
+ <atom segid=" A" residue="116" name="HG22"/>
+ <atom segid=" A" residue="116" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.459" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="116" name="HD11"/>
+ <atom segid=" A" residue="116" name="HD12"/>
+ <atom segid=" A" residue="116" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.459" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="C"/>
+ <chemical_shift value="174.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CB"/>
+ <chemical_shift value="38.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CA"/>
+ <chemical_shift value="60.103" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="N"/>
+ <chemical_shift value="129.611" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CD1"/>
+ <chemical_shift value="13.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="H"/>
+ <chemical_shift value="8.667" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="117" name="HD1"/>
+ <atom segid=" A" residue="117" name="HD2"/>
+ <atom segid=" A" residue="117" name="HE1"/>
+ <atom segid=" A" residue="117" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="C"/>
+ <chemical_shift value="172.945" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CB"/>
+ <chemical_shift value="42.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CA"/>
+ <chemical_shift value="54.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="N"/>
+ <chemical_shift value="121.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="H"/>
+ <chemical_shift value="9.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="C"/>
+ <chemical_shift value="175.772" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CB"/>
+ <chemical_shift value="37.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CA"/>
+ <chemical_shift value="52.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="N"/>
+ <chemical_shift value="121.187" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="H"/>
+ <chemical_shift value="9.303" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="119" name="HZ1"/>
+ <atom segid=" A" residue="119" name="HZ2"/>
+ <atom segid=" A" residue="119" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CB"/>
+ <chemical_shift value="32.435" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="C"/>
+ <chemical_shift value="177.723" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="H"/>
+ <chemical_shift value="8.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CA"/>
+ <chemical_shift value="58.733" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="N"/>
+ <chemical_shift value="125.522" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="C"/>
+ <chemical_shift value="177.651" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CB"/>
+ <chemical_shift value="40.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CA"/>
+ <chemical_shift value="56.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="N"/>
+ <chemical_shift value="115.687" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="121" name="HD21"/>
+ <atom segid=" A" residue="121" name="HD22"/>
+ <atom segid=" A" residue="121" name="HD23"/>
+ <chemical_shift value="0.779" error="0.0"/>
+ <chemical_shift value="0.665" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="121" name="HD11"/>
+ <atom segid=" A" residue="121" name="HD12"/>
+ <atom segid=" A" residue="121" name="HD13"/>
+ <chemical_shift value="0.779" error="0.0"/>
+ <chemical_shift value="0.665" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="C"/>
+ <chemical_shift value="176.749" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CB"/>
+ <chemical_shift value="44.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CA"/>
+ <chemical_shift value="55.765" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="N"/>
+ <chemical_shift value="117.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CD1"/>
+ <chemical_shift value="24.729" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CD2"/>
+ <chemical_shift value="22.791" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="H"/>
+ <chemical_shift value="7.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="122" name="HD21"/>
+ <atom segid=" A" residue="122" name="HD22"/>
+ <atom segid=" A" residue="122" name="HD23"/>
+ <chemical_shift value="0.937" error="0.0"/>
+ <chemical_shift value="0.93" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="122" name="HD11"/>
+ <atom segid=" A" residue="122" name="HD12"/>
+ <atom segid=" A" residue="122" name="HD13"/>
+ <chemical_shift value="0.937" error="0.0"/>
+ <chemical_shift value="0.93" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CB"/>
+ <chemical_shift value="44.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CA"/>
+ <chemical_shift value="51.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="N"/>
+ <chemical_shift value="119.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CD1"/>
+ <chemical_shift value="25.548" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CD2"/>
+ <chemical_shift value="26.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="C"/>
+ <chemical_shift value="176.075" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CB"/>
+ <chemical_shift value="31.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CA"/>
+ <chemical_shift value="62.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="127" name="HZ1"/>
+ <atom segid=" A" residue="127" name="HZ2"/>
+ <atom segid=" A" residue="127" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CB"/>
+ <chemical_shift value="33.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="C"/>
+ <chemical_shift value="177.427" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="H"/>
+ <chemical_shift value="8.137" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CA"/>
+ <chemical_shift value="56.778" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="N"/>
+ <chemical_shift value="118.457" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="128" name="HG21"/>
+ <atom segid=" A" residue="128" name="HG22"/>
+ <atom segid=" A" residue="128" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="C"/>
+ <chemical_shift value="174.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CB"/>
+ <chemical_shift value="71.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CA"/>
+ <chemical_shift value="60.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="N"/>
+ <chemical_shift value="108.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="H"/>
+ <chemical_shift value="10.183" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="C"/>
+ <chemical_shift value="179.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CB"/>
+ <chemical_shift value="28.48" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CA"/>
+ <chemical_shift value="60.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="N"/>
+ <chemical_shift value="123.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="C"/>
+ <chemical_shift value="178.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CB"/>
+ <chemical_shift value="28.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CA"/>
+ <chemical_shift value="61.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="N"/>
+ <chemical_shift value="118.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="H"/>
+ <chemical_shift value="10.583" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="C"/>
+ <chemical_shift value="176.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CB"/>
+ <chemical_shift value="31.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CA"/>
+ <chemical_shift value="57.205" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="N"/>
+ <chemical_shift value="116.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="H"/>
+ <chemical_shift value="7.606" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="132" name="HG21"/>
+ <atom segid=" A" residue="132" name="HG22"/>
+ <atom segid=" A" residue="132" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.56" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="132" name="HD11"/>
+ <atom segid=" A" residue="132" name="HD12"/>
+ <atom segid=" A" residue="132" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CB"/>
+ <chemical_shift value="33.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CA"/>
+ <chemical_shift value="66.928" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="N"/>
+ <chemical_shift value="121.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CD1"/>
+ <chemical_shift value="12.36" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="H"/>
+ <chemical_shift value="8.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="C"/>
+ <chemical_shift value="177.795" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CB"/>
+ <chemical_shift value="30.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CA"/>
+ <chemical_shift value="67.059" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="134" name="HB1"/>
+ <atom segid=" A" residue="134" name="HB2"/>
+ <atom segid=" A" residue="134" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="C"/>
+ <chemical_shift value="181.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="CB"/>
+ <chemical_shift value="17.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="CA"/>
+ <chemical_shift value="55.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="N"/>
+ <chemical_shift value="118.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="H"/>
+ <chemical_shift value="7.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="135" name="HD21"/>
+ <atom segid=" A" residue="135" name="HD22"/>
+ <atom segid=" A" residue="135" name="HD23"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ <chemical_shift value="0.888" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="135" name="HD11"/>
+ <atom segid=" A" residue="135" name="HD12"/>
+ <atom segid=" A" residue="135" name="HD13"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ <chemical_shift value="0.888" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="C"/>
+ <chemical_shift value="179.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CB"/>
+ <chemical_shift value="42.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CA"/>
+ <chemical_shift value="57.396" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="N"/>
+ <chemical_shift value="120.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CD1"/>
+ <chemical_shift value="24.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CD2"/>
+ <chemical_shift value="24.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="H"/>
+ <chemical_shift value="7.6" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="C"/>
+ <chemical_shift value="177.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CB"/>
+ <chemical_shift value="41.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CA"/>
+ <chemical_shift value="58.901" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="N"/>
+ <chemical_shift value="118.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="H"/>
+ <chemical_shift value="8.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="137" name="HZ1"/>
+ <atom segid=" A" residue="137" name="HZ2"/>
+ <atom segid=" A" residue="137" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CB"/>
+ <chemical_shift value="31.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="C"/>
+ <chemical_shift value="179.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="H"/>
+ <chemical_shift value="8.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CA"/>
+ <chemical_shift value="60.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="N"/>
+ <chemical_shift value="117.342" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="C"/>
+ <chemical_shift value="179.799" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CB"/>
+ <chemical_shift value="29.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CA"/>
+ <chemical_shift value="59.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="N"/>
+ <chemical_shift value="118.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="H"/>
+ <chemical_shift value="7.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="139" name="HD21"/>
+ <atom segid=" A" residue="139" name="HD22"/>
+ <atom segid=" A" residue="139" name="HD23"/>
+ <chemical_shift value="0.852" error="0.0"/>
+ <chemical_shift value="0.787" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="139" name="HD11"/>
+ <atom segid=" A" residue="139" name="HD12"/>
+ <atom segid=" A" residue="139" name="HD13"/>
+ <chemical_shift value="0.852" error="0.0"/>
+ <chemical_shift value="0.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="C"/>
+ <chemical_shift value="180.721" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CB"/>
+ <chemical_shift value="40.311" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CA"/>
+ <chemical_shift value="58.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="N"/>
+ <chemical_shift value="121.279" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CD1"/>
+ <chemical_shift value="25.914" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CD2"/>
+ <chemical_shift value="22.927" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="H"/>
+ <chemical_shift value="8.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="140" name="HZ1"/>
+ <atom segid=" A" residue="140" name="HZ2"/>
+ <atom segid=" A" residue="140" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CB"/>
+ <chemical_shift value="31.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="C"/>
+ <chemical_shift value="181.621" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="H"/>
+ <chemical_shift value="9.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CA"/>
+ <chemical_shift value="58.851" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="N"/>
+ <chemical_shift value="124.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="141" name="HB1"/>
+ <atom segid=" A" residue="141" name="HB2"/>
+ <atom segid=" A" residue="141" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="C"/>
+ <chemical_shift value="178.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="CB"/>
+ <chemical_shift value="17.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="CA"/>
+ <chemical_shift value="54.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="N"/>
+ <chemical_shift value="122.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="H"/>
+ <chemical_shift value="7.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="142" name="HZ1"/>
+ <atom segid=" A" residue="142" name="HZ2"/>
+ <atom segid=" A" residue="142" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CB"/>
+ <chemical_shift value="32.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="C"/>
+ <chemical_shift value="176.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="H"/>
+ <chemical_shift value="7.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CA"/>
+ <chemical_shift value="55.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="N"/>
+ <chemical_shift value="115.794" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="C"/>
+ <chemical_shift value="174.318" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="H"/>
+ <chemical_shift value="7.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="CA"/>
+ <chemical_shift value="46.128" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="N"/>
+ <chemical_shift value="107.82" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="144" name="HZ1"/>
+ <atom segid=" A" residue="144" name="HZ2"/>
+ <atom segid=" A" residue="144" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CB"/>
+ <chemical_shift value="35.01" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="C"/>
+ <chemical_shift value="173.812" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="H"/>
+ <chemical_shift value="7.86" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CA"/>
+ <chemical_shift value="53.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="N"/>
+ <chemical_shift value="119.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="C"/>
+ <chemical_shift value="174.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="CB"/>
+ <chemical_shift value="66.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="CA"/>
+ <chemical_shift value="56.884" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="N"/>
+ <chemical_shift value="109.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="H"/>
+ <chemical_shift value="7.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="146" name="HB1"/>
+ <atom segid=" A" residue="146" name="HB2"/>
+ <atom segid=" A" residue="146" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="C"/>
+ <chemical_shift value="175.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="CB"/>
+ <chemical_shift value="17.973" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="CA"/>
+ <chemical_shift value="55.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="N"/>
+ <chemical_shift value="122.791" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="H"/>
+ <chemical_shift value="9.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="147" name="HD21"/>
+ <atom segid=" A" residue="147" name="HD22"/>
+ <atom segid=" A" residue="147" name="HD23"/>
+ <chemical_shift value="0.936" error="0.0"/>
+ <chemical_shift value="0.683" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="147" name="HD11"/>
+ <atom segid=" A" residue="147" name="HD12"/>
+ <atom segid=" A" residue="147" name="HD13"/>
+ <chemical_shift value="0.936" error="0.0"/>
+ <chemical_shift value="0.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="C"/>
+ <chemical_shift value="175.05" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CB"/>
+ <chemical_shift value="45.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CA"/>
+ <chemical_shift value="54.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="N"/>
+ <chemical_shift value="116.868" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CD1"/>
+ <chemical_shift value="22.5" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CD2"/>
+ <chemical_shift value="27.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="H"/>
+ <chemical_shift value="8.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="148" name="HE1"/>
+ <atom segid=" A" residue="148" name="HE2"/>
+ <atom segid=" A" residue="148" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="C"/>
+ <chemical_shift value="174.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CB"/>
+ <chemical_shift value="37.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CA"/>
+ <chemical_shift value="55.8" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="N"/>
+ <chemical_shift value="121.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="H"/>
+ <chemical_shift value="8.179" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="149" name="HD1"/>
+ <atom segid=" A" residue="149" name="HD2"/>
+ <atom segid=" A" residue="149" name="HE1"/>
+ <atom segid=" A" residue="149" name="HE2"/>
+ <atom segid=" A" residue="149" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="C"/>
+ <chemical_shift value="171.59" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CB"/>
+ <chemical_shift value="41.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CA"/>
+ <chemical_shift value="55.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="N"/>
+ <chemical_shift value="120.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="H"/>
+ <chemical_shift value="8.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="C"/>
+ <chemical_shift value="172.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CB"/>
+ <chemical_shift value="37.305" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CA"/>
+ <chemical_shift value="53.341" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="N"/>
+ <chemical_shift value="116.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="H"/>
+ <chemical_shift value="8.671" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="151" name="HD22"/>
+ <atom segid=" A" residue="151" name="HD23"/>
+ <chemical_shift value="0.135" error="0.0"/>
+ <chemical_shift value="0.744" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="151" name="HD11"/>
+ <atom segid=" A" residue="151" name="HD12"/>
+ <atom segid=" A" residue="151" name="HD13"/>
+ <chemical_shift value="0.135" error="0.0"/>
+ <chemical_shift value="0.744" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="C"/>
+ <chemical_shift value="177.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CB"/>
+ <chemical_shift value="41.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CA"/>
+ <chemical_shift value="54.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="N"/>
+ <chemical_shift value="122.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CD1"/>
+ <chemical_shift value="26.232" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CD2"/>
+ <chemical_shift value="23.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="H"/>
+ <chemical_shift value="7.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="C"/>
+ <chemical_shift value="176.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CB"/>
+ <chemical_shift value="28.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CA"/>
+ <chemical_shift value="55.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="N"/>
+ <chemical_shift value="113.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="H"/>
+ <chemical_shift value="7.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CB"/>
+ <chemical_shift value="32.958" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CA"/>
+ <chemical_shift value="51.537" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="N"/>
+ <chemical_shift value="113.572" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="H"/>
+ <chemical_shift value="6.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="C"/>
+ <chemical_shift value="176.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CB"/>
+ <chemical_shift value="31.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CA"/>
+ <chemical_shift value="63.731" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="155" name="HD1"/>
+ <atom segid=" A" residue="155" name="HD2"/>
+ <atom segid=" A" residue="155" name="HE1"/>
+ <atom segid=" A" residue="155" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="C"/>
+ <chemical_shift value="176.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CB"/>
+ <chemical_shift value="40.447" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CA"/>
+ <chemical_shift value="62.679" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="N"/>
+ <chemical_shift value="117.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="H"/>
+ <chemical_shift value="7.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="156" name="HD1"/>
+ <atom segid=" A" residue="156" name="HD2"/>
+ <atom segid=" A" residue="156" name="HE1"/>
+ <atom segid=" A" residue="156" name="HE2"/>
+ <atom segid=" A" residue="156" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="C"/>
+ <chemical_shift value="176.222" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CB"/>
+ <chemical_shift value="41.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CA"/>
+ <chemical_shift value="60.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="N"/>
+ <chemical_shift value="112.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="H"/>
+ <chemical_shift value="8.045" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="157" name="HG21"/>
+ <atom segid=" A" residue="157" name="HG22"/>
+ <atom segid=" A" residue="157" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="C"/>
+ <chemical_shift value="176.039" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CB"/>
+ <chemical_shift value="69.29" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CA"/>
+ <chemical_shift value="63.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="N"/>
+ <chemical_shift value="106.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="H"/>
+ <chemical_shift value="7.59" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CB"/>
+ <chemical_shift value="28.509" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CA"/>
+ <chemical_shift value="60.968" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="N"/>
+ <chemical_shift value="124.195" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="C"/>
+ <chemical_shift value="178.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CB"/>
+ <chemical_shift value="30.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CA"/>
+ <chemical_shift value="65.931" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="160" name="HD21"/>
+ <atom segid=" A" residue="160" name="HD22"/>
+ <atom segid=" A" residue="160" name="HD23"/>
+ <chemical_shift value="-0.302" error="0.0"/>
+ <chemical_shift value="-1.003" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="160" name="HD11"/>
+ <atom segid=" A" residue="160" name="HD12"/>
+ <atom segid=" A" residue="160" name="HD13"/>
+ <chemical_shift value="-0.302" error="0.0"/>
+ <chemical_shift value="-1.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="C"/>
+ <chemical_shift value="176.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CB"/>
+ <chemical_shift value="42.223" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CA"/>
+ <chemical_shift value="56.069" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="N"/>
+ <chemical_shift value="111.624" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CD1"/>
+ <chemical_shift value="19.602" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CD2"/>
+ <chemical_shift value="25.084" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="H"/>
+ <chemical_shift value="6.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="161" name="HG21"/>
+ <atom segid=" A" residue="161" name="HG22"/>
+ <atom segid=" A" residue="161" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.76" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="161" name="HD11"/>
+ <atom segid=" A" residue="161" name="HD12"/>
+ <atom segid=" A" residue="161" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="C"/>
+ <chemical_shift value="175.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CB"/>
+ <chemical_shift value="37.395" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CA"/>
+ <chemical_shift value="65.625" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="N"/>
+ <chemical_shift value="119.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CD1"/>
+ <chemical_shift value="13.081" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="H"/>
+ <chemical_shift value="6.955" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="162" name="HB1"/>
+ <atom segid=" A" residue="162" name="HB2"/>
+ <atom segid=" A" residue="162" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="C"/>
+ <chemical_shift value="179.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="CB"/>
+ <chemical_shift value="18.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="CA"/>
+ <chemical_shift value="52.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="N"/>
+ <chemical_shift value="115.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="H"/>
+ <chemical_shift value="8.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="163" name="HB1"/>
+ <atom segid=" A" residue="163" name="HB2"/>
+ <atom segid=" A" residue="163" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="C"/>
+ <chemical_shift value="178.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="CB"/>
+ <chemical_shift value="19.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="CA"/>
+ <chemical_shift value="56.425" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="N"/>
+ <chemical_shift value="120.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="H"/>
+ <chemical_shift value="6.668" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="C"/>
+ <chemical_shift value="176.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CB"/>
+ <chemical_shift value="42.538" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CA"/>
+ <chemical_shift value="53.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="N"/>
+ <chemical_shift value="115.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="H"/>
+ <chemical_shift value="9.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="C"/>
+ <chemical_shift value="175.607" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="H"/>
+ <chemical_shift value="7.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="CA"/>
+ <chemical_shift value="45.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="N"/>
+ <chemical_shift value="103.622" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="C"/>
+ <chemical_shift value="172.227" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="H"/>
+ <chemical_shift value="7.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="CA"/>
+ <chemical_shift value="45.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="N"/>
+ <chemical_shift value="108.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="167" name="HD1"/>
+ <atom segid=" A" residue="167" name="HD2"/>
+ <atom segid=" A" residue="167" name="HE1"/>
+ <atom segid=" A" residue="167" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="C"/>
+ <chemical_shift value="173.273" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CB"/>
+ <chemical_shift value="39.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CA"/>
+ <chemical_shift value="57.657" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="N"/>
+ <chemical_shift value="115.865" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="H"/>
+ <chemical_shift value="8.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="168" name="HB1"/>
+ <atom segid=" A" residue="168" name="HB2"/>
+ <atom segid=" A" residue="168" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="C"/>
+ <chemical_shift value="173.012" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="CB"/>
+ <chemical_shift value="16.475" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="CA"/>
+ <chemical_shift value="53.124" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="N"/>
+ <chemical_shift value="124.0" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="H"/>
+ <chemical_shift value="10.209" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="169" name="HD1"/>
+ <atom segid=" A" residue="169" name="HD2"/>
+ <atom segid=" A" residue="169" name="HE1"/>
+ <atom segid=" A" residue="169" name="HE2"/>
+ <atom segid=" A" residue="169" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="C"/>
+ <chemical_shift value="176.744" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CB"/>
+ <chemical_shift value="42.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CA"/>
+ <chemical_shift value="55.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="N"/>
+ <chemical_shift value="108.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="H"/>
+ <chemical_shift value="6.324" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="170" name="HZ1"/>
+ <atom segid=" A" residue="170" name="HZ2"/>
+ <atom segid=" A" residue="170" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CB"/>
+ <chemical_shift value="32.355" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="C"/>
+ <chemical_shift value="174.716" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="H"/>
+ <chemical_shift value="8.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CA"/>
+ <chemical_shift value="57.027" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="N"/>
+ <chemical_shift value="125.705" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="171" name="HD1"/>
+ <atom segid=" A" residue="171" name="HD2"/>
+ <atom segid=" A" residue="171" name="HE1"/>
+ <atom segid=" A" residue="171" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="C"/>
+ <chemical_shift value="175.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CB"/>
+ <chemical_shift value="39.896" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CA"/>
+ <chemical_shift value="56.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="N"/>
+ <chemical_shift value="129.707" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="H"/>
+ <chemical_shift value="8.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CB"/>
+ <chemical_shift value="32.477" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CA"/>
+ <chemical_shift value="55.981" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="N"/>
+ <chemical_shift value="126.797" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="H"/>
+ <chemical_shift value="8.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="C"/>
+ <chemical_shift value="175.432" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CB"/>
+ <chemical_shift value="37.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CA"/>
+ <chemical_shift value="54.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="C"/>
+ <chemical_shift value="173.294" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="H"/>
+ <chemical_shift value="7.52" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="CA"/>
+ <chemical_shift value="45.705" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="N"/>
+ <chemical_shift value="102.08" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="175" name="HZ1"/>
+ <atom segid=" A" residue="175" name="HZ2"/>
+ <atom segid=" A" residue="175" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CB"/>
+ <chemical_shift value="35.233" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="C"/>
+ <chemical_shift value="174.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="H"/>
+ <chemical_shift value="7.107" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CA"/>
+ <chemical_shift value="54.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="N"/>
+ <chemical_shift value="118.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="176" name="HD1"/>
+ <atom segid=" A" residue="176" name="HD2"/>
+ <atom segid=" A" residue="176" name="HE1"/>
+ <atom segid=" A" residue="176" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="C"/>
+ <chemical_shift value="176.262" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CB"/>
+ <chemical_shift value="39.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CA"/>
+ <chemical_shift value="58.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="N"/>
+ <chemical_shift value="120.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="H"/>
+ <chemical_shift value="8.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="C"/>
+ <chemical_shift value="177.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CB"/>
+ <chemical_shift value="41.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CA"/>
+ <chemical_shift value="52.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="N"/>
+ <chemical_shift value="124.051" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="H"/>
+ <chemical_shift value="9.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="178" name="HG21"/>
+ <atom segid=" A" residue="178" name="HG22"/>
+ <atom segid=" A" residue="178" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.853" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="178" name="HD11"/>
+ <atom segid=" A" residue="178" name="HD12"/>
+ <atom segid=" A" residue="178" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="C"/>
+ <chemical_shift value="175.849" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CB"/>
+ <chemical_shift value="36.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CA"/>
+ <chemical_shift value="63.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="N"/>
+ <chemical_shift value="117.051" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CD1"/>
+ <chemical_shift value="13.905" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="H"/>
+ <chemical_shift value="7.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="179" name="HZ1"/>
+ <atom segid=" A" residue="179" name="HZ2"/>
+ <atom segid=" A" residue="179" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CB"/>
+ <chemical_shift value="31.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="C"/>
+ <chemical_shift value="176.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="H"/>
+ <chemical_shift value="8.302" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CA"/>
+ <chemical_shift value="54.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="N"/>
+ <chemical_shift value="116.075" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="C"/>
+ <chemical_shift value="172.993" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CB"/>
+ <chemical_shift value="40.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CA"/>
+ <chemical_shift value="53.425" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="N"/>
+ <chemical_shift value="123.259" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="H"/>
+ <chemical_shift value="7.754" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="181" name="HG21"/>
+ <atom segid=" A" residue="181" name="HG22"/>
+ <atom segid=" A" residue="181" name="HG23"/>
+ <chemical_shift value="0.711" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="181" name="HG11"/>
+ <atom segid=" A" residue="181" name="HG12"/>
+ <atom segid=" A" residue="181" name="HG13"/>
+ <chemical_shift value="0.711" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="C"/>
+ <chemical_shift value="176.899" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CB"/>
+ <chemical_shift value="35.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CA"/>
+ <chemical_shift value="59.481" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="N"/>
+ <chemical_shift value="122.883" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CG1"/>
+ <chemical_shift value="21.539" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="H"/>
+ <chemical_shift value="7.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CG2"/>
+ <chemical_shift value="22.538" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="C"/>
+ <chemical_shift value="174.259" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="H"/>
+ <chemical_shift value="7.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="CA"/>
+ <chemical_shift value="46.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="N"/>
+ <chemical_shift value="120.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="183" name="HG21"/>
+ <atom segid=" A" residue="183" name="HG22"/>
+ <atom segid=" A" residue="183" name="HG23"/>
+ <chemical_shift value="0.841" error="0.0"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="183" name="HG11"/>
+ <atom segid=" A" residue="183" name="HG12"/>
+ <atom segid=" A" residue="183" name="HG13"/>
+ <chemical_shift value="0.841" error="0.0"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="C"/>
+ <chemical_shift value="173.292" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CB"/>
+ <chemical_shift value="32.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CA"/>
+ <chemical_shift value="63.489" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="N"/>
+ <chemical_shift value="114.266" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CG1"/>
+ <chemical_shift value="22.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="H"/>
+ <chemical_shift value="6.757" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CG2"/>
+ <chemical_shift value="22.42" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="C"/>
+ <chemical_shift value="176.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CB"/>
+ <chemical_shift value="39.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CA"/>
+ <chemical_shift value="51.67" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="N"/>
+ <chemical_shift value="114.851" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="H"/>
+ <chemical_shift value="7.835" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CB"/>
+ <chemical_shift value="39.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CA"/>
+ <chemical_shift value="51.688" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="N"/>
+ <chemical_shift value="116.3" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="H"/>
+ <chemical_shift value="6.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="186" name="HB1"/>
+ <atom segid=" A" residue="186" name="HB2"/>
+ <atom segid=" A" residue="186" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="C"/>
+ <chemical_shift value="180.525" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="CB"/>
+ <chemical_shift value="18.22" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="CA"/>
+ <chemical_shift value="55.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="C"/>
+ <chemical_shift value="176.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="H"/>
+ <chemical_shift value="8.385" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="CA"/>
+ <chemical_shift value="47.366" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="N"/>
+ <chemical_shift value="109.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="188" name="HB1"/>
+ <atom segid=" A" residue="188" name="HB2"/>
+ <atom segid=" A" residue="188" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="C"/>
+ <chemical_shift value="180.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="CB"/>
+ <chemical_shift value="18.399" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="CA"/>
+ <chemical_shift value="54.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="N"/>
+ <chemical_shift value="127.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="H"/>
+ <chemical_shift value="8.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="189" name="HZ1"/>
+ <atom segid=" A" residue="189" name="HZ2"/>
+ <atom segid=" A" residue="189" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CB"/>
+ <chemical_shift value="31.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="C"/>
+ <chemical_shift value="180.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="H"/>
+ <chemical_shift value="7.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CA"/>
+ <chemical_shift value="59.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="N"/>
+ <chemical_shift value="115.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="190" name="HB1"/>
+ <atom segid=" A" residue="190" name="HB2"/>
+ <atom segid=" A" residue="190" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="C"/>
+ <chemical_shift value="181.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="CB"/>
+ <chemical_shift value="17.89" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="CA"/>
+ <chemical_shift value="55.835" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="N"/>
+ <chemical_shift value="124.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="H"/>
+ <chemical_shift value="8.224" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="C"/>
+ <chemical_shift value="174.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="H"/>
+ <chemical_shift value="8.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="CA"/>
+ <chemical_shift value="47.937" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="N"/>
+ <chemical_shift value="107.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="192" name="HD21"/>
+ <atom segid=" A" residue="192" name="HD22"/>
+ <atom segid=" A" residue="192" name="HD23"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="1.085" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="192" name="HD11"/>
+ <atom segid=" A" residue="192" name="HD12"/>
+ <atom segid=" A" residue="192" name="HD13"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="1.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="C"/>
+ <chemical_shift value="178.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CB"/>
+ <chemical_shift value="40.218" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CA"/>
+ <chemical_shift value="57.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="N"/>
+ <chemical_shift value="121.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CD1"/>
+ <chemical_shift value="24.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CD2"/>
+ <chemical_shift value="25.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="H"/>
+ <chemical_shift value="8.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="193" name="HG21"/>
+ <atom segid=" A" residue="193" name="HG22"/>
+ <atom segid=" A" residue="193" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="C"/>
+ <chemical_shift value="175.23" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CB"/>
+ <chemical_shift value="69.081" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CA"/>
+ <chemical_shift value="67.423" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="N"/>
+ <chemical_shift value="116.486" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="H"/>
+ <chemical_shift value="8.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="194" name="HD1"/>
+ <atom segid=" A" residue="194" name="HD2"/>
+ <atom segid=" A" residue="194" name="HE1"/>
+ <atom segid=" A" residue="194" name="HE2"/>
+ <atom segid=" A" residue="194" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="C"/>
+ <chemical_shift value="177.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CB"/>
+ <chemical_shift value="39.196" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CA"/>
+ <chemical_shift value="62.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="N"/>
+ <chemical_shift value="122.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="H"/>
+ <chemical_shift value="7.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="195" name="HD21"/>
+ <atom segid=" A" residue="195" name="HD22"/>
+ <atom segid=" A" residue="195" name="HD23"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="195" name="HD11"/>
+ <atom segid=" A" residue="195" name="HD12"/>
+ <atom segid=" A" residue="195" name="HD13"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="C"/>
+ <chemical_shift value="178.132" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CB"/>
+ <chemical_shift value="41.352" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CA"/>
+ <chemical_shift value="58.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="N"/>
+ <chemical_shift value="119.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CD1"/>
+ <chemical_shift value="23.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CD2"/>
+ <chemical_shift value="25.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="H"/>
+ <chemical_shift value="7.712" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="196" name="HG21"/>
+ <atom segid=" A" residue="196" name="HG22"/>
+ <atom segid=" A" residue="196" name="HG23"/>
+ <chemical_shift value="0.856" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="196" name="HG11"/>
+ <atom segid=" A" residue="196" name="HG12"/>
+ <atom segid=" A" residue="196" name="HG13"/>
+ <chemical_shift value="0.856" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="C"/>
+ <chemical_shift value="178.464" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CB"/>
+ <chemical_shift value="31.053" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CA"/>
+ <chemical_shift value="67.271" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="N"/>
+ <chemical_shift value="117.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CG1"/>
+ <chemical_shift value="21.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="H"/>
+ <chemical_shift value="8.589" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CG2"/>
+ <chemical_shift value="23.319" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="C"/>
+ <chemical_shift value="179.361" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CB"/>
+ <chemical_shift value="39.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CA"/>
+ <chemical_shift value="58.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="N"/>
+ <chemical_shift value="122.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="H"/>
+ <chemical_shift value="8.58" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="198" name="HD21"/>
+ <atom segid=" A" residue="198" name="HD22"/>
+ <atom segid=" A" residue="198" name="HD23"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="1.018" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="198" name="HD11"/>
+ <atom segid=" A" residue="198" name="HD12"/>
+ <atom segid=" A" residue="198" name="HD13"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="1.018" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="C"/>
+ <chemical_shift value="179.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CB"/>
+ <chemical_shift value="42.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CA"/>
+ <chemical_shift value="58.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="N"/>
+ <chemical_shift value="120.213" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CD1"/>
+ <chemical_shift value="25.598" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CD2"/>
+ <chemical_shift value="23.461" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="H"/>
+ <chemical_shift value="7.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="199" name="HG21"/>
+ <atom segid=" A" residue="199" name="HG22"/>
+ <atom segid=" A" residue="199" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.743" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="199" name="HD11"/>
+ <atom segid=" A" residue="199" name="HD12"/>
+ <atom segid=" A" residue="199" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.743" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="C"/>
+ <chemical_shift value="181.156" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CB"/>
+ <chemical_shift value="38.209" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CA"/>
+ <chemical_shift value="63.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="N"/>
+ <chemical_shift value="119.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CD1"/>
+ <chemical_shift value="14.222" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="H"/>
+ <chemical_shift value="7.434" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="200" name="HZ1"/>
+ <atom segid=" A" residue="200" name="HZ2"/>
+ <atom segid=" A" residue="200" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CB"/>
+ <chemical_shift value="32.127" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="C"/>
+ <chemical_shift value="178.834" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="H"/>
+ <chemical_shift value="9.393" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CA"/>
+ <chemical_shift value="59.943" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="N"/>
+ <chemical_shift value="124.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="C"/>
+ <chemical_shift value="173.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CB"/>
+ <chemical_shift value="38.686" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CA"/>
+ <chemical_shift value="53.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="N"/>
+ <chemical_shift value="113.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="H"/>
+ <chemical_shift value="8.004" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="202" name="HZ1"/>
+ <atom segid=" A" residue="202" name="HZ2"/>
+ <atom segid=" A" residue="202" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CB"/>
+ <chemical_shift value="27.266" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="C"/>
+ <chemical_shift value="175.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="H"/>
+ <chemical_shift value="7.932" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CA"/>
+ <chemical_shift value="57.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="N"/>
+ <chemical_shift value="111.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="C"/>
+ <chemical_shift value="175.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CB"/>
+ <chemical_shift value="28.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CA"/>
+ <chemical_shift value="57.268" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="N"/>
+ <chemical_shift value="116.235" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="H"/>
+ <chemical_shift value="8.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="204" name="HE1"/>
+ <atom segid=" A" residue="204" name="HE2"/>
+ <atom segid=" A" residue="204" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="C"/>
+ <chemical_shift value="173.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CB"/>
+ <chemical_shift value="37.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CA"/>
+ <chemical_shift value="54.646" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="N"/>
+ <chemical_shift value="114.03" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="H"/>
+ <chemical_shift value="7.477" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="C"/>
+ <chemical_shift value="176.088" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CB"/>
+ <chemical_shift value="40.287" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CA"/>
+ <chemical_shift value="52.185" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="N"/>
+ <chemical_shift value="118.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="H"/>
+ <chemical_shift value="8.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="206" name="HB1"/>
+ <atom segid=" A" residue="206" name="HB2"/>
+ <atom segid=" A" residue="206" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="C"/>
+ <chemical_shift value="176.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="CB"/>
+ <chemical_shift value="18.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="CA"/>
+ <chemical_shift value="54.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="N"/>
+ <chemical_shift value="125.067" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="H"/>
+ <chemical_shift value="9.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="C"/>
+ <chemical_shift value="176.539" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CB"/>
+ <chemical_shift value="39.943" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CA"/>
+ <chemical_shift value="53.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="N"/>
+ <chemical_shift value="112.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="H"/>
+ <chemical_shift value="8.172" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="208" name="HG21"/>
+ <atom segid=" A" residue="208" name="HG22"/>
+ <atom segid=" A" residue="208" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="C"/>
+ <chemical_shift value="173.305" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CB"/>
+ <chemical_shift value="69.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CA"/>
+ <chemical_shift value="66.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="N"/>
+ <chemical_shift value="116.637" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="H"/>
+ <chemical_shift value="7.344" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="C"/>
+ <chemical_shift value="175.818" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CB"/>
+ <chemical_shift value="42.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CA"/>
+ <chemical_shift value="51.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="N"/>
+ <chemical_shift value="130.935" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="H"/>
+ <chemical_shift value="6.982" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="210" name="HD1"/>
+ <atom segid=" A" residue="210" name="HD2"/>
+ <atom segid=" A" residue="210" name="HE1"/>
+ <atom segid=" A" residue="210" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="C"/>
+ <chemical_shift value="178.37" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CB"/>
+ <chemical_shift value="39.077" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CA"/>
+ <chemical_shift value="63.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="N"/>
+ <chemical_shift value="117.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="H"/>
+ <chemical_shift value="7.858" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="C"/>
+ <chemical_shift value="177.629" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="CB"/>
+ <chemical_shift value="63.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="CA"/>
+ <chemical_shift value="61.419" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="N"/>
+ <chemical_shift value="114.682" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="H"/>
+ <chemical_shift value="8.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="212" name="HG21"/>
+ <atom segid=" A" residue="212" name="HG22"/>
+ <atom segid=" A" residue="212" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.867" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="212" name="HD11"/>
+ <atom segid=" A" residue="212" name="HD12"/>
+ <atom segid=" A" residue="212" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="C"/>
+ <chemical_shift value="179.021" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CB"/>
+ <chemical_shift value="38.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CA"/>
+ <chemical_shift value="65.023" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="N"/>
+ <chemical_shift value="124.45" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CD1"/>
+ <chemical_shift value="13.11" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="H"/>
+ <chemical_shift value="8.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="213" name="HB1"/>
+ <atom segid=" A" residue="213" name="HB2"/>
+ <atom segid=" A" residue="213" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="C"/>
+ <chemical_shift value="177.865" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="CB"/>
+ <chemical_shift value="17.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="CA"/>
+ <chemical_shift value="55.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="N"/>
+ <chemical_shift value="120.747" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="H"/>
+ <chemical_shift value="7.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="C"/>
+ <chemical_shift value="178.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CB"/>
+ <chemical_shift value="29.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CA"/>
+ <chemical_shift value="58.941" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="N"/>
+ <chemical_shift value="117.551" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="215" name="HB1"/>
+ <atom segid=" A" residue="215" name="HB2"/>
+ <atom segid=" A" residue="215" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="C"/>
+ <chemical_shift value="179.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="CB"/>
+ <chemical_shift value="18.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="CA"/>
+ <chemical_shift value="54.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="N"/>
+ <chemical_shift value="119.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="H"/>
+ <chemical_shift value="7.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="216" name="HB1"/>
+ <atom segid=" A" residue="216" name="HB2"/>
+ <atom segid=" A" residue="216" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="C"/>
+ <chemical_shift value="180.736" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="CB"/>
+ <chemical_shift value="19.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="CA"/>
+ <chemical_shift value="55.247" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="N"/>
+ <chemical_shift value="117.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="H"/>
+ <chemical_shift value="7.789" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="217" name="HD1"/>
+ <atom segid=" A" residue="217" name="HD2"/>
+ <atom segid=" A" residue="217" name="HE1"/>
+ <atom segid=" A" residue="217" name="HE2"/>
+ <atom segid=" A" residue="217" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CB"/>
+ <chemical_shift value="38.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CA"/>
+ <chemical_shift value="62.919" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="N"/>
+ <chemical_shift value="119.446" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="H"/>
+ <chemical_shift value="8.338" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="C"/>
+ <chemical_shift value="176.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CB"/>
+ <chemical_shift value="36.484" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CA"/>
+ <chemical_shift value="55.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="219" name="HZ1"/>
+ <atom segid=" A" residue="219" name="HZ2"/>
+ <atom segid=" A" residue="219" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CB"/>
+ <chemical_shift value="32.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="C"/>
+ <chemical_shift value="177.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="H"/>
+ <chemical_shift value="7.713" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CA"/>
+ <chemical_shift value="56.131" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="N"/>
+ <chemical_shift value="116.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="C"/>
+ <chemical_shift value="175.309" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="H"/>
+ <chemical_shift value="7.717" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="CA"/>
+ <chemical_shift value="46.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="N"/>
+ <chemical_shift value="108.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="C"/>
+ <chemical_shift value="175.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CB"/>
+ <chemical_shift value="30.469" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CA"/>
+ <chemical_shift value="57.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="N"/>
+ <chemical_shift value="116.369" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="H"/>
+ <chemical_shift value="8.382" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="222" name="HG21"/>
+ <atom segid=" A" residue="222" name="HG22"/>
+ <atom segid=" A" residue="222" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="C"/>
+ <chemical_shift value="172.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CB"/>
+ <chemical_shift value="70.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CA"/>
+ <chemical_shift value="58.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="N"/>
+ <chemical_shift value="110.551" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="H"/>
+ <chemical_shift value="6.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="223" name="HB1"/>
+ <atom segid=" A" residue="223" name="HB2"/>
+ <atom segid=" A" residue="223" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="C"/>
+ <chemical_shift value="176.461" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="CB"/>
+ <chemical_shift value="20.427" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="CA"/>
+ <chemical_shift value="54.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="N"/>
+ <chemical_shift value="127.376" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="H"/>
+ <chemical_shift value="8.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="224" name="HE1"/>
+ <atom segid=" A" residue="224" name="HE2"/>
+ <atom segid=" A" residue="224" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="C"/>
+ <chemical_shift value="173.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CB"/>
+ <chemical_shift value="40.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CA"/>
+ <chemical_shift value="54.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="N"/>
+ <chemical_shift value="114.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="H"/>
+ <chemical_shift value="8.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="225" name="HG21"/>
+ <atom segid=" A" residue="225" name="HG22"/>
+ <atom segid=" A" residue="225" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="C"/>
+ <chemical_shift value="171.424" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CB"/>
+ <chemical_shift value="71.023" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CA"/>
+ <chemical_shift value="59.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="N"/>
+ <chemical_shift value="113.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="H"/>
+ <chemical_shift value="9.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="226" name="HG21"/>
+ <atom segid=" A" residue="226" name="HG22"/>
+ <atom segid=" A" residue="226" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.06" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="226" name="HD11"/>
+ <atom segid=" A" residue="226" name="HD12"/>
+ <atom segid=" A" residue="226" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.06" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="C"/>
+ <chemical_shift value="174.82" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CB"/>
+ <chemical_shift value="40.344" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CA"/>
+ <chemical_shift value="60.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="N"/>
+ <chemical_shift value="122.714" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CD1"/>
+ <chemical_shift value="11.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="H"/>
+ <chemical_shift value="7.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="C"/>
+ <chemical_shift value="175.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CB"/>
+ <chemical_shift value="42.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CA"/>
+ <chemical_shift value="52.466" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="N"/>
+ <chemical_shift value="121.906" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="H"/>
+ <chemical_shift value="8.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="H"/>
+ <chemical_shift value="8.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="CA"/>
+ <chemical_shift value="42.27" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="N"/>
+ <chemical_shift value="110.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CB"/>
+ <chemical_shift value="29.552" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CA"/>
+ <chemical_shift value="62.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="H"/>
+ <chemical_shift value="5.923" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CB"/>
+ <chemical_shift value="26.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CA"/>
+ <chemical_shift value="59.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="N"/>
+ <chemical_shift value="111.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="231" name="HB1"/>
+ <atom segid=" A" residue="231" name="HB2"/>
+ <atom segid=" A" residue="231" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="CB"/>
+ <chemical_shift value="19.11" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="CA"/>
+ <chemical_shift value="52.168" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="N"/>
+ <chemical_shift value="125.512" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="H"/>
+ <chemical_shift value="6.975" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="H"/>
+ <chemical_shift value="7.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CB"/>
+ <chemical_shift value="28.673" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CA"/>
+ <chemical_shift value="58.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="N"/>
+ <chemical_shift value="118.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="235" name="HG21"/>
+ <atom segid=" A" residue="235" name="HG22"/>
+ <atom segid=" A" residue="235" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="235" name="HD11"/>
+ <atom segid=" A" residue="235" name="HD12"/>
+ <atom segid=" A" residue="235" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="237" name="HG21"/>
+ <atom segid=" A" residue="237" name="HG22"/>
+ <atom segid=" A" residue="237" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="239" name="HZ1"/>
+ <atom segid=" A" residue="239" name="HZ2"/>
+ <atom segid=" A" residue="239" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="240" name="HG21"/>
+ <atom segid=" A" residue="240" name="HG22"/>
+ <atom segid=" A" residue="240" name="HG23"/>
+ <atom segid=" A" residue="240" name="HG11"/>
+ <atom segid=" A" residue="240" name="HG12"/>
+ <atom segid=" A" residue="240" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CB"/>
+ <chemical_shift value="37.371" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="242" name="HD1"/>
+ <atom segid=" A" residue="242" name="HD2"/>
+ <atom segid=" A" residue="242" name="HE1"/>
+ <atom segid=" A" residue="242" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="C"/>
+ <chemical_shift value="174.489" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CB"/>
+ <chemical_shift value="41.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CA"/>
+ <chemical_shift value="54.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="N"/>
+ <chemical_shift value="121.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="C"/>
+ <chemical_shift value="171.154" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="H"/>
+ <chemical_shift value="8.494" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="CA"/>
+ <chemical_shift value="42.935" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="N"/>
+ <chemical_shift value="107.501" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="244" name="HG21"/>
+ <atom segid=" A" residue="244" name="HG22"/>
+ <atom segid=" A" residue="244" name="HG23"/>
+ <chemical_shift value="0.636" error="0.0"/>
+ <chemical_shift value="1.072" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="244" name="HG11"/>
+ <atom segid=" A" residue="244" name="HG12"/>
+ <atom segid=" A" residue="244" name="HG13"/>
+ <chemical_shift value="0.636" error="0.0"/>
+ <chemical_shift value="1.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="C"/>
+ <chemical_shift value="174.872" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CB"/>
+ <chemical_shift value="34.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CA"/>
+ <chemical_shift value="61.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="N"/>
+ <chemical_shift value="120.896" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CG1"/>
+ <chemical_shift value="22.083" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="H"/>
+ <chemical_shift value="8.229" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CG2"/>
+ <chemical_shift value="21.606" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="245" name="HG21"/>
+ <atom segid=" A" residue="245" name="HG22"/>
+ <atom segid=" A" residue="245" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="C"/>
+ <chemical_shift value="174.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CB"/>
+ <chemical_shift value="71.559" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CA"/>
+ <chemical_shift value="59.071" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="N"/>
+ <chemical_shift value="119.808" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="H"/>
+ <chemical_shift value="9.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="246" name="HG21"/>
+ <atom segid=" A" residue="246" name="HG22"/>
+ <atom segid=" A" residue="246" name="HG23"/>
+ <chemical_shift value="0.983" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="246" name="HG11"/>
+ <atom segid=" A" residue="246" name="HG12"/>
+ <atom segid=" A" residue="246" name="HG13"/>
+ <chemical_shift value="0.983" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="C"/>
+ <chemical_shift value="175.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CB"/>
+ <chemical_shift value="32.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CA"/>
+ <chemical_shift value="62.433" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="N"/>
+ <chemical_shift value="123.607" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CG1"/>
+ <chemical_shift value="20.441" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CG2"/>
+ <chemical_shift value="21.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="247" name="HD21"/>
+ <atom segid=" A" residue="247" name="HD22"/>
+ <atom segid=" A" residue="247" name="HD23"/>
+ <chemical_shift value="0.645" error="0.0"/>
+ <chemical_shift value="0.663" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="247" name="HD11"/>
+ <atom segid=" A" residue="247" name="HD12"/>
+ <atom segid=" A" residue="247" name="HD13"/>
+ <chemical_shift value="0.645" error="0.0"/>
+ <chemical_shift value="0.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CB"/>
+ <chemical_shift value="40.229" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CA"/>
+ <chemical_shift value="54.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="N"/>
+ <chemical_shift value="125.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CD1"/>
+ <chemical_shift value="25.833" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CD2"/>
+ <chemical_shift value="23.824" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="H"/>
+ <chemical_shift value="8.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="C"/>
+ <chemical_shift value="175.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CB"/>
+ <chemical_shift value="30.183" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CA"/>
+ <chemical_shift value="61.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="249" name="HG21"/>
+ <atom segid=" A" residue="249" name="HG22"/>
+ <atom segid=" A" residue="249" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="C"/>
+ <chemical_shift value="174.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CB"/>
+ <chemical_shift value="71.441" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CA"/>
+ <chemical_shift value="61.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="N"/>
+ <chemical_shift value="111.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="H"/>
+ <chemical_shift value="8.815" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="250" name="HD1"/>
+ <atom segid=" A" residue="250" name="HD2"/>
+ <atom segid=" A" residue="250" name="HE1"/>
+ <atom segid=" A" residue="250" name="HE2"/>
+ <atom segid=" A" residue="250" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="C"/>
+ <chemical_shift value="174.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CB"/>
+ <chemical_shift value="41.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CA"/>
+ <chemical_shift value="56.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="N"/>
+ <chemical_shift value="121.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="H"/>
+ <chemical_shift value="9.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="251" name="HZ1"/>
+ <atom segid=" A" residue="251" name="HZ2"/>
+ <atom segid=" A" residue="251" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CB"/>
+ <chemical_shift value="28.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="C"/>
+ <chemical_shift value="177.723" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="H"/>
+ <chemical_shift value="10.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CA"/>
+ <chemical_shift value="57.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="N"/>
+ <chemical_shift value="129.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="C"/>
+ <chemical_shift value="173.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="H"/>
+ <chemical_shift value="9.031" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="CA"/>
+ <chemical_shift value="45.086" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="N"/>
+ <chemical_shift value="103.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CB"/>
+ <chemical_shift value="29.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CA"/>
+ <chemical_shift value="52.486" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="N"/>
+ <chemical_shift value="122.357" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="H"/>
+ <chemical_shift value="8.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="C"/>
+ <chemical_shift value="178.676" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CB"/>
+ <chemical_shift value="31.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CA"/>
+ <chemical_shift value="62.977" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="C"/>
+ <chemical_shift value="173.658" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="CB"/>
+ <chemical_shift value="64.942" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="CA"/>
+ <chemical_shift value="62.323" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="N"/>
+ <chemical_shift value="117.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="H"/>
+ <chemical_shift value="8.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="256" name="HZ1"/>
+ <atom segid=" A" residue="256" name="HZ2"/>
+ <atom segid=" A" residue="256" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CB"/>
+ <chemical_shift value="33.307" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="H"/>
+ <chemical_shift value="7.639" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CA"/>
+ <chemical_shift value="53.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="N"/>
+ <chemical_shift value="123.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="C"/>
+ <chemical_shift value="177.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CB"/>
+ <chemical_shift value="31.379" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CA"/>
+ <chemical_shift value="62.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="258" name="HD1"/>
+ <atom segid=" A" residue="258" name="HD2"/>
+ <atom segid=" A" residue="258" name="HE1"/>
+ <atom segid=" A" residue="258" name="HE2"/>
+ <atom segid=" A" residue="258" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="C"/>
+ <chemical_shift value="177.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CB"/>
+ <chemical_shift value="40.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CA"/>
+ <chemical_shift value="58.534" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="N"/>
+ <chemical_shift value="118.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="H"/>
+ <chemical_shift value="9.265" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="259" name="HG21"/>
+ <atom segid=" A" residue="259" name="HG22"/>
+ <atom segid=" A" residue="259" name="HG23"/>
+ <chemical_shift value="0.98" error="0.0"/>
+ <chemical_shift value="0.925" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="259" name="HG11"/>
+ <atom segid=" A" residue="259" name="HG12"/>
+ <atom segid=" A" residue="259" name="HG13"/>
+ <chemical_shift value="0.98" error="0.0"/>
+ <chemical_shift value="0.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="C"/>
+ <chemical_shift value="176.569" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CB"/>
+ <chemical_shift value="33.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CA"/>
+ <chemical_shift value="62.078" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="N"/>
+ <chemical_shift value="121.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CG1"/>
+ <chemical_shift value="21.509" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="H"/>
+ <chemical_shift value="8.777" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CG2"/>
+ <chemical_shift value="22.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="C"/>
+ <chemical_shift value="171.463" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="H"/>
+ <chemical_shift value="8.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="CA"/>
+ <chemical_shift value="44.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="N"/>
+ <chemical_shift value="116.16" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="261" name="HG21"/>
+ <atom segid=" A" residue="261" name="HG22"/>
+ <atom segid=" A" residue="261" name="HG23"/>
+ <chemical_shift value="0.565" error="0.0"/>
+ <chemical_shift value="0.679" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="261" name="HG11"/>
+ <atom segid=" A" residue="261" name="HG12"/>
+ <atom segid=" A" residue="261" name="HG13"/>
+ <chemical_shift value="0.565" error="0.0"/>
+ <chemical_shift value="0.679" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="C"/>
+ <chemical_shift value="179.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CB"/>
+ <chemical_shift value="32.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CA"/>
+ <chemical_shift value="60.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="N"/>
+ <chemical_shift value="128.971" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CG1"/>
+ <chemical_shift value="20.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="H"/>
+ <chemical_shift value="11.175" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CG2"/>
+ <chemical_shift value="20.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="262" name="HD21"/>
+ <atom segid=" A" residue="262" name="HD22"/>
+ <atom segid=" A" residue="262" name="HD23"/>
+ <chemical_shift value="0.885" error="0.0"/>
+ <chemical_shift value="0.806" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="262" name="HD11"/>
+ <atom segid=" A" residue="262" name="HD12"/>
+ <atom segid=" A" residue="262" name="HD13"/>
+ <chemical_shift value="0.885" error="0.0"/>
+ <chemical_shift value="0.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="C"/>
+ <chemical_shift value="175.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CB"/>
+ <chemical_shift value="41.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CA"/>
+ <chemical_shift value="56.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="N"/>
+ <chemical_shift value="134.056" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CD1"/>
+ <chemical_shift value="22.681" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CD2"/>
+ <chemical_shift value="25.314" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="H"/>
+ <chemical_shift value="8.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="C"/>
+ <chemical_shift value="170.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="CB"/>
+ <chemical_shift value="66.154" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="CA"/>
+ <chemical_shift value="58.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="N"/>
+ <chemical_shift value="126.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="H"/>
+ <chemical_shift value="8.77" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="264" name="HB1"/>
+ <atom segid=" A" residue="264" name="HB2"/>
+ <atom segid=" A" residue="264" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="C"/>
+ <chemical_shift value="176.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="CB"/>
+ <chemical_shift value="20.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="CA"/>
+ <chemical_shift value="49.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="N"/>
+ <chemical_shift value="123.788" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="H"/>
+ <chemical_shift value="9.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="C"/>
+ <chemical_shift value="171.119" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="H"/>
+ <chemical_shift value="9.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="CA"/>
+ <chemical_shift value="42.908" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="N"/>
+ <chemical_shift value="110.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="266" name="HG21"/>
+ <atom segid=" A" residue="266" name="HG22"/>
+ <atom segid=" A" residue="266" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.915" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="266" name="HD11"/>
+ <atom segid=" A" residue="266" name="HD12"/>
+ <atom segid=" A" residue="266" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.915" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="C"/>
+ <chemical_shift value="175.264" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CB"/>
+ <chemical_shift value="39.519" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CA"/>
+ <chemical_shift value="59.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="N"/>
+ <chemical_shift value="123.632" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CD1"/>
+ <chemical_shift value="13.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="H"/>
+ <chemical_shift value="10.299" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="C"/>
+ <chemical_shift value="177.436" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CB"/>
+ <chemical_shift value="38.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CA"/>
+ <chemical_shift value="53.657" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="N"/>
+ <chemical_shift value="125.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="H"/>
+ <chemical_shift value="8.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="268" name="HB1"/>
+ <atom segid=" A" residue="268" name="HB2"/>
+ <atom segid=" A" residue="268" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="C"/>
+ <chemical_shift value="178.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="CB"/>
+ <chemical_shift value="17.854" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="CA"/>
+ <chemical_shift value="55.511" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="N"/>
+ <chemical_shift value="131.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="H"/>
+ <chemical_shift value="8.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="269" name="HB2"/>
+ <atom segid=" A" residue="269" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="C"/>
+ <chemical_shift value="178.117" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="CB"/>
+ <chemical_shift value="18.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="CA"/>
+ <chemical_shift value="51.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="N"/>
+ <chemical_shift value="117.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="CB"/>
+ <chemical_shift value="64.366" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="CA"/>
+ <chemical_shift value="56.356" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="N"/>
+ <chemical_shift value="112.93" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="H"/>
+ <chemical_shift value="7.621" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="C"/>
+ <chemical_shift value="175.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CB"/>
+ <chemical_shift value="30.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CA"/>
+ <chemical_shift value="63.726" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="C"/>
+ <chemical_shift value="176.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CB"/>
+ <chemical_shift value="40.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CA"/>
+ <chemical_shift value="52.889" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="N"/>
+ <chemical_shift value="119.716" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="H"/>
+ <chemical_shift value="8.881" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="273" name="HZ1"/>
+ <atom segid=" A" residue="273" name="HZ2"/>
+ <atom segid=" A" residue="273" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CB"/>
+ <chemical_shift value="31.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="C"/>
+ <chemical_shift value="179.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="H"/>
+ <chemical_shift value="7.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CA"/>
+ <chemical_shift value="61.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="N"/>
+ <chemical_shift value="119.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="C"/>
+ <chemical_shift value="179.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CB"/>
+ <chemical_shift value="27.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CA"/>
+ <chemical_shift value="59.973" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="N"/>
+ <chemical_shift value="118.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="H"/>
+ <chemical_shift value="8.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="275" name="HD21"/>
+ <atom segid=" A" residue="275" name="HD22"/>
+ <atom segid=" A" residue="275" name="HD23"/>
+ <chemical_shift value="0.947" error="0.0"/>
+ <chemical_shift value="0.933" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="275" name="HD11"/>
+ <atom segid=" A" residue="275" name="HD12"/>
+ <atom segid=" A" residue="275" name="HD13"/>
+ <chemical_shift value="0.947" error="0.0"/>
+ <chemical_shift value="0.933" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="C"/>
+ <chemical_shift value="178.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CB"/>
+ <chemical_shift value="42.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CA"/>
+ <chemical_shift value="57.369" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="N"/>
+ <chemical_shift value="120.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CD1"/>
+ <chemical_shift value="25.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CD2"/>
+ <chemical_shift value="22.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="H"/>
+ <chemical_shift value="7.385" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="276" name="HB1"/>
+ <atom segid=" A" residue="276" name="HB2"/>
+ <atom segid=" A" residue="276" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="C"/>
+ <chemical_shift value="178.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="CB"/>
+ <chemical_shift value="17.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="CA"/>
+ <chemical_shift value="55.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="N"/>
+ <chemical_shift value="120.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="H"/>
+ <chemical_shift value="8.405" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="277" name="HZ1"/>
+ <atom segid=" A" residue="277" name="HZ2"/>
+ <atom segid=" A" residue="277" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CB"/>
+ <chemical_shift value="32.345" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="C"/>
+ <chemical_shift value="177.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="H"/>
+ <chemical_shift value="7.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CA"/>
+ <chemical_shift value="60.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="N"/>
+ <chemical_shift value="118.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="C"/>
+ <chemical_shift value="179.24" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CB"/>
+ <chemical_shift value="29.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CA"/>
+ <chemical_shift value="59.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="N"/>
+ <chemical_shift value="118.647" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="H"/>
+ <chemical_shift value="7.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="279" name="HD1"/>
+ <atom segid=" A" residue="279" name="HD2"/>
+ <atom segid=" A" residue="279" name="HE1"/>
+ <atom segid=" A" residue="279" name="HE2"/>
+ <atom segid=" A" residue="279" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="C"/>
+ <chemical_shift value="177.602" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CB"/>
+ <chemical_shift value="38.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CA"/>
+ <chemical_shift value="61.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="N"/>
+ <chemical_shift value="118.378" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="280" name="HD21"/>
+ <atom segid=" A" residue="280" name="HD22"/>
+ <atom segid=" A" residue="280" name="HD23"/>
+ <chemical_shift value="0.71" error="0.0"/>
+ <chemical_shift value="0.672" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="280" name="HD11"/>
+ <atom segid=" A" residue="280" name="HD12"/>
+ <atom segid=" A" residue="280" name="HD13"/>
+ <chemical_shift value="0.71" error="0.0"/>
+ <chemical_shift value="0.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="C"/>
+ <chemical_shift value="177.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CB"/>
+ <chemical_shift value="40.671" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CA"/>
+ <chemical_shift value="58.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="N"/>
+ <chemical_shift value="120.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CD1"/>
+ <chemical_shift value="25.779" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CD2"/>
+ <chemical_shift value="23.405" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="H"/>
+ <chemical_shift value="8.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="C"/>
+ <chemical_shift value="177.096" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CB"/>
+ <chemical_shift value="29.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CA"/>
+ <chemical_shift value="59.622" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="N"/>
+ <chemical_shift value="112.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="H"/>
+ <chemical_shift value="8.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="C"/>
+ <chemical_shift value="175.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CB"/>
+ <chemical_shift value="38.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CA"/>
+ <chemical_shift value="53.164" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="N"/>
+ <chemical_shift value="108.811" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="H"/>
+ <chemical_shift value="7.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="283" name="HD1"/>
+ <atom segid=" A" residue="283" name="HD2"/>
+ <atom segid=" A" residue="283" name="HE1"/>
+ <atom segid=" A" residue="283" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="C"/>
+ <chemical_shift value="176.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CB"/>
+ <chemical_shift value="38.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CA"/>
+ <chemical_shift value="59.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="N"/>
+ <chemical_shift value="116.373" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="H"/>
+ <chemical_shift value="7.164" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="284" name="HD21"/>
+ <atom segid=" A" residue="284" name="HD22"/>
+ <atom segid=" A" residue="284" name="HD23"/>
+ <chemical_shift value="1.039" error="0.0"/>
+ <chemical_shift value="0.843" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="284" name="HD11"/>
+ <atom segid=" A" residue="284" name="HD12"/>
+ <atom segid=" A" residue="284" name="HD13"/>
+ <chemical_shift value="1.039" error="0.0"/>
+ <chemical_shift value="0.843" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="C"/>
+ <chemical_shift value="176.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CB"/>
+ <chemical_shift value="41.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CA"/>
+ <chemical_shift value="58.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="N"/>
+ <chemical_shift value="121.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CD1"/>
+ <chemical_shift value="23.945" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CD2"/>
+ <chemical_shift value="27.398" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="H"/>
+ <chemical_shift value="8.101" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="285" name="HD21"/>
+ <atom segid=" A" residue="285" name="HD22"/>
+ <atom segid=" A" residue="285" name="HD23"/>
+ <chemical_shift value="1.119" error="0.0"/>
+ <chemical_shift value="1.052" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="285" name="HD11"/>
+ <atom segid=" A" residue="285" name="HD12"/>
+ <atom segid=" A" residue="285" name="HD13"/>
+ <chemical_shift value="1.119" error="0.0"/>
+ <chemical_shift value="1.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="C"/>
+ <chemical_shift value="174.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CB"/>
+ <chemical_shift value="38.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CA"/>
+ <chemical_shift value="54.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="N"/>
+ <chemical_shift value="119.204" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CD1"/>
+ <chemical_shift value="25.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CD2"/>
+ <chemical_shift value="24.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="H"/>
+ <chemical_shift value="7.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="286" name="HG21"/>
+ <atom segid=" A" residue="286" name="HG22"/>
+ <atom segid=" A" residue="286" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="C"/>
+ <chemical_shift value="174.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CB"/>
+ <chemical_shift value="73.569" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CA"/>
+ <chemical_shift value="59.007" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="N"/>
+ <chemical_shift value="108.713" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="H"/>
+ <chemical_shift value="8.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="C"/>
+ <chemical_shift value="177.87" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CB"/>
+ <chemical_shift value="39.534" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CA"/>
+ <chemical_shift value="58.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="N"/>
+ <chemical_shift value="122.217" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="H"/>
+ <chemical_shift value="8.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="C"/>
+ <chemical_shift value="180.161" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CB"/>
+ <chemical_shift value="29.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CA"/>
+ <chemical_shift value="59.339" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="N"/>
+ <chemical_shift value="115.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="H"/>
+ <chemical_shift value="8.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="175.256" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="8.328" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="CA"/>
+ <chemical_shift value="46.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="N"/>
+ <chemical_shift value="112.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
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+ <atom segid=" A" residue="290" name="HD22"/>
+ <atom segid=" A" residue="290" name="HD23"/>
+ <chemical_shift value="0.792" error="0.0"/>
+ <chemical_shift value="1.074" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="290" name="HD11"/>
+ <atom segid=" A" residue="290" name="HD12"/>
+ <atom segid=" A" residue="290" name="HD13"/>
+ <chemical_shift value="0.792" error="0.0"/>
+ <chemical_shift value="1.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="C"/>
+ <chemical_shift value="179.873" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CB"/>
+ <chemical_shift value="41.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CA"/>
+ <chemical_shift value="57.262" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="N"/>
+ <chemical_shift value="119.553" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CD1"/>
+ <chemical_shift value="27.886" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CD2"/>
+ <chemical_shift value="21.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="H"/>
+ <chemical_shift value="8.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="C"/>
+ <chemical_shift value="178.136" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CB"/>
+ <chemical_shift value="29.033" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CA"/>
+ <chemical_shift value="59.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="N"/>
+ <chemical_shift value="120.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="H"/>
+ <chemical_shift value="7.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="292" name="HB1"/>
+ <atom segid=" A" residue="292" name="HB2"/>
+ <atom segid=" A" residue="292" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="C"/>
+ <chemical_shift value="180.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="CB"/>
+ <chemical_shift value="17.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="CA"/>
+ <chemical_shift value="55.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="N"/>
+ <chemical_shift value="119.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="H"/>
+ <chemical_shift value="7.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="293" name="HG21"/>
+ <atom segid=" A" residue="293" name="HG22"/>
+ <atom segid=" A" residue="293" name="HG23"/>
+ <chemical_shift value="0.901" error="0.0"/>
+ <chemical_shift value="1.004" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="293" name="HG11"/>
+ <atom segid=" A" residue="293" name="HG12"/>
+ <atom segid=" A" residue="293" name="HG13"/>
+ <chemical_shift value="0.901" error="0.0"/>
+ <chemical_shift value="1.004" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="C"/>
+ <chemical_shift value="177.079" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CB"/>
+ <chemical_shift value="32.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CA"/>
+ <chemical_shift value="67.318" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="N"/>
+ <chemical_shift value="115.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CG1"/>
+ <chemical_shift value="21.422" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="H"/>
+ <chemical_shift value="7.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CG2"/>
+ <chemical_shift value="22.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="C"/>
+ <chemical_shift value="176.45" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CB"/>
+ <chemical_shift value="40.911" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CA"/>
+ <chemical_shift value="56.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="N"/>
+ <chemical_shift value="117.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="H"/>
+ <chemical_shift value="8.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="295" name="HZ1"/>
+ <atom segid=" A" residue="295" name="HZ2"/>
+ <atom segid=" A" residue="295" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CB"/>
+ <chemical_shift value="31.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="C"/>
+ <chemical_shift value="177.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CA"/>
+ <chemical_shift value="58.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="N"/>
+ <chemical_shift value="115.927" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="C"/>
+ <chemical_shift value="176.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CB"/>
+ <chemical_shift value="41.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CA"/>
+ <chemical_shift value="56.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="N"/>
+ <chemical_shift value="118.991" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="H"/>
+ <chemical_shift value="7.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="297" name="HZ1"/>
+ <atom segid=" A" residue="297" name="HZ2"/>
+ <atom segid=" A" residue="297" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CB"/>
+ <chemical_shift value="34.952" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="H"/>
+ <chemical_shift value="7.654" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CA"/>
+ <chemical_shift value="52.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="N"/>
+ <chemical_shift value="115.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="C"/>
+ <chemical_shift value="178.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CB"/>
+ <chemical_shift value="31.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CA"/>
+ <chemical_shift value="63.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="299" name="HD21"/>
+ <atom segid=" A" residue="299" name="HD22"/>
+ <atom segid=" A" residue="299" name="HD23"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="299" name="HD11"/>
+ <atom segid=" A" residue="299" name="HD12"/>
+ <atom segid=" A" residue="299" name="HD13"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="C"/>
+ <chemical_shift value="177.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CB"/>
+ <chemical_shift value="43.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CA"/>
+ <chemical_shift value="55.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="N"/>
+ <chemical_shift value="121.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CD1"/>
+ <chemical_shift value="26.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CD2"/>
+ <chemical_shift value="22.958" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="H"/>
+ <chemical_shift value="8.532" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="C"/>
+ <chemical_shift value="174.043" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="H"/>
+ <chemical_shift value="8.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="CA"/>
+ <chemical_shift value="44.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="N"/>
+ <chemical_shift value="103.351" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="301" name="HB1"/>
+ <atom segid=" A" residue="301" name="HB2"/>
+ <atom segid=" A" residue="301" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="C"/>
+ <chemical_shift value="177.667" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="CB"/>
+ <chemical_shift value="19.844" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="CA"/>
+ <chemical_shift value="51.558" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="N"/>
+ <chemical_shift value="123.834" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="H"/>
+ <chemical_shift value="7.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="302" name="HG22"/>
+ <atom segid=" A" residue="302" name="HG23"/>
+ <chemical_shift value="1.262" error="0.0"/>
+ <chemical_shift value="1.059" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="302" name="HG11"/>
+ <atom segid=" A" residue="302" name="HG12"/>
+ <atom segid=" A" residue="302" name="HG13"/>
+ <chemical_shift value="1.262" error="0.0"/>
+ <chemical_shift value="1.059" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="C"/>
+ <chemical_shift value="174.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CB"/>
+ <chemical_shift value="35.614" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CA"/>
+ <chemical_shift value="59.9" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="N"/>
+ <chemical_shift value="110.163" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CG1"/>
+ <chemical_shift value="22.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="H"/>
+ <chemical_shift value="8.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CG2"/>
+ <chemical_shift value="19.07" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="303" name="HB1"/>
+ <atom segid=" A" residue="303" name="HB2"/>
+ <atom segid=" A" residue="303" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="C"/>
+ <chemical_shift value="175.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="CB"/>
+ <chemical_shift value="19.491" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="CA"/>
+ <chemical_shift value="53.039" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="N"/>
+ <chemical_shift value="117.932" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="H"/>
+ <chemical_shift value="7.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="304" name="HD22"/>
+ <atom segid=" A" residue="304" name="HD23"/>
+ <chemical_shift value="0.702" error="0.0"/>
+ <chemical_shift value="0.848" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="304" name="HD11"/>
+ <atom segid=" A" residue="304" name="HD12"/>
+ <atom segid=" A" residue="304" name="HD13"/>
+ <chemical_shift value="0.702" error="0.0"/>
+ <chemical_shift value="0.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="C"/>
+ <chemical_shift value="175.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CB"/>
+ <chemical_shift value="44.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CA"/>
+ <chemical_shift value="54.335" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="N"/>
+ <chemical_shift value="114.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="24.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CD2"/>
+ <chemical_shift value="26.586" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="H"/>
+ <chemical_shift value="6.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="305" name="HZ2"/>
+ <atom segid=" A" residue="305" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CB"/>
+ <chemical_shift value="31.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="C"/>
+ <chemical_shift value="178.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="H"/>
+ <chemical_shift value="8.043" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CA"/>
+ <chemical_shift value="60.428" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="N"/>
+ <chemical_shift value="129.631" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="C"/>
+ <chemical_shift value="176.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="CB"/>
+ <chemical_shift value="60.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="CA"/>
+ <chemical_shift value="61.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="N"/>
+ <chemical_shift value="111.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="H"/>
+ <chemical_shift value="8.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="307" name="HD1"/>
+ <atom segid=" A" residue="307" name="HD2"/>
+ <atom segid=" A" residue="307" name="HE1"/>
+ <atom segid=" A" residue="307" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="C"/>
+ <chemical_shift value="177.811" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CB"/>
+ <chemical_shift value="38.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CA"/>
+ <chemical_shift value="58.904" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="N"/>
+ <chemical_shift value="122.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="H"/>
+ <chemical_shift value="6.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="C"/>
+ <chemical_shift value="177.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CB"/>
+ <chemical_shift value="26.173" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CA"/>
+ <chemical_shift value="58.466" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="N"/>
+ <chemical_shift value="122.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="H"/>
+ <chemical_shift value="8.473" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="C"/>
+ <chemical_shift value="178.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CB"/>
+ <chemical_shift value="28.862" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CA"/>
+ <chemical_shift value="58.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="N"/>
+ <chemical_shift value="114.962" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="H"/>
+ <chemical_shift value="7.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="C"/>
+ <chemical_shift value="178.868" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CB"/>
+ <chemical_shift value="29.333" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CA"/>
+ <chemical_shift value="57.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="N"/>
+ <chemical_shift value="116.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="H"/>
+ <chemical_shift value="7.092" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="311" name="HD21"/>
+ <atom segid=" A" residue="311" name="HD22"/>
+ <atom segid=" A" residue="311" name="HD23"/>
+ <chemical_shift value="0.797" error="0.0"/>
+ <chemical_shift value="0.87" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="311" name="HD11"/>
+ <atom segid=" A" residue="311" name="HD12"/>
+ <atom segid=" A" residue="311" name="HD13"/>
+ <chemical_shift value="0.797" error="0.0"/>
+ <chemical_shift value="0.87" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="C"/>
+ <chemical_shift value="179.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CB"/>
+ <chemical_shift value="41.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CA"/>
+ <chemical_shift value="57.324" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="N"/>
+ <chemical_shift value="120.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CD1"/>
+ <chemical_shift value="26.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CD2"/>
+ <chemical_shift value="22.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="H"/>
+ <chemical_shift value="8.021" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="312" name="HB1"/>
+ <atom segid=" A" residue="312" name="HB2"/>
+ <atom segid=" A" residue="312" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="C"/>
+ <chemical_shift value="174.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="CB"/>
+ <chemical_shift value="17.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="CA"/>
+ <chemical_shift value="54.037" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="N"/>
+ <chemical_shift value="114.676" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="H"/>
+ <chemical_shift value="8.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="313" name="HZ1"/>
+ <atom segid=" A" residue="313" name="HZ2"/>
+ <atom segid=" A" residue="313" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CB"/>
+ <chemical_shift value="31.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="C"/>
+ <chemical_shift value="177.97" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="H"/>
+ <chemical_shift value="6.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CA"/>
+ <chemical_shift value="58.418" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="N"/>
+ <chemical_shift value="119.315" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CB"/>
+ <chemical_shift value="41.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CA"/>
+ <chemical_shift value="50.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="N"/>
+ <chemical_shift value="121.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="H"/>
+ <chemical_shift value="8.311" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="C"/>
+ <chemical_shift value="179.227" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CB"/>
+ <chemical_shift value="32.168" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CA"/>
+ <chemical_shift value="64.525" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CB"/>
+ <chemical_shift value="29.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="C"/>
+ <chemical_shift value="179.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="H"/>
+ <chemical_shift value="8.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CA"/>
+ <chemical_shift value="58.813" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="N"/>
+ <chemical_shift value="116.913" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="317" name="HG21"/>
+ <atom segid=" A" residue="317" name="HG22"/>
+ <atom segid=" A" residue="317" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="1.118" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="317" name="HD11"/>
+ <atom segid=" A" residue="317" name="HD12"/>
+ <atom segid=" A" residue="317" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="1.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="C"/>
+ <chemical_shift value="178.067" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CB"/>
+ <chemical_shift value="35.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CA"/>
+ <chemical_shift value="64.418" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="N"/>
+ <chemical_shift value="123.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CD1"/>
+ <chemical_shift value="12.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="H"/>
+ <chemical_shift value="7.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="318" name="HB1"/>
+ <atom segid=" A" residue="318" name="HB2"/>
+ <atom segid=" A" residue="318" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="C"/>
+ <chemical_shift value="181.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="CB"/>
+ <chemical_shift value="17.268" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="CA"/>
+ <chemical_shift value="56.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="N"/>
+ <chemical_shift value="123.335" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="H"/>
+ <chemical_shift value="7.906" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="319" name="HB1"/>
+ <atom segid=" A" residue="319" name="HB2"/>
+ <atom segid=" A" residue="319" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="C"/>
+ <chemical_shift value="178.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="CB"/>
+ <chemical_shift value="17.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="CA"/>
+ <chemical_shift value="55.519" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="N"/>
+ <chemical_shift value="118.979" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="H"/>
+ <chemical_shift value="8.086" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="320" name="HG21"/>
+ <atom segid=" A" residue="320" name="HG22"/>
+ <atom segid=" A" residue="320" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="C"/>
+ <chemical_shift value="175.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="CB"/>
+ <chemical_shift value="69.151" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="CA"/>
+ <chemical_shift value="67.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="N"/>
+ <chemical_shift value="114.58" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="H"/>
+ <chemical_shift value="7.358" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="321" name="HE1"/>
+ <atom segid=" A" residue="321" name="HE2"/>
+ <atom segid=" A" residue="321" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="C"/>
+ <chemical_shift value="177.825" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CB"/>
+ <chemical_shift value="30.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CA"/>
+ <chemical_shift value="56.766" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="N"/>
+ <chemical_shift value="118.804" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="H"/>
+ <chemical_shift value="8.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="C"/>
+ <chemical_shift value="179.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CB"/>
+ <chemical_shift value="28.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CA"/>
+ <chemical_shift value="59.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="N"/>
+ <chemical_shift value="122.177" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="H"/>
+ <chemical_shift value="8.267" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="CB"/>
+ <chemical_shift value="39.313" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="CA"/>
+ <chemical_shift value="57.124" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="N"/>
+ <chemical_shift value="115.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="H"/>
+ <chemical_shift value="8.207" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="324" name="HB1"/>
+ <atom segid=" A" residue="324" name="HB2"/>
+ <atom segid=" A" residue="324" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="C"/>
+ <chemical_shift value="180.381" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="CB"/>
+ <chemical_shift value="17.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="CA"/>
+ <chemical_shift value="54.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="N"/>
+ <chemical_shift value="119.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="H"/>
+ <chemical_shift value="8.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="C"/>
+ <chemical_shift value="177.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CB"/>
+ <chemical_shift value="27.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CA"/>
+ <chemical_shift value="58.414" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="N"/>
+ <chemical_shift value="116.35" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="H"/>
+ <chemical_shift value="8.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="326" name="HZ2"/>
+ <atom segid=" A" residue="326" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CB"/>
+ <chemical_shift value="32.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="C"/>
+ <chemical_shift value="176.163" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="H"/>
+ <chemical_shift value="7.079" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CA"/>
+ <chemical_shift value="56.011" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="N"/>
+ <chemical_shift value="117.692" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="C"/>
+ <chemical_shift value="172.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="H"/>
+ <chemical_shift value="7.293" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="CA"/>
+ <chemical_shift value="44.518" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="N"/>
+ <chemical_shift value="106.636" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="C"/>
+ <chemical_shift value="176.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CB"/>
+ <chemical_shift value="32.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CA"/>
+ <chemical_shift value="54.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="N"/>
+ <chemical_shift value="121.098" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="H"/>
+ <chemical_shift value="8.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="329" name="HG21"/>
+ <atom segid=" A" residue="329" name="HG22"/>
+ <atom segid=" A" residue="329" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.821" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="329" name="HD11"/>
+ <atom segid=" A" residue="329" name="HD12"/>
+ <atom segid=" A" residue="329" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="C"/>
+ <chemical_shift value="178.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CB"/>
+ <chemical_shift value="37.812" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CA"/>
+ <chemical_shift value="62.15" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="N"/>
+ <chemical_shift value="127.522" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CD1"/>
+ <chemical_shift value="12.362" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="H"/>
+ <chemical_shift value="9.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="330" name="HE1"/>
+ <atom segid=" A" residue="330" name="HE2"/>
+ <atom segid=" A" residue="330" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CB"/>
+ <chemical_shift value="34.295" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CA"/>
+ <chemical_shift value="56.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="N"/>
+ <chemical_shift value="124.379" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="H"/>
+ <chemical_shift value="8.502" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="C"/>
+ <chemical_shift value="175.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CB"/>
+ <chemical_shift value="31.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CA"/>
+ <chemical_shift value="63.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="C"/>
+ <chemical_shift value="175.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CB"/>
+ <chemical_shift value="38.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CA"/>
+ <chemical_shift value="51.443" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="N"/>
+ <chemical_shift value="117.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="H"/>
+ <chemical_shift value="7.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="333" name="HG21"/>
+ <atom segid=" A" residue="333" name="HG22"/>
+ <atom segid=" A" residue="333" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="-0.138" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="333" name="HD11"/>
+ <atom segid=" A" residue="333" name="HD12"/>
+ <atom segid=" A" residue="333" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="-0.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CB"/>
+ <chemical_shift value="36.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CA"/>
+ <chemical_shift value="59.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="N"/>
+ <chemical_shift value="108.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CD1"/>
+ <chemical_shift value="12.253" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="H"/>
+ <chemical_shift value="6.382" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="C"/>
+ <chemical_shift value="178.686" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CB"/>
+ <chemical_shift value="31.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CA"/>
+ <chemical_shift value="65.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="C"/>
+ <chemical_shift value="177.018" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CB"/>
+ <chemical_shift value="26.389" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CA"/>
+ <chemical_shift value="59.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="N"/>
+ <chemical_shift value="116.31" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="336" name="HE1"/>
+ <atom segid=" A" residue="336" name="HE2"/>
+ <atom segid=" A" residue="336" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="C"/>
+ <chemical_shift value="177.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CB"/>
+ <chemical_shift value="30.289" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CA"/>
+ <chemical_shift value="56.084" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="N"/>
+ <chemical_shift value="118.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="H"/>
+ <chemical_shift value="7.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="C"/>
+ <chemical_shift value="177.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="CB"/>
+ <chemical_shift value="60.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="CA"/>
+ <chemical_shift value="62.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="N"/>
+ <chemical_shift value="113.543" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="H"/>
+ <chemical_shift value="7.924" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="338" name="HB1"/>
+ <atom segid=" A" residue="338" name="HB2"/>
+ <atom segid=" A" residue="338" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="C"/>
+ <chemical_shift value="180.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="CB"/>
+ <chemical_shift value="18.545" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="CA"/>
+ <chemical_shift value="54.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="N"/>
+ <chemical_shift value="122.856" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="H"/>
+ <chemical_shift value="7.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="339" name="HD1"/>
+ <atom segid=" A" residue="339" name="HD2"/>
+ <atom segid=" A" residue="339" name="HE1"/>
+ <atom segid=" A" residue="339" name="HE2"/>
+ <atom segid=" A" residue="339" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="C"/>
+ <chemical_shift value="176.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CB"/>
+ <chemical_shift value="38.827" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CA"/>
+ <chemical_shift value="61.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="N"/>
+ <chemical_shift value="118.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="H"/>
+ <chemical_shift value="7.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="H"/>
+ <chemical_shift value="8.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="C"/>
+ <chemical_shift value="179.128" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CB"/>
+ <chemical_shift value="30.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CA"/>
+ <chemical_shift value="59.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="N"/>
+ <chemical_shift value="118.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="341" name="HD1"/>
+ <atom segid=" A" residue="341" name="HD2"/>
+ <atom segid=" A" residue="341" name="HE1"/>
+ <atom segid=" A" residue="341" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="C"/>
+ <chemical_shift value="178.712" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CB"/>
+ <chemical_shift value="38.306" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CA"/>
+ <chemical_shift value="61.558" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="N"/>
+ <chemical_shift value="114.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="H"/>
+ <chemical_shift value="7.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="342" name="HB1"/>
+ <atom segid=" A" residue="342" name="HB2"/>
+ <atom segid=" A" residue="342" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="C"/>
+ <chemical_shift value="180.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="CB"/>
+ <chemical_shift value="19.012" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="CA"/>
+ <chemical_shift value="55.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="N"/>
+ <chemical_shift value="121.914" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="H"/>
+ <chemical_shift value="8.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="343" name="HG21"/>
+ <atom segid=" A" residue="343" name="HG22"/>
+ <atom segid=" A" residue="343" name="HG23"/>
+ <chemical_shift value="0.168" error="0.0"/>
+ <chemical_shift value="0.863" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="343" name="HG11"/>
+ <atom segid=" A" residue="343" name="HG12"/>
+ <atom segid=" A" residue="343" name="HG13"/>
+ <chemical_shift value="0.168" error="0.0"/>
+ <chemical_shift value="0.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="C"/>
+ <chemical_shift value="177.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CB"/>
+ <chemical_shift value="31.022" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CA"/>
+ <chemical_shift value="66.924" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="N"/>
+ <chemical_shift value="118.57" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CG1"/>
+ <chemical_shift value="21.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="H"/>
+ <chemical_shift value="8.63" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CG2"/>
+ <chemical_shift value="23.236" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CB"/>
+ <chemical_shift value="29.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="C"/>
+ <chemical_shift value="178.506" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="H"/>
+ <chemical_shift value="8.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CA"/>
+ <chemical_shift value="60.236" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="N"/>
+ <chemical_shift value="120.769" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="345" name="HG21"/>
+ <atom segid=" A" residue="345" name="HG22"/>
+ <atom segid=" A" residue="345" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="C"/>
+ <chemical_shift value="175.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CB"/>
+ <chemical_shift value="69.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CA"/>
+ <chemical_shift value="66.564" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="N"/>
+ <chemical_shift value="113.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="H"/>
+ <chemical_shift value="7.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="346" name="HB1"/>
+ <atom segid=" A" residue="346" name="HB2"/>
+ <atom segid=" A" residue="346" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="C"/>
+ <chemical_shift value="179.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="CB"/>
+ <chemical_shift value="18.537" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="CA"/>
+ <chemical_shift value="55.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="N"/>
+ <chemical_shift value="122.933" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="H"/>
+ <chemical_shift value="7.805" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="347" name="HG21"/>
+ <atom segid=" A" residue="347" name="HG22"/>
+ <atom segid=" A" residue="347" name="HG23"/>
+ <chemical_shift value="1.043" error="0.0"/>
+ <chemical_shift value="0.918" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="347" name="HG11"/>
+ <atom segid=" A" residue="347" name="HG12"/>
+ <atom segid=" A" residue="347" name="HG13"/>
+ <chemical_shift value="1.043" error="0.0"/>
+ <chemical_shift value="0.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="C"/>
+ <chemical_shift value="178.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CB"/>
+ <chemical_shift value="31.336" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CA"/>
+ <chemical_shift value="67.494" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="N"/>
+ <chemical_shift value="115.988" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CG1"/>
+ <chemical_shift value="20.468" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CG2"/>
+ <chemical_shift value="22.282" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="348" name="HG21"/>
+ <atom segid=" A" residue="348" name="HG22"/>
+ <atom segid=" A" residue="348" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.869" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="348" name="HD11"/>
+ <atom segid=" A" residue="348" name="HD12"/>
+ <atom segid=" A" residue="348" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.869" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="C"/>
+ <chemical_shift value="180.338" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CB"/>
+ <chemical_shift value="37.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CA"/>
+ <chemical_shift value="65.054" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="N"/>
+ <chemical_shift value="118.38" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CD1"/>
+ <chemical_shift value="12.965" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="H"/>
+ <chemical_shift value="7.771" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="C"/>
+ <chemical_shift value="178.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CB"/>
+ <chemical_shift value="37.166" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CA"/>
+ <chemical_shift value="55.948" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="N"/>
+ <chemical_shift value="121.103" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="H"/>
+ <chemical_shift value="8.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="350" name="HB1"/>
+ <atom segid=" A" residue="350" name="HB2"/>
+ <atom segid=" A" residue="350" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="C"/>
+ <chemical_shift value="181.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="CB"/>
+ <chemical_shift value="17.998" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="CA"/>
+ <chemical_shift value="54.159" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="N"/>
+ <chemical_shift value="122.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="H"/>
+ <chemical_shift value="8.52" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="351" name="HB1"/>
+ <atom segid=" A" residue="351" name="HB2"/>
+ <atom segid=" A" residue="351" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="C"/>
+ <chemical_shift value="178.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="CB"/>
+ <chemical_shift value="18.028" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="CA"/>
+ <chemical_shift value="55.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="N"/>
+ <chemical_shift value="121.112" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="H"/>
+ <chemical_shift value="9.165" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="C"/>
+ <chemical_shift value="175.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="CB"/>
+ <chemical_shift value="64.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="CA"/>
+ <chemical_shift value="58.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="N"/>
+ <chemical_shift value="107.997" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="H"/>
+ <chemical_shift value="7.88" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="C"/>
+ <chemical_shift value="174.546" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="H"/>
+ <chemical_shift value="7.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="CA"/>
+ <chemical_shift value="45.785" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="N"/>
+ <chemical_shift value="109.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CB"/>
+ <chemical_shift value="30.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="C"/>
+ <chemical_shift value="176.819" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="H"/>
+ <chemical_shift value="8.225" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CA"/>
+ <chemical_shift value="58.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="N"/>
+ <chemical_shift value="121.096" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="C"/>
+ <chemical_shift value="176.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CB"/>
+ <chemical_shift value="36.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CA"/>
+ <chemical_shift value="54.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="N"/>
+ <chemical_shift value="113.634" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="H"/>
+ <chemical_shift value="7.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="356" name="HG21"/>
+ <atom segid=" A" residue="356" name="HG22"/>
+ <atom segid=" A" residue="356" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="C"/>
+ <chemical_shift value="174.887" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CB"/>
+ <chemical_shift value="70.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CA"/>
+ <chemical_shift value="61.464" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="N"/>
+ <chemical_shift value="111.798" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="H"/>
+ <chemical_shift value="8.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="357" name="HG21"/>
+ <atom segid=" A" residue="357" name="HG22"/>
+ <atom segid=" A" residue="357" name="HG23"/>
+ <chemical_shift value="1.045" error="0.0"/>
+ <chemical_shift value="0.991" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="357" name="HG11"/>
+ <atom segid=" A" residue="357" name="HG12"/>
+ <atom segid=" A" residue="357" name="HG13"/>
+ <chemical_shift value="1.045" error="0.0"/>
+ <chemical_shift value="0.991" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="C"/>
+ <chemical_shift value="177.155" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CB"/>
+ <chemical_shift value="31.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CA"/>
+ <chemical_shift value="67.861" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="N"/>
+ <chemical_shift value="121.363" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CG1"/>
+ <chemical_shift value="21.315" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="H"/>
+ <chemical_shift value="8.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CG2"/>
+ <chemical_shift value="23.401" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="C"/>
+ <chemical_shift value="178.907" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CB"/>
+ <chemical_shift value="40.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CA"/>
+ <chemical_shift value="57.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="N"/>
+ <chemical_shift value="115.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="H"/>
+ <chemical_shift value="8.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="C"/>
+ <chemical_shift value="178.618" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CB"/>
+ <chemical_shift value="29.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CA"/>
+ <chemical_shift value="58.759" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="N"/>
+ <chemical_shift value="118.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="H"/>
+ <chemical_shift value="7.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="360" name="HB1"/>
+ <atom segid=" A" residue="360" name="HB2"/>
+ <atom segid=" A" residue="360" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="C"/>
+ <chemical_shift value="181.584" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="CB"/>
+ <chemical_shift value="18.27" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="CA"/>
+ <chemical_shift value="54.768" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="N"/>
+ <chemical_shift value="121.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="H"/>
+ <chemical_shift value="8.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="361" name="HD21"/>
+ <atom segid=" A" residue="361" name="HD22"/>
+ <atom segid=" A" residue="361" name="HD23"/>
+ <chemical_shift value="0.722" error="0.0"/>
+ <chemical_shift value="0.892" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="361" name="HD11"/>
+ <atom segid=" A" residue="361" name="HD12"/>
+ <atom segid=" A" residue="361" name="HD13"/>
+ <chemical_shift value="0.722" error="0.0"/>
+ <chemical_shift value="0.892" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="C"/>
+ <chemical_shift value="178.899" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CB"/>
+ <chemical_shift value="39.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CA"/>
+ <chemical_shift value="57.465" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="N"/>
+ <chemical_shift value="116.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CD1"/>
+ <chemical_shift value="25.264" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CD2"/>
+ <chemical_shift value="19.605" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="H"/>
+ <chemical_shift value="8.078" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="362" name="HZ1"/>
+ <atom segid=" A" residue="362" name="HZ2"/>
+ <atom segid=" A" residue="362" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CB"/>
+ <chemical_shift value="31.531" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="C"/>
+ <chemical_shift value="179.903" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="H"/>
+ <chemical_shift value="7.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CA"/>
+ <chemical_shift value="59.792" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="N"/>
+ <chemical_shift value="121.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="C"/>
+ <chemical_shift value="178.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CB"/>
+ <chemical_shift value="40.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CA"/>
+ <chemical_shift value="57.231" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="N"/>
+ <chemical_shift value="120.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="H"/>
+ <chemical_shift value="8.145" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="364" name="HB1"/>
+ <atom segid=" A" residue="364" name="HB2"/>
+ <atom segid=" A" residue="364" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="C"/>
+ <chemical_shift value="178.422" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="CB"/>
+ <chemical_shift value="17.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="CA"/>
+ <chemical_shift value="55.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="N"/>
+ <chemical_shift value="121.446" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="H"/>
+ <chemical_shift value="7.735" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="C"/>
+ <chemical_shift value="179.207" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CB"/>
+ <chemical_shift value="27.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CA"/>
+ <chemical_shift value="60.224" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="N"/>
+ <chemical_shift value="118.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="H"/>
+ <chemical_shift value="8.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="366" name="HG21"/>
+ <atom segid=" A" residue="366" name="HG22"/>
+ <atom segid=" A" residue="366" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="C"/>
+ <chemical_shift value="175.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CB"/>
+ <chemical_shift value="69.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CA"/>
+ <chemical_shift value="66.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="N"/>
+ <chemical_shift value="115.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="H"/>
+ <chemical_shift value="8.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CB"/>
+ <chemical_shift value="29.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="C"/>
+ <chemical_shift value="178.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="H"/>
+ <chemical_shift value="7.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CA"/>
+ <chemical_shift value="58.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="N"/>
+ <chemical_shift value="120.123" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="368" name="HG21"/>
+ <atom segid=" A" residue="368" name="HG22"/>
+ <atom segid=" A" residue="368" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.693" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="368" name="HD11"/>
+ <atom segid=" A" residue="368" name="HD12"/>
+ <atom segid=" A" residue="368" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.693" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="C"/>
+ <chemical_shift value="177.188" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CB"/>
+ <chemical_shift value="38.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CA"/>
+ <chemical_shift value="65.05" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="N"/>
+ <chemical_shift value="117.397" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CD1"/>
+ <chemical_shift value="15.285" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="H"/>
+ <chemical_shift value="8.005" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="369" name="HG21"/>
+ <atom segid=" A" residue="369" name="HG22"/>
+ <atom segid=" A" residue="369" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="C"/>
+ <chemical_shift value="174.309" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CB"/>
+ <chemical_shift value="70.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CA"/>
+ <chemical_shift value="62.641" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="N"/>
+ <chemical_shift value="107.043" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="H"/>
+ <chemical_shift value="7.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="370" name="HZ1"/>
+ <atom segid=" A" residue="370" name="HZ2"/>
+ <atom segid=" A" residue="370" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="O'"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="O''"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CB"/>
+ <chemical_shift value="32.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="H"/>
+ <chemical_shift value="7.399" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CA"/>
+ <chemical_shift value="59.013" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="N"/>
+ <chemical_shift value="128.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+</chemical_shift_list>
\ No newline at end of file
diff --git a/docs/examples/malecoli/data/xml/cn0_peaks.xml b/docs/examples/malecoli/data/xml/cn0_peaks.xml
new file mode 100644
index 0000000000000000000000000000000000000000..2ce29b6e9fcc33328a5f0aea4e8bc599b1164ce9
--- /dev/null
+++ b/docs/examples/malecoli/data/xml/cn0_peaks.xml
@@ -0,0 +1,16691 @@
+<!DOCTYPE spectrum SYSTEM "noesy_spectrum1.0.dtd">
+<spectrum name="cn0">
+ <peak number="1" reliable="no" ambiguity="">
+ <volume value="980000.0" error="0"/>
+ <intensity value="980000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="9.413" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="21.9" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="110.792" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2" reliable="no" ambiguity="">
+ <volume value="1130000.0" error="0"/>
+ <intensity value="1130000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.748" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="10.16" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="124.58" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="3" reliable="no" ambiguity="">
+ <volume value="754000.0" error="0"/>
+ <intensity value="754000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.696" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="12.535" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="123.552" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="4" reliable="no" ambiguity="">
+ <volume value="1780000.0" error="0"/>
+ <intensity value="1780000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.997" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="25.243" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="111.481" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="5" reliable="no" ambiguity="">
+ <volume value="394000.0" error="0"/>
+ <intensity value="394000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.998" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="24.119" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="111.458" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="6" reliable="no" ambiguity="">
+ <volume value="752000.0" error="0"/>
+ <intensity value="752000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.998" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="22.489" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="111.525" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="7" reliable="no" ambiguity="">
+ <volume value="409000.0" error="0"/>
+ <intensity value="409000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.997" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="10.124" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="111.504" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="8" reliable="no" ambiguity="">
+ <volume value="263000.0" error="0"/>
+ <intensity value="263000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.58" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="26.671" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="118.959" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="9" reliable="no" ambiguity="">
+ <volume value="2970000.0" error="0"/>
+ <intensity value="2970000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.574" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="25.248" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="118.85" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="10" reliable="no" ambiguity="">
+ <volume value="1120000.0" error="0"/>
+ <intensity value="1120000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.579" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="24.09" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="118.805" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="11" reliable="no" ambiguity="">
+ <volume value="902000.0" error="0"/>
+ <intensity value="902000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.599" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="23.446" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="118.739" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="12" reliable="no" ambiguity="">
+ <volume value="1560000.0" error="0"/>
+ <intensity value="1560000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.578" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="22.525" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="118.832" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="13" reliable="no" ambiguity="">
+ <volume value="558000.0" error="0"/>
+ <intensity value="558000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.583" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="21.4" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="118.852" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="14" reliable="no" ambiguity="">
+ <volume value="627000.0" error="0"/>
+ <intensity value="627000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.6" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="21.381" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="118.761" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="15" reliable="no" ambiguity="">
+ <volume value="698000.0" error="0"/>
+ <intensity value="698000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.588" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="13.904" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="118.822" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="16" reliable="no" ambiguity="">
+ <volume value="342000.0" error="0"/>
+ <intensity value="342000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.578" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="13.167" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="118.877" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="17" reliable="no" ambiguity="">
+ <volume value="577000.0" error="0"/>
+ <intensity value="577000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.572" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="10.179" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="118.867" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="18" reliable="no" ambiguity="">
+ <volume value="511000.0" error="0"/>
+ <intensity value="511000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="10.152" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="25.263" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="125.502" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="19" reliable="no" ambiguity="">
+ <volume value="1290000.0" error="0"/>
+ <intensity value="1290000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="10.149" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="24.085" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="125.509" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="20" reliable="no" ambiguity="">
+ <volume value="255000.0" error="0"/>
+ <intensity value="255000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="10.148" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="22.437" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="125.511" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="21" reliable="no" ambiguity="">
+ <volume value="4360000.0" error="0"/>
+ <intensity value="4360000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="10.15" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="21.405" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="125.499" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="22" reliable="no" ambiguity="">
+ <volume value="211000.0" error="0"/>
+ <intensity value="211000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="10.153" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="14.588" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="125.521" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="23" reliable="no" ambiguity="">
+ <volume value="409000.0" error="0"/>
+ <intensity value="409000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="9.113" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="26.879" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="128.199" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="24" reliable="no" ambiguity="">
+ <volume value="221000.0" error="0"/>
+ <intensity value="221000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="9.118" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="25.073" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="128.252" error=""/>
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+ <peak number="1012" reliable="no" ambiguity="">
+ <volume value="509000.0" error="0"/>
+ <intensity value="509000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
+ <shift value="25.704" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="126.063" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1013" reliable="no" ambiguity="">
+ <volume value="538000.0" error="0"/>
+ <intensity value="538000.0" error="0"/>
+ <proton1>
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+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
+ <shift value="23.826" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="126.063" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1014" reliable="no" ambiguity="">
+ <volume value="745000.0" error="0"/>
+ <intensity value="745000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.502" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="20.853" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="124.422" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1015" reliable="no" ambiguity="">
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+ <intensity value="582000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
+ <shift value="25.665" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="123.055" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1016" reliable="no" ambiguity="">
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+ <intensity value="2680000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
+ <shift value="21.518" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="123.055" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1017" reliable="no" ambiguity="">
+ <volume value="5340000.0" error="0"/>
+ <intensity value="5340000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
+ <shift value="21.098" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="123.055" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1018" reliable="no" ambiguity="">
+ <volume value="1810000.0" error="0"/>
+ <intensity value="1810000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.298" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="21.665" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="122.235" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1019" reliable="no" ambiguity="">
+ <volume value="2790000.0" error="0"/>
+ <intensity value="2790000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.762" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="20.785" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="121.962" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1020" reliable="no" ambiguity="">
+ <volume value="827000.0" error="0"/>
+ <intensity value="827000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="9.17" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="20.462" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="121.415" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1021" reliable="no" ambiguity="">
+ <volume value="3060000.0" error="0"/>
+ <intensity value="3060000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.232" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="22.076" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="120.868" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1022" reliable="no" ambiguity="">
+ <volume value="2170000.0" error="0"/>
+ <intensity value="2170000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="9.512" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="21.606" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="119.774" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1023" reliable="no" ambiguity="">
+ <volume value="935000.0" error="0"/>
+ <intensity value="935000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.184" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="21.528" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="119.774" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1024" reliable="no" ambiguity="">
+ <volume value="1750000.0" error="0"/>
+ <intensity value="1750000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="6.983" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="22.105" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="118.68" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1025" reliable="no" ambiguity="">
+ <volume value="557000.0" error="0"/>
+ <intensity value="557000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.078" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="22.144" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="118.954" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1026" reliable="no" ambiguity="">
+ <volume value="1150000.0" error="0"/>
+ <intensity value="1150000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.85" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="20.893" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="118.407" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1027" reliable="no" ambiguity="">
+ <volume value="1020000.0" error="0"/>
+ <intensity value="1020000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.847" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="25.821" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="118.407" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1028" reliable="no" ambiguity="">
+ <volume value="1660000.0" error="0"/>
+ <intensity value="1660000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.693" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="21.313" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="117.86" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1029" reliable="no" ambiguity="">
+ <volume value="410000.0" error="0"/>
+ <intensity value="410000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.053" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="25.401" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="117.04" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1030" reliable="no" ambiguity="">
+ <volume value="588000.0" error="0"/>
+ <intensity value="588000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.66" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="24.736" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="117.313" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1031" reliable="no" ambiguity="">
+ <volume value="511000.0" error="0"/>
+ <intensity value="511000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.156" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="23.552" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="116.493" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1032" reliable="no" ambiguity="">
+ <volume value="954000.0" error="0"/>
+ <intensity value="954000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.231" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="23.816" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="115.946" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1033" reliable="no" ambiguity="">
+ <volume value="466000.0" error="0"/>
+ <intensity value="466000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.441" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="21.978" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="115.672" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1034" reliable="no" ambiguity="">
+ <volume value="1370000.0" error="0"/>
+ <intensity value="1370000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.512" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="20.932" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="115.399" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1035" reliable="no" ambiguity="">
+ <volume value="1630000.0" error="0"/>
+ <intensity value="1630000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.066" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="22.858" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="114.305" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1036" reliable="no" ambiguity="">
+ <volume value="1500000.0" error="0"/>
+ <intensity value="1500000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.619" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="21.362" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="114.032" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1037" reliable="no" ambiguity="">
+ <volume value="2930000.0" error="0"/>
+ <intensity value="2930000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="9.147" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="22.535" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="113.212" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1038" reliable="no" ambiguity="">
+ <volume value="330000.0" error="0"/>
+ <intensity value="330000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.414" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="23.944" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="112.938" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1039" reliable="no" ambiguity="">
+ <volume value="579000.0" error="0"/>
+ <intensity value="579000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.508" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="24.022" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="112.938" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1040" reliable="no" ambiguity="">
+ <volume value="606000.0" error="0"/>
+ <intensity value="606000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="9.023" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="22.301" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="111.844" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1041" reliable="no" ambiguity="">
+ <volume value="324000.0" error="0"/>
+ <intensity value="324000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.674" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="23.983" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="108.837" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1042" reliable="no" ambiguity="">
+ <volume value="408000.0" error="0"/>
+ <intensity value="408000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.874" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="23.327" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="108.016" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="1043" reliable="no" ambiguity="">
+ <volume value="1480000.0" error="0"/>
+ <intensity value="1480000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.069" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="22.858" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="114.127" error=""/>
+ </hetero2>
+ </peak>
+</spectrum>
\ No newline at end of file
diff --git a/docs/examples/malecoli/data/xml/n20_cs.xml b/docs/examples/malecoli/data/xml/n20_cs.xml
new file mode 100644
index 0000000000000000000000000000000000000000..bcb3d46b809ec3f250726022e42af6cd1ed9b115
--- /dev/null
+++ b/docs/examples/malecoli/data/xml/n20_cs.xml
@@ -0,0 +1,31373 @@
+<!DOCTYPE chemical_shift_list SYSTEM "chemical_shift_list1.0.dtd">
+<chemical_shift_list>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="1" name="HZ1"/>
+ <atom segid=" A" residue="1" name="HZ2"/>
+ <atom segid=" A" residue="1" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="1" name="H1"/>
+ <atom segid=" A" residue="1" name="H2"/>
+ <atom segid=" A" residue="1" name="H3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="C"/>
+ <chemical_shift value="176.453" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CB"/>
+ <chemical_shift value="32.88" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CA"/>
+ <chemical_shift value="56.408" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="2" name="HG21"/>
+ <atom segid=" A" residue="2" name="HG22"/>
+ <atom segid=" A" residue="2" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.402" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="2" name="HD11"/>
+ <atom segid=" A" residue="2" name="HD12"/>
+ <atom segid=" A" residue="2" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.402" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="C"/>
+ <chemical_shift value="176.016" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CB"/>
+ <chemical_shift value="38.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CA"/>
+ <chemical_shift value="62.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="N"/>
+ <chemical_shift value="123.415" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CD1"/>
+ <chemical_shift value="13.054" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="H"/>
+ <chemical_shift value="7.988" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="C"/>
+ <chemical_shift value="176.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CB"/>
+ <chemical_shift value="31.187" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CA"/>
+ <chemical_shift value="56.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="N"/>
+ <chemical_shift value="126.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="H"/>
+ <chemical_shift value="8.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="C"/>
+ <chemical_shift value="177.433" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CB"/>
+ <chemical_shift value="30.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CA"/>
+ <chemical_shift value="56.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="N"/>
+ <chemical_shift value="124.204" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="H"/>
+ <chemical_shift value="8.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="C"/>
+ <chemical_shift value="172.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="H"/>
+ <chemical_shift value="8.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="CA"/>
+ <chemical_shift value="45.937" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="N"/>
+ <chemical_shift value="111.348" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="6" name="HZ1"/>
+ <atom segid=" A" residue="6" name="HZ2"/>
+ <atom segid=" A" residue="6" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CB"/>
+ <chemical_shift value="35.109" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="C"/>
+ <chemical_shift value="173.108" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="H"/>
+ <chemical_shift value="7.582" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CA"/>
+ <chemical_shift value="54.965" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="N"/>
+ <chemical_shift value="118.91" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="7" name="HD21"/>
+ <atom segid=" A" residue="7" name="HD22"/>
+ <atom segid=" A" residue="7" name="HD23"/>
+ <chemical_shift value="0.615" error="0.0"/>
+ <chemical_shift value="0.267" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="7" name="HD11"/>
+ <atom segid=" A" residue="7" name="HD12"/>
+ <atom segid=" A" residue="7" name="HD13"/>
+ <chemical_shift value="0.615" error="0.0"/>
+ <chemical_shift value="0.267" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="C"/>
+ <chemical_shift value="175.788" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CB"/>
+ <chemical_shift value="46.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CA"/>
+ <chemical_shift value="53.365" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="N"/>
+ <chemical_shift value="116.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CD1"/>
+ <chemical_shift value="25.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CD2"/>
+ <chemical_shift value="24.064" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="H"/>
+ <chemical_shift value="8.231" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="8" name="HG21"/>
+ <atom segid=" A" residue="8" name="HG22"/>
+ <atom segid=" A" residue="8" name="HG23"/>
+ <chemical_shift value="0.923" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="8" name="HG11"/>
+ <atom segid=" A" residue="8" name="HG12"/>
+ <atom segid=" A" residue="8" name="HG13"/>
+ <chemical_shift value="0.923" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="C"/>
+ <chemical_shift value="176.033" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CB"/>
+ <chemical_shift value="33.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CA"/>
+ <chemical_shift value="61.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="N"/>
+ <chemical_shift value="125.474" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CG1"/>
+ <chemical_shift value="20.962" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="H"/>
+ <chemical_shift value="10.155" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CG2"/>
+ <chemical_shift value="21.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="9" name="HG21"/>
+ <atom segid=" A" residue="9" name="HG22"/>
+ <atom segid=" A" residue="9" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.346" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="9" name="HD11"/>
+ <atom segid=" A" residue="9" name="HD12"/>
+ <atom segid=" A" residue="9" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.346" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="C"/>
+ <chemical_shift value="174.901" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CB"/>
+ <chemical_shift value="40.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CA"/>
+ <chemical_shift value="59.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="N"/>
+ <chemical_shift value="128.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CD1"/>
+ <chemical_shift value="14.523" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="H"/>
+ <chemical_shift value="9.114" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="H"/>
+ <chemical_shift value="9.032" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="C"/>
+ <chemical_shift value="174.116" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CB"/>
+ <chemical_shift value="32.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CA"/>
+ <chemical_shift value="54.451" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="N"/>
+ <chemical_shift value="126.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="11" name="HG21"/>
+ <atom segid=" A" residue="11" name="HG22"/>
+ <atom segid=" A" residue="11" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.107" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="11" name="HD11"/>
+ <atom segid=" A" residue="11" name="HD12"/>
+ <atom segid=" A" residue="11" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.107" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="C"/>
+ <chemical_shift value="171.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CB"/>
+ <chemical_shift value="41.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CA"/>
+ <chemical_shift value="59.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="N"/>
+ <chemical_shift value="122.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CD1"/>
+ <chemical_shift value="13.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="H"/>
+ <chemical_shift value="8.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="C"/>
+ <chemical_shift value="177.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CB"/>
+ <chemical_shift value="39.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CA"/>
+ <chemical_shift value="54.628" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="N"/>
+ <chemical_shift value="122.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="H"/>
+ <chemical_shift value="8.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="C"/>
+ <chemical_shift value="173.365" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="H"/>
+ <chemical_shift value="8.288" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="CA"/>
+ <chemical_shift value="46.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="N"/>
+ <chemical_shift value="106.789" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="C"/>
+ <chemical_shift value="176.544" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CB"/>
+ <chemical_shift value="39.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CA"/>
+ <chemical_shift value="53.217" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="N"/>
+ <chemical_shift value="117.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="H"/>
+ <chemical_shift value="7.99" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="15" name="HZ1"/>
+ <atom segid=" A" residue="15" name="HZ2"/>
+ <atom segid=" A" residue="15" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CB"/>
+ <chemical_shift value="32.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="C"/>
+ <chemical_shift value="177.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="H"/>
+ <chemical_shift value="7.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CA"/>
+ <chemical_shift value="53.23" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="N"/>
+ <chemical_shift value="118.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="C"/>
+ <chemical_shift value="175.872" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="H"/>
+ <chemical_shift value="8.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="CA"/>
+ <chemical_shift value="48.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="N"/>
+ <chemical_shift value="108.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="17" name="HD1"/>
+ <atom segid=" A" residue="17" name="HD2"/>
+ <atom segid=" A" residue="17" name="HE1"/>
+ <atom segid=" A" residue="17" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="C"/>
+ <chemical_shift value="177.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CB"/>
+ <chemical_shift value="37.646" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CA"/>
+ <chemical_shift value="59.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="N"/>
+ <chemical_shift value="120.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="H"/>
+ <chemical_shift value="8.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="C"/>
+ <chemical_shift value="179.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CB"/>
+ <chemical_shift value="37.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CA"/>
+ <chemical_shift value="56.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="N"/>
+ <chemical_shift value="123.761" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="H"/>
+ <chemical_shift value="8.109" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="C"/>
+ <chemical_shift value="176.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="H"/>
+ <chemical_shift value="9.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="CA"/>
+ <chemical_shift value="47.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="N"/>
+ <chemical_shift value="111.77" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="20" name="HD21"/>
+ <atom segid=" A" residue="20" name="HD22"/>
+ <atom segid=" A" residue="20" name="HD23"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="20" name="HD11"/>
+ <atom segid=" A" residue="20" name="HD12"/>
+ <atom segid=" A" residue="20" name="HD13"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="C"/>
+ <chemical_shift value="178.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CB"/>
+ <chemical_shift value="41.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CA"/>
+ <chemical_shift value="57.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="N"/>
+ <chemical_shift value="121.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CD1"/>
+ <chemical_shift value="24.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CD2"/>
+ <chemical_shift value="26.879" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="21" name="HB1"/>
+ <atom segid=" A" residue="21" name="HB2"/>
+ <atom segid=" A" residue="21" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="C"/>
+ <chemical_shift value="180.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="CB"/>
+ <chemical_shift value="17.478" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="CA"/>
+ <chemical_shift value="55.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="N"/>
+ <chemical_shift value="121.303" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="H"/>
+ <chemical_shift value="8.143" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="C"/>
+ <chemical_shift value="180.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CB"/>
+ <chemical_shift value="28.487" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CA"/>
+ <chemical_shift value="59.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="N"/>
+ <chemical_shift value="120.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="H"/>
+ <chemical_shift value="7.825" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="23" name="HG21"/>
+ <atom segid=" A" residue="23" name="HG22"/>
+ <atom segid=" A" residue="23" name="HG23"/>
+ <chemical_shift value="1.252" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="23" name="HG11"/>
+ <atom segid=" A" residue="23" name="HG12"/>
+ <atom segid=" A" residue="23" name="HG13"/>
+ <chemical_shift value="1.252" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="C"/>
+ <chemical_shift value="179.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CB"/>
+ <chemical_shift value="31.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CA"/>
+ <chemical_shift value="66.874" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="N"/>
+ <chemical_shift value="123.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CG1"/>
+ <chemical_shift value="22.314" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="H"/>
+ <chemical_shift value="7.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CG2"/>
+ <chemical_shift value="23.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="C"/>
+ <chemical_shift value="175.393" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="H"/>
+ <chemical_shift value="8.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="CA"/>
+ <chemical_shift value="47.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="N"/>
+ <chemical_shift value="106.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="25" name="HZ1"/>
+ <atom segid=" A" residue="25" name="HZ2"/>
+ <atom segid=" A" residue="25" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CB"/>
+ <chemical_shift value="31.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="C"/>
+ <chemical_shift value="179.664" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="H"/>
+ <chemical_shift value="8.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CA"/>
+ <chemical_shift value="59.448" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="N"/>
+ <chemical_shift value="123.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="26" name="HZ1"/>
+ <atom segid=" A" residue="26" name="HZ2"/>
+ <atom segid=" A" residue="26" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CB"/>
+ <chemical_shift value="31.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="C"/>
+ <chemical_shift value="178.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="H"/>
+ <chemical_shift value="7.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CA"/>
+ <chemical_shift value="59.777" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="N"/>
+ <chemical_shift value="123.048" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="27" name="HD1"/>
+ <atom segid=" A" residue="27" name="HD2"/>
+ <atom segid=" A" residue="27" name="HE1"/>
+ <atom segid=" A" residue="27" name="HE2"/>
+ <atom segid=" A" residue="27" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="C"/>
+ <chemical_shift value="179.166" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CB"/>
+ <chemical_shift value="39.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CA"/>
+ <chemical_shift value="61.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="N"/>
+ <chemical_shift value="120.111" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="H"/>
+ <chemical_shift value="8.131" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="C"/>
+ <chemical_shift value="180.031" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CB"/>
+ <chemical_shift value="29.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CA"/>
+ <chemical_shift value="59.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="N"/>
+ <chemical_shift value="124.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="H"/>
+ <chemical_shift value="8.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="29" name="HZ1"/>
+ <atom segid=" A" residue="29" name="HZ2"/>
+ <atom segid=" A" residue="29" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CB"/>
+ <chemical_shift value="31.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="H"/>
+ <chemical_shift value="8.151" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CA"/>
+ <chemical_shift value="59.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="N"/>
+ <chemical_shift value="122.162" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="C"/>
+ <chemical_shift value="178.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CB"/>
+ <chemical_shift value="41.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CA"/>
+ <chemical_shift value="56.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="N"/>
+ <chemical_shift value="116.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="H"/>
+ <chemical_shift value="7.615" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="31" name="HG21"/>
+ <atom segid=" A" residue="31" name="HG22"/>
+ <atom segid=" A" residue="31" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="C"/>
+ <chemical_shift value="176.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CB"/>
+ <chemical_shift value="72.293" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CA"/>
+ <chemical_shift value="62.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="N"/>
+ <chemical_shift value="107.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="H"/>
+ <chemical_shift value="7.929" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="C"/>
+ <chemical_shift value="173.645" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="H"/>
+ <chemical_shift value="8.6" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="CA"/>
+ <chemical_shift value="45.563" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="N"/>
+ <chemical_shift value="112.884" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="33" name="HG21"/>
+ <atom segid=" A" residue="33" name="HG22"/>
+ <atom segid=" A" residue="33" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.574" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="33" name="HD11"/>
+ <atom segid=" A" residue="33" name="HD12"/>
+ <atom segid=" A" residue="33" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.574" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="C"/>
+ <chemical_shift value="173.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CB"/>
+ <chemical_shift value="35.66" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CA"/>
+ <chemical_shift value="59.048" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="N"/>
+ <chemical_shift value="124.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CD1"/>
+ <chemical_shift value="10.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="H"/>
+ <chemical_shift value="7.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="34" name="HZ1"/>
+ <atom segid=" A" residue="34" name="HZ2"/>
+ <atom segid=" A" residue="34" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CB"/>
+ <chemical_shift value="32.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="C"/>
+ <chemical_shift value="175.675" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="H"/>
+ <chemical_shift value="7.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CA"/>
+ <chemical_shift value="56.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="N"/>
+ <chemical_shift value="125.011" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="35" name="HG21"/>
+ <atom segid=" A" residue="35" name="HG22"/>
+ <atom segid=" A" residue="35" name="HG23"/>
+ <chemical_shift value="0.776" error="0.0"/>
+ <chemical_shift value="0.331" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="35" name="HG11"/>
+ <atom segid=" A" residue="35" name="HG12"/>
+ <atom segid=" A" residue="35" name="HG13"/>
+ <chemical_shift value="0.776" error="0.0"/>
+ <chemical_shift value="0.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="C"/>
+ <chemical_shift value="175.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CB"/>
+ <chemical_shift value="33.372" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CA"/>
+ <chemical_shift value="61.064" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="N"/>
+ <chemical_shift value="124.42" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CG1"/>
+ <chemical_shift value="20.685" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="H"/>
+ <chemical_shift value="8.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CG2"/>
+ <chemical_shift value="22.478" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="36" name="HG21"/>
+ <atom segid=" A" residue="36" name="HG22"/>
+ <atom segid=" A" residue="36" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="C"/>
+ <chemical_shift value="172.762" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CB"/>
+ <chemical_shift value="70.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CA"/>
+ <chemical_shift value="61.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="N"/>
+ <chemical_shift value="125.312" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="H"/>
+ <chemical_shift value="9.176" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="37" name="HG21"/>
+ <atom segid=" A" residue="37" name="HG22"/>
+ <atom segid=" A" residue="37" name="HG23"/>
+ <chemical_shift value="0.766" error="0.0"/>
+ <chemical_shift value="0.951" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="37" name="HG11"/>
+ <atom segid=" A" residue="37" name="HG12"/>
+ <atom segid=" A" residue="37" name="HG13"/>
+ <chemical_shift value="0.766" error="0.0"/>
+ <chemical_shift value="0.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="C"/>
+ <chemical_shift value="175.348" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CB"/>
+ <chemical_shift value="32.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CA"/>
+ <chemical_shift value="61.689" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="N"/>
+ <chemical_shift value="127.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CG1"/>
+ <chemical_shift value="22.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="H"/>
+ <chemical_shift value="8.921" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CG2"/>
+ <chemical_shift value="20.673" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="C"/>
+ <chemical_shift value="173.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CB"/>
+ <chemical_shift value="33.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CA"/>
+ <chemical_shift value="54.475" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="N"/>
+ <chemical_shift value="127.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="H"/>
+ <chemical_shift value="9.644" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CB"/>
+ <chemical_shift value="28.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CA"/>
+ <chemical_shift value="51.527" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="N"/>
+ <chemical_shift value="115.306" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="H"/>
+ <chemical_shift value="8.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="C"/>
+ <chemical_shift value="176.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CB"/>
+ <chemical_shift value="30.665" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CA"/>
+ <chemical_shift value="62.226" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="C"/>
+ <chemical_shift value="176.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CB"/>
+ <chemical_shift value="41.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CA"/>
+ <chemical_shift value="54.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="N"/>
+ <chemical_shift value="121.165" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="H"/>
+ <chemical_shift value="8.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="42" name="HZ1"/>
+ <atom segid=" A" residue="42" name="HZ2"/>
+ <atom segid=" A" residue="42" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CB"/>
+ <chemical_shift value="29.442" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="C"/>
+ <chemical_shift value="178.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="H"/>
+ <chemical_shift value="8.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CA"/>
+ <chemical_shift value="56.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="N"/>
+ <chemical_shift value="119.242" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="43" name="HD21"/>
+ <atom segid=" A" residue="43" name="HD22"/>
+ <atom segid=" A" residue="43" name="HD23"/>
+ <chemical_shift value="1.133" error="0.0"/>
+ <chemical_shift value="1.101" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="43" name="HD11"/>
+ <atom segid=" A" residue="43" name="HD12"/>
+ <atom segid=" A" residue="43" name="HD13"/>
+ <chemical_shift value="1.133" error="0.0"/>
+ <chemical_shift value="1.101" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="C"/>
+ <chemical_shift value="175.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CB"/>
+ <chemical_shift value="40.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CA"/>
+ <chemical_shift value="59.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="N"/>
+ <chemical_shift value="120.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CD1"/>
+ <chemical_shift value="26.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CD2"/>
+ <chemical_shift value="26.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="H"/>
+ <chemical_shift value="7.387" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="C"/>
+ <chemical_shift value="178.284" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CB"/>
+ <chemical_shift value="24.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CA"/>
+ <chemical_shift value="57.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="N"/>
+ <chemical_shift value="123.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="H"/>
+ <chemical_shift value="10.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="C"/>
+ <chemical_shift value="178.462" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CB"/>
+ <chemical_shift value="29.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CA"/>
+ <chemical_shift value="56.456" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="N"/>
+ <chemical_shift value="120.295" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="H"/>
+ <chemical_shift value="7.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="46" name="HZ1"/>
+ <atom segid=" A" residue="46" name="HZ2"/>
+ <atom segid=" A" residue="46" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CB"/>
+ <chemical_shift value="33.277" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="C"/>
+ <chemical_shift value="179.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="H"/>
+ <chemical_shift value="8.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CA"/>
+ <chemical_shift value="58.611" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="N"/>
+ <chemical_shift value="120.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="47" name="HD1"/>
+ <atom segid=" A" residue="47" name="HD2"/>
+ <atom segid=" A" residue="47" name="HE1"/>
+ <atom segid=" A" residue="47" name="HE2"/>
+ <atom segid=" A" residue="47" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CB"/>
+ <chemical_shift value="36.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CA"/>
+ <chemical_shift value="63.747" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="N"/>
+ <chemical_shift value="116.928" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="H"/>
+ <chemical_shift value="8.655" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="C"/>
+ <chemical_shift value="178.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CB"/>
+ <chemical_shift value="30.015" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CA"/>
+ <chemical_shift value="65.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="C"/>
+ <chemical_shift value="178.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CB"/>
+ <chemical_shift value="28.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CA"/>
+ <chemical_shift value="58.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="N"/>
+ <chemical_shift value="115.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="H"/>
+ <chemical_shift value="6.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="50" name="HG21"/>
+ <atom segid=" A" residue="50" name="HG22"/>
+ <atom segid=" A" residue="50" name="HG23"/>
+ <chemical_shift value="0.906" error="0.0"/>
+ <chemical_shift value="0.967" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="50" name="HG11"/>
+ <atom segid=" A" residue="50" name="HG12"/>
+ <atom segid=" A" residue="50" name="HG13"/>
+ <chemical_shift value="0.906" error="0.0"/>
+ <chemical_shift value="0.967" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="C"/>
+ <chemical_shift value="178.512" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CB"/>
+ <chemical_shift value="32.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CA"/>
+ <chemical_shift value="62.603" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="N"/>
+ <chemical_shift value="111.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CG1"/>
+ <chemical_shift value="21.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="H"/>
+ <chemical_shift value="7.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CG2"/>
+ <chemical_shift value="19.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="51" name="HB1"/>
+ <atom segid=" A" residue="51" name="HB2"/>
+ <atom segid=" A" residue="51" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="C"/>
+ <chemical_shift value="180.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="CB"/>
+ <chemical_shift value="17.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="CA"/>
+ <chemical_shift value="54.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="N"/>
+ <chemical_shift value="125.692" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="H"/>
+ <chemical_shift value="8.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="52" name="HB1"/>
+ <atom segid=" A" residue="52" name="HB2"/>
+ <atom segid=" A" residue="52" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="C"/>
+ <chemical_shift value="178.618" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="CB"/>
+ <chemical_shift value="18.146" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="CA"/>
+ <chemical_shift value="53.841" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="N"/>
+ <chemical_shift value="118.243" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="H"/>
+ <chemical_shift value="7.396" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="53" name="HG21"/>
+ <atom segid=" A" residue="53" name="HG22"/>
+ <atom segid=" A" residue="53" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="C"/>
+ <chemical_shift value="175.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CB"/>
+ <chemical_shift value="69.75" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CA"/>
+ <chemical_shift value="61.307" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="N"/>
+ <chemical_shift value="106.045" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="H"/>
+ <chemical_shift value="7.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="C"/>
+ <chemical_shift value="172.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="H"/>
+ <chemical_shift value="7.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="CA"/>
+ <chemical_shift value="45.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="N"/>
+ <chemical_shift value="109.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="C"/>
+ <chemical_shift value="174.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CB"/>
+ <chemical_shift value="43.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CA"/>
+ <chemical_shift value="52.778" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="N"/>
+ <chemical_shift value="119.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="H"/>
+ <chemical_shift value="7.395" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="H"/>
+ <chemical_shift value="8.332" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="CA"/>
+ <chemical_shift value="43.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="N"/>
+ <chemical_shift value="105.496" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="C"/>
+ <chemical_shift value="175.448" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CB"/>
+ <chemical_shift value="30.658" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CA"/>
+ <chemical_shift value="61.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="C"/>
+ <chemical_shift value="176.037" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CB"/>
+ <chemical_shift value="43.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CA"/>
+ <chemical_shift value="58.668" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="N"/>
+ <chemical_shift value="117.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="H"/>
+ <chemical_shift value="8.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="59" name="HG21"/>
+ <atom segid=" A" residue="59" name="HG22"/>
+ <atom segid=" A" residue="59" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.735" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="59" name="HD11"/>
+ <atom segid=" A" residue="59" name="HD12"/>
+ <atom segid=" A" residue="59" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.735" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="C"/>
+ <chemical_shift value="173.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CB"/>
+ <chemical_shift value="42.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CA"/>
+ <chemical_shift value="58.982" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="N"/>
+ <chemical_shift value="114.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CD1"/>
+ <chemical_shift value="13.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="H"/>
+ <chemical_shift value="7.631" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="60" name="HG21"/>
+ <atom segid=" A" residue="60" name="HG22"/>
+ <atom segid=" A" residue="60" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.452" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="60" name="HD11"/>
+ <atom segid=" A" residue="60" name="HD12"/>
+ <atom segid=" A" residue="60" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="C"/>
+ <chemical_shift value="172.929" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CB"/>
+ <chemical_shift value="41.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CA"/>
+ <chemical_shift value="58.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="N"/>
+ <chemical_shift value="124.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CD1"/>
+ <chemical_shift value="14.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="H"/>
+ <chemical_shift value="8.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="61" name="HD1"/>
+ <atom segid=" A" residue="61" name="HD2"/>
+ <atom segid=" A" residue="61" name="HE1"/>
+ <atom segid=" A" residue="61" name="HE2"/>
+ <atom segid=" A" residue="61" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="C"/>
+ <chemical_shift value="176.742" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CB"/>
+ <chemical_shift value="41.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CA"/>
+ <chemical_shift value="55.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="N"/>
+ <chemical_shift value="126.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="H"/>
+ <chemical_shift value="8.603" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="H"/>
+ <chemical_shift value="9.181" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="C"/>
+ <chemical_shift value="173.771" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CB"/>
+ <chemical_shift value="31.813" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CA"/>
+ <chemical_shift value="57.786" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="N"/>
+ <chemical_shift value="121.356" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="63" name="HB1"/>
+ <atom segid=" A" residue="63" name="HB2"/>
+ <atom segid=" A" residue="63" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="C"/>
+ <chemical_shift value="179.957" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="CB"/>
+ <chemical_shift value="18.639" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="CA"/>
+ <chemical_shift value="54.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="N"/>
+ <chemical_shift value="125.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="H"/>
+ <chemical_shift value="6.296" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="C"/>
+ <chemical_shift value="178.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CB"/>
+ <chemical_shift value="30.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CA"/>
+ <chemical_shift value="60.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="N"/>
+ <chemical_shift value="115.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="H"/>
+ <chemical_shift value="8.028" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="C"/>
+ <chemical_shift value="177.968" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CB"/>
+ <chemical_shift value="39.5" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CA"/>
+ <chemical_shift value="57.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="N"/>
+ <chemical_shift value="119.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="H"/>
+ <chemical_shift value="7.721" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CB"/>
+ <chemical_shift value="29.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="C"/>
+ <chemical_shift value="177.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="H"/>
+ <chemical_shift value="6.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CA"/>
+ <chemical_shift value="55.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="N"/>
+ <chemical_shift value="116.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="67" name="HD1"/>
+ <atom segid=" A" residue="67" name="HD2"/>
+ <atom segid=" A" residue="67" name="HE1"/>
+ <atom segid=" A" residue="67" name="HE2"/>
+ <atom segid=" A" residue="67" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="C"/>
+ <chemical_shift value="177.883" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CB"/>
+ <chemical_shift value="36.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CA"/>
+ <chemical_shift value="58.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="N"/>
+ <chemical_shift value="116.954" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="H"/>
+ <chemical_shift value="7.688" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="C"/>
+ <chemical_shift value="175.81" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="H"/>
+ <chemical_shift value="7.272" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="CA"/>
+ <chemical_shift value="47.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="N"/>
+ <chemical_shift value="107.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="C"/>
+ <chemical_shift value="177.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="H"/>
+ <chemical_shift value="7.651" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="CA"/>
+ <chemical_shift value="47.089" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="N"/>
+ <chemical_shift value="107.532" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="70" name="HD1"/>
+ <atom segid=" A" residue="70" name="HD2"/>
+ <atom segid=" A" residue="70" name="HE1"/>
+ <atom segid=" A" residue="70" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="C"/>
+ <chemical_shift value="178.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CB"/>
+ <chemical_shift value="35.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CA"/>
+ <chemical_shift value="57.372" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="N"/>
+ <chemical_shift value="119.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="H"/>
+ <chemical_shift value="6.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="71" name="HB1"/>
+ <atom segid=" A" residue="71" name="HB2"/>
+ <atom segid=" A" residue="71" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="C"/>
+ <chemical_shift value="182.277" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="CB"/>
+ <chemical_shift value="18.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="CA"/>
+ <chemical_shift value="54.487" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="N"/>
+ <chemical_shift value="122.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="H"/>
+ <chemical_shift value="8.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="C"/>
+ <chemical_shift value="177.85" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CB"/>
+ <chemical_shift value="27.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CA"/>
+ <chemical_shift value="58.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="N"/>
+ <chemical_shift value="122.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="H"/>
+ <chemical_shift value="8.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="C"/>
+ <chemical_shift value="173.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="CB"/>
+ <chemical_shift value="64.148" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="CA"/>
+ <chemical_shift value="59.274" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="N"/>
+ <chemical_shift value="112.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="H"/>
+ <chemical_shift value="7.362" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="C"/>
+ <chemical_shift value="176.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="H"/>
+ <chemical_shift value="8.083" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="CA"/>
+ <chemical_shift value="46.341" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="N"/>
+ <chemical_shift value="109.4" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="75" name="HD21"/>
+ <atom segid=" A" residue="75" name="HD22"/>
+ <atom segid=" A" residue="75" name="HD23"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="75" name="HD11"/>
+ <atom segid=" A" residue="75" name="HD12"/>
+ <atom segid=" A" residue="75" name="HD13"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="C"/>
+ <chemical_shift value="177.608" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CB"/>
+ <chemical_shift value="42.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CA"/>
+ <chemical_shift value="55.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="N"/>
+ <chemical_shift value="113.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CD1"/>
+ <chemical_shift value="25.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CD2"/>
+ <chemical_shift value="20.664" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="H"/>
+ <chemical_shift value="7.815" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="76" name="HD21"/>
+ <atom segid=" A" residue="76" name="HD22"/>
+ <atom segid=" A" residue="76" name="HD23"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.897" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="76" name="HD11"/>
+ <atom segid=" A" residue="76" name="HD12"/>
+ <atom segid=" A" residue="76" name="HD13"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="C"/>
+ <chemical_shift value="176.782" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CB"/>
+ <chemical_shift value="43.798" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CA"/>
+ <chemical_shift value="52.794" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="N"/>
+ <chemical_shift value="115.902" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CD1"/>
+ <chemical_shift value="27.43" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CD2"/>
+ <chemical_shift value="21.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="H"/>
+ <chemical_shift value="7.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="77" name="HB1"/>
+ <atom segid=" A" residue="77" name="HB2"/>
+ <atom segid=" A" residue="77" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="C"/>
+ <chemical_shift value="176.398" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="CB"/>
+ <chemical_shift value="19.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="CA"/>
+ <chemical_shift value="51.102" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="N"/>
+ <chemical_shift value="125.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="H"/>
+ <chemical_shift value="9.007" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="C"/>
+ <chemical_shift value="176.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CB"/>
+ <chemical_shift value="29.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CA"/>
+ <chemical_shift value="56.426" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="N"/>
+ <chemical_shift value="120.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="H"/>
+ <chemical_shift value="8.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
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+ <atom segid=" A" residue="79" name="HG22"/>
+ <atom segid=" A" residue="79" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.161" error="0.0"/>
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+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="79" name="HD11"/>
+ <atom segid=" A" residue="79" name="HD12"/>
+ <atom segid=" A" residue="79" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.161" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="C"/>
+ <chemical_shift value="175.746" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CB"/>
+ <chemical_shift value="38.941" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CA"/>
+ <chemical_shift value="59.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="N"/>
+ <chemical_shift value="122.859" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CD1"/>
+ <chemical_shift value="12.313" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="H"/>
+ <chemical_shift value="8.176" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="80" name="HG21"/>
+ <atom segid=" A" residue="80" name="HG22"/>
+ <atom segid=" A" residue="80" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CB"/>
+ <chemical_shift value="69.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CA"/>
+ <chemical_shift value="57.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="N"/>
+ <chemical_shift value="112.766" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="H"/>
+ <chemical_shift value="8.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="C"/>
+ <chemical_shift value="177.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CB"/>
+ <chemical_shift value="31.586" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CA"/>
+ <chemical_shift value="62.548" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CB"/>
+ <chemical_shift value="41.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CA"/>
+ <chemical_shift value="53.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="N"/>
+ <chemical_shift value="123.843" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="H"/>
+ <chemical_shift value="9.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="83" name="HZ1"/>
+ <atom segid=" A" residue="83" name="HZ2"/>
+ <atom segid=" A" residue="83" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CB"/>
+ <chemical_shift value="31.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="C"/>
+ <chemical_shift value="177.708" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CA"/>
+ <chemical_shift value="59.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="84" name="HB1"/>
+ <atom segid=" A" residue="84" name="HB2"/>
+ <atom segid=" A" residue="84" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="C"/>
+ <chemical_shift value="180.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="CB"/>
+ <chemical_shift value="17.553" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="CA"/>
+ <chemical_shift value="54.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="N"/>
+ <chemical_shift value="119.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="H"/>
+ <chemical_shift value="8.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="85" name="HD1"/>
+ <atom segid=" A" residue="85" name="HD2"/>
+ <atom segid=" A" residue="85" name="HE1"/>
+ <atom segid=" A" residue="85" name="HE2"/>
+ <atom segid=" A" residue="85" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="C"/>
+ <chemical_shift value="178.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CB"/>
+ <chemical_shift value="39.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CA"/>
+ <chemical_shift value="62.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="N"/>
+ <chemical_shift value="118.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="H"/>
+ <chemical_shift value="7.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="C"/>
+ <chemical_shift value="180.14" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CB"/>
+ <chemical_shift value="28.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CA"/>
+ <chemical_shift value="59.616" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="N"/>
+ <chemical_shift value="117.272" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="H"/>
+ <chemical_shift value="8.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="C"/>
+ <chemical_shift value="176.576" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CB"/>
+ <chemical_shift value="40.956" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CA"/>
+ <chemical_shift value="56.177" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="N"/>
+ <chemical_shift value="116.913" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="H"/>
+ <chemical_shift value="8.053" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="88" name="HZ1"/>
+ <atom segid=" A" residue="88" name="HZ2"/>
+ <atom segid=" A" residue="88" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CB"/>
+ <chemical_shift value="31.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="C"/>
+ <chemical_shift value="176.797" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="H"/>
+ <chemical_shift value="7.816" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CA"/>
+ <chemical_shift value="58.402" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="N"/>
+ <chemical_shift value="117.299" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="89" name="HD21"/>
+ <atom segid=" A" residue="89" name="HD22"/>
+ <atom segid=" A" residue="89" name="HD23"/>
+ <chemical_shift value="0.484" error="0.0"/>
+ <chemical_shift value="0.526" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="89" name="HD11"/>
+ <atom segid=" A" residue="89" name="HD12"/>
+ <atom segid=" A" residue="89" name="HD13"/>
+ <chemical_shift value="0.484" error="0.0"/>
+ <chemical_shift value="0.526" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="C"/>
+ <chemical_shift value="176.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CB"/>
+ <chemical_shift value="42.609" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CA"/>
+ <chemical_shift value="53.55" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="N"/>
+ <chemical_shift value="120.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CD1"/>
+ <chemical_shift value="26.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CD2"/>
+ <chemical_shift value="25.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="H"/>
+ <chemical_shift value="7.661" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="90" name="HD1"/>
+ <atom segid=" A" residue="90" name="HD2"/>
+ <atom segid=" A" residue="90" name="HE1"/>
+ <atom segid=" A" residue="90" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CB"/>
+ <chemical_shift value="38.921" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CA"/>
+ <chemical_shift value="59.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="N"/>
+ <chemical_shift value="116.748" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="H"/>
+ <chemical_shift value="7.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="C"/>
+ <chemical_shift value="179.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CB"/>
+ <chemical_shift value="31.38" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CA"/>
+ <chemical_shift value="66.902" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="92" name="HD1"/>
+ <atom segid=" A" residue="92" name="HD2"/>
+ <atom segid=" A" residue="92" name="HE1"/>
+ <atom segid=" A" residue="92" name="HE2"/>
+ <atom segid=" A" residue="92" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="C"/>
+ <chemical_shift value="176.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CB"/>
+ <chemical_shift value="36.63" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CA"/>
+ <chemical_shift value="59.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="N"/>
+ <chemical_shift value="112.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="H"/>
+ <chemical_shift value="8.01" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="93" name="HG21"/>
+ <atom segid=" A" residue="93" name="HG22"/>
+ <atom segid=" A" residue="93" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="C"/>
+ <chemical_shift value="176.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CB"/>
+ <chemical_shift value="67.099" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CA"/>
+ <chemical_shift value="64.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="N"/>
+ <chemical_shift value="111.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="H"/>
+ <chemical_shift value="7.099" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="H"/>
+ <chemical_shift value="6.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="C"/>
+ <chemical_shift value="178.465" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CB"/>
+ <chemical_shift value="29.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CA"/>
+ <chemical_shift value="58.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="N"/>
+ <chemical_shift value="120.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="C"/>
+ <chemical_shift value="178.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CB"/>
+ <chemical_shift value="39.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CA"/>
+ <chemical_shift value="57.436" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="N"/>
+ <chemical_shift value="115.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="H"/>
+ <chemical_shift value="7.31" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="96" name="HB1"/>
+ <atom segid=" A" residue="96" name="HB2"/>
+ <atom segid=" A" residue="96" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="C"/>
+ <chemical_shift value="177.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="CB"/>
+ <chemical_shift value="17.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="CA"/>
+ <chemical_shift value="54.0" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="N"/>
+ <chemical_shift value="118.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="H"/>
+ <chemical_shift value="6.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="97" name="HG21"/>
+ <atom segid=" A" residue="97" name="HG22"/>
+ <atom segid=" A" residue="97" name="HG23"/>
+ <chemical_shift value="1.347" error="0.0"/>
+ <chemical_shift value="0.578" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="97" name="HG11"/>
+ <atom segid=" A" residue="97" name="HG12"/>
+ <atom segid=" A" residue="97" name="HG13"/>
+ <chemical_shift value="1.347" error="0.0"/>
+ <chemical_shift value="0.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="C"/>
+ <chemical_shift value="172.577" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CB"/>
+ <chemical_shift value="30.785" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CA"/>
+ <chemical_shift value="59.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="N"/>
+ <chemical_shift value="106.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CG1"/>
+ <chemical_shift value="22.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="H"/>
+ <chemical_shift value="7.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CG2"/>
+ <chemical_shift value="19.363" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CB"/>
+ <chemical_shift value="31.357" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="C"/>
+ <chemical_shift value="176.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="H"/>
+ <chemical_shift value="7.049" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CA"/>
+ <chemical_shift value="55.065" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="N"/>
+ <chemical_shift value="121.675" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="99" name="HD1"/>
+ <atom segid=" A" residue="99" name="HD2"/>
+ <atom segid=" A" residue="99" name="HE1"/>
+ <atom segid=" A" residue="99" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CB"/>
+ <chemical_shift value="41.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CA"/>
+ <chemical_shift value="58.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="N"/>
+ <chemical_shift value="127.473" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="H"/>
+ <chemical_shift value="9.707" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="C"/>
+ <chemical_shift value="175.4" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CB"/>
+ <chemical_shift value="37.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CA"/>
+ <chemical_shift value="53.907" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="C"/>
+ <chemical_shift value="173.987" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="H"/>
+ <chemical_shift value="8.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="CA"/>
+ <chemical_shift value="45.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="N"/>
+ <chemical_shift value="102.283" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="102" name="HZ1"/>
+ <atom segid=" A" residue="102" name="HZ2"/>
+ <atom segid=" A" residue="102" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CB"/>
+ <chemical_shift value="34.731" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="C"/>
+ <chemical_shift value="175.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="H"/>
+ <chemical_shift value="7.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CA"/>
+ <chemical_shift value="54.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="N"/>
+ <chemical_shift value="121.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="103" name="HD21"/>
+ <atom segid=" A" residue="103" name="HD22"/>
+ <atom segid=" A" residue="103" name="HD23"/>
+ <chemical_shift value="0.972" error="0.0"/>
+ <chemical_shift value="0.49" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="103" name="HD11"/>
+ <atom segid=" A" residue="103" name="HD12"/>
+ <atom segid=" A" residue="103" name="HD13"/>
+ <chemical_shift value="0.972" error="0.0"/>
+ <chemical_shift value="0.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="C"/>
+ <chemical_shift value="178.524" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CB"/>
+ <chemical_shift value="42.179" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CA"/>
+ <chemical_shift value="55.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="N"/>
+ <chemical_shift value="123.232" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CD1"/>
+ <chemical_shift value="24.748" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CD2"/>
+ <chemical_shift value="24.1" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="H"/>
+ <chemical_shift value="8.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="104" name="HG21"/>
+ <atom segid=" A" residue="104" name="HG22"/>
+ <atom segid=" A" residue="104" name="HG23"/>
+ <chemical_shift value="0.889" error="0.0"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="104" name="HD11"/>
+ <atom segid=" A" residue="104" name="HD12"/>
+ <atom segid=" A" residue="104" name="HD13"/>
+ <chemical_shift value="0.889" error="0.0"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="C"/>
+ <chemical_shift value="175.468" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CB"/>
+ <chemical_shift value="39.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CA"/>
+ <chemical_shift value="59.655" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="N"/>
+ <chemical_shift value="112.793" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CD1"/>
+ <chemical_shift value="14.779" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="H"/>
+ <chemical_shift value="8.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CG2"/>
+ <chemical_shift value="19.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="105" name="HB1"/>
+ <atom segid=" A" residue="105" name="HB2"/>
+ <atom segid=" A" residue="105" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="C"/>
+ <chemical_shift value="173.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="CB"/>
+ <chemical_shift value="22.111" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="CA"/>
+ <chemical_shift value="52.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="N"/>
+ <chemical_shift value="117.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="H"/>
+ <chemical_shift value="7.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="106" name="HD1"/>
+ <atom segid=" A" residue="106" name="HD2"/>
+ <atom segid=" A" residue="106" name="HE1"/>
+ <atom segid=" A" residue="106" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CB"/>
+ <chemical_shift value="39.931" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CA"/>
+ <chemical_shift value="56.214" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="N"/>
+ <chemical_shift value="113.919" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="H"/>
+ <chemical_shift value="8.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="C"/>
+ <chemical_shift value="174.609" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CB"/>
+ <chemical_shift value="32.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CA"/>
+ <chemical_shift value="62.281" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="108" name="HG21"/>
+ <atom segid=" A" residue="108" name="HG22"/>
+ <atom segid=" A" residue="108" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.637" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="108" name="HD11"/>
+ <atom segid=" A" residue="108" name="HD12"/>
+ <atom segid=" A" residue="108" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.637" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="C"/>
+ <chemical_shift value="176.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CB"/>
+ <chemical_shift value="37.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CA"/>
+ <chemical_shift value="60.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="N"/>
+ <chemical_shift value="115.381" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CD1"/>
+ <chemical_shift value="9.981" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="H"/>
+ <chemical_shift value="8.515" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="109" name="HB1"/>
+ <atom segid=" A" residue="109" name="HB2"/>
+ <atom segid=" A" residue="109" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="C"/>
+ <chemical_shift value="174.628" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="CB"/>
+ <chemical_shift value="23.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="CA"/>
+ <chemical_shift value="50.761" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="N"/>
+ <chemical_shift value="118.162" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="H"/>
+ <chemical_shift value="7.854" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="110" name="HG21"/>
+ <atom segid=" A" residue="110" name="HG22"/>
+ <atom segid=" A" residue="110" name="HG23"/>
+ <chemical_shift value="0.476" error="0.0"/>
+ <chemical_shift value="0.767" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="110" name="HG11"/>
+ <atom segid=" A" residue="110" name="HG12"/>
+ <atom segid=" A" residue="110" name="HG13"/>
+ <chemical_shift value="0.476" error="0.0"/>
+ <chemical_shift value="0.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="C"/>
+ <chemical_shift value="173.634" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CB"/>
+ <chemical_shift value="34.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CA"/>
+ <chemical_shift value="62.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="N"/>
+ <chemical_shift value="121.428" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CG1"/>
+ <chemical_shift value="20.954" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="H"/>
+ <chemical_shift value="8.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CG2"/>
+ <chemical_shift value="20.424" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="C"/>
+ <chemical_shift value="173.917" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CB"/>
+ <chemical_shift value="32.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CA"/>
+ <chemical_shift value="54.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="N"/>
+ <chemical_shift value="123.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="H"/>
+ <chemical_shift value="9.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="112" name="HB1"/>
+ <atom segid=" A" residue="112" name="HB2"/>
+ <atom segid=" A" residue="112" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="C"/>
+ <chemical_shift value="176.641" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="CB"/>
+ <chemical_shift value="22.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="CA"/>
+ <chemical_shift value="50.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="N"/>
+ <chemical_shift value="117.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="H"/>
+ <chemical_shift value="6.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="113" name="HD21"/>
+ <atom segid=" A" residue="113" name="HD22"/>
+ <atom segid=" A" residue="113" name="HD23"/>
+ <chemical_shift value="0.854" error="0.0"/>
+ <chemical_shift value="0.691" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="113" name="HD11"/>
+ <atom segid=" A" residue="113" name="HD12"/>
+ <atom segid=" A" residue="113" name="HD13"/>
+ <chemical_shift value="0.854" error="0.0"/>
+ <chemical_shift value="0.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="C"/>
+ <chemical_shift value="173.598" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CB"/>
+ <chemical_shift value="43.367" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CA"/>
+ <chemical_shift value="55.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="N"/>
+ <chemical_shift value="123.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CD1"/>
+ <chemical_shift value="26.792" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CD2"/>
+ <chemical_shift value="23.625" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="H"/>
+ <chemical_shift value="8.457" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="C"/>
+ <chemical_shift value="172.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="CB"/>
+ <chemical_shift value="67.447" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="CA"/>
+ <chemical_shift value="57.265" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="N"/>
+ <chemical_shift value="108.174" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="H"/>
+ <chemical_shift value="7.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="115" name="HD21"/>
+ <atom segid=" A" residue="115" name="HD22"/>
+ <atom segid=" A" residue="115" name="HD23"/>
+ <chemical_shift value="0.587" error="0.0"/>
+ <chemical_shift value="0.684" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="115" name="HD11"/>
+ <atom segid=" A" residue="115" name="HD12"/>
+ <atom segid=" A" residue="115" name="HD13"/>
+ <chemical_shift value="0.587" error="0.0"/>
+ <chemical_shift value="0.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="C"/>
+ <chemical_shift value="174.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CB"/>
+ <chemical_shift value="43.729" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CA"/>
+ <chemical_shift value="54.482" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="N"/>
+ <chemical_shift value="122.319" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CD1"/>
+ <chemical_shift value="22.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CD2"/>
+ <chemical_shift value="24.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="H"/>
+ <chemical_shift value="7.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="116" name="HG21"/>
+ <atom segid=" A" residue="116" name="HG22"/>
+ <atom segid=" A" residue="116" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.459" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="116" name="HD11"/>
+ <atom segid=" A" residue="116" name="HD12"/>
+ <atom segid=" A" residue="116" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.459" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="C"/>
+ <chemical_shift value="174.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CB"/>
+ <chemical_shift value="38.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CA"/>
+ <chemical_shift value="60.103" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="N"/>
+ <chemical_shift value="129.611" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CD1"/>
+ <chemical_shift value="13.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="H"/>
+ <chemical_shift value="8.667" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="117" name="HD1"/>
+ <atom segid=" A" residue="117" name="HD2"/>
+ <atom segid=" A" residue="117" name="HE1"/>
+ <atom segid=" A" residue="117" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="C"/>
+ <chemical_shift value="172.945" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CB"/>
+ <chemical_shift value="42.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CA"/>
+ <chemical_shift value="54.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="N"/>
+ <chemical_shift value="121.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="H"/>
+ <chemical_shift value="9.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="C"/>
+ <chemical_shift value="175.772" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CB"/>
+ <chemical_shift value="37.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CA"/>
+ <chemical_shift value="52.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="N"/>
+ <chemical_shift value="121.187" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="H"/>
+ <chemical_shift value="9.303" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="119" name="HZ1"/>
+ <atom segid=" A" residue="119" name="HZ2"/>
+ <atom segid=" A" residue="119" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CB"/>
+ <chemical_shift value="32.435" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="C"/>
+ <chemical_shift value="177.723" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="H"/>
+ <chemical_shift value="8.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CA"/>
+ <chemical_shift value="58.733" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="N"/>
+ <chemical_shift value="125.522" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="C"/>
+ <chemical_shift value="177.651" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CB"/>
+ <chemical_shift value="40.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CA"/>
+ <chemical_shift value="56.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="N"/>
+ <chemical_shift value="115.687" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="121" name="HD21"/>
+ <atom segid=" A" residue="121" name="HD22"/>
+ <atom segid=" A" residue="121" name="HD23"/>
+ <chemical_shift value="0.779" error="0.0"/>
+ <chemical_shift value="0.665" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="121" name="HD11"/>
+ <atom segid=" A" residue="121" name="HD12"/>
+ <atom segid=" A" residue="121" name="HD13"/>
+ <chemical_shift value="0.779" error="0.0"/>
+ <chemical_shift value="0.665" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="C"/>
+ <chemical_shift value="176.749" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CB"/>
+ <chemical_shift value="44.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CA"/>
+ <chemical_shift value="55.765" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="N"/>
+ <chemical_shift value="117.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CD1"/>
+ <chemical_shift value="24.729" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CD2"/>
+ <chemical_shift value="22.791" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="H"/>
+ <chemical_shift value="7.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="122" name="HD21"/>
+ <atom segid=" A" residue="122" name="HD22"/>
+ <atom segid=" A" residue="122" name="HD23"/>
+ <chemical_shift value="0.937" error="0.0"/>
+ <chemical_shift value="0.93" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="122" name="HD11"/>
+ <atom segid=" A" residue="122" name="HD12"/>
+ <atom segid=" A" residue="122" name="HD13"/>
+ <chemical_shift value="0.937" error="0.0"/>
+ <chemical_shift value="0.93" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CB"/>
+ <chemical_shift value="44.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CA"/>
+ <chemical_shift value="51.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="N"/>
+ <chemical_shift value="119.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CD1"/>
+ <chemical_shift value="25.548" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CD2"/>
+ <chemical_shift value="26.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="C"/>
+ <chemical_shift value="176.075" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CB"/>
+ <chemical_shift value="31.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CA"/>
+ <chemical_shift value="62.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="127" name="HZ1"/>
+ <atom segid=" A" residue="127" name="HZ2"/>
+ <atom segid=" A" residue="127" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CB"/>
+ <chemical_shift value="33.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="C"/>
+ <chemical_shift value="177.427" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="H"/>
+ <chemical_shift value="8.137" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CA"/>
+ <chemical_shift value="56.778" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="N"/>
+ <chemical_shift value="118.457" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="128" name="HG21"/>
+ <atom segid=" A" residue="128" name="HG22"/>
+ <atom segid=" A" residue="128" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="C"/>
+ <chemical_shift value="174.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CB"/>
+ <chemical_shift value="71.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CA"/>
+ <chemical_shift value="60.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="N"/>
+ <chemical_shift value="108.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="H"/>
+ <chemical_shift value="10.183" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="C"/>
+ <chemical_shift value="179.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CB"/>
+ <chemical_shift value="28.48" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CA"/>
+ <chemical_shift value="60.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="N"/>
+ <chemical_shift value="123.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="C"/>
+ <chemical_shift value="178.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CB"/>
+ <chemical_shift value="28.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CA"/>
+ <chemical_shift value="61.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="N"/>
+ <chemical_shift value="118.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="H"/>
+ <chemical_shift value="10.583" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="C"/>
+ <chemical_shift value="176.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CB"/>
+ <chemical_shift value="31.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CA"/>
+ <chemical_shift value="57.205" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="N"/>
+ <chemical_shift value="116.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="H"/>
+ <chemical_shift value="7.606" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="132" name="HG21"/>
+ <atom segid=" A" residue="132" name="HG22"/>
+ <atom segid=" A" residue="132" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.56" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="132" name="HD11"/>
+ <atom segid=" A" residue="132" name="HD12"/>
+ <atom segid=" A" residue="132" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CB"/>
+ <chemical_shift value="33.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CA"/>
+ <chemical_shift value="66.928" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="N"/>
+ <chemical_shift value="121.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CD1"/>
+ <chemical_shift value="12.36" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="H"/>
+ <chemical_shift value="8.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="C"/>
+ <chemical_shift value="177.795" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CB"/>
+ <chemical_shift value="30.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CA"/>
+ <chemical_shift value="67.059" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="134" name="HB1"/>
+ <atom segid=" A" residue="134" name="HB2"/>
+ <atom segid=" A" residue="134" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="C"/>
+ <chemical_shift value="181.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="CB"/>
+ <chemical_shift value="17.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="CA"/>
+ <chemical_shift value="55.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="N"/>
+ <chemical_shift value="118.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="H"/>
+ <chemical_shift value="7.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="135" name="HD21"/>
+ <atom segid=" A" residue="135" name="HD22"/>
+ <atom segid=" A" residue="135" name="HD23"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ <chemical_shift value="0.888" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="135" name="HD11"/>
+ <atom segid=" A" residue="135" name="HD12"/>
+ <atom segid=" A" residue="135" name="HD13"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ <chemical_shift value="0.888" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="C"/>
+ <chemical_shift value="179.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CB"/>
+ <chemical_shift value="42.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CA"/>
+ <chemical_shift value="57.396" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="N"/>
+ <chemical_shift value="120.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CD1"/>
+ <chemical_shift value="24.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CD2"/>
+ <chemical_shift value="24.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="H"/>
+ <chemical_shift value="7.6" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="C"/>
+ <chemical_shift value="177.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CB"/>
+ <chemical_shift value="41.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CA"/>
+ <chemical_shift value="58.901" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="N"/>
+ <chemical_shift value="118.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="H"/>
+ <chemical_shift value="8.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="137" name="HZ1"/>
+ <atom segid=" A" residue="137" name="HZ2"/>
+ <atom segid=" A" residue="137" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CB"/>
+ <chemical_shift value="31.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="C"/>
+ <chemical_shift value="179.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="H"/>
+ <chemical_shift value="8.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CA"/>
+ <chemical_shift value="60.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="N"/>
+ <chemical_shift value="117.342" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="C"/>
+ <chemical_shift value="179.799" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CB"/>
+ <chemical_shift value="29.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CA"/>
+ <chemical_shift value="59.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="N"/>
+ <chemical_shift value="118.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="H"/>
+ <chemical_shift value="7.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="139" name="HD21"/>
+ <atom segid=" A" residue="139" name="HD22"/>
+ <atom segid=" A" residue="139" name="HD23"/>
+ <chemical_shift value="0.852" error="0.0"/>
+ <chemical_shift value="0.787" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="139" name="HD11"/>
+ <atom segid=" A" residue="139" name="HD12"/>
+ <atom segid=" A" residue="139" name="HD13"/>
+ <chemical_shift value="0.852" error="0.0"/>
+ <chemical_shift value="0.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="C"/>
+ <chemical_shift value="180.721" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CB"/>
+ <chemical_shift value="40.311" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CA"/>
+ <chemical_shift value="58.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="N"/>
+ <chemical_shift value="121.279" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CD1"/>
+ <chemical_shift value="25.914" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CD2"/>
+ <chemical_shift value="22.927" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="H"/>
+ <chemical_shift value="8.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="140" name="HZ1"/>
+ <atom segid=" A" residue="140" name="HZ2"/>
+ <atom segid=" A" residue="140" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CB"/>
+ <chemical_shift value="31.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="C"/>
+ <chemical_shift value="181.621" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="H"/>
+ <chemical_shift value="9.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CA"/>
+ <chemical_shift value="58.851" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="N"/>
+ <chemical_shift value="124.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="141" name="HB1"/>
+ <atom segid=" A" residue="141" name="HB2"/>
+ <atom segid=" A" residue="141" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="C"/>
+ <chemical_shift value="178.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="CB"/>
+ <chemical_shift value="17.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="CA"/>
+ <chemical_shift value="54.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="N"/>
+ <chemical_shift value="122.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="H"/>
+ <chemical_shift value="7.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="142" name="HZ1"/>
+ <atom segid=" A" residue="142" name="HZ2"/>
+ <atom segid=" A" residue="142" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CB"/>
+ <chemical_shift value="32.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="C"/>
+ <chemical_shift value="176.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="H"/>
+ <chemical_shift value="7.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CA"/>
+ <chemical_shift value="55.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="N"/>
+ <chemical_shift value="115.794" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="C"/>
+ <chemical_shift value="174.318" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="H"/>
+ <chemical_shift value="7.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="CA"/>
+ <chemical_shift value="46.128" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="N"/>
+ <chemical_shift value="107.82" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="144" name="HZ1"/>
+ <atom segid=" A" residue="144" name="HZ2"/>
+ <atom segid=" A" residue="144" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CB"/>
+ <chemical_shift value="35.01" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="C"/>
+ <chemical_shift value="173.812" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="H"/>
+ <chemical_shift value="7.86" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CA"/>
+ <chemical_shift value="53.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="N"/>
+ <chemical_shift value="119.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="C"/>
+ <chemical_shift value="174.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="CB"/>
+ <chemical_shift value="66.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="CA"/>
+ <chemical_shift value="56.884" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="N"/>
+ <chemical_shift value="109.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="H"/>
+ <chemical_shift value="7.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="146" name="HB1"/>
+ <atom segid=" A" residue="146" name="HB2"/>
+ <atom segid=" A" residue="146" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="C"/>
+ <chemical_shift value="175.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="CB"/>
+ <chemical_shift value="17.973" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="CA"/>
+ <chemical_shift value="55.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="N"/>
+ <chemical_shift value="122.791" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="H"/>
+ <chemical_shift value="9.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="147" name="HD21"/>
+ <atom segid=" A" residue="147" name="HD22"/>
+ <atom segid=" A" residue="147" name="HD23"/>
+ <chemical_shift value="0.936" error="0.0"/>
+ <chemical_shift value="0.683" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="147" name="HD11"/>
+ <atom segid=" A" residue="147" name="HD12"/>
+ <atom segid=" A" residue="147" name="HD13"/>
+ <chemical_shift value="0.936" error="0.0"/>
+ <chemical_shift value="0.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="C"/>
+ <chemical_shift value="175.05" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CB"/>
+ <chemical_shift value="45.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CA"/>
+ <chemical_shift value="54.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="N"/>
+ <chemical_shift value="116.868" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CD1"/>
+ <chemical_shift value="22.5" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CD2"/>
+ <chemical_shift value="27.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="H"/>
+ <chemical_shift value="8.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="148" name="HE1"/>
+ <atom segid=" A" residue="148" name="HE2"/>
+ <atom segid=" A" residue="148" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="C"/>
+ <chemical_shift value="174.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CB"/>
+ <chemical_shift value="37.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CA"/>
+ <chemical_shift value="55.8" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="N"/>
+ <chemical_shift value="121.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="H"/>
+ <chemical_shift value="8.179" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="149" name="HD1"/>
+ <atom segid=" A" residue="149" name="HD2"/>
+ <atom segid=" A" residue="149" name="HE1"/>
+ <atom segid=" A" residue="149" name="HE2"/>
+ <atom segid=" A" residue="149" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="C"/>
+ <chemical_shift value="171.59" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CB"/>
+ <chemical_shift value="41.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CA"/>
+ <chemical_shift value="55.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="N"/>
+ <chemical_shift value="120.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="H"/>
+ <chemical_shift value="8.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="C"/>
+ <chemical_shift value="172.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CB"/>
+ <chemical_shift value="37.305" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CA"/>
+ <chemical_shift value="53.341" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="N"/>
+ <chemical_shift value="116.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="H"/>
+ <chemical_shift value="8.671" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="151" name="HD21"/>
+ <atom segid=" A" residue="151" name="HD22"/>
+ <atom segid=" A" residue="151" name="HD23"/>
+ <chemical_shift value="0.135" error="0.0"/>
+ <chemical_shift value="0.744" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="151" name="HD11"/>
+ <atom segid=" A" residue="151" name="HD12"/>
+ <atom segid=" A" residue="151" name="HD13"/>
+ <chemical_shift value="0.135" error="0.0"/>
+ <chemical_shift value="0.744" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="C"/>
+ <chemical_shift value="177.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CB"/>
+ <chemical_shift value="41.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CA"/>
+ <chemical_shift value="54.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="N"/>
+ <chemical_shift value="122.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CD1"/>
+ <chemical_shift value="26.232" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CD2"/>
+ <chemical_shift value="23.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="H"/>
+ <chemical_shift value="7.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="C"/>
+ <chemical_shift value="176.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CB"/>
+ <chemical_shift value="28.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CA"/>
+ <chemical_shift value="55.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="N"/>
+ <chemical_shift value="113.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="H"/>
+ <chemical_shift value="7.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CB"/>
+ <chemical_shift value="32.958" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CA"/>
+ <chemical_shift value="51.537" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="N"/>
+ <chemical_shift value="113.572" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="H"/>
+ <chemical_shift value="6.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="C"/>
+ <chemical_shift value="176.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CB"/>
+ <chemical_shift value="31.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CA"/>
+ <chemical_shift value="63.731" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="155" name="HD1"/>
+ <atom segid=" A" residue="155" name="HD2"/>
+ <atom segid=" A" residue="155" name="HE1"/>
+ <atom segid=" A" residue="155" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="C"/>
+ <chemical_shift value="176.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CB"/>
+ <chemical_shift value="40.447" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CA"/>
+ <chemical_shift value="62.679" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="N"/>
+ <chemical_shift value="117.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="H"/>
+ <chemical_shift value="7.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="156" name="HD1"/>
+ <atom segid=" A" residue="156" name="HD2"/>
+ <atom segid=" A" residue="156" name="HE1"/>
+ <atom segid=" A" residue="156" name="HE2"/>
+ <atom segid=" A" residue="156" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="C"/>
+ <chemical_shift value="176.222" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CB"/>
+ <chemical_shift value="41.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CA"/>
+ <chemical_shift value="60.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="N"/>
+ <chemical_shift value="112.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="H"/>
+ <chemical_shift value="8.045" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="157" name="HG21"/>
+ <atom segid=" A" residue="157" name="HG22"/>
+ <atom segid=" A" residue="157" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="C"/>
+ <chemical_shift value="176.039" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CB"/>
+ <chemical_shift value="69.29" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CA"/>
+ <chemical_shift value="63.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="N"/>
+ <chemical_shift value="106.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="H"/>
+ <chemical_shift value="7.59" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CB"/>
+ <chemical_shift value="28.509" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CA"/>
+ <chemical_shift value="60.968" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="N"/>
+ <chemical_shift value="124.195" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="C"/>
+ <chemical_shift value="178.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CB"/>
+ <chemical_shift value="30.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CA"/>
+ <chemical_shift value="65.931" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="160" name="HD21"/>
+ <atom segid=" A" residue="160" name="HD22"/>
+ <atom segid=" A" residue="160" name="HD23"/>
+ <chemical_shift value="-0.302" error="0.0"/>
+ <chemical_shift value="-1.003" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="160" name="HD11"/>
+ <atom segid=" A" residue="160" name="HD12"/>
+ <atom segid=" A" residue="160" name="HD13"/>
+ <chemical_shift value="-0.302" error="0.0"/>
+ <chemical_shift value="-1.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="C"/>
+ <chemical_shift value="176.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CB"/>
+ <chemical_shift value="42.223" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CA"/>
+ <chemical_shift value="56.069" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="N"/>
+ <chemical_shift value="111.624" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CD1"/>
+ <chemical_shift value="19.602" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CD2"/>
+ <chemical_shift value="25.084" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="H"/>
+ <chemical_shift value="6.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="161" name="HG21"/>
+ <atom segid=" A" residue="161" name="HG22"/>
+ <atom segid=" A" residue="161" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.76" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="161" name="HD11"/>
+ <atom segid=" A" residue="161" name="HD12"/>
+ <atom segid=" A" residue="161" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="C"/>
+ <chemical_shift value="175.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CB"/>
+ <chemical_shift value="37.395" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CA"/>
+ <chemical_shift value="65.625" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="N"/>
+ <chemical_shift value="119.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CD1"/>
+ <chemical_shift value="13.081" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="H"/>
+ <chemical_shift value="6.955" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="162" name="HB1"/>
+ <atom segid=" A" residue="162" name="HB2"/>
+ <atom segid=" A" residue="162" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="C"/>
+ <chemical_shift value="179.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="CB"/>
+ <chemical_shift value="18.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="CA"/>
+ <chemical_shift value="52.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="N"/>
+ <chemical_shift value="115.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="H"/>
+ <chemical_shift value="8.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="163" name="HB1"/>
+ <atom segid=" A" residue="163" name="HB2"/>
+ <atom segid=" A" residue="163" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="C"/>
+ <chemical_shift value="178.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="CB"/>
+ <chemical_shift value="19.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="CA"/>
+ <chemical_shift value="56.425" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="N"/>
+ <chemical_shift value="120.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="H"/>
+ <chemical_shift value="6.668" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="C"/>
+ <chemical_shift value="176.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CB"/>
+ <chemical_shift value="42.538" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CA"/>
+ <chemical_shift value="53.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="N"/>
+ <chemical_shift value="115.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="H"/>
+ <chemical_shift value="9.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="C"/>
+ <chemical_shift value="175.607" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="H"/>
+ <chemical_shift value="7.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="CA"/>
+ <chemical_shift value="45.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="N"/>
+ <chemical_shift value="103.622" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="C"/>
+ <chemical_shift value="172.227" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="H"/>
+ <chemical_shift value="7.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="CA"/>
+ <chemical_shift value="45.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="N"/>
+ <chemical_shift value="108.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="167" name="HD1"/>
+ <atom segid=" A" residue="167" name="HD2"/>
+ <atom segid=" A" residue="167" name="HE1"/>
+ <atom segid=" A" residue="167" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="C"/>
+ <chemical_shift value="173.273" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CB"/>
+ <chemical_shift value="39.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CA"/>
+ <chemical_shift value="57.657" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="N"/>
+ <chemical_shift value="115.865" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="H"/>
+ <chemical_shift value="8.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="168" name="HB1"/>
+ <atom segid=" A" residue="168" name="HB2"/>
+ <atom segid=" A" residue="168" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="C"/>
+ <chemical_shift value="173.012" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="CB"/>
+ <chemical_shift value="16.475" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="CA"/>
+ <chemical_shift value="53.124" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="N"/>
+ <chemical_shift value="124.0" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="H"/>
+ <chemical_shift value="10.209" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="169" name="HD1"/>
+ <atom segid=" A" residue="169" name="HD2"/>
+ <atom segid=" A" residue="169" name="HE1"/>
+ <atom segid=" A" residue="169" name="HE2"/>
+ <atom segid=" A" residue="169" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="C"/>
+ <chemical_shift value="176.744" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CB"/>
+ <chemical_shift value="42.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CA"/>
+ <chemical_shift value="55.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="N"/>
+ <chemical_shift value="108.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="H"/>
+ <chemical_shift value="6.324" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="170" name="HZ1"/>
+ <atom segid=" A" residue="170" name="HZ2"/>
+ <atom segid=" A" residue="170" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CB"/>
+ <chemical_shift value="32.355" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="C"/>
+ <chemical_shift value="174.716" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="H"/>
+ <chemical_shift value="8.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CA"/>
+ <chemical_shift value="57.027" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="N"/>
+ <chemical_shift value="125.705" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="171" name="HD1"/>
+ <atom segid=" A" residue="171" name="HD2"/>
+ <atom segid=" A" residue="171" name="HE1"/>
+ <atom segid=" A" residue="171" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="C"/>
+ <chemical_shift value="175.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CB"/>
+ <chemical_shift value="39.896" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CA"/>
+ <chemical_shift value="56.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="N"/>
+ <chemical_shift value="129.707" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="H"/>
+ <chemical_shift value="8.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CB"/>
+ <chemical_shift value="32.477" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CA"/>
+ <chemical_shift value="55.981" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="N"/>
+ <chemical_shift value="126.797" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="H"/>
+ <chemical_shift value="8.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="C"/>
+ <chemical_shift value="175.432" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CB"/>
+ <chemical_shift value="37.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CA"/>
+ <chemical_shift value="54.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="C"/>
+ <chemical_shift value="173.294" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="H"/>
+ <chemical_shift value="7.52" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="CA"/>
+ <chemical_shift value="45.705" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="N"/>
+ <chemical_shift value="102.08" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="175" name="HZ1"/>
+ <atom segid=" A" residue="175" name="HZ2"/>
+ <atom segid=" A" residue="175" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CB"/>
+ <chemical_shift value="35.233" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="C"/>
+ <chemical_shift value="174.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="H"/>
+ <chemical_shift value="7.107" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CA"/>
+ <chemical_shift value="54.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="N"/>
+ <chemical_shift value="118.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="176" name="HD1"/>
+ <atom segid=" A" residue="176" name="HD2"/>
+ <atom segid=" A" residue="176" name="HE1"/>
+ <atom segid=" A" residue="176" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="C"/>
+ <chemical_shift value="176.262" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CB"/>
+ <chemical_shift value="39.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CA"/>
+ <chemical_shift value="58.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="N"/>
+ <chemical_shift value="120.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="H"/>
+ <chemical_shift value="8.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="C"/>
+ <chemical_shift value="177.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CB"/>
+ <chemical_shift value="41.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CA"/>
+ <chemical_shift value="52.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="N"/>
+ <chemical_shift value="124.051" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="H"/>
+ <chemical_shift value="9.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="178" name="HG21"/>
+ <atom segid=" A" residue="178" name="HG22"/>
+ <atom segid=" A" residue="178" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.853" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="178" name="HD11"/>
+ <atom segid=" A" residue="178" name="HD12"/>
+ <atom segid=" A" residue="178" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="C"/>
+ <chemical_shift value="175.849" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CB"/>
+ <chemical_shift value="36.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CA"/>
+ <chemical_shift value="63.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="N"/>
+ <chemical_shift value="117.051" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CD1"/>
+ <chemical_shift value="13.905" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="H"/>
+ <chemical_shift value="7.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="179" name="HZ1"/>
+ <atom segid=" A" residue="179" name="HZ2"/>
+ <atom segid=" A" residue="179" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CB"/>
+ <chemical_shift value="31.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="C"/>
+ <chemical_shift value="176.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="H"/>
+ <chemical_shift value="8.302" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CA"/>
+ <chemical_shift value="54.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="N"/>
+ <chemical_shift value="116.075" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="C"/>
+ <chemical_shift value="172.993" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CB"/>
+ <chemical_shift value="40.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CA"/>
+ <chemical_shift value="53.425" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="N"/>
+ <chemical_shift value="123.259" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="H"/>
+ <chemical_shift value="7.754" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="181" name="HG21"/>
+ <atom segid=" A" residue="181" name="HG22"/>
+ <atom segid=" A" residue="181" name="HG23"/>
+ <chemical_shift value="0.711" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="181" name="HG11"/>
+ <atom segid=" A" residue="181" name="HG12"/>
+ <atom segid=" A" residue="181" name="HG13"/>
+ <chemical_shift value="0.711" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="C"/>
+ <chemical_shift value="176.899" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CB"/>
+ <chemical_shift value="35.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CA"/>
+ <chemical_shift value="59.481" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="N"/>
+ <chemical_shift value="122.883" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CG1"/>
+ <chemical_shift value="21.539" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="H"/>
+ <chemical_shift value="7.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CG2"/>
+ <chemical_shift value="22.538" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="C"/>
+ <chemical_shift value="174.259" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="H"/>
+ <chemical_shift value="7.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="CA"/>
+ <chemical_shift value="46.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="N"/>
+ <chemical_shift value="120.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="183" name="HG21"/>
+ <atom segid=" A" residue="183" name="HG22"/>
+ <atom segid=" A" residue="183" name="HG23"/>
+ <chemical_shift value="0.841" error="0.0"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="183" name="HG11"/>
+ <atom segid=" A" residue="183" name="HG12"/>
+ <atom segid=" A" residue="183" name="HG13"/>
+ <chemical_shift value="0.841" error="0.0"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="C"/>
+ <chemical_shift value="173.292" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CB"/>
+ <chemical_shift value="32.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CA"/>
+ <chemical_shift value="63.489" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="N"/>
+ <chemical_shift value="114.266" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CG1"/>
+ <chemical_shift value="22.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="H"/>
+ <chemical_shift value="6.757" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CG2"/>
+ <chemical_shift value="22.42" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="C"/>
+ <chemical_shift value="176.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CB"/>
+ <chemical_shift value="39.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CA"/>
+ <chemical_shift value="51.67" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="N"/>
+ <chemical_shift value="114.851" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="H"/>
+ <chemical_shift value="7.835" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CB"/>
+ <chemical_shift value="39.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CA"/>
+ <chemical_shift value="51.688" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="N"/>
+ <chemical_shift value="116.3" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="H"/>
+ <chemical_shift value="6.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="186" name="HB1"/>
+ <atom segid=" A" residue="186" name="HB2"/>
+ <atom segid=" A" residue="186" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="C"/>
+ <chemical_shift value="180.525" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="CB"/>
+ <chemical_shift value="18.22" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="CA"/>
+ <chemical_shift value="55.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="C"/>
+ <chemical_shift value="176.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="H"/>
+ <chemical_shift value="8.385" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="CA"/>
+ <chemical_shift value="47.366" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="N"/>
+ <chemical_shift value="109.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="188" name="HB1"/>
+ <atom segid=" A" residue="188" name="HB2"/>
+ <atom segid=" A" residue="188" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="C"/>
+ <chemical_shift value="180.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="CB"/>
+ <chemical_shift value="18.399" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="CA"/>
+ <chemical_shift value="54.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="N"/>
+ <chemical_shift value="127.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="H"/>
+ <chemical_shift value="8.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="189" name="HZ1"/>
+ <atom segid=" A" residue="189" name="HZ2"/>
+ <atom segid=" A" residue="189" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CB"/>
+ <chemical_shift value="31.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="C"/>
+ <chemical_shift value="180.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="H"/>
+ <chemical_shift value="7.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CA"/>
+ <chemical_shift value="59.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="N"/>
+ <chemical_shift value="115.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="190" name="HB1"/>
+ <atom segid=" A" residue="190" name="HB2"/>
+ <atom segid=" A" residue="190" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="C"/>
+ <chemical_shift value="181.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="CB"/>
+ <chemical_shift value="17.89" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="CA"/>
+ <chemical_shift value="55.835" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="N"/>
+ <chemical_shift value="124.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="H"/>
+ <chemical_shift value="8.224" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="C"/>
+ <chemical_shift value="174.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="H"/>
+ <chemical_shift value="8.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="CA"/>
+ <chemical_shift value="47.937" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="N"/>
+ <chemical_shift value="107.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="192" name="HD21"/>
+ <atom segid=" A" residue="192" name="HD22"/>
+ <atom segid=" A" residue="192" name="HD23"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="1.085" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="192" name="HD11"/>
+ <atom segid=" A" residue="192" name="HD12"/>
+ <atom segid=" A" residue="192" name="HD13"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="1.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="C"/>
+ <chemical_shift value="178.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CB"/>
+ <chemical_shift value="40.218" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CA"/>
+ <chemical_shift value="57.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="N"/>
+ <chemical_shift value="121.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CD1"/>
+ <chemical_shift value="24.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CD2"/>
+ <chemical_shift value="25.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="H"/>
+ <chemical_shift value="8.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="193" name="HG21"/>
+ <atom segid=" A" residue="193" name="HG22"/>
+ <atom segid=" A" residue="193" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="C"/>
+ <chemical_shift value="175.23" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CB"/>
+ <chemical_shift value="69.081" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CA"/>
+ <chemical_shift value="67.423" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="N"/>
+ <chemical_shift value="116.486" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="H"/>
+ <chemical_shift value="8.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="194" name="HD1"/>
+ <atom segid=" A" residue="194" name="HD2"/>
+ <atom segid=" A" residue="194" name="HE1"/>
+ <atom segid=" A" residue="194" name="HE2"/>
+ <atom segid=" A" residue="194" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="C"/>
+ <chemical_shift value="177.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CB"/>
+ <chemical_shift value="39.196" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CA"/>
+ <chemical_shift value="62.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="N"/>
+ <chemical_shift value="122.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="H"/>
+ <chemical_shift value="7.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="195" name="HD22"/>
+ <atom segid=" A" residue="195" name="HD23"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="195" name="HD11"/>
+ <atom segid=" A" residue="195" name="HD12"/>
+ <atom segid=" A" residue="195" name="HD13"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="C"/>
+ <chemical_shift value="178.132" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CB"/>
+ <chemical_shift value="41.352" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CA"/>
+ <chemical_shift value="58.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="N"/>
+ <chemical_shift value="119.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CD1"/>
+ <chemical_shift value="23.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CD2"/>
+ <chemical_shift value="25.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="H"/>
+ <chemical_shift value="7.712" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="196" name="HG21"/>
+ <atom segid=" A" residue="196" name="HG22"/>
+ <atom segid=" A" residue="196" name="HG23"/>
+ <chemical_shift value="0.856" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="196" name="HG11"/>
+ <atom segid=" A" residue="196" name="HG12"/>
+ <atom segid=" A" residue="196" name="HG13"/>
+ <chemical_shift value="0.856" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="C"/>
+ <chemical_shift value="178.464" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CB"/>
+ <chemical_shift value="31.053" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CA"/>
+ <chemical_shift value="67.271" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="N"/>
+ <chemical_shift value="117.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CG1"/>
+ <chemical_shift value="21.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="H"/>
+ <chemical_shift value="8.589" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CG2"/>
+ <chemical_shift value="23.319" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="C"/>
+ <chemical_shift value="179.361" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CB"/>
+ <chemical_shift value="39.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CA"/>
+ <chemical_shift value="58.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="N"/>
+ <chemical_shift value="122.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="H"/>
+ <chemical_shift value="8.58" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="198" name="HD21"/>
+ <atom segid=" A" residue="198" name="HD22"/>
+ <atom segid=" A" residue="198" name="HD23"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="1.018" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="198" name="HD11"/>
+ <atom segid=" A" residue="198" name="HD12"/>
+ <atom segid=" A" residue="198" name="HD13"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="1.018" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="C"/>
+ <chemical_shift value="179.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CB"/>
+ <chemical_shift value="42.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CA"/>
+ <chemical_shift value="58.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="N"/>
+ <chemical_shift value="120.213" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CD1"/>
+ <chemical_shift value="25.598" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CD2"/>
+ <chemical_shift value="23.461" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="H"/>
+ <chemical_shift value="7.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="199" name="HG21"/>
+ <atom segid=" A" residue="199" name="HG22"/>
+ <atom segid=" A" residue="199" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.743" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="199" name="HD11"/>
+ <atom segid=" A" residue="199" name="HD12"/>
+ <atom segid=" A" residue="199" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.743" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="C"/>
+ <chemical_shift value="181.156" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CB"/>
+ <chemical_shift value="38.209" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CA"/>
+ <chemical_shift value="63.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="N"/>
+ <chemical_shift value="119.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CD1"/>
+ <chemical_shift value="14.222" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="H"/>
+ <chemical_shift value="7.434" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="200" name="HZ1"/>
+ <atom segid=" A" residue="200" name="HZ2"/>
+ <atom segid=" A" residue="200" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CB"/>
+ <chemical_shift value="32.127" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="C"/>
+ <chemical_shift value="178.834" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="H"/>
+ <chemical_shift value="9.393" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CA"/>
+ <chemical_shift value="59.943" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="N"/>
+ <chemical_shift value="124.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="C"/>
+ <chemical_shift value="173.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CB"/>
+ <chemical_shift value="38.686" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CA"/>
+ <chemical_shift value="53.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="N"/>
+ <chemical_shift value="113.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="H"/>
+ <chemical_shift value="8.004" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="202" name="HZ1"/>
+ <atom segid=" A" residue="202" name="HZ2"/>
+ <atom segid=" A" residue="202" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CB"/>
+ <chemical_shift value="27.266" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="C"/>
+ <chemical_shift value="175.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="H"/>
+ <chemical_shift value="7.932" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CA"/>
+ <chemical_shift value="57.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="N"/>
+ <chemical_shift value="111.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="C"/>
+ <chemical_shift value="175.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CB"/>
+ <chemical_shift value="28.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CA"/>
+ <chemical_shift value="57.268" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="N"/>
+ <chemical_shift value="116.235" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="H"/>
+ <chemical_shift value="8.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="204" name="HE1"/>
+ <atom segid=" A" residue="204" name="HE2"/>
+ <atom segid=" A" residue="204" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="C"/>
+ <chemical_shift value="173.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CB"/>
+ <chemical_shift value="37.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CA"/>
+ <chemical_shift value="54.646" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="N"/>
+ <chemical_shift value="114.03" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="H"/>
+ <chemical_shift value="7.477" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="C"/>
+ <chemical_shift value="176.088" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CB"/>
+ <chemical_shift value="40.287" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CA"/>
+ <chemical_shift value="52.185" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="N"/>
+ <chemical_shift value="118.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="H"/>
+ <chemical_shift value="8.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="206" name="HB1"/>
+ <atom segid=" A" residue="206" name="HB2"/>
+ <atom segid=" A" residue="206" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="C"/>
+ <chemical_shift value="176.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="CB"/>
+ <chemical_shift value="18.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="CA"/>
+ <chemical_shift value="54.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="N"/>
+ <chemical_shift value="125.067" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="H"/>
+ <chemical_shift value="9.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="C"/>
+ <chemical_shift value="176.539" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CB"/>
+ <chemical_shift value="39.943" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CA"/>
+ <chemical_shift value="53.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="N"/>
+ <chemical_shift value="112.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="H"/>
+ <chemical_shift value="8.172" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="208" name="HG21"/>
+ <atom segid=" A" residue="208" name="HG22"/>
+ <atom segid=" A" residue="208" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="C"/>
+ <chemical_shift value="173.305" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CB"/>
+ <chemical_shift value="69.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CA"/>
+ <chemical_shift value="66.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="N"/>
+ <chemical_shift value="116.637" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="H"/>
+ <chemical_shift value="7.344" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="C"/>
+ <chemical_shift value="175.818" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CB"/>
+ <chemical_shift value="42.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CA"/>
+ <chemical_shift value="51.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="N"/>
+ <chemical_shift value="130.935" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="H"/>
+ <chemical_shift value="6.982" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="210" name="HD1"/>
+ <atom segid=" A" residue="210" name="HD2"/>
+ <atom segid=" A" residue="210" name="HE1"/>
+ <atom segid=" A" residue="210" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="C"/>
+ <chemical_shift value="178.37" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CB"/>
+ <chemical_shift value="39.077" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CA"/>
+ <chemical_shift value="63.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="N"/>
+ <chemical_shift value="117.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="H"/>
+ <chemical_shift value="7.858" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="C"/>
+ <chemical_shift value="177.629" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="CB"/>
+ <chemical_shift value="63.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="CA"/>
+ <chemical_shift value="61.419" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="N"/>
+ <chemical_shift value="114.682" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="H"/>
+ <chemical_shift value="8.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="212" name="HG21"/>
+ <atom segid=" A" residue="212" name="HG22"/>
+ <atom segid=" A" residue="212" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.867" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="212" name="HD11"/>
+ <atom segid=" A" residue="212" name="HD12"/>
+ <atom segid=" A" residue="212" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="C"/>
+ <chemical_shift value="179.021" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CB"/>
+ <chemical_shift value="38.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CA"/>
+ <chemical_shift value="65.023" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="N"/>
+ <chemical_shift value="124.45" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CD1"/>
+ <chemical_shift value="13.11" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="H"/>
+ <chemical_shift value="8.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="213" name="HB1"/>
+ <atom segid=" A" residue="213" name="HB2"/>
+ <atom segid=" A" residue="213" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="C"/>
+ <chemical_shift value="177.865" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="CB"/>
+ <chemical_shift value="17.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="CA"/>
+ <chemical_shift value="55.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="N"/>
+ <chemical_shift value="120.747" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="H"/>
+ <chemical_shift value="7.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="C"/>
+ <chemical_shift value="178.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CB"/>
+ <chemical_shift value="29.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CA"/>
+ <chemical_shift value="58.941" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="N"/>
+ <chemical_shift value="117.551" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="215" name="HB1"/>
+ <atom segid=" A" residue="215" name="HB2"/>
+ <atom segid=" A" residue="215" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="C"/>
+ <chemical_shift value="179.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="CB"/>
+ <chemical_shift value="18.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="CA"/>
+ <chemical_shift value="54.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="N"/>
+ <chemical_shift value="119.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="H"/>
+ <chemical_shift value="7.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="216" name="HB1"/>
+ <atom segid=" A" residue="216" name="HB2"/>
+ <atom segid=" A" residue="216" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="C"/>
+ <chemical_shift value="180.736" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="CB"/>
+ <chemical_shift value="19.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="CA"/>
+ <chemical_shift value="55.247" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="N"/>
+ <chemical_shift value="117.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="H"/>
+ <chemical_shift value="7.789" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="217" name="HD1"/>
+ <atom segid=" A" residue="217" name="HD2"/>
+ <atom segid=" A" residue="217" name="HE1"/>
+ <atom segid=" A" residue="217" name="HE2"/>
+ <atom segid=" A" residue="217" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CB"/>
+ <chemical_shift value="38.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CA"/>
+ <chemical_shift value="62.919" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="N"/>
+ <chemical_shift value="119.446" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="H"/>
+ <chemical_shift value="8.338" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="C"/>
+ <chemical_shift value="176.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CB"/>
+ <chemical_shift value="36.484" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CA"/>
+ <chemical_shift value="55.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="219" name="HZ1"/>
+ <atom segid=" A" residue="219" name="HZ2"/>
+ <atom segid=" A" residue="219" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CB"/>
+ <chemical_shift value="32.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="C"/>
+ <chemical_shift value="177.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="H"/>
+ <chemical_shift value="7.713" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CA"/>
+ <chemical_shift value="56.131" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="N"/>
+ <chemical_shift value="116.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="C"/>
+ <chemical_shift value="175.309" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="H"/>
+ <chemical_shift value="7.717" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="CA"/>
+ <chemical_shift value="46.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="N"/>
+ <chemical_shift value="108.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="C"/>
+ <chemical_shift value="175.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CB"/>
+ <chemical_shift value="30.469" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CA"/>
+ <chemical_shift value="57.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="N"/>
+ <chemical_shift value="116.369" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="H"/>
+ <chemical_shift value="8.382" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="222" name="HG21"/>
+ <atom segid=" A" residue="222" name="HG22"/>
+ <atom segid=" A" residue="222" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="C"/>
+ <chemical_shift value="172.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CB"/>
+ <chemical_shift value="70.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CA"/>
+ <chemical_shift value="58.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="N"/>
+ <chemical_shift value="110.551" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="H"/>
+ <chemical_shift value="6.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="223" name="HB1"/>
+ <atom segid=" A" residue="223" name="HB2"/>
+ <atom segid=" A" residue="223" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="C"/>
+ <chemical_shift value="176.461" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="CB"/>
+ <chemical_shift value="20.427" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="CA"/>
+ <chemical_shift value="54.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="N"/>
+ <chemical_shift value="127.376" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="H"/>
+ <chemical_shift value="8.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="224" name="HE1"/>
+ <atom segid=" A" residue="224" name="HE2"/>
+ <atom segid=" A" residue="224" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="C"/>
+ <chemical_shift value="173.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CB"/>
+ <chemical_shift value="40.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CA"/>
+ <chemical_shift value="54.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="N"/>
+ <chemical_shift value="114.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="H"/>
+ <chemical_shift value="8.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="225" name="HG21"/>
+ <atom segid=" A" residue="225" name="HG22"/>
+ <atom segid=" A" residue="225" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="C"/>
+ <chemical_shift value="171.424" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CB"/>
+ <chemical_shift value="71.023" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CA"/>
+ <chemical_shift value="59.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="N"/>
+ <chemical_shift value="113.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="H"/>
+ <chemical_shift value="9.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="226" name="HG21"/>
+ <atom segid=" A" residue="226" name="HG22"/>
+ <atom segid=" A" residue="226" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.06" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="226" name="HD11"/>
+ <atom segid=" A" residue="226" name="HD12"/>
+ <atom segid=" A" residue="226" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.06" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="C"/>
+ <chemical_shift value="174.82" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CB"/>
+ <chemical_shift value="40.344" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CA"/>
+ <chemical_shift value="60.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="N"/>
+ <chemical_shift value="122.714" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CD1"/>
+ <chemical_shift value="11.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="H"/>
+ <chemical_shift value="7.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="C"/>
+ <chemical_shift value="175.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CB"/>
+ <chemical_shift value="42.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CA"/>
+ <chemical_shift value="52.466" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="N"/>
+ <chemical_shift value="121.906" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="H"/>
+ <chemical_shift value="8.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="H"/>
+ <chemical_shift value="8.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="CA"/>
+ <chemical_shift value="42.27" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="N"/>
+ <chemical_shift value="110.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CB"/>
+ <chemical_shift value="29.552" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CA"/>
+ <chemical_shift value="62.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="H"/>
+ <chemical_shift value="5.923" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CB"/>
+ <chemical_shift value="26.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CA"/>
+ <chemical_shift value="59.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="N"/>
+ <chemical_shift value="111.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="231" name="HB1"/>
+ <atom segid=" A" residue="231" name="HB2"/>
+ <atom segid=" A" residue="231" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="CB"/>
+ <chemical_shift value="19.11" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="CA"/>
+ <chemical_shift value="52.168" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="N"/>
+ <chemical_shift value="125.512" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="H"/>
+ <chemical_shift value="6.975" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="H"/>
+ <chemical_shift value="7.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CB"/>
+ <chemical_shift value="28.673" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CA"/>
+ <chemical_shift value="58.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="N"/>
+ <chemical_shift value="118.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="235" name="HG21"/>
+ <atom segid=" A" residue="235" name="HG22"/>
+ <atom segid=" A" residue="235" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="235" name="HD11"/>
+ <atom segid=" A" residue="235" name="HD12"/>
+ <atom segid=" A" residue="235" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="237" name="HG21"/>
+ <atom segid=" A" residue="237" name="HG22"/>
+ <atom segid=" A" residue="237" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="239" name="HZ1"/>
+ <atom segid=" A" residue="239" name="HZ2"/>
+ <atom segid=" A" residue="239" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="240" name="HG21"/>
+ <atom segid=" A" residue="240" name="HG22"/>
+ <atom segid=" A" residue="240" name="HG23"/>
+ <atom segid=" A" residue="240" name="HG11"/>
+ <atom segid=" A" residue="240" name="HG12"/>
+ <atom segid=" A" residue="240" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CB"/>
+ <chemical_shift value="37.371" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="242" name="HD1"/>
+ <atom segid=" A" residue="242" name="HD2"/>
+ <atom segid=" A" residue="242" name="HE1"/>
+ <atom segid=" A" residue="242" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="C"/>
+ <chemical_shift value="174.489" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CB"/>
+ <chemical_shift value="41.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CA"/>
+ <chemical_shift value="54.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="N"/>
+ <chemical_shift value="121.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="C"/>
+ <chemical_shift value="171.154" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="H"/>
+ <chemical_shift value="8.494" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="CA"/>
+ <chemical_shift value="42.935" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="N"/>
+ <chemical_shift value="107.501" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="244" name="HG21"/>
+ <atom segid=" A" residue="244" name="HG22"/>
+ <atom segid=" A" residue="244" name="HG23"/>
+ <chemical_shift value="0.636" error="0.0"/>
+ <chemical_shift value="1.072" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="244" name="HG11"/>
+ <atom segid=" A" residue="244" name="HG12"/>
+ <atom segid=" A" residue="244" name="HG13"/>
+ <chemical_shift value="0.636" error="0.0"/>
+ <chemical_shift value="1.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="C"/>
+ <chemical_shift value="174.872" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CB"/>
+ <chemical_shift value="34.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CA"/>
+ <chemical_shift value="61.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="N"/>
+ <chemical_shift value="120.896" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CG1"/>
+ <chemical_shift value="22.083" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="H"/>
+ <chemical_shift value="8.229" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CG2"/>
+ <chemical_shift value="21.606" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="245" name="HG21"/>
+ <atom segid=" A" residue="245" name="HG22"/>
+ <atom segid=" A" residue="245" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="C"/>
+ <chemical_shift value="174.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CB"/>
+ <chemical_shift value="71.559" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CA"/>
+ <chemical_shift value="59.071" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="N"/>
+ <chemical_shift value="119.808" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="H"/>
+ <chemical_shift value="9.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="246" name="HG21"/>
+ <atom segid=" A" residue="246" name="HG22"/>
+ <atom segid=" A" residue="246" name="HG23"/>
+ <chemical_shift value="0.983" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="246" name="HG11"/>
+ <atom segid=" A" residue="246" name="HG12"/>
+ <atom segid=" A" residue="246" name="HG13"/>
+ <chemical_shift value="0.983" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="C"/>
+ <chemical_shift value="175.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CB"/>
+ <chemical_shift value="32.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CA"/>
+ <chemical_shift value="62.433" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="N"/>
+ <chemical_shift value="123.607" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CG1"/>
+ <chemical_shift value="20.441" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CG2"/>
+ <chemical_shift value="21.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="247" name="HD21"/>
+ <atom segid=" A" residue="247" name="HD22"/>
+ <atom segid=" A" residue="247" name="HD23"/>
+ <chemical_shift value="0.645" error="0.0"/>
+ <chemical_shift value="0.663" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="247" name="HD11"/>
+ <atom segid=" A" residue="247" name="HD12"/>
+ <atom segid=" A" residue="247" name="HD13"/>
+ <chemical_shift value="0.645" error="0.0"/>
+ <chemical_shift value="0.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CB"/>
+ <chemical_shift value="40.229" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CA"/>
+ <chemical_shift value="54.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="N"/>
+ <chemical_shift value="125.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CD1"/>
+ <chemical_shift value="25.833" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CD2"/>
+ <chemical_shift value="23.824" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="H"/>
+ <chemical_shift value="8.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="C"/>
+ <chemical_shift value="175.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CB"/>
+ <chemical_shift value="30.183" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CA"/>
+ <chemical_shift value="61.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="249" name="HG21"/>
+ <atom segid=" A" residue="249" name="HG22"/>
+ <atom segid=" A" residue="249" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="C"/>
+ <chemical_shift value="174.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CB"/>
+ <chemical_shift value="71.441" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CA"/>
+ <chemical_shift value="61.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="N"/>
+ <chemical_shift value="111.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="H"/>
+ <chemical_shift value="8.815" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="250" name="HD1"/>
+ <atom segid=" A" residue="250" name="HD2"/>
+ <atom segid=" A" residue="250" name="HE1"/>
+ <atom segid=" A" residue="250" name="HE2"/>
+ <atom segid=" A" residue="250" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="C"/>
+ <chemical_shift value="174.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CB"/>
+ <chemical_shift value="41.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CA"/>
+ <chemical_shift value="56.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="N"/>
+ <chemical_shift value="121.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="H"/>
+ <chemical_shift value="9.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="251" name="HZ1"/>
+ <atom segid=" A" residue="251" name="HZ2"/>
+ <atom segid=" A" residue="251" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CB"/>
+ <chemical_shift value="28.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="C"/>
+ <chemical_shift value="177.723" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="H"/>
+ <chemical_shift value="10.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CA"/>
+ <chemical_shift value="57.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="N"/>
+ <chemical_shift value="129.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="C"/>
+ <chemical_shift value="173.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="H"/>
+ <chemical_shift value="9.031" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="CA"/>
+ <chemical_shift value="45.086" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="N"/>
+ <chemical_shift value="103.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CB"/>
+ <chemical_shift value="29.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CA"/>
+ <chemical_shift value="52.486" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="N"/>
+ <chemical_shift value="122.357" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="H"/>
+ <chemical_shift value="8.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="C"/>
+ <chemical_shift value="178.676" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CB"/>
+ <chemical_shift value="31.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CA"/>
+ <chemical_shift value="62.977" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="C"/>
+ <chemical_shift value="173.658" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="CB"/>
+ <chemical_shift value="64.942" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="CA"/>
+ <chemical_shift value="62.323" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="N"/>
+ <chemical_shift value="117.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="H"/>
+ <chemical_shift value="8.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="256" name="HZ1"/>
+ <atom segid=" A" residue="256" name="HZ2"/>
+ <atom segid=" A" residue="256" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CB"/>
+ <chemical_shift value="33.307" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="H"/>
+ <chemical_shift value="7.639" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CA"/>
+ <chemical_shift value="53.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="N"/>
+ <chemical_shift value="123.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="C"/>
+ <chemical_shift value="177.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CB"/>
+ <chemical_shift value="31.379" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CA"/>
+ <chemical_shift value="62.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="258" name="HD1"/>
+ <atom segid=" A" residue="258" name="HD2"/>
+ <atom segid=" A" residue="258" name="HE1"/>
+ <atom segid=" A" residue="258" name="HE2"/>
+ <atom segid=" A" residue="258" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="C"/>
+ <chemical_shift value="177.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CB"/>
+ <chemical_shift value="40.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CA"/>
+ <chemical_shift value="58.534" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="N"/>
+ <chemical_shift value="118.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="H"/>
+ <chemical_shift value="9.265" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="259" name="HG21"/>
+ <atom segid=" A" residue="259" name="HG22"/>
+ <atom segid=" A" residue="259" name="HG23"/>
+ <chemical_shift value="0.98" error="0.0"/>
+ <chemical_shift value="0.925" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="259" name="HG11"/>
+ <atom segid=" A" residue="259" name="HG12"/>
+ <atom segid=" A" residue="259" name="HG13"/>
+ <chemical_shift value="0.98" error="0.0"/>
+ <chemical_shift value="0.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="C"/>
+ <chemical_shift value="176.569" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CB"/>
+ <chemical_shift value="33.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CA"/>
+ <chemical_shift value="62.078" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="N"/>
+ <chemical_shift value="121.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CG1"/>
+ <chemical_shift value="21.509" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="H"/>
+ <chemical_shift value="8.777" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CG2"/>
+ <chemical_shift value="22.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="C"/>
+ <chemical_shift value="171.463" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="H"/>
+ <chemical_shift value="8.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="CA"/>
+ <chemical_shift value="44.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="N"/>
+ <chemical_shift value="116.16" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="261" name="HG21"/>
+ <atom segid=" A" residue="261" name="HG22"/>
+ <atom segid=" A" residue="261" name="HG23"/>
+ <chemical_shift value="0.565" error="0.0"/>
+ <chemical_shift value="0.679" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="261" name="HG11"/>
+ <atom segid=" A" residue="261" name="HG12"/>
+ <atom segid=" A" residue="261" name="HG13"/>
+ <chemical_shift value="0.565" error="0.0"/>
+ <chemical_shift value="0.679" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="C"/>
+ <chemical_shift value="179.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CB"/>
+ <chemical_shift value="32.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CA"/>
+ <chemical_shift value="60.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="N"/>
+ <chemical_shift value="128.971" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CG1"/>
+ <chemical_shift value="20.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="H"/>
+ <chemical_shift value="11.175" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CG2"/>
+ <chemical_shift value="20.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="262" name="HD21"/>
+ <atom segid=" A" residue="262" name="HD22"/>
+ <atom segid=" A" residue="262" name="HD23"/>
+ <chemical_shift value="0.885" error="0.0"/>
+ <chemical_shift value="0.806" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="262" name="HD11"/>
+ <atom segid=" A" residue="262" name="HD12"/>
+ <atom segid=" A" residue="262" name="HD13"/>
+ <chemical_shift value="0.885" error="0.0"/>
+ <chemical_shift value="0.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="C"/>
+ <chemical_shift value="175.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CB"/>
+ <chemical_shift value="41.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CA"/>
+ <chemical_shift value="56.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="N"/>
+ <chemical_shift value="134.056" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CD1"/>
+ <chemical_shift value="22.681" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CD2"/>
+ <chemical_shift value="25.314" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="H"/>
+ <chemical_shift value="8.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="C"/>
+ <chemical_shift value="170.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="CB"/>
+ <chemical_shift value="66.154" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="CA"/>
+ <chemical_shift value="58.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="N"/>
+ <chemical_shift value="126.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="H"/>
+ <chemical_shift value="8.77" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="264" name="HB1"/>
+ <atom segid=" A" residue="264" name="HB2"/>
+ <atom segid=" A" residue="264" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="C"/>
+ <chemical_shift value="176.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="CB"/>
+ <chemical_shift value="20.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="CA"/>
+ <chemical_shift value="49.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="N"/>
+ <chemical_shift value="123.788" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="H"/>
+ <chemical_shift value="9.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="C"/>
+ <chemical_shift value="171.119" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="H"/>
+ <chemical_shift value="9.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="CA"/>
+ <chemical_shift value="42.908" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="N"/>
+ <chemical_shift value="110.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="266" name="HG21"/>
+ <atom segid=" A" residue="266" name="HG22"/>
+ <atom segid=" A" residue="266" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.915" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="266" name="HD11"/>
+ <atom segid=" A" residue="266" name="HD12"/>
+ <atom segid=" A" residue="266" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.915" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="C"/>
+ <chemical_shift value="175.264" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CB"/>
+ <chemical_shift value="39.519" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CA"/>
+ <chemical_shift value="59.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="N"/>
+ <chemical_shift value="123.632" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CD1"/>
+ <chemical_shift value="13.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="H"/>
+ <chemical_shift value="10.299" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="C"/>
+ <chemical_shift value="177.436" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CB"/>
+ <chemical_shift value="38.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CA"/>
+ <chemical_shift value="53.657" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="N"/>
+ <chemical_shift value="125.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="H"/>
+ <chemical_shift value="8.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="268" name="HB1"/>
+ <atom segid=" A" residue="268" name="HB2"/>
+ <atom segid=" A" residue="268" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="C"/>
+ <chemical_shift value="178.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="CB"/>
+ <chemical_shift value="17.854" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="CA"/>
+ <chemical_shift value="55.511" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="N"/>
+ <chemical_shift value="131.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="H"/>
+ <chemical_shift value="8.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="269" name="HB1"/>
+ <atom segid=" A" residue="269" name="HB2"/>
+ <atom segid=" A" residue="269" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="C"/>
+ <chemical_shift value="178.117" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="CB"/>
+ <chemical_shift value="18.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="CA"/>
+ <chemical_shift value="51.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="N"/>
+ <chemical_shift value="117.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="CB"/>
+ <chemical_shift value="64.366" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="CA"/>
+ <chemical_shift value="56.356" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="N"/>
+ <chemical_shift value="112.93" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="H"/>
+ <chemical_shift value="7.621" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="C"/>
+ <chemical_shift value="175.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CB"/>
+ <chemical_shift value="30.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CA"/>
+ <chemical_shift value="63.726" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="C"/>
+ <chemical_shift value="176.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CB"/>
+ <chemical_shift value="40.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CA"/>
+ <chemical_shift value="52.889" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="N"/>
+ <chemical_shift value="119.716" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="H"/>
+ <chemical_shift value="8.881" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="273" name="HZ1"/>
+ <atom segid=" A" residue="273" name="HZ2"/>
+ <atom segid=" A" residue="273" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CB"/>
+ <chemical_shift value="31.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="C"/>
+ <chemical_shift value="179.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="H"/>
+ <chemical_shift value="7.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CA"/>
+ <chemical_shift value="61.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="N"/>
+ <chemical_shift value="119.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="C"/>
+ <chemical_shift value="179.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CB"/>
+ <chemical_shift value="27.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CA"/>
+ <chemical_shift value="59.973" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="N"/>
+ <chemical_shift value="118.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="H"/>
+ <chemical_shift value="8.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="275" name="HD21"/>
+ <atom segid=" A" residue="275" name="HD22"/>
+ <atom segid=" A" residue="275" name="HD23"/>
+ <chemical_shift value="0.947" error="0.0"/>
+ <chemical_shift value="0.933" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="275" name="HD11"/>
+ <atom segid=" A" residue="275" name="HD12"/>
+ <atom segid=" A" residue="275" name="HD13"/>
+ <chemical_shift value="0.947" error="0.0"/>
+ <chemical_shift value="0.933" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="C"/>
+ <chemical_shift value="178.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CB"/>
+ <chemical_shift value="42.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CA"/>
+ <chemical_shift value="57.369" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="N"/>
+ <chemical_shift value="120.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CD1"/>
+ <chemical_shift value="25.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CD2"/>
+ <chemical_shift value="22.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="H"/>
+ <chemical_shift value="7.385" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="276" name="HB1"/>
+ <atom segid=" A" residue="276" name="HB2"/>
+ <atom segid=" A" residue="276" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="C"/>
+ <chemical_shift value="178.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="CB"/>
+ <chemical_shift value="17.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="CA"/>
+ <chemical_shift value="55.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="N"/>
+ <chemical_shift value="120.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="H"/>
+ <chemical_shift value="8.405" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="277" name="HZ1"/>
+ <atom segid=" A" residue="277" name="HZ2"/>
+ <atom segid=" A" residue="277" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CB"/>
+ <chemical_shift value="32.345" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="C"/>
+ <chemical_shift value="177.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="H"/>
+ <chemical_shift value="7.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CA"/>
+ <chemical_shift value="60.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="N"/>
+ <chemical_shift value="118.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="C"/>
+ <chemical_shift value="179.24" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CB"/>
+ <chemical_shift value="29.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CA"/>
+ <chemical_shift value="59.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="N"/>
+ <chemical_shift value="118.647" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="H"/>
+ <chemical_shift value="7.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="279" name="HD1"/>
+ <atom segid=" A" residue="279" name="HD2"/>
+ <atom segid=" A" residue="279" name="HE1"/>
+ <atom segid=" A" residue="279" name="HE2"/>
+ <atom segid=" A" residue="279" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="C"/>
+ <chemical_shift value="177.602" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CB"/>
+ <chemical_shift value="38.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CA"/>
+ <chemical_shift value="61.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="N"/>
+ <chemical_shift value="118.378" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="280" name="HD21"/>
+ <atom segid=" A" residue="280" name="HD22"/>
+ <atom segid=" A" residue="280" name="HD23"/>
+ <chemical_shift value="0.71" error="0.0"/>
+ <chemical_shift value="0.672" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="280" name="HD11"/>
+ <atom segid=" A" residue="280" name="HD12"/>
+ <atom segid=" A" residue="280" name="HD13"/>
+ <chemical_shift value="0.71" error="0.0"/>
+ <chemical_shift value="0.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="C"/>
+ <chemical_shift value="177.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CB"/>
+ <chemical_shift value="40.671" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CA"/>
+ <chemical_shift value="58.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="N"/>
+ <chemical_shift value="120.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CD1"/>
+ <chemical_shift value="25.779" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CD2"/>
+ <chemical_shift value="23.405" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="H"/>
+ <chemical_shift value="8.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="C"/>
+ <chemical_shift value="177.096" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CB"/>
+ <chemical_shift value="29.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CA"/>
+ <chemical_shift value="59.622" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="N"/>
+ <chemical_shift value="112.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="H"/>
+ <chemical_shift value="8.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="C"/>
+ <chemical_shift value="175.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CB"/>
+ <chemical_shift value="38.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CA"/>
+ <chemical_shift value="53.164" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="N"/>
+ <chemical_shift value="108.811" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="H"/>
+ <chemical_shift value="7.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="283" name="HD1"/>
+ <atom segid=" A" residue="283" name="HD2"/>
+ <atom segid=" A" residue="283" name="HE1"/>
+ <atom segid=" A" residue="283" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="C"/>
+ <chemical_shift value="176.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CB"/>
+ <chemical_shift value="38.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CA"/>
+ <chemical_shift value="59.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="N"/>
+ <chemical_shift value="116.373" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="H"/>
+ <chemical_shift value="7.164" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="284" name="HD21"/>
+ <atom segid=" A" residue="284" name="HD22"/>
+ <atom segid=" A" residue="284" name="HD23"/>
+ <chemical_shift value="1.039" error="0.0"/>
+ <chemical_shift value="0.843" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="284" name="HD11"/>
+ <atom segid=" A" residue="284" name="HD12"/>
+ <atom segid=" A" residue="284" name="HD13"/>
+ <chemical_shift value="1.039" error="0.0"/>
+ <chemical_shift value="0.843" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="C"/>
+ <chemical_shift value="176.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CB"/>
+ <chemical_shift value="41.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CA"/>
+ <chemical_shift value="58.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="N"/>
+ <chemical_shift value="121.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CD1"/>
+ <chemical_shift value="23.945" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CD2"/>
+ <chemical_shift value="27.398" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="H"/>
+ <chemical_shift value="8.101" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="285" name="HD21"/>
+ <atom segid=" A" residue="285" name="HD22"/>
+ <atom segid=" A" residue="285" name="HD23"/>
+ <chemical_shift value="1.119" error="0.0"/>
+ <chemical_shift value="1.052" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="285" name="HD11"/>
+ <atom segid=" A" residue="285" name="HD12"/>
+ <atom segid=" A" residue="285" name="HD13"/>
+ <chemical_shift value="1.119" error="0.0"/>
+ <chemical_shift value="1.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="C"/>
+ <chemical_shift value="174.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CB"/>
+ <chemical_shift value="38.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CA"/>
+ <chemical_shift value="54.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="N"/>
+ <chemical_shift value="119.204" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CD1"/>
+ <chemical_shift value="25.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CD2"/>
+ <chemical_shift value="24.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="H"/>
+ <chemical_shift value="7.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="286" name="HG21"/>
+ <atom segid=" A" residue="286" name="HG22"/>
+ <atom segid=" A" residue="286" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="C"/>
+ <chemical_shift value="174.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CB"/>
+ <chemical_shift value="73.569" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CA"/>
+ <chemical_shift value="59.007" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="N"/>
+ <chemical_shift value="108.713" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="H"/>
+ <chemical_shift value="8.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="C"/>
+ <chemical_shift value="177.87" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CB"/>
+ <chemical_shift value="39.534" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CA"/>
+ <chemical_shift value="58.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="N"/>
+ <chemical_shift value="122.217" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="H"/>
+ <chemical_shift value="8.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="C"/>
+ <chemical_shift value="180.161" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CB"/>
+ <chemical_shift value="29.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CA"/>
+ <chemical_shift value="59.339" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="N"/>
+ <chemical_shift value="115.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="H"/>
+ <chemical_shift value="8.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="C"/>
+ <chemical_shift value="175.256" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="H"/>
+ <chemical_shift value="8.328" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="CA"/>
+ <chemical_shift value="46.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="N"/>
+ <chemical_shift value="112.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
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+ <atom segid=" A" residue="290" name="HD22"/>
+ <atom segid=" A" residue="290" name="HD23"/>
+ <chemical_shift value="0.792" error="0.0"/>
+ <chemical_shift value="1.074" error="0.0"/>
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+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="290" name="HD11"/>
+ <atom segid=" A" residue="290" name="HD12"/>
+ <atom segid=" A" residue="290" name="HD13"/>
+ <chemical_shift value="0.792" error="0.0"/>
+ <chemical_shift value="1.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="C"/>
+ <chemical_shift value="179.873" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CB"/>
+ <chemical_shift value="41.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CA"/>
+ <chemical_shift value="57.262" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="N"/>
+ <chemical_shift value="119.553" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CD1"/>
+ <chemical_shift value="27.886" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CD2"/>
+ <chemical_shift value="21.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="H"/>
+ <chemical_shift value="8.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="C"/>
+ <chemical_shift value="178.136" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CB"/>
+ <chemical_shift value="29.033" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CA"/>
+ <chemical_shift value="59.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="N"/>
+ <chemical_shift value="120.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="H"/>
+ <chemical_shift value="7.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="292" name="HB1"/>
+ <atom segid=" A" residue="292" name="HB2"/>
+ <atom segid=" A" residue="292" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="C"/>
+ <chemical_shift value="180.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="CB"/>
+ <chemical_shift value="17.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="CA"/>
+ <chemical_shift value="55.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="N"/>
+ <chemical_shift value="119.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="H"/>
+ <chemical_shift value="7.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="293" name="HG21"/>
+ <atom segid=" A" residue="293" name="HG22"/>
+ <atom segid=" A" residue="293" name="HG23"/>
+ <chemical_shift value="0.901" error="0.0"/>
+ <chemical_shift value="1.004" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="293" name="HG11"/>
+ <atom segid=" A" residue="293" name="HG12"/>
+ <atom segid=" A" residue="293" name="HG13"/>
+ <chemical_shift value="0.901" error="0.0"/>
+ <chemical_shift value="1.004" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="C"/>
+ <chemical_shift value="177.079" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CB"/>
+ <chemical_shift value="32.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CA"/>
+ <chemical_shift value="67.318" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="N"/>
+ <chemical_shift value="115.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CG1"/>
+ <chemical_shift value="21.422" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="H"/>
+ <chemical_shift value="7.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CG2"/>
+ <chemical_shift value="22.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="C"/>
+ <chemical_shift value="176.45" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CB"/>
+ <chemical_shift value="40.911" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CA"/>
+ <chemical_shift value="56.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="N"/>
+ <chemical_shift value="117.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="H"/>
+ <chemical_shift value="8.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="295" name="HZ1"/>
+ <atom segid=" A" residue="295" name="HZ2"/>
+ <atom segid=" A" residue="295" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CB"/>
+ <chemical_shift value="31.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="C"/>
+ <chemical_shift value="177.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CA"/>
+ <chemical_shift value="58.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="N"/>
+ <chemical_shift value="115.927" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="C"/>
+ <chemical_shift value="176.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CB"/>
+ <chemical_shift value="41.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CA"/>
+ <chemical_shift value="56.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="N"/>
+ <chemical_shift value="118.991" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="H"/>
+ <chemical_shift value="7.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="297" name="HZ2"/>
+ <atom segid=" A" residue="297" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CB"/>
+ <chemical_shift value="34.952" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="H"/>
+ <chemical_shift value="7.654" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CA"/>
+ <chemical_shift value="52.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="N"/>
+ <chemical_shift value="115.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="C"/>
+ <chemical_shift value="178.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CB"/>
+ <chemical_shift value="31.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CA"/>
+ <chemical_shift value="63.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="299" name="HD21"/>
+ <atom segid=" A" residue="299" name="HD22"/>
+ <atom segid=" A" residue="299" name="HD23"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="299" name="HD11"/>
+ <atom segid=" A" residue="299" name="HD12"/>
+ <atom segid=" A" residue="299" name="HD13"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="C"/>
+ <chemical_shift value="177.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CB"/>
+ <chemical_shift value="43.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CA"/>
+ <chemical_shift value="55.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="N"/>
+ <chemical_shift value="121.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CD1"/>
+ <chemical_shift value="26.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CD2"/>
+ <chemical_shift value="22.958" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="H"/>
+ <chemical_shift value="8.532" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="44.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="301" name="HB2"/>
+ <atom segid=" A" residue="301" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="177.667" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="19.844" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="CA"/>
+ <chemical_shift value="51.558" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="123.834" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="7.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="302" name="HG22"/>
+ <atom segid=" A" residue="302" name="HG23"/>
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+ <chemical_shift value="1.059" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="302" name="HG11"/>
+ <atom segid=" A" residue="302" name="HG12"/>
+ <atom segid=" A" residue="302" name="HG13"/>
+ <chemical_shift value="1.262" error="0.0"/>
+ <chemical_shift value="1.059" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="174.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="35.614" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CA"/>
+ <chemical_shift value="59.9" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="N"/>
+ <chemical_shift value="110.163" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CG1"/>
+ <chemical_shift value="22.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="H"/>
+ <chemical_shift value="8.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="19.07" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="303" name="HB2"/>
+ <atom segid=" A" residue="303" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="175.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="19.491" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="53.039" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="117.932" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="7.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
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+ <atom segid=" A" residue="304" name="HD22"/>
+ <atom segid=" A" residue="304" name="HD23"/>
+ <chemical_shift value="0.702" error="0.0"/>
+ <chemical_shift value="0.848" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="304" name="HD12"/>
+ <atom segid=" A" residue="304" name="HD13"/>
+ <chemical_shift value="0.702" error="0.0"/>
+ <chemical_shift value="0.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="175.458" error="0.0"/>
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CB"/>
+ <chemical_shift value="44.147" error="0.0"/>
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="54.335" error="0.0"/>
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="114.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="24.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="26.586" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="6.347" error="0.0"/>
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="305" name="HZ1"/>
+ <atom segid=" A" residue="305" name="HZ2"/>
+ <atom segid=" A" residue="305" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CB"/>
+ <chemical_shift value="31.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="C"/>
+ <chemical_shift value="178.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="H"/>
+ <chemical_shift value="8.043" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CA"/>
+ <chemical_shift value="60.428" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="N"/>
+ <chemical_shift value="129.631" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="C"/>
+ <chemical_shift value="176.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="CB"/>
+ <chemical_shift value="60.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="CA"/>
+ <chemical_shift value="61.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="N"/>
+ <chemical_shift value="111.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="H"/>
+ <chemical_shift value="8.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="307" name="HD1"/>
+ <atom segid=" A" residue="307" name="HD2"/>
+ <atom segid=" A" residue="307" name="HE1"/>
+ <atom segid=" A" residue="307" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="C"/>
+ <chemical_shift value="177.811" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CB"/>
+ <chemical_shift value="38.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CA"/>
+ <chemical_shift value="58.904" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="N"/>
+ <chemical_shift value="122.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="H"/>
+ <chemical_shift value="6.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="C"/>
+ <chemical_shift value="177.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CB"/>
+ <chemical_shift value="26.173" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CA"/>
+ <chemical_shift value="58.466" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="N"/>
+ <chemical_shift value="122.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="H"/>
+ <chemical_shift value="8.473" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="C"/>
+ <chemical_shift value="178.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CB"/>
+ <chemical_shift value="28.862" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CA"/>
+ <chemical_shift value="58.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="N"/>
+ <chemical_shift value="114.962" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="H"/>
+ <chemical_shift value="7.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="C"/>
+ <chemical_shift value="178.868" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CB"/>
+ <chemical_shift value="29.333" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CA"/>
+ <chemical_shift value="57.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="N"/>
+ <chemical_shift value="116.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="H"/>
+ <chemical_shift value="7.092" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="311" name="HD22"/>
+ <atom segid=" A" residue="311" name="HD23"/>
+ <chemical_shift value="0.797" error="0.0"/>
+ <chemical_shift value="0.87" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="311" name="HD11"/>
+ <atom segid=" A" residue="311" name="HD12"/>
+ <atom segid=" A" residue="311" name="HD13"/>
+ <chemical_shift value="0.797" error="0.0"/>
+ <chemical_shift value="0.87" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="C"/>
+ <chemical_shift value="179.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CB"/>
+ <chemical_shift value="41.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CA"/>
+ <chemical_shift value="57.324" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="N"/>
+ <chemical_shift value="120.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CD1"/>
+ <chemical_shift value="26.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CD2"/>
+ <chemical_shift value="22.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="H"/>
+ <chemical_shift value="8.021" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="312" name="HB1"/>
+ <atom segid=" A" residue="312" name="HB2"/>
+ <atom segid=" A" residue="312" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="C"/>
+ <chemical_shift value="174.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="CB"/>
+ <chemical_shift value="17.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="CA"/>
+ <chemical_shift value="54.037" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="N"/>
+ <chemical_shift value="114.676" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="H"/>
+ <chemical_shift value="8.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="313" name="HZ1"/>
+ <atom segid=" A" residue="313" name="HZ2"/>
+ <atom segid=" A" residue="313" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CB"/>
+ <chemical_shift value="31.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="C"/>
+ <chemical_shift value="177.97" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="H"/>
+ <chemical_shift value="6.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CA"/>
+ <chemical_shift value="58.418" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="N"/>
+ <chemical_shift value="119.315" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CB"/>
+ <chemical_shift value="41.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CA"/>
+ <chemical_shift value="50.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="N"/>
+ <chemical_shift value="121.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="H"/>
+ <chemical_shift value="8.311" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="C"/>
+ <chemical_shift value="179.227" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CB"/>
+ <chemical_shift value="32.168" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CA"/>
+ <chemical_shift value="64.525" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CB"/>
+ <chemical_shift value="29.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="C"/>
+ <chemical_shift value="179.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="H"/>
+ <chemical_shift value="8.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CA"/>
+ <chemical_shift value="58.813" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="N"/>
+ <chemical_shift value="116.913" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="317" name="HG21"/>
+ <atom segid=" A" residue="317" name="HG22"/>
+ <atom segid=" A" residue="317" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="1.118" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="317" name="HD11"/>
+ <atom segid=" A" residue="317" name="HD12"/>
+ <atom segid=" A" residue="317" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="1.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="C"/>
+ <chemical_shift value="178.067" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CB"/>
+ <chemical_shift value="35.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CA"/>
+ <chemical_shift value="64.418" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="N"/>
+ <chemical_shift value="123.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CD1"/>
+ <chemical_shift value="12.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="H"/>
+ <chemical_shift value="7.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="318" name="HB1"/>
+ <atom segid=" A" residue="318" name="HB2"/>
+ <atom segid=" A" residue="318" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="C"/>
+ <chemical_shift value="181.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="CB"/>
+ <chemical_shift value="17.268" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="CA"/>
+ <chemical_shift value="56.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="N"/>
+ <chemical_shift value="123.335" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="H"/>
+ <chemical_shift value="7.906" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="319" name="HB1"/>
+ <atom segid=" A" residue="319" name="HB2"/>
+ <atom segid=" A" residue="319" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="C"/>
+ <chemical_shift value="178.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="CB"/>
+ <chemical_shift value="17.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="CA"/>
+ <chemical_shift value="55.519" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="N"/>
+ <chemical_shift value="118.979" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="H"/>
+ <chemical_shift value="8.086" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="320" name="HG21"/>
+ <atom segid=" A" residue="320" name="HG22"/>
+ <atom segid=" A" residue="320" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="C"/>
+ <chemical_shift value="175.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="CB"/>
+ <chemical_shift value="69.151" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="CA"/>
+ <chemical_shift value="67.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="N"/>
+ <chemical_shift value="114.58" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="H"/>
+ <chemical_shift value="7.358" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="321" name="HE1"/>
+ <atom segid=" A" residue="321" name="HE2"/>
+ <atom segid=" A" residue="321" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="C"/>
+ <chemical_shift value="177.825" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CB"/>
+ <chemical_shift value="30.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CA"/>
+ <chemical_shift value="56.766" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="N"/>
+ <chemical_shift value="118.804" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="H"/>
+ <chemical_shift value="8.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="C"/>
+ <chemical_shift value="179.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CB"/>
+ <chemical_shift value="28.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CA"/>
+ <chemical_shift value="59.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="N"/>
+ <chemical_shift value="122.177" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="H"/>
+ <chemical_shift value="8.267" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="CB"/>
+ <chemical_shift value="39.313" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="CA"/>
+ <chemical_shift value="57.124" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="N"/>
+ <chemical_shift value="115.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="H"/>
+ <chemical_shift value="8.207" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="324" name="HB2"/>
+ <atom segid=" A" residue="324" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="180.381" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="CB"/>
+ <chemical_shift value="17.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="CA"/>
+ <chemical_shift value="54.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="N"/>
+ <chemical_shift value="119.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="H"/>
+ <chemical_shift value="8.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="177.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CB"/>
+ <chemical_shift value="27.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CA"/>
+ <chemical_shift value="58.414" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="N"/>
+ <chemical_shift value="116.35" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="H"/>
+ <chemical_shift value="8.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="326" name="HZ1"/>
+ <atom segid=" A" residue="326" name="HZ2"/>
+ <atom segid=" A" residue="326" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CB"/>
+ <chemical_shift value="32.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="C"/>
+ <chemical_shift value="176.163" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="H"/>
+ <chemical_shift value="7.079" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CA"/>
+ <chemical_shift value="56.011" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="N"/>
+ <chemical_shift value="117.692" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="C"/>
+ <chemical_shift value="172.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="H"/>
+ <chemical_shift value="7.293" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="CA"/>
+ <chemical_shift value="44.518" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="N"/>
+ <chemical_shift value="106.636" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="C"/>
+ <chemical_shift value="176.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CB"/>
+ <chemical_shift value="32.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CA"/>
+ <chemical_shift value="54.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="N"/>
+ <chemical_shift value="121.098" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="H"/>
+ <chemical_shift value="8.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="329" name="HG21"/>
+ <atom segid=" A" residue="329" name="HG22"/>
+ <atom segid=" A" residue="329" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.821" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="329" name="HD11"/>
+ <atom segid=" A" residue="329" name="HD12"/>
+ <atom segid=" A" residue="329" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="C"/>
+ <chemical_shift value="178.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CB"/>
+ <chemical_shift value="37.812" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CA"/>
+ <chemical_shift value="62.15" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="N"/>
+ <chemical_shift value="127.522" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CD1"/>
+ <chemical_shift value="12.362" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="H"/>
+ <chemical_shift value="9.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="330" name="HE1"/>
+ <atom segid=" A" residue="330" name="HE2"/>
+ <atom segid=" A" residue="330" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CB"/>
+ <chemical_shift value="34.295" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CA"/>
+ <chemical_shift value="56.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="N"/>
+ <chemical_shift value="124.379" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="H"/>
+ <chemical_shift value="8.502" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="C"/>
+ <chemical_shift value="175.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CB"/>
+ <chemical_shift value="31.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CA"/>
+ <chemical_shift value="63.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="C"/>
+ <chemical_shift value="175.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CB"/>
+ <chemical_shift value="38.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CA"/>
+ <chemical_shift value="51.443" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="N"/>
+ <chemical_shift value="117.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="H"/>
+ <chemical_shift value="7.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="333" name="HG21"/>
+ <atom segid=" A" residue="333" name="HG22"/>
+ <atom segid=" A" residue="333" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="-0.138" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="333" name="HD11"/>
+ <atom segid=" A" residue="333" name="HD12"/>
+ <atom segid=" A" residue="333" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="-0.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CB"/>
+ <chemical_shift value="36.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CA"/>
+ <chemical_shift value="59.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="N"/>
+ <chemical_shift value="108.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CD1"/>
+ <chemical_shift value="12.253" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="H"/>
+ <chemical_shift value="6.382" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="C"/>
+ <chemical_shift value="178.686" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CB"/>
+ <chemical_shift value="31.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CA"/>
+ <chemical_shift value="65.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="C"/>
+ <chemical_shift value="177.018" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CB"/>
+ <chemical_shift value="26.389" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CA"/>
+ <chemical_shift value="59.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="N"/>
+ <chemical_shift value="116.31" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="336" name="HE1"/>
+ <atom segid=" A" residue="336" name="HE2"/>
+ <atom segid=" A" residue="336" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="C"/>
+ <chemical_shift value="177.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CB"/>
+ <chemical_shift value="30.289" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CA"/>
+ <chemical_shift value="56.084" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="N"/>
+ <chemical_shift value="118.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="H"/>
+ <chemical_shift value="7.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="C"/>
+ <chemical_shift value="177.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="CB"/>
+ <chemical_shift value="60.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="CA"/>
+ <chemical_shift value="62.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="N"/>
+ <chemical_shift value="113.543" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="H"/>
+ <chemical_shift value="7.924" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="338" name="HB1"/>
+ <atom segid=" A" residue="338" name="HB2"/>
+ <atom segid=" A" residue="338" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="C"/>
+ <chemical_shift value="180.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="CB"/>
+ <chemical_shift value="18.545" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="CA"/>
+ <chemical_shift value="54.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="N"/>
+ <chemical_shift value="122.856" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="H"/>
+ <chemical_shift value="7.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="339" name="HD1"/>
+ <atom segid=" A" residue="339" name="HD2"/>
+ <atom segid=" A" residue="339" name="HE1"/>
+ <atom segid=" A" residue="339" name="HE2"/>
+ <atom segid=" A" residue="339" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="C"/>
+ <chemical_shift value="176.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CB"/>
+ <chemical_shift value="38.827" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CA"/>
+ <chemical_shift value="61.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="N"/>
+ <chemical_shift value="118.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="H"/>
+ <chemical_shift value="7.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="H"/>
+ <chemical_shift value="8.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="C"/>
+ <chemical_shift value="179.128" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CB"/>
+ <chemical_shift value="30.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CA"/>
+ <chemical_shift value="59.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="N"/>
+ <chemical_shift value="118.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="341" name="HD1"/>
+ <atom segid=" A" residue="341" name="HD2"/>
+ <atom segid=" A" residue="341" name="HE1"/>
+ <atom segid=" A" residue="341" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="C"/>
+ <chemical_shift value="178.712" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CB"/>
+ <chemical_shift value="38.306" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CA"/>
+ <chemical_shift value="61.558" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="N"/>
+ <chemical_shift value="114.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="H"/>
+ <chemical_shift value="7.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="342" name="HB1"/>
+ <atom segid=" A" residue="342" name="HB2"/>
+ <atom segid=" A" residue="342" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="C"/>
+ <chemical_shift value="180.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="CB"/>
+ <chemical_shift value="19.012" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="CA"/>
+ <chemical_shift value="55.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="N"/>
+ <chemical_shift value="121.914" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="H"/>
+ <chemical_shift value="8.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="343" name="HG21"/>
+ <atom segid=" A" residue="343" name="HG22"/>
+ <atom segid=" A" residue="343" name="HG23"/>
+ <chemical_shift value="0.168" error="0.0"/>
+ <chemical_shift value="0.863" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="343" name="HG11"/>
+ <atom segid=" A" residue="343" name="HG12"/>
+ <atom segid=" A" residue="343" name="HG13"/>
+ <chemical_shift value="0.168" error="0.0"/>
+ <chemical_shift value="0.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="C"/>
+ <chemical_shift value="177.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CB"/>
+ <chemical_shift value="31.022" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CA"/>
+ <chemical_shift value="66.924" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="N"/>
+ <chemical_shift value="118.57" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CG1"/>
+ <chemical_shift value="21.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="H"/>
+ <chemical_shift value="8.63" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CG2"/>
+ <chemical_shift value="23.236" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CB"/>
+ <chemical_shift value="29.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="C"/>
+ <chemical_shift value="178.506" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="H"/>
+ <chemical_shift value="8.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CA"/>
+ <chemical_shift value="60.236" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="N"/>
+ <chemical_shift value="120.769" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="345" name="HG21"/>
+ <atom segid=" A" residue="345" name="HG22"/>
+ <atom segid=" A" residue="345" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="C"/>
+ <chemical_shift value="175.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CB"/>
+ <chemical_shift value="69.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CA"/>
+ <chemical_shift value="66.564" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="N"/>
+ <chemical_shift value="113.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="H"/>
+ <chemical_shift value="7.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="346" name="HB1"/>
+ <atom segid=" A" residue="346" name="HB2"/>
+ <atom segid=" A" residue="346" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="C"/>
+ <chemical_shift value="179.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="CB"/>
+ <chemical_shift value="18.537" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="CA"/>
+ <chemical_shift value="55.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="N"/>
+ <chemical_shift value="122.933" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="H"/>
+ <chemical_shift value="7.805" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="347" name="HG21"/>
+ <atom segid=" A" residue="347" name="HG22"/>
+ <atom segid=" A" residue="347" name="HG23"/>
+ <chemical_shift value="1.043" error="0.0"/>
+ <chemical_shift value="0.918" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="347" name="HG11"/>
+ <atom segid=" A" residue="347" name="HG12"/>
+ <atom segid=" A" residue="347" name="HG13"/>
+ <chemical_shift value="1.043" error="0.0"/>
+ <chemical_shift value="0.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="C"/>
+ <chemical_shift value="178.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CB"/>
+ <chemical_shift value="31.336" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CA"/>
+ <chemical_shift value="67.494" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="N"/>
+ <chemical_shift value="115.988" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CG1"/>
+ <chemical_shift value="20.468" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CG2"/>
+ <chemical_shift value="22.282" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="348" name="HG21"/>
+ <atom segid=" A" residue="348" name="HG22"/>
+ <atom segid=" A" residue="348" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.869" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="348" name="HD11"/>
+ <atom segid=" A" residue="348" name="HD12"/>
+ <atom segid=" A" residue="348" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.869" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="C"/>
+ <chemical_shift value="180.338" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CB"/>
+ <chemical_shift value="37.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CA"/>
+ <chemical_shift value="65.054" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="N"/>
+ <chemical_shift value="118.38" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CD1"/>
+ <chemical_shift value="12.965" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="H"/>
+ <chemical_shift value="7.771" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="C"/>
+ <chemical_shift value="178.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CB"/>
+ <chemical_shift value="37.166" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CA"/>
+ <chemical_shift value="55.948" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="N"/>
+ <chemical_shift value="121.103" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="H"/>
+ <chemical_shift value="8.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="350" name="HB1"/>
+ <atom segid=" A" residue="350" name="HB2"/>
+ <atom segid=" A" residue="350" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="C"/>
+ <chemical_shift value="181.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="CB"/>
+ <chemical_shift value="17.998" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="CA"/>
+ <chemical_shift value="54.159" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="N"/>
+ <chemical_shift value="122.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="H"/>
+ <chemical_shift value="8.52" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="351" name="HB1"/>
+ <atom segid=" A" residue="351" name="HB2"/>
+ <atom segid=" A" residue="351" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="C"/>
+ <chemical_shift value="178.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="CB"/>
+ <chemical_shift value="18.028" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="CA"/>
+ <chemical_shift value="55.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="N"/>
+ <chemical_shift value="121.112" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="H"/>
+ <chemical_shift value="9.165" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="C"/>
+ <chemical_shift value="175.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="CB"/>
+ <chemical_shift value="64.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="CA"/>
+ <chemical_shift value="58.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="N"/>
+ <chemical_shift value="107.997" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="H"/>
+ <chemical_shift value="7.88" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="C"/>
+ <chemical_shift value="174.546" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="H"/>
+ <chemical_shift value="7.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="CA"/>
+ <chemical_shift value="45.785" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="N"/>
+ <chemical_shift value="109.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CB"/>
+ <chemical_shift value="30.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="C"/>
+ <chemical_shift value="176.819" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="H"/>
+ <chemical_shift value="8.225" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CA"/>
+ <chemical_shift value="58.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="N"/>
+ <chemical_shift value="121.096" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="C"/>
+ <chemical_shift value="176.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CB"/>
+ <chemical_shift value="36.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CA"/>
+ <chemical_shift value="54.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="N"/>
+ <chemical_shift value="113.634" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="H"/>
+ <chemical_shift value="7.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="356" name="HG21"/>
+ <atom segid=" A" residue="356" name="HG22"/>
+ <atom segid=" A" residue="356" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="C"/>
+ <chemical_shift value="174.887" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CB"/>
+ <chemical_shift value="70.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CA"/>
+ <chemical_shift value="61.464" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="N"/>
+ <chemical_shift value="111.798" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="H"/>
+ <chemical_shift value="8.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="357" name="HG21"/>
+ <atom segid=" A" residue="357" name="HG22"/>
+ <atom segid=" A" residue="357" name="HG23"/>
+ <chemical_shift value="1.045" error="0.0"/>
+ <chemical_shift value="0.991" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="357" name="HG11"/>
+ <atom segid=" A" residue="357" name="HG12"/>
+ <atom segid=" A" residue="357" name="HG13"/>
+ <chemical_shift value="1.045" error="0.0"/>
+ <chemical_shift value="0.991" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="C"/>
+ <chemical_shift value="177.155" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CB"/>
+ <chemical_shift value="31.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CA"/>
+ <chemical_shift value="67.861" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="N"/>
+ <chemical_shift value="121.363" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CG1"/>
+ <chemical_shift value="21.315" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="H"/>
+ <chemical_shift value="8.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CG2"/>
+ <chemical_shift value="23.401" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="C"/>
+ <chemical_shift value="178.907" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CB"/>
+ <chemical_shift value="40.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CA"/>
+ <chemical_shift value="57.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="N"/>
+ <chemical_shift value="115.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="H"/>
+ <chemical_shift value="8.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="C"/>
+ <chemical_shift value="178.618" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CB"/>
+ <chemical_shift value="29.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CA"/>
+ <chemical_shift value="58.759" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="N"/>
+ <chemical_shift value="118.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="H"/>
+ <chemical_shift value="7.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="360" name="HB1"/>
+ <atom segid=" A" residue="360" name="HB2"/>
+ <atom segid=" A" residue="360" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="C"/>
+ <chemical_shift value="181.584" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="CB"/>
+ <chemical_shift value="18.27" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="CA"/>
+ <chemical_shift value="54.768" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="N"/>
+ <chemical_shift value="121.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="H"/>
+ <chemical_shift value="8.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="361" name="HD21"/>
+ <atom segid=" A" residue="361" name="HD22"/>
+ <atom segid=" A" residue="361" name="HD23"/>
+ <chemical_shift value="0.722" error="0.0"/>
+ <chemical_shift value="0.892" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="361" name="HD11"/>
+ <atom segid=" A" residue="361" name="HD12"/>
+ <atom segid=" A" residue="361" name="HD13"/>
+ <chemical_shift value="0.722" error="0.0"/>
+ <chemical_shift value="0.892" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="C"/>
+ <chemical_shift value="178.899" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CB"/>
+ <chemical_shift value="39.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CA"/>
+ <chemical_shift value="57.465" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="N"/>
+ <chemical_shift value="116.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CD1"/>
+ <chemical_shift value="25.264" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CD2"/>
+ <chemical_shift value="19.605" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="H"/>
+ <chemical_shift value="8.078" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="362" name="HZ1"/>
+ <atom segid=" A" residue="362" name="HZ2"/>
+ <atom segid=" A" residue="362" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CB"/>
+ <chemical_shift value="31.531" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="C"/>
+ <chemical_shift value="179.903" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="H"/>
+ <chemical_shift value="7.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CA"/>
+ <chemical_shift value="59.792" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="N"/>
+ <chemical_shift value="121.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="C"/>
+ <chemical_shift value="178.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CB"/>
+ <chemical_shift value="40.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CA"/>
+ <chemical_shift value="57.231" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="N"/>
+ <chemical_shift value="120.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="H"/>
+ <chemical_shift value="8.145" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="364" name="HB1"/>
+ <atom segid=" A" residue="364" name="HB2"/>
+ <atom segid=" A" residue="364" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="C"/>
+ <chemical_shift value="178.422" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="CB"/>
+ <chemical_shift value="17.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="CA"/>
+ <chemical_shift value="55.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="N"/>
+ <chemical_shift value="121.446" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="H"/>
+ <chemical_shift value="7.735" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="C"/>
+ <chemical_shift value="179.207" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CB"/>
+ <chemical_shift value="27.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CA"/>
+ <chemical_shift value="60.224" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="N"/>
+ <chemical_shift value="118.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="H"/>
+ <chemical_shift value="8.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="366" name="HG21"/>
+ <atom segid=" A" residue="366" name="HG22"/>
+ <atom segid=" A" residue="366" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="C"/>
+ <chemical_shift value="175.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CB"/>
+ <chemical_shift value="69.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CA"/>
+ <chemical_shift value="66.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="N"/>
+ <chemical_shift value="115.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="H"/>
+ <chemical_shift value="8.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CB"/>
+ <chemical_shift value="29.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="C"/>
+ <chemical_shift value="178.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="H"/>
+ <chemical_shift value="7.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CA"/>
+ <chemical_shift value="58.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="N"/>
+ <chemical_shift value="120.123" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="368" name="HG21"/>
+ <atom segid=" A" residue="368" name="HG22"/>
+ <atom segid=" A" residue="368" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.693" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="368" name="HD11"/>
+ <atom segid=" A" residue="368" name="HD12"/>
+ <atom segid=" A" residue="368" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.693" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="C"/>
+ <chemical_shift value="177.188" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CB"/>
+ <chemical_shift value="38.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CA"/>
+ <chemical_shift value="65.05" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="N"/>
+ <chemical_shift value="117.397" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CD1"/>
+ <chemical_shift value="15.285" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="H"/>
+ <chemical_shift value="8.005" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="369" name="HG21"/>
+ <atom segid=" A" residue="369" name="HG22"/>
+ <atom segid=" A" residue="369" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="C"/>
+ <chemical_shift value="174.309" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CB"/>
+ <chemical_shift value="70.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CA"/>
+ <chemical_shift value="62.641" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="N"/>
+ <chemical_shift value="107.043" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="H"/>
+ <chemical_shift value="7.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="370" name="HZ1"/>
+ <atom segid=" A" residue="370" name="HZ2"/>
+ <atom segid=" A" residue="370" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="O'"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="O''"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CB"/>
+ <chemical_shift value="32.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="H"/>
+ <chemical_shift value="7.399" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CA"/>
+ <chemical_shift value="59.013" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="N"/>
+ <chemical_shift value="128.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+</chemical_shift_list>
\ No newline at end of file
diff --git a/docs/examples/malecoli/data/xml/n20_peaks.xml b/docs/examples/malecoli/data/xml/n20_peaks.xml
new file mode 100644
index 0000000000000000000000000000000000000000..3d4f1c094b88dc8364f6fab102e0994112a000f0
--- /dev/null
+++ b/docs/examples/malecoli/data/xml/n20_peaks.xml
@@ -0,0 +1,37827 @@
+<!DOCTYPE spectrum SYSTEM "noesy_spectrum1.0.dtd">
+<spectrum name="n20">
+ <peak number="1" reliable="no" ambiguity="">
+ <volume value="2300000.0" error="0"/>
+ <intensity value="2300000.0" error="0"/>
+ <proton1>
+ <shift value="8.982" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.982" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="111.39" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2" reliable="no" ambiguity="">
+ <volume value="12500000.0" error="0"/>
+ <intensity value="12500000.0" error="0"/>
+ <proton1>
+ <shift value="7.582" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.582" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="118.91" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="3" reliable="no" ambiguity="">
+ <volume value="13100000.0" error="0"/>
+ <intensity value="13100000.0" error="0"/>
+ <proton1>
+ <shift value="8.232" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.232" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="116.116" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="4" reliable="no" ambiguity="">
+ <volume value="5300000.0" error="0"/>
+ <intensity value="5300000.0" error="0"/>
+ <proton1>
+ <shift value="10.151" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="10.151" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="125.462" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="5" reliable="no" ambiguity="">
+ <volume value="9450000.0" error="0"/>
+ <intensity value="9450000.0" error="0"/>
+ <proton1>
+ <shift value="9.114" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="9.114" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="128.221" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="6" reliable="no" ambiguity="">
+ <volume value="10900000.0" error="0"/>
+ <intensity value="10900000.0" error="0"/>
+ <proton1>
+ <shift value="9.031" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="9.031" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="126.707" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="7" reliable="no" ambiguity="">
+ <volume value="14500000.0" error="0"/>
+ <intensity value="14500000.0" error="0"/>
+ <proton1>
+ <shift value="8.7" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.7" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="122.118" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="8" reliable="no" ambiguity="">
+ <volume value="2000000.0" error="0"/>
+ <intensity value="2000000.0" error="0"/>
+ <proton1>
+ <shift value="8.921" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.921" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="123.001" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="9" reliable="no" ambiguity="">
+ <volume value="5320000.0" error="0"/>
+ <intensity value="5320000.0" error="0"/>
+ <proton1>
+ <shift value="8.287" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.287" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="106.795" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="10" reliable="no" ambiguity="">
+ <volume value="3030000.0" error="0"/>
+ <intensity value="3030000.0" error="0"/>
+ <proton1>
+ <shift value="7.99" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.99" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="117.021" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="11" reliable="no" ambiguity="">
+ <volume value="2960000.0" error="0"/>
+ <intensity value="2960000.0" error="0"/>
+ <proton1>
+ <shift value="8.739" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.739" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="108.137" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="12" reliable="no" ambiguity="">
+ <volume value="1830000.0" error="0"/>
+ <intensity value="1830000.0" error="0"/>
+ <proton1>
+ <shift value="8.109" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.109" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="123.749" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="13" reliable="no" ambiguity="">
+ <volume value="2490000.0" error="0"/>
+ <intensity value="2490000.0" error="0"/>
+ <proton1>
+ <shift value="9.023" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="9.023" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="111.795" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="14" reliable="no" ambiguity="">
+ <volume value="3830000.0" error="0"/>
+ <intensity value="3830000.0" error="0"/>
+ <proton1>
+ <shift value="8.336" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.336" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="121.847" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="15" reliable="no" ambiguity="">
+ <volume value="4700000.0" error="0"/>
+ <intensity value="4700000.0" error="0"/>
+ <proton1>
+ <shift value="8.143" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.143" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="121.301" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="16" reliable="no" ambiguity="">
+ <volume value="6880000.0" error="0"/>
+ <intensity value="6880000.0" error="0"/>
+ <proton1>
+ <shift value="7.825" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.825" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="120.556" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="17" reliable="no" ambiguity="">
+ <volume value="4190000.0" error="0"/>
+ <intensity value="4190000.0" error="0"/>
+ <proton1>
+ <shift value="7.843" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.843" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="123.324" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="18" reliable="no" ambiguity="">
+ <volume value="2750000.0" error="0"/>
+ <intensity value="2750000.0" error="0"/>
+ <proton1>
+ <shift value="8.722" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.722" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="106.862" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="19" reliable="no" ambiguity="">
+ <volume value="2240000.0" error="0"/>
+ <intensity value="2240000.0" error="0"/>
+ <proton1>
+ <shift value="8.34" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.34" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="122.986" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="20" reliable="no" ambiguity="">
+ <volume value="4990000.0" error="0"/>
+ <intensity value="4990000.0" error="0"/>
+ <proton1>
+ <shift value="7.69" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.69" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="123.049" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="21" reliable="no" ambiguity="">
+ <volume value="4710000.0" error="0"/>
+ <intensity value="4710000.0" error="0"/>
+ <proton1>
+ <shift value="8.127" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.127" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="120.155" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
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+ </hetero1>
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+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
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+ </proton1>
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+ </hetero1>
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+ </hetero2>
+ </peak>
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+ <proton1>
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+ </proton2>
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+ </hetero1>
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+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
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+ </hetero1>
+ <hetero2>
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+ </hetero2>
+ </peak>
+ <peak number="2330" reliable="no" ambiguity="">
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+ </hetero1>
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+ </hetero2>
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+ </hetero1>
+ <hetero2>
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+ </hetero2>
+ </peak>
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+ </proton2>
+ <hetero1>
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+ </hetero1>
+ <hetero2>
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+ </hetero2>
+ </peak>
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+ </proton2>
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+ </hetero1>
+ <hetero2>
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+ </hetero2>
+ </peak>
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+ <proton1>
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+ </hetero1>
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+ </hetero2>
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+ </hetero1>
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+ </hetero2>
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+ </proton2>
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+ </hetero1>
+ <hetero2>
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+ </hetero2>
+ </peak>
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+ <intensity value="748000.0" error="0"/>
+ <proton1>
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+ </proton1>
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+ </hetero1>
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+ </hetero2>
+ </peak>
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+ <intensity value="301000.0" error="0"/>
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+ </proton1>
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+ </proton2>
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+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
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+ <proton1>
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+ </proton1>
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+ </proton2>
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+ </hetero1>
+ <hetero2>
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+ </hetero2>
+ </peak>
+ <peak number="2347" reliable="no" ambiguity="">
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+ <intensity value="492000.0" error="0"/>
+ <proton1>
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+ </proton1>
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+ </proton2>
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+ </hetero1>
+ <hetero2>
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+ </hetero2>
+ </peak>
+ <peak number="2348" reliable="no" ambiguity="">
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+ <proton1>
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+ </proton1>
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+ </proton2>
+ <hetero1>
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+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
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+ <proton1>
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+ </proton1>
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+ <hetero1>
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+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2350" reliable="no" ambiguity="">
+ <volume value="2120000.0" error="0"/>
+ <intensity value="2120000.0" error="0"/>
+ <proton1>
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+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
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+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2351" reliable="no" ambiguity="">
+ <volume value="1290000.0" error="0"/>
+ <intensity value="1290000.0" error="0"/>
+ <proton1>
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+ </proton1>
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+ </proton2>
+ <hetero1>
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+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2352" reliable="no" ambiguity="">
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+ <intensity value="1220000.0" error="0"/>
+ <proton1>
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+ </proton1>
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+ </proton2>
+ <hetero1>
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+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2353" reliable="no" ambiguity="">
+ <volume value="1130000.0" error="0"/>
+ <intensity value="1130000.0" error="0"/>
+ <proton1>
+ <shift value="7.743" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.322" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="120.837" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2354" reliable="no" ambiguity="">
+ <volume value="2430000.0" error="0"/>
+ <intensity value="2430000.0" error="0"/>
+ <proton1>
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+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
+ <shift value="119.638" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2355" reliable="no" ambiguity="">
+ <volume value="349000.0" error="0"/>
+ <intensity value="349000.0" error="0"/>
+ <proton1>
+ <shift value="6.988" error=""/>
+ </proton1>
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+ <hetero1>
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+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2356" reliable="no" ambiguity="">
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+ <intensity value="279000.0" error="0"/>
+ <proton1>
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+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
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+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2357" reliable="no" ambiguity="">
+ <volume value="239000.0" error="0"/>
+ <intensity value="239000.0" error="0"/>
+ <proton1>
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+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
+ <shift value="134.974" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2358" reliable="no" ambiguity="">
+ <volume value="9390000.0" error="0"/>
+ <intensity value="9390000.0" error="0"/>
+ <proton1>
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+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
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+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2359" reliable="no" ambiguity="">
+ <volume value="292000.0" error="0"/>
+ <intensity value="292000.0" error="0"/>
+ <proton1>
+ <shift value="10.571" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="9.038" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="129.101" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2360" reliable="no" ambiguity="">
+ <volume value="138000.0" error="0"/>
+ <intensity value="138000.0" error="0"/>
+ <proton1>
+ <shift value="10.576" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="6.607" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="128.968" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2361" reliable="no" ambiguity="">
+ <volume value="2340000.0" error="0"/>
+ <intensity value="2340000.0" error="0"/>
+ <proton1>
+ <shift value="10.614" error=""/>
+ </proton1>
+ <proton2>
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+ </proton2>
+ <hetero1>
+ <shift value="129.374" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2362" reliable="no" ambiguity="">
+ <volume value="172000.0" error="0"/>
+ <intensity value="172000.0" error="0"/>
+ <proton1>
+ <shift value="10.613" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="8.695" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="129.311" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2363" reliable="no" ambiguity="">
+ <volume value="210000.0" error="0"/>
+ <intensity value="210000.0" error="0"/>
+ <proton1>
+ <shift value="10.611" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="7.647" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="129.374" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2364" reliable="no" ambiguity="">
+ <volume value="1630000.0" error="0"/>
+ <intensity value="1630000.0" error="0"/>
+ <proton1>
+ <shift value="8.501" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="13.183" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="124.437" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="" error=""/>
+ </hetero2>
+ </peak>
+</spectrum>
\ No newline at end of file
diff --git a/docs/examples/malecoli/data/xml/nc0_cs.xml b/docs/examples/malecoli/data/xml/nc0_cs.xml
new file mode 100644
index 0000000000000000000000000000000000000000..bcb3d46b809ec3f250726022e42af6cd1ed9b115
--- /dev/null
+++ b/docs/examples/malecoli/data/xml/nc0_cs.xml
@@ -0,0 +1,31373 @@
+<!DOCTYPE chemical_shift_list SYSTEM "chemical_shift_list1.0.dtd">
+<chemical_shift_list>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="1" name="HZ1"/>
+ <atom segid=" A" residue="1" name="HZ2"/>
+ <atom segid=" A" residue="1" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="1" name="H1"/>
+ <atom segid=" A" residue="1" name="H2"/>
+ <atom segid=" A" residue="1" name="H3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="C"/>
+ <chemical_shift value="176.453" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CB"/>
+ <chemical_shift value="32.88" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CA"/>
+ <chemical_shift value="56.408" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="2" name="HG21"/>
+ <atom segid=" A" residue="2" name="HG22"/>
+ <atom segid=" A" residue="2" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.402" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="2" name="HD11"/>
+ <atom segid=" A" residue="2" name="HD12"/>
+ <atom segid=" A" residue="2" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.402" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="C"/>
+ <chemical_shift value="176.016" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CB"/>
+ <chemical_shift value="38.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CA"/>
+ <chemical_shift value="62.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="N"/>
+ <chemical_shift value="123.415" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CD1"/>
+ <chemical_shift value="13.054" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="H"/>
+ <chemical_shift value="7.988" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="C"/>
+ <chemical_shift value="176.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CB"/>
+ <chemical_shift value="31.187" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CA"/>
+ <chemical_shift value="56.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="N"/>
+ <chemical_shift value="126.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="H"/>
+ <chemical_shift value="8.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="C"/>
+ <chemical_shift value="177.433" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CB"/>
+ <chemical_shift value="30.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CA"/>
+ <chemical_shift value="56.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="N"/>
+ <chemical_shift value="124.204" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="H"/>
+ <chemical_shift value="8.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="C"/>
+ <chemical_shift value="172.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="H"/>
+ <chemical_shift value="8.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="CA"/>
+ <chemical_shift value="45.937" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="N"/>
+ <chemical_shift value="111.348" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="6" name="HZ1"/>
+ <atom segid=" A" residue="6" name="HZ2"/>
+ <atom segid=" A" residue="6" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CB"/>
+ <chemical_shift value="35.109" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="C"/>
+ <chemical_shift value="173.108" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="H"/>
+ <chemical_shift value="7.582" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CA"/>
+ <chemical_shift value="54.965" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="N"/>
+ <chemical_shift value="118.91" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="7" name="HD21"/>
+ <atom segid=" A" residue="7" name="HD22"/>
+ <atom segid=" A" residue="7" name="HD23"/>
+ <chemical_shift value="0.615" error="0.0"/>
+ <chemical_shift value="0.267" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="7" name="HD11"/>
+ <atom segid=" A" residue="7" name="HD12"/>
+ <atom segid=" A" residue="7" name="HD13"/>
+ <chemical_shift value="0.615" error="0.0"/>
+ <chemical_shift value="0.267" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="C"/>
+ <chemical_shift value="175.788" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CB"/>
+ <chemical_shift value="46.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CA"/>
+ <chemical_shift value="53.365" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="N"/>
+ <chemical_shift value="116.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CD1"/>
+ <chemical_shift value="25.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CD2"/>
+ <chemical_shift value="24.064" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="H"/>
+ <chemical_shift value="8.231" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="8" name="HG21"/>
+ <atom segid=" A" residue="8" name="HG22"/>
+ <atom segid=" A" residue="8" name="HG23"/>
+ <chemical_shift value="0.923" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="8" name="HG11"/>
+ <atom segid=" A" residue="8" name="HG12"/>
+ <atom segid=" A" residue="8" name="HG13"/>
+ <chemical_shift value="0.923" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="C"/>
+ <chemical_shift value="176.033" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CB"/>
+ <chemical_shift value="33.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CA"/>
+ <chemical_shift value="61.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="N"/>
+ <chemical_shift value="125.474" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CG1"/>
+ <chemical_shift value="20.962" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="H"/>
+ <chemical_shift value="10.155" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CG2"/>
+ <chemical_shift value="21.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="9" name="HG21"/>
+ <atom segid=" A" residue="9" name="HG22"/>
+ <atom segid=" A" residue="9" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.346" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="9" name="HD11"/>
+ <atom segid=" A" residue="9" name="HD12"/>
+ <atom segid=" A" residue="9" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.346" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="C"/>
+ <chemical_shift value="174.901" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CB"/>
+ <chemical_shift value="40.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CA"/>
+ <chemical_shift value="59.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="N"/>
+ <chemical_shift value="128.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CD1"/>
+ <chemical_shift value="14.523" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="H"/>
+ <chemical_shift value="9.114" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="H"/>
+ <chemical_shift value="9.032" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="C"/>
+ <chemical_shift value="174.116" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CB"/>
+ <chemical_shift value="32.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CA"/>
+ <chemical_shift value="54.451" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="N"/>
+ <chemical_shift value="126.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="11" name="HG21"/>
+ <atom segid=" A" residue="11" name="HG22"/>
+ <atom segid=" A" residue="11" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.107" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="11" name="HD11"/>
+ <atom segid=" A" residue="11" name="HD12"/>
+ <atom segid=" A" residue="11" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.107" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="C"/>
+ <chemical_shift value="171.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CB"/>
+ <chemical_shift value="41.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CA"/>
+ <chemical_shift value="59.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="N"/>
+ <chemical_shift value="122.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CD1"/>
+ <chemical_shift value="13.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="H"/>
+ <chemical_shift value="8.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="C"/>
+ <chemical_shift value="177.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CB"/>
+ <chemical_shift value="39.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CA"/>
+ <chemical_shift value="54.628" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="N"/>
+ <chemical_shift value="122.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="H"/>
+ <chemical_shift value="8.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="C"/>
+ <chemical_shift value="173.365" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="H"/>
+ <chemical_shift value="8.288" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="CA"/>
+ <chemical_shift value="46.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="N"/>
+ <chemical_shift value="106.789" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="C"/>
+ <chemical_shift value="176.544" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CB"/>
+ <chemical_shift value="39.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CA"/>
+ <chemical_shift value="53.217" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="N"/>
+ <chemical_shift value="117.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="H"/>
+ <chemical_shift value="7.99" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="15" name="HZ1"/>
+ <atom segid=" A" residue="15" name="HZ2"/>
+ <atom segid=" A" residue="15" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CB"/>
+ <chemical_shift value="32.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="C"/>
+ <chemical_shift value="177.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="H"/>
+ <chemical_shift value="7.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CA"/>
+ <chemical_shift value="53.23" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="N"/>
+ <chemical_shift value="118.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="C"/>
+ <chemical_shift value="175.872" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="H"/>
+ <chemical_shift value="8.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="CA"/>
+ <chemical_shift value="48.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="N"/>
+ <chemical_shift value="108.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="17" name="HD1"/>
+ <atom segid=" A" residue="17" name="HD2"/>
+ <atom segid=" A" residue="17" name="HE1"/>
+ <atom segid=" A" residue="17" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="C"/>
+ <chemical_shift value="177.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CB"/>
+ <chemical_shift value="37.646" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CA"/>
+ <chemical_shift value="59.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="N"/>
+ <chemical_shift value="120.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="H"/>
+ <chemical_shift value="8.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="C"/>
+ <chemical_shift value="179.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CB"/>
+ <chemical_shift value="37.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CA"/>
+ <chemical_shift value="56.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="N"/>
+ <chemical_shift value="123.761" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="H"/>
+ <chemical_shift value="8.109" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="C"/>
+ <chemical_shift value="176.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="H"/>
+ <chemical_shift value="9.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="CA"/>
+ <chemical_shift value="47.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="N"/>
+ <chemical_shift value="111.77" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="20" name="HD21"/>
+ <atom segid=" A" residue="20" name="HD22"/>
+ <atom segid=" A" residue="20" name="HD23"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="20" name="HD11"/>
+ <atom segid=" A" residue="20" name="HD12"/>
+ <atom segid=" A" residue="20" name="HD13"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="C"/>
+ <chemical_shift value="178.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CB"/>
+ <chemical_shift value="41.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CA"/>
+ <chemical_shift value="57.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="N"/>
+ <chemical_shift value="121.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CD1"/>
+ <chemical_shift value="24.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CD2"/>
+ <chemical_shift value="26.879" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="21" name="HB1"/>
+ <atom segid=" A" residue="21" name="HB2"/>
+ <atom segid=" A" residue="21" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="C"/>
+ <chemical_shift value="180.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="CB"/>
+ <chemical_shift value="17.478" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="CA"/>
+ <chemical_shift value="55.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="N"/>
+ <chemical_shift value="121.303" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="H"/>
+ <chemical_shift value="8.143" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="C"/>
+ <chemical_shift value="180.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CB"/>
+ <chemical_shift value="28.487" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CA"/>
+ <chemical_shift value="59.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="N"/>
+ <chemical_shift value="120.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="H"/>
+ <chemical_shift value="7.825" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="23" name="HG21"/>
+ <atom segid=" A" residue="23" name="HG22"/>
+ <atom segid=" A" residue="23" name="HG23"/>
+ <chemical_shift value="1.252" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="23" name="HG11"/>
+ <atom segid=" A" residue="23" name="HG12"/>
+ <atom segid=" A" residue="23" name="HG13"/>
+ <chemical_shift value="1.252" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="C"/>
+ <chemical_shift value="179.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CB"/>
+ <chemical_shift value="31.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CA"/>
+ <chemical_shift value="66.874" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="N"/>
+ <chemical_shift value="123.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CG1"/>
+ <chemical_shift value="22.314" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="H"/>
+ <chemical_shift value="7.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CG2"/>
+ <chemical_shift value="23.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="C"/>
+ <chemical_shift value="175.393" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="H"/>
+ <chemical_shift value="8.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="CA"/>
+ <chemical_shift value="47.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="N"/>
+ <chemical_shift value="106.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="25" name="HZ1"/>
+ <atom segid=" A" residue="25" name="HZ2"/>
+ <atom segid=" A" residue="25" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CB"/>
+ <chemical_shift value="31.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="C"/>
+ <chemical_shift value="179.664" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="H"/>
+ <chemical_shift value="8.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CA"/>
+ <chemical_shift value="59.448" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="N"/>
+ <chemical_shift value="123.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="26" name="HZ1"/>
+ <atom segid=" A" residue="26" name="HZ2"/>
+ <atom segid=" A" residue="26" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CB"/>
+ <chemical_shift value="31.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="C"/>
+ <chemical_shift value="178.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="H"/>
+ <chemical_shift value="7.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CA"/>
+ <chemical_shift value="59.777" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="N"/>
+ <chemical_shift value="123.048" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="27" name="HD1"/>
+ <atom segid=" A" residue="27" name="HD2"/>
+ <atom segid=" A" residue="27" name="HE1"/>
+ <atom segid=" A" residue="27" name="HE2"/>
+ <atom segid=" A" residue="27" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="C"/>
+ <chemical_shift value="179.166" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CB"/>
+ <chemical_shift value="39.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CA"/>
+ <chemical_shift value="61.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="N"/>
+ <chemical_shift value="120.111" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="H"/>
+ <chemical_shift value="8.131" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="C"/>
+ <chemical_shift value="180.031" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CB"/>
+ <chemical_shift value="29.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CA"/>
+ <chemical_shift value="59.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="N"/>
+ <chemical_shift value="124.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="H"/>
+ <chemical_shift value="8.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="29" name="HZ1"/>
+ <atom segid=" A" residue="29" name="HZ2"/>
+ <atom segid=" A" residue="29" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CB"/>
+ <chemical_shift value="31.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="H"/>
+ <chemical_shift value="8.151" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CA"/>
+ <chemical_shift value="59.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="N"/>
+ <chemical_shift value="122.162" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="C"/>
+ <chemical_shift value="178.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CB"/>
+ <chemical_shift value="41.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CA"/>
+ <chemical_shift value="56.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="N"/>
+ <chemical_shift value="116.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="H"/>
+ <chemical_shift value="7.615" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="31" name="HG21"/>
+ <atom segid=" A" residue="31" name="HG22"/>
+ <atom segid=" A" residue="31" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="C"/>
+ <chemical_shift value="176.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CB"/>
+ <chemical_shift value="72.293" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CA"/>
+ <chemical_shift value="62.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="N"/>
+ <chemical_shift value="107.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="H"/>
+ <chemical_shift value="7.929" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="C"/>
+ <chemical_shift value="173.645" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="H"/>
+ <chemical_shift value="8.6" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="CA"/>
+ <chemical_shift value="45.563" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="N"/>
+ <chemical_shift value="112.884" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="33" name="HG21"/>
+ <atom segid=" A" residue="33" name="HG22"/>
+ <atom segid=" A" residue="33" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.574" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="33" name="HD11"/>
+ <atom segid=" A" residue="33" name="HD12"/>
+ <atom segid=" A" residue="33" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.574" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="C"/>
+ <chemical_shift value="173.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CB"/>
+ <chemical_shift value="35.66" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CA"/>
+ <chemical_shift value="59.048" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="N"/>
+ <chemical_shift value="124.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CD1"/>
+ <chemical_shift value="10.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="H"/>
+ <chemical_shift value="7.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="34" name="HZ1"/>
+ <atom segid=" A" residue="34" name="HZ2"/>
+ <atom segid=" A" residue="34" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CB"/>
+ <chemical_shift value="32.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="C"/>
+ <chemical_shift value="175.675" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="H"/>
+ <chemical_shift value="7.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CA"/>
+ <chemical_shift value="56.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="N"/>
+ <chemical_shift value="125.011" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="35" name="HG21"/>
+ <atom segid=" A" residue="35" name="HG22"/>
+ <atom segid=" A" residue="35" name="HG23"/>
+ <chemical_shift value="0.776" error="0.0"/>
+ <chemical_shift value="0.331" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="35" name="HG11"/>
+ <atom segid=" A" residue="35" name="HG12"/>
+ <atom segid=" A" residue="35" name="HG13"/>
+ <chemical_shift value="0.776" error="0.0"/>
+ <chemical_shift value="0.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="C"/>
+ <chemical_shift value="175.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CB"/>
+ <chemical_shift value="33.372" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CA"/>
+ <chemical_shift value="61.064" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="N"/>
+ <chemical_shift value="124.42" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CG1"/>
+ <chemical_shift value="20.685" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="H"/>
+ <chemical_shift value="8.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CG2"/>
+ <chemical_shift value="22.478" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="36" name="HG21"/>
+ <atom segid=" A" residue="36" name="HG22"/>
+ <atom segid=" A" residue="36" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="C"/>
+ <chemical_shift value="172.762" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CB"/>
+ <chemical_shift value="70.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CA"/>
+ <chemical_shift value="61.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="N"/>
+ <chemical_shift value="125.312" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="H"/>
+ <chemical_shift value="9.176" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="37" name="HG21"/>
+ <atom segid=" A" residue="37" name="HG22"/>
+ <atom segid=" A" residue="37" name="HG23"/>
+ <chemical_shift value="0.766" error="0.0"/>
+ <chemical_shift value="0.951" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="37" name="HG11"/>
+ <atom segid=" A" residue="37" name="HG12"/>
+ <atom segid=" A" residue="37" name="HG13"/>
+ <chemical_shift value="0.766" error="0.0"/>
+ <chemical_shift value="0.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="C"/>
+ <chemical_shift value="175.348" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CB"/>
+ <chemical_shift value="32.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CA"/>
+ <chemical_shift value="61.689" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="N"/>
+ <chemical_shift value="127.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CG1"/>
+ <chemical_shift value="22.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="H"/>
+ <chemical_shift value="8.921" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CG2"/>
+ <chemical_shift value="20.673" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="C"/>
+ <chemical_shift value="173.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CB"/>
+ <chemical_shift value="33.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CA"/>
+ <chemical_shift value="54.475" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="N"/>
+ <chemical_shift value="127.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="H"/>
+ <chemical_shift value="9.644" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CB"/>
+ <chemical_shift value="28.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CA"/>
+ <chemical_shift value="51.527" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="N"/>
+ <chemical_shift value="115.306" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="H"/>
+ <chemical_shift value="8.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="C"/>
+ <chemical_shift value="176.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CB"/>
+ <chemical_shift value="30.665" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CA"/>
+ <chemical_shift value="62.226" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="C"/>
+ <chemical_shift value="176.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CB"/>
+ <chemical_shift value="41.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CA"/>
+ <chemical_shift value="54.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="N"/>
+ <chemical_shift value="121.165" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="H"/>
+ <chemical_shift value="8.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="42" name="HZ1"/>
+ <atom segid=" A" residue="42" name="HZ2"/>
+ <atom segid=" A" residue="42" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CB"/>
+ <chemical_shift value="29.442" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="C"/>
+ <chemical_shift value="178.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="H"/>
+ <chemical_shift value="8.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CA"/>
+ <chemical_shift value="56.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="N"/>
+ <chemical_shift value="119.242" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="43" name="HD21"/>
+ <atom segid=" A" residue="43" name="HD22"/>
+ <atom segid=" A" residue="43" name="HD23"/>
+ <chemical_shift value="1.133" error="0.0"/>
+ <chemical_shift value="1.101" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="43" name="HD11"/>
+ <atom segid=" A" residue="43" name="HD12"/>
+ <atom segid=" A" residue="43" name="HD13"/>
+ <chemical_shift value="1.133" error="0.0"/>
+ <chemical_shift value="1.101" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="C"/>
+ <chemical_shift value="175.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CB"/>
+ <chemical_shift value="40.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CA"/>
+ <chemical_shift value="59.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="N"/>
+ <chemical_shift value="120.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CD1"/>
+ <chemical_shift value="26.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CD2"/>
+ <chemical_shift value="26.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="H"/>
+ <chemical_shift value="7.387" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="C"/>
+ <chemical_shift value="178.284" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CB"/>
+ <chemical_shift value="24.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CA"/>
+ <chemical_shift value="57.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="N"/>
+ <chemical_shift value="123.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="H"/>
+ <chemical_shift value="10.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="C"/>
+ <chemical_shift value="178.462" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CB"/>
+ <chemical_shift value="29.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CA"/>
+ <chemical_shift value="56.456" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="N"/>
+ <chemical_shift value="120.295" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="H"/>
+ <chemical_shift value="7.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="46" name="HZ1"/>
+ <atom segid=" A" residue="46" name="HZ2"/>
+ <atom segid=" A" residue="46" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CB"/>
+ <chemical_shift value="33.277" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="C"/>
+ <chemical_shift value="179.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="H"/>
+ <chemical_shift value="8.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CA"/>
+ <chemical_shift value="58.611" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="N"/>
+ <chemical_shift value="120.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="47" name="HD1"/>
+ <atom segid=" A" residue="47" name="HD2"/>
+ <atom segid=" A" residue="47" name="HE1"/>
+ <atom segid=" A" residue="47" name="HE2"/>
+ <atom segid=" A" residue="47" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CB"/>
+ <chemical_shift value="36.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CA"/>
+ <chemical_shift value="63.747" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="N"/>
+ <chemical_shift value="116.928" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="H"/>
+ <chemical_shift value="8.655" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="C"/>
+ <chemical_shift value="178.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CB"/>
+ <chemical_shift value="30.015" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CA"/>
+ <chemical_shift value="65.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="C"/>
+ <chemical_shift value="178.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CB"/>
+ <chemical_shift value="28.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CA"/>
+ <chemical_shift value="58.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="N"/>
+ <chemical_shift value="115.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="H"/>
+ <chemical_shift value="6.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="50" name="HG21"/>
+ <atom segid=" A" residue="50" name="HG22"/>
+ <atom segid=" A" residue="50" name="HG23"/>
+ <chemical_shift value="0.906" error="0.0"/>
+ <chemical_shift value="0.967" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="50" name="HG11"/>
+ <atom segid=" A" residue="50" name="HG12"/>
+ <atom segid=" A" residue="50" name="HG13"/>
+ <chemical_shift value="0.906" error="0.0"/>
+ <chemical_shift value="0.967" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="C"/>
+ <chemical_shift value="178.512" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CB"/>
+ <chemical_shift value="32.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CA"/>
+ <chemical_shift value="62.603" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="N"/>
+ <chemical_shift value="111.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CG1"/>
+ <chemical_shift value="21.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="H"/>
+ <chemical_shift value="7.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CG2"/>
+ <chemical_shift value="19.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="51" name="HB1"/>
+ <atom segid=" A" residue="51" name="HB2"/>
+ <atom segid=" A" residue="51" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="C"/>
+ <chemical_shift value="180.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="CB"/>
+ <chemical_shift value="17.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="CA"/>
+ <chemical_shift value="54.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="N"/>
+ <chemical_shift value="125.692" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="H"/>
+ <chemical_shift value="8.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="52" name="HB1"/>
+ <atom segid=" A" residue="52" name="HB2"/>
+ <atom segid=" A" residue="52" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="C"/>
+ <chemical_shift value="178.618" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="CB"/>
+ <chemical_shift value="18.146" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="CA"/>
+ <chemical_shift value="53.841" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="N"/>
+ <chemical_shift value="118.243" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="H"/>
+ <chemical_shift value="7.396" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="53" name="HG21"/>
+ <atom segid=" A" residue="53" name="HG22"/>
+ <atom segid=" A" residue="53" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="C"/>
+ <chemical_shift value="175.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CB"/>
+ <chemical_shift value="69.75" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CA"/>
+ <chemical_shift value="61.307" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="N"/>
+ <chemical_shift value="106.045" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="H"/>
+ <chemical_shift value="7.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="C"/>
+ <chemical_shift value="172.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="H"/>
+ <chemical_shift value="7.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="CA"/>
+ <chemical_shift value="45.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="N"/>
+ <chemical_shift value="109.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="C"/>
+ <chemical_shift value="174.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CB"/>
+ <chemical_shift value="43.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CA"/>
+ <chemical_shift value="52.778" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="N"/>
+ <chemical_shift value="119.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="H"/>
+ <chemical_shift value="7.395" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="H"/>
+ <chemical_shift value="8.332" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="CA"/>
+ <chemical_shift value="43.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="N"/>
+ <chemical_shift value="105.496" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="C"/>
+ <chemical_shift value="175.448" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CB"/>
+ <chemical_shift value="30.658" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CA"/>
+ <chemical_shift value="61.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="C"/>
+ <chemical_shift value="176.037" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CB"/>
+ <chemical_shift value="43.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CA"/>
+ <chemical_shift value="58.668" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="N"/>
+ <chemical_shift value="117.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="H"/>
+ <chemical_shift value="8.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="59" name="HG21"/>
+ <atom segid=" A" residue="59" name="HG22"/>
+ <atom segid=" A" residue="59" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.735" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="59" name="HD11"/>
+ <atom segid=" A" residue="59" name="HD12"/>
+ <atom segid=" A" residue="59" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.735" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="C"/>
+ <chemical_shift value="173.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CB"/>
+ <chemical_shift value="42.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CA"/>
+ <chemical_shift value="58.982" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="N"/>
+ <chemical_shift value="114.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CD1"/>
+ <chemical_shift value="13.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="H"/>
+ <chemical_shift value="7.631" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="60" name="HG21"/>
+ <atom segid=" A" residue="60" name="HG22"/>
+ <atom segid=" A" residue="60" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.452" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="60" name="HD11"/>
+ <atom segid=" A" residue="60" name="HD12"/>
+ <atom segid=" A" residue="60" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="C"/>
+ <chemical_shift value="172.929" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CB"/>
+ <chemical_shift value="41.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CA"/>
+ <chemical_shift value="58.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="N"/>
+ <chemical_shift value="124.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CD1"/>
+ <chemical_shift value="14.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="H"/>
+ <chemical_shift value="8.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="61" name="HD1"/>
+ <atom segid=" A" residue="61" name="HD2"/>
+ <atom segid=" A" residue="61" name="HE1"/>
+ <atom segid=" A" residue="61" name="HE2"/>
+ <atom segid=" A" residue="61" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="C"/>
+ <chemical_shift value="176.742" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CB"/>
+ <chemical_shift value="41.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CA"/>
+ <chemical_shift value="55.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="N"/>
+ <chemical_shift value="126.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="H"/>
+ <chemical_shift value="8.603" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="H"/>
+ <chemical_shift value="9.181" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="C"/>
+ <chemical_shift value="173.771" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CB"/>
+ <chemical_shift value="31.813" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CA"/>
+ <chemical_shift value="57.786" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="N"/>
+ <chemical_shift value="121.356" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="63" name="HB1"/>
+ <atom segid=" A" residue="63" name="HB2"/>
+ <atom segid=" A" residue="63" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="C"/>
+ <chemical_shift value="179.957" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="CB"/>
+ <chemical_shift value="18.639" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="CA"/>
+ <chemical_shift value="54.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="N"/>
+ <chemical_shift value="125.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="H"/>
+ <chemical_shift value="6.296" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="C"/>
+ <chemical_shift value="178.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CB"/>
+ <chemical_shift value="30.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CA"/>
+ <chemical_shift value="60.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="N"/>
+ <chemical_shift value="115.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="H"/>
+ <chemical_shift value="8.028" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="C"/>
+ <chemical_shift value="177.968" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CB"/>
+ <chemical_shift value="39.5" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CA"/>
+ <chemical_shift value="57.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="N"/>
+ <chemical_shift value="119.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="H"/>
+ <chemical_shift value="7.721" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CB"/>
+ <chemical_shift value="29.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="C"/>
+ <chemical_shift value="177.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="H"/>
+ <chemical_shift value="6.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CA"/>
+ <chemical_shift value="55.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="N"/>
+ <chemical_shift value="116.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="67" name="HD1"/>
+ <atom segid=" A" residue="67" name="HD2"/>
+ <atom segid=" A" residue="67" name="HE1"/>
+ <atom segid=" A" residue="67" name="HE2"/>
+ <atom segid=" A" residue="67" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="C"/>
+ <chemical_shift value="177.883" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CB"/>
+ <chemical_shift value="36.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CA"/>
+ <chemical_shift value="58.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="N"/>
+ <chemical_shift value="116.954" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="H"/>
+ <chemical_shift value="7.688" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="C"/>
+ <chemical_shift value="175.81" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="H"/>
+ <chemical_shift value="7.272" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="CA"/>
+ <chemical_shift value="47.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="N"/>
+ <chemical_shift value="107.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="C"/>
+ <chemical_shift value="177.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="H"/>
+ <chemical_shift value="7.651" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="CA"/>
+ <chemical_shift value="47.089" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="N"/>
+ <chemical_shift value="107.532" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="70" name="HD1"/>
+ <atom segid=" A" residue="70" name="HD2"/>
+ <atom segid=" A" residue="70" name="HE1"/>
+ <atom segid=" A" residue="70" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="C"/>
+ <chemical_shift value="178.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CB"/>
+ <chemical_shift value="35.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CA"/>
+ <chemical_shift value="57.372" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="N"/>
+ <chemical_shift value="119.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="H"/>
+ <chemical_shift value="6.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="71" name="HB1"/>
+ <atom segid=" A" residue="71" name="HB2"/>
+ <atom segid=" A" residue="71" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="C"/>
+ <chemical_shift value="182.277" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="CB"/>
+ <chemical_shift value="18.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="CA"/>
+ <chemical_shift value="54.487" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="N"/>
+ <chemical_shift value="122.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="H"/>
+ <chemical_shift value="8.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="C"/>
+ <chemical_shift value="177.85" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CB"/>
+ <chemical_shift value="27.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CA"/>
+ <chemical_shift value="58.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="N"/>
+ <chemical_shift value="122.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="H"/>
+ <chemical_shift value="8.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="C"/>
+ <chemical_shift value="173.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="CB"/>
+ <chemical_shift value="64.148" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="CA"/>
+ <chemical_shift value="59.274" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="N"/>
+ <chemical_shift value="112.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="H"/>
+ <chemical_shift value="7.362" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="C"/>
+ <chemical_shift value="176.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="H"/>
+ <chemical_shift value="8.083" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="CA"/>
+ <chemical_shift value="46.341" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="N"/>
+ <chemical_shift value="109.4" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="75" name="HD22"/>
+ <atom segid=" A" residue="75" name="HD23"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="75" name="HD11"/>
+ <atom segid=" A" residue="75" name="HD12"/>
+ <atom segid=" A" residue="75" name="HD13"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="42.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CA"/>
+ <chemical_shift value="55.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="N"/>
+ <chemical_shift value="113.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="20.664" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="H"/>
+ <chemical_shift value="7.815" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="76" name="HD22"/>
+ <atom segid=" A" residue="76" name="HD23"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.897" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="76" name="HD11"/>
+ <atom segid=" A" residue="76" name="HD12"/>
+ <atom segid=" A" residue="76" name="HD13"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="43.798" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CA"/>
+ <chemical_shift value="52.794" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="N"/>
+ <chemical_shift value="115.902" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CD1"/>
+ <chemical_shift value="27.43" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="21.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="H"/>
+ <chemical_shift value="7.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
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+ <atom segid=" A" residue="77" name="HB2"/>
+ <atom segid=" A" residue="77" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="176.398" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="19.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="CA"/>
+ <chemical_shift value="51.102" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="N"/>
+ <chemical_shift value="125.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="9.007" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="176.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CB"/>
+ <chemical_shift value="29.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CA"/>
+ <chemical_shift value="56.426" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="N"/>
+ <chemical_shift value="120.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="H"/>
+ <chemical_shift value="8.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
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+ <atom segid=" A" residue="79" name="HG22"/>
+ <atom segid=" A" residue="79" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.161" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="79" name="HD11"/>
+ <atom segid=" A" residue="79" name="HD12"/>
+ <atom segid=" A" residue="79" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.161" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="C"/>
+ <chemical_shift value="175.746" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CB"/>
+ <chemical_shift value="38.941" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CA"/>
+ <chemical_shift value="59.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="N"/>
+ <chemical_shift value="122.859" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CD1"/>
+ <chemical_shift value="12.313" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="H"/>
+ <chemical_shift value="8.176" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="80" name="HG21"/>
+ <atom segid=" A" residue="80" name="HG22"/>
+ <atom segid=" A" residue="80" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CB"/>
+ <chemical_shift value="69.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CA"/>
+ <chemical_shift value="57.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="N"/>
+ <chemical_shift value="112.766" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="H"/>
+ <chemical_shift value="8.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="C"/>
+ <chemical_shift value="177.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CB"/>
+ <chemical_shift value="31.586" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CA"/>
+ <chemical_shift value="62.548" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CB"/>
+ <chemical_shift value="41.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CA"/>
+ <chemical_shift value="53.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="N"/>
+ <chemical_shift value="123.843" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="H"/>
+ <chemical_shift value="9.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="83" name="HZ1"/>
+ <atom segid=" A" residue="83" name="HZ2"/>
+ <atom segid=" A" residue="83" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CB"/>
+ <chemical_shift value="31.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="C"/>
+ <chemical_shift value="177.708" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CA"/>
+ <chemical_shift value="59.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="84" name="HB1"/>
+ <atom segid=" A" residue="84" name="HB2"/>
+ <atom segid=" A" residue="84" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="C"/>
+ <chemical_shift value="180.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="CB"/>
+ <chemical_shift value="17.553" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="CA"/>
+ <chemical_shift value="54.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="N"/>
+ <chemical_shift value="119.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="H"/>
+ <chemical_shift value="8.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="85" name="HD1"/>
+ <atom segid=" A" residue="85" name="HD2"/>
+ <atom segid=" A" residue="85" name="HE1"/>
+ <atom segid=" A" residue="85" name="HE2"/>
+ <atom segid=" A" residue="85" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="C"/>
+ <chemical_shift value="178.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CB"/>
+ <chemical_shift value="39.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CA"/>
+ <chemical_shift value="62.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="N"/>
+ <chemical_shift value="118.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="H"/>
+ <chemical_shift value="7.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="C"/>
+ <chemical_shift value="180.14" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CB"/>
+ <chemical_shift value="28.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CA"/>
+ <chemical_shift value="59.616" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="N"/>
+ <chemical_shift value="117.272" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="H"/>
+ <chemical_shift value="8.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="C"/>
+ <chemical_shift value="176.576" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CB"/>
+ <chemical_shift value="40.956" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CA"/>
+ <chemical_shift value="56.177" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="N"/>
+ <chemical_shift value="116.913" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="H"/>
+ <chemical_shift value="8.053" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="88" name="HZ1"/>
+ <atom segid=" A" residue="88" name="HZ2"/>
+ <atom segid=" A" residue="88" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CB"/>
+ <chemical_shift value="31.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="C"/>
+ <chemical_shift value="176.797" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="H"/>
+ <chemical_shift value="7.816" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CA"/>
+ <chemical_shift value="58.402" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="N"/>
+ <chemical_shift value="117.299" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="89" name="HD21"/>
+ <atom segid=" A" residue="89" name="HD22"/>
+ <atom segid=" A" residue="89" name="HD23"/>
+ <chemical_shift value="0.484" error="0.0"/>
+ <chemical_shift value="0.526" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="89" name="HD11"/>
+ <atom segid=" A" residue="89" name="HD12"/>
+ <atom segid=" A" residue="89" name="HD13"/>
+ <chemical_shift value="0.484" error="0.0"/>
+ <chemical_shift value="0.526" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="C"/>
+ <chemical_shift value="176.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CB"/>
+ <chemical_shift value="42.609" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CA"/>
+ <chemical_shift value="53.55" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="N"/>
+ <chemical_shift value="120.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CD1"/>
+ <chemical_shift value="26.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CD2"/>
+ <chemical_shift value="25.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="H"/>
+ <chemical_shift value="7.661" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="90" name="HD1"/>
+ <atom segid=" A" residue="90" name="HD2"/>
+ <atom segid=" A" residue="90" name="HE1"/>
+ <atom segid=" A" residue="90" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CB"/>
+ <chemical_shift value="38.921" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CA"/>
+ <chemical_shift value="59.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="N"/>
+ <chemical_shift value="116.748" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="H"/>
+ <chemical_shift value="7.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="C"/>
+ <chemical_shift value="179.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CB"/>
+ <chemical_shift value="31.38" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CA"/>
+ <chemical_shift value="66.902" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="92" name="HD1"/>
+ <atom segid=" A" residue="92" name="HD2"/>
+ <atom segid=" A" residue="92" name="HE1"/>
+ <atom segid=" A" residue="92" name="HE2"/>
+ <atom segid=" A" residue="92" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="C"/>
+ <chemical_shift value="176.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CB"/>
+ <chemical_shift value="36.63" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CA"/>
+ <chemical_shift value="59.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="N"/>
+ <chemical_shift value="112.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="H"/>
+ <chemical_shift value="8.01" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="93" name="HG21"/>
+ <atom segid=" A" residue="93" name="HG22"/>
+ <atom segid=" A" residue="93" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="C"/>
+ <chemical_shift value="176.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CB"/>
+ <chemical_shift value="67.099" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CA"/>
+ <chemical_shift value="64.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="N"/>
+ <chemical_shift value="111.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="H"/>
+ <chemical_shift value="7.099" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="H"/>
+ <chemical_shift value="6.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="C"/>
+ <chemical_shift value="178.465" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CB"/>
+ <chemical_shift value="29.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CA"/>
+ <chemical_shift value="58.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="N"/>
+ <chemical_shift value="120.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="C"/>
+ <chemical_shift value="178.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CB"/>
+ <chemical_shift value="39.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CA"/>
+ <chemical_shift value="57.436" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="N"/>
+ <chemical_shift value="115.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="H"/>
+ <chemical_shift value="7.31" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="96" name="HB1"/>
+ <atom segid=" A" residue="96" name="HB2"/>
+ <atom segid=" A" residue="96" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="C"/>
+ <chemical_shift value="177.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="CB"/>
+ <chemical_shift value="17.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="CA"/>
+ <chemical_shift value="54.0" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="N"/>
+ <chemical_shift value="118.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="H"/>
+ <chemical_shift value="6.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="97" name="HG21"/>
+ <atom segid=" A" residue="97" name="HG22"/>
+ <atom segid=" A" residue="97" name="HG23"/>
+ <chemical_shift value="1.347" error="0.0"/>
+ <chemical_shift value="0.578" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="97" name="HG11"/>
+ <atom segid=" A" residue="97" name="HG12"/>
+ <atom segid=" A" residue="97" name="HG13"/>
+ <chemical_shift value="1.347" error="0.0"/>
+ <chemical_shift value="0.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="C"/>
+ <chemical_shift value="172.577" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CB"/>
+ <chemical_shift value="30.785" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CA"/>
+ <chemical_shift value="59.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="N"/>
+ <chemical_shift value="106.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CG1"/>
+ <chemical_shift value="22.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="H"/>
+ <chemical_shift value="7.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CG2"/>
+ <chemical_shift value="19.363" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CB"/>
+ <chemical_shift value="31.357" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="C"/>
+ <chemical_shift value="176.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="H"/>
+ <chemical_shift value="7.049" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CA"/>
+ <chemical_shift value="55.065" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="N"/>
+ <chemical_shift value="121.675" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="99" name="HD1"/>
+ <atom segid=" A" residue="99" name="HD2"/>
+ <atom segid=" A" residue="99" name="HE1"/>
+ <atom segid=" A" residue="99" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CB"/>
+ <chemical_shift value="41.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CA"/>
+ <chemical_shift value="58.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="N"/>
+ <chemical_shift value="127.473" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="H"/>
+ <chemical_shift value="9.707" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="C"/>
+ <chemical_shift value="175.4" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CB"/>
+ <chemical_shift value="37.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CA"/>
+ <chemical_shift value="53.907" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="C"/>
+ <chemical_shift value="173.987" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="H"/>
+ <chemical_shift value="8.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="CA"/>
+ <chemical_shift value="45.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="N"/>
+ <chemical_shift value="102.283" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="102" name="HZ1"/>
+ <atom segid=" A" residue="102" name="HZ2"/>
+ <atom segid=" A" residue="102" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CB"/>
+ <chemical_shift value="34.731" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="C"/>
+ <chemical_shift value="175.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="H"/>
+ <chemical_shift value="7.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CA"/>
+ <chemical_shift value="54.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="N"/>
+ <chemical_shift value="121.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="103" name="HD21"/>
+ <atom segid=" A" residue="103" name="HD22"/>
+ <atom segid=" A" residue="103" name="HD23"/>
+ <chemical_shift value="0.972" error="0.0"/>
+ <chemical_shift value="0.49" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="103" name="HD11"/>
+ <atom segid=" A" residue="103" name="HD12"/>
+ <atom segid=" A" residue="103" name="HD13"/>
+ <chemical_shift value="0.972" error="0.0"/>
+ <chemical_shift value="0.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="C"/>
+ <chemical_shift value="178.524" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CB"/>
+ <chemical_shift value="42.179" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CA"/>
+ <chemical_shift value="55.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="N"/>
+ <chemical_shift value="123.232" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CD1"/>
+ <chemical_shift value="24.748" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CD2"/>
+ <chemical_shift value="24.1" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="H"/>
+ <chemical_shift value="8.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="104" name="HG21"/>
+ <atom segid=" A" residue="104" name="HG22"/>
+ <atom segid=" A" residue="104" name="HG23"/>
+ <chemical_shift value="0.889" error="0.0"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="104" name="HD11"/>
+ <atom segid=" A" residue="104" name="HD12"/>
+ <atom segid=" A" residue="104" name="HD13"/>
+ <chemical_shift value="0.889" error="0.0"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="C"/>
+ <chemical_shift value="175.468" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CB"/>
+ <chemical_shift value="39.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CA"/>
+ <chemical_shift value="59.655" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="N"/>
+ <chemical_shift value="112.793" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CD1"/>
+ <chemical_shift value="14.779" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="H"/>
+ <chemical_shift value="8.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CG2"/>
+ <chemical_shift value="19.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="105" name="HB1"/>
+ <atom segid=" A" residue="105" name="HB2"/>
+ <atom segid=" A" residue="105" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="C"/>
+ <chemical_shift value="173.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="CB"/>
+ <chemical_shift value="22.111" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="CA"/>
+ <chemical_shift value="52.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="N"/>
+ <chemical_shift value="117.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="H"/>
+ <chemical_shift value="7.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="106" name="HD1"/>
+ <atom segid=" A" residue="106" name="HD2"/>
+ <atom segid=" A" residue="106" name="HE1"/>
+ <atom segid=" A" residue="106" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CB"/>
+ <chemical_shift value="39.931" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CA"/>
+ <chemical_shift value="56.214" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="N"/>
+ <chemical_shift value="113.919" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="H"/>
+ <chemical_shift value="8.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="C"/>
+ <chemical_shift value="174.609" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CB"/>
+ <chemical_shift value="32.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CA"/>
+ <chemical_shift value="62.281" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="108" name="HG21"/>
+ <atom segid=" A" residue="108" name="HG22"/>
+ <atom segid=" A" residue="108" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.637" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="108" name="HD11"/>
+ <atom segid=" A" residue="108" name="HD12"/>
+ <atom segid=" A" residue="108" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.637" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="C"/>
+ <chemical_shift value="176.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CB"/>
+ <chemical_shift value="37.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CA"/>
+ <chemical_shift value="60.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="N"/>
+ <chemical_shift value="115.381" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CD1"/>
+ <chemical_shift value="9.981" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="H"/>
+ <chemical_shift value="8.515" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="109" name="HB1"/>
+ <atom segid=" A" residue="109" name="HB2"/>
+ <atom segid=" A" residue="109" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="C"/>
+ <chemical_shift value="174.628" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="CB"/>
+ <chemical_shift value="23.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="CA"/>
+ <chemical_shift value="50.761" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="N"/>
+ <chemical_shift value="118.162" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="H"/>
+ <chemical_shift value="7.854" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="110" name="HG21"/>
+ <atom segid=" A" residue="110" name="HG22"/>
+ <atom segid=" A" residue="110" name="HG23"/>
+ <chemical_shift value="0.476" error="0.0"/>
+ <chemical_shift value="0.767" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="110" name="HG11"/>
+ <atom segid=" A" residue="110" name="HG12"/>
+ <atom segid=" A" residue="110" name="HG13"/>
+ <chemical_shift value="0.476" error="0.0"/>
+ <chemical_shift value="0.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="C"/>
+ <chemical_shift value="173.634" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CB"/>
+ <chemical_shift value="34.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CA"/>
+ <chemical_shift value="62.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="N"/>
+ <chemical_shift value="121.428" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CG1"/>
+ <chemical_shift value="20.954" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="H"/>
+ <chemical_shift value="8.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CG2"/>
+ <chemical_shift value="20.424" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="C"/>
+ <chemical_shift value="173.917" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CB"/>
+ <chemical_shift value="32.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CA"/>
+ <chemical_shift value="54.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="N"/>
+ <chemical_shift value="123.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="H"/>
+ <chemical_shift value="9.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="112" name="HB1"/>
+ <atom segid=" A" residue="112" name="HB2"/>
+ <atom segid=" A" residue="112" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="C"/>
+ <chemical_shift value="176.641" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="CB"/>
+ <chemical_shift value="22.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="CA"/>
+ <chemical_shift value="50.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="N"/>
+ <chemical_shift value="117.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="H"/>
+ <chemical_shift value="6.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="113" name="HD21"/>
+ <atom segid=" A" residue="113" name="HD22"/>
+ <atom segid=" A" residue="113" name="HD23"/>
+ <chemical_shift value="0.854" error="0.0"/>
+ <chemical_shift value="0.691" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="113" name="HD11"/>
+ <atom segid=" A" residue="113" name="HD12"/>
+ <atom segid=" A" residue="113" name="HD13"/>
+ <chemical_shift value="0.854" error="0.0"/>
+ <chemical_shift value="0.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="C"/>
+ <chemical_shift value="173.598" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CB"/>
+ <chemical_shift value="43.367" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CA"/>
+ <chemical_shift value="55.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="N"/>
+ <chemical_shift value="123.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CD1"/>
+ <chemical_shift value="26.792" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CD2"/>
+ <chemical_shift value="23.625" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="H"/>
+ <chemical_shift value="8.457" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="C"/>
+ <chemical_shift value="172.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="CB"/>
+ <chemical_shift value="67.447" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="CA"/>
+ <chemical_shift value="57.265" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="N"/>
+ <chemical_shift value="108.174" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="H"/>
+ <chemical_shift value="7.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="115" name="HD21"/>
+ <atom segid=" A" residue="115" name="HD22"/>
+ <atom segid=" A" residue="115" name="HD23"/>
+ <chemical_shift value="0.587" error="0.0"/>
+ <chemical_shift value="0.684" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="115" name="HD11"/>
+ <atom segid=" A" residue="115" name="HD12"/>
+ <atom segid=" A" residue="115" name="HD13"/>
+ <chemical_shift value="0.587" error="0.0"/>
+ <chemical_shift value="0.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="C"/>
+ <chemical_shift value="174.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CB"/>
+ <chemical_shift value="43.729" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CA"/>
+ <chemical_shift value="54.482" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="N"/>
+ <chemical_shift value="122.319" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CD1"/>
+ <chemical_shift value="22.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CD2"/>
+ <chemical_shift value="24.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="H"/>
+ <chemical_shift value="7.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="116" name="HG21"/>
+ <atom segid=" A" residue="116" name="HG22"/>
+ <atom segid=" A" residue="116" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.459" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="116" name="HD11"/>
+ <atom segid=" A" residue="116" name="HD12"/>
+ <atom segid=" A" residue="116" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.459" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="C"/>
+ <chemical_shift value="174.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CB"/>
+ <chemical_shift value="38.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CA"/>
+ <chemical_shift value="60.103" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="N"/>
+ <chemical_shift value="129.611" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CD1"/>
+ <chemical_shift value="13.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="H"/>
+ <chemical_shift value="8.667" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="117" name="HD1"/>
+ <atom segid=" A" residue="117" name="HD2"/>
+ <atom segid=" A" residue="117" name="HE1"/>
+ <atom segid=" A" residue="117" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="C"/>
+ <chemical_shift value="172.945" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CB"/>
+ <chemical_shift value="42.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CA"/>
+ <chemical_shift value="54.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="N"/>
+ <chemical_shift value="121.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="H"/>
+ <chemical_shift value="9.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="C"/>
+ <chemical_shift value="175.772" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CB"/>
+ <chemical_shift value="37.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CA"/>
+ <chemical_shift value="52.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="N"/>
+ <chemical_shift value="121.187" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="H"/>
+ <chemical_shift value="9.303" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="119" name="HZ1"/>
+ <atom segid=" A" residue="119" name="HZ2"/>
+ <atom segid=" A" residue="119" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CB"/>
+ <chemical_shift value="32.435" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="C"/>
+ <chemical_shift value="177.723" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="H"/>
+ <chemical_shift value="8.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CA"/>
+ <chemical_shift value="58.733" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="N"/>
+ <chemical_shift value="125.522" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="C"/>
+ <chemical_shift value="177.651" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CB"/>
+ <chemical_shift value="40.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CA"/>
+ <chemical_shift value="56.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="N"/>
+ <chemical_shift value="115.687" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="121" name="HD21"/>
+ <atom segid=" A" residue="121" name="HD22"/>
+ <atom segid=" A" residue="121" name="HD23"/>
+ <chemical_shift value="0.779" error="0.0"/>
+ <chemical_shift value="0.665" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="121" name="HD11"/>
+ <atom segid=" A" residue="121" name="HD12"/>
+ <atom segid=" A" residue="121" name="HD13"/>
+ <chemical_shift value="0.779" error="0.0"/>
+ <chemical_shift value="0.665" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="C"/>
+ <chemical_shift value="176.749" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CB"/>
+ <chemical_shift value="44.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CA"/>
+ <chemical_shift value="55.765" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="N"/>
+ <chemical_shift value="117.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CD1"/>
+ <chemical_shift value="24.729" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CD2"/>
+ <chemical_shift value="22.791" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="H"/>
+ <chemical_shift value="7.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="122" name="HD21"/>
+ <atom segid=" A" residue="122" name="HD22"/>
+ <atom segid=" A" residue="122" name="HD23"/>
+ <chemical_shift value="0.937" error="0.0"/>
+ <chemical_shift value="0.93" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="122" name="HD11"/>
+ <atom segid=" A" residue="122" name="HD12"/>
+ <atom segid=" A" residue="122" name="HD13"/>
+ <chemical_shift value="0.937" error="0.0"/>
+ <chemical_shift value="0.93" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CB"/>
+ <chemical_shift value="44.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CA"/>
+ <chemical_shift value="51.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="N"/>
+ <chemical_shift value="119.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CD1"/>
+ <chemical_shift value="25.548" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CD2"/>
+ <chemical_shift value="26.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="C"/>
+ <chemical_shift value="176.075" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CB"/>
+ <chemical_shift value="31.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CA"/>
+ <chemical_shift value="62.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="127" name="HZ1"/>
+ <atom segid=" A" residue="127" name="HZ2"/>
+ <atom segid=" A" residue="127" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CB"/>
+ <chemical_shift value="33.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="C"/>
+ <chemical_shift value="177.427" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="H"/>
+ <chemical_shift value="8.137" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CA"/>
+ <chemical_shift value="56.778" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="N"/>
+ <chemical_shift value="118.457" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="128" name="HG21"/>
+ <atom segid=" A" residue="128" name="HG22"/>
+ <atom segid=" A" residue="128" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="C"/>
+ <chemical_shift value="174.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CB"/>
+ <chemical_shift value="71.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CA"/>
+ <chemical_shift value="60.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="N"/>
+ <chemical_shift value="108.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="H"/>
+ <chemical_shift value="10.183" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="C"/>
+ <chemical_shift value="179.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CB"/>
+ <chemical_shift value="28.48" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CA"/>
+ <chemical_shift value="60.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="N"/>
+ <chemical_shift value="123.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="C"/>
+ <chemical_shift value="178.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CB"/>
+ <chemical_shift value="28.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CA"/>
+ <chemical_shift value="61.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="N"/>
+ <chemical_shift value="118.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="H"/>
+ <chemical_shift value="10.583" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="C"/>
+ <chemical_shift value="176.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CB"/>
+ <chemical_shift value="31.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CA"/>
+ <chemical_shift value="57.205" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="N"/>
+ <chemical_shift value="116.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="H"/>
+ <chemical_shift value="7.606" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="132" name="HG21"/>
+ <atom segid=" A" residue="132" name="HG22"/>
+ <atom segid=" A" residue="132" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.56" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="132" name="HD11"/>
+ <atom segid=" A" residue="132" name="HD12"/>
+ <atom segid=" A" residue="132" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CB"/>
+ <chemical_shift value="33.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CA"/>
+ <chemical_shift value="66.928" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="N"/>
+ <chemical_shift value="121.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CD1"/>
+ <chemical_shift value="12.36" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="H"/>
+ <chemical_shift value="8.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="C"/>
+ <chemical_shift value="177.795" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CB"/>
+ <chemical_shift value="30.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CA"/>
+ <chemical_shift value="67.059" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="134" name="HB1"/>
+ <atom segid=" A" residue="134" name="HB2"/>
+ <atom segid=" A" residue="134" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="C"/>
+ <chemical_shift value="181.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="CB"/>
+ <chemical_shift value="17.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="CA"/>
+ <chemical_shift value="55.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="N"/>
+ <chemical_shift value="118.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="H"/>
+ <chemical_shift value="7.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="135" name="HD21"/>
+ <atom segid=" A" residue="135" name="HD22"/>
+ <atom segid=" A" residue="135" name="HD23"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ <chemical_shift value="0.888" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="135" name="HD11"/>
+ <atom segid=" A" residue="135" name="HD12"/>
+ <atom segid=" A" residue="135" name="HD13"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ <chemical_shift value="0.888" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="C"/>
+ <chemical_shift value="179.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CB"/>
+ <chemical_shift value="42.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CA"/>
+ <chemical_shift value="57.396" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="N"/>
+ <chemical_shift value="120.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CD1"/>
+ <chemical_shift value="24.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CD2"/>
+ <chemical_shift value="24.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="H"/>
+ <chemical_shift value="7.6" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="C"/>
+ <chemical_shift value="177.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CB"/>
+ <chemical_shift value="41.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CA"/>
+ <chemical_shift value="58.901" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="N"/>
+ <chemical_shift value="118.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="H"/>
+ <chemical_shift value="8.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="137" name="HZ1"/>
+ <atom segid=" A" residue="137" name="HZ2"/>
+ <atom segid=" A" residue="137" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CB"/>
+ <chemical_shift value="31.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="C"/>
+ <chemical_shift value="179.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="H"/>
+ <chemical_shift value="8.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CA"/>
+ <chemical_shift value="60.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="N"/>
+ <chemical_shift value="117.342" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="C"/>
+ <chemical_shift value="179.799" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CB"/>
+ <chemical_shift value="29.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CA"/>
+ <chemical_shift value="59.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="N"/>
+ <chemical_shift value="118.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="H"/>
+ <chemical_shift value="7.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="139" name="HD21"/>
+ <atom segid=" A" residue="139" name="HD22"/>
+ <atom segid=" A" residue="139" name="HD23"/>
+ <chemical_shift value="0.852" error="0.0"/>
+ <chemical_shift value="0.787" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="139" name="HD11"/>
+ <atom segid=" A" residue="139" name="HD12"/>
+ <atom segid=" A" residue="139" name="HD13"/>
+ <chemical_shift value="0.852" error="0.0"/>
+ <chemical_shift value="0.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="C"/>
+ <chemical_shift value="180.721" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CB"/>
+ <chemical_shift value="40.311" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CA"/>
+ <chemical_shift value="58.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="N"/>
+ <chemical_shift value="121.279" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CD1"/>
+ <chemical_shift value="25.914" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CD2"/>
+ <chemical_shift value="22.927" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="H"/>
+ <chemical_shift value="8.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="140" name="HZ1"/>
+ <atom segid=" A" residue="140" name="HZ2"/>
+ <atom segid=" A" residue="140" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CB"/>
+ <chemical_shift value="31.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="C"/>
+ <chemical_shift value="181.621" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="H"/>
+ <chemical_shift value="9.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CA"/>
+ <chemical_shift value="58.851" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="N"/>
+ <chemical_shift value="124.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="141" name="HB1"/>
+ <atom segid=" A" residue="141" name="HB2"/>
+ <atom segid=" A" residue="141" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="C"/>
+ <chemical_shift value="178.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="CB"/>
+ <chemical_shift value="17.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="CA"/>
+ <chemical_shift value="54.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="N"/>
+ <chemical_shift value="122.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="H"/>
+ <chemical_shift value="7.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="142" name="HZ1"/>
+ <atom segid=" A" residue="142" name="HZ2"/>
+ <atom segid=" A" residue="142" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CB"/>
+ <chemical_shift value="32.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="C"/>
+ <chemical_shift value="176.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="H"/>
+ <chemical_shift value="7.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CA"/>
+ <chemical_shift value="55.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="N"/>
+ <chemical_shift value="115.794" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="C"/>
+ <chemical_shift value="174.318" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="H"/>
+ <chemical_shift value="7.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="CA"/>
+ <chemical_shift value="46.128" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="N"/>
+ <chemical_shift value="107.82" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="144" name="HZ1"/>
+ <atom segid=" A" residue="144" name="HZ2"/>
+ <atom segid=" A" residue="144" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CB"/>
+ <chemical_shift value="35.01" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="C"/>
+ <chemical_shift value="173.812" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="H"/>
+ <chemical_shift value="7.86" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CA"/>
+ <chemical_shift value="53.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="N"/>
+ <chemical_shift value="119.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="C"/>
+ <chemical_shift value="174.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="CB"/>
+ <chemical_shift value="66.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="CA"/>
+ <chemical_shift value="56.884" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="N"/>
+ <chemical_shift value="109.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="H"/>
+ <chemical_shift value="7.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="146" name="HB1"/>
+ <atom segid=" A" residue="146" name="HB2"/>
+ <atom segid=" A" residue="146" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="C"/>
+ <chemical_shift value="175.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="CB"/>
+ <chemical_shift value="17.973" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="CA"/>
+ <chemical_shift value="55.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="N"/>
+ <chemical_shift value="122.791" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="H"/>
+ <chemical_shift value="9.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="147" name="HD21"/>
+ <atom segid=" A" residue="147" name="HD22"/>
+ <atom segid=" A" residue="147" name="HD23"/>
+ <chemical_shift value="0.936" error="0.0"/>
+ <chemical_shift value="0.683" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="147" name="HD11"/>
+ <atom segid=" A" residue="147" name="HD12"/>
+ <atom segid=" A" residue="147" name="HD13"/>
+ <chemical_shift value="0.936" error="0.0"/>
+ <chemical_shift value="0.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="C"/>
+ <chemical_shift value="175.05" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CB"/>
+ <chemical_shift value="45.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CA"/>
+ <chemical_shift value="54.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="N"/>
+ <chemical_shift value="116.868" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CD1"/>
+ <chemical_shift value="22.5" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CD2"/>
+ <chemical_shift value="27.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="H"/>
+ <chemical_shift value="8.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="148" name="HE1"/>
+ <atom segid=" A" residue="148" name="HE2"/>
+ <atom segid=" A" residue="148" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="C"/>
+ <chemical_shift value="174.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CB"/>
+ <chemical_shift value="37.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CA"/>
+ <chemical_shift value="55.8" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="N"/>
+ <chemical_shift value="121.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="H"/>
+ <chemical_shift value="8.179" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="149" name="HD2"/>
+ <atom segid=" A" residue="149" name="HE1"/>
+ <atom segid=" A" residue="149" name="HE2"/>
+ <atom segid=" A" residue="149" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="171.59" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CB"/>
+ <chemical_shift value="41.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CA"/>
+ <chemical_shift value="55.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="N"/>
+ <chemical_shift value="120.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="H"/>
+ <chemical_shift value="8.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="C"/>
+ <chemical_shift value="172.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="37.305" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CA"/>
+ <chemical_shift value="53.341" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="N"/>
+ <chemical_shift value="116.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="H"/>
+ <chemical_shift value="8.671" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="151" name="HD22"/>
+ <atom segid=" A" residue="151" name="HD23"/>
+ <chemical_shift value="0.135" error="0.0"/>
+ <chemical_shift value="0.744" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="151" name="HD11"/>
+ <atom segid=" A" residue="151" name="HD12"/>
+ <atom segid=" A" residue="151" name="HD13"/>
+ <chemical_shift value="0.135" error="0.0"/>
+ <chemical_shift value="0.744" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="177.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CB"/>
+ <chemical_shift value="41.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CA"/>
+ <chemical_shift value="54.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="122.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="26.232" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="23.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="7.286" error="0.0"/>
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+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="C"/>
+ <chemical_shift value="176.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CB"/>
+ <chemical_shift value="28.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CA"/>
+ <chemical_shift value="55.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="N"/>
+ <chemical_shift value="113.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="H"/>
+ <chemical_shift value="7.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CB"/>
+ <chemical_shift value="32.958" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CA"/>
+ <chemical_shift value="51.537" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="N"/>
+ <chemical_shift value="113.572" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="H"/>
+ <chemical_shift value="6.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="C"/>
+ <chemical_shift value="176.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CB"/>
+ <chemical_shift value="31.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CA"/>
+ <chemical_shift value="63.731" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="155" name="HD1"/>
+ <atom segid=" A" residue="155" name="HD2"/>
+ <atom segid=" A" residue="155" name="HE1"/>
+ <atom segid=" A" residue="155" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="C"/>
+ <chemical_shift value="176.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CB"/>
+ <chemical_shift value="40.447" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CA"/>
+ <chemical_shift value="62.679" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="N"/>
+ <chemical_shift value="117.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="H"/>
+ <chemical_shift value="7.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="156" name="HD1"/>
+ <atom segid=" A" residue="156" name="HD2"/>
+ <atom segid=" A" residue="156" name="HE1"/>
+ <atom segid=" A" residue="156" name="HE2"/>
+ <atom segid=" A" residue="156" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="C"/>
+ <chemical_shift value="176.222" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CB"/>
+ <chemical_shift value="41.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CA"/>
+ <chemical_shift value="60.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="N"/>
+ <chemical_shift value="112.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="H"/>
+ <chemical_shift value="8.045" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="157" name="HG21"/>
+ <atom segid=" A" residue="157" name="HG22"/>
+ <atom segid=" A" residue="157" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="C"/>
+ <chemical_shift value="176.039" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CB"/>
+ <chemical_shift value="69.29" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CA"/>
+ <chemical_shift value="63.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="N"/>
+ <chemical_shift value="106.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="H"/>
+ <chemical_shift value="7.59" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CB"/>
+ <chemical_shift value="28.509" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CA"/>
+ <chemical_shift value="60.968" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="N"/>
+ <chemical_shift value="124.195" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="C"/>
+ <chemical_shift value="178.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CB"/>
+ <chemical_shift value="30.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CA"/>
+ <chemical_shift value="65.931" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="160" name="HD21"/>
+ <atom segid=" A" residue="160" name="HD22"/>
+ <atom segid=" A" residue="160" name="HD23"/>
+ <chemical_shift value="-0.302" error="0.0"/>
+ <chemical_shift value="-1.003" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="160" name="HD11"/>
+ <atom segid=" A" residue="160" name="HD12"/>
+ <atom segid=" A" residue="160" name="HD13"/>
+ <chemical_shift value="-0.302" error="0.0"/>
+ <chemical_shift value="-1.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="C"/>
+ <chemical_shift value="176.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CB"/>
+ <chemical_shift value="42.223" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CA"/>
+ <chemical_shift value="56.069" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="N"/>
+ <chemical_shift value="111.624" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CD1"/>
+ <chemical_shift value="19.602" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CD2"/>
+ <chemical_shift value="25.084" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="H"/>
+ <chemical_shift value="6.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="161" name="HG21"/>
+ <atom segid=" A" residue="161" name="HG22"/>
+ <atom segid=" A" residue="161" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.76" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="161" name="HD11"/>
+ <atom segid=" A" residue="161" name="HD12"/>
+ <atom segid=" A" residue="161" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="C"/>
+ <chemical_shift value="175.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CB"/>
+ <chemical_shift value="37.395" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CA"/>
+ <chemical_shift value="65.625" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="N"/>
+ <chemical_shift value="119.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CD1"/>
+ <chemical_shift value="13.081" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="H"/>
+ <chemical_shift value="6.955" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="162" name="HB1"/>
+ <atom segid=" A" residue="162" name="HB2"/>
+ <atom segid=" A" residue="162" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="C"/>
+ <chemical_shift value="179.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="CB"/>
+ <chemical_shift value="18.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="CA"/>
+ <chemical_shift value="52.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="N"/>
+ <chemical_shift value="115.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="H"/>
+ <chemical_shift value="8.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="163" name="HB1"/>
+ <atom segid=" A" residue="163" name="HB2"/>
+ <atom segid=" A" residue="163" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="C"/>
+ <chemical_shift value="178.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="CB"/>
+ <chemical_shift value="19.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="CA"/>
+ <chemical_shift value="56.425" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="N"/>
+ <chemical_shift value="120.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="H"/>
+ <chemical_shift value="6.668" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="C"/>
+ <chemical_shift value="176.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CB"/>
+ <chemical_shift value="42.538" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CA"/>
+ <chemical_shift value="53.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="N"/>
+ <chemical_shift value="115.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="H"/>
+ <chemical_shift value="9.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="C"/>
+ <chemical_shift value="175.607" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="H"/>
+ <chemical_shift value="7.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="CA"/>
+ <chemical_shift value="45.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="N"/>
+ <chemical_shift value="103.622" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="C"/>
+ <chemical_shift value="172.227" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="H"/>
+ <chemical_shift value="7.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="CA"/>
+ <chemical_shift value="45.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="N"/>
+ <chemical_shift value="108.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="167" name="HD1"/>
+ <atom segid=" A" residue="167" name="HD2"/>
+ <atom segid=" A" residue="167" name="HE1"/>
+ <atom segid=" A" residue="167" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="C"/>
+ <chemical_shift value="173.273" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CB"/>
+ <chemical_shift value="39.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CA"/>
+ <chemical_shift value="57.657" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="N"/>
+ <chemical_shift value="115.865" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="H"/>
+ <chemical_shift value="8.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="168" name="HB1"/>
+ <atom segid=" A" residue="168" name="HB2"/>
+ <atom segid=" A" residue="168" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="C"/>
+ <chemical_shift value="173.012" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="CB"/>
+ <chemical_shift value="16.475" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="CA"/>
+ <chemical_shift value="53.124" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="N"/>
+ <chemical_shift value="124.0" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="H"/>
+ <chemical_shift value="10.209" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="169" name="HD1"/>
+ <atom segid=" A" residue="169" name="HD2"/>
+ <atom segid=" A" residue="169" name="HE1"/>
+ <atom segid=" A" residue="169" name="HE2"/>
+ <atom segid=" A" residue="169" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="C"/>
+ <chemical_shift value="176.744" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CB"/>
+ <chemical_shift value="42.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CA"/>
+ <chemical_shift value="55.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="N"/>
+ <chemical_shift value="108.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="H"/>
+ <chemical_shift value="6.324" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="170" name="HZ1"/>
+ <atom segid=" A" residue="170" name="HZ2"/>
+ <atom segid=" A" residue="170" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CB"/>
+ <chemical_shift value="32.355" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="C"/>
+ <chemical_shift value="174.716" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="H"/>
+ <chemical_shift value="8.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CA"/>
+ <chemical_shift value="57.027" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="N"/>
+ <chemical_shift value="125.705" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="171" name="HD1"/>
+ <atom segid=" A" residue="171" name="HD2"/>
+ <atom segid=" A" residue="171" name="HE1"/>
+ <atom segid=" A" residue="171" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="C"/>
+ <chemical_shift value="175.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CB"/>
+ <chemical_shift value="39.896" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CA"/>
+ <chemical_shift value="56.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="N"/>
+ <chemical_shift value="129.707" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="H"/>
+ <chemical_shift value="8.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CB"/>
+ <chemical_shift value="32.477" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CA"/>
+ <chemical_shift value="55.981" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="N"/>
+ <chemical_shift value="126.797" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="H"/>
+ <chemical_shift value="8.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="C"/>
+ <chemical_shift value="175.432" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CB"/>
+ <chemical_shift value="37.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CA"/>
+ <chemical_shift value="54.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="C"/>
+ <chemical_shift value="173.294" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="H"/>
+ <chemical_shift value="7.52" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="CA"/>
+ <chemical_shift value="45.705" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="N"/>
+ <chemical_shift value="102.08" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="175" name="HZ1"/>
+ <atom segid=" A" residue="175" name="HZ2"/>
+ <atom segid=" A" residue="175" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CB"/>
+ <chemical_shift value="35.233" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="C"/>
+ <chemical_shift value="174.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="H"/>
+ <chemical_shift value="7.107" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CA"/>
+ <chemical_shift value="54.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="N"/>
+ <chemical_shift value="118.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="176" name="HD1"/>
+ <atom segid=" A" residue="176" name="HD2"/>
+ <atom segid=" A" residue="176" name="HE1"/>
+ <atom segid=" A" residue="176" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="C"/>
+ <chemical_shift value="176.262" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CB"/>
+ <chemical_shift value="39.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CA"/>
+ <chemical_shift value="58.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="N"/>
+ <chemical_shift value="120.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="H"/>
+ <chemical_shift value="8.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="C"/>
+ <chemical_shift value="177.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CB"/>
+ <chemical_shift value="41.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CA"/>
+ <chemical_shift value="52.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="N"/>
+ <chemical_shift value="124.051" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="H"/>
+ <chemical_shift value="9.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="178" name="HG21"/>
+ <atom segid=" A" residue="178" name="HG22"/>
+ <atom segid=" A" residue="178" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.853" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="178" name="HD11"/>
+ <atom segid=" A" residue="178" name="HD12"/>
+ <atom segid=" A" residue="178" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="C"/>
+ <chemical_shift value="175.849" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CB"/>
+ <chemical_shift value="36.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CA"/>
+ <chemical_shift value="63.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="N"/>
+ <chemical_shift value="117.051" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CD1"/>
+ <chemical_shift value="13.905" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="H"/>
+ <chemical_shift value="7.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="179" name="HZ1"/>
+ <atom segid=" A" residue="179" name="HZ2"/>
+ <atom segid=" A" residue="179" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CB"/>
+ <chemical_shift value="31.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="C"/>
+ <chemical_shift value="176.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="H"/>
+ <chemical_shift value="8.302" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CA"/>
+ <chemical_shift value="54.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="N"/>
+ <chemical_shift value="116.075" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="C"/>
+ <chemical_shift value="172.993" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CB"/>
+ <chemical_shift value="40.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CA"/>
+ <chemical_shift value="53.425" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="N"/>
+ <chemical_shift value="123.259" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="H"/>
+ <chemical_shift value="7.754" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="181" name="HG21"/>
+ <atom segid=" A" residue="181" name="HG22"/>
+ <atom segid=" A" residue="181" name="HG23"/>
+ <chemical_shift value="0.711" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="181" name="HG11"/>
+ <atom segid=" A" residue="181" name="HG12"/>
+ <atom segid=" A" residue="181" name="HG13"/>
+ <chemical_shift value="0.711" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="C"/>
+ <chemical_shift value="176.899" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CB"/>
+ <chemical_shift value="35.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CA"/>
+ <chemical_shift value="59.481" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="N"/>
+ <chemical_shift value="122.883" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CG1"/>
+ <chemical_shift value="21.539" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="H"/>
+ <chemical_shift value="7.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CG2"/>
+ <chemical_shift value="22.538" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="C"/>
+ <chemical_shift value="174.259" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="H"/>
+ <chemical_shift value="7.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="CA"/>
+ <chemical_shift value="46.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="N"/>
+ <chemical_shift value="120.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="183" name="HG21"/>
+ <atom segid=" A" residue="183" name="HG22"/>
+ <atom segid=" A" residue="183" name="HG23"/>
+ <chemical_shift value="0.841" error="0.0"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="183" name="HG11"/>
+ <atom segid=" A" residue="183" name="HG12"/>
+ <atom segid=" A" residue="183" name="HG13"/>
+ <chemical_shift value="0.841" error="0.0"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="C"/>
+ <chemical_shift value="173.292" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CB"/>
+ <chemical_shift value="32.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CA"/>
+ <chemical_shift value="63.489" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="N"/>
+ <chemical_shift value="114.266" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CG1"/>
+ <chemical_shift value="22.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="H"/>
+ <chemical_shift value="6.757" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CG2"/>
+ <chemical_shift value="22.42" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="C"/>
+ <chemical_shift value="176.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CB"/>
+ <chemical_shift value="39.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CA"/>
+ <chemical_shift value="51.67" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="N"/>
+ <chemical_shift value="114.851" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="H"/>
+ <chemical_shift value="7.835" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CB"/>
+ <chemical_shift value="39.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CA"/>
+ <chemical_shift value="51.688" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="N"/>
+ <chemical_shift value="116.3" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="H"/>
+ <chemical_shift value="6.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="186" name="HB1"/>
+ <atom segid=" A" residue="186" name="HB2"/>
+ <atom segid=" A" residue="186" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="C"/>
+ <chemical_shift value="180.525" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="CB"/>
+ <chemical_shift value="18.22" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="CA"/>
+ <chemical_shift value="55.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="C"/>
+ <chemical_shift value="176.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="H"/>
+ <chemical_shift value="8.385" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="CA"/>
+ <chemical_shift value="47.366" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="N"/>
+ <chemical_shift value="109.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="188" name="HB1"/>
+ <atom segid=" A" residue="188" name="HB2"/>
+ <atom segid=" A" residue="188" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="C"/>
+ <chemical_shift value="180.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="CB"/>
+ <chemical_shift value="18.399" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="CA"/>
+ <chemical_shift value="54.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="N"/>
+ <chemical_shift value="127.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="H"/>
+ <chemical_shift value="8.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="189" name="HZ1"/>
+ <atom segid=" A" residue="189" name="HZ2"/>
+ <atom segid=" A" residue="189" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CB"/>
+ <chemical_shift value="31.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="C"/>
+ <chemical_shift value="180.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="H"/>
+ <chemical_shift value="7.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CA"/>
+ <chemical_shift value="59.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="N"/>
+ <chemical_shift value="115.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="190" name="HB1"/>
+ <atom segid=" A" residue="190" name="HB2"/>
+ <atom segid=" A" residue="190" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="C"/>
+ <chemical_shift value="181.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="CB"/>
+ <chemical_shift value="17.89" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="CA"/>
+ <chemical_shift value="55.835" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="N"/>
+ <chemical_shift value="124.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="H"/>
+ <chemical_shift value="8.224" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="C"/>
+ <chemical_shift value="174.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="H"/>
+ <chemical_shift value="8.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="CA"/>
+ <chemical_shift value="47.937" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="N"/>
+ <chemical_shift value="107.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="192" name="HD21"/>
+ <atom segid=" A" residue="192" name="HD22"/>
+ <atom segid=" A" residue="192" name="HD23"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="1.085" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="192" name="HD11"/>
+ <atom segid=" A" residue="192" name="HD12"/>
+ <atom segid=" A" residue="192" name="HD13"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="1.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="C"/>
+ <chemical_shift value="178.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CB"/>
+ <chemical_shift value="40.218" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CA"/>
+ <chemical_shift value="57.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="N"/>
+ <chemical_shift value="121.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CD1"/>
+ <chemical_shift value="24.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CD2"/>
+ <chemical_shift value="25.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="H"/>
+ <chemical_shift value="8.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="193" name="HG21"/>
+ <atom segid=" A" residue="193" name="HG22"/>
+ <atom segid=" A" residue="193" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="C"/>
+ <chemical_shift value="175.23" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CB"/>
+ <chemical_shift value="69.081" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CA"/>
+ <chemical_shift value="67.423" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="N"/>
+ <chemical_shift value="116.486" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="H"/>
+ <chemical_shift value="8.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="194" name="HD1"/>
+ <atom segid=" A" residue="194" name="HD2"/>
+ <atom segid=" A" residue="194" name="HE1"/>
+ <atom segid=" A" residue="194" name="HE2"/>
+ <atom segid=" A" residue="194" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="C"/>
+ <chemical_shift value="177.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CB"/>
+ <chemical_shift value="39.196" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CA"/>
+ <chemical_shift value="62.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="N"/>
+ <chemical_shift value="122.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="H"/>
+ <chemical_shift value="7.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="195" name="HD21"/>
+ <atom segid=" A" residue="195" name="HD22"/>
+ <atom segid=" A" residue="195" name="HD23"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="195" name="HD11"/>
+ <atom segid=" A" residue="195" name="HD12"/>
+ <atom segid=" A" residue="195" name="HD13"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="C"/>
+ <chemical_shift value="178.132" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CB"/>
+ <chemical_shift value="41.352" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CA"/>
+ <chemical_shift value="58.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="N"/>
+ <chemical_shift value="119.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CD1"/>
+ <chemical_shift value="23.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CD2"/>
+ <chemical_shift value="25.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="H"/>
+ <chemical_shift value="7.712" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="196" name="HG21"/>
+ <atom segid=" A" residue="196" name="HG22"/>
+ <atom segid=" A" residue="196" name="HG23"/>
+ <chemical_shift value="0.856" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="196" name="HG11"/>
+ <atom segid=" A" residue="196" name="HG12"/>
+ <atom segid=" A" residue="196" name="HG13"/>
+ <chemical_shift value="0.856" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="C"/>
+ <chemical_shift value="178.464" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CB"/>
+ <chemical_shift value="31.053" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CA"/>
+ <chemical_shift value="67.271" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="N"/>
+ <chemical_shift value="117.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CG1"/>
+ <chemical_shift value="21.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="H"/>
+ <chemical_shift value="8.589" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CG2"/>
+ <chemical_shift value="23.319" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="C"/>
+ <chemical_shift value="179.361" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CB"/>
+ <chemical_shift value="39.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CA"/>
+ <chemical_shift value="58.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="N"/>
+ <chemical_shift value="122.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="H"/>
+ <chemical_shift value="8.58" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="198" name="HD21"/>
+ <atom segid=" A" residue="198" name="HD22"/>
+ <atom segid=" A" residue="198" name="HD23"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="1.018" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="198" name="HD11"/>
+ <atom segid=" A" residue="198" name="HD12"/>
+ <atom segid=" A" residue="198" name="HD13"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="1.018" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="C"/>
+ <chemical_shift value="179.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CB"/>
+ <chemical_shift value="42.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CA"/>
+ <chemical_shift value="58.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="N"/>
+ <chemical_shift value="120.213" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CD1"/>
+ <chemical_shift value="25.598" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CD2"/>
+ <chemical_shift value="23.461" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="H"/>
+ <chemical_shift value="7.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="199" name="HG21"/>
+ <atom segid=" A" residue="199" name="HG22"/>
+ <atom segid=" A" residue="199" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.743" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="199" name="HD11"/>
+ <atom segid=" A" residue="199" name="HD12"/>
+ <atom segid=" A" residue="199" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.743" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="C"/>
+ <chemical_shift value="181.156" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CB"/>
+ <chemical_shift value="38.209" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CA"/>
+ <chemical_shift value="63.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="N"/>
+ <chemical_shift value="119.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CD1"/>
+ <chemical_shift value="14.222" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="H"/>
+ <chemical_shift value="7.434" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="200" name="HZ1"/>
+ <atom segid=" A" residue="200" name="HZ2"/>
+ <atom segid=" A" residue="200" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CB"/>
+ <chemical_shift value="32.127" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="C"/>
+ <chemical_shift value="178.834" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="H"/>
+ <chemical_shift value="9.393" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CA"/>
+ <chemical_shift value="59.943" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="N"/>
+ <chemical_shift value="124.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="C"/>
+ <chemical_shift value="173.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CB"/>
+ <chemical_shift value="38.686" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CA"/>
+ <chemical_shift value="53.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="N"/>
+ <chemical_shift value="113.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="H"/>
+ <chemical_shift value="8.004" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="202" name="HZ1"/>
+ <atom segid=" A" residue="202" name="HZ2"/>
+ <atom segid=" A" residue="202" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CB"/>
+ <chemical_shift value="27.266" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="C"/>
+ <chemical_shift value="175.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="H"/>
+ <chemical_shift value="7.932" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CA"/>
+ <chemical_shift value="57.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="N"/>
+ <chemical_shift value="111.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="C"/>
+ <chemical_shift value="175.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CB"/>
+ <chemical_shift value="28.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CA"/>
+ <chemical_shift value="57.268" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="N"/>
+ <chemical_shift value="116.235" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="H"/>
+ <chemical_shift value="8.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="204" name="HE1"/>
+ <atom segid=" A" residue="204" name="HE2"/>
+ <atom segid=" A" residue="204" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="C"/>
+ <chemical_shift value="173.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CB"/>
+ <chemical_shift value="37.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CA"/>
+ <chemical_shift value="54.646" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="N"/>
+ <chemical_shift value="114.03" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="H"/>
+ <chemical_shift value="7.477" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="C"/>
+ <chemical_shift value="176.088" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CB"/>
+ <chemical_shift value="40.287" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CA"/>
+ <chemical_shift value="52.185" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="N"/>
+ <chemical_shift value="118.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="H"/>
+ <chemical_shift value="8.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="206" name="HB1"/>
+ <atom segid=" A" residue="206" name="HB2"/>
+ <atom segid=" A" residue="206" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="C"/>
+ <chemical_shift value="176.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="CB"/>
+ <chemical_shift value="18.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="CA"/>
+ <chemical_shift value="54.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="N"/>
+ <chemical_shift value="125.067" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="H"/>
+ <chemical_shift value="9.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="C"/>
+ <chemical_shift value="176.539" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CB"/>
+ <chemical_shift value="39.943" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CA"/>
+ <chemical_shift value="53.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="N"/>
+ <chemical_shift value="112.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="H"/>
+ <chemical_shift value="8.172" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="208" name="HG21"/>
+ <atom segid=" A" residue="208" name="HG22"/>
+ <atom segid=" A" residue="208" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="C"/>
+ <chemical_shift value="173.305" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CB"/>
+ <chemical_shift value="69.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CA"/>
+ <chemical_shift value="66.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="N"/>
+ <chemical_shift value="116.637" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="H"/>
+ <chemical_shift value="7.344" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="C"/>
+ <chemical_shift value="175.818" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CB"/>
+ <chemical_shift value="42.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CA"/>
+ <chemical_shift value="51.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="N"/>
+ <chemical_shift value="130.935" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="H"/>
+ <chemical_shift value="6.982" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="210" name="HD1"/>
+ <atom segid=" A" residue="210" name="HD2"/>
+ <atom segid=" A" residue="210" name="HE1"/>
+ <atom segid=" A" residue="210" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="C"/>
+ <chemical_shift value="178.37" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CB"/>
+ <chemical_shift value="39.077" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CA"/>
+ <chemical_shift value="63.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="N"/>
+ <chemical_shift value="117.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="H"/>
+ <chemical_shift value="7.858" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="C"/>
+ <chemical_shift value="177.629" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="CB"/>
+ <chemical_shift value="63.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="CA"/>
+ <chemical_shift value="61.419" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="N"/>
+ <chemical_shift value="114.682" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="H"/>
+ <chemical_shift value="8.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="212" name="HG21"/>
+ <atom segid=" A" residue="212" name="HG22"/>
+ <atom segid=" A" residue="212" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.867" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="212" name="HD11"/>
+ <atom segid=" A" residue="212" name="HD12"/>
+ <atom segid=" A" residue="212" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="C"/>
+ <chemical_shift value="179.021" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CB"/>
+ <chemical_shift value="38.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CA"/>
+ <chemical_shift value="65.023" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="N"/>
+ <chemical_shift value="124.45" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CD1"/>
+ <chemical_shift value="13.11" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="H"/>
+ <chemical_shift value="8.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="213" name="HB1"/>
+ <atom segid=" A" residue="213" name="HB2"/>
+ <atom segid=" A" residue="213" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="C"/>
+ <chemical_shift value="177.865" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="CB"/>
+ <chemical_shift value="17.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="CA"/>
+ <chemical_shift value="55.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="N"/>
+ <chemical_shift value="120.747" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="H"/>
+ <chemical_shift value="7.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="C"/>
+ <chemical_shift value="178.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CB"/>
+ <chemical_shift value="29.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CA"/>
+ <chemical_shift value="58.941" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="N"/>
+ <chemical_shift value="117.551" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="215" name="HB1"/>
+ <atom segid=" A" residue="215" name="HB2"/>
+ <atom segid=" A" residue="215" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="C"/>
+ <chemical_shift value="179.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="CB"/>
+ <chemical_shift value="18.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="CA"/>
+ <chemical_shift value="54.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="N"/>
+ <chemical_shift value="119.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="H"/>
+ <chemical_shift value="7.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="216" name="HB1"/>
+ <atom segid=" A" residue="216" name="HB2"/>
+ <atom segid=" A" residue="216" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="C"/>
+ <chemical_shift value="180.736" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="CB"/>
+ <chemical_shift value="19.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="CA"/>
+ <chemical_shift value="55.247" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="N"/>
+ <chemical_shift value="117.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="H"/>
+ <chemical_shift value="7.789" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="217" name="HD1"/>
+ <atom segid=" A" residue="217" name="HD2"/>
+ <atom segid=" A" residue="217" name="HE1"/>
+ <atom segid=" A" residue="217" name="HE2"/>
+ <atom segid=" A" residue="217" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CB"/>
+ <chemical_shift value="38.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CA"/>
+ <chemical_shift value="62.919" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="N"/>
+ <chemical_shift value="119.446" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="H"/>
+ <chemical_shift value="8.338" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="C"/>
+ <chemical_shift value="176.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CB"/>
+ <chemical_shift value="36.484" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CA"/>
+ <chemical_shift value="55.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="219" name="HZ1"/>
+ <atom segid=" A" residue="219" name="HZ2"/>
+ <atom segid=" A" residue="219" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CB"/>
+ <chemical_shift value="32.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="C"/>
+ <chemical_shift value="177.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="H"/>
+ <chemical_shift value="7.713" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CA"/>
+ <chemical_shift value="56.131" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="N"/>
+ <chemical_shift value="116.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="C"/>
+ <chemical_shift value="175.309" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="H"/>
+ <chemical_shift value="7.717" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="CA"/>
+ <chemical_shift value="46.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="N"/>
+ <chemical_shift value="108.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="C"/>
+ <chemical_shift value="175.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CB"/>
+ <chemical_shift value="30.469" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CA"/>
+ <chemical_shift value="57.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="N"/>
+ <chemical_shift value="116.369" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="H"/>
+ <chemical_shift value="8.382" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="222" name="HG21"/>
+ <atom segid=" A" residue="222" name="HG22"/>
+ <atom segid=" A" residue="222" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="C"/>
+ <chemical_shift value="172.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CB"/>
+ <chemical_shift value="70.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CA"/>
+ <chemical_shift value="58.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="N"/>
+ <chemical_shift value="110.551" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="H"/>
+ <chemical_shift value="6.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="223" name="HB1"/>
+ <atom segid=" A" residue="223" name="HB2"/>
+ <atom segid=" A" residue="223" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="C"/>
+ <chemical_shift value="176.461" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="CB"/>
+ <chemical_shift value="20.427" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="CA"/>
+ <chemical_shift value="54.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="N"/>
+ <chemical_shift value="127.376" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="H"/>
+ <chemical_shift value="8.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="224" name="HE1"/>
+ <atom segid=" A" residue="224" name="HE2"/>
+ <atom segid=" A" residue="224" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="C"/>
+ <chemical_shift value="173.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CB"/>
+ <chemical_shift value="40.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CA"/>
+ <chemical_shift value="54.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="N"/>
+ <chemical_shift value="114.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="H"/>
+ <chemical_shift value="8.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="225" name="HG21"/>
+ <atom segid=" A" residue="225" name="HG22"/>
+ <atom segid=" A" residue="225" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="C"/>
+ <chemical_shift value="171.424" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CB"/>
+ <chemical_shift value="71.023" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CA"/>
+ <chemical_shift value="59.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="N"/>
+ <chemical_shift value="113.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="H"/>
+ <chemical_shift value="9.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="226" name="HG21"/>
+ <atom segid=" A" residue="226" name="HG22"/>
+ <atom segid=" A" residue="226" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.06" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="226" name="HD11"/>
+ <atom segid=" A" residue="226" name="HD12"/>
+ <atom segid=" A" residue="226" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.06" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="C"/>
+ <chemical_shift value="174.82" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CB"/>
+ <chemical_shift value="40.344" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CA"/>
+ <chemical_shift value="60.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="N"/>
+ <chemical_shift value="122.714" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CD1"/>
+ <chemical_shift value="11.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="H"/>
+ <chemical_shift value="7.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="C"/>
+ <chemical_shift value="175.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CB"/>
+ <chemical_shift value="42.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CA"/>
+ <chemical_shift value="52.466" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="N"/>
+ <chemical_shift value="121.906" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="H"/>
+ <chemical_shift value="8.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="H"/>
+ <chemical_shift value="8.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="CA"/>
+ <chemical_shift value="42.27" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="N"/>
+ <chemical_shift value="110.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CB"/>
+ <chemical_shift value="29.552" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CA"/>
+ <chemical_shift value="62.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="H"/>
+ <chemical_shift value="5.923" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CB"/>
+ <chemical_shift value="26.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CA"/>
+ <chemical_shift value="59.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="N"/>
+ <chemical_shift value="111.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="231" name="HB1"/>
+ <atom segid=" A" residue="231" name="HB2"/>
+ <atom segid=" A" residue="231" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="CB"/>
+ <chemical_shift value="19.11" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="CA"/>
+ <chemical_shift value="52.168" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="N"/>
+ <chemical_shift value="125.512" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="H"/>
+ <chemical_shift value="6.975" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="H"/>
+ <chemical_shift value="7.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CB"/>
+ <chemical_shift value="28.673" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CA"/>
+ <chemical_shift value="58.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="N"/>
+ <chemical_shift value="118.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="235" name="HG21"/>
+ <atom segid=" A" residue="235" name="HG22"/>
+ <atom segid=" A" residue="235" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="235" name="HD11"/>
+ <atom segid=" A" residue="235" name="HD12"/>
+ <atom segid=" A" residue="235" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="237" name="HG21"/>
+ <atom segid=" A" residue="237" name="HG22"/>
+ <atom segid=" A" residue="237" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="239" name="HZ1"/>
+ <atom segid=" A" residue="239" name="HZ2"/>
+ <atom segid=" A" residue="239" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="240" name="HG21"/>
+ <atom segid=" A" residue="240" name="HG22"/>
+ <atom segid=" A" residue="240" name="HG23"/>
+ <atom segid=" A" residue="240" name="HG11"/>
+ <atom segid=" A" residue="240" name="HG12"/>
+ <atom segid=" A" residue="240" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CB"/>
+ <chemical_shift value="37.371" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="242" name="HD1"/>
+ <atom segid=" A" residue="242" name="HD2"/>
+ <atom segid=" A" residue="242" name="HE1"/>
+ <atom segid=" A" residue="242" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="C"/>
+ <chemical_shift value="174.489" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CB"/>
+ <chemical_shift value="41.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CA"/>
+ <chemical_shift value="54.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="N"/>
+ <chemical_shift value="121.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="C"/>
+ <chemical_shift value="171.154" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="H"/>
+ <chemical_shift value="8.494" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="CA"/>
+ <chemical_shift value="42.935" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="N"/>
+ <chemical_shift value="107.501" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="244" name="HG21"/>
+ <atom segid=" A" residue="244" name="HG22"/>
+ <atom segid=" A" residue="244" name="HG23"/>
+ <chemical_shift value="0.636" error="0.0"/>
+ <chemical_shift value="1.072" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="244" name="HG11"/>
+ <atom segid=" A" residue="244" name="HG12"/>
+ <atom segid=" A" residue="244" name="HG13"/>
+ <chemical_shift value="0.636" error="0.0"/>
+ <chemical_shift value="1.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="C"/>
+ <chemical_shift value="174.872" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CB"/>
+ <chemical_shift value="34.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CA"/>
+ <chemical_shift value="61.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="N"/>
+ <chemical_shift value="120.896" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CG1"/>
+ <chemical_shift value="22.083" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="H"/>
+ <chemical_shift value="8.229" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CG2"/>
+ <chemical_shift value="21.606" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="245" name="HG21"/>
+ <atom segid=" A" residue="245" name="HG22"/>
+ <atom segid=" A" residue="245" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="C"/>
+ <chemical_shift value="174.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CB"/>
+ <chemical_shift value="71.559" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CA"/>
+ <chemical_shift value="59.071" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="N"/>
+ <chemical_shift value="119.808" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="H"/>
+ <chemical_shift value="9.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="246" name="HG21"/>
+ <atom segid=" A" residue="246" name="HG22"/>
+ <atom segid=" A" residue="246" name="HG23"/>
+ <chemical_shift value="0.983" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="246" name="HG11"/>
+ <atom segid=" A" residue="246" name="HG12"/>
+ <atom segid=" A" residue="246" name="HG13"/>
+ <chemical_shift value="0.983" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="C"/>
+ <chemical_shift value="175.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CB"/>
+ <chemical_shift value="32.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CA"/>
+ <chemical_shift value="62.433" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="N"/>
+ <chemical_shift value="123.607" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CG1"/>
+ <chemical_shift value="20.441" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CG2"/>
+ <chemical_shift value="21.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="247" name="HD21"/>
+ <atom segid=" A" residue="247" name="HD22"/>
+ <atom segid=" A" residue="247" name="HD23"/>
+ <chemical_shift value="0.645" error="0.0"/>
+ <chemical_shift value="0.663" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="247" name="HD11"/>
+ <atom segid=" A" residue="247" name="HD12"/>
+ <atom segid=" A" residue="247" name="HD13"/>
+ <chemical_shift value="0.645" error="0.0"/>
+ <chemical_shift value="0.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CB"/>
+ <chemical_shift value="40.229" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CA"/>
+ <chemical_shift value="54.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="N"/>
+ <chemical_shift value="125.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CD1"/>
+ <chemical_shift value="25.833" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CD2"/>
+ <chemical_shift value="23.824" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="H"/>
+ <chemical_shift value="8.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="C"/>
+ <chemical_shift value="175.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CB"/>
+ <chemical_shift value="30.183" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CA"/>
+ <chemical_shift value="61.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="249" name="HG21"/>
+ <atom segid=" A" residue="249" name="HG22"/>
+ <atom segid=" A" residue="249" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="C"/>
+ <chemical_shift value="174.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CB"/>
+ <chemical_shift value="71.441" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CA"/>
+ <chemical_shift value="61.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="N"/>
+ <chemical_shift value="111.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="H"/>
+ <chemical_shift value="8.815" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="250" name="HD1"/>
+ <atom segid=" A" residue="250" name="HD2"/>
+ <atom segid=" A" residue="250" name="HE1"/>
+ <atom segid=" A" residue="250" name="HE2"/>
+ <atom segid=" A" residue="250" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="C"/>
+ <chemical_shift value="174.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CB"/>
+ <chemical_shift value="41.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CA"/>
+ <chemical_shift value="56.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="N"/>
+ <chemical_shift value="121.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="H"/>
+ <chemical_shift value="9.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="251" name="HZ1"/>
+ <atom segid=" A" residue="251" name="HZ2"/>
+ <atom segid=" A" residue="251" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CB"/>
+ <chemical_shift value="28.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="C"/>
+ <chemical_shift value="177.723" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="H"/>
+ <chemical_shift value="10.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CA"/>
+ <chemical_shift value="57.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="N"/>
+ <chemical_shift value="129.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="C"/>
+ <chemical_shift value="173.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="H"/>
+ <chemical_shift value="9.031" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="CA"/>
+ <chemical_shift value="45.086" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="N"/>
+ <chemical_shift value="103.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CB"/>
+ <chemical_shift value="29.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CA"/>
+ <chemical_shift value="52.486" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="N"/>
+ <chemical_shift value="122.357" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="H"/>
+ <chemical_shift value="8.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="C"/>
+ <chemical_shift value="178.676" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CB"/>
+ <chemical_shift value="31.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CA"/>
+ <chemical_shift value="62.977" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="C"/>
+ <chemical_shift value="173.658" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="CB"/>
+ <chemical_shift value="64.942" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="CA"/>
+ <chemical_shift value="62.323" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="N"/>
+ <chemical_shift value="117.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="H"/>
+ <chemical_shift value="8.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="256" name="HZ1"/>
+ <atom segid=" A" residue="256" name="HZ2"/>
+ <atom segid=" A" residue="256" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CB"/>
+ <chemical_shift value="33.307" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="H"/>
+ <chemical_shift value="7.639" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CA"/>
+ <chemical_shift value="53.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="N"/>
+ <chemical_shift value="123.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="C"/>
+ <chemical_shift value="177.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CB"/>
+ <chemical_shift value="31.379" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CA"/>
+ <chemical_shift value="62.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="258" name="HD1"/>
+ <atom segid=" A" residue="258" name="HD2"/>
+ <atom segid=" A" residue="258" name="HE1"/>
+ <atom segid=" A" residue="258" name="HE2"/>
+ <atom segid=" A" residue="258" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="C"/>
+ <chemical_shift value="177.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CB"/>
+ <chemical_shift value="40.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CA"/>
+ <chemical_shift value="58.534" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="N"/>
+ <chemical_shift value="118.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="H"/>
+ <chemical_shift value="9.265" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="259" name="HG21"/>
+ <atom segid=" A" residue="259" name="HG22"/>
+ <atom segid=" A" residue="259" name="HG23"/>
+ <chemical_shift value="0.98" error="0.0"/>
+ <chemical_shift value="0.925" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="259" name="HG11"/>
+ <atom segid=" A" residue="259" name="HG12"/>
+ <atom segid=" A" residue="259" name="HG13"/>
+ <chemical_shift value="0.98" error="0.0"/>
+ <chemical_shift value="0.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="C"/>
+ <chemical_shift value="176.569" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CB"/>
+ <chemical_shift value="33.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CA"/>
+ <chemical_shift value="62.078" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="N"/>
+ <chemical_shift value="121.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CG1"/>
+ <chemical_shift value="21.509" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="H"/>
+ <chemical_shift value="8.777" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CG2"/>
+ <chemical_shift value="22.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="C"/>
+ <chemical_shift value="171.463" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="H"/>
+ <chemical_shift value="8.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="CA"/>
+ <chemical_shift value="44.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="N"/>
+ <chemical_shift value="116.16" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="261" name="HG21"/>
+ <atom segid=" A" residue="261" name="HG22"/>
+ <atom segid=" A" residue="261" name="HG23"/>
+ <chemical_shift value="0.565" error="0.0"/>
+ <chemical_shift value="0.679" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="261" name="HG11"/>
+ <atom segid=" A" residue="261" name="HG12"/>
+ <atom segid=" A" residue="261" name="HG13"/>
+ <chemical_shift value="0.565" error="0.0"/>
+ <chemical_shift value="0.679" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="C"/>
+ <chemical_shift value="179.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CB"/>
+ <chemical_shift value="32.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CA"/>
+ <chemical_shift value="60.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="N"/>
+ <chemical_shift value="128.971" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CG1"/>
+ <chemical_shift value="20.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="H"/>
+ <chemical_shift value="11.175" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CG2"/>
+ <chemical_shift value="20.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="262" name="HD21"/>
+ <atom segid=" A" residue="262" name="HD22"/>
+ <atom segid=" A" residue="262" name="HD23"/>
+ <chemical_shift value="0.885" error="0.0"/>
+ <chemical_shift value="0.806" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="262" name="HD11"/>
+ <atom segid=" A" residue="262" name="HD12"/>
+ <atom segid=" A" residue="262" name="HD13"/>
+ <chemical_shift value="0.885" error="0.0"/>
+ <chemical_shift value="0.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="C"/>
+ <chemical_shift value="175.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CB"/>
+ <chemical_shift value="41.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CA"/>
+ <chemical_shift value="56.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="N"/>
+ <chemical_shift value="134.056" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CD1"/>
+ <chemical_shift value="22.681" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CD2"/>
+ <chemical_shift value="25.314" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="H"/>
+ <chemical_shift value="8.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="C"/>
+ <chemical_shift value="170.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="CB"/>
+ <chemical_shift value="66.154" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="CA"/>
+ <chemical_shift value="58.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="N"/>
+ <chemical_shift value="126.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="H"/>
+ <chemical_shift value="8.77" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="264" name="HB1"/>
+ <atom segid=" A" residue="264" name="HB2"/>
+ <atom segid=" A" residue="264" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="C"/>
+ <chemical_shift value="176.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="CB"/>
+ <chemical_shift value="20.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="CA"/>
+ <chemical_shift value="49.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="N"/>
+ <chemical_shift value="123.788" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="H"/>
+ <chemical_shift value="9.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="C"/>
+ <chemical_shift value="171.119" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="H"/>
+ <chemical_shift value="9.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="CA"/>
+ <chemical_shift value="42.908" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="N"/>
+ <chemical_shift value="110.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="266" name="HG21"/>
+ <atom segid=" A" residue="266" name="HG22"/>
+ <atom segid=" A" residue="266" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.915" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="266" name="HD11"/>
+ <atom segid=" A" residue="266" name="HD12"/>
+ <atom segid=" A" residue="266" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.915" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="C"/>
+ <chemical_shift value="175.264" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CB"/>
+ <chemical_shift value="39.519" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CA"/>
+ <chemical_shift value="59.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="N"/>
+ <chemical_shift value="123.632" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CD1"/>
+ <chemical_shift value="13.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="H"/>
+ <chemical_shift value="10.299" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="C"/>
+ <chemical_shift value="177.436" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CB"/>
+ <chemical_shift value="38.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CA"/>
+ <chemical_shift value="53.657" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="N"/>
+ <chemical_shift value="125.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="H"/>
+ <chemical_shift value="8.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="268" name="HB1"/>
+ <atom segid=" A" residue="268" name="HB2"/>
+ <atom segid=" A" residue="268" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="C"/>
+ <chemical_shift value="178.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="CB"/>
+ <chemical_shift value="17.854" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="CA"/>
+ <chemical_shift value="55.511" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="N"/>
+ <chemical_shift value="131.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="H"/>
+ <chemical_shift value="8.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="269" name="HB1"/>
+ <atom segid=" A" residue="269" name="HB2"/>
+ <atom segid=" A" residue="269" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="C"/>
+ <chemical_shift value="178.117" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="CB"/>
+ <chemical_shift value="18.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="CA"/>
+ <chemical_shift value="51.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="N"/>
+ <chemical_shift value="117.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="CB"/>
+ <chemical_shift value="64.366" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="CA"/>
+ <chemical_shift value="56.356" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="N"/>
+ <chemical_shift value="112.93" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="H"/>
+ <chemical_shift value="7.621" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="270" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="C"/>
+ <chemical_shift value="175.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CB"/>
+ <chemical_shift value="30.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CA"/>
+ <chemical_shift value="63.726" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="271" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="C"/>
+ <chemical_shift value="176.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CB"/>
+ <chemical_shift value="40.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CA"/>
+ <chemical_shift value="52.889" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="N"/>
+ <chemical_shift value="119.716" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="H"/>
+ <chemical_shift value="8.881" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="272" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="273" name="HZ1"/>
+ <atom segid=" A" residue="273" name="HZ2"/>
+ <atom segid=" A" residue="273" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CB"/>
+ <chemical_shift value="31.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="C"/>
+ <chemical_shift value="179.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="H"/>
+ <chemical_shift value="7.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CA"/>
+ <chemical_shift value="61.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="N"/>
+ <chemical_shift value="119.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="273" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="C"/>
+ <chemical_shift value="179.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CB"/>
+ <chemical_shift value="27.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CA"/>
+ <chemical_shift value="59.973" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="N"/>
+ <chemical_shift value="118.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="H"/>
+ <chemical_shift value="8.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="274" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="275" name="HD21"/>
+ <atom segid=" A" residue="275" name="HD22"/>
+ <atom segid=" A" residue="275" name="HD23"/>
+ <chemical_shift value="0.947" error="0.0"/>
+ <chemical_shift value="0.933" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="275" name="HD11"/>
+ <atom segid=" A" residue="275" name="HD12"/>
+ <atom segid=" A" residue="275" name="HD13"/>
+ <chemical_shift value="0.947" error="0.0"/>
+ <chemical_shift value="0.933" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="C"/>
+ <chemical_shift value="178.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CB"/>
+ <chemical_shift value="42.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CA"/>
+ <chemical_shift value="57.369" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="N"/>
+ <chemical_shift value="120.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CD1"/>
+ <chemical_shift value="25.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="CD2"/>
+ <chemical_shift value="22.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="H"/>
+ <chemical_shift value="7.385" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="275" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="276" name="HB1"/>
+ <atom segid=" A" residue="276" name="HB2"/>
+ <atom segid=" A" residue="276" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="C"/>
+ <chemical_shift value="178.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="CB"/>
+ <chemical_shift value="17.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="CA"/>
+ <chemical_shift value="55.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="N"/>
+ <chemical_shift value="120.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="H"/>
+ <chemical_shift value="8.405" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="276" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="277" name="HZ1"/>
+ <atom segid=" A" residue="277" name="HZ2"/>
+ <atom segid=" A" residue="277" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CB"/>
+ <chemical_shift value="32.345" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="C"/>
+ <chemical_shift value="177.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="H"/>
+ <chemical_shift value="7.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CA"/>
+ <chemical_shift value="60.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="N"/>
+ <chemical_shift value="118.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="277" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="C"/>
+ <chemical_shift value="179.24" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CB"/>
+ <chemical_shift value="29.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CA"/>
+ <chemical_shift value="59.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="N"/>
+ <chemical_shift value="118.647" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="H"/>
+ <chemical_shift value="7.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="278" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="279" name="HD1"/>
+ <atom segid=" A" residue="279" name="HD2"/>
+ <atom segid=" A" residue="279" name="HE1"/>
+ <atom segid=" A" residue="279" name="HE2"/>
+ <atom segid=" A" residue="279" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="C"/>
+ <chemical_shift value="177.602" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CB"/>
+ <chemical_shift value="38.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CA"/>
+ <chemical_shift value="61.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="N"/>
+ <chemical_shift value="118.378" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="279" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="280" name="HD21"/>
+ <atom segid=" A" residue="280" name="HD22"/>
+ <atom segid=" A" residue="280" name="HD23"/>
+ <chemical_shift value="0.71" error="0.0"/>
+ <chemical_shift value="0.672" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="280" name="HD11"/>
+ <atom segid=" A" residue="280" name="HD12"/>
+ <atom segid=" A" residue="280" name="HD13"/>
+ <chemical_shift value="0.71" error="0.0"/>
+ <chemical_shift value="0.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="C"/>
+ <chemical_shift value="177.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CB"/>
+ <chemical_shift value="40.671" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CA"/>
+ <chemical_shift value="58.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="N"/>
+ <chemical_shift value="120.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CD1"/>
+ <chemical_shift value="25.779" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="CD2"/>
+ <chemical_shift value="23.405" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="H"/>
+ <chemical_shift value="8.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="280" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="C"/>
+ <chemical_shift value="177.096" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CB"/>
+ <chemical_shift value="29.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CA"/>
+ <chemical_shift value="59.622" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="N"/>
+ <chemical_shift value="112.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="H"/>
+ <chemical_shift value="8.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="281" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="C"/>
+ <chemical_shift value="175.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CB"/>
+ <chemical_shift value="38.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CA"/>
+ <chemical_shift value="53.164" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="N"/>
+ <chemical_shift value="108.811" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="H"/>
+ <chemical_shift value="7.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="282" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="283" name="HD1"/>
+ <atom segid=" A" residue="283" name="HD2"/>
+ <atom segid=" A" residue="283" name="HE1"/>
+ <atom segid=" A" residue="283" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="C"/>
+ <chemical_shift value="176.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CB"/>
+ <chemical_shift value="38.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CA"/>
+ <chemical_shift value="59.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="N"/>
+ <chemical_shift value="116.373" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="H"/>
+ <chemical_shift value="7.164" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="283" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="284" name="HD21"/>
+ <atom segid=" A" residue="284" name="HD22"/>
+ <atom segid=" A" residue="284" name="HD23"/>
+ <chemical_shift value="1.039" error="0.0"/>
+ <chemical_shift value="0.843" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="284" name="HD11"/>
+ <atom segid=" A" residue="284" name="HD12"/>
+ <atom segid=" A" residue="284" name="HD13"/>
+ <chemical_shift value="1.039" error="0.0"/>
+ <chemical_shift value="0.843" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="C"/>
+ <chemical_shift value="176.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CB"/>
+ <chemical_shift value="41.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CA"/>
+ <chemical_shift value="58.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="N"/>
+ <chemical_shift value="121.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CD1"/>
+ <chemical_shift value="23.945" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="CD2"/>
+ <chemical_shift value="27.398" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="H"/>
+ <chemical_shift value="8.101" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="284" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="285" name="HD21"/>
+ <atom segid=" A" residue="285" name="HD22"/>
+ <atom segid=" A" residue="285" name="HD23"/>
+ <chemical_shift value="1.119" error="0.0"/>
+ <chemical_shift value="1.052" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="285" name="HD11"/>
+ <atom segid=" A" residue="285" name="HD12"/>
+ <atom segid=" A" residue="285" name="HD13"/>
+ <chemical_shift value="1.119" error="0.0"/>
+ <chemical_shift value="1.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="C"/>
+ <chemical_shift value="174.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CB"/>
+ <chemical_shift value="38.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CA"/>
+ <chemical_shift value="54.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="N"/>
+ <chemical_shift value="119.204" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CD1"/>
+ <chemical_shift value="25.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="CD2"/>
+ <chemical_shift value="24.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="H"/>
+ <chemical_shift value="7.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="285" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="286" name="HG21"/>
+ <atom segid=" A" residue="286" name="HG22"/>
+ <atom segid=" A" residue="286" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="C"/>
+ <chemical_shift value="174.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CB"/>
+ <chemical_shift value="73.569" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CA"/>
+ <chemical_shift value="59.007" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="N"/>
+ <chemical_shift value="108.713" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="H"/>
+ <chemical_shift value="8.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="286" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="C"/>
+ <chemical_shift value="177.87" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CB"/>
+ <chemical_shift value="39.534" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CA"/>
+ <chemical_shift value="58.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="N"/>
+ <chemical_shift value="122.217" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="H"/>
+ <chemical_shift value="8.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="287" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="C"/>
+ <chemical_shift value="180.161" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CB"/>
+ <chemical_shift value="29.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CA"/>
+ <chemical_shift value="59.339" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="N"/>
+ <chemical_shift value="115.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="H"/>
+ <chemical_shift value="8.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="288" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="C"/>
+ <chemical_shift value="175.256" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="H"/>
+ <chemical_shift value="8.328" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="CA"/>
+ <chemical_shift value="46.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="N"/>
+ <chemical_shift value="112.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="289" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="290" name="HD21"/>
+ <atom segid=" A" residue="290" name="HD22"/>
+ <atom segid=" A" residue="290" name="HD23"/>
+ <chemical_shift value="0.792" error="0.0"/>
+ <chemical_shift value="1.074" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="290" name="HD11"/>
+ <atom segid=" A" residue="290" name="HD12"/>
+ <atom segid=" A" residue="290" name="HD13"/>
+ <chemical_shift value="0.792" error="0.0"/>
+ <chemical_shift value="1.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="C"/>
+ <chemical_shift value="179.873" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CB"/>
+ <chemical_shift value="41.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CA"/>
+ <chemical_shift value="57.262" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="N"/>
+ <chemical_shift value="119.553" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CD1"/>
+ <chemical_shift value="27.886" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="CD2"/>
+ <chemical_shift value="21.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="H"/>
+ <chemical_shift value="8.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="290" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="C"/>
+ <chemical_shift value="178.136" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CB"/>
+ <chemical_shift value="29.033" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CA"/>
+ <chemical_shift value="59.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="N"/>
+ <chemical_shift value="120.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="H"/>
+ <chemical_shift value="7.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="291" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="292" name="HB1"/>
+ <atom segid=" A" residue="292" name="HB2"/>
+ <atom segid=" A" residue="292" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="C"/>
+ <chemical_shift value="180.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="CB"/>
+ <chemical_shift value="17.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="CA"/>
+ <chemical_shift value="55.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="N"/>
+ <chemical_shift value="119.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="H"/>
+ <chemical_shift value="7.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="292" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="293" name="HG21"/>
+ <atom segid=" A" residue="293" name="HG22"/>
+ <atom segid=" A" residue="293" name="HG23"/>
+ <chemical_shift value="0.901" error="0.0"/>
+ <chemical_shift value="1.004" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="293" name="HG11"/>
+ <atom segid=" A" residue="293" name="HG12"/>
+ <atom segid=" A" residue="293" name="HG13"/>
+ <chemical_shift value="0.901" error="0.0"/>
+ <chemical_shift value="1.004" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="C"/>
+ <chemical_shift value="177.079" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CB"/>
+ <chemical_shift value="32.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CA"/>
+ <chemical_shift value="67.318" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="N"/>
+ <chemical_shift value="115.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CG1"/>
+ <chemical_shift value="21.422" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="H"/>
+ <chemical_shift value="7.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="293" name="CG2"/>
+ <chemical_shift value="22.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="C"/>
+ <chemical_shift value="176.45" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CB"/>
+ <chemical_shift value="40.911" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CA"/>
+ <chemical_shift value="56.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="N"/>
+ <chemical_shift value="117.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="H"/>
+ <chemical_shift value="8.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="294" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="295" name="HZ1"/>
+ <atom segid=" A" residue="295" name="HZ2"/>
+ <atom segid=" A" residue="295" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CB"/>
+ <chemical_shift value="31.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="C"/>
+ <chemical_shift value="177.444" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CA"/>
+ <chemical_shift value="58.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="N"/>
+ <chemical_shift value="115.927" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="295" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="C"/>
+ <chemical_shift value="176.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CB"/>
+ <chemical_shift value="41.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CA"/>
+ <chemical_shift value="56.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="N"/>
+ <chemical_shift value="118.991" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="H"/>
+ <chemical_shift value="7.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="296" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="297" name="HZ1"/>
+ <atom segid=" A" residue="297" name="HZ2"/>
+ <atom segid=" A" residue="297" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CB"/>
+ <chemical_shift value="34.952" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="H"/>
+ <chemical_shift value="7.654" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CA"/>
+ <chemical_shift value="52.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="N"/>
+ <chemical_shift value="115.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="297" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="C"/>
+ <chemical_shift value="178.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CB"/>
+ <chemical_shift value="31.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CA"/>
+ <chemical_shift value="63.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="298" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="299" name="HD22"/>
+ <atom segid=" A" residue="299" name="HD23"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="299" name="HD11"/>
+ <atom segid=" A" residue="299" name="HD12"/>
+ <atom segid=" A" residue="299" name="HD13"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="C"/>
+ <chemical_shift value="177.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CB"/>
+ <chemical_shift value="43.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CA"/>
+ <chemical_shift value="55.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="N"/>
+ <chemical_shift value="121.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="26.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="22.958" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="H"/>
+ <chemical_shift value="8.532" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="299" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="C"/>
+ <chemical_shift value="174.043" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="H"/>
+ <chemical_shift value="8.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="CA"/>
+ <chemical_shift value="44.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="N"/>
+ <chemical_shift value="103.351" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="300" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="301" name="HB1"/>
+ <atom segid=" A" residue="301" name="HB2"/>
+ <atom segid=" A" residue="301" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="C"/>
+ <chemical_shift value="177.667" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="CB"/>
+ <chemical_shift value="19.844" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="CA"/>
+ <chemical_shift value="51.558" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="N"/>
+ <chemical_shift value="123.834" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="H"/>
+ <chemical_shift value="7.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="301" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="302" name="HG21"/>
+ <atom segid=" A" residue="302" name="HG22"/>
+ <atom segid=" A" residue="302" name="HG23"/>
+ <chemical_shift value="1.262" error="0.0"/>
+ <chemical_shift value="1.059" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="302" name="HG11"/>
+ <atom segid=" A" residue="302" name="HG12"/>
+ <atom segid=" A" residue="302" name="HG13"/>
+ <chemical_shift value="1.262" error="0.0"/>
+ <chemical_shift value="1.059" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="C"/>
+ <chemical_shift value="174.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CB"/>
+ <chemical_shift value="35.614" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CA"/>
+ <chemical_shift value="59.9" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="N"/>
+ <chemical_shift value="110.163" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CG1"/>
+ <chemical_shift value="22.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="H"/>
+ <chemical_shift value="8.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="302" name="CG2"/>
+ <chemical_shift value="19.07" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="303" name="HB1"/>
+ <atom segid=" A" residue="303" name="HB2"/>
+ <atom segid=" A" residue="303" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="C"/>
+ <chemical_shift value="175.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="CB"/>
+ <chemical_shift value="19.491" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="CA"/>
+ <chemical_shift value="53.039" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="N"/>
+ <chemical_shift value="117.932" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="H"/>
+ <chemical_shift value="7.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="303" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
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+ <atom segid=" A" residue="304" name="HD22"/>
+ <atom segid=" A" residue="304" name="HD23"/>
+ <chemical_shift value="0.702" error="0.0"/>
+ <chemical_shift value="0.848" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="304" name="HD11"/>
+ <atom segid=" A" residue="304" name="HD12"/>
+ <atom segid=" A" residue="304" name="HD13"/>
+ <chemical_shift value="0.702" error="0.0"/>
+ <chemical_shift value="0.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="C"/>
+ <chemical_shift value="175.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CB"/>
+ <chemical_shift value="44.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CA"/>
+ <chemical_shift value="54.335" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="N"/>
+ <chemical_shift value="114.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CD1"/>
+ <chemical_shift value="24.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="CD2"/>
+ <chemical_shift value="26.586" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="H"/>
+ <chemical_shift value="6.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="304" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="305" name="HZ1"/>
+ <atom segid=" A" residue="305" name="HZ2"/>
+ <atom segid=" A" residue="305" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CB"/>
+ <chemical_shift value="31.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="C"/>
+ <chemical_shift value="178.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="H"/>
+ <chemical_shift value="8.043" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CA"/>
+ <chemical_shift value="60.428" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="N"/>
+ <chemical_shift value="129.631" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="305" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="C"/>
+ <chemical_shift value="176.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="CB"/>
+ <chemical_shift value="60.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="CA"/>
+ <chemical_shift value="61.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="N"/>
+ <chemical_shift value="111.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="H"/>
+ <chemical_shift value="8.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="306" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="307" name="HD1"/>
+ <atom segid=" A" residue="307" name="HD2"/>
+ <atom segid=" A" residue="307" name="HE1"/>
+ <atom segid=" A" residue="307" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="C"/>
+ <chemical_shift value="177.811" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CB"/>
+ <chemical_shift value="38.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CA"/>
+ <chemical_shift value="58.904" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="N"/>
+ <chemical_shift value="122.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="H"/>
+ <chemical_shift value="6.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="307" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="C"/>
+ <chemical_shift value="177.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CB"/>
+ <chemical_shift value="26.173" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CA"/>
+ <chemical_shift value="58.466" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="N"/>
+ <chemical_shift value="122.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="H"/>
+ <chemical_shift value="8.473" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="308" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="C"/>
+ <chemical_shift value="178.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CB"/>
+ <chemical_shift value="28.862" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CA"/>
+ <chemical_shift value="58.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="N"/>
+ <chemical_shift value="114.962" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="H"/>
+ <chemical_shift value="7.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="309" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="C"/>
+ <chemical_shift value="178.868" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CB"/>
+ <chemical_shift value="29.333" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CA"/>
+ <chemical_shift value="57.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="N"/>
+ <chemical_shift value="116.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="H"/>
+ <chemical_shift value="7.092" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="310" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="311" name="HD21"/>
+ <atom segid=" A" residue="311" name="HD22"/>
+ <atom segid=" A" residue="311" name="HD23"/>
+ <chemical_shift value="0.797" error="0.0"/>
+ <chemical_shift value="0.87" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="311" name="HD11"/>
+ <atom segid=" A" residue="311" name="HD12"/>
+ <atom segid=" A" residue="311" name="HD13"/>
+ <chemical_shift value="0.797" error="0.0"/>
+ <chemical_shift value="0.87" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="C"/>
+ <chemical_shift value="179.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CB"/>
+ <chemical_shift value="41.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CA"/>
+ <chemical_shift value="57.324" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="N"/>
+ <chemical_shift value="120.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CD1"/>
+ <chemical_shift value="26.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="CD2"/>
+ <chemical_shift value="22.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="H"/>
+ <chemical_shift value="8.021" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="311" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="312" name="HB1"/>
+ <atom segid=" A" residue="312" name="HB2"/>
+ <atom segid=" A" residue="312" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="C"/>
+ <chemical_shift value="174.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="CB"/>
+ <chemical_shift value="17.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="CA"/>
+ <chemical_shift value="54.037" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="N"/>
+ <chemical_shift value="114.676" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="H"/>
+ <chemical_shift value="8.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="312" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="313" name="HZ1"/>
+ <atom segid=" A" residue="313" name="HZ2"/>
+ <atom segid=" A" residue="313" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CB"/>
+ <chemical_shift value="31.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="C"/>
+ <chemical_shift value="177.97" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="H"/>
+ <chemical_shift value="6.992" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CA"/>
+ <chemical_shift value="58.418" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="N"/>
+ <chemical_shift value="119.315" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="313" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CB"/>
+ <chemical_shift value="41.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CA"/>
+ <chemical_shift value="50.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="N"/>
+ <chemical_shift value="121.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="H"/>
+ <chemical_shift value="8.311" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="314" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="C"/>
+ <chemical_shift value="179.227" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CB"/>
+ <chemical_shift value="32.168" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CA"/>
+ <chemical_shift value="64.525" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="315" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CB"/>
+ <chemical_shift value="29.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="C"/>
+ <chemical_shift value="179.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="H"/>
+ <chemical_shift value="8.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CA"/>
+ <chemical_shift value="58.813" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="N"/>
+ <chemical_shift value="116.913" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="316" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="317" name="HG21"/>
+ <atom segid=" A" residue="317" name="HG22"/>
+ <atom segid=" A" residue="317" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="1.118" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="317" name="HD11"/>
+ <atom segid=" A" residue="317" name="HD12"/>
+ <atom segid=" A" residue="317" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="1.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="C"/>
+ <chemical_shift value="178.067" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CB"/>
+ <chemical_shift value="35.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CA"/>
+ <chemical_shift value="64.418" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="N"/>
+ <chemical_shift value="123.536" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CD1"/>
+ <chemical_shift value="12.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="H"/>
+ <chemical_shift value="7.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="317" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="318" name="HB1"/>
+ <atom segid=" A" residue="318" name="HB2"/>
+ <atom segid=" A" residue="318" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="C"/>
+ <chemical_shift value="181.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="CB"/>
+ <chemical_shift value="17.268" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="CA"/>
+ <chemical_shift value="56.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="N"/>
+ <chemical_shift value="123.335" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="H"/>
+ <chemical_shift value="7.906" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="318" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="319" name="HB1"/>
+ <atom segid=" A" residue="319" name="HB2"/>
+ <atom segid=" A" residue="319" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="C"/>
+ <chemical_shift value="178.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="CB"/>
+ <chemical_shift value="17.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="CA"/>
+ <chemical_shift value="55.519" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="N"/>
+ <chemical_shift value="118.979" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="H"/>
+ <chemical_shift value="8.086" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="319" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="320" name="HG21"/>
+ <atom segid=" A" residue="320" name="HG22"/>
+ <atom segid=" A" residue="320" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="C"/>
+ <chemical_shift value="175.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="CB"/>
+ <chemical_shift value="69.151" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="CA"/>
+ <chemical_shift value="67.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="N"/>
+ <chemical_shift value="114.58" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="H"/>
+ <chemical_shift value="7.358" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="320" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="321" name="HE1"/>
+ <atom segid=" A" residue="321" name="HE2"/>
+ <atom segid=" A" residue="321" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="C"/>
+ <chemical_shift value="177.825" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CB"/>
+ <chemical_shift value="30.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CA"/>
+ <chemical_shift value="56.766" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="N"/>
+ <chemical_shift value="118.804" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="H"/>
+ <chemical_shift value="8.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="321" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="C"/>
+ <chemical_shift value="179.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CB"/>
+ <chemical_shift value="28.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CA"/>
+ <chemical_shift value="59.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="N"/>
+ <chemical_shift value="122.177" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="H"/>
+ <chemical_shift value="8.267" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="322" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="CB"/>
+ <chemical_shift value="39.313" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="CA"/>
+ <chemical_shift value="57.124" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="N"/>
+ <chemical_shift value="115.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="H"/>
+ <chemical_shift value="8.207" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="323" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="324" name="HB1"/>
+ <atom segid=" A" residue="324" name="HB2"/>
+ <atom segid=" A" residue="324" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="C"/>
+ <chemical_shift value="180.381" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="CB"/>
+ <chemical_shift value="17.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="CA"/>
+ <chemical_shift value="54.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="N"/>
+ <chemical_shift value="119.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="H"/>
+ <chemical_shift value="8.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="324" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="C"/>
+ <chemical_shift value="177.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CB"/>
+ <chemical_shift value="27.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CA"/>
+ <chemical_shift value="58.414" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="N"/>
+ <chemical_shift value="116.35" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="H"/>
+ <chemical_shift value="8.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="325" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="326" name="HZ1"/>
+ <atom segid=" A" residue="326" name="HZ2"/>
+ <atom segid=" A" residue="326" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CB"/>
+ <chemical_shift value="32.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="C"/>
+ <chemical_shift value="176.163" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="H"/>
+ <chemical_shift value="7.079" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CA"/>
+ <chemical_shift value="56.011" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="N"/>
+ <chemical_shift value="117.692" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="326" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="C"/>
+ <chemical_shift value="172.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="H"/>
+ <chemical_shift value="7.293" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="CA"/>
+ <chemical_shift value="44.518" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="N"/>
+ <chemical_shift value="106.636" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="327" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="C"/>
+ <chemical_shift value="176.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CB"/>
+ <chemical_shift value="32.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CA"/>
+ <chemical_shift value="54.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="N"/>
+ <chemical_shift value="121.098" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="H"/>
+ <chemical_shift value="8.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="328" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="329" name="HG21"/>
+ <atom segid=" A" residue="329" name="HG22"/>
+ <atom segid=" A" residue="329" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.821" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="329" name="HD11"/>
+ <atom segid=" A" residue="329" name="HD12"/>
+ <atom segid=" A" residue="329" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="C"/>
+ <chemical_shift value="178.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CB"/>
+ <chemical_shift value="37.812" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CA"/>
+ <chemical_shift value="62.15" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="N"/>
+ <chemical_shift value="127.522" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CD1"/>
+ <chemical_shift value="12.362" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="H"/>
+ <chemical_shift value="9.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="329" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="330" name="HE1"/>
+ <atom segid=" A" residue="330" name="HE2"/>
+ <atom segid=" A" residue="330" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CB"/>
+ <chemical_shift value="34.295" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CA"/>
+ <chemical_shift value="56.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="N"/>
+ <chemical_shift value="124.379" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="H"/>
+ <chemical_shift value="8.502" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="330" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="C"/>
+ <chemical_shift value="175.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CB"/>
+ <chemical_shift value="31.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CA"/>
+ <chemical_shift value="63.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="331" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="C"/>
+ <chemical_shift value="175.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CB"/>
+ <chemical_shift value="38.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CA"/>
+ <chemical_shift value="51.443" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="N"/>
+ <chemical_shift value="117.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="H"/>
+ <chemical_shift value="7.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="332" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="333" name="HG21"/>
+ <atom segid=" A" residue="333" name="HG22"/>
+ <atom segid=" A" residue="333" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="-0.138" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="333" name="HD11"/>
+ <atom segid=" A" residue="333" name="HD12"/>
+ <atom segid=" A" residue="333" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="-0.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CB"/>
+ <chemical_shift value="36.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CA"/>
+ <chemical_shift value="59.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="N"/>
+ <chemical_shift value="108.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CD1"/>
+ <chemical_shift value="12.253" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="H"/>
+ <chemical_shift value="6.382" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="333" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="C"/>
+ <chemical_shift value="178.686" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CB"/>
+ <chemical_shift value="31.199" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CA"/>
+ <chemical_shift value="65.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="334" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="C"/>
+ <chemical_shift value="177.018" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CB"/>
+ <chemical_shift value="26.389" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CA"/>
+ <chemical_shift value="59.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="N"/>
+ <chemical_shift value="116.31" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="335" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="336" name="HE1"/>
+ <atom segid=" A" residue="336" name="HE2"/>
+ <atom segid=" A" residue="336" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="C"/>
+ <chemical_shift value="177.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CB"/>
+ <chemical_shift value="30.289" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CA"/>
+ <chemical_shift value="56.084" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="N"/>
+ <chemical_shift value="118.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="H"/>
+ <chemical_shift value="7.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="336" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="C"/>
+ <chemical_shift value="177.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="CB"/>
+ <chemical_shift value="60.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="CA"/>
+ <chemical_shift value="62.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="N"/>
+ <chemical_shift value="113.543" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="H"/>
+ <chemical_shift value="7.924" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="337" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="338" name="HB1"/>
+ <atom segid=" A" residue="338" name="HB2"/>
+ <atom segid=" A" residue="338" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="C"/>
+ <chemical_shift value="180.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="CB"/>
+ <chemical_shift value="18.545" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="CA"/>
+ <chemical_shift value="54.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="N"/>
+ <chemical_shift value="122.856" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="H"/>
+ <chemical_shift value="7.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="338" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="339" name="HD1"/>
+ <atom segid=" A" residue="339" name="HD2"/>
+ <atom segid=" A" residue="339" name="HE1"/>
+ <atom segid=" A" residue="339" name="HE2"/>
+ <atom segid=" A" residue="339" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="C"/>
+ <chemical_shift value="176.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CB"/>
+ <chemical_shift value="38.827" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CA"/>
+ <chemical_shift value="61.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="N"/>
+ <chemical_shift value="118.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="H"/>
+ <chemical_shift value="7.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="339" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="H"/>
+ <chemical_shift value="8.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="C"/>
+ <chemical_shift value="179.128" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CB"/>
+ <chemical_shift value="30.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CA"/>
+ <chemical_shift value="59.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="N"/>
+ <chemical_shift value="118.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="340" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="341" name="HD1"/>
+ <atom segid=" A" residue="341" name="HD2"/>
+ <atom segid=" A" residue="341" name="HE1"/>
+ <atom segid=" A" residue="341" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="C"/>
+ <chemical_shift value="178.712" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CB"/>
+ <chemical_shift value="38.306" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CA"/>
+ <chemical_shift value="61.558" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="N"/>
+ <chemical_shift value="114.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="H"/>
+ <chemical_shift value="7.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="341" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="342" name="HB1"/>
+ <atom segid=" A" residue="342" name="HB2"/>
+ <atom segid=" A" residue="342" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="C"/>
+ <chemical_shift value="180.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="CB"/>
+ <chemical_shift value="19.012" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="CA"/>
+ <chemical_shift value="55.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="N"/>
+ <chemical_shift value="121.914" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="H"/>
+ <chemical_shift value="8.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="342" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="343" name="HG21"/>
+ <atom segid=" A" residue="343" name="HG22"/>
+ <atom segid=" A" residue="343" name="HG23"/>
+ <chemical_shift value="0.168" error="0.0"/>
+ <chemical_shift value="0.863" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="343" name="HG11"/>
+ <atom segid=" A" residue="343" name="HG12"/>
+ <atom segid=" A" residue="343" name="HG13"/>
+ <chemical_shift value="0.168" error="0.0"/>
+ <chemical_shift value="0.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="C"/>
+ <chemical_shift value="177.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CB"/>
+ <chemical_shift value="31.022" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CA"/>
+ <chemical_shift value="66.924" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="N"/>
+ <chemical_shift value="118.57" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CG1"/>
+ <chemical_shift value="21.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="H"/>
+ <chemical_shift value="8.63" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="343" name="CG2"/>
+ <chemical_shift value="23.236" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CB"/>
+ <chemical_shift value="29.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="C"/>
+ <chemical_shift value="178.506" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="H"/>
+ <chemical_shift value="8.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CA"/>
+ <chemical_shift value="60.236" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="N"/>
+ <chemical_shift value="120.769" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="344" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="345" name="HG21"/>
+ <atom segid=" A" residue="345" name="HG22"/>
+ <atom segid=" A" residue="345" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="C"/>
+ <chemical_shift value="175.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CB"/>
+ <chemical_shift value="69.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CA"/>
+ <chemical_shift value="66.564" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="N"/>
+ <chemical_shift value="113.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="H"/>
+ <chemical_shift value="7.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="345" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="346" name="HB1"/>
+ <atom segid=" A" residue="346" name="HB2"/>
+ <atom segid=" A" residue="346" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="C"/>
+ <chemical_shift value="179.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="CB"/>
+ <chemical_shift value="18.537" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="CA"/>
+ <chemical_shift value="55.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="N"/>
+ <chemical_shift value="122.933" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="H"/>
+ <chemical_shift value="7.805" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="346" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="347" name="HG21"/>
+ <atom segid=" A" residue="347" name="HG22"/>
+ <atom segid=" A" residue="347" name="HG23"/>
+ <chemical_shift value="1.043" error="0.0"/>
+ <chemical_shift value="0.918" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="347" name="HG11"/>
+ <atom segid=" A" residue="347" name="HG12"/>
+ <atom segid=" A" residue="347" name="HG13"/>
+ <chemical_shift value="1.043" error="0.0"/>
+ <chemical_shift value="0.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="C"/>
+ <chemical_shift value="178.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CB"/>
+ <chemical_shift value="31.336" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CA"/>
+ <chemical_shift value="67.494" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="N"/>
+ <chemical_shift value="115.988" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CG1"/>
+ <chemical_shift value="20.468" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="347" name="CG2"/>
+ <chemical_shift value="22.282" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="348" name="HG21"/>
+ <atom segid=" A" residue="348" name="HG22"/>
+ <atom segid=" A" residue="348" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.869" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="348" name="HD11"/>
+ <atom segid=" A" residue="348" name="HD12"/>
+ <atom segid=" A" residue="348" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.869" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="C"/>
+ <chemical_shift value="180.338" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CB"/>
+ <chemical_shift value="37.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CA"/>
+ <chemical_shift value="65.054" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="N"/>
+ <chemical_shift value="118.38" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CD1"/>
+ <chemical_shift value="12.965" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="H"/>
+ <chemical_shift value="7.771" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="348" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="C"/>
+ <chemical_shift value="178.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CB"/>
+ <chemical_shift value="37.166" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CA"/>
+ <chemical_shift value="55.948" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="N"/>
+ <chemical_shift value="121.103" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="H"/>
+ <chemical_shift value="8.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="349" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="350" name="HB1"/>
+ <atom segid=" A" residue="350" name="HB2"/>
+ <atom segid=" A" residue="350" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="C"/>
+ <chemical_shift value="181.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="CB"/>
+ <chemical_shift value="17.998" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="CA"/>
+ <chemical_shift value="54.159" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="N"/>
+ <chemical_shift value="122.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="H"/>
+ <chemical_shift value="8.52" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="350" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="351" name="HB1"/>
+ <atom segid=" A" residue="351" name="HB2"/>
+ <atom segid=" A" residue="351" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="C"/>
+ <chemical_shift value="178.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="CB"/>
+ <chemical_shift value="18.028" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="CA"/>
+ <chemical_shift value="55.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="N"/>
+ <chemical_shift value="121.112" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="H"/>
+ <chemical_shift value="9.165" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="351" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="C"/>
+ <chemical_shift value="175.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="CB"/>
+ <chemical_shift value="64.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="CA"/>
+ <chemical_shift value="58.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="N"/>
+ <chemical_shift value="107.997" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="H"/>
+ <chemical_shift value="7.88" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="352" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="C"/>
+ <chemical_shift value="174.546" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="H"/>
+ <chemical_shift value="7.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="CA"/>
+ <chemical_shift value="45.785" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="N"/>
+ <chemical_shift value="109.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="353" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CB"/>
+ <chemical_shift value="30.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="C"/>
+ <chemical_shift value="176.819" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="H"/>
+ <chemical_shift value="8.225" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CA"/>
+ <chemical_shift value="58.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="N"/>
+ <chemical_shift value="121.096" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="354" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="C"/>
+ <chemical_shift value="176.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CB"/>
+ <chemical_shift value="36.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CA"/>
+ <chemical_shift value="54.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="N"/>
+ <chemical_shift value="113.634" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="H"/>
+ <chemical_shift value="7.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="355" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="356" name="HG21"/>
+ <atom segid=" A" residue="356" name="HG22"/>
+ <atom segid=" A" residue="356" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="C"/>
+ <chemical_shift value="174.887" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CB"/>
+ <chemical_shift value="70.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CA"/>
+ <chemical_shift value="61.464" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="N"/>
+ <chemical_shift value="111.798" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="H"/>
+ <chemical_shift value="8.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="356" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="357" name="HG21"/>
+ <atom segid=" A" residue="357" name="HG22"/>
+ <atom segid=" A" residue="357" name="HG23"/>
+ <chemical_shift value="1.045" error="0.0"/>
+ <chemical_shift value="0.991" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="357" name="HG11"/>
+ <atom segid=" A" residue="357" name="HG12"/>
+ <atom segid=" A" residue="357" name="HG13"/>
+ <chemical_shift value="1.045" error="0.0"/>
+ <chemical_shift value="0.991" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="C"/>
+ <chemical_shift value="177.155" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CB"/>
+ <chemical_shift value="31.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CA"/>
+ <chemical_shift value="67.861" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="N"/>
+ <chemical_shift value="121.363" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CG1"/>
+ <chemical_shift value="21.315" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="H"/>
+ <chemical_shift value="8.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="357" name="CG2"/>
+ <chemical_shift value="23.401" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="C"/>
+ <chemical_shift value="178.907" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CB"/>
+ <chemical_shift value="40.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CA"/>
+ <chemical_shift value="57.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="N"/>
+ <chemical_shift value="115.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="H"/>
+ <chemical_shift value="8.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="358" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="C"/>
+ <chemical_shift value="178.618" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CB"/>
+ <chemical_shift value="29.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CA"/>
+ <chemical_shift value="58.759" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="N"/>
+ <chemical_shift value="118.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="H"/>
+ <chemical_shift value="7.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="359" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="360" name="HB1"/>
+ <atom segid=" A" residue="360" name="HB2"/>
+ <atom segid=" A" residue="360" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="C"/>
+ <chemical_shift value="181.584" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="CB"/>
+ <chemical_shift value="18.27" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="CA"/>
+ <chemical_shift value="54.768" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="N"/>
+ <chemical_shift value="121.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="H"/>
+ <chemical_shift value="8.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="360" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="361" name="HD21"/>
+ <atom segid=" A" residue="361" name="HD22"/>
+ <atom segid=" A" residue="361" name="HD23"/>
+ <chemical_shift value="0.722" error="0.0"/>
+ <chemical_shift value="0.892" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="361" name="HD11"/>
+ <atom segid=" A" residue="361" name="HD12"/>
+ <atom segid=" A" residue="361" name="HD13"/>
+ <chemical_shift value="0.722" error="0.0"/>
+ <chemical_shift value="0.892" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="C"/>
+ <chemical_shift value="178.899" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CB"/>
+ <chemical_shift value="39.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CA"/>
+ <chemical_shift value="57.465" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="N"/>
+ <chemical_shift value="116.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CD1"/>
+ <chemical_shift value="25.264" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="CD2"/>
+ <chemical_shift value="19.605" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="H"/>
+ <chemical_shift value="8.078" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="361" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="362" name="HZ1"/>
+ <atom segid=" A" residue="362" name="HZ2"/>
+ <atom segid=" A" residue="362" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CB"/>
+ <chemical_shift value="31.531" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="C"/>
+ <chemical_shift value="179.903" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="H"/>
+ <chemical_shift value="7.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CA"/>
+ <chemical_shift value="59.792" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="N"/>
+ <chemical_shift value="121.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="362" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="C"/>
+ <chemical_shift value="178.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CB"/>
+ <chemical_shift value="40.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CA"/>
+ <chemical_shift value="57.231" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="N"/>
+ <chemical_shift value="120.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="H"/>
+ <chemical_shift value="8.145" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="363" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="364" name="HB1"/>
+ <atom segid=" A" residue="364" name="HB2"/>
+ <atom segid=" A" residue="364" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="C"/>
+ <chemical_shift value="178.422" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="CB"/>
+ <chemical_shift value="17.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="CA"/>
+ <chemical_shift value="55.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="N"/>
+ <chemical_shift value="121.446" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="H"/>
+ <chemical_shift value="7.735" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="364" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="C"/>
+ <chemical_shift value="179.207" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CB"/>
+ <chemical_shift value="27.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CA"/>
+ <chemical_shift value="60.224" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="N"/>
+ <chemical_shift value="118.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="H"/>
+ <chemical_shift value="8.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="365" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="366" name="HG21"/>
+ <atom segid=" A" residue="366" name="HG22"/>
+ <atom segid=" A" residue="366" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="C"/>
+ <chemical_shift value="175.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CB"/>
+ <chemical_shift value="69.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CA"/>
+ <chemical_shift value="66.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="N"/>
+ <chemical_shift value="115.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="H"/>
+ <chemical_shift value="8.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="366" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CB"/>
+ <chemical_shift value="29.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="C"/>
+ <chemical_shift value="178.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="H"/>
+ <chemical_shift value="7.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CA"/>
+ <chemical_shift value="58.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="N"/>
+ <chemical_shift value="120.123" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="367" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="368" name="HG21"/>
+ <atom segid=" A" residue="368" name="HG22"/>
+ <atom segid=" A" residue="368" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.693" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="368" name="HD11"/>
+ <atom segid=" A" residue="368" name="HD12"/>
+ <atom segid=" A" residue="368" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.693" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="C"/>
+ <chemical_shift value="177.188" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CB"/>
+ <chemical_shift value="38.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CA"/>
+ <chemical_shift value="65.05" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="N"/>
+ <chemical_shift value="117.397" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CD1"/>
+ <chemical_shift value="15.285" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="H"/>
+ <chemical_shift value="8.005" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="368" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="369" name="HG21"/>
+ <atom segid=" A" residue="369" name="HG22"/>
+ <atom segid=" A" residue="369" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="C"/>
+ <chemical_shift value="174.309" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CB"/>
+ <chemical_shift value="70.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CA"/>
+ <chemical_shift value="62.641" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="N"/>
+ <chemical_shift value="107.043" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="H"/>
+ <chemical_shift value="7.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="369" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="370" name="HZ1"/>
+ <atom segid=" A" residue="370" name="HZ2"/>
+ <atom segid=" A" residue="370" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="O'"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="O''"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CB"/>
+ <chemical_shift value="32.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="H"/>
+ <chemical_shift value="7.399" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CA"/>
+ <chemical_shift value="59.013" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="N"/>
+ <chemical_shift value="128.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="370" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+</chemical_shift_list>
\ No newline at end of file
diff --git a/docs/examples/malecoli/data/xml/nc0_peaks.xml b/docs/examples/malecoli/data/xml/nc0_peaks.xml
new file mode 100644
index 0000000000000000000000000000000000000000..07539eaa5e2131729517a4126f70cab37311e409
--- /dev/null
+++ b/docs/examples/malecoli/data/xml/nc0_peaks.xml
@@ -0,0 +1,9331 @@
+<!DOCTYPE spectrum SYSTEM "noesy_spectrum1.0.dtd">
+<spectrum name="nc0">
+ <peak number="1" reliable="no" ambiguity="">
+ <volume value="4040000.0" error="0"/>
+ <intensity value="4040000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="1.348" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="106.221" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="19.347" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="2" reliable="no" ambiguity="">
+ <volume value="5540000.0" error="0"/>
+ <intensity value="5540000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="1.265" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="110.078" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="19.036" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="3" reliable="no" ambiguity="">
+ <volume value="410000.0" error="0"/>
+ <intensity value="410000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.266" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="125.246" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="25.18" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="4" reliable="no" ambiguity="">
+ <volume value="294000.0" error="0"/>
+ <intensity value="294000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.261" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="124.677" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="25.22" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="5" reliable="no" ambiguity="">
+ <volume value="469000.0" error="0"/>
+ <intensity value="469000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.264" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="120.118" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="25.219" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="6" reliable="no" ambiguity="">
+ <volume value="418000.0" error="0"/>
+ <intensity value="418000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.264" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="118.289" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="25.182" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="7" reliable="no" ambiguity="">
+ <volume value="372000.0" error="0"/>
+ <intensity value="372000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.263" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="115.912" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="25.251" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="8" reliable="no" ambiguity="">
+ <volume value="643000.0" error="0"/>
+ <intensity value="643000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.345" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="127.704" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="14.467" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="9" reliable="no" ambiguity="">
+ <volume value="642000.0" error="0"/>
+ <intensity value="642000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.345" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="125.33" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="14.505" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="10" reliable="no" ambiguity="">
+ <volume value="230000.0" error="0"/>
+ <intensity value="230000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.347" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="124.276" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="14.429" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="11" reliable="no" ambiguity="">
+ <volume value="226000.0" error="0"/>
+ <intensity value="226000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.101" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="121.733" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="13.059" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="12" reliable="no" ambiguity="">
+ <volume value="431000.0" error="0"/>
+ <intensity value="431000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.878" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="123.139" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="24.736" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="13" reliable="no" ambiguity="">
+ <volume value="738000.0" error="0"/>
+ <intensity value="738000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.879" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="121.566" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="24.641" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="14" reliable="no" ambiguity="">
+ <volume value="418000.0" error="0"/>
+ <intensity value="418000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.88" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="115.822" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="24.796" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="15" reliable="no" ambiguity="">
+ <volume value="453000.0" error="0"/>
+ <intensity value="453000.0" error="0"/>
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+ <peak number="580" reliable="no" ambiguity="">
+ <volume value="1760000.0" error="0"/>
+ <intensity value="1760000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.999" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="121.706" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="21.523" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="581" reliable="no" ambiguity="">
+ <volume value="629000.0" error="0"/>
+ <intensity value="629000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.952" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="126.791" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="21.367" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="582" reliable="no" ambiguity="">
+ <volume value="397000.0" error="0"/>
+ <intensity value="397000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.544" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="116.279" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="20.742" error=""/>
+ </hetero2>
+ </peak>
+ <peak number="583" reliable="no" ambiguity="">
+ <volume value="947000.0" error="0"/>
+ <intensity value="947000.0" error="0"/>
+ <proton1>
+ <shift value="999.0" error=""/>
+ </proton1>
+ <proton2>
+ <shift value="0.539" error=""/>
+ </proton2>
+ <hetero1>
+ <shift value="123.564" error=""/>
+ </hetero1>
+ <hetero2>
+ <shift value="20.586" error=""/>
+ </hetero2>
+ </peak>
+</spectrum>
\ No newline at end of file
diff --git a/docs/examples/malecoli/data/xml/nn20_cs.xml b/docs/examples/malecoli/data/xml/nn20_cs.xml
new file mode 100644
index 0000000000000000000000000000000000000000..bcb3d46b809ec3f250726022e42af6cd1ed9b115
--- /dev/null
+++ b/docs/examples/malecoli/data/xml/nn20_cs.xml
@@ -0,0 +1,31373 @@
+<!DOCTYPE chemical_shift_list SYSTEM "chemical_shift_list1.0.dtd">
+<chemical_shift_list>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="1" name="HZ1"/>
+ <atom segid=" A" residue="1" name="HZ2"/>
+ <atom segid=" A" residue="1" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="1" name="H1"/>
+ <atom segid=" A" residue="1" name="H2"/>
+ <atom segid=" A" residue="1" name="H3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="C"/>
+ <chemical_shift value="176.453" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CB"/>
+ <chemical_shift value="32.88" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CA"/>
+ <chemical_shift value="56.408" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="1" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="2" name="HG21"/>
+ <atom segid=" A" residue="2" name="HG22"/>
+ <atom segid=" A" residue="2" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.402" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="2" name="HD11"/>
+ <atom segid=" A" residue="2" name="HD12"/>
+ <atom segid=" A" residue="2" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.402" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="C"/>
+ <chemical_shift value="176.016" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CB"/>
+ <chemical_shift value="38.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CA"/>
+ <chemical_shift value="62.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="N"/>
+ <chemical_shift value="123.415" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CD1"/>
+ <chemical_shift value="13.054" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="H"/>
+ <chemical_shift value="7.988" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="2" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="C"/>
+ <chemical_shift value="176.438" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CB"/>
+ <chemical_shift value="31.187" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CA"/>
+ <chemical_shift value="56.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="N"/>
+ <chemical_shift value="126.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="H"/>
+ <chemical_shift value="8.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="3" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="C"/>
+ <chemical_shift value="177.433" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CB"/>
+ <chemical_shift value="30.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CA"/>
+ <chemical_shift value="56.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="N"/>
+ <chemical_shift value="124.204" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="H"/>
+ <chemical_shift value="8.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="4" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="C"/>
+ <chemical_shift value="172.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="H"/>
+ <chemical_shift value="8.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="CA"/>
+ <chemical_shift value="45.937" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="N"/>
+ <chemical_shift value="111.348" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="5" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="6" name="HZ1"/>
+ <atom segid=" A" residue="6" name="HZ2"/>
+ <atom segid=" A" residue="6" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CB"/>
+ <chemical_shift value="35.109" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="C"/>
+ <chemical_shift value="173.108" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="H"/>
+ <chemical_shift value="7.582" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CA"/>
+ <chemical_shift value="54.965" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="N"/>
+ <chemical_shift value="118.91" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="6" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="7" name="HD21"/>
+ <atom segid=" A" residue="7" name="HD22"/>
+ <atom segid=" A" residue="7" name="HD23"/>
+ <chemical_shift value="0.615" error="0.0"/>
+ <chemical_shift value="0.267" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="7" name="HD11"/>
+ <atom segid=" A" residue="7" name="HD12"/>
+ <atom segid=" A" residue="7" name="HD13"/>
+ <chemical_shift value="0.615" error="0.0"/>
+ <chemical_shift value="0.267" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="C"/>
+ <chemical_shift value="175.788" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CB"/>
+ <chemical_shift value="46.699" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CA"/>
+ <chemical_shift value="53.365" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="N"/>
+ <chemical_shift value="116.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CD1"/>
+ <chemical_shift value="25.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="CD2"/>
+ <chemical_shift value="24.064" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="H"/>
+ <chemical_shift value="8.231" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="7" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="8" name="HG21"/>
+ <atom segid=" A" residue="8" name="HG22"/>
+ <atom segid=" A" residue="8" name="HG23"/>
+ <chemical_shift value="0.923" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="8" name="HG11"/>
+ <atom segid=" A" residue="8" name="HG12"/>
+ <atom segid=" A" residue="8" name="HG13"/>
+ <chemical_shift value="0.923" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="C"/>
+ <chemical_shift value="176.033" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CB"/>
+ <chemical_shift value="33.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CA"/>
+ <chemical_shift value="61.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="N"/>
+ <chemical_shift value="125.474" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CG1"/>
+ <chemical_shift value="20.962" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="H"/>
+ <chemical_shift value="10.155" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="8" name="CG2"/>
+ <chemical_shift value="21.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="9" name="HG21"/>
+ <atom segid=" A" residue="9" name="HG22"/>
+ <atom segid=" A" residue="9" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.346" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="9" name="HD11"/>
+ <atom segid=" A" residue="9" name="HD12"/>
+ <atom segid=" A" residue="9" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.346" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="C"/>
+ <chemical_shift value="174.901" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CB"/>
+ <chemical_shift value="40.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CA"/>
+ <chemical_shift value="59.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="N"/>
+ <chemical_shift value="128.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CD1"/>
+ <chemical_shift value="14.523" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="H"/>
+ <chemical_shift value="9.114" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="9" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="H"/>
+ <chemical_shift value="9.032" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="C"/>
+ <chemical_shift value="174.116" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CB"/>
+ <chemical_shift value="32.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CA"/>
+ <chemical_shift value="54.451" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="N"/>
+ <chemical_shift value="126.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="10" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="11" name="HG21"/>
+ <atom segid=" A" residue="11" name="HG22"/>
+ <atom segid=" A" residue="11" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.107" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="11" name="HD11"/>
+ <atom segid=" A" residue="11" name="HD12"/>
+ <atom segid=" A" residue="11" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.107" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="C"/>
+ <chemical_shift value="171.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CB"/>
+ <chemical_shift value="41.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CA"/>
+ <chemical_shift value="59.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="N"/>
+ <chemical_shift value="122.063" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CD1"/>
+ <chemical_shift value="13.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="H"/>
+ <chemical_shift value="8.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="11" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="C"/>
+ <chemical_shift value="177.503" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CB"/>
+ <chemical_shift value="39.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CA"/>
+ <chemical_shift value="54.628" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="N"/>
+ <chemical_shift value="122.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="H"/>
+ <chemical_shift value="8.922" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="12" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="C"/>
+ <chemical_shift value="173.365" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="H"/>
+ <chemical_shift value="8.288" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="CA"/>
+ <chemical_shift value="46.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="N"/>
+ <chemical_shift value="106.789" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="13" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="C"/>
+ <chemical_shift value="176.544" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CB"/>
+ <chemical_shift value="39.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CA"/>
+ <chemical_shift value="53.217" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="N"/>
+ <chemical_shift value="117.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="H"/>
+ <chemical_shift value="7.99" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="14" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="15" name="HZ1"/>
+ <atom segid=" A" residue="15" name="HZ2"/>
+ <atom segid=" A" residue="15" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CB"/>
+ <chemical_shift value="32.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="C"/>
+ <chemical_shift value="177.64" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="H"/>
+ <chemical_shift value="7.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CA"/>
+ <chemical_shift value="53.23" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="N"/>
+ <chemical_shift value="118.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="15" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="C"/>
+ <chemical_shift value="175.872" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="H"/>
+ <chemical_shift value="8.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="CA"/>
+ <chemical_shift value="48.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="N"/>
+ <chemical_shift value="108.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="16" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="17" name="HD1"/>
+ <atom segid=" A" residue="17" name="HD2"/>
+ <atom segid=" A" residue="17" name="HE1"/>
+ <atom segid=" A" residue="17" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="C"/>
+ <chemical_shift value="177.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CB"/>
+ <chemical_shift value="37.646" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CA"/>
+ <chemical_shift value="59.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="N"/>
+ <chemical_shift value="120.633" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="H"/>
+ <chemical_shift value="8.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="17" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="C"/>
+ <chemical_shift value="179.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CB"/>
+ <chemical_shift value="37.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CA"/>
+ <chemical_shift value="56.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="N"/>
+ <chemical_shift value="123.761" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="H"/>
+ <chemical_shift value="8.109" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="18" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="C"/>
+ <chemical_shift value="176.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="H"/>
+ <chemical_shift value="9.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="CA"/>
+ <chemical_shift value="47.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="N"/>
+ <chemical_shift value="111.77" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="19" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="20" name="HD21"/>
+ <atom segid=" A" residue="20" name="HD22"/>
+ <atom segid=" A" residue="20" name="HD23"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="20" name="HD11"/>
+ <atom segid=" A" residue="20" name="HD12"/>
+ <atom segid=" A" residue="20" name="HD13"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ <chemical_shift value="0.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="C"/>
+ <chemical_shift value="178.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CB"/>
+ <chemical_shift value="41.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CA"/>
+ <chemical_shift value="57.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="N"/>
+ <chemical_shift value="121.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CD1"/>
+ <chemical_shift value="24.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="CD2"/>
+ <chemical_shift value="26.879" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="20" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="21" name="HB1"/>
+ <atom segid=" A" residue="21" name="HB2"/>
+ <atom segid=" A" residue="21" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="C"/>
+ <chemical_shift value="180.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="CB"/>
+ <chemical_shift value="17.478" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="CA"/>
+ <chemical_shift value="55.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="N"/>
+ <chemical_shift value="121.303" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="H"/>
+ <chemical_shift value="8.143" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="21" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="C"/>
+ <chemical_shift value="180.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CB"/>
+ <chemical_shift value="28.487" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CA"/>
+ <chemical_shift value="59.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="N"/>
+ <chemical_shift value="120.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="H"/>
+ <chemical_shift value="7.825" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="22" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="23" name="HG21"/>
+ <atom segid=" A" residue="23" name="HG22"/>
+ <atom segid=" A" residue="23" name="HG23"/>
+ <chemical_shift value="1.252" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="23" name="HG11"/>
+ <atom segid=" A" residue="23" name="HG12"/>
+ <atom segid=" A" residue="23" name="HG13"/>
+ <chemical_shift value="1.252" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="C"/>
+ <chemical_shift value="179.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CB"/>
+ <chemical_shift value="31.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CA"/>
+ <chemical_shift value="66.874" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="N"/>
+ <chemical_shift value="123.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CG1"/>
+ <chemical_shift value="22.314" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="H"/>
+ <chemical_shift value="7.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="23" name="CG2"/>
+ <chemical_shift value="23.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="C"/>
+ <chemical_shift value="175.393" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="H"/>
+ <chemical_shift value="8.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="CA"/>
+ <chemical_shift value="47.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="N"/>
+ <chemical_shift value="106.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="24" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="25" name="HZ1"/>
+ <atom segid=" A" residue="25" name="HZ2"/>
+ <atom segid=" A" residue="25" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CB"/>
+ <chemical_shift value="31.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="C"/>
+ <chemical_shift value="179.664" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="H"/>
+ <chemical_shift value="8.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CA"/>
+ <chemical_shift value="59.448" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="N"/>
+ <chemical_shift value="123.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="25" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="26" name="HZ1"/>
+ <atom segid=" A" residue="26" name="HZ2"/>
+ <atom segid=" A" residue="26" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CB"/>
+ <chemical_shift value="31.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="C"/>
+ <chemical_shift value="178.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="H"/>
+ <chemical_shift value="7.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CA"/>
+ <chemical_shift value="59.777" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="N"/>
+ <chemical_shift value="123.048" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="26" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="27" name="HD1"/>
+ <atom segid=" A" residue="27" name="HD2"/>
+ <atom segid=" A" residue="27" name="HE1"/>
+ <atom segid=" A" residue="27" name="HE2"/>
+ <atom segid=" A" residue="27" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="C"/>
+ <chemical_shift value="179.166" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CB"/>
+ <chemical_shift value="39.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CA"/>
+ <chemical_shift value="61.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="N"/>
+ <chemical_shift value="120.111" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="H"/>
+ <chemical_shift value="8.131" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="27" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="C"/>
+ <chemical_shift value="180.031" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CB"/>
+ <chemical_shift value="29.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CA"/>
+ <chemical_shift value="59.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="N"/>
+ <chemical_shift value="124.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="H"/>
+ <chemical_shift value="8.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="28" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="29" name="HZ1"/>
+ <atom segid=" A" residue="29" name="HZ2"/>
+ <atom segid=" A" residue="29" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CB"/>
+ <chemical_shift value="31.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="H"/>
+ <chemical_shift value="8.151" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CA"/>
+ <chemical_shift value="59.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="N"/>
+ <chemical_shift value="122.162" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="29" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="C"/>
+ <chemical_shift value="178.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CB"/>
+ <chemical_shift value="41.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CA"/>
+ <chemical_shift value="56.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="N"/>
+ <chemical_shift value="116.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="H"/>
+ <chemical_shift value="7.615" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="30" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="31" name="HG21"/>
+ <atom segid=" A" residue="31" name="HG22"/>
+ <atom segid=" A" residue="31" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="C"/>
+ <chemical_shift value="176.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CB"/>
+ <chemical_shift value="72.293" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CA"/>
+ <chemical_shift value="62.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="N"/>
+ <chemical_shift value="107.246" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="H"/>
+ <chemical_shift value="7.929" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="31" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="C"/>
+ <chemical_shift value="173.645" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="H"/>
+ <chemical_shift value="8.6" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="CA"/>
+ <chemical_shift value="45.563" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="N"/>
+ <chemical_shift value="112.884" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="32" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="33" name="HG21"/>
+ <atom segid=" A" residue="33" name="HG22"/>
+ <atom segid=" A" residue="33" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.574" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="33" name="HD11"/>
+ <atom segid=" A" residue="33" name="HD12"/>
+ <atom segid=" A" residue="33" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.574" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="C"/>
+ <chemical_shift value="173.715" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CB"/>
+ <chemical_shift value="35.66" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CA"/>
+ <chemical_shift value="59.048" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="N"/>
+ <chemical_shift value="124.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CD1"/>
+ <chemical_shift value="10.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="H"/>
+ <chemical_shift value="7.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="33" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="34" name="HZ1"/>
+ <atom segid=" A" residue="34" name="HZ2"/>
+ <atom segid=" A" residue="34" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CB"/>
+ <chemical_shift value="32.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="C"/>
+ <chemical_shift value="175.675" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="H"/>
+ <chemical_shift value="7.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CA"/>
+ <chemical_shift value="56.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="N"/>
+ <chemical_shift value="125.011" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="34" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="35" name="HG21"/>
+ <atom segid=" A" residue="35" name="HG22"/>
+ <atom segid=" A" residue="35" name="HG23"/>
+ <chemical_shift value="0.776" error="0.0"/>
+ <chemical_shift value="0.331" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="35" name="HG11"/>
+ <atom segid=" A" residue="35" name="HG12"/>
+ <atom segid=" A" residue="35" name="HG13"/>
+ <chemical_shift value="0.776" error="0.0"/>
+ <chemical_shift value="0.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="C"/>
+ <chemical_shift value="175.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CB"/>
+ <chemical_shift value="33.372" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CA"/>
+ <chemical_shift value="61.064" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="N"/>
+ <chemical_shift value="124.42" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CG1"/>
+ <chemical_shift value="20.685" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="H"/>
+ <chemical_shift value="8.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="35" name="CG2"/>
+ <chemical_shift value="22.478" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="36" name="HG21"/>
+ <atom segid=" A" residue="36" name="HG22"/>
+ <atom segid=" A" residue="36" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="C"/>
+ <chemical_shift value="172.762" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CB"/>
+ <chemical_shift value="70.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CA"/>
+ <chemical_shift value="61.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="N"/>
+ <chemical_shift value="125.312" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="H"/>
+ <chemical_shift value="9.176" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="36" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="37" name="HG21"/>
+ <atom segid=" A" residue="37" name="HG22"/>
+ <atom segid=" A" residue="37" name="HG23"/>
+ <chemical_shift value="0.766" error="0.0"/>
+ <chemical_shift value="0.951" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="37" name="HG11"/>
+ <atom segid=" A" residue="37" name="HG12"/>
+ <atom segid=" A" residue="37" name="HG13"/>
+ <chemical_shift value="0.766" error="0.0"/>
+ <chemical_shift value="0.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="C"/>
+ <chemical_shift value="175.348" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CB"/>
+ <chemical_shift value="32.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CA"/>
+ <chemical_shift value="61.689" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="N"/>
+ <chemical_shift value="127.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CG1"/>
+ <chemical_shift value="22.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="H"/>
+ <chemical_shift value="8.921" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="37" name="CG2"/>
+ <chemical_shift value="20.673" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="C"/>
+ <chemical_shift value="173.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CB"/>
+ <chemical_shift value="33.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CA"/>
+ <chemical_shift value="54.475" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="N"/>
+ <chemical_shift value="127.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="H"/>
+ <chemical_shift value="9.644" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="38" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CB"/>
+ <chemical_shift value="28.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CA"/>
+ <chemical_shift value="51.527" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="N"/>
+ <chemical_shift value="115.306" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="H"/>
+ <chemical_shift value="8.297" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="39" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="C"/>
+ <chemical_shift value="176.926" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CB"/>
+ <chemical_shift value="30.665" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CA"/>
+ <chemical_shift value="62.226" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="40" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="C"/>
+ <chemical_shift value="176.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CB"/>
+ <chemical_shift value="41.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CA"/>
+ <chemical_shift value="54.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="N"/>
+ <chemical_shift value="121.165" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="H"/>
+ <chemical_shift value="8.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="41" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="42" name="HZ1"/>
+ <atom segid=" A" residue="42" name="HZ2"/>
+ <atom segid=" A" residue="42" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CB"/>
+ <chemical_shift value="29.442" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="C"/>
+ <chemical_shift value="178.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="H"/>
+ <chemical_shift value="8.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CA"/>
+ <chemical_shift value="56.642" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="N"/>
+ <chemical_shift value="119.242" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="42" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="43" name="HD21"/>
+ <atom segid=" A" residue="43" name="HD22"/>
+ <atom segid=" A" residue="43" name="HD23"/>
+ <chemical_shift value="1.133" error="0.0"/>
+ <chemical_shift value="1.101" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="43" name="HD11"/>
+ <atom segid=" A" residue="43" name="HD12"/>
+ <atom segid=" A" residue="43" name="HD13"/>
+ <chemical_shift value="1.133" error="0.0"/>
+ <chemical_shift value="1.101" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="C"/>
+ <chemical_shift value="175.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CB"/>
+ <chemical_shift value="40.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CA"/>
+ <chemical_shift value="59.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="N"/>
+ <chemical_shift value="120.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CD1"/>
+ <chemical_shift value="26.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="CD2"/>
+ <chemical_shift value="26.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="H"/>
+ <chemical_shift value="7.387" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="43" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="C"/>
+ <chemical_shift value="178.284" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CB"/>
+ <chemical_shift value="24.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CA"/>
+ <chemical_shift value="57.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="N"/>
+ <chemical_shift value="123.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="H"/>
+ <chemical_shift value="10.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="44" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="C"/>
+ <chemical_shift value="178.462" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CB"/>
+ <chemical_shift value="29.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CA"/>
+ <chemical_shift value="56.456" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="N"/>
+ <chemical_shift value="120.295" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="H"/>
+ <chemical_shift value="7.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="45" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="46" name="HZ1"/>
+ <atom segid=" A" residue="46" name="HZ2"/>
+ <atom segid=" A" residue="46" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CB"/>
+ <chemical_shift value="33.277" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="C"/>
+ <chemical_shift value="179.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="H"/>
+ <chemical_shift value="8.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CA"/>
+ <chemical_shift value="58.611" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="N"/>
+ <chemical_shift value="120.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="46" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="47" name="HD1"/>
+ <atom segid=" A" residue="47" name="HD2"/>
+ <atom segid=" A" residue="47" name="HE1"/>
+ <atom segid=" A" residue="47" name="HE2"/>
+ <atom segid=" A" residue="47" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CB"/>
+ <chemical_shift value="36.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CA"/>
+ <chemical_shift value="63.747" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="N"/>
+ <chemical_shift value="116.928" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="H"/>
+ <chemical_shift value="8.655" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="47" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="C"/>
+ <chemical_shift value="178.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CB"/>
+ <chemical_shift value="30.015" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CA"/>
+ <chemical_shift value="65.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="48" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="C"/>
+ <chemical_shift value="178.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CB"/>
+ <chemical_shift value="28.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CA"/>
+ <chemical_shift value="58.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="N"/>
+ <chemical_shift value="115.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="H"/>
+ <chemical_shift value="6.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="49" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="50" name="HG21"/>
+ <atom segid=" A" residue="50" name="HG22"/>
+ <atom segid=" A" residue="50" name="HG23"/>
+ <chemical_shift value="0.906" error="0.0"/>
+ <chemical_shift value="0.967" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="50" name="HG11"/>
+ <atom segid=" A" residue="50" name="HG12"/>
+ <atom segid=" A" residue="50" name="HG13"/>
+ <chemical_shift value="0.906" error="0.0"/>
+ <chemical_shift value="0.967" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="C"/>
+ <chemical_shift value="178.512" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CB"/>
+ <chemical_shift value="32.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CA"/>
+ <chemical_shift value="62.603" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="N"/>
+ <chemical_shift value="111.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CG1"/>
+ <chemical_shift value="21.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="H"/>
+ <chemical_shift value="7.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="50" name="CG2"/>
+ <chemical_shift value="19.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="51" name="HB1"/>
+ <atom segid=" A" residue="51" name="HB2"/>
+ <atom segid=" A" residue="51" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="C"/>
+ <chemical_shift value="180.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="CB"/>
+ <chemical_shift value="17.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="CA"/>
+ <chemical_shift value="54.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="N"/>
+ <chemical_shift value="125.692" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="H"/>
+ <chemical_shift value="8.349" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="51" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="52" name="HB1"/>
+ <atom segid=" A" residue="52" name="HB2"/>
+ <atom segid=" A" residue="52" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="C"/>
+ <chemical_shift value="178.618" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="CB"/>
+ <chemical_shift value="18.146" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="CA"/>
+ <chemical_shift value="53.841" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="N"/>
+ <chemical_shift value="118.243" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="H"/>
+ <chemical_shift value="7.396" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="52" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="53" name="HG21"/>
+ <atom segid=" A" residue="53" name="HG22"/>
+ <atom segid=" A" residue="53" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="C"/>
+ <chemical_shift value="175.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CB"/>
+ <chemical_shift value="69.75" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CA"/>
+ <chemical_shift value="61.307" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="N"/>
+ <chemical_shift value="106.045" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="H"/>
+ <chemical_shift value="7.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="53" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="C"/>
+ <chemical_shift value="172.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="H"/>
+ <chemical_shift value="7.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="CA"/>
+ <chemical_shift value="45.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="N"/>
+ <chemical_shift value="109.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="54" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="C"/>
+ <chemical_shift value="174.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CB"/>
+ <chemical_shift value="43.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CA"/>
+ <chemical_shift value="52.778" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="N"/>
+ <chemical_shift value="119.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="H"/>
+ <chemical_shift value="7.395" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="55" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="H"/>
+ <chemical_shift value="8.332" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="CA"/>
+ <chemical_shift value="43.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="N"/>
+ <chemical_shift value="105.496" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="56" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="C"/>
+ <chemical_shift value="175.448" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CB"/>
+ <chemical_shift value="30.658" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CA"/>
+ <chemical_shift value="61.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="57" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="C"/>
+ <chemical_shift value="176.037" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CB"/>
+ <chemical_shift value="43.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CA"/>
+ <chemical_shift value="58.668" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="N"/>
+ <chemical_shift value="117.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="H"/>
+ <chemical_shift value="8.698" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="58" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="59" name="HG21"/>
+ <atom segid=" A" residue="59" name="HG22"/>
+ <atom segid=" A" residue="59" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.735" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="59" name="HD11"/>
+ <atom segid=" A" residue="59" name="HD12"/>
+ <atom segid=" A" residue="59" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.735" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="C"/>
+ <chemical_shift value="173.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CB"/>
+ <chemical_shift value="42.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CA"/>
+ <chemical_shift value="58.982" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="N"/>
+ <chemical_shift value="114.106" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CD1"/>
+ <chemical_shift value="13.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="H"/>
+ <chemical_shift value="7.631" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="59" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="60" name="HG22"/>
+ <atom segid=" A" residue="60" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.452" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="60" name="HD11"/>
+ <atom segid=" A" residue="60" name="HD12"/>
+ <atom segid=" A" residue="60" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="C"/>
+ <chemical_shift value="172.929" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CB"/>
+ <chemical_shift value="41.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CA"/>
+ <chemical_shift value="58.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="N"/>
+ <chemical_shift value="124.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CD1"/>
+ <chemical_shift value="14.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="H"/>
+ <chemical_shift value="8.898" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="60" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="61" name="HD2"/>
+ <atom segid=" A" residue="61" name="HE1"/>
+ <atom segid=" A" residue="61" name="HE2"/>
+ <atom segid=" A" residue="61" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="C"/>
+ <chemical_shift value="176.742" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CB"/>
+ <chemical_shift value="41.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CA"/>
+ <chemical_shift value="55.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="N"/>
+ <chemical_shift value="126.189" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="H"/>
+ <chemical_shift value="8.603" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="61" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="H"/>
+ <chemical_shift value="9.181" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="C"/>
+ <chemical_shift value="173.771" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CB"/>
+ <chemical_shift value="31.813" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CA"/>
+ <chemical_shift value="57.786" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="N"/>
+ <chemical_shift value="121.356" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="62" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="63" name="HB1"/>
+ <atom segid=" A" residue="63" name="HB2"/>
+ <atom segid=" A" residue="63" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="C"/>
+ <chemical_shift value="179.957" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="CB"/>
+ <chemical_shift value="18.639" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="CA"/>
+ <chemical_shift value="54.068" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="N"/>
+ <chemical_shift value="125.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="H"/>
+ <chemical_shift value="6.296" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="63" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="C"/>
+ <chemical_shift value="178.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CB"/>
+ <chemical_shift value="30.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CA"/>
+ <chemical_shift value="60.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="N"/>
+ <chemical_shift value="115.831" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="H"/>
+ <chemical_shift value="8.028" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="64" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="C"/>
+ <chemical_shift value="177.968" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CB"/>
+ <chemical_shift value="39.5" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CA"/>
+ <chemical_shift value="57.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="N"/>
+ <chemical_shift value="119.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="H"/>
+ <chemical_shift value="7.721" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="65" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CB"/>
+ <chemical_shift value="29.53" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="C"/>
+ <chemical_shift value="177.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="H"/>
+ <chemical_shift value="6.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CA"/>
+ <chemical_shift value="55.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="N"/>
+ <chemical_shift value="116.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="66" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="67" name="HD1"/>
+ <atom segid=" A" residue="67" name="HD2"/>
+ <atom segid=" A" residue="67" name="HE1"/>
+ <atom segid=" A" residue="67" name="HE2"/>
+ <atom segid=" A" residue="67" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="C"/>
+ <chemical_shift value="177.883" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CB"/>
+ <chemical_shift value="36.331" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CA"/>
+ <chemical_shift value="58.703" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="N"/>
+ <chemical_shift value="116.954" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="H"/>
+ <chemical_shift value="7.688" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="67" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="C"/>
+ <chemical_shift value="175.81" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="H"/>
+ <chemical_shift value="7.272" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="CA"/>
+ <chemical_shift value="47.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="N"/>
+ <chemical_shift value="107.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="68" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="C"/>
+ <chemical_shift value="177.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="H"/>
+ <chemical_shift value="7.651" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="CA"/>
+ <chemical_shift value="47.089" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="N"/>
+ <chemical_shift value="107.532" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="69" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="70" name="HD1"/>
+ <atom segid=" A" residue="70" name="HD2"/>
+ <atom segid=" A" residue="70" name="HE1"/>
+ <atom segid=" A" residue="70" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="C"/>
+ <chemical_shift value="178.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CB"/>
+ <chemical_shift value="35.758" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CA"/>
+ <chemical_shift value="57.372" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="N"/>
+ <chemical_shift value="119.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="H"/>
+ <chemical_shift value="6.974" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="70" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="71" name="HB1"/>
+ <atom segid=" A" residue="71" name="HB2"/>
+ <atom segid=" A" residue="71" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="C"/>
+ <chemical_shift value="182.277" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="CB"/>
+ <chemical_shift value="18.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="CA"/>
+ <chemical_shift value="54.487" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="N"/>
+ <chemical_shift value="122.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="H"/>
+ <chemical_shift value="8.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="71" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="C"/>
+ <chemical_shift value="177.85" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CB"/>
+ <chemical_shift value="27.562" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CA"/>
+ <chemical_shift value="58.635" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="N"/>
+ <chemical_shift value="122.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="H"/>
+ <chemical_shift value="8.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="72" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="C"/>
+ <chemical_shift value="173.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="CB"/>
+ <chemical_shift value="64.148" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="CA"/>
+ <chemical_shift value="59.274" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="N"/>
+ <chemical_shift value="112.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="H"/>
+ <chemical_shift value="7.362" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="73" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="C"/>
+ <chemical_shift value="176.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="H"/>
+ <chemical_shift value="8.083" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="CA"/>
+ <chemical_shift value="46.341" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="N"/>
+ <chemical_shift value="109.4" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="74" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="75" name="HD22"/>
+ <atom segid=" A" residue="75" name="HD23"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="75" name="HD11"/>
+ <atom segid=" A" residue="75" name="HD12"/>
+ <atom segid=" A" residue="75" name="HD13"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="C"/>
+ <chemical_shift value="177.608" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CB"/>
+ <chemical_shift value="42.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CA"/>
+ <chemical_shift value="55.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="N"/>
+ <chemical_shift value="113.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CD1"/>
+ <chemical_shift value="25.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="CD2"/>
+ <chemical_shift value="20.664" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="H"/>
+ <chemical_shift value="7.815" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="75" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="76" name="HD22"/>
+ <atom segid=" A" residue="76" name="HD23"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.897" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="76" name="HD11"/>
+ <atom segid=" A" residue="76" name="HD12"/>
+ <atom segid=" A" residue="76" name="HD13"/>
+ <chemical_shift value="0.538" error="0.0"/>
+ <chemical_shift value="0.897" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="C"/>
+ <chemical_shift value="176.782" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CB"/>
+ <chemical_shift value="43.798" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CA"/>
+ <chemical_shift value="52.794" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="N"/>
+ <chemical_shift value="115.902" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CD1"/>
+ <chemical_shift value="27.43" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="CD2"/>
+ <chemical_shift value="21.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="H"/>
+ <chemical_shift value="7.431" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="76" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="77" name="HB1"/>
+ <atom segid=" A" residue="77" name="HB2"/>
+ <atom segid=" A" residue="77" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="C"/>
+ <chemical_shift value="176.398" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="CB"/>
+ <chemical_shift value="19.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="CA"/>
+ <chemical_shift value="51.102" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="N"/>
+ <chemical_shift value="125.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="H"/>
+ <chemical_shift value="9.007" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="77" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="C"/>
+ <chemical_shift value="176.784" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CB"/>
+ <chemical_shift value="29.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CA"/>
+ <chemical_shift value="56.426" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="N"/>
+ <chemical_shift value="120.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="H"/>
+ <chemical_shift value="8.228" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="78" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="79" name="HG21"/>
+ <atom segid=" A" residue="79" name="HG22"/>
+ <atom segid=" A" residue="79" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.161" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="79" name="HD11"/>
+ <atom segid=" A" residue="79" name="HD12"/>
+ <atom segid=" A" residue="79" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.161" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="C"/>
+ <chemical_shift value="175.746" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CB"/>
+ <chemical_shift value="38.941" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CA"/>
+ <chemical_shift value="59.839" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="N"/>
+ <chemical_shift value="122.859" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CD1"/>
+ <chemical_shift value="12.313" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="H"/>
+ <chemical_shift value="8.176" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="79" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="80" name="HG21"/>
+ <atom segid=" A" residue="80" name="HG22"/>
+ <atom segid=" A" residue="80" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CB"/>
+ <chemical_shift value="69.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CA"/>
+ <chemical_shift value="57.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="N"/>
+ <chemical_shift value="112.766" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="H"/>
+ <chemical_shift value="8.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="80" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="C"/>
+ <chemical_shift value="177.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CB"/>
+ <chemical_shift value="31.586" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CA"/>
+ <chemical_shift value="62.548" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="81" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CB"/>
+ <chemical_shift value="41.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CA"/>
+ <chemical_shift value="53.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="N"/>
+ <chemical_shift value="123.843" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="H"/>
+ <chemical_shift value="9.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="82" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="83" name="HZ1"/>
+ <atom segid=" A" residue="83" name="HZ2"/>
+ <atom segid=" A" residue="83" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CB"/>
+ <chemical_shift value="31.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="C"/>
+ <chemical_shift value="177.708" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CA"/>
+ <chemical_shift value="59.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="83" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="84" name="HB1"/>
+ <atom segid=" A" residue="84" name="HB2"/>
+ <atom segid=" A" residue="84" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="C"/>
+ <chemical_shift value="180.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="CB"/>
+ <chemical_shift value="17.553" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="CA"/>
+ <chemical_shift value="54.875" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="N"/>
+ <chemical_shift value="119.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="H"/>
+ <chemical_shift value="8.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="84" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="85" name="HD1"/>
+ <atom segid=" A" residue="85" name="HD2"/>
+ <atom segid=" A" residue="85" name="HE1"/>
+ <atom segid=" A" residue="85" name="HE2"/>
+ <atom segid=" A" residue="85" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="C"/>
+ <chemical_shift value="178.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CB"/>
+ <chemical_shift value="39.035" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CA"/>
+ <chemical_shift value="62.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="N"/>
+ <chemical_shift value="118.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="H"/>
+ <chemical_shift value="7.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="85" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="C"/>
+ <chemical_shift value="180.14" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CB"/>
+ <chemical_shift value="28.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CA"/>
+ <chemical_shift value="59.616" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="N"/>
+ <chemical_shift value="117.272" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="H"/>
+ <chemical_shift value="8.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="86" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="C"/>
+ <chemical_shift value="176.576" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CB"/>
+ <chemical_shift value="40.956" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CA"/>
+ <chemical_shift value="56.177" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="N"/>
+ <chemical_shift value="116.913" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="H"/>
+ <chemical_shift value="8.053" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="87" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="88" name="HZ1"/>
+ <atom segid=" A" residue="88" name="HZ2"/>
+ <atom segid=" A" residue="88" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CB"/>
+ <chemical_shift value="31.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="C"/>
+ <chemical_shift value="176.797" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="H"/>
+ <chemical_shift value="7.816" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CA"/>
+ <chemical_shift value="58.402" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="N"/>
+ <chemical_shift value="117.299" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="88" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="89" name="HD21"/>
+ <atom segid=" A" residue="89" name="HD22"/>
+ <atom segid=" A" residue="89" name="HD23"/>
+ <chemical_shift value="0.484" error="0.0"/>
+ <chemical_shift value="0.526" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="89" name="HD11"/>
+ <atom segid=" A" residue="89" name="HD12"/>
+ <atom segid=" A" residue="89" name="HD13"/>
+ <chemical_shift value="0.484" error="0.0"/>
+ <chemical_shift value="0.526" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="C"/>
+ <chemical_shift value="176.725" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CB"/>
+ <chemical_shift value="42.609" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CA"/>
+ <chemical_shift value="53.55" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="N"/>
+ <chemical_shift value="120.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CD1"/>
+ <chemical_shift value="26.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="CD2"/>
+ <chemical_shift value="25.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="H"/>
+ <chemical_shift value="7.661" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="89" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="90" name="HD1"/>
+ <atom segid=" A" residue="90" name="HD2"/>
+ <atom segid=" A" residue="90" name="HE1"/>
+ <atom segid=" A" residue="90" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CB"/>
+ <chemical_shift value="38.921" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CA"/>
+ <chemical_shift value="59.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="N"/>
+ <chemical_shift value="116.748" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="H"/>
+ <chemical_shift value="7.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="90" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="C"/>
+ <chemical_shift value="179.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CB"/>
+ <chemical_shift value="31.38" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CA"/>
+ <chemical_shift value="66.902" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="91" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="92" name="HD1"/>
+ <atom segid=" A" residue="92" name="HD2"/>
+ <atom segid=" A" residue="92" name="HE1"/>
+ <atom segid=" A" residue="92" name="HE2"/>
+ <atom segid=" A" residue="92" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="C"/>
+ <chemical_shift value="176.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CB"/>
+ <chemical_shift value="36.63" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CA"/>
+ <chemical_shift value="59.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="N"/>
+ <chemical_shift value="112.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="H"/>
+ <chemical_shift value="8.01" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="92" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="93" name="HG21"/>
+ <atom segid=" A" residue="93" name="HG22"/>
+ <atom segid=" A" residue="93" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="C"/>
+ <chemical_shift value="176.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CB"/>
+ <chemical_shift value="67.099" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CA"/>
+ <chemical_shift value="64.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="N"/>
+ <chemical_shift value="111.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="H"/>
+ <chemical_shift value="7.099" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="93" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="H"/>
+ <chemical_shift value="6.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="C"/>
+ <chemical_shift value="178.465" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CB"/>
+ <chemical_shift value="29.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CA"/>
+ <chemical_shift value="58.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="N"/>
+ <chemical_shift value="120.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="94" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="C"/>
+ <chemical_shift value="178.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CB"/>
+ <chemical_shift value="39.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CA"/>
+ <chemical_shift value="57.436" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="N"/>
+ <chemical_shift value="115.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="H"/>
+ <chemical_shift value="7.31" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="95" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="96" name="HB1"/>
+ <atom segid=" A" residue="96" name="HB2"/>
+ <atom segid=" A" residue="96" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="C"/>
+ <chemical_shift value="177.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="CB"/>
+ <chemical_shift value="17.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="CA"/>
+ <chemical_shift value="54.0" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="N"/>
+ <chemical_shift value="118.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="H"/>
+ <chemical_shift value="6.989" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="96" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="97" name="HG21"/>
+ <atom segid=" A" residue="97" name="HG22"/>
+ <atom segid=" A" residue="97" name="HG23"/>
+ <chemical_shift value="1.347" error="0.0"/>
+ <chemical_shift value="0.578" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="97" name="HG11"/>
+ <atom segid=" A" residue="97" name="HG12"/>
+ <atom segid=" A" residue="97" name="HG13"/>
+ <chemical_shift value="1.347" error="0.0"/>
+ <chemical_shift value="0.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="C"/>
+ <chemical_shift value="172.577" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CB"/>
+ <chemical_shift value="30.785" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CA"/>
+ <chemical_shift value="59.857" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="N"/>
+ <chemical_shift value="106.203" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CG1"/>
+ <chemical_shift value="22.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="H"/>
+ <chemical_shift value="7.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="97" name="CG2"/>
+ <chemical_shift value="19.363" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CB"/>
+ <chemical_shift value="31.357" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="C"/>
+ <chemical_shift value="176.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="H"/>
+ <chemical_shift value="7.049" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CA"/>
+ <chemical_shift value="55.065" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="N"/>
+ <chemical_shift value="121.675" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NH1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="NH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HH11"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="98" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="99" name="HD1"/>
+ <atom segid=" A" residue="99" name="HD2"/>
+ <atom segid=" A" residue="99" name="HE1"/>
+ <atom segid=" A" residue="99" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CB"/>
+ <chemical_shift value="41.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CA"/>
+ <chemical_shift value="58.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="N"/>
+ <chemical_shift value="127.473" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="H"/>
+ <chemical_shift value="9.707" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="99" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="C"/>
+ <chemical_shift value="175.4" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CB"/>
+ <chemical_shift value="37.221" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CA"/>
+ <chemical_shift value="53.907" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="100" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="C"/>
+ <chemical_shift value="173.987" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="H"/>
+ <chemical_shift value="8.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="CA"/>
+ <chemical_shift value="45.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="N"/>
+ <chemical_shift value="102.283" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="101" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="102" name="HZ1"/>
+ <atom segid=" A" residue="102" name="HZ2"/>
+ <atom segid=" A" residue="102" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CB"/>
+ <chemical_shift value="34.731" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="C"/>
+ <chemical_shift value="175.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="H"/>
+ <chemical_shift value="7.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CA"/>
+ <chemical_shift value="54.578" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="N"/>
+ <chemical_shift value="121.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="102" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="103" name="HD21"/>
+ <atom segid=" A" residue="103" name="HD22"/>
+ <atom segid=" A" residue="103" name="HD23"/>
+ <chemical_shift value="0.972" error="0.0"/>
+ <chemical_shift value="0.49" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="103" name="HD11"/>
+ <atom segid=" A" residue="103" name="HD12"/>
+ <atom segid=" A" residue="103" name="HD13"/>
+ <chemical_shift value="0.972" error="0.0"/>
+ <chemical_shift value="0.49" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="C"/>
+ <chemical_shift value="178.524" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CB"/>
+ <chemical_shift value="42.179" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CA"/>
+ <chemical_shift value="55.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="N"/>
+ <chemical_shift value="123.232" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CD1"/>
+ <chemical_shift value="24.748" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="CD2"/>
+ <chemical_shift value="24.1" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="H"/>
+ <chemical_shift value="8.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="103" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="104" name="HG21"/>
+ <atom segid=" A" residue="104" name="HG22"/>
+ <atom segid=" A" residue="104" name="HG23"/>
+ <chemical_shift value="0.889" error="0.0"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="104" name="HD11"/>
+ <atom segid=" A" residue="104" name="HD12"/>
+ <atom segid=" A" residue="104" name="HD13"/>
+ <chemical_shift value="0.889" error="0.0"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="C"/>
+ <chemical_shift value="175.468" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CB"/>
+ <chemical_shift value="39.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CA"/>
+ <chemical_shift value="59.655" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="N"/>
+ <chemical_shift value="112.793" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CD1"/>
+ <chemical_shift value="14.779" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="H"/>
+ <chemical_shift value="8.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="104" name="CG2"/>
+ <chemical_shift value="19.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="105" name="HB1"/>
+ <atom segid=" A" residue="105" name="HB2"/>
+ <atom segid=" A" residue="105" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="C"/>
+ <chemical_shift value="173.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="CB"/>
+ <chemical_shift value="22.111" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="CA"/>
+ <chemical_shift value="52.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="N"/>
+ <chemical_shift value="117.391" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="H"/>
+ <chemical_shift value="7.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="105" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="106" name="HD1"/>
+ <atom segid=" A" residue="106" name="HD2"/>
+ <atom segid=" A" residue="106" name="HE1"/>
+ <atom segid=" A" residue="106" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CB"/>
+ <chemical_shift value="39.931" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CA"/>
+ <chemical_shift value="56.214" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="N"/>
+ <chemical_shift value="113.919" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="H"/>
+ <chemical_shift value="8.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="106" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="C"/>
+ <chemical_shift value="174.609" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CB"/>
+ <chemical_shift value="32.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CA"/>
+ <chemical_shift value="62.281" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="107" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="108" name="HG21"/>
+ <atom segid=" A" residue="108" name="HG22"/>
+ <atom segid=" A" residue="108" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.637" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="108" name="HD11"/>
+ <atom segid=" A" residue="108" name="HD12"/>
+ <atom segid=" A" residue="108" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.637" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="C"/>
+ <chemical_shift value="176.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CB"/>
+ <chemical_shift value="37.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CA"/>
+ <chemical_shift value="60.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="N"/>
+ <chemical_shift value="115.381" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CD1"/>
+ <chemical_shift value="9.981" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="H"/>
+ <chemical_shift value="8.515" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="108" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="109" name="HB1"/>
+ <atom segid=" A" residue="109" name="HB2"/>
+ <atom segid=" A" residue="109" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="C"/>
+ <chemical_shift value="174.628" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="CB"/>
+ <chemical_shift value="23.471" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="CA"/>
+ <chemical_shift value="50.761" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="N"/>
+ <chemical_shift value="118.162" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="H"/>
+ <chemical_shift value="7.854" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="109" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="110" name="HG21"/>
+ <atom segid=" A" residue="110" name="HG22"/>
+ <atom segid=" A" residue="110" name="HG23"/>
+ <chemical_shift value="0.476" error="0.0"/>
+ <chemical_shift value="0.767" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="110" name="HG11"/>
+ <atom segid=" A" residue="110" name="HG12"/>
+ <atom segid=" A" residue="110" name="HG13"/>
+ <chemical_shift value="0.476" error="0.0"/>
+ <chemical_shift value="0.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="C"/>
+ <chemical_shift value="173.634" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CB"/>
+ <chemical_shift value="34.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CA"/>
+ <chemical_shift value="62.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="N"/>
+ <chemical_shift value="121.428" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CG1"/>
+ <chemical_shift value="20.954" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="H"/>
+ <chemical_shift value="8.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="110" name="CG2"/>
+ <chemical_shift value="20.424" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="C"/>
+ <chemical_shift value="173.917" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CB"/>
+ <chemical_shift value="32.976" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CA"/>
+ <chemical_shift value="54.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="N"/>
+ <chemical_shift value="123.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="H"/>
+ <chemical_shift value="9.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="111" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="112" name="HB1"/>
+ <atom segid=" A" residue="112" name="HB2"/>
+ <atom segid=" A" residue="112" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="C"/>
+ <chemical_shift value="176.641" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="CB"/>
+ <chemical_shift value="22.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="CA"/>
+ <chemical_shift value="50.959" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="N"/>
+ <chemical_shift value="117.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="H"/>
+ <chemical_shift value="6.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="112" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="113" name="HD21"/>
+ <atom segid=" A" residue="113" name="HD22"/>
+ <atom segid=" A" residue="113" name="HD23"/>
+ <chemical_shift value="0.854" error="0.0"/>
+ <chemical_shift value="0.691" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="113" name="HD11"/>
+ <atom segid=" A" residue="113" name="HD12"/>
+ <atom segid=" A" residue="113" name="HD13"/>
+ <chemical_shift value="0.854" error="0.0"/>
+ <chemical_shift value="0.691" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="C"/>
+ <chemical_shift value="173.598" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CB"/>
+ <chemical_shift value="43.367" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CA"/>
+ <chemical_shift value="55.257" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="N"/>
+ <chemical_shift value="123.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CD1"/>
+ <chemical_shift value="26.792" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="CD2"/>
+ <chemical_shift value="23.625" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="H"/>
+ <chemical_shift value="8.457" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="113" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="C"/>
+ <chemical_shift value="172.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="CB"/>
+ <chemical_shift value="67.447" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="CA"/>
+ <chemical_shift value="57.265" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="N"/>
+ <chemical_shift value="108.174" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="H"/>
+ <chemical_shift value="7.493" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="114" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="115" name="HD21"/>
+ <atom segid=" A" residue="115" name="HD22"/>
+ <atom segid=" A" residue="115" name="HD23"/>
+ <chemical_shift value="0.587" error="0.0"/>
+ <chemical_shift value="0.684" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="115" name="HD11"/>
+ <atom segid=" A" residue="115" name="HD12"/>
+ <atom segid=" A" residue="115" name="HD13"/>
+ <chemical_shift value="0.587" error="0.0"/>
+ <chemical_shift value="0.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="C"/>
+ <chemical_shift value="174.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CB"/>
+ <chemical_shift value="43.729" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CA"/>
+ <chemical_shift value="54.482" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="N"/>
+ <chemical_shift value="122.319" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CD1"/>
+ <chemical_shift value="22.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="CD2"/>
+ <chemical_shift value="24.597" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="H"/>
+ <chemical_shift value="7.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="115" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="116" name="HG21"/>
+ <atom segid=" A" residue="116" name="HG22"/>
+ <atom segid=" A" residue="116" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.459" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="116" name="HD11"/>
+ <atom segid=" A" residue="116" name="HD12"/>
+ <atom segid=" A" residue="116" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.459" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="C"/>
+ <chemical_shift value="174.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CB"/>
+ <chemical_shift value="38.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CA"/>
+ <chemical_shift value="60.103" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="N"/>
+ <chemical_shift value="129.611" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CD1"/>
+ <chemical_shift value="13.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="H"/>
+ <chemical_shift value="8.667" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="116" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="117" name="HD1"/>
+ <atom segid=" A" residue="117" name="HD2"/>
+ <atom segid=" A" residue="117" name="HE1"/>
+ <atom segid=" A" residue="117" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="C"/>
+ <chemical_shift value="172.945" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CB"/>
+ <chemical_shift value="42.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CA"/>
+ <chemical_shift value="54.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="N"/>
+ <chemical_shift value="121.832" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="H"/>
+ <chemical_shift value="9.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="117" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="C"/>
+ <chemical_shift value="175.772" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CB"/>
+ <chemical_shift value="37.62" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CA"/>
+ <chemical_shift value="52.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="N"/>
+ <chemical_shift value="121.187" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="H"/>
+ <chemical_shift value="9.303" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="118" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="119" name="HZ1"/>
+ <atom segid=" A" residue="119" name="HZ2"/>
+ <atom segid=" A" residue="119" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CB"/>
+ <chemical_shift value="32.435" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="C"/>
+ <chemical_shift value="177.723" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="H"/>
+ <chemical_shift value="8.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CA"/>
+ <chemical_shift value="58.733" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="N"/>
+ <chemical_shift value="125.522" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="119" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="C"/>
+ <chemical_shift value="177.651" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CB"/>
+ <chemical_shift value="40.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CA"/>
+ <chemical_shift value="56.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="N"/>
+ <chemical_shift value="115.687" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="120" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="121" name="HD21"/>
+ <atom segid=" A" residue="121" name="HD22"/>
+ <atom segid=" A" residue="121" name="HD23"/>
+ <chemical_shift value="0.779" error="0.0"/>
+ <chemical_shift value="0.665" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="121" name="HD11"/>
+ <atom segid=" A" residue="121" name="HD12"/>
+ <atom segid=" A" residue="121" name="HD13"/>
+ <chemical_shift value="0.779" error="0.0"/>
+ <chemical_shift value="0.665" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="C"/>
+ <chemical_shift value="176.749" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CB"/>
+ <chemical_shift value="44.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CA"/>
+ <chemical_shift value="55.765" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="N"/>
+ <chemical_shift value="117.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CD1"/>
+ <chemical_shift value="24.729" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="CD2"/>
+ <chemical_shift value="22.791" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="H"/>
+ <chemical_shift value="7.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="121" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="122" name="HD21"/>
+ <atom segid=" A" residue="122" name="HD22"/>
+ <atom segid=" A" residue="122" name="HD23"/>
+ <chemical_shift value="0.937" error="0.0"/>
+ <chemical_shift value="0.93" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="122" name="HD11"/>
+ <atom segid=" A" residue="122" name="HD12"/>
+ <atom segid=" A" residue="122" name="HD13"/>
+ <chemical_shift value="0.937" error="0.0"/>
+ <chemical_shift value="0.93" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CB"/>
+ <chemical_shift value="44.118" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CA"/>
+ <chemical_shift value="51.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="N"/>
+ <chemical_shift value="119.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CD1"/>
+ <chemical_shift value="25.548" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="CD2"/>
+ <chemical_shift value="26.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="H"/>
+ <chemical_shift value="8.337" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="122" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="123" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="124" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="125" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="C"/>
+ <chemical_shift value="176.075" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CB"/>
+ <chemical_shift value="31.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CA"/>
+ <chemical_shift value="62.495" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="126" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="127" name="HZ1"/>
+ <atom segid=" A" residue="127" name="HZ2"/>
+ <atom segid=" A" residue="127" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CB"/>
+ <chemical_shift value="33.055" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="C"/>
+ <chemical_shift value="177.427" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="H"/>
+ <chemical_shift value="8.137" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CA"/>
+ <chemical_shift value="56.778" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="N"/>
+ <chemical_shift value="118.457" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="127" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="128" name="HG21"/>
+ <atom segid=" A" residue="128" name="HG22"/>
+ <atom segid=" A" residue="128" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="C"/>
+ <chemical_shift value="174.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CB"/>
+ <chemical_shift value="71.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CA"/>
+ <chemical_shift value="60.211" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="N"/>
+ <chemical_shift value="108.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="128" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="H"/>
+ <chemical_shift value="10.183" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="C"/>
+ <chemical_shift value="179.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CB"/>
+ <chemical_shift value="28.48" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CA"/>
+ <chemical_shift value="60.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="N"/>
+ <chemical_shift value="123.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="129" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="C"/>
+ <chemical_shift value="178.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CB"/>
+ <chemical_shift value="28.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CA"/>
+ <chemical_shift value="61.701" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="N"/>
+ <chemical_shift value="118.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="H"/>
+ <chemical_shift value="10.583" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="130" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="C"/>
+ <chemical_shift value="176.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CB"/>
+ <chemical_shift value="31.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CA"/>
+ <chemical_shift value="57.205" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="N"/>
+ <chemical_shift value="116.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="H"/>
+ <chemical_shift value="7.606" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="131" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="132" name="HG21"/>
+ <atom segid=" A" residue="132" name="HG22"/>
+ <atom segid=" A" residue="132" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.56" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="132" name="HD11"/>
+ <atom segid=" A" residue="132" name="HD12"/>
+ <atom segid=" A" residue="132" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.56" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CB"/>
+ <chemical_shift value="33.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CA"/>
+ <chemical_shift value="66.928" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="N"/>
+ <chemical_shift value="121.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CD1"/>
+ <chemical_shift value="12.36" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="H"/>
+ <chemical_shift value="8.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="132" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="C"/>
+ <chemical_shift value="177.795" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CB"/>
+ <chemical_shift value="30.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CA"/>
+ <chemical_shift value="67.059" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="133" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="134" name="HB1"/>
+ <atom segid=" A" residue="134" name="HB2"/>
+ <atom segid=" A" residue="134" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="C"/>
+ <chemical_shift value="181.28" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="CB"/>
+ <chemical_shift value="17.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="CA"/>
+ <chemical_shift value="55.458" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="N"/>
+ <chemical_shift value="118.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="H"/>
+ <chemical_shift value="7.848" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="134" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="135" name="HD21"/>
+ <atom segid=" A" residue="135" name="HD22"/>
+ <atom segid=" A" residue="135" name="HD23"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ <chemical_shift value="0.888" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="135" name="HD11"/>
+ <atom segid=" A" residue="135" name="HD12"/>
+ <atom segid=" A" residue="135" name="HD13"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ <chemical_shift value="0.888" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="C"/>
+ <chemical_shift value="179.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CB"/>
+ <chemical_shift value="42.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CA"/>
+ <chemical_shift value="57.396" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="N"/>
+ <chemical_shift value="120.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CD1"/>
+ <chemical_shift value="24.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="CD2"/>
+ <chemical_shift value="24.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="H"/>
+ <chemical_shift value="7.6" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="135" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="C"/>
+ <chemical_shift value="177.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CB"/>
+ <chemical_shift value="41.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CA"/>
+ <chemical_shift value="58.901" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="N"/>
+ <chemical_shift value="118.561" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="H"/>
+ <chemical_shift value="8.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="136" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="137" name="HZ1"/>
+ <atom segid=" A" residue="137" name="HZ2"/>
+ <atom segid=" A" residue="137" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CB"/>
+ <chemical_shift value="31.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="C"/>
+ <chemical_shift value="179.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="H"/>
+ <chemical_shift value="8.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CA"/>
+ <chemical_shift value="60.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="N"/>
+ <chemical_shift value="117.342" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="137" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="C"/>
+ <chemical_shift value="179.799" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CB"/>
+ <chemical_shift value="29.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CA"/>
+ <chemical_shift value="59.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="N"/>
+ <chemical_shift value="118.65" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="H"/>
+ <chemical_shift value="7.483" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="138" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="139" name="HD21"/>
+ <atom segid=" A" residue="139" name="HD22"/>
+ <atom segid=" A" residue="139" name="HD23"/>
+ <chemical_shift value="0.852" error="0.0"/>
+ <chemical_shift value="0.787" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="139" name="HD11"/>
+ <atom segid=" A" residue="139" name="HD12"/>
+ <atom segid=" A" residue="139" name="HD13"/>
+ <chemical_shift value="0.852" error="0.0"/>
+ <chemical_shift value="0.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="C"/>
+ <chemical_shift value="180.721" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CB"/>
+ <chemical_shift value="40.311" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CA"/>
+ <chemical_shift value="58.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="N"/>
+ <chemical_shift value="121.279" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CD1"/>
+ <chemical_shift value="25.914" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="CD2"/>
+ <chemical_shift value="22.927" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="H"/>
+ <chemical_shift value="8.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="139" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="140" name="HZ1"/>
+ <atom segid=" A" residue="140" name="HZ2"/>
+ <atom segid=" A" residue="140" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CB"/>
+ <chemical_shift value="31.84" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="C"/>
+ <chemical_shift value="181.621" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="H"/>
+ <chemical_shift value="9.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CA"/>
+ <chemical_shift value="58.851" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="N"/>
+ <chemical_shift value="124.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="140" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="141" name="HB1"/>
+ <atom segid=" A" residue="141" name="HB2"/>
+ <atom segid=" A" residue="141" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="C"/>
+ <chemical_shift value="178.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="CB"/>
+ <chemical_shift value="17.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="CA"/>
+ <chemical_shift value="54.521" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="N"/>
+ <chemical_shift value="122.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="H"/>
+ <chemical_shift value="7.261" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="141" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="142" name="HZ1"/>
+ <atom segid=" A" residue="142" name="HZ2"/>
+ <atom segid=" A" residue="142" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CB"/>
+ <chemical_shift value="32.237" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="C"/>
+ <chemical_shift value="176.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="H"/>
+ <chemical_shift value="7.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CA"/>
+ <chemical_shift value="55.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="N"/>
+ <chemical_shift value="115.794" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="142" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="C"/>
+ <chemical_shift value="174.318" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="H"/>
+ <chemical_shift value="7.877" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="CA"/>
+ <chemical_shift value="46.128" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="N"/>
+ <chemical_shift value="107.82" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="143" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="144" name="HZ1"/>
+ <atom segid=" A" residue="144" name="HZ2"/>
+ <atom segid=" A" residue="144" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CB"/>
+ <chemical_shift value="35.01" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="C"/>
+ <chemical_shift value="173.812" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="H"/>
+ <chemical_shift value="7.86" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CA"/>
+ <chemical_shift value="53.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="N"/>
+ <chemical_shift value="119.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="144" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="C"/>
+ <chemical_shift value="174.656" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="CB"/>
+ <chemical_shift value="66.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="CA"/>
+ <chemical_shift value="56.884" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="N"/>
+ <chemical_shift value="109.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="H"/>
+ <chemical_shift value="7.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="145" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="146" name="HB1"/>
+ <atom segid=" A" residue="146" name="HB2"/>
+ <atom segid=" A" residue="146" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="C"/>
+ <chemical_shift value="175.894" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="CB"/>
+ <chemical_shift value="17.973" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="CA"/>
+ <chemical_shift value="55.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="N"/>
+ <chemical_shift value="122.791" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="H"/>
+ <chemical_shift value="9.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="146" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="147" name="HD21"/>
+ <atom segid=" A" residue="147" name="HD22"/>
+ <atom segid=" A" residue="147" name="HD23"/>
+ <chemical_shift value="0.936" error="0.0"/>
+ <chemical_shift value="0.683" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="147" name="HD11"/>
+ <atom segid=" A" residue="147" name="HD12"/>
+ <atom segid=" A" residue="147" name="HD13"/>
+ <chemical_shift value="0.936" error="0.0"/>
+ <chemical_shift value="0.683" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="C"/>
+ <chemical_shift value="175.05" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CB"/>
+ <chemical_shift value="45.575" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CA"/>
+ <chemical_shift value="54.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="N"/>
+ <chemical_shift value="116.868" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="CD1"/>
+ <chemical_shift value="22.5" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="27.555" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="H"/>
+ <chemical_shift value="8.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="147" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="148" name="HE1"/>
+ <atom segid=" A" residue="148" name="HE2"/>
+ <atom segid=" A" residue="148" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="C"/>
+ <chemical_shift value="174.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CB"/>
+ <chemical_shift value="37.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CA"/>
+ <chemical_shift value="55.8" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="N"/>
+ <chemical_shift value="121.711" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="H"/>
+ <chemical_shift value="8.179" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="148" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="149" name="HD2"/>
+ <atom segid=" A" residue="149" name="HE1"/>
+ <atom segid=" A" residue="149" name="HE2"/>
+ <atom segid=" A" residue="149" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="C"/>
+ <chemical_shift value="171.59" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CB"/>
+ <chemical_shift value="41.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CA"/>
+ <chemical_shift value="55.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="N"/>
+ <chemical_shift value="120.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="H"/>
+ <chemical_shift value="8.612" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="149" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="C"/>
+ <chemical_shift value="172.549" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CB"/>
+ <chemical_shift value="37.305" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CA"/>
+ <chemical_shift value="53.341" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="N"/>
+ <chemical_shift value="116.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="H"/>
+ <chemical_shift value="8.671" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="150" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="151" name="HD21"/>
+ <atom segid=" A" residue="151" name="HD22"/>
+ <atom segid=" A" residue="151" name="HD23"/>
+ <chemical_shift value="0.135" error="0.0"/>
+ <chemical_shift value="0.744" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="151" name="HD11"/>
+ <atom segid=" A" residue="151" name="HD12"/>
+ <atom segid=" A" residue="151" name="HD13"/>
+ <chemical_shift value="0.135" error="0.0"/>
+ <chemical_shift value="0.744" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="C"/>
+ <chemical_shift value="177.963" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CB"/>
+ <chemical_shift value="41.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CA"/>
+ <chemical_shift value="54.594" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="N"/>
+ <chemical_shift value="122.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CD1"/>
+ <chemical_shift value="26.232" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="CD2"/>
+ <chemical_shift value="23.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="H"/>
+ <chemical_shift value="7.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="151" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="C"/>
+ <chemical_shift value="176.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CB"/>
+ <chemical_shift value="28.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CA"/>
+ <chemical_shift value="55.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="N"/>
+ <chemical_shift value="113.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="H"/>
+ <chemical_shift value="7.94" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="152" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CB"/>
+ <chemical_shift value="32.958" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CA"/>
+ <chemical_shift value="51.537" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="N"/>
+ <chemical_shift value="113.572" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="H"/>
+ <chemical_shift value="6.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="153" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="C"/>
+ <chemical_shift value="176.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CB"/>
+ <chemical_shift value="31.966" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CA"/>
+ <chemical_shift value="63.731" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="154" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="155" name="HD1"/>
+ <atom segid=" A" residue="155" name="HD2"/>
+ <atom segid=" A" residue="155" name="HE1"/>
+ <atom segid=" A" residue="155" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="C"/>
+ <chemical_shift value="176.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CB"/>
+ <chemical_shift value="40.447" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CA"/>
+ <chemical_shift value="62.679" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="N"/>
+ <chemical_shift value="117.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="H"/>
+ <chemical_shift value="7.822" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="155" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="156" name="HD2"/>
+ <atom segid=" A" residue="156" name="HE1"/>
+ <atom segid=" A" residue="156" name="HE2"/>
+ <atom segid=" A" residue="156" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="C"/>
+ <chemical_shift value="176.222" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CB"/>
+ <chemical_shift value="41.587" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CA"/>
+ <chemical_shift value="60.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="N"/>
+ <chemical_shift value="112.212" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="H"/>
+ <chemical_shift value="8.045" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="156" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="157" name="HG21"/>
+ <atom segid=" A" residue="157" name="HG22"/>
+ <atom segid=" A" residue="157" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="C"/>
+ <chemical_shift value="176.039" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CB"/>
+ <chemical_shift value="69.29" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CA"/>
+ <chemical_shift value="63.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="N"/>
+ <chemical_shift value="106.105" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="H"/>
+ <chemical_shift value="7.59" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="157" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="H"/>
+ <chemical_shift value="8.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CB"/>
+ <chemical_shift value="28.509" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CA"/>
+ <chemical_shift value="60.968" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="N"/>
+ <chemical_shift value="124.195" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="158" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="C"/>
+ <chemical_shift value="178.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CB"/>
+ <chemical_shift value="30.052" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CA"/>
+ <chemical_shift value="65.931" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="159" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="160" name="HD21"/>
+ <atom segid=" A" residue="160" name="HD22"/>
+ <atom segid=" A" residue="160" name="HD23"/>
+ <chemical_shift value="-0.302" error="0.0"/>
+ <chemical_shift value="-1.003" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="160" name="HD11"/>
+ <atom segid=" A" residue="160" name="HD12"/>
+ <atom segid=" A" residue="160" name="HD13"/>
+ <chemical_shift value="-0.302" error="0.0"/>
+ <chemical_shift value="-1.003" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="C"/>
+ <chemical_shift value="176.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CB"/>
+ <chemical_shift value="42.223" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CA"/>
+ <chemical_shift value="56.069" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="N"/>
+ <chemical_shift value="111.624" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CD1"/>
+ <chemical_shift value="19.602" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="CD2"/>
+ <chemical_shift value="25.084" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="H"/>
+ <chemical_shift value="6.439" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="160" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="161" name="HG21"/>
+ <atom segid=" A" residue="161" name="HG22"/>
+ <atom segid=" A" residue="161" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.76" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="161" name="HD11"/>
+ <atom segid=" A" residue="161" name="HD12"/>
+ <atom segid=" A" residue="161" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="C"/>
+ <chemical_shift value="175.677" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CB"/>
+ <chemical_shift value="37.395" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CA"/>
+ <chemical_shift value="65.625" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="N"/>
+ <chemical_shift value="119.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CD1"/>
+ <chemical_shift value="13.081" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="H"/>
+ <chemical_shift value="6.955" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="161" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="162" name="HB1"/>
+ <atom segid=" A" residue="162" name="HB2"/>
+ <atom segid=" A" residue="162" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="C"/>
+ <chemical_shift value="179.724" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="CB"/>
+ <chemical_shift value="18.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="CA"/>
+ <chemical_shift value="52.32" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="N"/>
+ <chemical_shift value="115.26" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="H"/>
+ <chemical_shift value="8.001" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="162" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="163" name="HB1"/>
+ <atom segid=" A" residue="163" name="HB2"/>
+ <atom segid=" A" residue="163" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="C"/>
+ <chemical_shift value="178.286" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="CB"/>
+ <chemical_shift value="19.604" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="CA"/>
+ <chemical_shift value="56.425" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="N"/>
+ <chemical_shift value="120.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="H"/>
+ <chemical_shift value="6.668" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="163" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="C"/>
+ <chemical_shift value="176.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CB"/>
+ <chemical_shift value="42.538" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CA"/>
+ <chemical_shift value="53.44" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="N"/>
+ <chemical_shift value="115.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="H"/>
+ <chemical_shift value="9.571" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="164" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="C"/>
+ <chemical_shift value="175.607" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="H"/>
+ <chemical_shift value="7.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="CA"/>
+ <chemical_shift value="45.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="N"/>
+ <chemical_shift value="103.622" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="165" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="C"/>
+ <chemical_shift value="172.227" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="H"/>
+ <chemical_shift value="7.383" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="CA"/>
+ <chemical_shift value="45.592" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="N"/>
+ <chemical_shift value="108.12" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="166" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="167" name="HD1"/>
+ <atom segid=" A" residue="167" name="HD2"/>
+ <atom segid=" A" residue="167" name="HE1"/>
+ <atom segid=" A" residue="167" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="C"/>
+ <chemical_shift value="173.273" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CB"/>
+ <chemical_shift value="39.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CA"/>
+ <chemical_shift value="57.657" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="N"/>
+ <chemical_shift value="115.865" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="H"/>
+ <chemical_shift value="8.327" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="167" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="168" name="HB1"/>
+ <atom segid=" A" residue="168" name="HB2"/>
+ <atom segid=" A" residue="168" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="C"/>
+ <chemical_shift value="173.012" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="CB"/>
+ <chemical_shift value="16.475" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="CA"/>
+ <chemical_shift value="53.124" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="N"/>
+ <chemical_shift value="124.0" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="H"/>
+ <chemical_shift value="10.209" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="168" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="169" name="HD1"/>
+ <atom segid=" A" residue="169" name="HD2"/>
+ <atom segid=" A" residue="169" name="HE1"/>
+ <atom segid=" A" residue="169" name="HE2"/>
+ <atom segid=" A" residue="169" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="C"/>
+ <chemical_shift value="176.744" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CB"/>
+ <chemical_shift value="42.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CA"/>
+ <chemical_shift value="55.752" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="N"/>
+ <chemical_shift value="108.304" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="H"/>
+ <chemical_shift value="6.324" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="169" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="170" name="HZ1"/>
+ <atom segid=" A" residue="170" name="HZ2"/>
+ <atom segid=" A" residue="170" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
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+ <chemical_shift value="32.355" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="C"/>
+ <chemical_shift value="174.716" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="H"/>
+ <chemical_shift value="8.864" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CA"/>
+ <chemical_shift value="57.027" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="N"/>
+ <chemical_shift value="125.705" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="170" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
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+ <atom segid=" A" residue="171" name="HD2"/>
+ <atom segid=" A" residue="171" name="HE1"/>
+ <atom segid=" A" residue="171" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="C"/>
+ <chemical_shift value="175.029" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CB"/>
+ <chemical_shift value="39.896" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CA"/>
+ <chemical_shift value="56.2" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="N"/>
+ <chemical_shift value="129.707" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="H"/>
+ <chemical_shift value="8.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="171" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CB"/>
+ <chemical_shift value="32.477" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CA"/>
+ <chemical_shift value="55.981" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="N"/>
+ <chemical_shift value="126.797" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="H"/>
+ <chemical_shift value="8.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="172" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="C"/>
+ <chemical_shift value="175.432" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CB"/>
+ <chemical_shift value="37.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CA"/>
+ <chemical_shift value="54.334" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="173" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="C"/>
+ <chemical_shift value="173.294" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="H"/>
+ <chemical_shift value="7.52" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="CA"/>
+ <chemical_shift value="45.705" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="N"/>
+ <chemical_shift value="102.08" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="174" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="175" name="HZ1"/>
+ <atom segid=" A" residue="175" name="HZ2"/>
+ <atom segid=" A" residue="175" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CB"/>
+ <chemical_shift value="35.233" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="C"/>
+ <chemical_shift value="174.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="H"/>
+ <chemical_shift value="7.107" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CA"/>
+ <chemical_shift value="54.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="N"/>
+ <chemical_shift value="118.702" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="175" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="176" name="HD1"/>
+ <atom segid=" A" residue="176" name="HD2"/>
+ <atom segid=" A" residue="176" name="HE1"/>
+ <atom segid=" A" residue="176" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="C"/>
+ <chemical_shift value="176.262" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CB"/>
+ <chemical_shift value="39.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CA"/>
+ <chemical_shift value="58.92" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="N"/>
+ <chemical_shift value="120.134" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="H"/>
+ <chemical_shift value="8.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="176" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="C"/>
+ <chemical_shift value="177.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CB"/>
+ <chemical_shift value="41.216" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CA"/>
+ <chemical_shift value="52.944" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="N"/>
+ <chemical_shift value="124.051" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="H"/>
+ <chemical_shift value="9.044" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="177" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="178" name="HG21"/>
+ <atom segid=" A" residue="178" name="HG22"/>
+ <atom segid=" A" residue="178" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.853" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="178" name="HD11"/>
+ <atom segid=" A" residue="178" name="HD12"/>
+ <atom segid=" A" residue="178" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="C"/>
+ <chemical_shift value="175.849" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CB"/>
+ <chemical_shift value="36.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CA"/>
+ <chemical_shift value="63.627" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="N"/>
+ <chemical_shift value="117.051" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CD1"/>
+ <chemical_shift value="13.905" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="H"/>
+ <chemical_shift value="7.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="178" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="179" name="HZ1"/>
+ <atom segid=" A" residue="179" name="HZ2"/>
+ <atom segid=" A" residue="179" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CB"/>
+ <chemical_shift value="31.878" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="C"/>
+ <chemical_shift value="176.528" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="H"/>
+ <chemical_shift value="8.302" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CA"/>
+ <chemical_shift value="54.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="N"/>
+ <chemical_shift value="116.075" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="179" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="C"/>
+ <chemical_shift value="172.993" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CB"/>
+ <chemical_shift value="40.826" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CA"/>
+ <chemical_shift value="53.425" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="N"/>
+ <chemical_shift value="123.259" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="H"/>
+ <chemical_shift value="7.754" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="180" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="181" name="HG21"/>
+ <atom segid=" A" residue="181" name="HG22"/>
+ <atom segid=" A" residue="181" name="HG23"/>
+ <chemical_shift value="0.711" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="181" name="HG11"/>
+ <atom segid=" A" residue="181" name="HG12"/>
+ <atom segid=" A" residue="181" name="HG13"/>
+ <chemical_shift value="0.711" error="0.0"/>
+ <chemical_shift value="0.823" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="C"/>
+ <chemical_shift value="176.899" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CB"/>
+ <chemical_shift value="35.024" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CA"/>
+ <chemical_shift value="59.481" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="N"/>
+ <chemical_shift value="122.883" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CG1"/>
+ <chemical_shift value="21.539" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="H"/>
+ <chemical_shift value="7.492" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="181" name="CG2"/>
+ <chemical_shift value="22.538" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="C"/>
+ <chemical_shift value="174.259" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="H"/>
+ <chemical_shift value="7.066" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="CA"/>
+ <chemical_shift value="46.411" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="N"/>
+ <chemical_shift value="120.863" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="182" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="183" name="HG21"/>
+ <atom segid=" A" residue="183" name="HG22"/>
+ <atom segid=" A" residue="183" name="HG23"/>
+ <chemical_shift value="0.841" error="0.0"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="183" name="HG11"/>
+ <atom segid=" A" residue="183" name="HG12"/>
+ <atom segid=" A" residue="183" name="HG13"/>
+ <chemical_shift value="0.841" error="0.0"/>
+ <chemical_shift value="0.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="C"/>
+ <chemical_shift value="173.292" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CB"/>
+ <chemical_shift value="32.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CA"/>
+ <chemical_shift value="63.489" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="N"/>
+ <chemical_shift value="114.266" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CG1"/>
+ <chemical_shift value="22.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="H"/>
+ <chemical_shift value="6.757" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="183" name="CG2"/>
+ <chemical_shift value="22.42" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="C"/>
+ <chemical_shift value="176.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CB"/>
+ <chemical_shift value="39.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CA"/>
+ <chemical_shift value="51.67" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="N"/>
+ <chemical_shift value="114.851" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="H"/>
+ <chemical_shift value="7.835" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="184" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CB"/>
+ <chemical_shift value="39.263" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CA"/>
+ <chemical_shift value="51.688" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="N"/>
+ <chemical_shift value="116.3" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="H"/>
+ <chemical_shift value="6.891" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="185" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="186" name="HB1"/>
+ <atom segid=" A" residue="186" name="HB2"/>
+ <atom segid=" A" residue="186" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="C"/>
+ <chemical_shift value="180.525" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="CB"/>
+ <chemical_shift value="18.22" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="CA"/>
+ <chemical_shift value="55.672" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="186" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="C"/>
+ <chemical_shift value="176.046" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="H"/>
+ <chemical_shift value="8.385" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="CA"/>
+ <chemical_shift value="47.366" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="N"/>
+ <chemical_shift value="109.513" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="187" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="188" name="HB1"/>
+ <atom segid=" A" residue="188" name="HB2"/>
+ <atom segid=" A" residue="188" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="C"/>
+ <chemical_shift value="180.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="CB"/>
+ <chemical_shift value="18.399" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="CA"/>
+ <chemical_shift value="54.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="N"/>
+ <chemical_shift value="127.734" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="H"/>
+ <chemical_shift value="8.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="188" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="189" name="HZ1"/>
+ <atom segid=" A" residue="189" name="HZ2"/>
+ <atom segid=" A" residue="189" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CB"/>
+ <chemical_shift value="31.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="C"/>
+ <chemical_shift value="180.343" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="H"/>
+ <chemical_shift value="7.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CA"/>
+ <chemical_shift value="59.83" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="N"/>
+ <chemical_shift value="115.239" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="189" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="190" name="HB1"/>
+ <atom segid=" A" residue="190" name="HB2"/>
+ <atom segid=" A" residue="190" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="C"/>
+ <chemical_shift value="181.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="CB"/>
+ <chemical_shift value="17.89" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="CA"/>
+ <chemical_shift value="55.835" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="N"/>
+ <chemical_shift value="124.669" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="H"/>
+ <chemical_shift value="8.224" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="190" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="C"/>
+ <chemical_shift value="174.985" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="H"/>
+ <chemical_shift value="8.208" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="CA"/>
+ <chemical_shift value="47.937" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="N"/>
+ <chemical_shift value="107.568" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="191" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="192" name="HD21"/>
+ <atom segid=" A" residue="192" name="HD22"/>
+ <atom segid=" A" residue="192" name="HD23"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="1.085" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="192" name="HD11"/>
+ <atom segid=" A" residue="192" name="HD12"/>
+ <atom segid=" A" residue="192" name="HD13"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="1.085" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="C"/>
+ <chemical_shift value="178.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CB"/>
+ <chemical_shift value="40.218" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CA"/>
+ <chemical_shift value="57.325" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="N"/>
+ <chemical_shift value="121.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CD1"/>
+ <chemical_shift value="24.249" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="CD2"/>
+ <chemical_shift value="25.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="H"/>
+ <chemical_shift value="8.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="192" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="193" name="HG21"/>
+ <atom segid=" A" residue="193" name="HG22"/>
+ <atom segid=" A" residue="193" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="C"/>
+ <chemical_shift value="175.23" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CB"/>
+ <chemical_shift value="69.081" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CA"/>
+ <chemical_shift value="67.423" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="N"/>
+ <chemical_shift value="116.486" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="H"/>
+ <chemical_shift value="8.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="193" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="194" name="HD1"/>
+ <atom segid=" A" residue="194" name="HD2"/>
+ <atom segid=" A" residue="194" name="HE1"/>
+ <atom segid=" A" residue="194" name="HE2"/>
+ <atom segid=" A" residue="194" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="C"/>
+ <chemical_shift value="177.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CB"/>
+ <chemical_shift value="39.196" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CA"/>
+ <chemical_shift value="62.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="N"/>
+ <chemical_shift value="122.074" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="H"/>
+ <chemical_shift value="7.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="194" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="195" name="HD21"/>
+ <atom segid=" A" residue="195" name="HD22"/>
+ <atom segid=" A" residue="195" name="HD23"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="195" name="HD11"/>
+ <atom segid=" A" residue="195" name="HD12"/>
+ <atom segid=" A" residue="195" name="HD13"/>
+ <chemical_shift value="0.845" error="0.0"/>
+ <chemical_shift value="0.893" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="C"/>
+ <chemical_shift value="178.132" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CB"/>
+ <chemical_shift value="41.352" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CA"/>
+ <chemical_shift value="58.694" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="N"/>
+ <chemical_shift value="119.61" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CD1"/>
+ <chemical_shift value="23.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="CD2"/>
+ <chemical_shift value="25.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="H"/>
+ <chemical_shift value="7.712" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="195" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="196" name="HG21"/>
+ <atom segid=" A" residue="196" name="HG22"/>
+ <atom segid=" A" residue="196" name="HG23"/>
+ <chemical_shift value="0.856" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="196" name="HG11"/>
+ <atom segid=" A" residue="196" name="HG12"/>
+ <atom segid=" A" residue="196" name="HG13"/>
+ <chemical_shift value="0.856" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="C"/>
+ <chemical_shift value="178.464" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CB"/>
+ <chemical_shift value="31.053" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CA"/>
+ <chemical_shift value="67.271" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="N"/>
+ <chemical_shift value="117.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CG1"/>
+ <chemical_shift value="21.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="H"/>
+ <chemical_shift value="8.589" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="196" name="CG2"/>
+ <chemical_shift value="23.319" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="C"/>
+ <chemical_shift value="179.361" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CB"/>
+ <chemical_shift value="39.828" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CA"/>
+ <chemical_shift value="58.171" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="N"/>
+ <chemical_shift value="122.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="H"/>
+ <chemical_shift value="8.58" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="197" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="198" name="HD21"/>
+ <atom segid=" A" residue="198" name="HD22"/>
+ <atom segid=" A" residue="198" name="HD23"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="1.018" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="198" name="HD11"/>
+ <atom segid=" A" residue="198" name="HD12"/>
+ <atom segid=" A" residue="198" name="HD13"/>
+ <chemical_shift value="0.813" error="0.0"/>
+ <chemical_shift value="1.018" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="C"/>
+ <chemical_shift value="179.126" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CB"/>
+ <chemical_shift value="42.167" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CA"/>
+ <chemical_shift value="58.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="N"/>
+ <chemical_shift value="120.213" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CD1"/>
+ <chemical_shift value="25.598" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="CD2"/>
+ <chemical_shift value="23.461" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="H"/>
+ <chemical_shift value="7.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="198" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="199" name="HG21"/>
+ <atom segid=" A" residue="199" name="HG22"/>
+ <atom segid=" A" residue="199" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.743" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="199" name="HD11"/>
+ <atom segid=" A" residue="199" name="HD12"/>
+ <atom segid=" A" residue="199" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.743" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="C"/>
+ <chemical_shift value="181.156" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CB"/>
+ <chemical_shift value="38.209" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CA"/>
+ <chemical_shift value="63.317" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="N"/>
+ <chemical_shift value="119.983" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CD1"/>
+ <chemical_shift value="14.222" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="H"/>
+ <chemical_shift value="7.434" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="199" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="200" name="HZ1"/>
+ <atom segid=" A" residue="200" name="HZ2"/>
+ <atom segid=" A" residue="200" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CB"/>
+ <chemical_shift value="32.127" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="C"/>
+ <chemical_shift value="178.834" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="H"/>
+ <chemical_shift value="9.393" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CA"/>
+ <chemical_shift value="59.943" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="N"/>
+ <chemical_shift value="124.565" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="200" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="C"/>
+ <chemical_shift value="173.244" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CB"/>
+ <chemical_shift value="38.686" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CA"/>
+ <chemical_shift value="53.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="N"/>
+ <chemical_shift value="113.978" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="H"/>
+ <chemical_shift value="8.004" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="201" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="202" name="HZ1"/>
+ <atom segid=" A" residue="202" name="HZ2"/>
+ <atom segid=" A" residue="202" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CB"/>
+ <chemical_shift value="27.266" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="C"/>
+ <chemical_shift value="175.847" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="H"/>
+ <chemical_shift value="7.932" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CA"/>
+ <chemical_shift value="57.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="N"/>
+ <chemical_shift value="111.499" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="202" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="C"/>
+ <chemical_shift value="175.643" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HD1"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CB"/>
+ <chemical_shift value="28.529" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CA"/>
+ <chemical_shift value="57.268" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="N"/>
+ <chemical_shift value="116.235" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="H"/>
+ <chemical_shift value="8.354" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="ND1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="203" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="204" name="HE1"/>
+ <atom segid=" A" residue="204" name="HE2"/>
+ <atom segid=" A" residue="204" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="C"/>
+ <chemical_shift value="173.186" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CB"/>
+ <chemical_shift value="37.454" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CA"/>
+ <chemical_shift value="54.646" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="N"/>
+ <chemical_shift value="114.03" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="H"/>
+ <chemical_shift value="7.477" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="204" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="C"/>
+ <chemical_shift value="176.088" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CB"/>
+ <chemical_shift value="40.287" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CA"/>
+ <chemical_shift value="52.185" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="N"/>
+ <chemical_shift value="118.497" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="H"/>
+ <chemical_shift value="8.71" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="205" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="206" name="HB1"/>
+ <atom segid=" A" residue="206" name="HB2"/>
+ <atom segid=" A" residue="206" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="C"/>
+ <chemical_shift value="176.403" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="CB"/>
+ <chemical_shift value="18.252" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="CA"/>
+ <chemical_shift value="54.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="N"/>
+ <chemical_shift value="125.067" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="H"/>
+ <chemical_shift value="9.082" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="206" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="C"/>
+ <chemical_shift value="176.539" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CB"/>
+ <chemical_shift value="39.943" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CA"/>
+ <chemical_shift value="53.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="N"/>
+ <chemical_shift value="112.745" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="H"/>
+ <chemical_shift value="8.172" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="207" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="208" name="HG21"/>
+ <atom segid=" A" residue="208" name="HG22"/>
+ <atom segid=" A" residue="208" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="C"/>
+ <chemical_shift value="173.305" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CB"/>
+ <chemical_shift value="69.073" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CA"/>
+ <chemical_shift value="66.76" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="N"/>
+ <chemical_shift value="116.637" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="H"/>
+ <chemical_shift value="7.344" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="208" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="C"/>
+ <chemical_shift value="175.818" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CB"/>
+ <chemical_shift value="42.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CA"/>
+ <chemical_shift value="51.852" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="N"/>
+ <chemical_shift value="130.935" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="H"/>
+ <chemical_shift value="6.982" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="209" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="210" name="HD1"/>
+ <atom segid=" A" residue="210" name="HD2"/>
+ <atom segid=" A" residue="210" name="HE1"/>
+ <atom segid=" A" residue="210" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="C"/>
+ <chemical_shift value="178.37" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CB"/>
+ <chemical_shift value="39.077" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CA"/>
+ <chemical_shift value="63.648" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="N"/>
+ <chemical_shift value="117.467" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="H"/>
+ <chemical_shift value="7.858" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="210" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="C"/>
+ <chemical_shift value="177.629" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="CB"/>
+ <chemical_shift value="63.042" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="CA"/>
+ <chemical_shift value="61.419" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="N"/>
+ <chemical_shift value="114.682" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="H"/>
+ <chemical_shift value="8.202" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="211" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="212" name="HG21"/>
+ <atom segid=" A" residue="212" name="HG22"/>
+ <atom segid=" A" residue="212" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.867" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="212" name="HD11"/>
+ <atom segid=" A" residue="212" name="HD12"/>
+ <atom segid=" A" residue="212" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="C"/>
+ <chemical_shift value="179.021" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CB"/>
+ <chemical_shift value="38.613" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CA"/>
+ <chemical_shift value="65.023" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="N"/>
+ <chemical_shift value="124.45" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CD1"/>
+ <chemical_shift value="13.11" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="H"/>
+ <chemical_shift value="8.96" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="212" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="213" name="HB1"/>
+ <atom segid=" A" residue="213" name="HB2"/>
+ <atom segid=" A" residue="213" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="C"/>
+ <chemical_shift value="177.865" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="CB"/>
+ <chemical_shift value="17.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="CA"/>
+ <chemical_shift value="55.567" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="N"/>
+ <chemical_shift value="120.747" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="H"/>
+ <chemical_shift value="7.619" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="213" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="C"/>
+ <chemical_shift value="178.115" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CB"/>
+ <chemical_shift value="29.652" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CA"/>
+ <chemical_shift value="58.941" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="N"/>
+ <chemical_shift value="117.551" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="214" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="215" name="HB1"/>
+ <atom segid=" A" residue="215" name="HB2"/>
+ <atom segid=" A" residue="215" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="C"/>
+ <chemical_shift value="179.783" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="CB"/>
+ <chemical_shift value="18.034" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="CA"/>
+ <chemical_shift value="54.696" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="N"/>
+ <chemical_shift value="119.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="H"/>
+ <chemical_shift value="7.95" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="215" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="216" name="HB1"/>
+ <atom segid=" A" residue="216" name="HB2"/>
+ <atom segid=" A" residue="216" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="C"/>
+ <chemical_shift value="180.736" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="CB"/>
+ <chemical_shift value="19.732" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="CA"/>
+ <chemical_shift value="55.247" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="N"/>
+ <chemical_shift value="117.581" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="H"/>
+ <chemical_shift value="7.789" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="216" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="217" name="HD1"/>
+ <atom segid=" A" residue="217" name="HD2"/>
+ <atom segid=" A" residue="217" name="HE1"/>
+ <atom segid=" A" residue="217" name="HE2"/>
+ <atom segid=" A" residue="217" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CB"/>
+ <chemical_shift value="38.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CA"/>
+ <chemical_shift value="62.919" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="N"/>
+ <chemical_shift value="119.446" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="H"/>
+ <chemical_shift value="8.338" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="217" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="C"/>
+ <chemical_shift value="176.867" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CB"/>
+ <chemical_shift value="36.484" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CA"/>
+ <chemical_shift value="55.368" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="218" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="219" name="HZ1"/>
+ <atom segid=" A" residue="219" name="HZ2"/>
+ <atom segid=" A" residue="219" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CB"/>
+ <chemical_shift value="32.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="C"/>
+ <chemical_shift value="177.78" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="H"/>
+ <chemical_shift value="7.713" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CA"/>
+ <chemical_shift value="56.131" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="N"/>
+ <chemical_shift value="116.751" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="219" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="C"/>
+ <chemical_shift value="175.309" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="H"/>
+ <chemical_shift value="7.717" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="CA"/>
+ <chemical_shift value="46.152" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="N"/>
+ <chemical_shift value="108.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="220" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="C"/>
+ <chemical_shift value="175.803" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CB"/>
+ <chemical_shift value="30.469" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CA"/>
+ <chemical_shift value="57.326" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="N"/>
+ <chemical_shift value="116.369" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="H"/>
+ <chemical_shift value="8.382" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="OE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="221" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="222" name="HG21"/>
+ <atom segid=" A" residue="222" name="HG22"/>
+ <atom segid=" A" residue="222" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="C"/>
+ <chemical_shift value="172.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CB"/>
+ <chemical_shift value="70.566" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CA"/>
+ <chemical_shift value="58.169" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="N"/>
+ <chemical_shift value="110.551" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="H"/>
+ <chemical_shift value="6.855" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="222" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="223" name="HB1"/>
+ <atom segid=" A" residue="223" name="HB2"/>
+ <atom segid=" A" residue="223" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="C"/>
+ <chemical_shift value="176.461" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="CB"/>
+ <chemical_shift value="20.427" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="CA"/>
+ <chemical_shift value="54.727" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="N"/>
+ <chemical_shift value="127.376" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="H"/>
+ <chemical_shift value="8.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="223" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="224" name="HE1"/>
+ <atom segid=" A" residue="224" name="HE2"/>
+ <atom segid=" A" residue="224" name="HE3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="C"/>
+ <chemical_shift value="173.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CB"/>
+ <chemical_shift value="40.062" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CA"/>
+ <chemical_shift value="54.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="N"/>
+ <chemical_shift value="114.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="SD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="H"/>
+ <chemical_shift value="8.076" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="224" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="225" name="HG21"/>
+ <atom segid=" A" residue="225" name="HG22"/>
+ <atom segid=" A" residue="225" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="C"/>
+ <chemical_shift value="171.424" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CB"/>
+ <chemical_shift value="71.023" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CA"/>
+ <chemical_shift value="59.728" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="N"/>
+ <chemical_shift value="113.33" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="H"/>
+ <chemical_shift value="9.153" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="225" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="226" name="HG21"/>
+ <atom segid=" A" residue="226" name="HG22"/>
+ <atom segid=" A" residue="226" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.06" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="226" name="HD11"/>
+ <atom segid=" A" residue="226" name="HD12"/>
+ <atom segid=" A" residue="226" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.06" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="C"/>
+ <chemical_shift value="174.82" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CB"/>
+ <chemical_shift value="40.344" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CA"/>
+ <chemical_shift value="60.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="N"/>
+ <chemical_shift value="122.714" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CD1"/>
+ <chemical_shift value="11.775" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="H"/>
+ <chemical_shift value="7.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="226" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="C"/>
+ <chemical_shift value="175.514" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CB"/>
+ <chemical_shift value="42.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CA"/>
+ <chemical_shift value="52.466" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="N"/>
+ <chemical_shift value="121.906" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="H"/>
+ <chemical_shift value="8.472" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="227" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="H"/>
+ <chemical_shift value="8.192" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="CA"/>
+ <chemical_shift value="42.27" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="N"/>
+ <chemical_shift value="110.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="228" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CB"/>
+ <chemical_shift value="29.552" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CA"/>
+ <chemical_shift value="62.755" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="229" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="H"/>
+ <chemical_shift value="5.923" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CB"/>
+ <chemical_shift value="26.445" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CA"/>
+ <chemical_shift value="59.276" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="N"/>
+ <chemical_shift value="111.722" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="230" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="231" name="HB1"/>
+ <atom segid=" A" residue="231" name="HB2"/>
+ <atom segid=" A" residue="231" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="CB"/>
+ <chemical_shift value="19.11" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="CA"/>
+ <chemical_shift value="52.168" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="N"/>
+ <chemical_shift value="125.512" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="H"/>
+ <chemical_shift value="6.975" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="231" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CH2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HZ3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="H"/>
+ <chemical_shift value="7.198" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CB"/>
+ <chemical_shift value="28.673" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CA"/>
+ <chemical_shift value="58.678" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HZ2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="N"/>
+ <chemical_shift value="118.541" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="NE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="232" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="233" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="234" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="235" name="HG21"/>
+ <atom segid=" A" residue="235" name="HG22"/>
+ <atom segid=" A" residue="235" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="235" name="HD11"/>
+ <atom segid=" A" residue="235" name="HD12"/>
+ <atom segid=" A" residue="235" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="235" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="OD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="236" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="237" name="HG21"/>
+ <atom segid=" A" residue="237" name="HG22"/>
+ <atom segid=" A" residue="237" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="237" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="238" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="239" name="HZ1"/>
+ <atom segid=" A" residue="239" name="HZ2"/>
+ <atom segid=" A" residue="239" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="239" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="240" name="HG21"/>
+ <atom segid=" A" residue="240" name="HG22"/>
+ <atom segid=" A" residue="240" name="HG23"/>
+ <atom segid=" A" residue="240" name="HG11"/>
+ <atom segid=" A" residue="240" name="HG12"/>
+ <atom segid=" A" residue="240" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="240" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CB"/>
+ <chemical_shift value="37.371" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="H"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="241" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="242" name="HD1"/>
+ <atom segid=" A" residue="242" name="HD2"/>
+ <atom segid=" A" residue="242" name="HE1"/>
+ <atom segid=" A" residue="242" name="HE2"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="C"/>
+ <chemical_shift value="174.489" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="OH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CB"/>
+ <chemical_shift value="41.485" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CA"/>
+ <chemical_shift value="54.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="N"/>
+ <chemical_shift value="121.814" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HH"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="H"/>
+ <chemical_shift value="7.871" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="242" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="C"/>
+ <chemical_shift value="171.154" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="H"/>
+ <chemical_shift value="8.494" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="CA"/>
+ <chemical_shift value="42.935" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="N"/>
+ <chemical_shift value="107.501" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="243" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="244" name="HG21"/>
+ <atom segid=" A" residue="244" name="HG22"/>
+ <atom segid=" A" residue="244" name="HG23"/>
+ <chemical_shift value="0.636" error="0.0"/>
+ <chemical_shift value="1.072" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="244" name="HG11"/>
+ <atom segid=" A" residue="244" name="HG12"/>
+ <atom segid=" A" residue="244" name="HG13"/>
+ <chemical_shift value="0.636" error="0.0"/>
+ <chemical_shift value="1.072" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="C"/>
+ <chemical_shift value="174.872" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CB"/>
+ <chemical_shift value="34.455" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CA"/>
+ <chemical_shift value="61.547" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="N"/>
+ <chemical_shift value="120.896" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CG1"/>
+ <chemical_shift value="22.083" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="H"/>
+ <chemical_shift value="8.229" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="244" name="CG2"/>
+ <chemical_shift value="21.606" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="245" name="HG21"/>
+ <atom segid=" A" residue="245" name="HG22"/>
+ <atom segid=" A" residue="245" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="C"/>
+ <chemical_shift value="174.234" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CB"/>
+ <chemical_shift value="71.559" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CA"/>
+ <chemical_shift value="59.071" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="N"/>
+ <chemical_shift value="119.808" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="H"/>
+ <chemical_shift value="9.517" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="245" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="246" name="HG21"/>
+ <atom segid=" A" residue="246" name="HG22"/>
+ <atom segid=" A" residue="246" name="HG23"/>
+ <chemical_shift value="0.983" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="246" name="HG11"/>
+ <atom segid=" A" residue="246" name="HG12"/>
+ <atom segid=" A" residue="246" name="HG13"/>
+ <chemical_shift value="0.983" error="0.0"/>
+ <chemical_shift value="0.969" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="C"/>
+ <chemical_shift value="175.04" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CB"/>
+ <chemical_shift value="32.412" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CA"/>
+ <chemical_shift value="62.433" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="N"/>
+ <chemical_shift value="123.607" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CG1"/>
+ <chemical_shift value="20.441" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="H"/>
+ <chemical_shift value="8.158" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="246" name="CG2"/>
+ <chemical_shift value="21.596" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="247" name="HD21"/>
+ <atom segid=" A" residue="247" name="HD22"/>
+ <atom segid=" A" residue="247" name="HD23"/>
+ <chemical_shift value="0.645" error="0.0"/>
+ <chemical_shift value="0.663" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="247" name="HD11"/>
+ <atom segid=" A" residue="247" name="HD12"/>
+ <atom segid=" A" residue="247" name="HD13"/>
+ <chemical_shift value="0.645" error="0.0"/>
+ <chemical_shift value="0.663" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CB"/>
+ <chemical_shift value="40.229" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CA"/>
+ <chemical_shift value="54.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="N"/>
+ <chemical_shift value="125.542" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CD1"/>
+ <chemical_shift value="25.833" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="CD2"/>
+ <chemical_shift value="23.824" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="H"/>
+ <chemical_shift value="8.649" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="247" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="C"/>
+ <chemical_shift value="175.498" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CB"/>
+ <chemical_shift value="30.183" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CA"/>
+ <chemical_shift value="61.842" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="248" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="249" name="HG21"/>
+ <atom segid=" A" residue="249" name="HG22"/>
+ <atom segid=" A" residue="249" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="C"/>
+ <chemical_shift value="174.599" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CB"/>
+ <chemical_shift value="71.441" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CA"/>
+ <chemical_shift value="61.157" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="OG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="N"/>
+ <chemical_shift value="111.706" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="HG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="H"/>
+ <chemical_shift value="8.815" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="249" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="250" name="HD1"/>
+ <atom segid=" A" residue="250" name="HD2"/>
+ <atom segid=" A" residue="250" name="HE1"/>
+ <atom segid=" A" residue="250" name="HE2"/>
+ <atom segid=" A" residue="250" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="C"/>
+ <chemical_shift value="174.684" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CB"/>
+ <chemical_shift value="41.787" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CA"/>
+ <chemical_shift value="56.938" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="N"/>
+ <chemical_shift value="121.916" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="H"/>
+ <chemical_shift value="9.579" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="250" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="251" name="HZ1"/>
+ <atom segid=" A" residue="251" name="HZ2"/>
+ <atom segid=" A" residue="251" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CB"/>
+ <chemical_shift value="28.138" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="C"/>
+ <chemical_shift value="177.723" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="H"/>
+ <chemical_shift value="10.573" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CA"/>
+ <chemical_shift value="57.416" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="N"/>
+ <chemical_shift value="129.7" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="251" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="C"/>
+ <chemical_shift value="173.912" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="H"/>
+ <chemical_shift value="9.031" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="CA"/>
+ <chemical_shift value="45.086" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="N"/>
+ <chemical_shift value="103.626" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="252" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CB"/>
+ <chemical_shift value="29.298" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CA"/>
+ <chemical_shift value="52.486" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="N"/>
+ <chemical_shift value="122.357" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="H"/>
+ <chemical_shift value="8.245" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HE22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HE21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="NE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="OE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="253" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="C"/>
+ <chemical_shift value="178.676" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CB"/>
+ <chemical_shift value="31.093" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CA"/>
+ <chemical_shift value="62.977" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="254" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="C"/>
+ <chemical_shift value="173.658" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="CB"/>
+ <chemical_shift value="64.942" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="CA"/>
+ <chemical_shift value="62.323" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="N"/>
+ <chemical_shift value="117.984" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="H"/>
+ <chemical_shift value="8.002" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="255" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="256" name="HZ1"/>
+ <atom segid=" A" residue="256" name="HZ2"/>
+ <atom segid=" A" residue="256" name="HZ3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HE3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="NZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CB"/>
+ <chemical_shift value="33.307" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="C"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="H"/>
+ <chemical_shift value="7.639" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CA"/>
+ <chemical_shift value="53.191" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="N"/>
+ <chemical_shift value="123.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CE"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="256" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="C"/>
+ <chemical_shift value="177.147" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HD3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CB"/>
+ <chemical_shift value="31.379" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CA"/>
+ <chemical_shift value="62.452" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HG3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="N"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="CD"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="257" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="258" name="HD1"/>
+ <atom segid=" A" residue="258" name="HD2"/>
+ <atom segid=" A" residue="258" name="HE1"/>
+ <atom segid=" A" residue="258" name="HE2"/>
+ <atom segid=" A" residue="258" name="HZ"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="C"/>
+ <chemical_shift value="177.449" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CB"/>
+ <chemical_shift value="40.121" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CA"/>
+ <chemical_shift value="58.534" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="N"/>
+ <chemical_shift value="118.347" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CZ"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CE2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CE1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="H"/>
+ <chemical_shift value="9.265" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="CD2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="258" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="259" name="HG21"/>
+ <atom segid=" A" residue="259" name="HG22"/>
+ <atom segid=" A" residue="259" name="HG23"/>
+ <chemical_shift value="0.98" error="0.0"/>
+ <chemical_shift value="0.925" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="259" name="HG11"/>
+ <atom segid=" A" residue="259" name="HG12"/>
+ <atom segid=" A" residue="259" name="HG13"/>
+ <chemical_shift value="0.98" error="0.0"/>
+ <chemical_shift value="0.925" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="C"/>
+ <chemical_shift value="176.569" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CB"/>
+ <chemical_shift value="33.876" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CA"/>
+ <chemical_shift value="62.078" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="N"/>
+ <chemical_shift value="121.951" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CG1"/>
+ <chemical_shift value="21.509" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="H"/>
+ <chemical_shift value="8.777" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="259" name="CG2"/>
+ <chemical_shift value="22.697" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="C"/>
+ <chemical_shift value="171.463" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="H"/>
+ <chemical_shift value="8.961" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="CA"/>
+ <chemical_shift value="44.79" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="N"/>
+ <chemical_shift value="116.16" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="260" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="261" name="HG21"/>
+ <atom segid=" A" residue="261" name="HG22"/>
+ <atom segid=" A" residue="261" name="HG23"/>
+ <chemical_shift value="0.565" error="0.0"/>
+ <chemical_shift value="0.679" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="261" name="HG11"/>
+ <atom segid=" A" residue="261" name="HG12"/>
+ <atom segid=" A" residue="261" name="HG13"/>
+ <chemical_shift value="0.565" error="0.0"/>
+ <chemical_shift value="0.679" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="C"/>
+ <chemical_shift value="179.695" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CB"/>
+ <chemical_shift value="32.821" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CA"/>
+ <chemical_shift value="60.241" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="N"/>
+ <chemical_shift value="128.971" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CG1"/>
+ <chemical_shift value="20.308" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="H"/>
+ <chemical_shift value="11.175" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="261" name="CG2"/>
+ <chemical_shift value="20.936" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="262" name="HD21"/>
+ <atom segid=" A" residue="262" name="HD22"/>
+ <atom segid=" A" residue="262" name="HD23"/>
+ <chemical_shift value="0.885" error="0.0"/>
+ <chemical_shift value="0.806" error="0.0"/>
+ </spin_system>
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="262" name="HD11"/>
+ <atom segid=" A" residue="262" name="HD12"/>
+ <atom segid=" A" residue="262" name="HD13"/>
+ <chemical_shift value="0.885" error="0.0"/>
+ <chemical_shift value="0.806" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="C"/>
+ <chemical_shift value="175.254" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CB"/>
+ <chemical_shift value="41.091" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CA"/>
+ <chemical_shift value="56.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="N"/>
+ <chemical_shift value="134.056" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CD1"/>
+ <chemical_shift value="22.681" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="CD2"/>
+ <chemical_shift value="25.314" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="H"/>
+ <chemical_shift value="8.838" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="262" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="C"/>
+ <chemical_shift value="170.638" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="OG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="CB"/>
+ <chemical_shift value="66.154" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="CA"/>
+ <chemical_shift value="58.853" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="N"/>
+ <chemical_shift value="126.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="H"/>
+ <chemical_shift value="8.77" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="263" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="264" name="HB1"/>
+ <atom segid=" A" residue="264" name="HB2"/>
+ <atom segid=" A" residue="264" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="C"/>
+ <chemical_shift value="176.219" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="CB"/>
+ <chemical_shift value="20.73" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="CA"/>
+ <chemical_shift value="49.918" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="N"/>
+ <chemical_shift value="123.788" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="H"/>
+ <chemical_shift value="9.142" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="264" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="C"/>
+ <chemical_shift value="171.119" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="H"/>
+ <chemical_shift value="9.417" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="CA"/>
+ <chemical_shift value="42.908" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="N"/>
+ <chemical_shift value="110.739" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="HA2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="265" name="HA3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="FLOATING">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="266" name="HG21"/>
+ <atom segid=" A" residue="266" name="HG22"/>
+ <atom segid=" A" residue="266" name="HG23"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.915" error="0.0"/>
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+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="266" name="HD11"/>
+ <atom segid=" A" residue="266" name="HD12"/>
+ <atom segid=" A" residue="266" name="HD13"/>
+ <chemical_shift value="" error=""/>
+ <chemical_shift value="0.915" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="C"/>
+ <chemical_shift value="175.264" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CB"/>
+ <chemical_shift value="39.519" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CA"/>
+ <chemical_shift value="59.829" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="N"/>
+ <chemical_shift value="123.632" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CG1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HG12"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HG13"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CD1"/>
+ <chemical_shift value="13.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="H"/>
+ <chemical_shift value="10.299" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="HB"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="266" name="CG2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="C"/>
+ <chemical_shift value="177.436" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HD22"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HD21"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CB"/>
+ <chemical_shift value="38.767" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CA"/>
+ <chemical_shift value="53.657" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="CG"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="N"/>
+ <chemical_shift value="125.882" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="OD1"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="H"/>
+ <chemical_shift value="8.25" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="ND2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HB3"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="267" name="HB2"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="268" name="HB1"/>
+ <atom segid=" A" residue="268" name="HB2"/>
+ <atom segid=" A" residue="268" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="C"/>
+ <chemical_shift value="178.479" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="CB"/>
+ <chemical_shift value="17.854" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="CA"/>
+ <chemical_shift value="55.511" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="O"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="N"/>
+ <chemical_shift value="131.139" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="H"/>
+ <chemical_shift value="8.845" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="268" name="HA"/>
+ <chemical_shift value="" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="EQUIVALENT">
+ <spin_system averaging_method="FAST">
+ <atom segid=" A" residue="269" name="HB1"/>
+ <atom segid=" A" residue="269" name="HB2"/>
+ <atom segid=" A" residue="269" name="HB3"/>
+ <chemical_shift value="" error=""/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <spin_system averaging_method="NONE">
+ <atom segid=" A" residue="269" name="C"/>
+ <chemical_shift value="178.117" error="0.0"/>
+ </spin_system>
+ </shift_assignment>
+ <shift_assignment method="STEREO_SPECIFIC">
+ <